CN101995596A - Exposed glass bead reflecting film capable of reflecting colored light and manufacturing method thereof - Google Patents

Exposed glass bead reflecting film capable of reflecting colored light and manufacturing method thereof Download PDF

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CN101995596A
CN101995596A CN2010102954868A CN201010295486A CN101995596A CN 101995596 A CN101995596 A CN 101995596A CN 2010102954868 A CN2010102954868 A CN 2010102954868A CN 201010295486 A CN201010295486 A CN 201010295486A CN 101995596 A CN101995596 A CN 101995596A
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layer
transparent
color
reflective
glass beads
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CN2010102954868A
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CN101995596B (en
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陆楞渊
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晋江市夜视明反光材料有限公司
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Abstract

The invention discloses an exposed glass bead reflecting film capable of reflecting colored light and a manufacturing method thereof. The exposed glass bead reflecting film comprises a base material, a reflecting layer, a transparent color layer and a plurality of glass bead convex lenses; the reflecting layer and the transparent color layer are arranged on the base material in turn; the plurality of glass bead convex lenses are planted on the transparent color layer through a transparent adhesive layer; each glass bead convex lens penetrates the transparent adhesive layer and is in point contact with the upper plane of the transparent color layer; and a laser pattern can be pressed on the transparent color layer according to requirements. The manufacturing method for the reflecting material comprises a reflecting layer direct plating method and a reflecting layer reverse adhesion method. Compared with the conventional exposed reflecting material, when applied to a night reflecting device, the exposed glass bead reflecting film can reflect the colored light, also has the laser effect, and has positive effects of reducing accidents at night, improving night work management and beautifying some wearing products and daily products.

Description

能反射彩色光的暴露型玻璃微珠反光膜及制作方法 Light color capable of reflecting glass beads is exposed reflective film fabrication method

技术领域 FIELD

[0001] 本发明公开一种暴露型玻璃微珠反光膜及制作方法,按国际专利分类表(IPC)划分属于玻璃微珠反光材料制造技术领域,本发明反光膜可以使白光入射时而反射的是各种所设定的颜色光,可广泛应用于雨伞、遮阳伞、鞋、箱包或服装等领域。 [0001] The present invention discloses a type of glass beads exposed reflective film fabrication method, according to the international patent classification (IPC) belongs to divided glass bead reflective material manufacturing technical field, reflective film of the present invention can sometimes incident white light is reflected set the various colors of light can be widely used in umbrellas, parasols, shoes, bags, or other apparel.

背景技术 Background technique

[0002] 玻璃微珠,是近年来发展起来的一种用途广泛、性能特殊的一种新型材料,可应用于城市交通道路的斑马线、禁停线、双黄线的夜间反光、和交通标志牌的夜间反光装置中。 [0002] glass beads, is a versatile developed in recent years, the special properties of a new material can be used in the zebra crossing, no-parking lines of urban roads, night-reflective double yellow lines, and traffic signs the night reflective device.

[0003] 用玻璃微珠和树脂制成的反光膜,除了广泛应用于各类交通标志,如道路标识、汽车号牌、桥梁隧道入口标志、海上救生用具反光标记、航标、机场道路信号牌等外,还可用来制成彩色印花反光织物,用于制作矿山、消防、环卫、市政等部门夜间作业者的工作服,例如反光服和反光的帽子、鞋子、包、袖章、伞等等。 [0003] reflective film with glass beads and resin, in addition to widely used in all kinds of traffic signs, such as road signs, car number plate, entrance sign bridges, tunnels, marine life preservers reflective markers, beacons, airports, road signals, such as licensing in addition, color printing may also be used to form reflective fabric, making clothes for mining, fire, sanitation, municipal departments who work at night, such retroreflective reflective clothing and hats, shoes, bags, armbands, like an umbrella. 一般暴露型玻璃微珠反光材料,由于其玻璃微珠是用二氧化钛和氧化钡为主材所制的高折射率玻璃而制成,所以被公认为它的反射光色是白光,或者说它的反射光色是由入射光色而决定,即入射光是白色的,它的反射光就是白色的,入射光是红色的它的反射光就是红色的。 Usually reflective material exposed glass beads, glass beads is mainly due to its high refractive index glass material is made of barium oxide and titanium dioxide is made, so that it is recognized as reflected light color is white, or that it color of reflected light is determined by the color of the incident light, the incident light is white i.e., it reflected light is white, red incident light is reflected light it is red.

[0004] 如图1是一种普通反光材料结构示意图,该反光材料的玻璃微珠C上涂了一个反射体D其基材A上通过粘结层(树脂)B与基材上的玻璃微珠C结合为一体,该反光材料只能反射白光或与入射光一致的光;图2是一种普通反射 [0004] FIG. 1 is a schematic view of a conventional reflective material structure coated with a reflector on the glass microspheres D and the substrate by the adhesive layer B (resin) on a substrate A on which the glass beads reflective material C C beads combined into one, the reflective material can reflect white light or light incident consistent; FIG. 2 is a common reflection

[0005] 白光的彩色反光材料结构示意图;其与图1结构不同的是粘结层(树脂)B'添加反射材料和颜料,但该反光材料仍然不能反射彩色光。 [0005] Materials schematic structural white color reflective; with the structure of FIG. 1 except that the adhesive layer (resin) B 'add reflective material and a pigment, but the reflective material is still not reflect colored light. 图1和图2中两种结构的反光材料, 粘结层(树脂)B、B'均具有反射功能,各玻璃微珠都是嵌入到粘结层(树脂)中,且玻璃微珠大约有半个球面嵌入到粘结层(树脂)中,但由于玻璃微珠是由二氧化钛和氧化钡为主要成分的高折射率材料,本身具有比较大的反射能力,它反射的光由入射光决定,故白色光入射,它的反射光也是白色。 Reflective material both structures in FIG. 1 and FIG. 2, the adhesive layer (resin) B, B 'have the reflection function, each of the glass beads are embedded in the adhesive layer (resin) and glass beads about hemispherical surfaces embedded in the adhesive layer (resin), but since the glass beads as titanium dioxide and barium oxide as a main component a high refractive index material itself has a relatively large reflectivity, which is determined by the incident reflected light, therefore, white light is incident, its reflected light is white.

发明内容 SUMMARY

[0006] 针对现有反光材料反射技术的不足,本发明提供一种结构合理、能反射彩色光的暴露型玻璃微珠反光膜,应用于夜间反光装置时,当入射光为白光通过该反光膜可以反射出彩色光线,更能有效警示相关人员,进一步减少夜间事故,从而改善夜间工作管理。 [0006] The reflective material for reflecting deficiencies of the prior art, the present invention provides a rational structure, the reflective film that reflects light colored glass beads exposed reflective film, reflective means when applied at night, when the incident light is white light by a color light can be reflected, more effective warning personnel, to further reduce the accidents at night, thereby improving night work management.

[0007] 同时,本发明还提供两种制备上述反光膜的方法。 [0007] Meanwhile, the present invention also provides a method for preparing the above-described two kinds of reflective film.

[0008] 为达到上述目的,本发明是通过以下技术方案实现的: [0008] To achieve the above object, the present invention is achieved by the following technical solution:

[0009] 一种能反射彩色光的暴露型玻璃微珠反光膜,包括基材、反射层、透明颜色层和若干玻璃微珠凸镜,基材上依次设有反射层和透明颜色层,透明颜色层上通过透明粘结层植上若干玻璃微珠凸镜,且各玻璃微珠凸镜部分穿透于透明粘结层并与透明颜色层的上平面呈点接触,入射光通过玻璃微珠凸镜及透明颜色层到达反射层聚焦反光,反射光再透过透明颜色层及玻璃微珠凸镜使之形成进入视觉的有色反光;同时入射光源的其他其他光线透过玻璃微珠凸镜之间的透明粘结层、颜色层且在反射层形成漫反射影射到玻璃微珠凸镜并在其聚焦反射的共同作用下形成视觉上全面的彩色反光。 [0009] A type of glass beads which reflects exposure light colored reflective film comprising a substrate, a reflective layer, a color layer and a plurality of transparent glass beads convex mirror, a reflective layer are sequentially provided on a substrate and a transparent color layer is transparent color layer on the transparent adhesive layer by a plurality of glass beads explants convex mirror, and a convex mirror portion of each glass beads penetrate the transparent adhesive layer on a plane and the transparent color layer is point contact, incident light passes through glass beads convex mirror and the transparent color layer to the reflective layer reflecting the focus, the reflected light enters again so as to form a colored visual color through the transparent layer and reflective glass beads convex mirror; other light sources simultaneously incident through the glass microspheres of a convex mirror a transparent adhesive layer between the color forming layer and the diffuse reflection alluding to the glass beads and a convex lens is formed on the overall visual color reflective focusing under the action of its reflection in the reflective layer.

[0010] 进一步,透明颜色层和透明粘结层的厚度受玻璃微珠折射率的限制,玻璃微珠折射高,这二层厚度就薄,反之这二层就厚,总之要保证入射光透过玻璃微珠这个凸镜加透明颜色层和透明粘结层到达反射层正好形成聚焦点。 [0010] Further, the thickness of the transparent color layer and a transparent adhesive layer of a restricted refractive index glass beads, high refractive glass beads, the thickness of the floor on which thin thickness on the floor and vice versa which, in short, to ensure that the incident light lens the glass beads had convex mirror color-plus-clear transparent layer and the adhesive layer to the reflective layer is formed just focus point. 根据计算及实际操作经验,透明颜色层和透明粘结层叠加层的厚度要使之保证它在玻璃微珠球面底部与反射层之间在2um-6um, 且玻璃微珠的折射率在1. 90-1. 93之间。 The calculation and practical experience, the color thickness of the transparent layer and a transparent adhesive layer applied to make the laminate to ensure that it 2um-6um, and the refractive index glass beads is between the bottom of the spherical glass beads with a reflective layer. 90-1. 93 between.

[0011] 进一步,所述的相邻透玻璃微珠凸镜之间的透明粘结层为等厚度的平面,其折射率在1. 45-1. 55之间。 [0011] Further, the transparent adhesive layer between the adjacent transparent glass beads and the like convex mirror is planar thickness, a refractive index between 1. 45-1. 55.

[0012] 进一步,所述的透明颜色层由透明树脂和其内的颜料加工成一平面层,根据需要还可在上面压镭射纹,颜料或染料必须为透明型的,颜料为汽巴或奥利沙染料,透明树脂为丙稀酸树脂或Pu树脂。 [0012] Further, the transparent color layer is fabricated from a transparent resin and a pigment into a planar inner layer, the above pressure may be required laser pattern, it must be transparent pigment or a dye type, the pigment or oxaliplatin Ciba dye, transparent resin is acrylic resin or resin Pu.

[0013] 进一步,所述的透明粘结层还可以为透明颜色粘结层,则反射光的颜色是透明颜色层和透明颜色粘结层两种颜色的叠加。 [0013] Further, the transparent adhesive layer may also be a transparent color adhesive layer, the color of reflected light is superimposed transparent color and two colors of a transparent adhesive layer is a color layer.

[0014] 进一步,所述的透明粘结层为丙稀酸树脂或Pu树脂。 [0014] Further, the adhesive layer is a transparent acrylic resin or a resin Pu.

[0015] 一种能反射彩色光的暴露型玻璃微珠反光膜的制作方法,该方法为反射层反贴法,其步骤如下: [0015] A color capable of reflecting light exposure method for manufacturing glass beads reflective film, anti-reflection layer which is a paste method, the following steps:

[0016] 一)、将PET或其他材质薄膜先涂上脱离层制作为辅助膜; [0016] a) the first PET film or other materials coated with the release layer made of the auxiliary film;

[0017] 二)、在辅助膜的脱离层表面做上透明颜色层,其做法可以是直接涂层或印刷; [0017] b), the transparent color cook auxiliary film layer on the surface of the release layer, which may be a direct approach coating or printing;

[0018] 三)、在上述透明颜色层表面上镀铝加工形成反射层; [0018] c), the upper surface of the transparent color layer is processed to form a reflective layer of aluminum;

[0019] 四)、在步骤三)中的反射层通过粘合剂与基材为一体,并剥离辅助膜; [0019] d), a reflective layer in step c) in the substrate by an adhesive as a whole, the auxiliary film and peeled;

[0020] 五)、剥离辅助膜后其透明颜色层粘合的面通过透明粘结层并植上玻璃微珠使其与透明颜色层表面点接触而加工为成品。 [0020] v), which auxiliary film after peeling the transparent color layer of the adhesive surface through the transparent adhesive layer and the glass beads explant into contact with the surface of the transparent layer and the color point of processing into finished products.

[0021] 另外,一种能反射彩色光的暴露型玻璃微珠反光膜的制作方法,该方法为反射层直镀法,其步骤如下: [0021] Further a color capable of reflecting light exposure method for manufacturing glass beads reflective film, a reflective layer which direct plating method comprises the following steps:

[0022] 一)、将基材涂上树脂或其他方法使之表面平整以便于镀反射层; [0022] a), the substrate is coated with a resin or other methods so as to make the surface smooth reflective coating layer;

[0023] 二)、在基材的加工面镀反射层; [0023] II) coating the working surface of the substrate reflective layer;

[0024] 三)、在反射层表面做上透明颜料层; [0024] c), the cook surface of the reflective layer is transparent pigment layer;

[0025] 四)、在透明颜料层通过透明粘结层植上玻璃微珠使其与透明颜色层表面点接触加工为成品。 [0025] d), a transparent pigment layer by the transparent adhesive layer on the glass beads explant into contact with the surface of the transparent layer is processed into finished color point.

[0026] 进一步,所述的透明颜色层由透明树脂和其内的颜料加工成一平面层,颜料为汽巴或奥利沙染料,透明树脂为丙稀酸树脂或Pu树脂。 [0026] Further, the transparent color layer is fabricated from a transparent resin and a pigment into a planar inner layer, or oxaliplatin Ciba pigment dye, transparent resin is acrylic resin or resin Pu.

[0027] 进一步,所述的透明颜料层上还可压设有镭射图案,透明粘结层添加颜料形成透明颜色粘结层,则反射光的颜色是透明颜色层和透明颜色粘结层两种颜色的叠加,透明颜色层和透明粘结层叠加层的厚度要使之保证它在玻璃微珠球面底部与反射层之间在2um-6um,根据玻璃微珠的粒径和折射率变化而变化。 [0027] Further, also the pressure on said transparent pigment layer is provided with laser design, the transparent adhesive layer to add color pigments transparent adhesive layer is formed, the color of reflected light color is transparent adhesive layer and the transparent color layers of two overlay color, color thickness of the transparent layer and a transparent adhesive layer applied to make the laminate to ensure that it 2um-6um, according to the change in refractive index glass beads and the particle size varies between the bottom of the spherical glass beads and the reflective layer .

[0028] 本发明的反射机理如下:入射白光通过玻璃微珠透过透明颜色层变色调焦使之聚焦点在金属反射层上并反射,所反射光通过透明颜色层使之为有色;同时入射光源的其他漫射光透过玻璃微珠之间的透明粘结层到达透明颜色层,由于它只是一个平面且折射率在1. 5左右,所以不会形成聚焦只会互相漫射,将颜色光线互相影射到玻璃微珠凸镜,且其反射层前有一层透明颜色层,白色光透过透明颜色层到达反射层,变色后通过反射层形成漫反射,其反射光再通过透明颜色层在二者共同作用下,使玻璃微珠凸镜的反射光从视觉上形成全面彩色。 [0028] The present invention reflection mechanism is as follows: the incident white light by the color layer through the transparent glass beads so that the focal point of the focus color on the metal reflective layer and reflected light reflected by a colored transparent so that the color layer; incident simultaneously other diffuse light source reach the transparent color layer is transmitted through the transparent adhesive layer between the glass beads, because it is just a plane and a refractive index of about 1.5, the focus is not formed will diffuse to each other, the color of the light glass beads each mapped to a convex mirror, and a layer of transparent color layer of the front reflection layer, white light reaching the reflective layer through the transparent color layers, the color is formed by diffusely reflecting reflective layer, then the reflected light passes through the transparent layer in the second color jointly under the action of the reflective glass beads round convex mirror is formed of a light color visually.

[0029] 本发明与现有的反光材料相比,应用于夜间反光装置时,由于能反射彩色光,对于减少夜间事故,改善夜间工作管理,提高夜间工作效率都起着极为重要的作用。 [0029] The present invention compared with the conventional reflective material, when applied to night reflective device, since the color can reflect light, night to reduce accidents, improve night work management, improve the efficiency of night work plays a very important role.

附图说明 BRIEF DESCRIPTION

[0030] 图1是一种现有反光材料结构示意图; [0030] FIG. 1 is a schematic view of conventional reflective material structure;

[0031] 图2是现有另一种反射白光的彩色反光材料结构示意图; [0031] FIG. 2 is another conventional color to reflect white light reflecting material structural diagram;

[0032] 图3是本发明结构示意图; [0032] FIG. 3 is a structural diagram of the present invention;

[0033] 图4是本发明反射机理示意图。 [0033] FIG. 4 is a schematic view of the mechanism of the present invention reflection.

具体实施方式 Detailed ways

[0034] 下面结合附图对本发明作进一步说明: [0034] DRAWINGS The present invention is further described:

[0035] 实施例:请参阅图3,一种能反射彩色光的暴露型玻璃微珠反光膜,包括基材1、反射层2、透明颜色层3和若干玻璃微珠凸镜4,基材1上依次设有反射层2和透明颜色层3, 根据需要还可在透明颜色层上压镭色纹,透明颜色层3上通过透明粘结层5植上若干玻璃微珠凸镜4,且各玻璃微珠凸镜4穿透于透明粘结层5并与透明颜色层3的上平面呈点接触。 [0035] Example: Referring to FIG. 3 A light color capable of reflecting glass beads is exposed reflective film, comprising a substrate 1, a reflective layer 2, transparent color layer 3 and a plurality of glass beads convex lens 4, the substrate 2 and the reflective layer are sequentially provided with a transparent color layer 3 is 1, if necessary also laminated on the transparent color laser pattern color, transparent color layer 3 by a plurality of glass beads on the transparent adhesive layer 5 explants convex mirror 4, and each convex mirror glass beads penetrate the transparent adhesive layer 4 and 5 on a plane of the transparent color layer 3 point contact.

[0036] 本发明中,玻璃微珠凸镜4的折射率在1. 90-1. 93之间。 [0036] In the present invention, the refractive index of glass beads between the convex mirror 4 1. 90-1. 93. 相邻透玻璃微珠凸镜4 之间的透明粘结层5为等厚度的平面,其折射率在1. 45-1. 55之间。 Transparent adhesive layer 4 between adjacent convex mirror transparent glass microspheres 5 to the thickness of the other plane, a refractive index between 1. 45-1. 55. 透明颜色层3由透明树脂和其内的颜料加工成一平面层,颜料或染料为透明型,透明树脂为丙稀酸树脂或Pu树脂和聚脂树脂,透明粘结层5为丙稀酸树脂或Pu树脂和聚脂树脂,透明颜色层3还具有调焦的作用,使经过玻璃微珠凸镜入射光的焦点聚焦在反射层上并反射。 Transparent color layer 3 is fabricated from a transparent resin and a pigment therein as a planar layer, in a transparent pigment or a dye, transparent resin is acrylic resin or polyester resin and Pu resin, the adhesive layer 5 is a transparent acrylic resin or Pu resin and polyester resin, transparent color layer 3 further has a focusing effect of the glass bead through the focus of a convex lens to focus incident light on the reflecting layer and reflection. 透明颜色层和透明粘结层厚度的叠加在2um-6um之间。 Color transparent layer and the transparent adhesive layer thickness between superposed 2um-6um.

[0037] —种能反射彩色光的暴露型玻璃微珠反光膜的制作方法,该方法为反射层反贴法,其步骤如下: [0037] - species capable of reflecting colored light exposure method for manufacturing glass beads reflective film, anti-reflection layer which is a paste method, the following steps:

[0038] 一)、将PET或其他材质薄膜先涂上脱离层制作为辅助膜; [0038] a) the first PET film or other materials coated with the release layer made of the auxiliary film;

[0039] 二)、在辅助膜的脱离层表面做上透明颜色层,其做法可以是直接涂层或印刷; [0039] b), the transparent color cook auxiliary film layer on the surface of the release layer, which may be a direct approach coating or printing;

[0040] 三)、在上述透明颜色层表面上镀铝加工形成反射层; [0040] c), the upper surface of the transparent color layer is processed to form a reflective layer of aluminum;

[0041] 四)、在步骤三)中的反射层通过粘合剂与基材为一体,并剥离辅助膜; [0041] d), a reflective layer in step c) in the substrate by an adhesive as a whole, the auxiliary film and peeled;

[0042] 五)、剥离辅助膜后其透明颜色层粘合的面通过透明粘结层并植上玻璃微珠制加工为成品。 [0042] v), which auxiliary film after peeling the transparent color layer is bonded by a transparent adherent layer surface of the plant and processed into finished products made of glass beads.

[0043] 另外,一种能反射彩色光的暴露型玻璃微珠反光膜的制作方法,该方法为反射层直镀法,其步骤如下: [0043] Further a color capable of reflecting light exposure method for manufacturing glass beads reflective film, a reflective layer which direct plating method comprises the following steps:

[0044] — )、将基材涂上树脂或其他方法使之表面平整以便于镀反射层; [0044] -), the substrate is coated with a resin or other methods so as to make the surface smooth reflective coating layer;

[0045] 二)、在基材的加工面镀反射层; [0045] II) coating the working surface of the substrate reflective layer;

[0046] 三)、在反射层表面做上透明颜料层,可以印刷、直涂或涂在离型膜上反贴;[0047] 四)、在透明颜料层通过透明粘结层植上玻璃微珠加工为成品。 [0046] c), the cook surface of the reflective layer of the transparent pigment layer, may be printed, coated or painted directly release film paste trans; [0047] d), a transparent layer of paint on the glass microspheres implanted through a transparent adhesive layer Pearl processed into finished products.

[0048] 上述两种方法中颜色由透明颜色层决定;对玻璃微珠要求折射率在1. 90-1. 93之间,透明颜色层和透明粘结层并无特殊要求,一般市场上的丙稀酸树脂粘合剂或Pu树脂粘合剂都能满足要求。 [0048] The above two methods is determined by the color layer, a transparent color; of refractive index between the glass beads in claim 1. 90-193, transparent color layer and a transparent adhesive layer is not particularly required, in the general market. Pu acrylic resin binder or a resin binder can meet the requirements. 颜色层颜料或染料必须为透明型。 Color layer must be transparent pigment or a dye type.

[0049] 如图1、图2及图3对比看,能反射彩色光和不能反射彩色光的结构最大区别在于: 不能反射彩色光的其反射层是直接在玻璃微珠的球面并大约有半个球面;而能反射彩色光的其反射层是玻璃微珠透过一层透明颜色层才能达到,且反射层不是包裹半个球面,只是接触到玻璃微珠球面顶点的一个点。 [0049] 1, 2 and 3 see FIG contrast, the maximum difference between the structure capable of reflecting light and the color can not be reflected colored light in that: a reflective layer which is not directly reflected light colored spherical glass beads and about half spherical surfaces; and a reflective layer which is capable of reflecting colored light through glass beads to achieve color layer to a transparent, and the reflective layer is not wrapped hemispherical surfaces, but the contact point of the glass beads to a vertex sphere.

[0050] 一种能反射彩色光的暴露型玻璃微珠反光材料,包括基材、反射层、透明颜色层, 根据需要还可在透明颜色层上压上镭射图案。 [0050] A light color capable of reflecting glass beads is exposed reflective material comprising a substrate, a reflective layer, a transparent color layer, may be required on the transparent color layer is pressed on the laser design. 基材上依次设有反射层和透明颜色层,透明颜色层通过透明粘结层植上若干玻璃微珠凸镜,且各玻璃微珠凸镜贯穿于透明粘结层并与透明颜色层的上平面呈点接触。 And a reflective layer are sequentially provided on a substrate transparent color layers, the color layer is formed by a transparent adhesive layer on the transparent convex lens implant several glass beads, glass beads and each convex lens through the transparent layer and the adhesive layer and the transparent color point contact plane. 其基材根据用途可进行适当选择,如雨伞上用可选择涤纶化纤布,做鞋用可选择各种皮革材料,服装、箱包上用可选择各种面料布。 The use of a substrate which may be appropriately selected, such as polyester fiber with a selectable umbrella cloth, leather shoes with a selectable variety of materials, clothing, cloth fabric with a selectable variety of luggage. 透明颜色层和透明粘结层的厚度受玻璃微珠折射率的限制,玻璃微珠折射率高,粒径小,这二层厚度就薄, 反之这二层就厚,总之要保证入射光透过玻璃微珠这个凸镜加透明颜色层和透明粘结层到达反射层正好形成聚焦点。 Color thickness of the transparent layer and the transparent adhesive layer is limited by the refractive index glass beads, glass beads of high refractive index, a small particle diameter, the thickness of the floor on which thin thickness on the floor and vice versa which, in short, to ensure that the incident light lens the glass beads had convex mirror color-plus-clear transparent layer and the adhesive layer to the reflective layer is formed just focus point. 根据计算及实际操作经验,透明颜色层和透明粘结层叠加层的厚度要使之保证它在玻璃微珠球面底部与反射层之间在2um-6um,且玻璃微珠的折射率在1. 90-1. 93之间。 The calculation and practical experience, the color thickness of the transparent layer and a transparent adhesive layer applied to make the laminate to ensure that it 2um-6um, and the refractive index glass beads is between the bottom of the spherical glass beads with a reflective layer. 90-1. 93 between. 如果将透明粘结层做成透明颜色粘结层,则其反射光的颜色是透明颜色层和透明颜色粘结层二种颜色的叠加。 If the transparent adhesive layer made of a transparent adhesive layer color, the color of reflected light is the superposition of the transparent color layer and a transparent adhesive layer color of two colors.

[0051] 本发明中,透明颜色层叠加透明粘结层厚度介于玻璃微珠球面底部与反射层之间且厚度在2um-6um。 [0051] In the present invention, the transparent color-plus-clear laminate thickness and the thickness of the adhesive layer between the bottom of the 2um-6um spherical glass beads and the reflective layer is interposed.

[0052] 本发明公开一种暴露型玻璃微珠反光材料及制作方法,包括基材、反射层、透明颜色层和若干玻璃微珠凸镜,基材上依次设有反射层和透明颜色层,根据需要还可在透明颜色层上压上镭射图案。 [0052] The present invention discloses an exposed glass bead reflective material and manufacturing method, comprising a substrate, a reflective layer, a color layer and a plurality of transparent glass beads convex mirror, the reflective layer are sequentially provided on a substrate and a transparent color layer, the required colors may also be laminated on a transparent pattern on the CD. 透明颜色层上通过透明粘结层植上若干玻璃微珠凸镜,且各玻璃微珠凸镜贯穿于透明粘结层并与透明颜色层的上平面呈点接触。 Color layer on the transparent adhesive layer on the transparent convex lens implant several glass beads, glass beads and each convex lens through the transparent adhesive layer on a plane and the transparent color layer is point contact. 该反光材料的制作方法有反射层直镀法和反射层反贴法,本发明的入射白光通过玻璃微珠反射为白色光,而经过透明粘结层的入射白光由于其折射率为1.5左右,互相漫射,将透明颜色层的颜色互相影射到玻璃微珠凸镜,且其反射层前有一层透明颜色层,白色光通过透明颜色层到达反射层变色后成焦点形成反射,其反射光再透过透明颜色层,在二者作用下,使玻璃微珠凸镜的反射光从视觉上形成全面彩色。 The method of manufacturing a reflective layer of reflective material and a reflective layer plating direct anti paste method, according to the present invention, incident white light reflected by the glass beads into white light, and white light is incident through the transparent adhesive layer due to a refractive index of about 1.5, mutual diffusion, the transparent color to another color mapping layer of glass beads convex mirror, and a layer of transparent color layer of the front reflection layer, color white light into focus after reflection layer is formed by a transparent reflective layer to the color, the reflected light then through the transparent color layers, both under action of the reflective glass beads round convex mirror is formed of a light color visually. 本发明与现有的暴露反光材料相比,应用于夜间反光装置时,由于能反射彩色光,且还可有镭射效果,对于减少夜间事故,改善夜间工作管理及美化一些身着用品和日常用品都起着积极的作用。 Present invention compared with the conventional exposure reflective material, when applied to night reflective device, since the color can reflect light, and may also have a laser effect, a number of supplies and daily necessities wearing night to reduce accidents, improve management of night work and landscaping They play an active role.

[0053] 以上所记载,仅为利用本创作技术内容的实施例,任何熟悉本项技艺者运用本创作所做的修饰、变化,皆属本创作主张的专利范围,而不限于实施例所揭示者。 [0053] described above, the present embodiment utilizes only technical content creation, any use Skilled persons present creation made modifications, changes, as both the creation of the present patent claims scope, not limited to the disclosed embodiments By.

Claims (10)

  1. 一种能反射彩色光的暴露型玻璃微珠反光膜,其特征在于:包括基材、反射层、透明颜色层和若干玻璃微珠凸镜,其中:基材,其上依次设有反射层和透明颜色层,透明颜色层上通过透明粘结层植上若干玻璃微珠凸镜,且各玻璃微珠凸镜部分穿透于透明粘结层并与透明颜色层的上平面呈点接触;入射光通过玻璃微珠凸镜及透明颜色层到达反射层聚焦反光,反射光再透过透明颜色层及玻璃微珠凸镜使之形成进入视觉的有色反光;同时入射光源的其他其他光线透过玻璃微珠凸镜之间的透明粘结层、颜色层且在反射层形成漫反射影射到玻璃微珠凸镜并在其聚焦反射的共同作用下形成视觉上全面的彩色反光。 Type can be one kind of reflective glass beads exposed colored light reflective film, characterized by: comprising a substrate, a reflective layer, a color layer and a plurality of transparent glass beads convex mirror, wherein: the substrate, and a reflective layer are sequentially provided thereon transparent color layers, the color layer is formed by a transparent adhesive layer on the transparent convex lens implant several glass beads, glass beads and each of the convex mirror portion penetrating the transparent adhesive layer on a plane and the transparent color layer is point contact; incident light convex mirror and the transparent color layer to the reflective layer by focusing reflective glass beads, and then the reflected light enters so as to form a colored visual color through the transparent layer and reflective glass beads convex mirror; other sources of light incident through the glass while a transparent adhesive layer between the beads convex mirror, and a color layer formed into glass microspheres mapping diffuse reflection mirror and a convex is formed on the overall visual color reflective focusing under the action of its reflection in the reflective layer.
  2. 2.根据权利要求1所述的能反射彩色光的暴露型玻璃微珠反光膜,其特征在于:所述的玻璃微珠凸镜的折射率在1. 90-1. 93之间。 Reflective color can according to claim 1 of the light-exposed glass beads reflective film, wherein: the refractive index of the glass beads is between the convex mirror 1. 90-193.
  3. 3.根据权利要求1所述的能反射彩色光的暴露型玻璃微珠反光膜,其特征在于:所述的相邻透玻璃微珠凸镜之间的透明粘结层为等厚度的平面,其折射率在1. 45-1. 55之间。 According to claim 1, which reflects the exposure light colored glass beads reflective film, wherein: the transparent adhesive layer between the adjacent transparent glass beads and the like convex mirror is planar thickness, a refractive index between 1. 45-1. 55.
  4. 4.根据权利要求1所述的能反射彩色光的暴露型玻璃微珠反光膜,其特征在于:所述的透明颜色层由透明树脂和其内的颜料加工成一平面层,根据需要还可在上面压镭射纹, 颜料或染料必须为透明型的,颜料为汽巴或奥利沙染料,透明树脂为丙稀酸树脂或Pu树脂。 The exposed glass beads reflective film according to claim colored light can be reflected in claim 1, characterized in that: the transparent color layer is fabricated from a transparent resin and a pigment into a planar inner layer, it may be required in the above pressure pattern laser, a dye or a pigment must be transparent type, Ciba pigment or dye oxaliplatin, acrylic resin, or transparent resin is a resin Pu.
  5. 5.根据权利要求1所述的能反射彩色光的暴露型玻璃微珠反光膜,其特征在于:所述的透明粘结层还可以为透明颜色粘结层,则反射光的颜色是透明颜色层和透明颜色粘结层两种颜色的叠加。 The color capable of reflecting the light exposed glass beads reflective film as claimed in claim, wherein: said transparent adhesive layer may also be the color of the transparent adhesive layer, the color of reflected light color is transparent and a transparent color overlays the adhesive layer of two colors.
  6. 6.根据权利要求1所述的能反射彩色光的暴露型玻璃微珠反光膜,其特征在于:所述的透明粘结层为丙稀酸树脂或Pu树脂。 The can according to claim 1 reflected colored light exposed glass beads reflective film, wherein: said adhesive layer is a transparent acrylic resin or a resin Pu.
  7. 7. 一种能反射彩色光的暴露型玻璃微珠反光膜的制作方法,该方法为反射层反贴法, 其步骤如下:一)、将PET或其他材质薄膜先涂上脱离层制作为辅助膜;二)、在辅助膜的脱离层表面做上透明颜色层,其做法可以是直接涂层或印刷;三)、在上述透明颜色层表面上镀铝加工形成反射层;四)、在步骤三)中的反射层通过粘合剂与基材为一体,并剥离辅助膜;五)、剥离辅助膜后其透明颜色层粘合的面通过透明粘结层并植上玻璃微珠使其与透明颜色层表面点接触而加工为成品。 A color capable of reflecting light exposure method for manufacturing glass beads reflective film, anti-reflection layer which is a paste method, the following steps: a) the first PET film or other materials coated with the release layer made of an auxiliary membrane; b), the cook surface of the auxiliary layer of the transparent film from the color layer, which may be a direct approach coating or printing; c), the upper surface of the transparent color layer is processed to form a reflective layer of aluminum; d), at step the reflective layer c) is an adhesive and the substrate as a whole, and the auxiliary film release; e), the auxiliary film after peeling the adhesive layer which is a transparent color and planted on the surface of the adhesive layer through the transparent glass beads reacted with transparent color layer is processed into the surface of the finished contact points.
  8. 8. 一种能反射彩色光的暴露型玻璃微珠反光膜的制作方法,该方法为反射层直镀法, 其步骤如下:一)、将基材涂上树脂或其他方法使之表面平整以便于镀反射层;二)、在基材的加工面镀反射层;三)、在反射层表面做上透明颜料层;四)、在透明颜料层通过透明粘结层植上玻璃微珠使其与透明颜色层表面点接触加工为成品。 A color capable of reflecting light exposure method for manufacturing glass beads reflective film, a reflective layer which direct plating method comprises the following steps: a) the substrate is coated with a resin or other methods to make the surface smooth a reflective layer on the plating; b), in the processing surface of the substrate plating reflective layer; iii), cook surface of the reflective layer is transparent pigment layer; iv), the plant via the transparent adhesive layer so that the transparent pigment layer of glass beads point-contact processing with the transparent surface layer is a finished color.
  9. 9.根据权利要求7或8所述的能反射彩色光的暴露型玻璃微珠反光膜的制作方法,其特征在于:所述的透明颜色层由透明树脂和其内的颜料加工成一平面层,颜料为汽巴或奥利沙染料,透明树脂为丙稀酸树脂或Pu树脂。 According to claim 7 or claim 8 capable of reflecting colored light exposure method for manufacturing glass beads type retroreflective film, wherein: the transparent color layer is fabricated from a transparent resin and a pigment therein as a planar layer, Ciba pigment or dye oxaliplatin, acrylic resin, or transparent resin is a resin Pu.
  10. 10.根据权利要求7或8所述的能反射彩色光的暴露型玻璃微珠反光膜的制作方法,其特征在于:所述的透明颜料层上还压设有镭射图案,透明粘结层添加颜料形成透明颜色粘结层,则反射光的颜色是透明颜色层和透明颜色粘结层两种颜色的叠加,透明颜色层和透明粘结层叠加层的厚度要使之保证它在玻璃微珠球面底部与反射层之间在2um-6um。 Capable of reflecting the color according to claim 7 or 8 light exposure method for manufacturing glass beads type retroreflective film, wherein: the layer of the transparent pigment is further provided with laser design pressure, adding a transparent adhesive layer forming a transparent adhesive layer color pigment, the color of reflected light is the superposition of the transparent color layer and a transparent adhesive layer color two colors, color thickness of the transparent layer and a transparent adhesive layer applied to make the laminate to ensure that the glass beads in 2um-6um between the spherical bottom and the reflective layer.
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