CN101973679B - Distributed sewage treatment and regeneration technology - Google Patents
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Abstract
一种适合于小城镇的分散式城市污水处理与再生工艺,属于水污染处理技术领域。本工艺包括如下步骤:城市污水首先进行水解酸化处理,后经潜污泵进入曝气生物流化床,去除有机物并通过其缺氧段进行脱氮处理,然后进入沉淀池进行泥水分离;沉淀池出水经快速砂滤池去除悬浮物,然后进入缓冲池;水从缓冲池经人工土壤渗滤进一步净化后经收集管进入清水池。该污水处理方法工艺简单,出水水质稳定,水质满足城市污水再生利用-城市杂用水质标准(GB/T 18920-2002)。
A decentralized urban sewage treatment and regeneration process suitable for small towns belongs to the technical field of water pollution treatment. The process includes the following steps: urban sewage is first hydrolyzed and acidified, and then enters the aerated biological fluidized bed through the submersible sewage pump, removes organic matter and undergoes denitrification treatment through its anoxic section, and then enters the sedimentation tank for mud-water separation; the sedimentation tank The effluent goes through the quick sand filter to remove suspended solids, and then enters the buffer tank; the water from the buffer tank is further purified by artificial soil infiltration, and then enters the clear water tank through the collection pipe. The sewage treatment method has a simple process, stable effluent quality, and the water quality meets the urban sewage recycling-urban miscellaneous water quality standard (GB/T 18920-2002).
Description
技术领域 technical field
本发明属于水污染处理技术领域,尤其涉及一种适用于中小城镇的分散式污水处理与再生工艺。The invention belongs to the technical field of water pollution treatment, and in particular relates to a decentralized sewage treatment and regeneration process suitable for small and medium-sized towns.
背景技术 Background technique
污水处理可以分为集中式污水处理和分散式污水处理。分散式处理是指建立集预处理、二级处理、深度处理于一体的小型污水处理系统,对污水进行处理的一种方式。分散式处理在上世纪末开始受到人们的注意和研究,现在已经成为国内外生活污水处理的一种新理念。随着我国国民经济的发展和城市化进程的加快,以及对环境质量的要求不断提高,分散式处理在我国有非常广阔的发展空间。Sewage treatment can be divided into centralized sewage treatment and decentralized sewage treatment. Distributed treatment refers to the establishment of a small sewage treatment system integrating pretreatment, secondary treatment and advanced treatment to treat sewage. Distributed treatment began to attract people's attention and research at the end of the last century, and now it has become a new concept of domestic sewage treatment at home and abroad. With the development of my country's national economy and the acceleration of urbanization, as well as the continuous improvement of environmental quality requirements, decentralized processing has a very broad space for development in our country.
与集中式污水处理方式相比,分散式处理具有独特的优势。首先,分散式处理规模较小,有利于最新处理技术的示范应用,技术更新快,推动技术创新;其次,我国很多地区,中小城镇的经济水平不具备建设大型的集中式污水处理厂和相应的下水设施的条件,应首选分散式处理设施;第三,分散式处理装置能耗低,节约处理费用;第三,分散式处理能有效减少有害物质的扩散,提供污水再生利用的机会,还可以补充涵养当地的地下水,将污水处理的环境影响降低到最小程度。Compared with centralized sewage treatment, decentralized treatment has unique advantages. First of all, the small scale of decentralized treatment is conducive to the demonstration application of the latest treatment technology, rapid technological update, and promotion of technological innovation; secondly, in many areas of our country, the economic level of small and medium-sized towns does not have the ability to build large-scale centralized sewage treatment plants and corresponding Distributed treatment facilities should be the first choice for the conditions of sewage facilities; third, decentralized treatment devices have low energy consumption and save treatment costs; third, decentralized treatment can effectively reduce the spread of harmful substances and provide opportunities for sewage recycling. Replenish and conserve local groundwater to minimize the environmental impact of sewage treatment.
目前污水分散式处理的常规技术包括:The current conventional technologies for decentralized sewage treatment include:
(1)厌氧-好氧生物处理技术,将厌氧、好氧生物处理技术相结合,可以达到既去除有机物又去除含磷、含氮物质的目的,降低能耗,减少污泥量。(1) Anaerobic-aerobic biological treatment technology, combining anaerobic and aerobic biological treatment technology, can achieve the purpose of removing not only organic matter but also phosphorus and nitrogen-containing substances, reducing energy consumption and sludge volume.
(2)膜生物反应器技术,该技术是把生物处理与膜分离相结合的工艺,由于膜具有高效分离的特点,因此出水水质好,可以直接达到回用所需的水质,在生物反应器中维持高浓度生物量并提高了负荷。(2) Membrane bioreactor technology, which is a process that combines biological treatment and membrane separation. Because the membrane has the characteristics of high-efficiency separation, the effluent water quality is good, and the water quality required for reuse can be directly achieved. In the bioreactor High concentrations of biomass were maintained and loads increased.
(3)自然净化。在地理、气候条件适合以及土地可得到情况下,利用人工湿地、土地渗滤、氧化塘等自然净化系统对污水进行处理,具有处理效果稳定,投资少,管理简单等特点。土地处理是城市郊区以及农村分散式处理技术的最佳选择。(3) Natural purification. When the geographical and climatic conditions are suitable and the land is available, natural purification systems such as artificial wetlands, land infiltration, and oxidation ponds are used to treat sewage, which has the characteristics of stable treatment effects, low investment, and simple management. Land treatment is the best choice for urban suburbs as well as decentralized treatment technology in rural areas.
在污水的好氧生物处理技术中,污水、微生物、氧,三者之间的传质条件是决定反应器效率的关键因素。与传统的生物处理法相比,好氧生物流化床生物量高,有机负荷高,水力停留时间短,因此设备体积可以大大减小,节约占地面积和基建费用;不存在活性污泥法中的污泥膨胀或者生物滤池中的床层堵塞问题,运行稳定;另外生物流化床还具有较高的抗冲击负荷能力,上述特点使得生物流化床成为适合城市污水分散式处理的要求的处理工艺。In the aerobic biological treatment technology of sewage, the mass transfer conditions between sewage, microorganisms and oxygen are the key factors to determine the efficiency of the reactor. Compared with the traditional biological treatment method, the aerobic biological fluidized bed has high biomass, high organic load, and short hydraulic retention time, so the equipment volume can be greatly reduced, saving floor space and infrastructure costs; it does not exist in the activated sludge process. The problem of sludge bulking or bed blockage in the biological filter is stable, and the biological fluidized bed also has a high impact load resistance. The above characteristics make the biological fluidized bed suitable for the requirements of the decentralized treatment of urban sewage. Processing technology.
人工土壤渗滤是将生态学原理与工程学方法相结合而形成的城市污水的生态处理技术,通过人工构建土壤系统,将污水以一定的水力学条件渗滤通过该系统,借助土壤系统的物理、化学、生物机制,以及能够自我调节的生态学机制,截留、吸附、降解水中的污染物质,充分降解吸收污水中可生物降解的有机物质,实现污水无害化与资源化的生态系统工程。Artificial soil infiltration is an ecological treatment technology for urban sewage formed by combining ecological principles and engineering methods. By artificially constructing a soil system, the sewage is infiltrated through the system under certain hydraulic conditions. , chemical, biological mechanisms, and self-regulating ecological mechanisms, intercepting, adsorbing, and degrading pollutants in water, fully degrading and absorbing biodegradable organic substances in sewage, and realizing the ecological system engineering of harmless and resourceful sewage.
人工土壤渗滤借助上述多种处理机制,污水处理效果好,同时具有自我生态调节的机能,对来水水质、水量具有一定的缓冲能力,运行状态稳定可靠,操作管理简单,构建和运行维护成本低廉,适用范围广泛。With the help of the above-mentioned various treatment mechanisms, artificial soil infiltration has good sewage treatment effect, and at the same time has the function of self-ecological adjustment, has a certain buffer capacity for incoming water quality and water volume, stable and reliable operation status, simple operation and management, and low construction and operation maintenance costs. Inexpensive and widely applicable.
发明内容 Contents of the invention
本发明将曝气生物流化床与人工土壤渗滤相结合,提出了一种适合于小城镇的分散式污水处理与再生工艺。The invention combines an aerated biological fluidized bed with artificial soil infiltration, and proposes a decentralized sewage treatment and regeneration process suitable for small towns.
本发明所述工艺通过如下步骤实现:Process of the present invention realizes through following steps:
(1)污水首先进入水解酸化池,停留时间控制在2.5~3.0小时;污水水解酸化后,经潜污泵抽吸进入曝气生物流化床;曝气生物流化床分为缺氧区和好氧区,由缺氧区对污水进行脱氮处理;污水从曝气生物流化床流出后进入沉淀池进行泥水分离;(1) The sewage first enters the hydrolytic acidification tank, and the residence time is controlled at 2.5 to 3.0 hours; after the sewage is hydrolyzed and acidified, it is sucked into the aerated biological fluidized bed by the submersible sewage pump; the aerated biological fluidized bed is divided into anoxic zone and In the aerobic zone, the sewage is denitrified by the anoxic zone; the sewage flows out of the aerated biological fluidized bed and enters the sedimentation tank for mud-water separation;
(2)沉淀池的污泥回流到曝气生物流化床中,沉淀池的出水进入快速砂滤池,去除水中的悬浮颗粒;快速砂滤池的出水进入缓冲池;(2) The sludge from the sedimentation tank flows back into the aerated biological fluidized bed, and the effluent from the sedimentation tank enters the rapid sand filter to remove suspended particles in the water; the effluent from the rapid sand filter enters the buffer tank;
(3)在缓冲池的一侧布置人工土壤渗滤池,该人工土壤渗滤池的纵深≥5m,土壤深度≥1m,靠水一侧设置为斜坡,所述斜坡与缓冲池的底面夹角大于0°且不大于45°;在人工土壤渗滤池的底部设置收集管,收集管的出水进入清水池;所述人工土壤渗滤池的过滤速度≤5m/天,水力停留时间≥7天。(3) An artificial soil infiltration tank is arranged on one side of the buffer tank, the depth of the artificial soil infiltration tank is ≥ 5m, the soil depth is ≥ 1m, and the side near the water is set as a slope, and the angle between the slope and the bottom surface of the buffer tank Greater than 0° and not greater than 45°; a collection pipe is installed at the bottom of the artificial soil infiltration tank, and the outlet water of the collection pipe enters the clear water pool; the filtration speed of the artificial soil infiltration tank is ≤5m/day, and the hydraulic retention time is ≥7 days .
所述曝气生物流化床的缺氧区与好氧区的容积比为1∶3,水力停留时间为3~6h;好氧区填充空心柱状立体空心填料,DO控制在3~5mg/L,污泥回流比200%;载体附着污泥浓度维持在700mg/L~900mg/L。The volume ratio of the anoxic zone to the aerobic zone of the aerated biological fluidized bed is 1:3, and the hydraulic retention time is 3 to 6 hours; the aerobic zone is filled with hollow columnar three-dimensional hollow packing, and the DO is controlled at 3 to 5 mg/L , The sludge reflux ratio is 200%; the concentration of the carrier-attached sludge is maintained at 700mg/L-900mg/L.
所述快速砂滤池的填砂粒径范围为0.5~1.0mm,流速控制在3~5m/h。The particle size range of the sand filling in the fast sand filter is 0.5-1.0 mm, and the flow rate is controlled at 3-5 m/h.
所述人工土壤渗滤池的土壤粒径范围为0.075~0.5mm,每隔8~12天将缓冲池与人工土壤渗滤池内的水放空,清除缓冲池底部淤泥,翻晾人工土壤渗滤池表层砂层,翻晾深度≥0.5m,以增进砂层复氧。The soil particle size of the artificial soil infiltration tank ranges from 0.075 to 0.5mm, empty the water in the buffer tank and the artificial soil infiltration tank every 8 to 12 days, remove the silt at the bottom of the buffer tank, and turn over to dry the artificial soil infiltration For the sand layer on the surface of the pool, the depth of turning over and drying should be ≥0.5m to promote reoxygenation of the sand layer.
本发明的有益效果为:The beneficial effects of the present invention are:
(1)城市污水首先经过水解酸化预处理,不仅可以有效去除COD、BOD5和SS,还可以有效提高BOD5/COD,有利于后续的生物处理。(1) Urban sewage is first pretreated by hydrolysis and acidification, which can not only effectively remove COD, BOD 5 and SS, but also effectively increase BOD 5 /COD, which is beneficial to subsequent biological treatment.
(2)潜污泵将预处理后的生活污水输入曝气生物流化床的底部,与由流化床底部的空气分布器进入的空气充分混合,向上带动负载生物膜的载体形成流化状态。生物流化床中的填料具有较大的比表面积,能有效降解去除有机物。(2) The submersible sewage pump feeds the pretreated domestic sewage into the bottom of the aerated biological fluidized bed, fully mixes with the air entering from the air distributor at the bottom of the fluidized bed, and drives the carrier carrying the biofilm upward to form a fluidized state . The filler in the biological fluidized bed has a large specific surface area, which can effectively degrade and remove organic matter.
(3)曝气生物流化床出水进入沉淀池进行泥水分离,部分硝化液回流进入生物流化床缺氧区,回流硝化液在反硝化细菌的作用下还原成氮气,实现脱氮。沉淀池上清液进入快速砂滤池,去除水中的悬浮颗粒。(3) The effluent of the aerated biological fluidized bed enters the sedimentation tank for mud-water separation, and part of the nitrifying liquid flows back into the anoxic zone of the biological fluidized bed, and the returning nitrifying liquid is reduced to nitrogen under the action of denitrifying bacteria to realize denitrification. The supernatant of the sedimentation tank enters the rapid sand filter to remove suspended particles in the water.
(4)快速砂滤池出水自流进入缓冲池,通过人工土壤渗滤池。土壤渗滤池停留时间较长,可以有效去除部分难降解有机物和病原微生物,出水满足城市污水再生利用的城市杂用水标准。(4) The effluent from the quick sand filter flows into the buffer tank by itself and passes through the artificial soil infiltration tank. The soil infiltration tank has a long residence time, which can effectively remove some refractory organic matter and pathogenic microorganisms, and the effluent meets the urban miscellaneous water standard for urban sewage recycling.
(5)具有占地省、投资少、运行成本低,处理效果好的优点,满足中小城镇的实际需求情况,易于推广使用。(5) It has the advantages of low land occupation, less investment, low operating cost and good treatment effect, meets the actual needs of small and medium-sized towns, and is easy to popularize and use.
附图说明 Description of drawings
图1是本发明的工艺流程图;Fig. 1 is a process flow diagram of the present invention;
图2为缓冲池及人工土壤渗滤池的剖面示意图。Figure 2 is a schematic cross-sectional view of the buffer tank and the artificial soil infiltration tank.
图中标号:Labels in the figure:
1-水解酸化池;2-潜污泵;3-曝气生物流化床;4-沉淀池;5-快速砂滤池;1-hydrolytic acidification tank; 2-submersible sewage pump; 3-aerated biological fluidized bed; 4-sedimentation tank; 5-rapid sand filter;
6-缓冲池;7-人工土壤渗滤池;8-集水管;9-清水池。6-buffer tank; 7-artificial soil infiltration tank; 8-collection pipe; 9-clear water tank.
具体实施方式 Detailed ways
本发明提供了一种分散式污水处理与再生工艺,下面结合附图和具体实施方式对本发明做进一步说明。The present invention provides a decentralized sewage treatment and regeneration process, which will be further described below in conjunction with the accompanying drawings and specific implementation methods.
如图1和图2所示,本发明的工艺主要为以下步骤:As shown in Figure 1 and Figure 2, technique of the present invention mainly is the following steps:
(1)污水首先进入水解酸化池1,停留时间控制在2.5~3.0小时;污水水解酸化后,经潜污泵2抽吸进入曝气生物流化床3;曝气生物流化床3分为缺氧区和好氧区,由缺氧区对污水进行脱氮处理;曝气生物流化床3的缺氧区与好氧区的容积比为1∶3,水力停留时间为3~6h,好氧区DO控制在3~5mg/L,污泥回流比200%;载体附着污泥浓度维持在700mg/L~900mg/L;污水从曝气生物流化床3流出后进入沉淀池4进行泥水分离;(1) The sewage first enters the
(2)沉淀池4的污泥回流到曝气生物流化床3中,沉淀池4的出水进入快速砂滤池5,去除水中的悬浮颗粒;快速砂滤池的填砂粒径范围为0.5~1.0mm,流速控制在3~5m/h;快速砂滤池5的出水进入缓冲池6;(2) The sludge in the
(3)在缓冲池6的一侧布置人工土壤渗滤池7,该人工土壤渗滤池7的纵深≥5m,土壤深度≥1m,土壤粒径范围为0.075~0.5mm,靠水一侧设置为斜坡,所述斜坡与缓冲池6的底面夹角大于0°且不大于45°;在人工土壤渗滤池7的底部设置收集管8,收集管8的出水进入清水池9;所述人工土壤渗滤池7的过滤速度≤5m/天,水力停留时间≥7天;(3) An artificial
(4)每隔10天将缓冲池6与人工土壤渗滤池7内的水放空,清除缓冲池6底部淤泥,翻晾人工土壤渗滤池7表层砂层,翻晾深度≥0.5m,以增进砂层复氧。(4) Empty the water in the
以下实施例分别使用城市污水处理厂污水、工业废水对本工艺提出的曝气生物流化床进行了试验,在试验基础上建立了实际的污水处理工程,设计处理量30m3/h,出水满足城市污水再生利用-城市杂用水质标准(GB/T 18920-2002)。The following examples use urban sewage treatment plant sewage and industrial wastewater to test the aerated biological fluidized bed proposed by this process. On the basis of the test, an actual sewage treatment project is established. The design treatment capacity is 30m 3 /h, and the effluent meets the urban Sewage Reuse-Urban Miscellaneous Water Quality Standards (GB/T 18920-2002).
实施例1:北京市北小河污水厂中试试验Example 1: Pilot test of Beijing Beixiaohe Sewage Plant
以北京市北小河污水厂的初沉池出水作为原水,水中CODCr=200~450mg/L,BOD5为150~250mg/L,SS为200~400mg/L,氨氮浓度为70~90mg/L。采用本发明中提出的流化床工艺处理,出水中CODCr≤70mg/L,BOD5≤20mg/L,SS≤70mg/L,氨氮≤15mg/L,进水与出水的pH均在6~9的范围内。The effluent from the primary sedimentation tank of Beijing Beixiaohe Sewage Plant is used as the raw water. The COD Cr in the water is 200-450mg/L, the BOD 5 is 150-250mg/L, the SS is 200-400mg/L, and the ammonia nitrogen concentration is 70-90mg/L. . Using the fluidized bed process proposed in the present invention, COD Cr ≤70mg/L in the effluent, BOD 5 ≤20mg/L, SS ≤70mg/L, ammonia nitrogen ≤15mg/L, and the pH of the influent and effluent are both 6~ 9 range.
试验发现,本工艺中的流化床工艺具备在低温下运行的能力,5℃时的硝化活性为18℃时的60%左右,最佳水力停留时间为6h。试验还对流化床中污泥的微观形态结构进行了观察。污泥中细菌种类丰富,细菌排列紧密,以短杆菌为主,另外观察可见球菌、丝菌、长杆菌以及原生动物。电镜发现钟虫和等肢虫为污泥中主要的微生物。The test found that the fluidized bed process in this process has the ability to operate at low temperature, the nitrification activity at 5°C is about 60% of that at 18°C, and the optimal hydraulic retention time is 6h. The test also observed the micro-morphological structure of the sludge in the fluidized bed. There are many types of bacteria in the sludge, and the bacteria are closely arranged, mainly Brevibacteria. In addition, cocci, mycelium, longbacteria and protozoa can be observed. Electron microscopy found that bell worms and isopods were the main microorganisms in the sludge.
实施例2:工业废水中试试验Embodiment 2: industrial wastewater pilot test
甜菜制糖废水,CODCr为1000~5000mg/L,BOD5为500~3000mg/L,SS为200~1500mg/L,pH 3.5~7.5。采用本工艺中的流化床工艺处理,流化床的启动采用自然挂膜法,启动后,水力停留时间为6h,容积负荷为5.625kgCOD/m3-d。好氧流化床出水COD稳定在350mg/L左右。Sugar beet sugar wastewater, COD Cr is 1000-5000mg/L, BOD 5 is 500-3000mg/L, SS is 200-1500mg/L, pH 3.5-7.5. Using the fluidized bed process in this process, the fluidized bed is started by the natural film-hanging method. After the start-up, the hydraulic retention time is 6h, and the volume load is 5.625kgCOD/m 3 -d. The COD of the effluent of the aerobic fluidized bed is stable at about 350mg/L.
实施例3:实际运行的污水处理工程Embodiment 3: Sewage treatment project in actual operation
清华大学核研院,污水性质为生活污水和实验废水,设计水量30m3/h,进水水质DOC为5~7mg/L,UV254为15~20m-1,总磷4~5mg/L,氨氮28~30mg/L,NO3-N为3~7mg/L。采用本发明所提出工艺进行处理,曝气生物流化床填充新型柱状空心填料,比表面积达1040m2/m3,汽水比12.75∶1。出水浊度<1,DOC<3mg/L,UV254为10~11m-1,TP<0.05mg/L,氨氮2~5mg/L,NO3-N为3~5mg/L。出水满足GB/T 18920-2002水质标准,可以用作城市杂用等用途。Tsinghua University Institute of Nuclear Research, the nature of sewage is domestic sewage and experimental wastewater, the design water volume is 30m 3 /h, the influent water quality is DOC 5-7mg/L, UV254 is 15-20m -1 , total phosphorus 4-5mg/L, ammonia nitrogen 28~30mg/L, NO 3 -
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| CN103449659B (en) * | 2013-07-23 | 2014-12-24 | 宁波清天地环境工程有限公司 | Novel partial nitrification-denitrification biological nitrogen removal device |
| CN104528968A (en) * | 2014-10-20 | 2015-04-22 | 苏州富奇诺水治理设备有限公司 | Treatment system for living sewage |
| CN106045015B (en) * | 2016-07-26 | 2019-02-12 | 南京柯若环境技术有限公司 | A multi-stage tubular cyclone oxygenation biological filter sewage treatment system and treatment method |
| CN106145567A (en) * | 2016-09-10 | 2016-11-23 | 安徽蓝鼎环保能源科技有限公司 | A kind of decentralized type sewage processes and regeneration technology |
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| CN113213618A (en) * | 2021-03-09 | 2021-08-06 | 中国环境科学研究院 | Tail end treatment system and method for purifying urban non-point source organic pollution |
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