TW200948269A - Emulsifiable concentrate - Google Patents

Abstract

The present application relates to an emulsifiable concentrate (EC) formulation, comprising (a) a fungicidal triazole or an agriculturally acceptable salt or adduct thereof, (b) a solvent system, comprising (b1) a substituted phenole (b2) one or more organic solvents (c) one or more emulsifiers, (d) optionally, further formulation additives, a process for their preparation and a use for controlling harmful fungi.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an emulsifiable concentrate (EC) comprising fungicidal triazole, a process for the preparation thereof, and the use of such an EC for controlling harmful fungi. [Prior Art] European Patent No. EP-A 0 357 559 discloses a water-insoluble crop protectant, in particular an aqueous formulation of furathiocarb and substituted phenol, which inhibits the crystallization of sulphur or Stabilize the lotion. European Patent No. EP-A 〇 5 〇 5 053 discloses an aqueous formulation comprising prochloraz, a nonionic surfactant and a substituted phenol. Specifically, &lt;RTIgt; </RTI> a sigma sitting (e.g., ep〇xic〇naz〇le) is formulated into a suspension concentrate (SC). European Patent No. EP-A 0 707 445 discloses an aqueous heterogeneous stable formulation of a crop protection active compound comprising a keel segment polymer, an anionic dispersant, a wetting agent and a thickener. These SC formulations are difficult to prepare, for example, by grinding to homogenize the distribution of the active ingredients to avoid deposition. Specifically, it is desirable to stabilize the sc formulation in the presence of an adjuvant or a continuous phase due to the ease of crystallization of the active ingredient in the continuous phase. Accordingly, it is an object of the present invention to provide formulations of the above compounds which are stable in storage and use and which have high biological activity. It has now been found that this object can be achieved by using the EC formulations of the invention. SUMMARY OF THE INVENTION 139305.doc 200948269 Accordingly, in one aspect of the invention, there is provided an emulsifiable concentrate (EC) formulation comprising: a) a fungicidal triazole or an agriculturally acceptable salt thereof or Compound, b) a solvent system comprising bl) substituted phenol b2) - or a plurality of organic solvents c) one or more emulsifiers, d) other formulation additives as appropriate. The EC formulations of the present invention exhibit good storage stability and biological activity. [Examples] Suitable fungicidal triazoles or agriculturally acceptable salts or adducts thereof: azaconazole, bitertanol, bromuconazole Pro (cyproconazole), cifenoconazole, diniconazole, dilute alcohol-M, epoxiconazole, fenbucon sit (fenbuconazole), fluoroquinone 0 sitting ( Fluquinconazole), flusilazole, flurifaol, and six Kang. Hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, oxpoconazole, paclobutrazole, Pancon 0, peniconazole, propiconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon ), triadimenol, triticonazole, singapore 0 sitting 139305.doc 200948269 (uniconazoU), diterpene phenyl)_2_([1,2 4]triazole small) cycloheptanol . People who are sitting in the industry are well-known and described in www.alanwood.net/pillicides/index-cn-frarne.html. It is a good diazole-based oxiconazole, fluoroquinazole, inocastazole, meconazole, propiconazole, thioconazole, dextran and triteconazole. The best is epoxyconazole. Due to its basic character of the nitrogen atom, the compound I is capable of forming a salt or adduct with a mineral acid or an organic acid or with a metal ion. Examples of inorganic acids are hydrogen acids (e.g. hydrofluoric acid, hydrochloric acid, hydrobromic acid and hydroiodic acid), carbonic acid, sulfuric acid, phosphoric acid and nitric acid. Suitable organic acids are, for example, citric acid and alkanoic acids (such as acetic acid, trifluoroacetic acid, diacetic acid and propionic acid) and also include glycolic acid, thiocyanate, lactic acid, succinic acid, citric acid, benzoic acid, Cinnamic acid, oxalic acid), alkylsulfonic acid (sulfonic acid having a linear or branched alkyl group of 1 to 20 carbon atoms), arylsulfonic acid or aryldisulfonic acid (having one or two sulfonic acids) Aromatic groups such as phenyl and naphthyl), alkylphosphonic acids (linear or branched alkyl phosphonic acids having 1 to 2 carbon atoms), arylphosphonic acids or aryl diphosphonic acids (aromatic groups bearing one or two phosphate groups, such as phenyl and naphthyl), wherein the alkyl or aryl group may carry other substituents, such as p-methylbenzoic acid, salicylic acid, For amino-based salicylic acid, 2-phenoxybenzoic acid, 2-ethyloxybenzoic acid, and the like. Suitable metal ions are, in particular, ions of the second main group element (specifically, fishing and magnesium), ions of the third and fourth main group elements (specifically, aluminum, tin and lead), and transitional groups one to eight. Ions of elements (specifically chromium, manganese, iron, 139305.doc 200948269 drill, record, copper, rhetoric, and other elements). The better one is the metal ion of the transition element of the fourth cycle. The metals may be present at a variety of valences that they may exhibit. The EC formulations according to the invention generally comprise from 0.1 to 30% by weight, preferably from 3 to 2% by weight, in particular from 5 to 15% by weight, of component a) fungicidal triazoles. The EC formulations of the present invention typically comprise from 6 to 97% by weight, preferably from 1% to 9% by weight, specifically from 15% to 80% by weight, of the solvent system (b). The component bl) is a substituted phenol having the formula: R1—0-X, wherein R1 is a phenyl group substituted by 1-3 Ci-C^-alkyl groups, and X is hydrogen, an alkali metal, a soil-checking metal. Or NR3, wherein each R is the same or different and is hydrogen or, optionally, a Q-C8-alkyl group substituted with a hydroxy group.

The Ci-C^-alkyl group has a linear or branched alkyl group having 1 to 12 carbon atoms. Examples are methyl, ethyl, propyl, isopropyl, n-butyl, t-butyl, isobutyl, tert-butyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimercaptopropyl, 1-ethylpropyl, 1, quinone-dimercaptopropyl, 1,2-dimethylpropyl, hexyl, methylpenta Base, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-di-f-butyl, iota, 2-didecylbutyl, 1,3-dimethyl Butyl, 2,2-dimethylbutyl, 2,3-didecylbutyl, 3,3-dimethylbutyl, oxime-ethylbutyl, 2-ethylbutyl, tridecyl Propyl, 1,2,2-trimercaptopropyl, ethyl-丨-methylpropyl, 丨_ethyl_2_mercaptopropyl, heptyl, octyl, 2-ethylhexyl, decyl 'Indenyl, eleven alkyl, dodecyl and its positional isomers. Examples of suitable substituted phenols are 2,*3,6-trimethylphenol, p-third 139305.doc 200948269 phenol, o-t-butyl phenol, 2-tert-butyl phenol, p- Tripentylphenol, heptyl derivative (p-heptylphenol), p-third-octylphenol, p-octylphenol, 2,4-di-t-butylphenol, 2,6-di- Tertiary butyl, p-(α,α-dimercapto)phenyl, p-nonylbenzene, 2,4-di-tris-pentylphenol, p-dodecylphenol, 4-second butyl-2,6-di-tert-butylphenol, 2,4,6-tri-tert-butylphenol and 2,4-bis(α,α-diindenyl)benzene A lot. Preferred substituted phenol-p-tert-butylphenol, o-butyl butyl phenol, 2-tert-butyl phenol, 2,4-di-t-butyl phenol, 2,6-di- Tributylphenol, 4-second butyl-2,6-di-tert-butylphenol, and 2,4,6-tri-tert-butylphenol. The best one is o-butyl phenol. The / granule system includes an organic solvent as component (b2). Preferably, a mixture of an alkyl group-containing aromatic compound, specifically an alkylbenzene and an alkylnaphthalene, having an alkyl group having 1 to 20 carbon atoms is used. Such mixtures can be, for example,

Solvesso® (eg Solvesso 200 (Exxon Mobil, USA)), Aromatic (eg 'Aromatic 200 (Exxon Mobil)) or Shellsol® (Deutsehe Shell Chemie GmbH, Germany) gamble. Other suitable organic solvents as component (b2) are paraffin, alcohol, pyrrolidone, acetate, glycol, fatty acid, dimethylguanamine, fatty acid decylguanamine, fatty acid esters, and mixtures thereof. Examples of suitable solvents (b2) are: methanol, ethanol, isopropanol, butanol, pentanol, 2-ethylhexanol, 13 dimethyl-2-imidazolidinone, 2-methyl-2, heart Pentyl glycol, acetone, acetophenone, propionic acid, 2-hydroxy-2-ethylhexyl ester, carbon 139305.doc 200948269 di-n-octyl acid ester, benzyl acetate, benzyl alcohol, benzyl benzoate Ester, cyclohexane 'cyclohexanol, cyclohexanone, butyl lactate, 2-ethylhexyl lactate, ethyl lactate, decyl lactate, n-propyl lactate, tetrahydrofurfuryl alcohol, diphenyl benzene, diethylene glycol Alcohol, dimethylformamide, dimethyl sulfoxide, dipropylene glycol, • 5 mercapto-3-heptanone, ethyl alcohol, γ-butane vinegar, glycerol, hexanol, isopropanol, butylene carbonate , propylene carbonate, methyl benzoate, mercapto-ethyl ketone methyl-isobutyl ketone, η-ethyl-2-° 〇 each ketone, η-methyl caprolactam , n-octylpyrrolidone, propionic acid, and mixtures thereof. The best group injury (b2) is s〇ivesso 200, Solvesso 200 ND, Solvesso 150 ND, Caromax 28 LN, Aromatic 200 and

The amount of Hydrosol A 230/270 ND ° organic solvent component (b2) is usually from 丨35 wt%, preferably from 1 to 30 wt%, specifically 5-25 wt 0/〇, of the formulation. The EC formulations of the invention also contain at least one emulsifier. The emulsifier is used to reduce the surface tension between the continuous phase and the dispersed phase, thereby stabilizing the φ droplets of the dispersed phase. The emulsifier also contributes to the dissolution of the triazole. Suitable emulsifiers are well known in the industry, for example from McCutchen〇n, s Detergents ad

Emulsifiers, Int. Ed" Ridgewood, New York. Suitable emulsifiers - agents comprising nonionic, anionic, cationic and zwitterionic emulsifiers and mixtures thereof. Emulsifiers may be polymeric emulsifiers or non-polymeric emulsifiers. In contrast to emulsifiers, the non-polymeric emulsifiers generally have a molecular weight of less than 2 Torr (number average), specifically 150-2000, preferably 2 〇〇 15 。. The emulsifier may be nonionic or ionic, or a combination of the two. It is preferred to use at least 2 139305.doc 200948269, preferably 3-5 emulsifiers, preferably having different HLB values, at different temperatures. Achieving good EC physicochemical properties. HLB (hydrophilic-lipophilic balance) is an empirical parameter defined by wC Griffin (J. Soc. Cosmetic Chemists, 1, 31 1 (1949)), which represents an emulsification reagent (especially nonionic Amphiphilic properties of the type emulsifier. The emulsifier with the lowest hydrophilicity is specified to have the lowest HLB value. Suitable nonionic emulsifiers are, for example, alkoxylated fats or oils of animal or vegetable origin (eg corn oil ethoxylate, castor oil Ethoxylate, tallow ethoxylate) 'glyceride (eg 'glycerol monostearate fatty alcohol alkoxide and carbonyl alkoxide, fatty acid alkoxide (eg oleic acid ethoxylate), alkyl benzene Base-burning oxides (eg, isodecyl, isooctyl, tributyl- and tristearyl phenyl ethoxylates, aliphatic amine alkoxylates, fatty acid guanamine alkoxides), sugar emulsifiers (eg Sorbitol fatty acid ester (sorbitan monooleate, sorbitan tristearate), polyoxyethylene sorbitan fatty acid ester, alkyl polyglycoside, N-alkylglucoside Amine, alkyl methyl sulfoxide, alkyl dimethyl phosphine oxide (such as tetradecyl diindenylphosphine oxide), ethylene oxide / propylene oxide copolymer and mixtures of such nonionic emulsifiers The nonionic emulsifier specifically comprises a polyoxy-CrG-alkylene C8_C22_alkyl ether, in particular a linear or branched CVC22-alkaline polyethoxylate and a poly-ethoxylate. _ propoxylate, more preferably polyethoxylated fatty alcohol and polyethoxylated carbonyl alcohol, such as polyethoxylation: lauric alcohol, polyethyl b Oxidation of isotridecyl alcohol, polyethoxylated cetyl alcohol, polyethoxylated stearyl alcohol and esters thereof, such as acetate; 139305.doc -10· 200948269 - polyoxy-C2-C3-streater aryl Key and polyoxy-C2-C3-alkylene-based Ci-Ci6_alkyl aryl ether (for example polyoxy-c2-c3-alkylene c8-c22-alkyl phenyl ether) 'specifically C^-C^ a polyethoxylate of a ruthenium group, such as a polyethoxylate of mercaptobenzene, nonylphenol, isodecylphenol, dodecylphenol or isotridecylphenol,

❹ - polyoxy-C2_C3-alkylene mono-, di- or tristyrylphenyl ether, in particular polyethoxylates of mono-, di- and tristyrylphenol; and furfural condensates thereof And esters thereof, such as acetate; -c6-c22-alkyl glycoside and c6_c22-alkylpolyglycoside; -CyC22-alkyl glycoside polyethoxylate and C6_C22_alkylpolyglycoside polyethoxylate; a polyethoxylate of an aliphatic amine; a polyethoxylate of a fatty acid and a polyethoxylate of a hydroxy fatty acid; a partial ester of a polyterpene alcohol with a C6_C22_alkanoic acid, in particular a monoacetic acid and a diester of glycerol and Single vinegar of sorbitan, two 6 and three, such as glycerol monostearyl (IV) 'sorbitol liver monooleic acid vinegar, sorbitan tristearic acid-poly 7C alcohol and C6_C22_ acid part Polyacetate, glycerin monohydrate and diacetate polyethoxylate and sorbitol wild: single two = and 1! polyethoxylates such as glycerol mono-hard fat _ of the mountain 4 sugar Polyvinyl ethoxylate monopolystearate polyethyl 4, xylitol ethoxylate; ... compound and mountain 4 sugar alcohol sterol tristearic acid poly-vegetable oil or animal fat Polyethoxylate J π jade oil ethoxylated 139305.doc -11 · 200948269 substance, _ ethoxylate, tallow oil ethoxylate; -5-decyne-ethyl fast diol, such as 2,4,7,9 _tetramethyl-4,7-bis(trans-base) polyoxyethylene polyoxypropylene-block copolymer; and - fatty amines. Polyethylene Oxide of Ethylamine or Fatty Acid Ethanolamine The term polyoxy-CVCV (4) refers to a polyradyl group derived from epoxy or burnt. The term polyethoxylate refers to a polyether group derived from ethylene oxide. Also the term polyoxyethylene-co-polyoxypropylene refers to a polyether group derived from a ring: a mixture of ethane and propylene oxide. The number of repeating units in the polyether group typically varies between 4-100, specifically 5_5. Preferred nonionic emulsifiers are, for example, sorbitol liver fatty acid vinegar, in particular sorbitol and its anhydride part of vinegar (eg sorbitol hepatic monooleate), polyoxyethylene sorbitan fat An acid ester (for example, polyethoxylated (preferably having about 20 moles of ethylene oxide) sorbitan monolaurate and sorbitan monooleate), castor oil ethoxylate (preferably An ethylene oxide having about moles, and an ethylene oxide/propylene oxide copolymer (for example, an alkyl oxirane/propylene oxide copolymer, preferably having a molecular weight of 2 〇〇〇 5 〇〇〇) Within the scope). The ionic emulsifier may be an anionic emulsifier or a cationic emulsifier or a mixture of an anion and a cationic emulsifier. Examples of anionic emulsifiers are poly(preferably 2-3 0) ethoxylated (preferably C6-C22) fatty alcohol sulphates and sulphuric acid vinegars, such as ethoxylation (2 ε〇(Ε〇•思─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─ ─

Crodafos® N serie, Croda Oleochemicals, UK), ethoxylated (2-10 EO), alcoholic/stearyl sulphate 1 (eg, Crodafos® CS serie, Croda Oleochemicals, UK), ethoxylated (4- 6 EO) thirteen alcoholic acid filled vinegar (eg, Emphos® PS serie, CK Witco, USA), ethoxylated fatty oleic acid vinegar (eg, Crafol® AP serie, Henkel Iberica, Spain), ethoxylated ( 3-6 EO) fatty alcohols (for example, Rhodafac® serie, Rhodia Chimie, France), complex organic acid-based free acids (eg, Beycostat® serie, Ceca SA, France), polyethoxylation (8-w 25 EO) phosphates of aryl phenol (for example, poly(ethylene oxide di- and tris-ethenyl benzene) S (for example, Soprophor 3D33, Rhodia Chimie, France), polyethyl emulsified aryl benzene Sulfuric acid vinegar (for example, polyethoxylated di- and tristyrylbenzene) (for example, Soprophor DSS/7, Soprophor 4D384, Rhodia Chimie, France) ° Anionic emulsifiers specifically include the following sodium, potassium, Calcium or ammonium salt: -C6-C22-alkyl sulfonate, such as lauryl sulfonate, isotridecyl sulfonate a salt; -c6-c22-alkyl sulfate, such as lauryl sulfate, isotridecyl sulfate, hexadecyl sulfate, and stearyl sulfate; - - aryl- and sulfonate, specific In terms of CrCM-alkylbenzenesulfonate, for example, cumene sulfonate, octylbenzenesulfonate, nonylbenzenesulfonate, dodecylbenzenesulfonate, naphthylsulfonate, Mono- and di-Ci-C^-alkylnaphthyl sulfonates, such as dibutylnaphthyl sulfonate; - early- and di-Ci_Ci6-alkyl. Diphenyl mystery (II) For example, dodecyl diphenyl ether disulfonate; 139305.doc -13- 200948269 - sulfates and sulfonates of fatty acids and fatty acid esters; - polyoxy-C2_C3 - extended alkyl C8-C22_alkyl Ether sulfate, specifically ethoxylated Cg-C; 22 sulphuric acid sulfates such as sulphate sulphate sulphate; - polyoxy-C: 2-C3-extended alkyl Ci-C^- styrene benzene Mysterious sulphate, specifically sulphate of Ci-Cifi-alkylphenol; one of the bases of C4-Ci8 sulphuric acid (= C4-Ci8 - dialkyl base) For example, dioctyl sulfosuccinate; -naphthalenesulfonic acid, CrCw-alkylnaphthalenesulfonic acid or a condensate of phenolsulfonic acid and formaldehyde (=(c--Cl6.alkyl)naphthalenesulfonate-formaldehyde condensate and phenolsulfonate furfural condensate); -polyoxy-C2_(:3-alkylene) Mono-, di- or tristyrylphenyl ether sulfates - in particular mono-, di- or tristyrylphenol polyethoxylates; - mono- and di-C8-C22-alkyl sulfates - polyoxy-C2_C3-alkylene c8-C22-alkyl ether phosphate; - polyoxy-CyC3 · alkylene (^-Cm-alkyl phenyl ether phosphate; - polyoxy-C2_C3_alkylene) Mono-, di- or tristyrylphenyl ether phosphate; - polyoxyethylene polycarboxylate, in particular, monoethylenically unsaturated mono- or dicarboxylic acid having from 3 to 8 carbon atoms Polymers and copolymers, which also have polyethylene oxide side chains; - fatty acid salts such as stearates; and -polyphosphates such as hexametaphosphate and triphosphate tripolyphosphate ). Examples of cationic emulsifiers include alkyl trimethyl ammonium halide or alkyl trimethyl 139305.doc 200948269 alkyl alkyl sulfate, alkyl pyridinium or dialkyl dimethyl ammonium halide and monoalkyl dimethyl Base sulfuric acid. Among the ionic emulsifiers, an anionic emulsifier is preferred. In a preferred embodiment of the invention, the emulsifier component comprises at least one sorbitan derived from a sorbitan fatty acid monoester, in particular sorbitan monooleate, and one or more Preferably, two emulsifiers derived from polyoxyethylene sorbitan fatty acid esters, in particular sorbitan monooleate and sorbitan monolaurate, each having about 20 moles of earrings Oxyethane ethane ethoxylate. In a preferred embodiment of the invention, the emulsifier component comprises an emulsifier from a group of sorbitan fatty acid monoesters, one or more preferably two of which are derived from polyethoxylated sorbitan fatty acid esters. An emulsifier and one or more emulsifiers derived from a group of castor oil ethoxylates and ethylene oxide/propylene oxide copolymers. All of the nonionic emulsifiers mentioned are commercially available. For example, sorbitan-sugar anhydride fatty acids are commercially available as S-MAZ® (BASF, Germany) or Span® (UNIQEMA, US) series, and polyoxyethylene sorbitan fatty acid esters are used as T-MAZ® (BASF, Germany) or Tween® (UNIQEMA, US) series purchased from castor oil ethoxylate as Trylox 5909 (Cognis, * Germany) and ethylene oxide/propylene oxide copolymer as Tergitol series (eg Tergitol® XD) (Dow, USA)) or the SurfonU® LPP series. The amount of emulsifier in the EC is usually 2 to 2% by weight, preferably 5 to 15% by weight, based on the formulation. 139305.doc •15· 200948269 In preferred and preferred embodiments, the amount of sorbitan fatty acid monoester is typically from 0.1 to 15% by weight, preferably from 1 to 5% by weight of the formulation: The amount of the ethoxylated sorbitan fatty acid ester is usually from 1 to 5% by weight, preferably from 1 to 5% by weight of the formulation, and the amount of the polyethoxylated castor oil is usually 〇i 5 weight ° / 〇 of the formulation, Preferably, it is 0 to 5% by weight, and the amount of the ethylene oxide/propylene oxide copolymer is usually from 0 to 15% by weight, preferably from 0 to 5% by weight, based on the formulation. In another embodiment, the nonionic and anionic emulsifiers are selected from the group consisting of polymeric emulsifiers. Polymeric emulsifiers include statistical (random) polymers and copolymers, dad copolymers, graft polymers, and copolymers. The nonionic block copolymer emulsifier comprises at least one poly(ethylene oxide) moiety PEO and at least one hydrophobic polyether moiety pao. The pao portion generally comprises at least 3, preferably at least 5, specifically 1〇_1〇〇 repeating units (number average) derived from C3_C G-alkale alkanes, such as propylene oxide, 1, 2-butylene oxide, cis- or trans-_2,3_butylene oxide or methyl epoxidized, 1,2-epoxypentane, i,2_epoxyhexanol-2 Brothel and styrene oxide, of which c3-c4 alkylene oxide is preferred. Preferably, the pA moiety comprises from 10 to 60% by weight of repeating units derived from propylene oxide. The cleavage moiety typically comprises from 2 to 6, preferably from 3 to 5, and more preferably from 3 or 4 repeating units derived from epoxidation (the number average is between _above and _dalton, preferably _ __ Dalton and specifically 15〇〇_

The average molecular weight of M in 5000 Daltons is better. Nonionic block copolymer emulsifiers are described under the trade names of, for example, plur〇nic®, such as Phrononi_ p 65, p84, p i〇3 m P 123 and Pluronic® L 31, L 43 , τ Μ τ ,

43 L 62 , L 62 LF , L 64 , L 139305.doc 16 200948269 81, L 92 and L 121 ; Pluraflo®, eg Pluraflo® L 860, L1030 and L 1060; Tetronic®, eg Tetronic® 704, 709, 1104 , 1304, 702, 1102, 1302, 701, 901, 1101, 1301 (BASF Aktiengesellschaft); Agrilan® A.EC 167 and Agrilan® AEC 178 (Akcros Chemicals); Antarox® B/848 (Rhodia); Berol® 370 and Berol® 374 (Akzo Nobel Surface Chemistry); Dowfax® 50 C15, 63 N10, 63 N30, 64 N40 and 81 N10 (Dow Europe); Genapol® PF (Clariant); Monolan®, such as Monolan® PB, Monolan® PC, Monolan® PK (Akcros Chemicals); Panox® PE (Pan Asian Chemical Corporation); Symperonic®, such as Symperonic® PE/L, Symperonic® PE/F, Symperonic® PE/P, Symperonic® PE/T (ICI Surfactants); Tergitol® XD, Tergitol® XH and Tergitol® XJ (Union Carbide); Triton® CF-32 (Union Carbide); Teric PE Series (Huntsman); Toximul® 8320 (Stepan) and Witconol®, such as Witconol® APEB, Witconol ® NS 5 00 K and the like. In another embodiment, the nonionic polymeric emulsifier is an ethylene oxide-propylene oxide block copolymer comprising an alkyl or alkyl phenol ether base such as butyl ether, methyl ether, propyl ether, diethyl ether, or Its mixture. As an example of the emulsifier, a commercially available product, Toximul® 8320 (Stepan), which is a butyl ether derivative of an ethylene oxide-propylene oxide block copolymer, may be mentioned. The amount of the above block copolymer is usually from 2 to 20% by weight, specifically from 5 to 17% by weight and more preferably from 5 to 12% by weight, based on the total weight of the formulation. 139305.doc 17 200948269 In another embodiment, the nonionic polymeric emulsifier is a polyalkylene oxide modified dimethyl polyoxyalkylene, such as the Silwet® trademark, specifically Silwet® L-77 (GE Silicones) Sale of organic polyoxygen emulsifiers. Such emulsifiers are disclosed in U.S. Patent No. 2,970,150. The amount of the organopolyoxy emulsifier is usually from 0 to 6% by weight, specifically from 0.5 to 5% by weight and more preferably from 1 to 4% by weight, based on the total weight of the formulation. In another embodiment, the nonionic polymeric emulsifier is a water soluble polymer selected from the group consisting of polyvinylpyrrolidone, vinyl pyridoxone-vinyl acetate-copolymer, and polyethylene. Intrinsic amine, polyvinyl carbamide, polyglycolide, polypropionate, polymethyl methacrylate, polypropylene decylamine, polyethyleneimine, polyethyleneamine, Base-based cellulose, alkyl-hydroxyalkyl cellulose, carboxyalkyl cellulose, alkyl-hydroxyalkyl cellulose acetate succinate, alkyl-hydroxyalkyl cellulose acetate phthalate , alkyl-hydroxyalkyl cellulose phthalic acid vinegar, cellulose acetate ortho-sulphuric acid vinegar, temple powder, base-based base powder, base-based base powder, modified starch, octene Star succinate starch, dextran, polyoxyethylene _ polyoxypropylene-block copolymer, polyethylene oxide, polypropylene oxide, polyamino acid. In another embodiment, the anionic polymerization emulsifier is a random free radical copolymerization comprising at least one olefinic unsaturated acid anhydride of the formula I as a monomer

139305.doc -18- 200948269 wherein X is oxygen or NR5, R1 is hydrogen or sulfhydryl, η can be between 0-10, R2 and R3 are independently q-Cr alkyl, and R5 is hydrogen, alkyl , aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkane An amino group aryl group, a (di)arylaminoalkyl group, an alkylarylaminoalkyl group or an alkylarylaminoaryl 'aryl group may also be substituted, and wherein the olefin-based unsaturated sulfonic acid may be In the presence of an acid or salt form or as a mixture of acid and salt forms, at least one olefinically unsaturated monomer of formula II is h2c=cr'

Wherein Y is oxygen or NR5, R4 is hydrogen or methyl, and R5 and R6 are each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkane Alkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminealkyl Or a pyraryl aryl aryl group and optionally other monomers. The salt of the sulfonic acid of the formula 1 is preferably an alkali metal salt or a salt. Cl_c2()-alkyl, either alone or in combination of the above, is suitable as the alkyl group. In particular, it may be mentioned that the core-匚6·alkyl group, such as methyl, ethyl, propyl, decylethyl, butyl, 1-mercaptopropyl, 2-hydrazinopropyl, ^di Ethyl ethyl, pentyl, 1-decyl butyl, 2-mercaptobutyl, 3-methylbutyl, methylpropyl, 1,2-dimethylpropyl, 2,2-dimethyl Propyl, ethylidenepropyl, hexyl, 4-decylpentyl, 1-decylpentyl, 2-methylpentyl, 3-decylpentyl, 1,1-dimethylbutyl, 1&gt; 2_dimercaptobutyl, -di1,3-dimethyl 139305.doc -19- 200948269 butyl, 2,2-dimercaptobutyl, 2,3-dimethylbutyl, 3,3 _Dimethylbutyl, 1-ethylbutyl, 1,1,2-trimercaptopropyl, trimethylpropyl, 1-ethyl-1-methylpropyl and Lethyl_2_ Mercaptopropyl, cyclohexyl, n-heptyl, n-octyl, 2-ethylhexyl, decyl, isodecyl, undecyl, lauryl, tridecyl, tetradecyl, pentadecane Base, cetyl, heptadecyl or stearyl. It is to be understood that aryl means monocyclic or polycyclic (if appropriate substituted) aromatic hydrocarbon groups. Mention may be made, for example, of phenyl, naphthyl or phenyl substituted by a meridin (e.g., fluorine or chlorine). The morphoxy group is bonded to the alkyl group of the main chain via an oxoproo (-〇-). The aryloxy group is bonded to the aryl group of the main chain via an oxygen atom (-〇-). Other monomers may include, for example, vinyl aromatic monomers (eg, styrene and styrene derivatives such as alpha-mercaptostyrene, vinyl toluene, o-, m-, and p-methyl phenyl hydrazine, Ethylvinylbenzene, vinylnaphthalene, vinyl quinone benzene) and the corresponding halogenated ethylenic aromatic monomer, or having a nitro group, an alkoxy group, a dentate group, an alkoxycarbonyl group, a carboxyl group, Amino- and alkylamino-based ethylenic aromatic monomers, alpha-dilute hydrocarbons (eg, acetamethylene, propylene, hydrazine-butene, 1-pentene, 1-hexene, isobutylene, or long chains (ClG_C2) ()) alkyl (X-olefin) 'diene (such as butadiene and isoprene), vinyl alcohol ester (such as vinyl acetate), vinyl halide (such as ethylene, vinyl bromide or fluorine) Ethylene, diethylene vinylene, difluoroethylene vinyl, dibromoethylene bromide), vinyl nitrile, vinyl carboxylate, 1-vinylamine (eg 1 -vinylpyrrolidone, 1-vinyl six) Hydropyridone, 1-vinyl caprolactam, 1-vinylamine, vinylacetamide or 1-methyl-indole-vinylacetamide, N-B 139305. Doc -20- 200948269 alkenyl imidazole), a monoethylenically unsaturated monomer (such as acrylic acid, methacrylic acid, fumaric acid, maleic acid and itaconic acid) &lt;^-(:24-alkyl ester and Monosubstituted and disubstituted and unsubstituted decylamines, vinyl phthalic anhydrides (eg maleic anhydride), unsaturated aldehydes (eg acrolein), or unsaturated ethers (eg 1,4-cyclohexane) Sterol divinyl ether, L4-cyclohexane dimethanol monoethyl ether, butanediol diethyl ether, butanediol monovinyl ether, cyclohexyl vinyl ether, diethylene glycol divinyl Ether, ethylene glycol monovinyl ether, ethyl e vinyl ether, methyl vinyl ether, n-butyl vinyl ether, octadecyl vinyl ether, triethylene glycol vinyl methyl ether, vinyl Isobutyl ether, ethenyl (2-ethylhexyl) ether, vinyl propyl ether, vinyl isopropyl ether, vinyl lauryl ether, vinyl tert-butyl ether, hexanediol Divinyl sulphide, hexanediol monovinyl ether, diethylene glycol monovinyl ether, diethylaminoethyl vinyl ether, polytetrahydrofuran _290 divinyl ether, Ethylene glycol divinyl ether, ethylene glycol butyl vinyl ether, ethylene glycol divinyl ether, diethylene glycol divinyl ether, trimethylolpropane trivinyl ether or aminopropyl ethylene It should be understood that a polymer described by "free radical" means a polymer prepared by radical polymerization. It should be understood that a copolymer described by "random" means that the monomer sequence is by a monomer. Copolymerization parameters are used to determine the copolymer. Accordingly, this is also effective for copolymers composed of two or more types of monomers. Such polymers are also described as statistical copolymers. In another preferred embodiment A, random The free-radical copolymer is a monomer of the above formula 1, specifically 2-acryloylamino-2-indole-based propylene-based acid and at least 139305.doc -21 - 200948269 olefin-based unsaturated monomer of formula II Form H, C=CR4 1 O^Y-R6 Π wherein Y is oxygen or NR, R4 is hydrogen or fluorenyl, and R5 and R6 are hydrogen alkyl, aryl, alkylaryl, arylalkyl, alkane Oxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (two An arylaminoalkyl group, an alkylarylaminoalkyl group or an alkylarylaminoaryl group (wherein both the alkyl group and the aryl group have the above meanings) and, as the case may be, another monomer. In a further preferred embodiment, the random free radical copolymer comprises 2-acrylamido-2-indenyl-1-propanesulfonic acid as a monomer and at least one olefinic unsaturated monomer of the formula 1] Wherein Y is oxygen, R4 is hydrogen and R6 is hydrogen or alkyl. Thus, in this preferred embodiment, the random radical copolymer comprises 2-acrylamido-2-methyl as a monomer -1-propidone acid and at least one acrylic acid. These acrylates are, for example, methyl acrylate, ethyl acrylate, propylene acrylate, isopropyl acrylate, butyl acrylate, acrylic acid 2- Methylpropyl S曰, butyl acrylate, hexyl acrylate, hexamethacrylate, n-octyl acrylate, 2-ethylhexyl acrylate, decyl acrylate, isophthalic acid acrylate, acrylic acid Monoalkyl ester, lauryl acrylate, tridecyl acrylate, tetradecyl acrylate, pentadecyl acrylate, hexadecyl acrylate, hexadecanthate or stearyl acrylate The copolymers and their preparation are disclosed in WO 05/046328. 139305.doc -22- 200948269 In the embodiment, component c) comprises at least one polymeric emulsifier. In another preferred embodiment, component c) comprises at least one water soluble polymeric emulsifier. In another preferred embodiment, component c) comprises at least one anionic polymeric emulsifier. In another preferred embodiment, component C) comprises at least 2 emulsifiers, preferably 3-5 emulsifiers. In still another preferred embodiment, component c) comprises a polymerization and a non-polymeric emulsifier. In still another preferred embodiment, component c) comprises a water soluble polymeric emulsifier and at least one non-polymeric emulsifier. In another preferred embodiment, component c) comprises an anionic polymeric emulsifier and at least one non-polymeric emulsifier. In other preferred embodiments, component e) comprises a water-soluble polymeric emulsifier, a nonionic non-polymeric emulsifier, and an anionic non-polymeric emulsifier. In another preferred embodiment, component c) comprises an anionic polymeric emulsifier, a nonionic non-polymeric emulsifier and an anionic non-polymeric emulsifier. The combination of several different emulsifiers improves the stability of the EC formulation. In addition, the EC of the present invention may include other conventional formulation additives such as heart, antifoam, antifreeze, preservative, colorant, and wetting agent. Suitable antifoaming agents are, for example, aliphatic or aromatic monoalcohols having 4 to 14, preferably 6 to 1 carbon atoms, such as n-octanol or n-nonanol or polyoxo emulsification 139305.doc -23· 200948269 Agent. The amount of antifoaming agent is usually from 0 to 10% by weight, preferably from 0.011% by weight, based on the formulation. Typical antifreeze agents are, for example, ethylene glycol, propylene glycol, and glycerin. Typical preservatives are, for example, vitamin E acetate, benzoic acid, sorbic acid, furfural and trace microbicidal compounds. The amount of preservative is usually from 0 to 10% by weight of the formulation, preferably 〇 1 by weight 〇 / 〇. Typical colorants include oil-soluble dyes such as Vitasyn® Patentblau (Clariant, Germany) 〇 Typical wetting agents (for example) polyethoxylated phenols (containing 丨 3 〇 Mo Er Ethylene Oxide), Poly B Oxidized fatty alcohols (containing U0 molar ethylene oxide), tridecyl alcohol polyglycol ethers and alkyl- or alkylphenyl-sulfonates. The amount of wetting agent is usually from 0 to 50% by weight of the formulation, preferably from 〇 1 〇 by weight. The total content of the other formulation additives is usually from 〇52% by weight, preferably from 0% to 30% by weight, more preferably from 5% to 25% by weight, based on the formulation. The EC formulations of the present invention are prepared in a manner known per se by mixing, if desired, the components by mixing and/or heating. The product so obtained is usually a homogeneous emulsion concentrate. Containers suitable for formulation are customary for all containers of crop protection products, primarily bottles, canisters and bags made of chemically resistant polymers. In particular, water-soluble containers (mainly w-w, I-water) cereal film bags are advantageous based on the use of polyvinyl alcohol. For antifungal applications, the EC formulation is usually formulated with a suitable diluent (usually water), preferably at least 10-400', preferably a 10-150 fold excess of diluent. 139305.doc •24- 200948269 The spray liquid thus obtained can be used in household and garden applications, vector control and public health to control fungi on crop plants, their environment, seeds or propagation materials. Ο ❹ The formulations of the invention are suitable for use as fungicides. It is known for its outstanding efficacy against a broad spectrum of phytopathogenic fungi including soil-borne fungi, which are especially derived from Plasin〇di〇phoromycete and Peronosporomycete (again Oomycetes (CyomyCete, Chytridiomycete, Zyg〇mycete, ASCOmyCete, Basidi〇mycete, and Deuteromycetes) (Deuteromycete) (also known as Fungi ___. Certain internal absorption methods are effective and can be used as leaf fungicides, fungicides for seed dressing and soil fungicides for crop protection. In addition, it is suitable for control Especially harmful fungi that appear in the roots of trees or plants. Many phytopathogenic fungi on the control of various cultivated plants and plant propagation materials (eg, seeds, and harvested materials of such plants) are important 'cultivated plants' (for example) booties, such as wheat, rye, barley, black wheat, oats or rice, · secret paper. ^ ^ ^ ^, sweet, such as sugar beet or feed pear: Li: peach: Pear:, stone fruit or non-nuclear fruit, such as apple, legume strawberry, tree, blackberry, or gooseberry, · illusion such as lentils, peas, purple flower seedlings, such as hγ alienation or ugly; oil planting , oil palm, Huafeng "... sunflower coconut, cocoa beans, 10,000 fiber plants, such as cotton / Asian: reed 'such as pumpkin, cucumber or melon; such as thumb, lemon ^ hemp; ##类's lemon 桓, _ or Citrus, vegetables, such as fried vegetables, Ge J393〇 5.d〇c -25- 200948269 Chicory, asparagus, kale, carrot, red pepper; laurel plant, bismuth, potato, sprout or or, , pear tree, cinnamon tree or camphor; energy and raw plant, such as jade __ to rice. Tobacco. Nuts, ', Dan, rape, sugar cane or oil palm; jade wood, buried early, nuts, coffee pot. And grapes , 10 Ml talents, bananas; vines (edible grapes (four) vines), hops; turf; days _ (four) objects or views # plants and forest plants, such as &amp; such as conifers. / Huomu, broadleaf trees or often Green plants, for example, preferably 'these formulations are used to control many of the crops on the crop g, farm crop systems (for example) horse yam, sugar beet, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, canola, beans: plant 4 turns, coffee or sugar cane; fruit; vine Plants; ornamental plants, or vegetables 'eg cucumbers, tomatoes, beans, or squashes. Labels. Plant propagation materials' are understood to mean all plant reproductive sigma such as seeds and vegetative plants such as shoots and tubers (eg potatoes): It can be used for plant proliferation. This includes seeds, roots, fruits, y balls, rhizomes, shoots, buds and other parts of plants. Seedlings and young plants that can be transplanted after germination or after emergence from the soil can also be mentioned. These young plants can also be protected by partial or partial treatment prior to transplantation. Preferably, the plant propagation material is treated with Compound I and compositions thereof for controlling many fungi on cereals such as wheat, rye, barley and oats, rice, corn, cotton and soybeans.

The term "cultivated plants" is understood to include plants which have been modified by propagation, mutagenesis or genetic engineering. Genetically modified plants are the following plants: I 139305.doc •26· 200948269 Genetic material has been modified using recombinant DNA technology and cannot be obtained by cross-breeding, mutation or natural recombination in the natural environment. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to modify certain characteristics of the plant. The term "cultivated plants" is understood to also include plants which have been rendered tolerant to the application of specific herbicides by means of conventional methods of breeding or genetic engineering, such as hydroxyphenylpyruvate dioxygenase. (HPPD) inhibitor; acetaminolate synthase (ALS) inhibitors, such as sulfonic acid ureas (see, for example, U.S. Patent No. 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98 /02 526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073) or imidazolidone (see, for example, U.S. Patent No. 6,222,100) WO 01/82685, WO 00/26390 'WO 97/41218, WO 98/02526 'WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356 WO 04/16073); enol-type acetone-mercaptooxalic acid-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate (see for example WO 92/00377); glutamine synthase ( GS) inhibitors, such as glufosinate (see, for example, European Patent No. EP-A-0242236, European Patent No. EP-A-242246) or Oxney (ox) Ynil) herbicides (see, e.g., U.S. Patent No. 5,559,024). Many cultivated plants have been rendered tolerant to herbicides by conventional methods of breeding (mutagenesis), for example, Clearfield® canola is resistant to imidazolinones such as imazamox. Genetic engineering methods have been used to cultivate cultivating plants (eg, soybean, cotton, corn, sugar beet, and canola) from herbicides such as glyphosate and glyphosate, some of which are marketed under the trade name RoundupReady® ( Glyphosate) and LibertyLink® (glyphosate) are commercially available. The term "cultivated plants" is understood to also include plants which are capable of synthesizing one or more insecticidal proteins by means of recombinant DNA techniques, in particular those known to be from the genus Bacillus, in particular From Bacillus thuringiensis i/iwrMgiewsz··?), such as δ-endotoxin, such as CrylA (b), CrylA (c), CrylF, CryIF (a2), CryIIA (b), CrylllA, CrylllB (bl) or Cry9c Nutrient insecticidal protein (VIP), such as VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins infesting nematodes by bacteria, such as Photorhabdus spp. or Xenorhabdus spp.; Toxins, such as scorpion toxin, spider toxin, melittin toxin or other insect-specific neurotoxin; toxins produced by fungi, such as Streptomycetes toxins; plant lectins, such as pea or barley plant lectins; coagulation; Protease inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cysteine protease inhibitors or papain inhibitors; Inactivating protein (RIP), such as ricin, maize-RIP, acacia, loofah, saporin or synodin; steroid metabolism enzymes such as 3-hydroxysteroid oxidase , pepisol-IDP-glycosyl-transferase, cholesterol oxidase, ecdysone inhibitor or HMG-CoA-reductase; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase Diuretic hormone receptor (helicokinin receptor); laughing synthase, bibenzyl synthase, chitinase or 139305.doc -28- 200948269 glucanase. In the context of the present invention, such insecticidal proteins or toxins should be expressly understood to be also protoxins, hybrid proteins, truncated or modified proteins. Hybrid proteins are characterized by a new combination of protein domains (see for example WO 02/015701). For example, such toxins or other examples of genetically modified plants capable of synthesizing such toxins are disclosed in European Patent No. EP-A 374 753, WO 93/007278, WO 95/34656, European Patent No. EP-A 427 No. 529, European Patent No. EP-A 451 878, WO 03/018810 and WO 03/052073. Methods of producing such genetically modified plants are widely known to those skilled in the art and are described, for example, in the publications mentioned above. The insecticidal proteins contained in the genetically modified plants allow the plants producing the proteins to obtain the susceptibility to pests from all taxonomic insect populations, especially for beetles (Coeloptera), two-winged insects. (Diptera) and the butterfly (Lepidoptera) financial acceptability. Genetically modified plants capable of synthesizing one or more insecticidal proteins are described, for example, in the above publication, and some are commercially available, for example, YieldGard® (a corn cultivar producing Cry 1 Ab toxin), YieldGard® Plus (creating CrylAb and Cry3Bbl toxin corn cultivar), Starlink® (Cry9c toxin-producing corn cultivar), Herculex® RW (producing Cry34Abl, Cry35Abl and enzymatic phosphinothricin-N-acetyltransferase (Phosphinothricin-N-Acetyltransferase) [PAT Corn cultivar); NuCOTN® 33B (cotton cultivar producing CrylAc toxin), Bollgard® 1 (cotton cultivar producing Cry 1 Ac toxin), Bollgard® 11 (cotton cultivar producing Cry 1 Ac and Cry2Ab2 toxin) 139305.doc -29- 200948269 species; VIPCOT® (cotton cultivar producing VIP-toxin); NewLeaf® (potato cultivar producing Cry3 A toxin); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Btll (eg Agrisure® CB) and Bt 176 from Syngenta Seeds SAS, France (corn cultivar producing Cry lAb toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (a modified form of corn cultivar producing Cry3A toxin, see WO 03/018810), MON 863 from Monsanto Europe S_A·, Belgium (corn cultivar producing Cry3Bbl toxin), from Monsanto Europe SA, Belgium's IPC 53 1 (a cotton cultivar that produces a modified form of Cry 1 Ac toxin) and 1507 from Pioneer Overseas, Belgium (a corn cultivar that produces Cry 1F toxin and PAT enzyme). The term "cultivated plants" is understood to also include plants which are capable of synthesizing one or more proteins by recombinant DNA techniques to enhance the resistance or tolerance of the plants themselves to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenic associated proteins" (PR proteins, see, for example, European Patent No. EP-A 0 392 225), and plant resistance genes (such as potato cultivars) whose performance acts to inhibit wild potato originating from Mexico. (Solanum bulbocastanum) Phytophthora infestans resistance gene) or T4-lysozyme (for example, capable of synthesizing such bacteria with enhanced resistance to diseases such as Erwini a _ amyl v or a a potato cultivar of resistant protein). Methods of producing such genetically modified plants are widely known to those skilled in the art and are described, for example, in the publications mentioned above. 139305.doc -30- 200948269 The term "cultivated plants" is understood to also include plants which are capable of synthesizing one or more proteins by means of recombinant DNA technology to increase the productivity of their plants (eg biomass production, grain production). , starch content, oil content or protein content), tolerance to drought, salinity or other growth limiting environmental factors, or tolerance to pests and fungal, bacterial or viral pathogens. The term "cultivated plants" is understood to also include plants which comprise, by means of recombinant DNA techniques, a quantity-altering inclusion or a new inclusion to specifically improve human or animal nutrition', for example to produce a long chain ω_3 promoting health. An oil crop of fatty acids or unsaturated omega-9 fatty acids (eg Nexera® canola). The term "cultivated plants" is understood to also include plants which, by using recombinant DNA techniques, contain varying amounts of inclusions or new inclusions to specifically improve the production of raw materials, for example, to increase the number of branches. Horse-aged potatoes (eg Amflora® potato). These formulations are especially useful for controlling the following plant diseases: ❸ From the genus Albug0 spP., in ornamental plants and vegetables (for example, A. Candida) And to the hollyhock (for example, A trag〇p〇g〇nis), -• Alternaria (10) (4) State "spp." (chain genus leaf spot), stored in vegetables ' Vegetable rapeseed (A. brassicola or b sicae), sugar beet (a. t_is), fruit, rice bran, large Dan, potato (for example, eggplant) Alternaria (A. solani) or Alternata (Alternata), Fanyou (for example, Alternaria solani or Alternaria alternata) and wheat, 139305.doc -31- 200948269 • (Aphanomyces spp.) 'On sugar beets and vegetables, • Ascochyta species on sorghum and vegetables' For example, wheat on wheat, A. tritici (anthrax) Disease (anthracnose) and barley on barley (A. hordei) ' • Helminthosporium and Helicobacter genus (Bipolaris and Drechslera SPP.) (sexual type : Cochliobolus spp.) 'stored in corn (eg, D. maydis), pupa (eg, B. sorokiniana: spotted), rice榖 (for example, B. oryzae) and turf, • Blumeria graminis (formerly known as Erysiphe) (powder disease), deposited on sputum ( For example, wheat or barley), Botrytis cinerea (sex type: Botryotinia fuckeliana: grey mold), stored in fruits and berries (for example, Strawberries, vegetables (eg, lettuce, carrots, celery and kale), rapeseed, flowers, vines, forest plants and wheat, • Bremia lactucae (downy mildew), • long Ceratocystis spp. (also known as Ophi〇st〇ma) (rot disease or blight), deposited on broad-leaved trees and evergreen plants, for example, Dutch plague bacteria on eucalyptus (C. ulmi) (eucalyptus disease), • Cercospora spp. (tail Is a leaf spot), stored in corn, rice, sugar beet (for example, C. beticola), Gan 139305.doc -32· 200948269 cane, vegetables, coffee, soybeans (eg 'soybean gray benefits Human spot disease il (C·S0jina) or soybean porphyra (C. kikuchii) and rice husk, Fan 'J, Mai · Cladosporium spp., stored in tomato (for example, eggplant leaves) Mold (C. fulvum): leaf mold) and Yiyi, such as C. herbamm (black smut (black with...

• Claviceps pUrpurea (Claviceps pUrpurea) (Eloba (3), • Cochliobolus spp. (Asexual type: Helminthosporium) (leaf leaf spot), stored in corn (C. carbormm), grain (eg, Helicobacter pylori ^ sativus), asexual type: wheat root rot) and rice blast (eg, uterine C. miyabeanus 'asexual type: rice leaf spot pathogen ', 'Colletotrichum spp.' (sexual type: Glomerella (anthrax)' stored in cotton (eg, cotton gossypii), corn (eg, C. graminic〇la), seedless fruits, potatoes (eg, C. cocc〇des: special Black dot), legumes (eg, c. lindemuthianum), and soybeans (eg, c truncatum), • Corticium spp., for example, rice C. sasakii (sheath blight), on soybeans and ornamental plants Corynespora cassiicola (leaf spots), • Cycloconium spp., for example, C. oleaginum, 139305. Doc -33- 200948269 • Cylindrocarpon spp. (eg, fruit tree canker or young vine atrophy, sexual type: Nectria spp. or Neocetrica spp. )), stored in fruit trees, vines (for example, C. liriodendri, sexual type: Neonectria liriodendri: black foot disease) and ornamental plants, • Dematophora necatrix on soybeans (sexual type: R〇sellinia) (root and stem spoilage), • Diaporthe spp., for example, D. phaseolorum (damping off) on soybean, 脐• umbilical cord genus (also known as snail) (sexual type: genus genus) Corn, grains such as barley (eg, D. teres, net blotch) and small (For example, D. tritici-repentis: tan spot), rice and turf, • Phyllostachys pubescens (Formitip〇ria pUnctata) (aka Phellinus, f mediterranea, Phaeomoniella chlamydospora (Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and/or grapevine cavity Esca (Butterry phasicus) Enzymes (Ε· veneta): charcoal disease) and vines (E. ampelina: anthracnose), • Entyloma oryzae (black powder) on rice blast ), 139305.doc -34- 200948269 • Epicoccum spp. (black mold) on wheat, • Erysiphe spp. (powder disease), stored in sugar beet (beet) E. betae), vegetables (eg, pea powdery mildew (E. pisi) For example, gourd (for example, E. cichoracearum), cabbage, rapeseed (for example, E. cruciferarum), • Euthypa lata (curvular ulcer) Disease (Eutypa canker) or dieback (dieback), asexual type: Cytosporina lata, also known as Libertella blepharis, stored in fruit trees, vines and ornamental plants, • umbilical cord Exserohilum spp. (also known as the genus Echinochloa), stored in corn (eg, E. turcicum), • Fusarium spp. on various plants (sexual) Type: Gibberella (Fusarium wilt, root or stem spoilage), such as F. grarninearum or F. culmorum (root rot) on cereals (eg, wheat or barley) Disease, spot disease or scab), F. oxysporum on tomato, F. solani on soybean, and F. verticillioide on corn, • 榖(eg wheat or barley) and the top cyst of the corn (Gaeu Mannomyces graminis) (take-all), • Gibberella spp. 'in the grain (eg, G. zeae) and rice blast (eg, rice seedlings) G. fujikuroi: Bakanae disease, • Glomerella cingulata on vines, pome fruits and other plants and cotton cubs on ladder flowers (G. gossypii) ), 139305.doc -35- 200948269 • Aphid staining complex on rice blast, • Guignardia bidwellii (black rot) on the vine, • Rosaceae and amaranth Gymnosporangium spp., for example, G. sabinae on the pear tree (recorded), • Helminthosporium spp. on corn, grain, and rice (again In the name Helminthosporium, sexual type: Helminthosporium), • Hemileia spp., for example, Hemileia vastatrix (Caf non-leaf) Recorded disease), Isariopsis clavispora on the vine (also known as the grape branch) Ladosporium vitis)), • Macrophomina phaseolina (also known as phaseoli (root and stem spoilage) on soybeans and cotton • Snow mold microseat on booty (eg wheat or barley) Microdochium nivale (also known as Fusarium) (Pink snow mold); • Microsphaera diffusa (soy powdery mildew) on soybeans, • Chains on stone fruits and other Rosaceae plants Monilinia SPP. 'For example, M. laxa, M. fructicola, and M. fructigena (flowers) Diseases and blight, brown rot), cereals, bananas, seedless fruits, and Mycosphaerella spp. on peanuts, for example, Gryptobacter sinensis on wheat (M. 139305.doc • 36 - 200948269 graminicola) (asexual type: Septoria tritici, Septoria blotch) or banana on the banana (M. Hjieiisis) (banana leaf spot (black) Sigatoka disease)),

• Peronospora spp. (downy mildew), stored in cabbage (eg, cruciferous plant P. brassicae), canola (eg, P. parasitica), onion ( For example, p destructor), tobacco (p. tabacina), and soybean (for example, P. manshurica), the potato rust il on soybean (Phakopsora) Pachyrhizi) and P. meibomiae (soybean rust), Phialophora sPP·, present in, for example, vines (eg P. tracheiphila and tetrasporium) It belongs to the fungus (f tetraspora) and soybean (for example, the soybean stem rot fungus (Phomopsis spp), which is stored in the sun, (eg 'vine disease (P· viticola) ): cans and leaf spot) and soybean stem spoilage: P. phaseoli, sexual type: Diaporthe phase〇l〇rum), vine (eg, I northern stem corn) Phys〇rma maydis (Phyto-Pr. Phytophthora) (Phyt-a spp is wilt, root rot) 1 39305.doc -37- 1 gre8ata): Stem spoilage)) • Ph〇ma iingam on roots and (sickness) and sugar beet p. betae) (root rot stem rot disease and stagnation disease), 'leaf spot 200948269 fruit rot and stem rot), stored in various plants such as red pepper and gourd (for example, P. capsici) ), soybeans (for example, P. megasperma, Phytophthora sojae (also known as P. sojae), potatoes and idiots (for example, P. infestans: Late blight and broad-leaved trees (for example, P. ramorum: sudden oak death) • Plasmodiophora brassicae (club root) ), stored in cabbage, canola, radish and other plants, • Plasmopara spp., for example, P. viticola (grape downy mildew) and sunflower on the vine P. halstedii, • Rosaceae, hops, pears and seedless fruits Podosphaera spp. (powder disease), for example, P. leucotricha on apples, Polymyxa spp., for example, in cereals (eg barley and Wheat) (P. graminis) and sugar beet (P. betae) and thereby spread viral diseases, • cereals (eg wheat or barley) Pseudocercosporella herpotrichoides (eye-like markings, sexual type: Tapesia yallundae), • Pseudoperonospora (downy mildew) on various plants, for example, Cuban pseudo-frozen mold on gourd (P. humilis) or P. humili on hops, • Pseudopezicula 139305.doc -38- 200948269 tracheiphila on vines (red fire disease) ) or, rotbrenner', anamorphic: Phytophthora (Phialophora), • Puccinia spp. (rust) on various plants, for example, cereals (eg 'wheat, barley or rye) Occult rust (P. tricensis) P. graminis (stalk rust or black rust) or P. recondita (brown rust or leaf rust) and asparagus (for example, P. asparagi), • Pyrenophora tritici-repentis on wheat (asexual type: Helminthosporium) (brown spot) or barley on barley (P. teres) (reticular pathosis) , • Pyricularia spp., for example, P. oryzae on rice stalks (sex type: Magnaporthe grisea, rice stalk) and turf and grain fatigue P. gri sea, • turf, rice, corn, wheat, cotton, canola, geranium, sugar beet, vegetables, and various other plants of the genus Pythium spp. For example, P. ultiumum or P. aphanidermatum, • Ramularia spp., for example, R. on barley. Collo-cygni (column leaf spot, physiological leaf spot) and R. beticola on sugar beet, • cotton, rice bran, potato, turf, corn, canola, potato, Rhizomes on sugar beet, vegetables and various other plants 139305.doc •39- 200948269 (Rhizoctonia spp.), for example, R. solani (root and stem spoilage) on soybean, Rhizoctonia solani (rice sheath blight) on rice or R. cerealis on wheat or barley (silk fungus spring blight), • strawberries, carrots, cabbage, vines and tomatoes Rhizopus stolonifer (black mold, soft rot), Rhynchosporium secali on barley, rye and triticale (tiger skin disease ( Scald)), • Sarocladium oryzae on rice stalks and S. attenuatum (sheath rot), • Sclerotinia spp. Corruption or white mold), in vegetables and crops (such as rapeseed, sunflower ( For example, S. sclerotiorum and soybeans (for example, s. rolfsii), • Septoriaspp. on various plants, for example, on soybeans. S. glyCines (brown spot), S. tritici (Saccharomyces cerevisiae) on wheat, and s. nodorum on the sputum (also known as stagonospora) (Saccharomyces cerevisiae), • Uncinula necator (also known as powdery mildew) on the vine (smut) 'asexual type: grape powder spore (Oidium tuckeri)), • Setospaeria spp. (leaf blight), stored in corn (for example, S. turcicum, also known as S. cerevisiae 139305.doc -40 - 200948269 (Helminthosporium turcicum)) and on the turf, • Sphacelotheca spp. (smut) is stored in corn (for example, S. reiliana: silk Head smut), sorghum and sugar cane, • Sphaerotheca fuliginea (powder disease) on gourd, Spongospora subterranea (powdery scab) on potato and thereby spread viral diseases, • Stagonospora spp. on cereals, for example, spores of wheat on the wheat (S. nodorum) (shell polyspora, sexual type: Leptosphaeria nodorum [also known as Phaeosphaeria]), • Synchronic endobioticum on potato (potato wart disease), • Taphrina spp., for example, τ. deformans (leaf curl disease) and T. pruni (plum pocket) on plum, • Thielaviopsis spp. on tobacco, pome fruit, vegetables, soybeans and cotton (black root rot) Disease), for example, T. basicola (also known as chalara elegans), • Tilletia spp. (common bunt (common bunt) Or stinking smut)), for example, wheat twigs (T. tritici) on wheat (again Wheat ticks (τ. caries), wheat head smut and wheat smut (τ. 139305.doc -41 - 200948269 controversa) (wheat dwarf bunt), • Typhula incarnata (grey snow mold) on barley or wheat, • Urocystis spp. on rye, for example, rye powdery mildew (U. occulta) (stem smut), • Uromyces spp. on vegetables, for example, beans (eg, U. appendiculatus, Also known as U. phaseoli and sugar beet (for example, U. betae), • Ustilago spp. (loose smut) )), stored in stolen goods (for example, U. nuda and U. avaenae), corn (for example, U. maydis: corn black) Powder disease) and sugar cane, • Venturia spp. (spot disease (scab)), stored in apples (eg, V. inaequalis) and pears • Verticillium spp. (wilt) on various plants such as fruits and ornamentals, vines, seedless fruits, vegetables and farm crops, for example, strawberries, canola, potatoes and tomatoes Verticillium dahliae (V. dahliae). These formulations are also suitable for controlling harmful fungi in terms of protection of materials (e.g., wood, paper, paint, dispersion, fiber or fabric) and storage product protection. Regarding the protection of wood and structural materials, special attention should be paid to the following harmful fungi: Ascomycetes, such as the genus Aspergillus spp.), Ceratocystis spp., and A. glabrata. _ 139305.doc - 42- 200948269 corpse, scorpion genus (*SWero/&gt;/zc&gt;mi3! spp.), Chaetomium (C/zaeiow/wm spp.), humus genus (opening Spp·), emblem PeirieZ/a spp., Spp.; Basidiomycetes, such as the genus C. m. 〇^ora spp., and the genus C. — • SPP·), GloeophyHum spp., Lentl (nus SPP·) Pleurotus (P/ewroiw Spp.), genus (ρ〇η·β Spp.), Longsuke Genus ("SerpM/a spp." and Stem. (Spp.); deuteromycetes, _ such as Aspergillus (10) spp.), genus Bacillus sp. (C/doaoWwm spp.), Penicillium (Pgm) .c&quot;&quot;called spp), Trichoderma (7WC/mr hall spp.), Alternaria (74/order like heart spp), Paecilomyces 〇Ρα such as 7〇m;; ceiS spp· ); and zygomycetes, such as Mucor spp.); and in addition to the protection of stored products, notable 疋The following yeasts: Candida (c(10) heart and spp.) and Saccharomyces cerevisiae ("Sacc/zarc» less cej cerevz'jize). The β-specific formulation is used by treating a fungus or a plant that is intended to protect against fungal attack, plant propagation material (e.g., seed), soil, surface, material, or habitat by using a fungicidal effective amount of the active substance. The application can be carried out before or after the plant, plant propagation material (e.g., seed), soil, surface, material, or habitat. • The formulations and compositions of the invention have a strong plant strengthening effect. It is suitable for stimulating the plant's defense against undesired microorganisms (for example, the above-mentioned harmful fungi as well as viruses and bacteria). The term "plant enhancer (the compound which induces resistance)" is understood to be followed by subsequent inoculation with the undesired microorganisms. The treated plants then exhibit a greater degree of resistance to resistance by such microorganisms. 139305.doc -43 200948269 Formulas can stimulate their compounds in formulations of plant defense systems. Thus, the formulations can be used to protect plants from infection by undesirable microorganisms for a certain period of time after application. After administration of the formulation, the period in which the vine is induced is typically extended by 1-28 days, preferably 1-14 days, or in the case of processing the seed, up to 9 months after sowing. Formulations of the invention are also suitable for increasing harvest yield. In addition, it is less toxic and exhibits good plant compatibility. The formulations may be applied to the plant propagation material either diluted or undiluted

The material 'is especially seed. The formulation is diluted from 2 to 1 Torr to yield from 0.01 to 60% by weight, preferably from 0.1 to 4% by weight, in the ready-to-use preparation. /◦ The active substance concentration. Methods of applying or treating agricultural chemical compounds and compositions thereof to plant propagation materials, particularly seeds, prior to sowing, are well known in the art and include seed dressing, coating, and Granulation and dip application methods. In a preferred embodiment, the compound or composition thereof is applied to the plant propagation material by a method that does not induce germination (e.g., by seed dressing, granulation, and coating).

The concentration of the active substance in the ready-to-use product can vary over a relatively wide range. - Generally speaking, the concentration is 11 G%, preferably 〇 (10). When used in plant protection, depending on the type of desired effect, the applied amount is between reading kilograms of active substance per hectare and 2. G kilogram of active substance per male seed treatment, for example by coating or soaking seeds. , through the amount of 0.1 grams -10 kg, usually U000 grams, kilograms of seeds. i car jiaji active substance / 139305.doc -44 - 200948269 When used for the protection of materials or museum products, the amount of active substance applied depends on the type of area and the desired effect. The amount normally applied in the protection of the material is, for example, 0. Sheikh _2 kg, preferably 克 5 g _! kg of active substance per cubic meter of treated material. L. It is preferred to add various types of adjuvants, herbicides, bactericides, other fungicides and/or insecticides (tank mix) to the formulation until use. These agents may be mixed with the formulation of the present invention in a weight ratio of 1:1 team i, preferably 1 〇. The adjuvants which may be used are, in particular, organically modified polyoxyalkylenes, for example 6ak ThrU S 240 , alcohol alkoxylates, such as Atplus 245®,

Atplus MBA 1303® &gt; Plurafac LF 300®^ Lutensol ON 30® ; E=/P〇肷 segmented polymers such as piur〇nic RpE 2〇30 and Gaap〇i B , alcohol ethoxylates such as Lutens〇i χρ 8〇, and sodium dioctylsulfosuccinate, such as Leophen RA®. Formulations of the invention in the form of fungicides may also be present with other active enamels, for example, with herbicides, insecticides, growth regulators, fungicides or otherwise with chemical fertilizers as premixes, or (if appropriate) does not exist until before use (bucket mixing). Mixing the formulation in the form of a fungicide with other fungicides may, in many cases, extend the range of fungicidal activity obtained or prevent the emergence of fungicide resistance. In addition, in many cases, synergies can be achieved. The following fungicides which may be added to the formulations of the present invention are intended to illustrate possible combinations, but are not intended to be limiting: A) Str〇bilurin, which is selected from the group consisting of: 139305 .doc -45- 200948269 0 by azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metoprol Metominostrobin, oresastrobin, picoxystrobin, pyraclostrobin, pyribencarb, trifloxystrobin, 2-(2-( 6-(3-Chloro-2-indolyl-phenoxy)-5-fluoro-pyrimidin-4-yloxy)-phenyl)-2-indolyloxyimido-N-indenyl-acetamidine Amine, 3-methoxy-2-(2-(N-(4-decyloxy-phenyl)-cyclopropane-carbiniminothioindolyl)-phenyl)-propionic acid methyl ester, Methyl 2-chloro-5-[l-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate and 2-(2-(3-(2,6-dichloro) Phenyl)-1-indolyl-allylaminooxyindenyl)- Phenyl)-2-nonyloxyimido-N-indenyl-acetamide; B) decylamines selected from the group consisting of: - formazan: benaxyl ), dinaraxi-M, bixafen, boscalid, carboxin, 〇, fenfuram, fenhexamid, fluenton Flutolanil, furametpyr, isopyrazam, isotianil, kiralaxyl, mepronil, statin (metalaxyl), 达达乐-Μ (high-efficiency mefenoxam), ofurace, oxadixyl, oxycarboxin, ° ratio of 0 ceramide (penthiopyrad) ), tecloftalam, thifluzamide, tiadinil, 2-amino-4-methyl-嚷0 sit- 139305.doc -46- 200948269 5-aniline aniline, 2-Chloro-N-(l,l,3-tridecyl-dihydroindol-4-yl)-nicotinamide, 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (2·, 4'-dioxadiphenyl-2-yl)-decylamine, 3-difluoromethyl-1-indolyl-1Η- Pyrazole-4-f acid (2',4'-dichlorodiphenyl-2-yl)-decylamine, 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (2 ',5'-Difluorodiphenyl-2-yl)-decylamine, 3-difluorodecyl-1-methyl-ίΗ-pyrazole-4-furic acid (2',5'-dichlorodi Phenyl-2-yl)-nonylamine, 3-difluoromethyl-1-indolyl-1Η-pyrazole-4-carboxylic acid (3',5'-difluorodiphenyl-2-yl)-indole Amine, 3-difluoromethyl-1-methyl-1Η-pyrazole-4-furic acid (3',5'-dichlorodiphenyl-2-yl)-decylamine, 3-difluoromethyl -1-methyl-1 Η-pyrazole-4-carboxylic acid (3'-fluorodiphenyl-2-yl)-decylamine, 3-difluoroindol-1-yl-1 -pyrazole-4- Capric acid (3'-chlorodiphenyl-2-yl)-decylamine, 3-difluoromethyl-1-indolyl-1Η-pyrazole-4-carboxylic acid (2匕fluorodiphenyl-2-yl) - indoleamine, 3-difluoromethyl-1-methyl-1Η-pyrazole-4-carboxylic acid (2, chlorodiphenyl-2-yl)-decylamine, 3-difluorodecyl-1- Mercapto-1Η-pyrazole-4-carboxylic acid (3',4',5|-trifluorodiphenyl-2-yl)-decylamine, 3-difluorodecyl-1-indenyl-111-pyridyl Oxazole-4-carboxylic acid (2',4',5|-trifluorodiphenyl-2-yl)-decylamine, 3-difluoroindol-1-yl-1 -pyrazole-4-decanoic acid [2-(1,1,2,3,3,3-hexafluoropropoxy) )-phenyl]-nonylamine, 3-difluorodecyl-1-indolyl-1Η-pyrazole-4-carboxylic acid [2-(1,1,2,2-tetrafluoroethoxy)-phenyl ]-decylamine, 3-difluorodecyl-1-indolyl-1Η-pyrazole-4-furic acid (4'-trifluorodecylthiodiphenyl-2-yl)-decylamine, N-( 3W-Dichloro-5-fluoro-diphenyl-2-yl)-3-difluorodecyl-1-indenyl-1H-pyrazole-4-nonanoate decylamine, N-(2-(l, 3-dimercapto-butyl)-phenyl)-1,3,3-trimethyl-5-fluoro-1H-pyrazole-4-nonanoate decylamine, N-(4'-chloro-31, 51-mono-diphenyl-2-yl)-3-dimurendyl·1-indolyl-1Η-° than saliva_139305.doc • 47· 200948269 4-decanoate, Ν-(4 ·-Gas-3,5,-difluoro-diphenyl-2-yl)-3-trifluoromethyl-1-indolyl-1H-pyrazole-4-carboxylic acid decylamine, hydrazine-(3· , 4'-digas _5, _ fluoro-monophenyl-2-yl)-3-trifluoromethyl-1-methyl- ΐΗ-° than 吐-4- decanoic acid, Ν-(3 ',5'-Difluoro-4,-methyl-diphenyl-2-yl)-3-difluoromethyl-L methyl-1Η-pyrazole-4-carboxylic acid decylamine, Ν-(3, ,5,-difluoro-4·-methyl·diphenyl-2-yl)-3-trifluoromethyl-1-methyl-1Η-pyrazole-4-decanoic acid decylamine,

(2-Dicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1-indolyl-1Η-pyrazine. 4-carboxylic acid decylamine, hydrazine-(cis-2-dicyclopropyl -2-yl-phenyl)-3-difluoromethyl-1-methyl-1 Η-pyrazole-4-decanoic acid decylamine, hydrazine-(trans-2-dicyclopropyl-2.yl-benzene ))-3-difluorodecyl-1-indolyl-1 Η-pyrazole-4-carboxylic acid decylamine; - sulphuric acid 醯 琳 类 class: dimethyl phor, flumorph; - phthalic acid guanamine : Flumetover, Fluopicolde, Fluopyram; _ Other methotrexate: carpropamid, dicyclomet, double Mandiproamid, oxytetracyclin, silthi〇faml and N-(6-methoxy _

° 唆-3-yl) Cyclopropanol decylamine; C) ° Sitting class' is selected from the group consisting of: - diazoles, azaconazole, battanol, bromconazole, ring Conazole, fenconazole, diniconazole, diniconazole-M, oxiconazole, fenbuconazole, and ketoconazole. Sit, Fluoride, Salvation, Difluxon, Liukang Jun, Acetamazole, Species, Ye Ye Saliva, Maidini, Nie, Bacchus, Pan Kangyu: Huanqi, Fushun Kangxi, Shi Xi Fluoride, Dekli, Sikhli, Tri-Tylon, Triteconazole, Monoconazole, 1-(4-Phenylphenyl I39305.doc -48- 200948269 ([1,2,4] Triazole-1 -yl)-cycloheptanol; - imidazoles: cyazofamid, imazalil, pefurazoate, propionate, triflumizol; - benzo σ米0 sitting class: benomyl, carbendazim, fuberidazole, thiabendazole; - other: ethaboxam, soil fungus ( Etridiazole) and hymexazole; D) a heterocyclic compound selected from the group consisting of: -° ratio biting: fluazinam, pyrifenox, 3-[5 -(4-chloro-phenyl)-2,3-dimethyl-isoxazodin-3-yl]-pyridine, 3-[5-(4"methyl-phenyl)-2,3-di Methyl-isoxazolidine-3-yl]-pyridine, 2.3.5.6-tetra-chloro-4-nonanesulfonyl-pyridine, 3,4,5-tris-pyridine-2.6- Di-曱 guess, N-(l-(5- desert-3-gas-D ratio bit-2-yl)-ethyl)-2,4-di-nicotinamine, N-[(5-bromo- 3-oxo-pyridin-2-yl)-methyl]-2,4-dichloro-nicotamine; - biting class: B, bupirimate, cyprodinil, II Diflumetorim, fenarimol, ferimzone, mepanipyrim, nitrapyrin, nuarimol, pyrimethanil ; - Hexahydrogen &quot;Comparative category: triforine; -»Bilo: fenpiclonil, fludioxonil; - chlorin: aldimorph , morpholine, 139305.doc •49- 200948269 dodemorph-acetate, fenpropimorph, tridemorph; - hexahydrogen ratio: Benzene rust (fenpropidin); - bismuth imine: fluoroimid, iprodione, procymidone, vinclozolin; - non-aromatic 5 - Heterocyclic ring: famoxadone, fen nano-same (fen Amidone), octhilinone, probenazole, 5-amino-2-isopropyl-3-oxo-4-o-tolyl-2,3-dihydro-pyridyl S-allyl ester of oxazol-1-thiocarbamate; - Others: acibenzolar-S-methyl, sigma sulphate (amisulbrom), avidin (anilazin) ), blasticidin-S, captafol, captan, chinomethionat, dazomet, debacarb, dexamethasone Dioxolezine, difenzoquat, oatmeal-methylsulfate, fenoxanil, Folpet, oxolinic acid, piperalin, general Proquinazid, ° pyroquilon, quinoxyfen, triazoxide, tricyclic. Tricyclazole, 2-butoxy-6-shidin-3-propyl decen-4-one, 5-chloro-1-(4,6-dimethoxy-pyrimidin-2-yl)- 2-mercapto-1H-benzimidazole, N-(4-(3-methoxy-1-(5-methyl-[1,2,3]thiadiazol-4-yl)-naphthalene-2 -yl)-thiazol-2-yl)-butanamine, 5-chloro-7-(4-methylhexahydropyridin-1-yl)-6-(2,4,6-trifluorophenyl )-[1,2,4]triazolo[l,5-a]pyrimidine, 6-(3,4-dichloro-phenyl)-5-methyl-[1,2,4]triazole -50- 139305.doc 200948269 [1,5-called 〇 唆-7-ylamine, 6-(V-tert-butylphenyl)-5-fluorenyl-[1,2,4]triazolo-p' Ta]pyrimidine. ? *W1 , 哫7'-amine, 5_mercapto-6-(3,5,5-trimethyl-hexyl)-[1,2,4]triazolo η ς L,5 -a]pyrimidin-7-ylamine, 5-methyl-6-octyl-[1,2,4]triazole and 丨5 π-open 15-a]pyrimidine _7-ylamine, 6-fluorenyl % octyl-[1,2,4]disindol [i,5_a] spray. J 疋'7-ylamine, 6-ethyl-5-octyl_[1,2,4]2 弁[i,5-a]u densely biting J* decylamine, 5-ethyl-6-octyl-[1,2,4]dipyridinium [i,5-a] mouth σ定_7_ Its ^ «疋" base amine, 5_ethyl_6_(3,5,5_3

F-hexyl)[1,2,4]disintegrated _7·ylamine, 6•octyl _ 5_propyl-[1,2,4]tris-[1,5-a] Pyridin-7-yloxy, 5-methoxymethyl 6-octyl[1,2,4]disindol [i,5_a], lysine, 6-octyl_5_fluoro Base [1,2,4]disindol [i,5_a], _7-amine and 5-trimethylmethyl-6-(3,5,5-trimethyl-hexyl)-[124]triazole And [i5a]pyrimidin-7-amine; E)carbamate' is selected from the group consisting of: - thio and dithioamino phthalates: ferbam, manganese powder Mancozeb, maneb, metam, methasulphocarb, metiram, propineb, thiram, renaissance Zineb), ziram; - amino carboxylic acid vinegar: benthiavalicarb, diefhofencarb, flubenthiavalicarb, iprovalicarb , propamocarb, propanmoca hydrochloride, valiphenal and N-(l-(l-(4-cyanophenyl)ethanesulfonyl)butan-2- Aminocarbamic acid-(4-fluorophenyl) 139305.doc -51- 200948269 F) Other active substances selected from the group consisting of: - veins: guanidine, dodine, tannin, diterpene octylamine Guazatine), bis-octylamine acetate, iminoctadine, imipenem triacetate, iminoctadine-tris (albesilate); - Antibiotics: kasugamycin, spring lysine hydrochloride hydrate, streptomycin, polyoxin, validamycin A; - tribasic phenyl derivative : binapacryl, Dinobuton, dinocap, nitrthal-isopropyl, Tecnazen, organometallic compound: fentin salt, For example, triphenyltin acetate, triphenyltin hydrochloride or triphenyltin hydroxide; - sulfur-containing heterocyclic compounds: dithianon, isoprothiolane; - organic compound: granules Edifenphos), fosetyl, fosetyl-aluminum, propyl chelsson (i Probenfos), sub-acids and their salts, pyrazophos, tolclofos-methyl; - organochlorine compounds: chlorothalonil, dichlofluanid, digas Dichlorophen, Husulfamide, hexa-benzene, pencycuron, pentachlorphenole and its salts, phthalide, quintozene, thiophanate- Thiophanate-methyl, 139305.doc -52- 200948269 tolylfluanid, N-(4-chloro-2-stone phenyl)-N-ethyl-4-mercapto-benzenesulfonate Indoleamine; - Inorganic active substances: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur; - Others: biphenyl, bronopol, race Cyflufenamid, cymoxanil, diphenylamine, metrafenone, mildiomycin, oxin 0# oxin-copper, cyclamate I-pro salt (prohexadione calcium), spiroxamine, tolylfluanid, N- (ring Methoxymethoxyimido-(6-difluoro-indolyl-2,3-difluoro-phenyl)-methyl)-2-phenylacetamide, Ν·-(4-(4- Chloro-3-trifluoromethyl-phenoxy)-2,5-dimethyl-phenyl)-indole-ethyl-indole-methylformamidine, Ν'-(4-(4-gas_3) - bis-methyl-p-oxy)-2,5-dimethyl-phenyl)-indole-ethyl-indole-methylformamidine, Ν--(2-mercapto-5-trifluoromethyl 4-(3-tridecyloxyalkoxy-propoxy)-phenyl)-indole-ethyl-fluorenyl-mercaptomethylhydrazine and Ν'-(5-difluoroindol-2-yl)- 4-(3-Methyl succinyl-propyloxy)-phenyl)-indole-ethyl-hydrazine-- fluorenyl hydrazine. The following growth regulators which may be added to the formulations of the present invention are intended to illustrate possible combinations, but are not limited thereto: G) abscisic acid, amidochlor, ancymidol, 6-Benzylaminopurine. Brassinolide, brassinate, chlormequat, chloramphenicol, cyclanilide, daminozide , dikegulac, alpha statin 139305.doc -53- 200948269 (dimethipin), 2,6-dimethyl D ratio bite, ethephon, flumetralin, strontium '1 flurprimidol, fluthiacet, fluben forurfenon, gibberellic acid, inafenfide, 0 丨 朵 -3- acetic acid, maleic acid肼, Fluoride mefluidide, mepiquat (strong cottonseed hydrochloride), naphthaleneacetic acid, N-6-benzyl adenine, bucksin, cyclamate (calcium cyclate) , jasmonic acid propyl vinegar (prohydrojasmon), 0 thidiazuron (thidiazuron), bud bud (triapenthenol), tributyl trithiolate vinegar, 2,3,5-three-filled sulphuric acid, anti-pour vinegar (trinexapac-ethyl) and single health. The following herbicides which may be added to the formulations of the invention are intended to illustrate possible combinations, but are not intended to be limiting: H) herbicides such as glyphosate, sulfosate, sulfosin, qiqiju S Tefluthrin, terbufos, chlorpyrifos, chlorethoxyfos, tebupirimfos, phenoxyca.rb, diofenolan, Pymetrozine, imazethapyr, imazamox, imazapyr, imazapic or dimethenamid- P); The following insecticides which may be added to the formulations of the invention are intended to illustrate possible combinations, but are not intended to limit them: I) insecticides, such as fipronil, imidacloprid, Acetamiprid, nitenpyram, carbofuran, carbosulfan, benfuracarb, dinotefuran, ° (thiacloprid), the United States estimated 139305.doc -54- 200948269 (thiamethox Am), ci〇thianidin, diflubenzuron, flufenoxuron, teflubenzur〇n &amp; alpha-cypermethrin.

It will be understood in accordance with the invention that the administration of a formulation comprising a triazole and at least one other active substance means that at least one triazole and at least one other active substance may be present at the site of action at the same time as the fungicidal effective amount (ie, the harmful fungus to be controlled) Or its habitat 'eg infected plants, plant propagation material (especially seeds), surface, material or soil and plants, plant propagation materials (especially seeds), soil, surface, materials or habitats to be protected against fungi. This can be obtained by simultaneously (ie jointly (eg, in a barrel mixing) or separately) or continuously applying a formulation containing triterpenoids and at least one other active substance, and selecting the time interval between separate administrations in # It is ensured that the active substance applied is first present at the site of action in a sufficient amount when the other, 3⁄4 substance is applied. The order of administration is not critical to the practice of the invention. The formulations of the present invention may be prepared using components that are either partially or partially mixed with each other. It is also possible to further package and use the composition (e.g., a kit of parts) in the form of a combination. In one embodiment of the invention, the kits may comprise one or more (including all) components that can be used to prepare a target agrochemical composition. For example, the kit may comprise a red fungus component and/or an adjuvant component and/or a pesticide component and/or a raw and growing component and/or weeding sword. One or more components may have been combined in a mouth-up or pre-disposed. In the group of the two groups, the sounds of the two or more components are provided, and the components can be combined and packaged in a single text crying from the early 4 benefits, such as m, bottle 1 4 139305.doc •55· 200948269 Bag, bag or tube. In other embodiments, two or more components of the kit may be individually packaged', i.e., not pre-equipped. As such, the kit can include one or more:: a single container (e.g., a vial, can, bottle, pouch, bag, or canister), each of which has a separate component for the agrochemical composition. In either form, the components of the kit can be administered separately or together with the other components or as a component of the compositions of the present invention to prepare the formulations of the present invention. The car 乂 者 亦 包括 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及Formulations of active substances of West Stable, Parac, and Trichostatin. The car 乂 者 is also included, including three d sitting and at least one selected from the group B) methotrexate and especially selected from cyclosporin, genita, high-efficiency arsenic, oufusi, dimethyl Formulation of active substances of a groom, flu〇pic〇Hd, pic〇benzamid, zoxamide, carbopamer and dipropargylamine. The cultivar includes a diazole and at least one selected from the group consisting of azoles of the group c) and especially selected from the group consisting of shanghai, shanghai, sulphur, fluoroquine, fluoxazole, flufenazole, Maidinidin, panconazole, propiconazole, thiopyrazole, a 』, 析, 泰泰隆, 得克利, 四克利, triteconazole, prochloraz, 赛米法,免赖得, Formulation of active substances of carbendazim and escarpone. Preferably, it also comprises a triazole and at least one heterocyclic compound selected from the group consisting of D) and especially 7 is selected from the group consisting of chlorpromazine, cyprodinil, fenrimyl, mipanibine, and biley&quot; , Sai Fanning, fluorodioxin, carbendazim, butyl benzene #, thirteen? 139305.doc 200948269 porphyrin, benzene rust, yiputong, kekening, ubiquitin ##] sub-nano, Formulations of active substances of allyl benzothiazole, puquinaz, azizazole-s_ τ, dexamethasone, fluphene phenoxy and quinoxacillin. Preferably, it also includes three wows and at least one selected from the group consisting of arginine formic acid vinegar and especially selected from the group consisting of pulverized powder, free of rot, methyl zinc is xiao, der der der, cumfafalka, flubensef Formulation of active substances of Lika and Ppanmoka. ❹

Preferably, it also comprises trisal and at least one fungicide selected from the group consisting of F) and is especially selected from the group consisting of nitrile sulphur, triphenyltin (for example, triphenyl hexaacetate), forsyth, and blessing.赛得绍, h3P〇3 and its salts, tetrachloroisophthalonitrile, Yifaling, thiophanate-methyl, copper acetate, hydrogenated L-rolled copper, oxygenated copper, copper sulfate, sulfur, and simian , mechafenlone, snail amine and 5_gas_7*methylhexahydro end!-yl)-6-(2,4,6-trifluoroindolyl 1,2,4]_trimist[ Ma] formulation of active substance for squeezing. Triazole in such formulations of the invention including active substances of the three species and other active substances (for example, a group from A) to I) The weight ratio to the second active substance is usually in the range of 1:1 〇〇 1 〇〇: 1 often in the range of uo-soa, preferably in the range of 1:2 〇 2 〇: 1 and especially in coffee 1 〇: 1 range. In such a formulation of the invention comprising a diazole and a first other active substance (component 2) and a second direct active substance (component paste, such as two active substances from the A_ group), The weight ratio of the trisal to the second active substance is preferably in the range of 1:5 〇 -5 〇:1 and especially in the range of Η·], and the weight ratio of the triazole to the third active substance is preferably 1 : 5 〇 _ 5 〇: 1 range and especially in the range of 1:10-10:1. 139305.doc -57- 200948269 The following examples illustrate the invention 'but are not to be considered as limiting. 1. Preparation Examples Examples F-1 to F-3 were prepared by preparing a solvent mixture and adding industrial grade oxiconazole under heating and agitation. When the oxiconazole is completely dissolved to form a clear solution, an emulsifier is added and mixed until a clear EC is obtained. A comparative example of F-0 SC (suspension concentrate) formulation. Table 1: Preparation Example F-0 Name Amount % - Review / Comment Active Ingredient Epoxy Condene 15 Dispersant 1 Pluoronic® PE 10500 3 Wetting Agent Naphthalene Sulfonic Acid Formaldehyde Condensate, Na Salt 4 Thickener Xanthan Gum 2 Antifreeze propylene glycol 2 defoamer is typically based on the dream depilation agent 'Silfoam type 0,5 from Wacker preservative substituted isothiazolin-3-class 0,2 solvent water 73,8 F-1 %-w/w active ingredient oxiconazole 12,5 emulsifier 1 triptycyl phenol ethoxylate 16 EO 8 emulsifier 2 Ca, dodecyl benzo sulfonate 8 polymer emulsifier MMA-total -AMPS-co-LA (45:15:40) 6,5 Solvent phenylhydrin 25 Solvent o-butylphenol 20 Solvent Solvesso 200 20 F-2 Name i%_w/w Active ingredient Epoxyconazole 6 Emulsifier 1 Trisinyl vinyl phenol ethoxylate 16 EO 15 139305.doc • 58 · 200948269 Emulsifier 2 Na, 7 Dodecyl benzosulfonate adjuvant Plurafac LF 300® 8 Polymer emulsifier Stat. VP -Vac (60:40) 7 Solvent Benzyl Benzoate 22 Solvent o-Secondylphenol 25 Solvent Solvesso 200 10 F-3 Name Active Ingredients Oxygen 8 emulsifier 1 tristyryl phenol ethoxylate 16 EO 9 emulsifier 2 Na, dodecyl benzosulfonate 8 polymer emulsifier Stat. VP-Vac (60:40) 7 solvent benzene Methanol 22 Solvent o-Secondylphenol 12 Solvent Solvesso 200 41 Use example F-0 to F-3: Treatment against wheat leaf smut on wheat (Pwcckz_&lt;3 reco«Mountain 7fl) (wheat brown disease) The spore suspension of wheat brown rust (wheat leaf rust) was applied to the potted wheat seedling leaves of the cultivar "Kanzler". The plants were then placed in a chamber with high air humidity (90-95%) at 20-22 ° C for 24 hours. During this time, the spores germinate and the germinating tubes penetrate into the leaf tissue. On the second day, the infected plants were sprayed to the runoff point with a formulation having the following concentration of active substance. After the spray formulation has dried, the test plants are returned to the greenhouse and incubated for a further 7 days at a temperature between 20 and 22 ° C and a relative humidity of 65-70%. The degree of development of rust on the leaves was then visually observed. In this test, plants treated with EC formulations showed much lower infections than plants treated with SC formulations or untreated plants (Table 2). 139305.doc -59- 200948269 Table 2: Examples of biological examples Active ingredient concentration (g/L) Concentration [ppm] Bonitur Mean K-1 0 0 85 K-3 0 100 80 F-0 125 50 50 25 67 12,5 83 F-1 125 50 3 25 27 12,5 65 F-2 62,5 50 0 25 0 12,5 8 F-3 83 64 0 32 4 16 32 139305.doc 60-

Claims (1)

200948269 VII. Scope of application: 1. An emulsifiable concentrate (EC) formulation comprising a) fungicidal triketone or an agriculturally acceptable salt or adduct thereof, b) a solvent system comprising b 1 Substituted phenol b2) - or a plurality of organic solvents c) one or more emulsifiers, d) other formulation additives as appropriate. 2. The EC of claim 1, wherein the trisal is selected from the group consisting of: azaconazole, bitertanol, bromuconazole, and cycloconazole beta ( Cyproconazole), cifenoconazole, diniconazole, diniconazole-M, ep0XiC0naz0le, fenbuconazole, flubenzol Squat (flUqUinconazole), flusilazole, flutriafol, hexacon &quot;hexaconazole, imibenconazole, ipconazole, sputum sputum Metconazole), myclobutanil, oxpoconazole, paclobutrazole, pankang sputum, sulphur beta, spleen, penconazole, propiconazole , (prothioconazole), simeconazole (tebuconazole), tetraconazole, diconazole, triadimefon, triadimenol (triticonazole), singular saliva (uniconazole), ([1,2,4]three&lt;»sitting-1-base)-ring Alcohol. 139305.doc 200948269 3. The EC of claim 2, wherein the three saliva is loyal, is selected from the group consisting of: epoxiconazole, fluoroquinazole, inoculum carbazole, propiconazole , acesulfame, dexamethasone and triteconazole. 4. The EC of claim 3, wherein the three saliva is ketamine. Sit. 5. If pleading for any of items 1 to 4, ep , Gan, which includes one or more other crop protection agents. 6. The EC of claim 5, wherein the other crop protection agents are selected from the group consisting of the lower jaw J. Dimeth〇m〇rph ), butyl morpholine (Pr〇PimorPh), tridemorph, fenpropidin, prochi〇raz, kresoxim-methyl, ousha orySastr〇bin 'metconazole, pyrac〇 str〇bin, boscalid and metrafenone. 7. The EC of any one of claims 1 to 4, which consists essentially of the following components: a) 0.1 to 30% by weight of the triazole, b) 6 to 97% by weight of the solvent system, Included is bl) the substituted phenol, b2) one or more organic solvents, c) from 2 to 20% by weight of one or more emulsifiers, and d) from 0 to 52°/. Other formulation additives. 8. The EC of any one of claims 1 to 4, wherein the solvent system comprises phenol··R1—0-X as a component (bl), 139305.doc 200948269 wherein R1 is 1 to 3 a C^-Cu-alkyl substituted phenyl group and X is hydrogen, an alkali metal, an alkaline earth metal or NR3, wherein each R is the same or different and is a hydrazine or, optionally, a hydroxy group substituted iC^-Cs-alkyl. 9. The EC of claim 8, wherein the phenol is selected from the group consisting of: ^ 2,3,6-trimethylphenol, p-tert-butylphenol, o-dibutylphenol, 2- Third butyl phenol, p-third amyl phenol, heptyl derivative (p-heptyl phenol), p-t-octyl phenol, p-octyl phenol, 2,4-di-t-butyl Phenol, 2,6-di-tert-butylphenol, p-(α,α-dimethylbenzyl)phenol, p-nonylphenol, 2,4-di-p-pentylphenol, p-ten Dialkylphenol, 4-second butyl-2,6-di-t-butylphenol, 2,4,6-tri-tert-butylphenol, and 2,4_bis (〇1,〇1_ Di-based benzyl) phenol. 10. The EC of claim 9 wherein the phenol is o-second butyl phenol. The EC of any one of claims 1 to 4, wherein the solvent system comprises an aromatic hydrocarbon as the organic solvent component (b2). 12. The EC of any one of clauses 4 to 4 wherein the emulsifier component (c) comprises ❹ at least one polymeric emulsifier. 13. The EC of any one of clauses 4 to 4 wherein the emulsifier component (c) comprises at least one water soluble polymeric emulsifier. The EC of any one of items 1 to 4, wherein the emulsifier component (c) comprises at least one anionic polymerization emulsifier. The emulsifier component of the emulsifier component comprises at least two emulsifiers, as claimed in any one of claims 1 to 4. 16. A method of preparing EC, comprising the steps of: if appropriate, mixing and/or heating, such as a request item! Component a, 139305.doc 200948269 17. b, c and optionally d as defined in any of i. One of the claims 1 to 15 - for controlling harmful fungi. The use of EC as defined in the item is a method for controlling harmful fungi, and the method comprises the following steps: dilution as in any of claims 1 to 15 EC, and apply it directly or indirectly to §H. harmful fungi, 1 iL lit. a? /^L· I is a biologically-bred or plant, bandit or seed that is intended to protect against fungal attack. 139305.doc 200948269 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: Φ 5. If there is a chemical formula in this case, please reveal the best display invention. Chemical formula of the feature: (none) 139305.doc