CN101995596A - Exposed glass bead reflecting film capable of reflecting colored light and manufacturing method thereof - Google Patents
Exposed glass bead reflecting film capable of reflecting colored light and manufacturing method thereof Download PDFInfo
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- CN101995596A CN101995596A CN2010102954868A CN201010295486A CN101995596A CN 101995596 A CN101995596 A CN 101995596A CN 2010102954868 A CN2010102954868 A CN 2010102954868A CN 201010295486 A CN201010295486 A CN 201010295486A CN 101995596 A CN101995596 A CN 101995596A
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Abstract
The invention discloses an exposed glass bead reflecting film capable of reflecting colored light and a manufacturing method thereof. The exposed glass bead reflecting film comprises a base material, a reflecting layer, a transparent color layer and a plurality of glass bead convex lenses; the reflecting layer and the transparent color layer are arranged on the base material in turn; the plurality of glass bead convex lenses are planted on the transparent color layer through a transparent adhesive layer; each glass bead convex lens penetrates the transparent adhesive layer and is in point contact with the upper plane of the transparent color layer; and a laser pattern can be pressed on the transparent color layer according to requirements. The manufacturing method for the reflecting material comprises a reflecting layer direct plating method and a reflecting layer reverse adhesion method. Compared with the conventional exposed reflecting material, when applied to a night reflecting device, the exposed glass bead reflecting film can reflect the colored light, also has the laser effect, and has positive effects of reducing accidents at night, improving night work management and beautifying some wearing products and daily products.
Description
Technical field
The present invention discloses a kind of exposed type glass microbead reflecting film and method for making, belong to glass microballoon reflectorized material manufacturing technology field by International Patent Classification (IPC) (IPC) division, when reflective membrane of the present invention can make white light incident and what reflect is the various color of light that set, can be widely used in fields such as umbrella, parasols, footwear, case and bag or clothes.
Background technology
Glass microballoon is a kind of of many uses, a kind of new material that performance is special that development in recent years is got up, and the night that can be applicable to reflective and traffic mark board at night of zebra stripes, stop forbidden line, double amber lines of urban traffic road is in the reflex reflector.
The reflective membrane made from glass microballoon and resin, except being widely used in all kinds of traffic signs, outside road markings, License Plate, bridge tunnel entrance and mark, sea rescue apparatus reflective marker, navigation mark, airport roadway annunciator etc., also can be used to make colour printed reflective fabric, be used to make the night work persons' of department such as mine, fire-fighting, environmental sanitation, municipal administration working cloth, for example reflective clothes and reflective cap, shoes, bag, armband, umbrella or the like.General exposed type glass microballoon reflectorized material, owing to its glass microballoon is to be that the made glass of high refractive index of main material is made with titania and baryta, so being acknowledged as its reflection photochromic is white light, its reflection in other words is photochromic to be photochromic and determine by incident, be that incident light is white, its reflected light white, incident light are that the reflected light of red it is red.
As Fig. 1 is a kind of common reflectorized material structural representation, be coated with its base material of reflecting body D A on the glass microballoon C of this reflectorized material and gone up and to be combined as a whole by the glass microballoon C on tack coat (resin) B and the base material, this reflectorized material can only reflected white-light or the light consistent with incident light; Fig. 2 is a kind of common reflection
The color reflective material structure synoptic diagram of white light; What they were different with Fig. 1 structure is that tack coat (resin) B ' adds reflecting material and pigment, but this reflectorized material still can not reflect color light.The reflectorized material of two kinds of structures among Fig. 1 and Fig. 2, tack coat (resin) B, B ' all have reflection function, each glass microballoon all is to be embedded in the tack coat (resin), and nearly half sphere of glass microballoon is embedded in the tack coat (resin), but because glass microballoon is to be the high-index material of principal ingredient by titania and baryta, itself have bigger reflection potential, the light of its reflection is determined by incident light, so white light incident, its reflected light also are white.
Summary of the invention
Deficiency at existing reflectorized material reflection technology, the invention provides a kind of rational in infrastructure, exposed type glass microbead reflecting film that can reflect color light, be applied to night during reflex reflector, when incident light is that white light can reflect colored light by this reflective membrane, more can effectively warn the related personnel, further reduce the accident at night, thereby improve the management of working at night.
Simultaneously, the present invention also provides two kinds of methods that prepare above-mentioned reflective membrane.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of exposed type glass microbead reflecting film of energy reflect color light, comprise base material, the reflection horizon, transparent color layers and some glass microballoon convex lens, be provided with reflection horizon and transparent color layers on the base material successively, plant some glass microballoon convex lens by transparent bonding layer on the transparent color layers, and each glass microballoon convex lens partial penetration is in transparent bonding layer and with the last plane of transparent color layers and contacts, incident light arrives the reflection horizon by glass microballoon convex lens and transparent color layers and focuses on reflectively, and reflected light sees through transparent color layers and glass microballoon convex lens again and makes it to form and enter the coloured reflective of vision; Other other light of incident light source see through transparent bonding layer, the color layers between the glass microballoon convex lens and form diffuse reflection in the reflection horizon and hint obliquely at the visually comprehensive color reflective of formation under glass microballoon convex lens and the acting in conjunction at its focus reflection simultaneously.
Further, the thickness of transparent color layers and transparent bonding layer is subjected to the restriction of glass microballoon refractive index, the glass microballoon refraction is high, this two layer thickness is just thin, otherwise these two layers just thick, will guarantee that in a word incident light sees through this convex lens of glass microballoon and adds transparent color layers and transparent bonding layer and arrive the reflection horizon and just in time form focus point.According to calculating and the practical operation experience, the thickness of transparent color layers and transparent bonding layer superimposed layer to make it to guarantee it between glass microballoon sphere bottom and reflection horizon at 2um-6um, and the refractive index of glass microballoon is between 1.90-1.93.
Further, the transparent bonding layer between the described adjacent glass microballoon convex lens is the plane of equal thickness, and its refractive index is between 1.45-1.55.
Further, described transparent color layers is processed into a plane layer by the pigment of transparent resin and Qi Nei, also can press radium-shine line in the above as required, and pigment or dyestuff are necessary for transparent type, pigment is vapour crust or Ao Lisha dyestuff, and transparent resin is acrylic acid resin or Pu resin.
Further, described transparent bonding layer can also be transparent color tack coat, and then catoptrical color is the stack of transparent color layers and two kinds of colors of transparent color tack coat.
Further, described transparent bonding layer is acrylic acid resin or Pu resin.
A kind of method for making of exposed type glass microbead reflecting film of energy reflect color light, this method is the anti-method of pasting in reflection horizon, its step is as follows:
One), PET or other material films are coated abscission layer earlier and be made as auxiliary film;
Two), do transparent color layers on the abscission layer surface of auxiliary film, its way can be direct coating or printing;
Three), on above-mentioned transparent color layers surface, aluminize and be processed to form the reflection horizon;
Four), in step 3) in the reflection horizon be one by bonding agent and base material, and peel off auxiliary film;
Five), peel off the bonding face of its transparent color layers after the auxiliary film by transparent bonding layer and plant the upper glass microballon and it is contacted with transparent color layers surface point be processed as finished product.
In addition, a kind of method for making of exposed type glass microbead reflecting film of energy reflect color light, this method is that method is directly plated in the reflection horizon, its step is as follows:
One), base material is coated resin or additive method make it surfacing so that the plating reflection horizon;
Two), the machined surface at base material plates the reflection horizon;
Three), do the transparent pigment layer on the surface, reflection horizon;
Four), planting the upper glass microballon at the transparent pigment layer by transparent bonding layer makes it contact with transparent color layers surface point to be processed as finished product.
Further, described transparent color layers is processed into a plane layer by the pigment of transparent resin and Qi Nei, and pigment is vapour crust or Ao Lisha dyestuff, and transparent resin is acrylic acid resin or Pu resin.
Further, also can press on the described transparent pigment layer and be provided with laser pattern, transparent bonding layer adds pigment and forms transparent color tack coat, then catoptrical color is the stack of transparent color layers and two kinds of colors of transparent color tack coat, the thickness of transparent color layers and transparent bonding layer superimposed layer to make it to guarantee it between glass microballoon sphere bottom and reflection horizon at 2um-6um, change according to the particle diameter and the variations in refractive index of glass microballoon.
Reflectance mechanism of the present invention is as follows: the incident white light sees through transparent color layers variable color focusing by glass microballoon and makes it focus point also reflection on metallic reflector, and institute's reflected light makes it to coloured by transparent color layers; Other diffused lights of incident light source arrive transparent color layers through the transparent bonding layer between the glass microballoon simultaneously, a plane and refractive index are about 1.5 because it is, do not focus on the only mutual diffusion of meeting so can not form, color light is hinted obliquely at the glass microballoon convex lens mutually, and the layer of transparent color layers is arranged before its reflection horizon, white light sees through transparent color layers and arrives the reflection horizon, form diffuse reflection by the reflection horizon after the variable color, its reflected light again by transparent color layers under the two acting in conjunction, the reflected light that makes the glass microballoon convex lens is colored comprehensively from visually forming.
The present invention compares with existing reflectorized material, is applied to night during reflex reflector, because can reflect color light, for reducing the accident at night, improves the management of working at night, and the raising efficient of working at night all plays a part very important.
Description of drawings
Fig. 1 is a kind of existing reflectorized material structural representation;
Fig. 2 is the color reflective material structure synoptic diagram of existing another kind of reflected white-light;
Fig. 3 is a structural representation of the present invention;
Fig. 4 is a reflectance mechanism synoptic diagram of the present invention.
Embodiment
The invention will be further described below in conjunction with accompanying drawing:
Embodiment: see also Fig. 3, a kind of exposed type glass microbead reflecting film of energy reflect color light, comprise base material 1, reflection horizon 2, transparent color layers 3 and some glass microballoon convex lens 4, be provided with reflection horizon 2 and transparent color layers 3 on the base material 1 successively, also can on transparent color layers, press the radium pigment figure as required, plant some glass microballoon convex lens 4 by transparent bonding layer 5 on the transparent color layers 3, and each glass microballoon convex lens 4 penetrates to be in transparent bonding layer 5 and with the last plane of transparent color layers 3 and contacts.
Among the present invention, the refractive index of glass microballoon convex lens 4 is between 1.90-1.93.Transparent bonding layer 5 between the adjacent glass microballoon convex lens 4 is the plane of equal thickness, and its refractive index is between 1.45-1.55.Transparent color layers 3 is processed into a plane layer by the pigment of transparent resin and Qi Nei, pigment or dyestuff are transparent type, transparent resin is acrylic acid resin or Pu resin and alkyd resin, transparent bonding layer 5 is acrylic acid resin or Pu resin and alkyd resin, transparent color layers 3 also has the effect of focusing, makes the focus through glass microballoon convex lens incident light focus on the reflection horizon and reflection.Being superimposed upon between the 2um-6um of transparent color layers and transparent bonding layer thickness.
A kind of method for making of exposed type glass microbead reflecting film of energy reflect color light, this method is the anti-method of pasting in reflection horizon, its step is as follows:
One), PET or other material films are coated abscission layer earlier and be made as auxiliary film;
Two), do transparent color layers on the abscission layer surface of auxiliary film, its way can be direct coating or printing;
Three), on above-mentioned transparent color layers surface, aluminize and be processed to form the reflection horizon;
Four), in step 3) in the reflection horizon be one by bonding agent and base material, and peel off auxiliary film;
Five), peel off the bonding face of its transparent color layers after the auxiliary film by transparent bonding layer and plant upper glass microballon system and be processed as finished product.
In addition, a kind of method for making of exposed type glass microbead reflecting film of energy reflect color light, this method is that method is directly plated in the reflection horizon, its step is as follows:
One), base material is coated resin or additive method make it surfacing so that the plating reflection horizon;
Two), the machined surface at base material plates the reflection horizon;
Three), do the transparent pigment layer, can print, directly be coated with or be coated on the release film and instead paste on the surface, reflection horizon;
Four), plant the upper glass microballon by transparent bonding layer and be processed as finished product at the transparent pigment layer.
Color is determined by transparent color layers in above-mentioned two kinds of methods; Require refractive index between 1.90-1.93 to glass microballoon, transparent color layers and transparent bonding layer there is no specific (special) requirements, and acrylic acid resin binder or Pu resin binder on the open market can both meet the demands.Color layers pigment or dyestuff are necessary for transparent type.
Contrast is seen as Fig. 1, Fig. 2 and Fig. 3, can reflect color light and the maximum difference of structure that can not reflect color light be: its reflection horizon that can not reflect color light is directly at sphere and nearly half sphere of glass microballoon; Just can reach and to be glass microballoon see through the layer of transparent color layers in its reflection horizon that can reflect color light, and the reflection horizon not half sphere of parcel, just touch a point on glass microballoon sphere summit.
A kind of exposed type glass microballoon reflectorized material of energy reflect color light comprises base material, reflection horizon, transparent color layers, also can press laser pattern on transparent color layers as required.Be provided with reflection horizon and transparent color layers on the base material successively, transparent color layers is planted some glass microballoon convex lens by transparent bonding layer, and each glass microballoon convex lens is through transparent bonding layer and with the last plane of transparent color layers and contacts.Its base material can suitably be selected according to purposes, as on the umbrella with selecting the terylene chemical fabric, make footwear with can selecting various leather substances, on clothes, the case and bag with selecting various fabric cloths.The thickness of transparent color layers and transparent bonding layer is subjected to the restriction of glass microballoon refractive index, glass microballoon refractive index height, particle diameter is little, this two layer thickness is just thin, otherwise these two layers just thick, will guarantee that in a word incident light sees through this convex lens of glass microballoon and adds transparent color layers and transparent bonding layer and arrive the reflection horizon and just in time form focus point.According to calculating and the practical operation experience, the thickness of transparent color layers and transparent bonding layer superimposed layer to make it to guarantee it between glass microballoon sphere bottom and reflection horizon at 2um-6um, and the refractive index of glass microballoon is between 1.90-1.93.If transparent bonding layer is made transparent color tack coat, then its catoptrical color is the stack of transparent color layers and two kinds of colors of transparent color tack coat.
Among the present invention, transparent color layers stack transparent bonding layer thickness between glass microballoon sphere bottom and reflection horizon and thickness at 2um-6um.
The present invention discloses a kind of exposed type glass microballoon reflectorized material and method for making, comprise base material, reflection horizon, transparent color layers and some glass microballoon convex lens, be provided with reflection horizon and transparent color layers on the base material successively, also can on transparent color layers, press laser pattern as required.Plant some glass microballoon convex lens by transparent bonding layer on the transparent color layers, and each glass microballoon convex lens is through transparent bonding layer and with the last plane of transparent color layers and contacts.The method for making of this reflectorized material has the reflection horizon directly to plate the anti-method of pasting of method and reflection horizon, incident white light of the present invention is reflected into white light by glass microballoon, and the incident white light of process transparent bonding layer is because its refractive index is about 1.5, diffusion mutually, the color of transparent color layers is hinted obliquely at the glass microballoon convex lens mutually, and the layer of transparent color layers is arranged before its reflection horizon, white light becomes focus to form reflection after arriving the reflection horizon variable color by transparent color layers, its reflected light sees through transparent color layers again, under the two effect, make the reflected light of glass microballoon convex lens colored comprehensively from visually forming.The present invention compares with existing exposure reflectorized material, be applied to night during reflex reflector, because can reflect color light, and also laser effect can be arranged, for reducing the accident at night, improve the management and beautify some and wear articles for use and articles for daily use all play a part positive of working at night.
The above record only for utilizing the embodiment of this origination techniques content, anyly is familiar with modification, the variation that this skill person uses this creation to do, and all belongs to the claim of this creation opinion, and is not limited to those disclosed embodiments.
Claims (10)
1. the exposed type glass microbead reflecting film of an energy reflect color light is characterized in that: comprise base material, reflection horizon, transparent color layers and some glass microballoon convex lens, wherein:
Base material is provided with reflection horizon and transparent color layers successively on it, plant some glass microballoon convex lens by transparent bonding layer on the transparent color layers, and each glass microballoon convex lens partial penetration is in transparent bonding layer and with the last plane of transparent color layers and contacts;
Incident light arrives the reflection horizon by glass microballoon convex lens and transparent color layers and focuses on reflectively, and reflected light sees through transparent color layers and glass microballoon convex lens again and makes it to form and enter the coloured reflective of vision; Other other light of incident light source see through transparent bonding layer, the color layers between the glass microballoon convex lens and form diffuse reflection in the reflection horizon and hint obliquely at the visually comprehensive color reflective of formation under glass microballoon convex lens and the acting in conjunction at its focus reflection simultaneously.
2. the exposed type glass microbead reflecting film of energy reflect color light according to claim 1, it is characterized in that: the refractive index of described glass microballoon convex lens is between 1.90-1.93.
3. the exposed type glass microbead reflecting film of energy reflect color light according to claim 1, it is characterized in that: the transparent bonding layer between the described adjacent glass microballoon convex lens is the plane of equal thickness, and its refractive index is between 1.45-1.55.
4. the exposed type glass microbead reflecting film of energy reflect color light according to claim 1, it is characterized in that: described transparent color layers is processed into a plane layer by the pigment of transparent resin and Qi Nei, also can press radium-shine line in the above as required, pigment or dyestuff are necessary for transparent type, pigment is vapour crust or Ao Lisha dyestuff, and transparent resin is acrylic acid resin or Pu resin.
5. the exposed type glass microbead reflecting film of energy reflect color light according to claim 1, it is characterized in that: described transparent bonding layer can also be transparent color tack coat, and then catoptrical color is the stack of transparent color layers and two kinds of colors of transparent color tack coat.
6. the exposed type glass microbead reflecting film of energy reflect color light according to claim 1, it is characterized in that: described transparent bonding layer is acrylic acid resin or Pu resin.
7. the method for making of the exposed type glass microbead reflecting film of an energy reflect color light, this method is the anti-method of pasting in reflection horizon, its step is as follows:
One), PET or other material films are coated abscission layer earlier and be made as auxiliary film;
Two), do transparent color layers on the abscission layer surface of auxiliary film, its way can be direct coating or printing;
Three), on above-mentioned transparent color layers surface, aluminize and be processed to form the reflection horizon;
Four), in step 3) in the reflection horizon be one by bonding agent and base material, and peel off auxiliary film;
Five), peel off the bonding face of its transparent color layers after the auxiliary film by transparent bonding layer and plant the upper glass microballon and it is contacted with transparent color layers surface point be processed as finished product.
8. the method for making of the exposed type glass microbead reflecting film of an energy reflect color light, this method is that method is directly plated in the reflection horizon, its step is as follows:
One), base material is coated resin or additive method make it surfacing so that the plating reflection horizon;
Two), the machined surface at base material plates the reflection horizon;
Three), do the transparent pigment layer on the surface, reflection horizon;
Four), planting the upper glass microballon at the transparent pigment layer by transparent bonding layer makes it contact with transparent color layers surface point to be processed as finished product.
9. according to the method for making of claim 7 or 8 described exposed type glass microbead reflecting films that can reflect color light, it is characterized in that: described transparent color layers is processed into a plane layer by the pigment of transparent resin and Qi Nei, pigment is vapour crust or Ao Lisha dyestuff, and transparent resin is acrylic acid resin or Pu resin.
10. according to the method for making of claim 7 or 8 described exposed type glass microbead reflecting films that can reflect color light, it is characterized in that: also press on the described transparent pigment layer to be provided with laser pattern, transparent bonding layer adds pigment and forms transparent color tack coat, then catoptrical color is the stack of transparent color layers and two kinds of colors of transparent color tack coat, the thickness of transparent color layers and transparent bonding layer superimposed layer to make it to guarantee it between glass microballoon sphere bottom and reflection horizon at 2um-6um.
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| CN201010295486.8A CN101995596B (en) | 2010-09-25 | 2010-09-25 | Exposed glass bead reflecting film capable of reflecting colored light and manufacturing method thereof |
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| CN201310399038.6A Division CN103424793B (en) | 2010-09-25 | 2010-09-25 | Manufacturing method of exposure glass micro-sphere reflective membrane capable of reflecting colorful light |
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| CN102998727A (en) * | 2012-11-07 | 2013-03-27 | 苏州萃智新技术开发有限公司 | High-weather-resistance household washing permanent-color high-strength reflecting material with TC (terylene cotton) fabric as base |
| CN103884688A (en) * | 2014-02-28 | 2014-06-25 | 成都中节能反光材料有限公司 | Method for inspecting inverse reflection factors of glass beads |
| CN105717565A (en) * | 2016-04-28 | 2016-06-29 | 福建新力元反光材料有限公司 | Production method for glass microsphere light reflecting product reflecting colour lights |
| CN106084868A (en) * | 2016-06-14 | 2016-11-09 | 江苏联创人造草坪股份有限公司 | A kind of reflective type chinampa |
| CN108673985A (en) * | 2018-06-14 | 2018-10-19 | 广东昂斯新材料技术有限公司 | A kind of color reflective material and preparation method thereof that band is textured |
| CN108919396A (en) * | 2018-08-24 | 2018-11-30 | 福建夜光达科技股份有限公司 | A kind of changeable reflective fabric of phantom and preparation method thereof |
| CN109973932A (en) * | 2017-12-15 | 2019-07-05 | 株式会社小糸制作所 | Resin molding part and vehicle part |
| CN112859221A (en) * | 2021-01-18 | 2021-05-28 | 合肥市辉耀真空材料有限责任公司 | Vacuum coating reflective product and preparation process thereof |
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| DE202015102692U1 (en) * | 2015-05-26 | 2015-06-23 | Büchel GmbH & Co. Fahrzeugteilefabrik KG | Light-reflecting spoke clip |
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Denomination of invention: Exposed glass bead reflecting film capable of reflecting colored light and manufacturing method thereof Effective date of registration: 20181031 Granted publication date: 20140101 Pledgee: Industrial Bank, Limited by Share Ltd, Jinjiang branch Pledgor: Jinjiang City Yeshiming Reflecting Material Co., Ltd. Registration number: 2018990001009 |