CN102014617A

CN102014617A - Emulsifiable concentrate

Info

Publication number: CN102014617A
Application number: CN2009801158471A
Authority: CN
Inventors: C·迪勒曼; M·克拉普; U·史添布仁诺; A·谢弗尔; S·库恩; E·迪尔曼
Original assignee: BASF SE
Current assignee: BASF SE
Priority date: 2008-04-08
Filing date: 2009-04-07
Publication date: 2011-04-13
Anticipated expiration: 2029-04-07
Also published as: CN102014617B; WO2009124920A3; BRPI0910402A2; EP2303006A2; MX2010010335A; EA017661B1; EA201001575A1; TW200948269A; AR071465A1; CR11694A; WO2009124920A2

Abstract

The present application relates to an emulsifiable concentrate (EC) formulation, comprising: a) a fungicidal triazole or an agriculturally acceptable salt or adduct thereof; b) a solvent system, comprising: b1 ) a substituted phenole; b2) one or more organic solvents; c) one or more emulsifiers; d) optionally, further formulation additives, a process for their preparation and a use for controlling harmful fungi.

Description

Emulsifiable concentrate

The present invention relates to comprise emulsifiable concentrate (EC), its production method and such EC purposes in the control harmful fungoid of fungicidal triazole class.

EP-A 0,357 559 discloses the aqueous formulation of water-insoluble crop protection agents (especially furathiocarb (furathiocarb)) and substituted phenol, and it has suppressed the crystallization of furathiocarb or has stablized this emulsion.

EP-A 0,505 053 discloses the aqueous formulation that comprises Prochloraz (prochloraz), non-ionic surface active agent and substituted phenol.

Especially triazole type such as oxole bacterium (epoxiconazole) are mixed with suspending concentrate (SC).EP-A 0,707 445 discloses the moisture heterogeneous stable preparaton of the crop protection reactive compound that comprises block polymer, anion surfactant, wetting agent and thickener.

These SC preparatons are difficult to preparation, for example are difficult to by grinding active component evenly be distributed to avoid sedimentation.

The SC preparaton needs stabilisation, especially in the presence of auxiliary agent or continuous phase, because active component is owing to the solvability in continuous phase is tended to crystallization.

Therefore, the purpose of this invention is to provide a kind of preparaton of stablizing and having the above-claimed cpd of high bioactivity that stores and use.

Have now found that the EC preparaton that this purpose can the application of the invention realizes.

Therefore, in one aspect of the invention, provide emulsifiable concentrate (EC) preparaton, it comprises:

But a) fungicidal triazole class or its agricultural salt or adduct,

B) comprise b1) substituted phenol, b2) dicyandiamide solution of one or more organic solvents,

C) one or more emulsifier,

D) optional other additive preparations.

EC preparaton of the present invention has excellent storage stability and biologically active.

But suitable antifungal triazole type or its agricultural salt or adduct be penta ring azoles (azaconazole), Bitertanol (bitertanol), bromuconazole (bromuconazole), cyproconazole (cyproconazole),

Ether azoles (cifenoconazole), alkene azoles alcohol (diniconazole), alkene azoles alcohol M (diniconazole-M), oxole bacterium, RH-7592 (fenbuconazole), Fluquinconazole (fluquinconazole), Flusilazole (flusilazole), Flutriafol (flutriafol), own azoles alcohol (hexaconazole), acid amides azoles (imibenconazole), cycltebuconazole (ipconazole), encircle penta azoles bacterium (metconazole), nitrile bacterium azoles (myclobutanil), oxpoconazole, paclobutrazol (paclobutrazole), penconazole (penconazole), propiconazole (propiconazole), prothioconazoles (prothioconazole), simeconazoles (simeconazole), Tebuconazole (tebuconazole), fluorine ether azoles (tetraconazole), triazolone (triadimefon), triadimenol (triadimenol), triticonazole (triticonazole), uniconazole P (uniconazole), 1-(4-chlorphenyl)-2-([1,2,4] suberol triazol-1-yl).

These triazole type are known and are described in Www.alanwood.net/pesticides/ Index cn frame.htmlIn.

Preferred triazole type is oxole bacterium, Fluquinconazole, cycltebuconazole, ring penta azoles bacterium, propiconazole, prothioconazoles, Tebuconazole and triticonazole.

Oxole bacterium most preferably.

Because the basic character of the nitrogen-atoms of Compound I, Compound I can form salt or adduct with inorganic or organic acid or metal ion.

Representative examples of mineral pigments is a halogen acids, as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, and carbonic acid, sulfuric acid, phosphoric acid and nitric acid.

Appropriate organic for example is formic acid and alkanoic acid, as acetate, trifluoroacetic acid, trichloroacetic acid and propionic acid, also has glycolic, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid, cinnamic acid, oxalic acid, alkyl sulfonic acid (having the straight chain of 1-20 carbon atom or the sulfonic acid of branched-alkyl), aryl sulfonic acid or the aryl disulfonic (aromatic group that has one or two sulfonic acid group, as phenyl and naphthyl), alkyl phosphonic acid (having the straight chain of 1-20 carbon atom or the phosphonic acids of branched-alkyl), arylphosphonic acid or the aryl di 2 ethylhexyl phosphonic acid (aromatic group that has one or two phosphate group, as phenyl and naphthyl), wherein alkyl or aryl can have other substituting groups, for example p-methyl benzenesulfonic acid, salicylic acid, Para-amino-salicylic acid, the 2-phenoxy benzoic acid, 2-acetoxy-benzoic acid etc.

Suitable metal ion is the ion of second major element especially, especially the ion of calcium and magnesium, the ion of third and fourth major element, especially aluminium, tin and plumbous ion, and the ion of the ion of first to the 8th transition element, especially chromium, manganese, iron, cobalt, nickel, copper, zinc and other elements.The metal ion of preferred especially period 4 transition element.Metal can exist with the various valence states that they may present.

EC preparaton of the present invention comprises 0.1-30 weight % usually, preferred 3-20 weight %, the especially component of 5-15 weight % antifungal triazole type a).

EC preparaton of the present invention comprises 6-97 weight % usually, preferred 10-90 weight %, especially 15-80 weight % dicyandiamide solution (b).

Components b 1) be the substituted phenol of following formula:

R ¹-O-X，

R wherein ¹For by 1-3 C ₁-C ₁₂Phenyl and X that alkyl replaces are hydrogen, alkali metal, alkaline earth metal or NR ₃, wherein each R is identical or different and be hydrogen or the optional C that is replaced by hydroxyl ₁-C ₈Alkyl.

C ₁-C ₁₂Alkyl is linearity or the branched-alkyl with 1-12 carbon atom.Example is a methyl, ethyl, propyl group, isopropyl, normal-butyl, sec-butyl, isobutyl group, the tert-butyl group, amyl group, the 1-methyl butyl, the 2-methyl butyl, the 3-methyl butyl, 2, the 2-dimethyl propyl, the 1-ethyl propyl, 1, the 1-dimethyl propyl, 1, the 2-dimethyl propyl, hexyl, the 1-methyl amyl, the 2-methyl amyl, the 3-methyl amyl, the 4-methyl amyl, 1, the 1-dimethylbutyl, 1, the 2-dimethylbutyl, 1, the 3-dimethylbutyl, 2, the 2-dimethylbutyl, 2, the 3-dimethylbutyl, 3, the 3-dimethylbutyl, the 1-ethyl-butyl, the 2-ethyl-butyl, 1,1,2-trimethyl propyl group, 1,2,2-trimethyl propyl group, 1-ethyl-1-methyl-propyl, 1-ethyl-2-methyl-propyl, heptyl, octyl group, the 2-ethylhexyl, nonyl, decyl, undecyl, dodecyl and position isomer thereof.

The example of suitable substituted phenol is 2,3,6-pseudocuminol, p-tert-butylphenol, neighbour-sec-butyl phenol, 2-tert-butyl phenol, right-tert-amyl phenol, heptyl derivative (right-heptylphenol), to tert-octyl phenol, paraoctyl phenol, 2,4-DI-tert-butylphenol compounds, 2,6-DI-tert-butylphenol compounds, right-(α, α-Er Jiajibianji) phenol, to nonyl phenol, 2, the 4-di-tert-pentyl phenol, to dodecyl phenol, 4-sec-butyl-2,6-DI-tert-butylphenol compounds, 2,4,6-tri-butyl-phenol and 2,4-two (α, α-Er Jiajibianji) phenol.

Preferred substituted phenol is p-t-butyl phenol, neighbour-sec-butyl phenol, 2-tert-butyl phenol, 2,4-DI-tert-butylphenol compounds, 2,6-DI-tert-butylphenol compounds, 4-sec-butyl-2,6-DI-tert-butylphenol compounds and 2,4,6-tri-butyl-phenol.

Neighbour-sec-butyl phenol most preferably.

Dicyandiamide solution comprises organic solvent as component (b2).Preferred mixture, the especially alkylbenzene of alkylaromatic hydrocarbon and the mixture of Fluhyzon of using, its alkyl has 1-20 carbon atom.Such mixture can be commercial, for example with As Solvesso 200 (Exxon Mobil, USA), Aromatic such as Aromatic 200 (Exxon Mobil) or

(German Deutsche ShellChemie GmbH) is commercial for product.Other suitable organic solvents as component (b2) are paraffin, alcohols, pyrrolidinone compounds, acetate esters, glycols, fatty acid, dimethylformamide class, fatty acid dimethylformamide, fatty acid ester and composition thereof.

The example of suitable solvent (b2) is a methyl alcohol, ethanol, isopropyl alcohol, butanols, amylalcohol, 2-Ethylhexyl Alcohol, 1,3-dimethyl-2-imidazolone, 2-methyl-2, the 4-pentanediol, acetone, acetophenone, propionic acid, 2-hydroxyl-2-ethylhexyl, the carbonic acid di-n-octyl, benzyl acetate, benzylalcohol, Ergol, cyclohexane, cyclohexanol, cyclohexanone, butyl lactate, lactic acid 2-ethylhexyl, ethyl lactate, methyl lactate, lactic acid n-propyl ester, tetrahydrofurfuryl alcohol, mixed xylenes (xylole), diethylene glycol (DEG), dimethyl formamide, methyl-sulfoxide, dipropylene glycol, 5-methyl-3-heptanone, ethylene glycol, gamma-butyrolacton, glycerine, hexanol, isopropyl alcohol, butylene carbonate, propylene carbonate, methyl benzoate, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), the N-ethyl-2-pyrrolidone, N-methyl caprolactam (caprolactame), N-octyl group-2-Pyrrolidone, propionic acid and composition thereof.

Especially preferably as component (b2) be Solvesso 200, Solvesso 200 ND, Solvesso150 ND, Caromax 28 LN, Aromatic 200 and Hydrosol A 230/270 ND.

Organic solvent component (b2) accounts for the 1-35 weight % of this preparaton usually, preferred 1-30 weight %, especially 5-25 weight %.

EC preparaton of the present invention also contains at least a emulsifier.This emulsifier is used to reduce the surface tension between continuous phase and the disperse phase, the drop of stable dispersion phase thus.This emulsifier also helps the solubilization of triazole type.Suitable emulsifier is well known in the art, for example by McCutcheon ' sDetergents and Emulsifiers, and Int.Ed., Ridgewood, New York is known.Suitable emulsifier comprises nonionic, anion, cation and amphion emulsifier and composition thereof.Emulsifier can be polymer emulsifier or non-polymer emulsifier.Opposite with polymer emulsifier, the non-polymer emulsifier has usually and is lower than 2000 (number average), especially 150-2000, the molecular weight of preferred 200-1500.

Contained emulsifier can be nonionic or ionic among the EC of the present invention, or the combination of the two.At least two kinds of preferred uses, preferred 3-5 kind emulsifier, the emulsifier that preferably has different HLB values is to realize the good physical chemical behavior of this EC under different temperatures.

HLB (hydrophilic lipophilic balance) is the experience yardstick by the amphipathic characteristic of the expression emulsifier (particularly nonionic emulsifier) of W.C.Griffin (J.Soc.Cosmetic Chemists, 1,311 (1949)) definition.Least hydrophilic emulsifier has minimum HLB value.

Suitable nonionic emulsifier for example for the alkoxylated fats in animal or plant source or oil as the corn oil ethoxylate, castor oil ethoxylate, the tallow ethoxylate, glyceride such as glyceryl monostearate, fatty alcohol alkoxy compound and oxo alcohol alcoxylates, fatty acid alkoxylates such as oleic acid ethoxylate, alkyl phenyl alcoxylates such as different nonyl-, iso-octyl-, tributyl-and three stearyl phenyl ethoxy things, the fatty amine alcoxylates, fatty acid amide alkoxy compound, emulsifying saccharide agent such as fatty acid esters of sorbitan (Arlacel-80, Arlacel-65), polyoxyethylene sorbitan fatty acid ester, alkyl poly glucoside, the N-alkyl glucose amide, the alkyl methyl sulfoxide, alkyl dimethyl phosphine oxide such as myristyl dimethyl oxidation phosphine, the mixture of ethylene oxide/propylene oxide copolymer and such nonionic emulsifier.

Nonionic emulsifier especially comprises:

-poly--C ₂-C ₃Oxyalkylene C ₈-C ₂₂Alkyl ether, especially linearity or branching C ₈-C ₂₂The polyethoxylate of alkanol and polyethoxylated-co-propoxylate, more preferably polyethoxylated fatty alcohol and polyethoxylated oxo alcohol, as polyethoxylated laruyl alcohol, the different tridecanol of polyethoxylated, polyethoxylated cetanol, polyethoxylated stearyl alcohol, and their ester, as acetic acid esters;

-poly--C ₂-C ₃Oxyalkylene aryl ether and poly--C ₂-C ₃Oxyalkylene C ₁-C ₁₆Alkyl aryl ether is as poly--C ₂-C ₃Oxyalkylene C ₈-C ₂₂Alkyl phenylate, especially C ₁-C ₁₆The polyethoxylate of alkyl phenol, as the polyethoxylate of nonyl phenol, decyl phenol, isodecyl phenol, dodecyl phenol or isotridecyl phenol,

-poly--C ₂-C ₃The oxyalkylene list-, two-or triphenylethylene base phenyl ether, especially single-, two-and the polyethoxylate of triphenyl vinyl phenol; And their formaldehyde condensation products and ester, for example acetic acid esters;

-C ₆-C ₂₂Alkyl glucoside and C ₆-C ₂₂Alkyl polyglucoside;

-C ₆-C ₂₂The polyethoxylate of alkyl glucoside and C ₆-C ₂₂The polyethoxylate of alkyl polyglucoside;

The polyethoxylate of-fatty amine;

The polyethoxylate of-fatty acid and the polyethoxylate of hydroxy fatty acid;

-polyalcohol and C ₆-C ₂₂The monoesters of part ester, the especially glycerine of alkanoic acid and the monoesters of diester and anhydro sorbitol, diester and three esters are as glyceryl monostearate, Arlacel-80, Arlacel-65;

-polyalcohol and C ₆-C ₂₂The polyethoxylate of the part ester of alkanoic acid, especially the polyethoxylate of the monoesters of the polyethoxylate of the monoesters of glycerine and diester and anhydro sorbitol, diester and three esters is as the polyethoxylate of glyceryl monostearate, the polyethoxylate of Arlacel-80, the polyethoxylate of Arlacel-60 and the polyethoxylate of Arlacel-65;

The polyethoxylate of-vegetable oil or animal tallow such as corn oil ethoxylate, castor oil ethoxylate, tallow ethoxylate;

-acetylenediol is as 2,4,7,9-tetramethyl-4,7-dihydroxy-5-decine;

-polyox-yethylene-polyoxypropylene block copolymer; With

The polyethoxylate of-fatty amine, fatty acid amide or fatty diglycollic amide.

Term gathers-C ₂-C ₃Oxyalkylene ether refers to be derived from the polyether group of ethylene oxide or propylene oxide.The term polyethoxylate refers to be derived from the polyether group of ethylene oxide.Equally, term polyoxyethylene-co-polyoxypropylene refers to be derived from the polyether group of the mixture of ethylene oxide and propylene oxide.Number of repeat unit in the polyether group is generally 4-100, especially 5-50.

Preferred nonionic emulsifier for example is a fatty acid esters of sorbitan, especially the part ester of sorbierite and acid anhydrides thereof, Arlacel-80 for example, polyoxyethylene sorbitan fatty acid ester, as polyethoxylated (preferred about 20 mole ethylene oxides) Arlacel-20 and Arlacel-80, castor oil ethoxylate (preferred about 40 mole ethylene oxides), and ethylene oxide/propylene oxide copolymer, as alkyl ethylene oxide/propylene oxide copolymer, preferred molecular weight is 2000-5000.

Ionic emulsifying agent can be the mixture of anion emulsifier or cationic emulsifier or anion emulsifier and cationic emulsifier.

The example of anion emulsifier is poly-(preferred 2-30) ethoxylation (preferred C ₆-C ₂₂) (2EO (EO represents ethylene oxide unit) oleyl alcohol phosphate (for example for fatty alcohol phosphate and sulfuric ester such as ethoxylation

O3D, Albright ﹠amp; Wilson, UK), ethoxylation oleyl alcohol phosphate (for example

Series, Croda Oleochemicals, UK), ethoxylation (2-10EO) 16/octadecanol phosphate is (for example

CS series, Croda Oleochemicals, UK), ethoxylation (4-6EO) tridecanol phosphate is (for example

PS series, CK Witco, USA), the ethoxylized fatty alcohol phosphate is (for example Series, Spain HenkelIberica), ethoxylation (3-6EO) fatty alcohol phosphate is (for example

Series, French Rhodia Chimie), the free acid of compound organophosphorus ester is (for example

Series, France Ceca S.A.), the phosphate of polyethoxylated (8-25 EO) aryl phenol (as polyethoxylated two-and triphenyl vinyl phenol) (Soprophor 3D33 for example, France Rhodia Chimie), the sulfuric ester of polyethoxylated aryl phenol (as polyethoxylated two-and triphenyl vinyl phenol) (SoprophorDSS/7 for example, Soprophor 4D384, French Rhodia Chimie).

Anion emulsifier especially comprises following sodium, potassium, calcium or ammonium salt:

-C ₆-C ₂₂Alkylsulfonate such as lauryl sulfonate, isotridecyl sulfonate;

-C ₆-C ₂₂Alkyl sulfate such as lauryl sulfate, isotridecyl sulphate, cetyl sulphate and stearin-based sulfate;

-aryl-and sulfonate, especially C ₁-C ₁₆Alkylbenzenesulfonate, as cumyl sulfonate, octyl group benzene sulfonate, nonylbenzene sulfonates and dodecyl benzene sulfonate, naphthalene sulfonate, single-and two-C ₁-C ₁₆Alkylnaphthalene sulfonate such as dibutyl naphthalene sulfonate;

-single-and two-C ₁-C ₁₆Alkyl diphenyl base ether (two) sulfonate such as dodecyl diphenyl ether disulfonate;

The sulphate of-fatty acid and fatty acid ester and sulfonate;

-poly--C ₂-C ₃Oxyalkylene C ₈-C ₂₂Alkyl ether sulfate, especially ethoxylation C ₈-C ₂₂The sulphate of the sulphate of alkanol such as ethoxylation laruyl alcohol;

-poly-C ₂-C ₃Oxyalkylene C ₁-C ₁₆Alkylbenzene ether sulfate, especially ethoxylation C ₁-C ₁₆The sulphate of alkyl phenol;

Two-C of-sulfosuccinic acid ₄-C ₁₈Arrcostab (=sulfosuccinic acid two-C ₄-C ₁₈Arrcostab) as dioctylsulfosuccinat;

-naphthalene sulfonic acids, C ₁-C ₁₆The condensation product of alkyl naphthalene sulfonic acid or phenolsulfonic acid and formaldehyde (=(C ₁-C ₁₆Alkyl) naphthalene sulfonate-formaldehyde condensation products and phenolsulfonate-formaldehyde condensation products);

-poly--C ₂-C ₃The oxyalkylene list-, two-or triphenylethylene base phenyl ether sulphate, especially single-, two-or the polyethoxylate of triphenyl vinyl phenol;

-single-and two-C ₈-C ₂₂Alkyl sulfate;

-poly--C ₂-C ₃Oxyalkylene C ₈-C ₂₂Alkyl ether phosphate;

-poly--C ₂-C ₃Oxyalkylene C ₁-C ₁₆The alkylbenzene ether phosphate;

-poly--C ₂-C ₃The oxyalkylene list-, two-or triphenylethylene base phenyl ether phosphate;

-polyoxyethylene polycarboxylate, the monoene that especially has a 3-8 carbon atom belong to unsaturated list-or the homopolymers and the copolymer of dicarboxylic acids, and wherein copolymer also has polyethylene oxide side-chain;

The salt of-fatty acid such as stearate; With

-Quadrafos such as hexametaphosphate and triphosphate (=tripolyphosphate).

The example of cationic emulsifier comprises alkyl trimethyl ammonium halide or alkylsurfuric acid alkyl trimethyl ammonium, halogenated alkyl pyridine

Or dialkyl dimethyl ammonium halide and alkylsurfuric acid dialkyl dimethyl ammonium.

In ionic emulsifier, the preferred anionic emulsifier.

In a preferred embodiment of the invention, emulsifier component comprises at least a anhydro sorbitol fat monoesters that is selected from, especially the emulsifier of Arlacel-80, and one or more, preferred two kinds are selected from the polyethenoxy sorbitan fatty ester, especially separately by the emulsifier of the Arlacel-80 of about 20 mole ethylene oxide ethoxylations and Arlacel-20.

In particularly preferred embodiment of the present invention, emulsifier component comprises the emulsifier that is selected from anhydro sorbitol fat monoesters, one or more, preferred two kinds of emulsifier that are selected from the polyethoxylated sorbitan fatty esters, and one or more are selected from the emulsifier of castor oil ethoxylate and ethylene oxide/propylene oxide copolymer.

The nonionic emulsifier of being mentioned is all commercially available.For example, anhydro sorbitol fatty acid with

(German BASF) or

(UNIQEMA, US) series commercial, the polyethenoxy sorbitan fatty ester with

(German BASF) or

(UNIQEMA, US) series is commercial, and castor oil ethoxylate is commercial with Trylox 5909 (German Cognis), and the ethylene oxide/propylene oxide copolymer is with Tergitol series, as

XD (Dow, USA) or

LPP series is commercial.

Emulsifier among the EC is generally the 2-20 weight % of this preparaton, preferred 5-15 weight %.

In preferred and particularly preferred embodiment, anhydro sorbitol fat monoesters is generally the 0.1-15 weight % of this preparaton, preferred 1-5 weight %; The polyethoxylated sorbitan fatty esters is generally the 1-5 weight % of this preparaton, preferred 1-5 weight %, GREMAPHOR GS32 is generally the 0-15 weight % of this preparaton, preferred 0-5 weight %, and the ethylene oxide/propylene oxide copolymer is generally the 0-15 weight % of this preparaton, preferred 0-5 weight %.

In another embodiment, this nonionic and anion emulsifier are selected from polymer emulsifier.Polymer emulsifier comprises statistics (random) polymer and copolymer, block copolymer, graft polymers and copolymer.

The non-ionic block copolymer emulsifier comprises at least one poly-(ethylene oxide) structure division PEO and at least one hydrophobicity polyether structure part PAO.The PAO structure division comprises at least 3 usually, and preferably at least 5, especially 10-100 is derived from C ₃-C ₁₀Oxyalkylene such as propylene oxide, 1,2-butylene oxide, cis-or trans-2,3-butylene oxide or oxidation isobutene, 1,2-oxidation amylene, 1,2-oxidation hexene, 1, the repetitive of 2-oxidation decene and styrene oxide (number average), wherein preferred C ₃-C ₄Oxyalkylene.Preferred PAO structure division comprises the repetitive that 10-60 weight % is derived from propylene oxide.The PEO structure division comprises 2-6 usually, and preferred 3-5 is individual, more preferably 3 or 4 repetitives (number average) that are derived from ethylene oxide.Preferred those number-average molecular weights M _NFor greater than 600 to 8000 dalton, the preferred daltonian emulsifier of 1000-6000 dalton, especially 1500-5000 c.12.

This non-ionic block copolymer emulsifier is for example commercial with following trade (brand) name:

As

P 65, and P 84, and P 103, and P 105, P 123 and L 31, and L 43, and L 62, L 62LF, and L 64, and L 81, L 92 and L 121,

As L860, L1030 and L 1060;

As 704,709,1104,1304,702,1102,1302,701,901,1101,1301 (BASF Aktiengesellschaft),

AEC 167 Hes AEC 178 (Akcros Chemicals),

B/848 (Rhodia),

370 Hes

374 (Akzo Nobel SurfaceChemistry),

50 C15,63 N10,63 N30,64 N40 and 81 N10 (DowEurope),

PF (Clariant),

As

PB,

PC,

PK (Akcros Chemicals),

PE (Pan AsianChemical Corporation),

As PE/L,

PE/F,

PE/P,

PE/T (ICISurfactants),

XD,

XH and

XJ (UnionCarbide),

CF-32 (Union Carbide), Teric PE Series (Huntsman),

8320 (Stepan Co.) and As

APEB,

NS 500K etc.

In another embodiment, the non-ionic polymers emulsifier is the ethylene oxide-oxypropylene block copolymer that comprises alkyl or alkyl phenol ether matrix such as butyl ether, methyl ether, propyl ether, ethyl ether or its mixture.As the example of such emulsifier, can mention the commercially available prod

8320 (Stepan Co.), i.e. the butyl ether derivative of ethylene oxide/propylene oxide block copolymer.The amount of above-mentioned block copolymer is generally 2-20 weight % based on the gross weight of this preparaton, especially 5-17 weight %, more preferably 5-12 weight %.

In another embodiment, this non-ionic polymers emulsifier is the dimethyl polysiloxane of polyoxyalkylene modification, as with trade mark

Especially

The organopolysiloxane emulsifier that L-77 (GE Silicones) sells.These emulsifier are disclosed in US 2,970, in 150.The amount of organopolysiloxane emulsifier is generally 0-6 weight % based on the gross weight of this preparaton, especially 0.5-5 weight %, more preferably 1-4 weight %.

In another embodiment, the non-ionic polymers emulsifier is to be selected from other water-soluble polymer of following polymer class: PVP(polyvinyl pyrrolidone), vinylpyrrolidone/vinyl acetate copolymer, Vinylcaprolactam homopolymer, polyvinyl formamide, PVAA, polyacrylate, polymethacrylates, polyacrylamide, polymine, polyvinylamine, hydroxy alkyl cellulose, alkyl-hydroxy alkyl cellulose, carboxyl alkyl cellulose, acetate succinic acid alkyl-hydroxy alkyl cellulose, acetate O-phthalic dialkylaminobenzoic acid-hydroxy alkyl cellulose, O-phthalic dialkylaminobenzoic acid-hydroxy alkyl cellulose, Cellacefate, starch, hydroxyalkyl starch, carboxyalkyl starch, modified starch, ocentyl succinic salt starch, glucan, polyox-yethylene-polyoxypropylene block copolymer, polyoxyethylene, polyoxypropylene, polyaminoacid.

In another embodiment, the anionic polymer emulsifier is to comprise the ethylenically unsaturated monomer of the olefinic unsaturated sulfonic acid of at least a formula I, at least a formula II and the optional additional monomers random free-radical polymerized thing as monomer:

Wherein X is oxygen or NR ⁵, R ¹Be hydrogen or methyl, n can value be 0-10, R ²And R ³Be C independently of each other ₁-C ₆Alkyl, and R ⁵Be hydrogen, alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl, aryloxy alkyl, alkoxy aryl, hydroxyalkyl, (two) alkyl amino alkyl, (two) alkyl amino aryl, (two) arylamino alkyl, alkyl aryl amino alkyl or alkyl aryl amino aryl, wherein aryl can be substituted, and wherein this olefinic unsaturated sulfonic acid can acid or salt form or exist with the mixture of acid and salt form

Wherein Y is oxygen or NR ⁵, R ⁴Be hydrogen or methyl, and R ⁵And R ⁶Be hydrogen, alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl, aryloxy alkyl, alkoxy aryl, hydroxyalkyl, (two) alkyl amino alkyl, (two) alkyl amino aryl, (two) arylamino alkyl, alkyl aryl amino alkyl or alkyl aryl amino aryl independently of each other.

The salt of the sulfonic acid of formula I is preferably alkali metal or ammonium salt.

C ₁-C ₂₀Alkyl be fit to separately or with combinations thereof as alkyl.Especially can mention C ₁-C ₆Alkyl, as methyl, ethyl, propyl group, the 1-Methylethyl, butyl, the 1-methyl-propyl, the 2-methyl-propyl, 1, the 1-dimethyl ethyl, amyl group, the 1-methyl butyl, the 2-methyl butyl, the 3-methyl butyl, 1, the 1-dimethyl propyl, 1, the 2-dimethyl propyl, 2, the 2-dimethyl propyl, the 1-ethyl propyl, hexyl, the 1-methyl amyl, the 2-methyl amyl, the 3-methyl amyl, the 4-methyl amyl, 1, the 1-dimethylbutyl, 1, the 2-dimethylbutyl, 1, the 3-dimethylbutyl, 2, the 2-dimethylbutyl, 2, the 3-dimethylbutyl, 3, the 3-dimethylbutyl, the 1-ethyl-butyl, 1,1,2-trimethyl propyl group, 1,2,2-trimethyl propyl group, 1-ethyl-1-methyl-propyl and 1-ethyl-2-methyl-propyl, cyclohexyl, n-heptyl, n-octyl, the 2-ethylhexyl, decyl, isodecyl, undecyl, lauryl, tridecyl, myristyl, pentadecyl, cetyl, heptadecyl or stearyl.

Aryl is interpreted as referring to the aromatic hydrocarbyl that monocycle or many rings, suitable words replace.The phenyl that for example can mention phenyl, naphthyl or be replaced by halogen such as fluorine or chlorine.

Alkoxyl is (O-) with the alkyl of skeleton bonding via oxygen atom.

Aryloxy group is (O-) with the aryl of skeleton bonding via oxygen atom.

Additional monomers for example can comprise vi-ny l aromatic monomers, as styrene and styrene derivative, as AMS, vinyltoluene, o-methyl styrene, a methyl styrene, p-methylstyrene, vinyl xylene, ethyl vinyl benzene, vinyl naphthalene, vinyl-dimethyl benzene and corresponding vinyl halides base aromatic monomer, or have a vi-ny l aromatic monomers of nitro, alkoxyl, haloalkyl, alkoxy carbonyl group, carboxyl, amino and alkyl amino, alpha-olefin, as ethene, propylene, 1-butylene, 1-amylene, 1-hexene, isobutene, or comprise long-chain (C ₁₀-C ₂₀) alpha-olefin of alkyl, diene is as butadiene and isoprene, the ethene alcohol ester, as vinyl acetate, halogen ethene, as vinyl chloride, bromine ethene or PVF, vinylidene chloride, vinylidene fluoride, inclined to one side dibromoethane, vinyl nitrile, vinyl carboxylates, 1-vinylamide class, as 1-vinyl pyrrolidone, 1-vinyl piperidones, 1-caprolactam, 1-vinyl formamide, 1-vinyl acetamide or 1-methyl isophthalic acid-vinyl acetamide, N-vinyl imidazole, C ₁-C ₂₄Arrcostab and monoene belong to the list of unsaturated monomer such as acrylic acid, methacrylic acid, fumaric acid, maleic acid and itaconic acid-and two replace and do not replace C ₁-C ₂₄Alkylamide, vinyl sulfonic acid, acid anhydrides such as maleic anhydride, unsaturated aldehyde, as acrolein, or unsaturated ethers, as 1,4-cyclohexanedimethanol divinyl ether, 1,4-cyclohexanedimethanol mono vinyl ether, the butanediol divinyl ether, the butanediol mono vinyl ether, cyclohexyl vinyl ether, diethylene glycol divinyl ether, the glycol monomethyl vinyl ethers, ethyl vinyl ether, methyl vinyl ether, n-butyl vinyl ether, octadecyl vinyl ether, the triethylene glycol vinyl methyl ether, vinyl isobutyl ether, vinyl (2-ethylhexyl) ether, the vinyl propyl ether, the vinyl isopropyl ether, the vinyl lauryl ether, the vinyl tertbutyl ether, the hexylene glycol divinyl ether, the hexylene glycol mono vinyl ether, the diglycol monotertiary vinyl ethers, the diethylamino ethyl vinyl ether, PolyTHF-290 divinyl ether, the tetraethylene glycol divinyl ether, the ethylene glycol butyl vinyl ether, the ethylene glycol bisthioglycolate vinyl ethers, triethylene glycol divinyl ether, trimethylolpropane tris vinyl ethers or aminopropyl vinyl ethers.

The polymer of describing with " free radical " is interpreted as referring to the polymer by the radical polymerization preparation.

The copolymer of describing with " random " is interpreted as referring to that wherein sequence monomer is by the copolymer of the copolymerization parameter decision of monomer.This is also corresponding effectively to the copolymer of being made up of more than two types of monomers.

This base polymer also is described as statistical copolymer.

In another preferred embodiment, random free-radical polymerized thing is formed by the monomer (especially 2-acrylamido-2-methyl isophthalic acid-propane sulfonic acid) of following formula I, ethylenically unsaturated monomer and the optional additional monomers of at least a formula II:

Wherein Y is oxygen or NR ⁵, R ⁴Be hydrogen or methyl, and R ⁵And R ⁶Be hydrogen, alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl, aryloxy alkyl, alkoxy aryl, hydroxyalkyl, (two) alkyl amino alkyl, (two) alkyl amino aryl, (two) arylamino alkyl, alkyl aryl amino alkyl or alkyl aryl amino aryl, wherein alkyl and aryl have above-mentioned implication.

In another particularly preferred embodiment, random free-radical polymerized thing comprises 2-acrylamido-2-methyl isophthalic acid-propane sulfonic acid and at least a wherein Y is an oxygen, R ⁴Be hydrogen and R ⁶For the ethylenically unsaturated monomer of the formula II of hydrogen or alkyl as monomer.

Therefore, random free-radical polymerized thing comprises 2-acrylamido-2-methyl isophthalic acid-propane sulfonic acid and at least a acrylic acid ester as monomer in this particularly preferred embodiment.

Acrylic acid such ester for example is a methyl acrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, butyl acrylate, acrylic acid 2-methyl-propyl ester, tert-butyl acrylate, Hexyl 2-propenoate, cyclohexyl acrylate, the acrylic acid n-octyl, 2-ethylhexyl acrylate, decyl acrylate, isodecyl acrylate, acrylic acid undecyl ester, lauryl acrylate, tridecyl acrylate, acrylic acid myristyl ester, acrylic acid pentadecyl ester, acrylic acid cetyl ester, acrylic acid heptadecyl ester or stearyl acrylate base ester.

These copolymers and preparation method thereof are disclosed among the WO 05/046328.

In preferred embodiments, amount of component b) comprise at least a polymer emulsifier.

In another preferred embodiment, amount of component b) comprises at least a water-soluble polymer emulsifier.

In another preferred embodiment, amount of component b) comprises at least a anionic polymer emulsifier.

In another preferred embodiment, amount of component b) comprises at least two kinds of emulsifier, preferred 3-5 kind emulsifier.

In another preferred embodiment, amount of component b) comprises a kind of polymer emulsifier and a kind of non-polymer emulsifier.

In another preferred embodiment, amount of component b) comprises a kind of water-soluble polymer emulsifier and at least a non-polymer emulsifier.

In another preferred embodiment, amount of component b) comprises a kind of anionic polymer emulsifier and at least a non-polymer emulsifier.

In another preferred embodiment, amount of component b) comprises a kind of water-soluble polymer emulsifier, a kind of nonionic non-polymer emulsifier and a kind of anion non-polymer emulsifier.

In another preferred embodiment, amount of component b) comprises a kind of anionic polymer emulsifier, a kind of nonionic non-polymer emulsifier and a kind of anion non-polymer emulsifier.

The combination of several different emulsifiers has improved the stability of EC preparaton.

In addition, EC of the present invention can comprise other conventional additive preparations, as cosolvent, defoamer, antifreezing agent, preservative, colouring agent and wetting agent.

Suitable defoamer is for example for having 4-14, the aliphatic series or the aromatics monohydric alcohol of preferred 6-10 carbon atom, and as n-octyl alcohol or Decanol, or silicone emulsifiers.Defoamer accounts for the 0-10 weight % of this preparaton usually, preferred 0.01-1 weight %.

Typical antifreezing agent for example is ethylene glycol, propane diols and glycerine.

Typical preservatives for example is vitamin e acetate, benzoic acid, sorbic acid, formaldehyde and trace Microbicidal compound.Preservative is generally the 0-10 weight % of this preparaton, preferred 0-1 weight %.Typical colouring agent comprises oil-soluble dyes, as

Patentblau (German Clariant).

Typical wetting agent for example is polyethoxylated alkyl phenol (containing the 1-30 mole ethylene oxide), polyethoxylated fatty alcohol (containing the 1-30 mole ethylene oxide), tridecanol polyglycol ether and alkyl-or alkyl benzene sulfonate.Wetting agent accounts for the 0-50 weight % of this preparaton usually, preferred 0-10 weight %.

The total content of other additive preparations is generally the 0-52 weight % of this preparaton, preferred 0-30 weight %, more preferably 5-25 weight %.

EC preparaton of the present invention is preparation in a manner known way by mixing each component, and suitable words stir and/or heating.The product that can so obtain is generally uniform emulsion concentrates.

The container that is fit to this preparaton is all containers that are usually used in crop protection products, is mainly bottle, jar and the bag made by the polymer of chemicals-resistant.Advantageously using water-soluble container, mainly is the water-soluble film bag, especially based on the water-soluble film bag of polyvinyl alcohol.

For fungi is used, usually this EC preparaton is diluted with suitable diluents (being generally water), preferably use excessive 10-400 at least doubly, preferred 10-150 thinner dilution doubly.

The spray liquid that so obtains can be used to prevent and treat fungi, its environment, seed or the propagating materials on the crops in a usual manner, is used for family and garden and uses, and is used for vector control and public health.

Preparaton of the present invention is suitable as fungicide.They are characterised in that the plant pathogenic fungi to wide region [comprises and especially comes from Plasmodiophoromycetes (Plasmodiophoromycetes), Peronosporomycetes (synonym Oomycete (Oomycetes)), Chytridiomycetes (Chytridiomycetes), Zygomycetes (Zygomycetes), Ascomycetes (Ascomycetes), the soil-borne fungus of Basidiomycetes (Basidiomycetes) and deuteromycetes (Deuteromycetes) (synonym Fungi imperfecti (Fungi imperfecti))] have significant validity.Some interior suctions are effective and can be used as blade face fungicide, seed dressing is used for crop protection with fungicide and soil fungicide.In addition, they are fit to the harmful fungoid that control especially occurs in timber or plant root.

Preparaton of the present invention is for various cultivated plants such as cereal class, for example wheat, rye, barley, triticale, oat or rice; Beet, for example sugar beet or fodder beet; Fruit, as a kind of fruit, such as apple, pear, etc., drupe or berry, for example apple, pears, Lee, peach, almond, cherry, strawberry, raspberry, blackberry, blueberry or dayberry; Leguminous plant, for example French beans, pea, clover or soybean; Oil plants, for example rape, leaf mustard, olive, sunflower, coconut, cocoa bean, castor oil plant, oil palm, peanut or soybean; Cucurbitaceous plant, for example pumpkin, cucumber or muskmelon; Fibre plant, for example cotton, flax, hemp or jute; Cedra fruits, for example orange, lemon, grapefruit or tangerine; Vegetables, for example spinach, lettuce, asparagus, cabbage, carrot, onion, tomato, potato, cucurbit or green pepper; Bay class plant, for example avocado, Chinese cassia tree or camphor; Energy and material plant, for example corn, soybean, rape, sugarcane or oil palm; Corn; Tobacco; Nut; Coffee; Tea; Banana; Grape vine (table grapes and must grape vine); Lupulus; The lawn; Natural rubber plant or view and admire and forest plants, for example flowers, shrub, broad-leaved tree or evergreen tree such as coniferous tree, and plant propagation material such as seed, and a large amount of plant pathogenic fungi particular importances of control in the crop material of these plants.

Preferred formulations is used in field crop, for example potato, sugar beet, tobacco, wheat, rye, barley, oat, rice, corn, cotton, soybean, rape, beans, sunflower, coffee or sugarcane; Fruit; Grape vine; The a large amount of fungies of control on ornamental plants or vegetables such as cucumber, tomato, Kidney bean and the pumpkin.

Term " plant propagation material " is interpreted as referring to all breeding parts of plant as seed, and the asexual vegetable material that can be used for breeding plant is as cutting and stem tuber (for example potato).This comprises seed, root, fruit, stem tuber, bulb, subterranean stem, spray, bud and other plant part.Rice shoot and the seedling that can also mention after sprouting or emerge and afterwards transplant by soil.These seedling can also be by the protection before transplanting via the processing wholly or in part of dipping or pouring.

Preferably Compound I and composition thereof are used for cereal crop such as wheat, rye, barley and oat the processing of plant propagation material respectively; The a large amount of fungies of control in rice, corn, cotton and the soybean.

Term " cultivated plant " is understood to include the plant of having modified by breeding, mutagenesis or gene engineering.Genetically modified plant is its genetic material can not be by hybridization, sudden change or the plant of the recombinant DNA technology modification that obtains of reorganization naturally by using under field conditions (factors).Usually with one or more gene integrations in the genetic material of genetically modified plant to improve some performance of plant.

Term " cultivated plant " for example is interpreted as also comprising the plant that tolerates the herbicide application of special category because of conventional breeding or gene engineering method, and described weed killer herbicide is medical midbodies of para (ortho)-hydroxybenzoic acetone acid dioxygenase (HPPD) inhibitor for example; Acetolactate synthestase (ALS) inhibitor such as sulfonylurea are (for example referring to US 6,222,100, WO 01/82685, and WO 00/26390, and WO 97/41218, WO98/02526, WO 98/02527, and WO 04/106529, WO 05/20673, WO03/14357, and WO 03/13225, WO 03/14356, and WO 04/16073) or imidazolone type (for example referring to US 6,222,100, WO 01/82685, and WO 00/26390, WO 97/41218, WO98/02526, and WO 98/02527, WO 04/106529, WO 05/20673, WO03/14357, and WO 03/13225, WO 03/14356, and WO 04/16073); Enol pyruvoyl shikimic acid 3-phosphate synthase (EPSPS) inhibitor such as glyphosate (glyphosate) (for example referring to WO92/00377); Glutamine synthelase (GS) inhibitor such as careless ammonium phosphine (glufosinate) are (for example referring to EP-A-0242236, EP-A-242246) or oxynil weed killer herbicide (for example referring to US 5,559,024).Several cultivated plants pass through conventional breeding (mutagenesis) method and herbicide-tolerant, for example

Summer sowing rape (Canola) tolerance imidazolone type such as imazamox (imazamox).Gene engineering method has been used to make cultivated plant such as soybean, cotton, corn, beet and rape herbicide-tolerant such as glyphosate and careless ammonium phosphine, and some in them can be with trade (brand) name

(tolerance glyphosate) and

(tolerating careless ammonium phosphine) is commercial.

Term " cultivated plant " is interpreted as also comprising the plant that can synthesize one or more insecticidal proteins by using recombinant DNA technology, this albumen is especially by known those of bacillus (Bacillus) bacterium, particularly by known those of bacillus thuringiensis (Bacillus thuringiensis), for example delta-endotoxin such as CryIA (b), CryIA (c), CryIF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (b1) or Cry9c; Asexual insecticidal proteins (VIP) is as VIP1, VIP2, VIP3 or VIP3A; Nematode is settled down insecticidal proteins such as Photobacterium (Photorhabdus) or the Xenorhabdus genus (Xenorhabdus) of bacterium; Toxin such as scorpion toxin, spider toxin, wasp toxin or other insect-specific neurotoxins that animal produces; Mycetogenetic toxin such as streptomyces (Streptomycetes) toxin, phytolectin such as pea or barley lectin element; Agglutinin; Protease inhibitors such as trypsin inhibitor, serpin, patatin, cystatin or antipain; Ribosome inactivating protein (RIP) is as ricin, corn-RIP, abrin, sponge gourd seed albumen, saporin or different strain diarrhoea toxalbumin (bryodin); Steroid metabolism enzyme such as 3-hydroxy steroid oxidase, ecdysteroids-IDP glycosyl transferase, cholesterol oxidase, moulting hormone inhibitor or HMG-CoA reductase; Ion channel blocking agent such as sodium channel or calcium channel blocker; Juvenile hormone esterase; Diuretic hormone acceptor (helicokinin acceptor); Stilbene synthase, bibenzyl synzyme, chitinase or dextranase.For the present invention, these insecticidal proteins or toxin also specifically are interpreted as preceding toxin, hybrid protein, albumen brachymemma or other aspect modifications.Hybrid protein is characterised in that the novel combination (for example referring to WO02/015701) in albumen territory.Other examples that this toxoid maybe can synthesize the genetically modified plant of this toxoid for example are disclosed among EP-A 374753, WO 93/007278, WO 95/34656, EP-A 427529, EP-A 451878, WO 03/018810 and the WO 03/052073.The method of producing such genetically modified plant to those skilled in the art normally known and for example be described in the above-mentioned publication.These are contained in insecticidal proteins in the genetically modified plant and give the plant that produces these albumen with to the insect from all entomological taxonomies, especially the tolerance of beetle (coleoptera (Coeleropta)), dipteral insect (diptera (Diptera)) and butterfly (Lepidoptera (Lepidoptera)).

Genetically modified plant that can synthetic one or more insecticidal proteins for example is described in the above-mentioned publication, and in them some are commercially available, for example

(producing the maize culture kind of Cry1Ab toxin), Plus (producing the maize culture kind of Cry1Ab and Cry3Bb1 toxin), (producing the maize culture kind of Cry9c toxin),

RW (producing the maize culture kind of Cry34Ab1, Cry35Ab1 and enzyme phosphinothricin-N-acetyl-transferase [PAT]);

33B (producing the cotton culture kind of Cry1Ac toxin),

I (producing the cotton culture kind of Cry1Ac toxin),

II (producing the cotton culture kind of Cry1Ac and Cry2Ab2 toxin);

(producing the cotton culture kind of VIP toxin); (producing the potato cultivar of Cry3A toxin); France Syngenta Seeds SAS's

Bt11 (for example

CB) and Bt176 (producing the maize culture kind of Cry1Ab toxin and PAT enzyme), the MIR604 of France Syngenta Seeds SAS (produces the maize culture kind of the modification translation of Cry3A toxin, referring to WO 03/018810), the MON 863 (producing the maize culture kind of Cry3Bb1 toxin) of Belgium Monsanto Europe S.A., 1507 (the producing the maize culture kind of Cry1F toxin and PAT enzyme) of the IPC 531 of Belgian Monsanto EuropeS.A. (producing the cotton culture kind of the modification translation of Cry1Ac toxin) and Belgian Pioneer Overseas Corporation.

Term " cultivated plant " is interpreted as also comprising by using recombinant DNA technology and can synthesizes one or more albumen to increase its plant to the resistance or the tolerance of bacterium, virus or fungal pathogens.The example of this plastein is so-called " albumen relevant with pathogenesis " (PR albumen, for example referring to EP-A 0 392 225), plant disease resistant gene (for example expression) or T4 lysozyme (for example can synthesize the potato cultivar that bacterium such as Erwiniaamylvora is had these albumen that strengthen resistance) at potato cultivar from the resistant gene of the phytophthora infestans (Phytophthora infestans) of wild Mexico potato Solanum bulbocastanum.It is known and for example be described in the above-mentioned publication that the method for producing this genoid modified plant is generally those skilled in the art.

Term " cultivated plant " is interpreted as also comprising and can synthesizes one or more albumen by using recombinant DNA technology improving output (for example yield of biomass, grain output, content of starch, oil content or protein content), to the tolerance of the environmental factor of arid, salt or other limiting growths or to the plant of the tolerance of insect and fungi, bacterium or its viral pathogen.

Term " cultivated plant " is interpreted as also comprising by using recombinant DNA technology to contain the content of material of the amount of changing or novel substance content especially to improve human or zootrophic plant, and the oil crop that for example produce sanatory long-chain omega-fatty acid or unsaturated ω-9 fatty acid (for example

Rape).

Term " cultivated plant " is interpreted as also comprising by using recombinant DNA technology to contain the content of material of the amount of changing or novel substance content especially to improve the plant that raw material is produced, for example produce recruitment amylopectin potato (for example

Potato).

Preparaton is particularly suitable for preventing and treating the following plants disease:

Albugo (Albugo) (white blister) on ornamental plants, vegetables (for example white rust (A.candida)) and the sunflower (for example salsify white rust (A.tragopogonis)),

Alternaria (Alternaria) (chain lattice spore leaf spot) on vegetables, rape (rape gives birth to chain lattice spores (A.brassicola) or alternaria brassica (A.brassicae)), sugar beet (A.tenuis), fruit, rice, soybean, potato (for example early epidemic disease chain lattice spores (A.solani) or chain lattice spore (A.alternata)), tomato (for example early epidemic disease chain lattice spore or chain lattice spore) and the wheat

Aphanomyces on sugar beet and the vegetables (Aphanomyces),

Ascochyta on cereal class and the vegetables (Ascochyta), big wheat husk two spores (A.hordei) on A.tritici on the wheat (anthracnose) and the barley for example,

Spot blight), flat navel Helminthosporium (Bipolaris) and interior navel Helminthosporium (Drechslera) (epigamous: cochliobolus belongs to (Cochliobolus)) on rice (for example the flat navel of rice wriggle spore (B.oryzae)) and the lawn corn (for example the flat navel of maize wriggle spore (D.maydis)), cereal class (the flat navel of the wheat root-rot spore (B.sorokiniana) of wriggling for example:

Wheat powdery mildew on the cereal class (for example wheat or barley) (Blumeria (in the past: Erysiphe) graminis) (powdery mildew),

Botrytis cinerea (Botrytis cinerea) (epigamous: Botrytis cinerea (Botryotinia fuckeliana): gray mold) on fruit and berry (for example strawberry), vegetables (for example lettuce, carrot, celeriac and cabbage), rape, flowers, grape vine, forest plants and the wheat;

Lettuce dish stalk mould (Bremia lactucae) (downy mildew) on the lettuce,

Long beak shell on broad-leaved tree and the evergreen tree belongs to (Ceratocystis) (synonym line mouth shell belongs to (Ophiostoma)) (rot or withered), the elm wilt (C.ulmi) (dutch elm disease) on the elm for example,

Cercospora (Cercospora) (tail spore leaf spot) on corn, rice, sugar beet (for example beet is given birth to tail spore (C.beticola)), sugarcane, vegetables, coffee, soybean (for example grey speck of soybean bacterium (C.sojina) or soybean purple speck bacterium (C.kikuchii)) and the rice

Tomato (tomato leaf mould (C.fulvum) for example: leaf mold) and the Cladosporium (Cladosporium) on the cereal class (for example careless bud branch spore (C.herbarum) (smut) on the wheat),

Ergot on the cereal class (Claviceps purpurea) (ergot),

Corn (grey length wriggle spore (C.carbonum)), cereal class (standing grain cochliobolus (C.sativus) for example, the flat navel of the wheat root-rot spore of wriggling) and rice (palace portion cochliobolus (C.miyabeanus) for example phorozoon:, phorozoon: the cochliobolus the long spore (H.oryzae) of wriggling of paddy rice) belongs to (phorozoon: Helminthosporium (Helminthosporium) or flat navel Helminthosporium) (leaf spot), cotton (for example cotton anthracnose bacterium (C.gossypii)), corn (for example standing grain is given birth to anthrax bacteria (C.Graminicola)), berry, potato (watermelon anthrax bacteria (C.coccodes) for example: diplostomiasis), perverse dish spore on Kidney bean (for example bean anthrax bacteria (C.lindemuthianum)) and the soybean (for example soybean anthracnose bacterium (C.truncatum)) belongs to (Colletotrichum) (epigamous: enclose small cluster shell Pseudomonas (Glomerella) (anthracnose)

Corticium (Corticium), rice Shang De Bamboo grass wood photovoltaicing leather bacteria (C.sasakii) (banded sclerotial blight) for example,

Cucumber brown patch germ on soybean and the ornamental plants (Corynespora cassiicola) (leaf spot),

The rust staining germ belongs to (Cycloconium), the C.Oleaginum on the olive tree for example,

Fruit tree, grape vine (C.liriodendri for example, epigamous: Neonectria liriodendri: Blackfoot Disease) and the genseng on the ornamental plants give birth to Ramularia (Cylindrocarpon) (for example fruit tree putrefaction disease or the weak disease of grape vine seedling, epigamous: Nectria (Nectria) or lady's slipper mycorhiza Pseudomonas (Neonectria))

Lineae ablicantes plumage bacterium on the soybean (Dematophora (epigamous: Rosellinia) necatrix) (root rot/stem rot),

North stem canker Pseudomonas (Diaporthe), the soybean on soybean north stem canker germ (D.phaseolorum) (upright withered ulcer) for example,

Corn, cereal class such as barley (the navel spore (D.teres) of wriggling in the barley filigree for example, net blotch) and wheat (D.tritici-repentis for example: maculopathy), interior navel Helminthosporium (the synonym Helminthosporium on rice and the lawn, epigamous: nuclear cavity Pseudomonas (Pyrenophora))

Eschka (Esca) (fusarium wilt on the grape vine that causes by the brown pore fungi of spot (Formitiporia (synonym Phellinus) punctata), F.mediterranea, Phaeomoniella chlamydospora (being Phaeoacremoniumchlamydosporum in the past), Phaeoacremonium aleophilum and/or grape seat chamber bacterium (Botryosphaeria obtusa), die back disease)

A kind of fruit, such as apple, pear, etc. (E.pyri), berry (raspberry Elsinochrome (E.veneta): anthracnose) and grape vine (grape Elsinochrome (E.ampelina): the Elsinoe anthracnose) (Elsinoe),

Rice leaf smut (Entyloma oryzae) (leaf smut) on the rice,

Epicoccum on the wheat (Epicoccum) (black points),

Sugar beet (beet powdery mildew (E.betae)), vegetables (for example pea powdery mildew (E.pisi)) are as the Erysiphe (Erysiphe) (powdery mildew) on cucurbit (for example two spore powdery mildews (E.cichoracearum)), cabbage, the rape (for example E.cruciferarum)

Fruit tree, grape vine and view and admire side Curvularia lunata (Eutypa lata) (Eutypa canker or fusarium wilt, phorozoon: Cytosporina lata, synonym Libertella blepharis) on the tree,

Prominent navel Helminthosporium (Exserohilum) (synonym Helminthosporium) on the corn (for example Exserohilum turcicum (E.turcicum)),

Fusarium on each plant species (Fusarium) (epigamous: (fusarium wilt Gibberella (Gibberella)), root rot or stem rot), for example fusarium graminaria (F.graminearum) on the cereal class (for example wheat or barley) or machete sickle spore (F.culmorum) (root rot, scab or fringe mildew), sharp sickle spore (F.oxysporum) on the tomato, eggplant sickle spore (F.solani) on the soybean and the wheel branch sickle spore (F.verticillioides) on the corn

Gaeumannomyce (Gaeumannomycesgraminis) (full rot) on cereal class (for example wheat or barley) and the corn,

Cereal class (for example Gibberella zeae (G.zeae)) and rice (gibberella fujikuroi (G.fujikuroi) for example: the Gibberella bakanae disease),

Cotton anthracnose bacterium (G.gossypii) on apple anthrax bacteria on grape vine, a kind of fruit, such as apple, pear, etc. and the other plant (Glomerella cingulata) and the cotton,

Grainstaining complex on the rice,

Black rot of vine grape bacterium on the grape vine (Guignardia bidwellii) (black rot),

Rust on rosaceous plant and the Chinese juniper (Gymnosporangium), the G.sabinae on the pears (rust) for example,

Helminthosporium on corn, cereal class and the rice (navel Helminthosporium in the synonym, epigamous: cochliobolus belongs to),

Camel spore Rust (Hemileia), the coffee on coffee camel spore rest fungus (H.vastatrix) (coffee leaf rust) for example,

Foxiness on the grape vine is intended Isaria (Isariopsis clavispora) (synonym Cladosporiumvitis),

Kidney bean shell ball spore on soybean and the cotton (Macrophomina phaseolina (synonym phaseoli)) (root rot and stem rot),

The withered bacterium of the mould leaf of snow on the cereal class (for example wheat or barley) (Microdochium (synonym Fusarium) nivale) (snow mold),

Diffusion cross hair shell (Microsphaera diffusa) (powdery mildew) on the soybean,

Clump stalk spore belongs to (Monilinia), drupe chain sclerotinia sclerotiorum (M.laxa), peach brown rot fungus (M.fructicola) and the M.fructigena on drupe and other rosaceous plants (the rotten disease of blossom rot and branch, brown rot) for example,

Mycosphaerella on cereal class, banana, berry and the peanut (Mycosphaerella), the Fijian ball chamber bacterium (M.fijiensis) (black spot) on standing grain green-ball chamber bacterium (M.graminicola) on the wheat (phorozoon: wheat septoria (Septoriatritici), septoria musiva leaf spot) or the banana for example;

Peronospora (Peronospora) (downy mildew) on cabbage (for example rape downy mildew (P.brassicae)), rape (for example parasitic downy mildew (P.parasitica)), onion (for example shallot downy mildew (P.destructor)), tobacco (tobacco downy mildew (P.tabacina)) and the soybean (for example soybean downey mildew bacterium (P.manshurica))

Yam bean layer rest fungus (Phakopsora pachyrhizi) and mountain horseleech layer rest fungus (P.Meibomiae) (soybean rust) on the soybean,

The Phialophora (Phialophora) on grape vine (for example P.Tracheiphila and P.tetraspora) and the soybean (for example brown stem rot bacterium (P.gregata): stem disease evil) for example,

Black shin stem on rape and the cabbage is selected the beet stem point mould (P.betae) (root rot, leaf spot and damping off) on mould (Phoma lingam) (root rot and stem rot) and the sugar beet,

Sunflower, grape vine (for example black rot of vine grape bacterium (P.viticola): stem blight and leaf spot) and soybean (stem wilt: P.phaseoli for example, epigamous: the Phomopsis (Phomopsis) soybean north stem canker germ (Diaporthephaseolorum))

Maize brown spot bacterium on the corn (Physoderma maydis) (brown spot),

Each plant species such as green pepper and cucumber plant (for example Phytophthora capsici (P.capsici)), soybean (soybean phytophthora (P.megasperma) for example, late blight) and Phytophthora (the Phytophthora) (fusarium wilt on the broad-leaved tree (for example robur sudden death pathogen (P.ramorum): Oak Tree is anxious dead sick) synonym P.sojae), potato and tomato (phytophthora infestans (P.infestans) for example:, root rot, leaf rot, stem rot and fruit tree putrefaction disease)

Plasmodiophora brassica bacteria on cabbage, rape, radish and the other plant (Plasmodiophorabrassicae) (club root),

Peronospora (Plasmopara), for example the grape on the grape vine is given birth to this single shaft of Hall mould (P.halstedii) on single shaft mould (P.viticola) (grape vine downy mildew) and the sunflower,

Podosphaera on rosaceous plant, lupulus, a kind of fruit, such as apple, pear, etc. and the berry (Podosphaera) (powdery mildew), the apple mildew bacterium (P.leucotricha) on the apple for example,

The for example many Acarasiales genus (Polymyxa) on cereal class such as barley and wheat (the many Acarasiales of cereal (P.graminis)) and the sugar beet (the many Acarasiales of beet (P.betae)) and the virus disease of propagation thus,

The rotten germ (Pseudocercosporellaherpotrichoides) of wheat-based on cereal class such as wheat or the barley (eye spot, epigamous: Tapesia yallundae),

False Peronospora (Pseudoperonospora) (downy mildew) on each plant species, for example humulus grass vacation white (P.humili) on false downy mildew (P.cubensis) of the Cuba on the cucumber plant or the lupulus,

Pseudopezicula tracheiphila on the grape vine (the burnt germ of grape angle variegated leaf or ' rotbrenner ', phorozoon: Saksenaea (Phialophora)),

Puccinia on each Plants (Puccinia) (rust); The wheat handle rest fungus (P.triticina) (leaf rust or leaf rust) on Cereal such as wheat, barley or the rye for example; Bar shaped handle rust (P.striiformis) (stripe rust or yellow rust); Barley handle rust (P.hordei) (yellow dwarf's leaf rust); Puccinia graminis (P.graminis) (stem rust or stalk rust) or puccinia triticinia (P.recondita) (leaf rust or leaf rust); And the Puccinia on the asparagus (for example Asparagus handle rust (P.asparagi))

Wheat macula lutea leaf spoting bacteria on the wheat (Pyrenophora (phorozoon: the navel spore (P.teres) (net blotch) of wriggling in the barley filigree on (maculopathy) or barley Drechslera) tritici-repentis),

Pyricularia Sacc. (Pyricularia), the piricularia oryzae (P.grisea) on the Pyricularia oryzae on the rice (P.oryzae) (epigamous: Magnaporthe grisea, rice blast) and lawn and the cereal class for example,

Pythium (Pythium) (damping off) on lawn, rice, corn, wheat, cotton, rape, sunflower, soybean, sugar beet, vegetables and the various other plant (for example ultimate pythium spp (P.ultimum) or melon and fruit corruption mould (P.aphanidermatum))

Ramularia (Ramularia), the beet leaf spot fungi (R.beticola) on R.collo-cygni on the barley (Ramularia leaf spot, physiology leaf spot) and the sugar beet for example,

Rhizoctonia (Rhizoctonia) on cotton, rice, potato, lawn, corn, rape, sugar beet, vegetables and the various other plant, the Rhizoctonia solani Kuhn on the soybean (R.solani) (root rot and stem rot) for example, cereal rhizoctonia (R.Cerealis) (Rhizoctonia banded sclerotial blight) on R.solani on the rice (banded sclerotial blight) or wheat or the barley

Rhizopus stolonifer on strawberry, carrot, cabbage, grape vine and the tomato (Rhizopusstolonifer) (black points, soft rot),

Rye beak spore (Rhynchosporium secalis) (brown spot) on barley, rye and the triticale,

Rice broom branch on the rice mould (Sarocladium oryzae) and S.attenuatum (sheath rot disease),

Sclerotinia (Sclerotinia) (stem rot or southern blight) on vegetables and field crop such as rape, sunflower (for example sclerotinite (S.sclerotiorum)) and the soybean (for example S.rolfsii),

Septoria on each plant species (Septoria), the soybean septoria musiva (S.glycines) (brown spot) on the soybean for example, the many spores of clever withered shell on wheat septoria on the wheat (S.tritici) (septoria musiva leaf spot) and the cereal class (S. (synonym Stagonospora) nodorum) (leaf piebald rot)

Grape snag shell on the grape vine (Uncinula (synonym Erysiphe) necator) (powdery mildew, phorozoon: Oidium tuckeri),

Leaf blight Pseudomonas (Setospaeria) (leaf blight) on corn (Exserohilum turcicum (S.turcicum) for example, the protruding navel of the big spot of synonym wriggle spore (Helminthosporium turcicum)) and the lawn,

Corn (silk axle smut (S.reiliana) for example: head smut), the axle Ustilago (Sphacelotheca) (smut) on Chinese sorghum and the sugarcane,

Monofilament shell powdery mildew (Sphaerotheca fuliginea) (powdery mildew) on the cucumber plant,

Powder scab bacterium (Spongospora subterranea) (powdery scab) on the potato and the virus disease of propagating thus,

The many spores of shell on the cereal class belong to (Stagonospora), for example the many spores of clever withered shell (S.nodorum) on the wheat (leaf piebald rot, epigamous: clever withered ball chamber bacterium (Leptosphaeria[synonym Phaeosphaeria] nodorum)),

Synchytrium endobioticum percival on the potato (Synchytrium endobioticum) (potato canker),

Exoascus (Taphrina), for example lopsided external capsule bacterium (T.deformans) (leaf-curl) on the peach and Lee's external capsule bacterium (T.pruni) (cystocarp Lee) on Lee,

Thiclaviopsis on tobacco, a kind of fruit, such as apple, pear, etc., vegetables, soybean and the cotton (Thielaviopsis) (black root rot), black root rot bacterium (T.basicola) (synonym Chalara elegans) for example,

Tilletia on the cereal class (Tilletia) (bunt or the bunt smut of wheat), for example T.tritici on the wheat (synonym T.caries, the bunt of wheat) and T.controversa (dwarf bunt),

Meat spore nuclear coral bacterium (Typhula incarnata) (grey snow mold) on barley or the wheat,

Ustilago (Urocystis), the latent bar smut (U.occulta) (bar smut) on the rye for example,

Vegetables belong to (Uromyces) (rust) as the rust of the monospore on Kidney bean (for example wart top uromyce (U.appendiculatus), synonym U.phaseoli) and the sugar beet (for example rust of beet (Uromyces betae) bacterium (U.betae)),

The cereal class (for example wheat loose smut (U.nuda) and U.avaenae), corn (Ustilago maydis (U.maydis) for example: smut of maize) and the Ustilago on the sugarcane (Ustilago) (smut),

Venturia (Venturia) (scab) on apple (for example apple scab (V.inaequalis)) and the pears,

Verticillium (Verticillium) (fusarium wilt) on each plant species if tree and ornamental plants, grape vine, berry, vegetables and the field crop, for example the eggplant verticillium wilt pathogen (V.dahliae) on strawberry, rape, potato and the tomato.

Preparaton also is fit to the product of control harmful fungoid with protective material (for example timber, paper, lacquer dispersion, fiber or fabric) and protection storage.In timber and construction material protection, should note following harmful fungoid especially: the Ascomycetes fungi, for example line mouth shell belongs to, long beak shell belongs to, Aureobasidium pullulans (Aureobasidium pullulans), Sclerophoma spp., Chaetomium (Chaetomium), Humicola (Humicola), Peter's shell belongs to (Petriella), the mould genus of pieces (Trichurus); The Basidiomycetes fungi; for example cellar fungus belongs to (Coniophora); Coriolus Qu61 (Coriolus); sticking gill fungus belongs to (Gloeophyllum); Lentinus (Lentinus); Pleurotus (Pleurotus); hole genus (Poria) crouches; Merulius (Serpula) and cheese Pseudomonas (Tyromyces); the deuteromycetes fungi, aspergillus (Aspergillus) for example, Cladosporium; Penicillium (Penicillium); trichoderma (Trichorma), Alternaria, paecilomyces (Paecilomyces) and Zygomycetes (Zygomycetes) fungi; for example mucor (Mucor) should be noted following yeast fungus in this external storage product protection: candida (Candida) and saccharomyces cerevisiae (Saccharomyces cerevisae).

Preparaton needs maybe to prevent that by handle fungi with the active substance of antifungal effective dose plant, plant propagation material such as seed, soil, surface, material or the space of fungal attack from using.Use and before plant, plant propagation material such as seed, soil, surface, material or space are by fungal infection and afterwards, to carry out.

Preparaton of the present invention and composition have strong plant reinforced effects.Their be fit to improve (moilisiing) to undesirable microorganism such as above-mentioned harmful fungoid, also have the plant defense reaction of virus and bacterium.Term " plant reinforcing agent (tolerance is brought out compound) " is interpreted as being meant in the preparaton and can demonstrates those compounds to the mode stimulating plant system of defense of the tolerances of these microorganisms significantly with processed plant when inoculating described undesirable microorganism subsequently.

Therefore, preparaton can be used for protective plant in a period of time and avoid undesirable microbial infection after using.This time bar that wherein brings out protection is generally 1-28 days after using preparaton, and preferred 1-14 days, perhaps under the seed treatment situation after sowing 9 months at the most.

Preparaton of the present invention also is fit to improve crop.In addition, their toxicity is less and demonstrate good plant compatibility.

These preparatons can be applied on the plant propagation material, particularly seed through dilution or without dilution.Described preparaton provides 0.01-60 weight % in preparation in that dilution 2-10 is in sight after doubly, preferably the active material concentration of 0.1-40 weight %.Use and before sowing, to carry out.At plant propagation material, especially use farmingization compound and composition thereof on the seed or be known in this area and comprise seed dressing, dressing, granulation and the immersion application process of propagating materials with the method for its processing.In preferred embodiments, by not bringing out the method for sprouting, for example compound or its composition are applied on the plant propagation material by seed dressing, granulation and dressing.

Active material concentration can change in relative broad range in the off-the-shelf.They are generally 0.0001-10%, preferred 0.001-1%.

When being used for plant protection, amount of application depends on that the kind of required effect is 0.01-2.0kg active substance/ha.

By seed being carried out in the seed treatment of dressing or infiltration, the active matter quality that requires is the 0.1g-10kg/100kg seed usually, usually be the 1-1000g/100kg seed for example, preferably the 5-100g/100kg seed.

When being used for protective material or stored prod, the amount of application of active substance depends on kind and the required effect of using the zone.Common amount of application for example is 0.001g-2kg in material protection, preferred 0.005g-1kg active substance/m ³Processed material.

Can add various types of oil, wetting agent, adjuvant, weed killer herbicide, bactericide, other fungicides and/or insecticide in preparaton, suitable words add (bucket mixes) before being close to use.These reagent can be with 1: 100-100: 1, preferred 1: 10-10: 1 weight ratio is mixed with preparaton of the present invention.

The polysiloxanes that operable adjuvant is especially organically-modified, for example Break Thru S

Alcohol alkoxylates, for example Atplus

Atplus MBA PlurafacLF

With Lutensol ON

EO/PO block polymer, for example Pluronic RPE

With

Alcohol ethoxylate, for example

And Sodium docusate, for example

The preparaton of the present invention that is the fungicide type of service can also exist as pre-composition or suitablely uses preceding mixing (bucket mixes) being close to other active substances (for example weed killer herbicide, insecticide, growth regulator, fungicide or fertilizer).

The preparaton that will be the fungicide type of service mixes the expansion that causes the Fungicidally active spectrum in many cases or prevents the drug-fast generation of fungicide with other fungicides.In addition, obtain synergistic function in many cases.

The following fungicide that can add in the preparaton of the present invention is used for possible combination is described, but does not limit them:

A) the strobilurins class is selected from

Nitrile Fluoxastrobin (azoxystrobin), ether bacterium amine (dimoxystrobin), Enestroburin (enestroburin), fluoxastrobin (fluoxastrobin), imines bacterium (kresoxim-methyl), fork phenalgin acid amides (metominostrobin), orysastrobin (orysastrobin), ZEN 90160 (picoxystrobin), pyraclostrobin (pyraclostrobin), pyribencarb, oxime bacterium ester (trifloxystrobin), 2-(2-(6-(3-chloro-2-methylphenoxy)-5-fluorine pyrimidine-4-base oxygen base) phenyl)-2-methoxyimino-N-methylacetamide, 3-methoxyl group-2-(2-(N-(4-methoxyphenyl) cyclopropane imines acyl sulfenyl methyl) phenyl) methyl acrylate, (2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate and 2-(2-(3-(2, the 6-dichlorophenyl)-1-methyl acrol amino oxygen methyl) phenyl)-2-methoxyimino-N-methylacetamide;

B) carboxyl acylamide is selected from

-carboxanilides class: M 9834 (benalaxyl), smart M 9834 (benalaxyl-M), bixafen, Boscalid (boscalid), carboxin (carboxin), methuroxam (fenfuram), fenhexamid (fenhexamid), flutolanil (flutolanil), furan pyrazoles spirit (furametpyr), isopyrazam, different metsulfovax (isotianil), kiralaxyl, third oxygen goes out and embroiders amine (mepronil), metalaxyl (metalaxyl), Metalaxyl-M (metalaxyl-M) (mefenoxam), fenfuram (ofurace);

Frost spirit (oxadixyl), oxycarboxin (oxycarboxin), pyrrole metsulfovax (penthiopyrad), tecloftalam (tecloftalam), thifluzamide (thifluzamide), tiadinil (tiadinil), 2-amino-4-methylthiazol-5-formailide, 2-chloro-N-(1,1,3-trimethyl-2,3-dihydroindene-4-yl) vitamin PP, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 ', 4 '-DfBP-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 ', 4 '-DCBP-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 ', 5 '-DfBP-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 ', 5 '-DCBP-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (3 ', 5 '-DfBP-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (3 ', 5 '-DCBP-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (3 '-fluorine biphenyl-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (3 '-chlordiphenyl-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 '-fluorine biphenyl-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 '-chlordiphenyl-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl) acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl) acid amides, the 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-[2-(1 for 4-formic acid, 1,2,3,3,3-hexafluoro propoxyl group) phenyl] acid amides, the 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-[2-(1 for 4-formic acid, 1,2,2-tetrafluoro ethyoxyl) phenyl] acid amides, 3-difluoromethyl-1-methyl isophthalic acid H-pyrazoles-4-formic acid (4 '-trifluoromethylthio biphenyl-2-yl) acid amides, N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, (2-(1 for N-, the 3-dimethylbutyl) phenyl)-1,3,3-trimethyl-5-fluoro-1H-pyrazole-4-carboxamide, N-(4 '-chloro-3 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(4 '-chloro-3 ', 5 '-DfBP-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 '-two chloro-5 '-fluorine biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 5 '-two fluoro-4 '-methyl biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 5 '-two fluoro-4 '-methyl biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2-dicyclo third-2-base phenyl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(cis-2-dicyclo third-2-base phenyl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(trans-2-dicyclo third-2-base phenyl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide;

-carboxylic acid morpholine thing: dimethomorph (dimethomorph), flumorph (flumorph);

-benzamides: fluorine biphenyl bacterium (flumetover), fluorine pyrrole bacterium amine (fluopicolide), fluorine pyrrole bacterium acid amides (fluopyram);

-other carboxyl acylamides: carpropamide (carpropamid), two chlorine zarilamid (dicyclomet), mandipropamid amine (mandiproamid), terramycin (oxytetracyclin), silicon metsulfovax (silthiofarm) and N-(6-methoxypyridine-3-yl) cyclopropane carboxamide;

C) azole is selected from

-triazole type: penta ring azoles (azaconazole), Bitertanol (bitertanol), bromuconazole (bromuconazole), cyproconazole (cyproconazole), Ether azoles (difenoconazole), alkene azoles alcohol (diniconazole), alkene azoles alcohol M (diniconazole-M), oxole bacterium (epoxiconazole), RH-7592 (fenbuconazole), Fluquinconazole (fluquinconazole), Flusilazole (flusilazole), Flutriafol (flutriafol), own azoles alcohol (hexaconazole), acid amides azoles (imibenconazole), cycltebuconazole (ipconazole), encircle penta azoles bacterium (metconazol), nitrile bacterium azoles (myclobutanil), oxpoconazole, paclobutrazol (paclobutrazole), penconazole (penconazole), propiconazole (propiconazole), prothioconazoles (prothioconazole), simeconazoles (simeconazole), Tebuconazole (tebuconazole), fluorine ether azoles (tetraconazole), triazolone (triadimefon), triadimenol (triadimenol), triticonazole (triticonazole), uniconazole P (uniconazole), 1-(4-chlorphenyl)-2-([1,2,4] suberol triazol-1-yl);

-imidazoles: cyanogen frost azoles (cyazofamid), IMAZALIL (imazalil), pefurazoate (pefurazoate), Prochloraz, fluorine bacterium azoles (triflumizol);

-benzimidazole: benomyl (benomyl), carbendazim (carbendazim), furidazol (fuberidazole), thiabendazole (thiabendazole);

-other: Guardian (ethaboxam), kobam (etridiazole) and hydroxyisoxazole (hymexazole);

D) heterocyclic compound is selected from

-pyridines: fluazinam (fluazinam), pyrifenox (pyrifenox), 3-[5-(4-chlorphenyl)-2, the 3-dimethyl is different

Azoles alkane-3-yl] pyridine, 3-[5-(4-aminomethyl phenyl)-2, the 3-dimethyl is different

Azoles alkane-3-yl]

Pyridine, 2,3,5,6-tetrachloro-4-mesyl pyridine, 3,4,5-trichloropyridine-2,6-dimethoxy nitrile, N-(1-(5-bromo-3-chloropyridine-2-yl) ethyl)-2,4-two chloro-nicotinamides, N-[(5-bromo-3-chloropyridine-2-yl) methyl]-2,4-two chloro-nicotinamides;

-miazines: the phonetic bacterium spirit of sulphur (bupirimate), ring third pyrimidine (cyprodinil), difluoro woods (diflumetorim), fenarimol (fenarimol), ferimzone (ferimzone), mepanipyrim (mepanipyrim), daxtron (nitrapyrin), nuarimol (nuarimol), pyrimethanil (pyrimethanil);

-piperazines: triforine (triforine);

-pyroles: fenpiclonil (fenpiclonil), fluorine

Bacterium (fludioxonil);

-morpholine class: 4-dodecyl-2,6-thebaine (aldimorph), dodemorfe (dodemorph), dodemorfe acetic acid esters (dodemorph-acetate), butadiene morpholine (fenpropimorph), tridemorph (tridemorph);

-piperidines: fenpropidin (fenpropidin);

-dicarboximide class: fluorine bacterium peace (fluoroimid), different third fixed (iprodione), the sterilization profit (procymidone), vinclozolin (vinclozolin);

-non-aromatics 5 element heterocycles:

Famoxadone (famoxadone), Fenamidone (fenamidone), different thiophene bacterium ketone (octhilinone), probenazole (probenazole), 5-amino-2-isopropyl-3-oxo-4-o-tolyl-2,3-pyrazoline-1-bamic acid S-allyl ester;

-other: thiadiazoles element (acibenzolar-S-methyl), amisulbrom, anilazine (anilazin), blasticidin-S (blasticidin-S), difoltan (captafol), captan (captan), the mite grasshopper (chinomethionat) of going out, dazomet (dazomet), debacarb (debacarb), diclomezine (diclomezine), difenzoquat (difenzoquat), difenzoquat methylsulfuric acid ester (difenzoquat-methylsulfate), zarilamid (fenoxanil), folpet (folpet), oxolinic acid (oxolinic acid), pipron (piperalin), the third oxygen quinoline (proquinazid), pyroquilon (pyroquilon), quinoxyfen (quinoxyfen), azoles bacterium piperazine (triazoxide), tricyclazole (tricyclazole), 2-butoxy-6-iodo-3-propyl group chromene-4-ketone, 5-chloro-1-(4,6-dimethoxypyridin-2-yl)-2-methyl isophthalic acid H-benzimidazole, N-(4-(3-methoxyl group-1-(5-methyl-[1,2,3] butyramide thiazol-2-yl naphthalene-2-yl thiadiazoles-4-yl))), 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidine, 6-(3, the 4-dichlorophenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and 5-trifluoromethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine; E) carbamate is selected from

-sulfo--and dithiocarbamate: ferbam (ferbam), mancozeb (mancozeb), maneb (maneb), metham-sodium (metam), methasulfocarb (methasulphocarb), Carbatene (metiram), propineb (propineb), tmtd (thiram), zineb (zineb), ziram (ziram);

-carbamate: benzene metsulfovax (benthiavalicarb), the mould prestige of second (diethofencarb), flubenthiavalicarb, iprovalicarb (iprovalicarb), hundred dimension spirit (propamocarb), propamocarbs (propamocarb hydrochlorid), valiphenal, N-(1-(1-(4-cyano-phenyl) ethylsulfonyl) fourth-2-yl) carbamic acid 4-fluorophenyl ester;

F) other active substances are selected from

-guanidine class: guanidine, dodine (dodine), dodine free alkali, guazatine (guazatine), iminoctadine (guazatine-acetate), biguanide spicy acid salt (iminoctadine), iminoctadine triacetate (iminoctadine-triacetate), two eight guanidinesalts (iminoctadine-tris (albesilate));

-antibiotics: spring thunder element (kasugamycin), hydration spring thunder element (kasugamycinhydrochloride-hydrate), streptomycin (streptomycin), Polyoxin (polyoxine), jinggangmeisu (validamycin A);

-nitrophenyl derivative: binapacryl (binapacryl), dinobuton (dinobuton), karathane (dinocap), different third disappear (nitrthal-isopropyl), tecnazene (tecnazen);

-organo-metallic compound: triphenyltin salt, for example fentinacetate (fentin-acetate), Fentin chloride (fentin chloride) or fentin hydroxide (fentin hydroxide);

-sulfur heterocyclic compound: Delan (dithianon), Isoprothiolane (isoprothiolane);

-organic phosphorus compound: Hinosan (edifenphos), fosetyl (fosetyl), aliette (fosetyl-aluminum), iprobenfos (iprobenfos), phosphorous acid and salt thereof, Ppyrazophos (pyrazophos), tolelofos-methyl (tolclofos-methyl);

-organochlorine compound: tpn (chlorothalonil), Euparen (dichlofluanid), antiphen (dichlorophen), flusulfamide (flusulfamide), hexachloro-benzene (hexachlorobenzene), Pencycuron (pencycuron), pentachlorophenol (pentachlorphenole) and salt thereof, Rabcide (phthalide), pcnb (quintozene), thiophanate methyl (thiophanate-methyl), tolyfluanid (tolylfluanid), N-(4-chloro-2-nitrobenzophenone)-N-ethyl-4-methyl benzenesulfonamide;

-inorganic active material: bordeaux mixture (Bordeaux mixture), Schweinfurt green, Kocide SD, Cupravit (copper oxychloride), basic copper sulfate, sulphur;

-other: biphenyl, bronopol (bronopol), cyflufenamid (cyflufenamid), cymoxanil (cymoxanil), diphenylamines, metrafenone (metrafenone), midolthromycin (mildiomycin), copper 8-hydroxyquinolinate (oxine-copper), Prohexadione calcium (prohexadione calcium), spiral shell Luxuriant amine (spiroxamine), tolyfluanid, N-(cyclopropyl methoxyimino-(6-difluoro-methoxy-2, the 3-difluorophenyl) methyl)-the 2-phenyl-acetamides, N '-(4-(4-chloro-3-4-trifluoromethylphenopendant)-2, the 5-3,5-dimethylphenyl)-N-ethyl-N-methyl carbonamidine, N '-(4-(4-fluoro-3-4-trifluoromethylphenopendant)-2,5-3,5-dimethylphenyl)-N-ethyl-N-methyl carbonamidine, N '-(2-methyl-5-trifluoromethyl-4-(3-TMS propoxyl group) phenyl)-N-ethyl-N-methyl carbonamidine and N '-(5-difluoromethyl-2-methyl-4-(3-TMS propoxyl group) phenyl)-N-ethyl-N-methyl carbonamidine.

The following growth regulator that can add in the preparaton of the present invention is used to possible combination is described, and does not limit them:

G) abscisic acid (abscisic acid), elder generation's alachlor (amidochlor), ancymidol (ancymidol), benzamido group purine (6-benzylaminopurine), brassinosteroid (brassinolide), Amex820 (butralin), chlormequat (chlormequat) (chlormequat (chlormequat chloride)), Choline Chloride (choline chloride), cyclanilide (cyclanilide), daminozide (daminozide), dikegulac (dikegulac), dimethipin (dimethipin), 2,6-lutidines (2,6-dimethylpuridine), ethrel (ethephon), maleic Min (flumetralin), flurprimidol (flurprimidol), reach careless fluorine (fluthiacet), forchlorfenuron (forchlorfenuron), 92 O (gibberellic acid), inabenfide (inabenfide), indole-3-acetic acid, maleic hydrazide (maleichydrazide), fluorine grass sulphur (mefluidide), help strong plain cation (mepiquat) (helping strong plain (mepiquat chloride)), methyl, the N-6-benzyladenine, paclobutrazol, transfer naphthenic acid (prohexadione) (Prohexadione calcium), jasmonic propyl ester (prohydrojasmon), match diazole element (thidiazuron), triapenthenol (triapenthenol), De-Green (tributyl phosphorotrithioate), 2,3, the 5-Triiodobenzoic acid, anti-ester (trinexapac-ethyl) and uniconazole P.

The following weed killer herbicide that can add in the preparaton of the present invention is used to possible combination is described, and does not limit them:

H) weed killer herbicide such as glyphosate, sulphosate (sulfosate), careless ammonium phosphine (gluphosinate), tefluthrin (tefluthrin), Terbufos (terbufos), chlopyrifos (chlorpyrifos), earth worm chlorine phosphorus (chlorethoxyfos), Tebupirimphos (tebupirimfos), ABG-6215 (phenoxycarb),

Luxuriant ether (diofenolan), pymetrozine (pymetrozine), Imazethapyr (imazethapyr), imazamox, weed eradication cigarette (imazapyr), imazapic (imazapic) or smart P DimethenamidP (dimethenamid-P).

The following insecticide that can add in the preparaton of the present invention is used to possible combination is described, and does not limit them:

I) insecticide such as sharp strength spy (fipronil), Imidacloprid (imidacloprid), pyrrole worm clear (acetamiprid), nitenpyram (nitenpyram), furadan (carbofuran), carbosulfan (carbosulfan), Benfuracard micro (benfuracarb), MTI-446 (dinotefuran), thiophene worm quinoline (thiacloprid), thiophene worm piperazine (thiamethoxam), thiophene worm amine (clothianidin), TH-6040 (diflubenzuron), flufenoxuron (flufenoxuron), Teflubenzuron (teflubenzuron) and nail body cypermethrin (alpha-cypermethrin).

According to the present invention, use the preparaton that contains triazole type and at least a other active substances and be interpreted as representing that at least a triazole type and at least a other active substances are present in active position (harmful fungoid promptly to be prevented and treated or its habitat plant as infecting simultaneously with the antifungal effective dose, plant propagation material, especially seed, the surface, material or soil and the plant that will prevent fungal attack, plant propagation material, especially seed, soil, the surface, material or space).This can be by simultaneously, i.e. associating (for example as bucket a mixed thing) or separately, or use the preparaton that contains triazole type and at least a other active substances successively and obtain, wherein select the time interval of each time between using when using other active substances, to be present in active position with q.s with the active substance of guaranteeing at first to use.Order of administration is unimportant to enforcement of the present invention.

Each component can be used separately or partially or completely mix mutually with preparation preparaton of the present invention.They can also be packed and further use as binding compositions such as multicomponent packaging kit.

In one embodiment of the invention, packaging kit can comprise that one or more (comprise all) can be used to prepare the component of the present invention's farmingization composition.For example these packaging kits can comprise one or more fungicide components and/or adjuvant component and/or insecticide component and/or growth regulator component and/or weed killer herbicide.One or more components can make up or preformulation mutually.Two or more therein components are provided in those embodiments in the packaging kit, and each component can make up mutually and directly be packaged in independent container such as bottle, jar, bucket, bag, capsule or the case.In other embodiments, two or more components of packaging kit can separately be packed, i.e. preformulation not.Therefore, packaging kit can comprise one or more containers that separate such as bottle, bucket, jar, bag, capsule or case, and wherein each container comprises the independent component of farmingization composition.In two kinds of forms, a kind of component of packaging kit can be with other components separately or or be used to prepare preparaton of the present invention as the component of binding compositions of the present invention.

Also preferably comprise triazole type and at least a A of being selected from) organize the strobilurins class, be preferably selected from the preparaton of the active substance of nitrile Fluoxastrobin, ether bacterium amine, fluoxastrobin, imines bacterium, orysastrobin, ZEN 90160, pyraclostrobin and oxime bacterium ester especially.

Also preferably comprise triazole type and at least a B of being selected from) organize carboxyl acylamide, especially be selected from the preparaton of the active substance of fenhexamid, metalaxyl, Metalaxyl-M, fenfuram, dimethomorph, flumorph, fluorine pyrrole bacterium amine (picobenzamid), zoxamide (zoxamide), carpropamide and mandipropamid amine (mandipropamid).

Preferably comprise triazole type and at least a C of being selected from) group azole, especially be selected from cyproconazole,

The preparaton of the active substance of ether azoles, oxole bacterium, Fluquinconazole, Flusilazole, Flutriafol, ring penta azoles bacterium, nitrile bacterium azoles, penconazole, propiconazole, prothioconazoles, triazolone, triadimenol, Tebuconazole, fluorine ether azoles, triticonazole, Prochloraz, cyanogen frost azoles, benomyl, carbendazim and Guardian.

Also preferably comprise triazole type and at least a D of being selected from) the group heterocyclic compound, especially be selected from fluazinam, ring third pyrimidine, fenarimol, mepanipyrim, pyrimethanil, triforine, fluorine Bacterium, dodemorfe, butadiene morpholine, tridemorph, fenpropidin, different third fixed, vinclozolin,

The preparaton of the active substance of famoxadone, Fenamidone, probenazole, the third oxygen quinoline, thiadiazoles element, difoltan, folpet, zarilamid and quinoxyfen.

Also preferably comprise triazole type and at least a E of being selected from) organize carbamate, especially be selected from the preparaton of the active substance of mancozeb, Carbatene, propineb, tmtd, iprovalicarb, flubenthiavalicarb and hundred dimension spirits.

Also preferably comprise triazole type and at least a F of being selected from) group fungicide, especially be selected from Delan, triphenyltin salt such as fentinacetate, fosetyl, aliette, H ₃PO ₃And salt, tpn, Euparen, thiophanate methyl, Schweinfurt green, Kocide SD, Cupravit, copper sulphate, sulphur, cymoxanil, metrafenone, spiral shell

The preparaton of the active substance of luxuriant amine and 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4]-triazol [1,5-a] pyrimidine.

Comprising a kind of triazole type and a kind of other active substances such as a kind of A of being selected from)-I) in such preparaton of the present invention of active substance of group, the weight ratio of the triazole type and second active substance is generally 1: 100-100: 1, usually be 1: 50-50: 1, preferred 1: 20-20: 1,1: 10 to 10 particularly: 1.

Comprising a kind of triazole type and first kind of other active substance (component 2) and second kind of other active substance (component 3), for example two kinds are selected from A)-I) in such preparaton of the present invention of active substance of group, the weight ratio of the triazole type and second active substance is preferably 1: 50-50: 1, particularly 1: 10-10: 1, and the weight ratio of triazole type and the 3rd active substance is preferably 1: 50-50: 1, particularly 1: 10-10: 1.

The following example explanation the present invention, but should not think restriction the present invention.

1. preparation embodiment

By the mixture of preparation solvent and in heating with add the former medicine of oxole bacterium under stirring and prepare embodiment F-1 to F-3.When oxole bacterium dissolves the formation clear solution fully, add emulsifier and mixing, up to preparing limpid EC.

F-0 is the comparative example of SC (suspending concentrate) preparaton.

Table 1: preparation embodiment

F-1	Title	Amount, weight %
			Active component	Oxole bacterium	12.5
Emulsifier 1	Tristyrylphenol ethoxylates 16EO	8
			Emulsifier 2	Calcium dodecyl benzene sulfonate	8
Polymer emulsifier	MMA-co-AMPS-co-LA(45∶15∶40)	6.5
			Solvent	Benzylalcohol	25
Solvent	Neighbour-sec-butyl phenol	20
			Solvent	Solvesso?200	20

F-3	Title	Amount, weight %
			Active component	Oxole bacterium	8

Emulsifier 1	Tristyrylphenol ethoxylates 16EO	9
			Emulsifier 2	Neopelex	8
Polymer emulsifier	Stat.VP-Vac(60∶40)	7
			Solvent	Benzylalcohol	22
Solvent	Neighbour-sec-butyl phenol	12
			Solvent	Solvesso?200	41

Application Example F-0 to F-3: to the therapeutic action of the puccinia triticinia on the wheat (brown rust of wheat)

The leaf of potted plant wheat rice shoot that with cultivar is " Kanzler " is with the spore suspension dusting of brown rust of wheat bacterium (puccinia triticinia).Under 20-22 ℃, plant is placed the chamber 24 hours of high atmospheric humidity (90-95%) then.Spore germination and germ tube are penetrated in the leaf texture during this period.The plant that to infect in second day is sprayed to the drip point with active material concentration preparaton as described below.After the preparaton drying of spraying, test plant sent back in the greenhouse and under the relative atmospheric humidity with 65-70% of 20-22 ℃ temperature cultivated again 7 days.Naked eyes are measured the rust development degree on the leaf then.

In this test, the plant of handling with this EC preparaton demonstrate than with the plant of SC preparaton processing or the plant of being untreated much lower infect (table 2).

Table 2: biology embodiment

Claims

1. an emulsifiable concentrate (EC) preparaton comprises:

But a) fungicidal triazole class or its agricultural salt or adduct,

C) one or more emulsifier,

D) optional other additive preparations.

2. as the desired EC of claim 1, wherein said triazole type be selected from penta ring azoles, Bitertanol, bromuconazole, cyproconazole,

Ether azoles, alkene azoles alcohol, alkene azoles alcohol M, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, own azoles alcohol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, oxpoconazole, paclobutrazol, penconazole, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P, 1-(4-chlorphenyl)-2-([1,2,4] suberol triazol-1-yl).

3. as the desired EC of claim 2, wherein said triazole type is selected from oxole bacterium, Fluquinconazole, cycltebuconazole, ring penta azoles bacterium, propiconazole, prothioconazoles, Tebuconazole and triticonazole.

4. as the desired EC of claim 3, wherein said triazole type is an oxole bacterium.

5. each desired EC in the claim as described above comprises one or more other crop protection agents.

6. as the desired EC of claim 5, wherein said other crop protection agents are selected from dimethomorph, butadiene morpholine, tridemorph, fenpropidin, Prochloraz, imines bacterium, orysastrobin, ring penta azoles bacterium, pyraclostrobin, Boscalid and metrafenone.

7. each desired EC in the claim as described above, be made up of following component substantially:

A) 0.1-30 weight % triazole type,

B) 6-97 weight % dicyandiamide solution, it comprises

B1) substituted phenol,

B2) one or more organic solvents;

C) one or more emulsifier of 2-20 weight % and

D) other additive preparations of 0-52%.

8. the phenol that each desired EC in the claim as described above, wherein said dicyandiamide solution comprise following formula is as component (b1):

R ¹-O-X，

9. as the desired EC of claim 8, wherein said phenol is selected from 2,3, the 6-pseudocuminol, p-tert-butylphenol, neighbour-sec-butyl phenol, the 2-tert-butyl phenol, right-tert-amyl phenol, heptyl derivative (right-heptylphenol), to tert-octyl phenol, paraoctyl phenol, 2, the 4-DI-tert-butylphenol compounds, 2, the 6-DI-tert-butylphenol compounds, right-(α, α-Er Jiajibianji) phenol, to nonyl phenol, 2, the 4-di-tert-pentyl phenol, to dodecyl phenol, 4-sec-butyl-2, the 6-DI-tert-butylphenol compounds, 2,4,6-tri-butyl-phenol and 2,4-two (α, α-Er Jiajibianji) phenol.

10. as the desired EC of claim 9, wherein said phenol is neighbour-sec-butyl phenol.

11. each desired EC in the claim as described above, wherein said dicyandiamide solution comprises aromatic hydrocarbon as organic solvent component (b2).

12. each desired EC in the claim as described above, wherein said emulsifier component (c) comprises at least a polymer emulsifier.

13. each desired EC in the claim as described above, wherein said emulsifier component (c) comprises at least a water-soluble polymer emulsifier.

14. each desired EC in the claim as described above, wherein said emulsifier component (c) comprises at least a anionic polymer emulsifier.

15. each desired EC in the claim as described above, wherein said emulsifier component (c) comprises at least two kinds of emulsifier.

16. a method for preparing EC comprises the step of mixing according to each defined component a, b, c and the optional suitable words of d in the aforementioned claim under stirring and/or heating.

17. according to the purposes of each defined EC among the claim 1-15 in the control harmful fungoid.

18. a methods for fighting harmful mushrooms, comprise dilution according to each defined EC among the claim 1-15 and with its directly or indirectly be applied to harmful fungoid, its habitat maybe needs prevent the step of plant, soil or the seed of fungal attack.