CN101891446B - Preparation method of novel energy-saving inorganic thermal insulation plate - Google Patents

Preparation method of novel energy-saving inorganic thermal insulation plate Download PDF

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Publication number
CN101891446B
CN101891446B CN2010102176715A CN201010217671A CN101891446B CN 101891446 B CN101891446 B CN 101891446B CN 2010102176715 A CN2010102176715 A CN 2010102176715A CN 201010217671 A CN201010217671 A CN 201010217671A CN 101891446 B CN101891446 B CN 101891446B
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China
Prior art keywords
thermal insulation
insulation plate
novel energy
preparation
weight part
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Expired - Fee Related
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CN2010102176715A
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Chinese (zh)
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CN101891446A (en
Inventor
王秋彬
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QUANZHOU QUANGANG DISTRICT HANGLI INDUSTRY TRADE Co Ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/001Alkaline earth metal or Mg-compounds
    • C04B2103/0012Mg
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Building Environments (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a preparation method of a novel energy-saving inorganic thermal insulation plate, which comprises the steps of taking magnesium oxide, magnesium chloride and environment-friendly filling material as main raw materials, adding polystyrene foam and anti-aging agent SP for preparing slurry, sequentially carrying out forming, curing, stripping and secondary curing on the slurry, and finally obtaining the novel energy-saving inorganic thermal insulation plate. The novel energy-saving inorganic thermal insulation plate prepared through the method has the characteristics of good thermal insulation effect, low cost, light weight, convenient installation, energy conservation and environmental protection; and the production process does not produce the waste, thereby being in line with the environment-friendly production requirements.

Description

The preparation method of novel energy-saving inorganic thermal insulation plate
Technical field
The present invention relates to a kind of material of construction, specifically the heat insulation preparation method of a kind of novel energy-saving inorganic.
Background technology
Lagging material on construction market is various in style at present, and as hollow concrete block, interbedded water mud product, extruded sheet etc., hollow concrete block and interbedded water mud product are large because of its load-bearing, cause producing, taking time and effort when constructing, and effect of heat insulation is undesirable; And extruded sheet not only cost is too high, and due to the combustibility of extruded sheet, can discharge obnoxious flavour during burning, as CO, CO 2Deng.And when construction, require first levelling to lay, also to add iron wire or the reinforcing bar of diameter 4-8mm above extruded sheet, then spread the concrete mortar, re-lay the higher wear resistant products of steel brick or color density and beautify roofing, so both increased construction cost, also increased the load of buildings, and be difficult to apply.Therefore, develop a kind of good heat-insulation effect, cost is low, quality is light, the lagging material of easy for installation and energy-conserving and environment-protective, just becomes the objective of the struggle that the knowledgeable people seek assiduously.
Summary of the invention
The preparation method who the purpose of this invention is to provide a kind of novel energy-saving inorganic thermal insulation plate by the novel energy-saving inorganic thermal insulation plate that the inventive method prepares, has good heat-insulation effect, cost is low, quality is light, the characteristics of easy for installation and energy-conserving and environment-protective.
Technical scheme of the present invention is such: the preparation method of novel energy-saving inorganic thermal insulation plate, realize as follows:
One, preparation slurry:
A, the magnesium chloride and the sal epsom that are 5-7: 0.75-1 with mass ratio are dissolved into the mixing solutions that concentration is the 24-26 degree Beaume;
B, the mixing solutions of getting 80-100 weight part steps A gained and the magnesium oxide of 100-120 weight part mix, and stir to obtain gelinite;
Add the environment-protection filling material of 20-95 weight part in C, the gelinite with step B gained, and stir;
D, add again the polyphenyl alkene foam of 5-15 weight part on the basis of step C, again stir;
E, add again the antioxidant SP of 0.2-1.0 weight part on the basis of step D, again stir, obtain required slurry;
Two, moulding: adopt known technique commonly used, will be pressed into blanket through slurry and the lining material one that step 1 prepares by the plate forming sheet-leveling machine;
Three, maintenance: above-mentioned blanket is delivered in curing room under normal temperature maintenance 12-24 hour;
Four, the demoulding: the demoulding by conventional methods obtains slab;
Five, secondary maintenance: the slab buttress that the above-mentioned demoulding is obtained piles up normal temperature laboratory and carried out the secondary maintenance 7-30 days, namely obtains novel energy-saving inorganic thermal insulation plate of the present invention.
In above-mentioned steps C, described environment-protection filling material comprises the stone flour of 20-80 weight part, and the wood saw end of 0-15 weight part or straw end.
In above-mentioned steps E, also add the silicon-dioxide of 0.1-0.5 weight part.
In above-mentioned steps E, also add the titanium dioxide of 0.1-0.5 weight part.
In above-mentioned steps two, lining material used is glass-fiber-fabric and non-woven fabrics, and slurry is tiled between glass-fiber-fabric and non-woven fabrics.
Above-mentioned glass-fiber-fabric is two layers to four layers that are stacked.
After adopting such scheme, in the inventive method, take magnesium oxide, magnesium chloride and environment-protection filling material as main raw material, and add polyphenyl alkene foam and antioxidant SP is made slurry.The environment-protection filling material can adopt wood saw end or straw, and the discarded stone flour of stone processing industry, adds stone flour and can reduce magnesian consumption, saves cost; Add wood saw end or straw and can strengthen toughness and the splitting resistance of goods, and be the waste recycling, economize on resources, reduce costs; Antioxidant SP have do not absorb heat, the characteristics such as resistance to oxidation; Polyphenyl alkene foam can reduce the density of goods, and can cut off the pore of goods, the favourable halogen that returns, the water-intake rate of minimizing goods.Therefore, by the prepared novel energy-saving inorganic thermal insulation plate of the inventive method, have good heat-insulation effect, cost is low, quality is light, the characteristics of easy for installation and energy-conserving and environment-protective; And there is no waste in production process, meet the production requirement of environment-friendly type.
In the inventive method, the silicon-dioxide that adds in slurry and titanium dioxide can increase wear resistance, acid resistance and the oil-proofness of goods.
In the inventive method, use glass-fiber-fabric as lining material in moulding, can strengthen the intensity of goods, and improve the heat-proof quality of goods.
Embodiment
The preparation method of novel energy-saving inorganic thermal insulation plate of the present invention, realize as follows:
One, preparation slurry:
A, the magnesium chloride and the sal epsom that are 5-7: 0.75-1 with mass ratio are dissolved into the mixing solutions that concentration is the 24-26 degree Beaume, best desirable 7: 1 of the mass ratio of magnesium chloride and sal epsom, desirable 25 degree Beaume of the optimum concn of this mixing solutions;
B, the mixing solutions of getting 80-100 gram steps A gained and the magnesium oxide of 100-120 gram mix, and stir and obtain gelinite, and the optimum amount of this mixing solutions can be 100 grams, and magnesian optimum amount can be 100 grams;
Add the environment-protection filling material of 20-95 weight part in C, the gelinite with step B gained, and stir, the environment-protection filling material here can use the stone flour of 20-80 gram, and the wood saw end of 0-15 gram or straw end; Stone flour, wood saw end or straw end are ground into 120-200 purpose fineness;
D, add 5-15 gram polyphenyl alkene foam on the basis of step C again, again stir, the optimum amount of polyphenyl alkene foam can be 5 grams;
The silicon-dioxide of E, the antioxidant SP that adds again the 0.2-1.0 gram on the basis of step D, 0.1-0.5 gram and the titanium dioxide of 0.1-0.5 gram stir again, obtain required slurry;
Two, moulding: adopt known technique commonly used, will be pressed into blanket through slurry and the lining material one that step 1 prepares by the plate forming sheet-leveling machine; The lining material here adopts glass-fiber-fabric and non-woven fabrics, and slurry is tiled between glass-fiber-fabric and non-woven fabrics, and glass-fiber-fabric adopts two layers to four layers that are stacked;
Three, maintenance: above-mentioned blanket was delivered in curing room under normal temperature (25 ℃ of left and right) maintenance 12-24 hour;
Four, the demoulding: the demoulding by conventional methods obtains slab;
Five, secondary maintenance: the slab buttress that the above-mentioned demoulding is obtained piles up normal temperature laboratory and carried out the secondary maintenance 7-30 days, namely obtains novel energy-saving inorganic thermal insulation plate of the present invention.
In the inventive method, can clean stirrer and board after every day, production was completed, sewage after cleaning is changed pond sedimentation and filtration step by step through three, also contain the magnesium chloride solution of certain degree Beaume and needed other material compositions of goods of the inventive method gained in its supernatant liquor, the raw material of this supernatant liquor as slurry re-used, can save the consumption of magnesium chloride and water, can further reduce production costs.
In the inventive method, goods need not special oven dry setting in maintenance processes, only need to allow it naturally congeal under normal temperature in curing room, effectively prevent the waste of resource and the energy.
By the goods that the inventive method makes, do not use the raw material of any urea-formaldehyde resin class, can not produce formaldehyde phenylamino and radiocontamination, belong to very Green Product.
By the novel energy-saving inorganic thermal insulation plate that the inventive method makes, have following advantage:
1, quality is light: take the sheet material of thickness 10mm as example, the weight of its unit surface is 14g/m 2
2, good heat-insulation effect: take the sheet material of thickness 10mm as example, when the sun is exposed to the sun in full summer, the temperature of outdoor cement or brick face can reach 55-56 ℃, indoor common plate surface temperature reaches 47-50 ℃, and the indoor plate surface temperature of laying product of the present invention only has 35-35.5 ℃, only is equivalent to the temperature of open-air.
3, use and easy for installation: product of the present invention can be sawed, can throw, can bore, can follow closely, and arbitrarily assembly unit can be carried when not fixing at any time, can be bonding with grout when fixing, manufacture craft is identical with the laying floor brick, need not special processing, need not be soaked, can save a large amount of manpower and financial resources.
4, this product also has corrosion-resistant, acid and alkali-resistance, wear-resistant, the advantage of hardness good toughness, and work-ing life is longer.

Claims (6)

1. the preparation method of novel energy-saving inorganic thermal insulation plate is characterized in that: realize as follows:
One, preparation slurry:
A, the magnesium chloride and the sal epsom that are 5-7: 0.75-1 with mass ratio are dissolved into the mixing solutions that concentration is the 24-26 degree Beaume;
B, the mixing solutions of getting 80-100 weight part steps A gained and the magnesium oxide of 100-120 weight part mix, and stir to obtain gelinite;
Add the environment-protection filling material of 20-95 weight part in C, the gelinite with step B gained, and stir;
D, add again the polyphenyl alkene foam of 5-15 weight part on the basis of step C, again stir;
E, add again the antioxidant SP of 0.2-1.0 weight part on the basis of step D, again stir, obtain required slurry;
Two, moulding: adopt known technique commonly used, will be pressed into blanket through slurry and the lining material one that step 1 prepares by the plate forming sheet-leveling machine;
Three, maintenance: above-mentioned blanket is delivered in curing room under normal temperature maintenance 12-24 hour;
Four, the demoulding: the demoulding by conventional methods obtains slab;
Five, secondary maintenance: the slab buttress that the above-mentioned demoulding is obtained piles up normal temperature laboratory and carried out the secondary maintenance 7-30 days, namely obtains novel energy-saving inorganic thermal insulation plate.
2. the preparation method of novel energy-saving inorganic thermal insulation plate according to claim 1, it is characterized in that: in above-mentioned steps C, described environment-protection filling material comprises the stone flour of 20-80 weight part, and the wood saw end of 0-15 weight part or straw end.
3. the preparation method of novel energy-saving inorganic thermal insulation plate according to claim 1, is characterized in that: in above-mentioned steps E, also add the silicon-dioxide of 0.1-0.5 weight part.
4. the preparation method of novel energy-saving inorganic thermal insulation plate according to claim 1, is characterized in that: in above-mentioned steps E, also add the titanium dioxide of 0.1-0.5 weight part.
5. the preparation method of novel energy-saving inorganic thermal insulation plate according to claim 1, it is characterized in that: in above-mentioned steps two, lining material used is glass-fiber-fabric and non-woven fabrics, and slurry is tiled between glass-fiber-fabric and non-woven fabrics.
6. the preparation method of novel energy-saving inorganic thermal insulation plate according to claim 5, it is characterized in that: above-mentioned glass-fiber-fabric is two layers to four layers that are stacked.
CN2010102176715A 2010-06-29 2010-06-29 Preparation method of novel energy-saving inorganic thermal insulation plate Expired - Fee Related CN101891446B (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036694A (en) * 2015-07-08 2015-11-11 苏州金莘保温材料科技有限公司 Silica purification material and preparation method therefor
CN105272132A (en) * 2015-09-28 2016-01-27 宁夏中汇盛丰建材科技有限公司 Energy-saving and environment-protection lightweight separation wall
CN105330333B (en) * 2015-10-22 2018-07-06 海门市泰利来新型建材有限公司 Environmentally friendly integrated building lightweight assembled composite wall body material and its production technology
CN109574618A (en) * 2018-12-13 2019-04-05 广东国汇新材料有限公司 Modified magnesite anti-fire door core board and the preparation method and application thereof
CN111689754B (en) * 2019-12-06 2022-03-25 江苏中砼新材料科技有限公司 Fireproof heat-insulating lightweight concrete for roof pouring

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3514269A (en) * 1966-01-26 1970-05-26 Fuji Chem Ind Co Ltd Process for manufacture of dimagnesium aluminosilicate for medical uses
CN1093431A (en) * 1993-12-10 1994-10-12 张树荣 The lightweight composite building board
CN1302779A (en) * 2001-01-23 2001-07-11 董月 Building decoration material and preparation method thereof
CN101386515A (en) * 2007-09-13 2009-03-18 江苏江中集团有限公司 Light flame-retardant decorating material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3514269A (en) * 1966-01-26 1970-05-26 Fuji Chem Ind Co Ltd Process for manufacture of dimagnesium aluminosilicate for medical uses
CN1093431A (en) * 1993-12-10 1994-10-12 张树荣 The lightweight composite building board
CN1302779A (en) * 2001-01-23 2001-07-11 董月 Building decoration material and preparation method thereof
CN101386515A (en) * 2007-09-13 2009-03-18 江苏江中集团有限公司 Light flame-retardant decorating material and preparation method thereof

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Owner name: QUANZHOU QUANGANG DISTRICT HANGLI INDUSTRY + TRADE

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Address after: 362114 village head village, Tu Ling Town, Quangang District, Fujian, Quanzhou

Patentee after: Quanzhou Quangang District Hangli Industry Trade Co., Ltd.

Address before: 362114, No. 108 South Tian Village, Tu Ling Town, Quangang District, Fujian, Quanzhou

Patentee before: Wang Qiubin

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130605

Termination date: 20160629