CN103449658B - Sewage treatment method - Google Patents
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Abstract
Description
技术领域: Technical field:
本发明涉及一种分散式生活污水的处理方法,尤其涉及一种疗养院、大型酒店宾馆、休闲旅游度假村、风景区山庄、高速公路服务区等生活污水的处理方法。The invention relates to a treatment method for distributed domestic sewage, in particular to a treatment method for domestic sewage in sanatoriums, large hotels, leisure resorts, villas in scenic spots, expressway service areas, and the like.
背景技术 Background technique
我国《水污染防治法》规定对不能纳入城市污水收集系统的居民区、旅游景点、度假村、疗养院、机场、铁路车站、经济开发区等分散的人群聚居地排放的污水和独立工矿区的工业废水应就地处理达标排放。疗养院、大型酒店宾馆、大型饭店、休闲旅游度假村、风景区山庄、高速公路服务区都是分散式生活污水排放源。疗养院、度假村、山庄一般都依山傍水,远离城市,无法与城市排水管网相连。另外还涉及敏感水体,因此排放的标准要求很高,如果实现达标排放,污水处理设施的投资会很大,运行费用也会相应提高。my country's "Water Pollution Prevention Law" stipulates that the sewage discharged from residential areas, tourist attractions, resorts, sanatoriums, airports, railway stations, economic development zones and other scattered crowd settlements that cannot be included in the urban sewage collection system and industrial wastewater from independent industrial and mining areas Standardized discharge should be treated locally. Nursing homes, large hotels, large restaurants, leisure tourism resorts, scenic villas, and expressway service areas are all distributed domestic sewage discharge sources. Nursing homes, resorts, and mountain villas are generally located near mountains and rivers, far away from cities, and cannot be connected to urban drainage pipe networks. In addition, sensitive water bodies are also involved, so the discharge standards are very high. If the discharge meets the standards, the investment in sewage treatment facilities will be large, and the operating costs will increase accordingly.
疗养院等分散式生活污水的水质一般包括厨房餐厅排水;洗浴、盥洗、洗衣排水和卫生间排水,与生活污水水质相比,油、洗涤剂、氮、磷等待处理的污染物含量会较高,具有水量变化大,水质复杂,难处理等特点。此类水质变化幅度较大,化学需氧量(COD):300~500mg/L;氨氮(NH3-N):20~60mg/L;总磷(TP):2.6~3.7mg/L;悬浮物(SS):200~500mg/L。由于无法与城市排水管网相连,即使经过生物处理,达到《城镇污水处理厂污染物排放标准GB18918-2002》中的一级A类标准,排入水体也将对环境造成较大影响。The water quality of distributed domestic sewage such as nursing homes generally includes kitchen and restaurant drainage; bathing, washing, laundry drainage and toilet drainage. The water volume changes greatly, the water quality is complicated, and it is difficult to handle. The quality of this kind of water changes greatly, chemical oxygen demand (COD): 300~500mg/L; ammonia nitrogen (NH 3 -N): 20~60mg/L; total phosphorus (TP): 2.6~3.7mg/L; Substance (SS): 200~500mg/L. Since it cannot be connected to the urban drainage pipe network, even if it reaches the first-class A standard in the "Pollutant Discharge Standard for Urban Sewage Treatment Plant GB18918-2002" after biological treatment, it will have a great impact on the environment if it is discharged into the water body.
目前该类污水多采用膜生物反应器(Membrane Bioreactor,MBR)工艺处理,处理后可达到相关标准进行排放或回用。膜生物反应器结合了传统的生物处理工艺和膜分离技术,是一种由膜过滤取代传统生化处理技术中二次沉淀池和砂滤池的水处理技术。膜生物反应器以膜单元(超滤膜或微滤膜)取代二沉池,所有悬浮物和胶体都被膜分离截留,污泥的沉降性不会影响到出水水质。同时,膜分离单元增加了曝气池中活性污泥的浓度、提高了生物降解的速率,并减少了剩余污泥的产生量。At present, this kind of sewage is mostly treated by Membrane Bioreactor (MBR) process, and after treatment, it can meet the relevant standards for discharge or reuse. Membrane bioreactor combines traditional biological treatment process and membrane separation technology. It is a water treatment technology that replaces secondary sedimentation tank and sand filter tank in traditional biochemical treatment technology by membrane filtration. The membrane bioreactor replaces the secondary sedimentation tank with a membrane unit (ultrafiltration membrane or microfiltration membrane). All suspended solids and colloids are separated and retained by the membrane, and the sedimentation of the sludge will not affect the quality of the effluent. At the same time, the membrane separation unit increases the concentration of activated sludge in the aeration tank, increases the rate of biodegradation, and reduces the amount of excess sludge generated.
膜生物反应器(MBR)目前缺点在于膜堵塞问题,反冲洗问题,由此造成运行保养困难,从而造成膜的寿命短,又因为膜的价格比较昂贵,因此运行费用高!The current disadvantage of membrane bioreactor (MBR) lies in the problem of membrane clogging and backwashing, which makes operation and maintenance difficult, resulting in short life of the membrane, and because the price of the membrane is relatively expensive, the operating cost is high!
膜堵塞的原因在于,餐饮废水中的营养成分主要是油、淀粉、蛋白质等,经过微生物的分解、吸收作用,将其转变成能量和自身的一部分。微生物正常代谢会产生粘性多糖类物质、粘性多肽分子和蛋白质分子等。细菌死亡后,这些物质一部分可被其它微生物所利用,一部分可能存在于活性污泥混合液中。同样,来自餐饮废水的少量无机盐也会部分被细菌等微生物摄入,剩余部分也存在于活性污泥混合液中。这些残留在污泥混合液中的成分,最终到达膜表面,形成了堵塞膜的凝胶层。The reason for the clogging of the membrane is that the nutrients in the catering wastewater are mainly oil, starch, protein, etc., which are transformed into energy and a part of itself through the decomposition and absorption of microorganisms. The normal metabolism of microorganisms will produce viscous polysaccharides, viscous polypeptide molecules and protein molecules. After the bacteria die, some of these substances can be used by other microorganisms, and some of them may exist in the activated sludge mixture. Similarly, a small amount of inorganic salts from catering wastewater will be partly ingested by microorganisms such as bacteria, and the rest will also exist in the activated sludge mixture. These components remaining in the sludge mixture eventually reach the membrane surface and form a gel layer that clogs the membrane.
CN1994937介绍了一种宾馆污水气浮-富氧生物处理与回用方法。其工艺流程是:污水经调节池、厌氧水解池、气浮池、富氧生物接触氧化池、活性炭滤池、二氧化氯消毒池,达到回用水的指标。工艺中需要投加聚合氯化铝,进行混凝,经过气浮后,产生大量的浮渣。造成固体废物的污染。CN1994937 introduces a hotel sewage air flotation-oxygen-enriched biological treatment and reuse method. Its technological process is as follows: the sewage passes through the regulating tank, anaerobic hydrolysis tank, air flotation tank, oxygen-enriched biological contact oxidation tank, activated carbon filter tank, and chlorine dioxide disinfection tank to reach the target of reuse water. In the process, polyaluminum chloride needs to be added for coagulation, and after air flotation, a large amount of scum is produced. Contamination of solid waste.
发明内容 Contents of the invention
本发明的目的是提供一种分散式生活污水的处理方法,特别是分散式餐饮住宿服务性场所污水的处理方法,该方法可以保证该类污水的有效处理,可以安全地实现污水回用,实现污水的零排放。该种废水经过处理后,出水可达到《城市污水再生利用城市杂用水水质》(GB/T18920-2002),最严格的主要指标为:五日生化需氧量BOD5≤10mg/L;悬浮固体≤10mg/L;浊度≤10度;色度≤30度;pH:6.0~9.0;总大肠菌群≤3个/L;嗅:无不快感觉;游离余氯:管网末端不少于0.2mg/L。出水全部作为中水进行回用。The purpose of the present invention is to provide a decentralized treatment method for domestic sewage, especially a decentralized treatment method for sewage in catering and accommodation service places. This method can ensure the effective treatment of such sewage, and can safely realize sewage reuse and realize Zero discharge of sewage. After this kind of wastewater is treated, the effluent can reach the "Water Quality of Urban Miscellaneous Water for Recycling of Urban Sewage" (GB/T18920-2002). The most stringent main indicators are: five-day biochemical oxygen demand BOD 5 ≤10mg/L; suspended solids ≤10mg/L; turbidity≤10 degrees; chromaticity≤30 degrees; pH: 6.0~9.0; total coliforms ≤3/L; smell: no unpleasant feeling; mg/L. All the effluent is reused as reclaimed water.
污水处理后的出水除了回用于生活杂用水外,剩余中水排入景观河、人工湖或水景类水体,执行再生水用于景观水体的水质标准GB18921-2002。采用该工艺出水水质全部达到《城市污水再生利用景现环境用水水质》中观赏性景观环境用水最严格的水景类的标准中:五日生化需氧量(BOD5)≤6;悬浮物(SS)≤10;总磷(以P计)≤0.5;总氮≤15;氨氮(以N计)≤5;色度(度)≤30;粪大肠菌群(个/L)≤2000;石油类≤1.0。The effluent after sewage treatment is not only reused for domestic miscellaneous water, but the remaining reclaimed water is discharged into landscape rivers, artificial lakes or waterscape water bodies, and the water quality standard GB18921-2002 for reclaimed water used in landscape water bodies is implemented. The effluent water quality of this process has all reached the most stringent waterscape standard for ornamental landscape environmental water in the "Urban Sewage Recycling Scenery Environmental Water Quality": five-day biochemical oxygen demand (BOD 5 ) ≤ 6; suspended solids (SS ) ≤ 10; total phosphorus (in P) ≤ 0.5; total nitrogen ≤ 15; ammonia nitrogen (in N) ≤ 5; chroma (degree) ≤ 30; ≤1.0.
本发明所述的污水处理方法采取的技术方案为:该类分散式生活污水经过格栅、隔油池、水解酸化池、初沉池、缺氧生化池、好氧生化池、二沉池、清水池、生物活性炭反应器、臭氧接触池,出水全部回用。The technical scheme adopted by the sewage treatment method of the present invention is: the distributed domestic sewage passes through the grid, the grease trap, the hydrolytic acidification pond, the primary sedimentation pond, the anoxic biochemical pond, the aerobic biochemical pond, the secondary sedimentation pond, Clean water pool, biological activated carbon reactor, ozone contact pool, all effluents are reused.
其具体步骤如下:The specific steps are as follows:
经过构筑物化粪池的生活污水经过管线进入废水处理站。因污水中含有一定量的大颗粒悬浮物和漂浮物,在污水进入隔油池前先经过一道机械格栅将这些大颗粒及漂浮物拦截去除,经过机械格栅粗过滤的污水进入隔油池,再进入水解酸化池。The domestic sewage passing through the septic tank of the structure enters the wastewater treatment station through the pipeline. Because the sewage contains a certain amount of large particle suspended matter and floating matter, before the sewage enters the grease trap, these large particles and floating matter are intercepted and removed by a mechanical grille, and the sewage that has been roughly filtered by the mechanical grille enters the grease trap , and then into the hydrolytic acidification tank.
在水解酸化池,将污水中的大分子有机物分解为小分子有机物,去除部分COD,减轻后续好氧生物处理的负荷。池底设有穿孔管曝气器,通入空气,既能防止污泥沉积,又能起到均化水质和预曝气作用;在池中设置组合填料,组合填料由塑料半软性填料与纤维软性填料组成。通过微生物作用,起到一定的水解酸化作用。In the hydrolytic acidification tank, the macromolecular organic matter in the sewage is decomposed into small molecular organic matter, part of COD is removed, and the load of subsequent aerobic biological treatment is reduced. There is a perforated tube aerator at the bottom of the pool, and the air is introduced, which can not only prevent sludge deposition, but also play a role in homogenizing water quality and pre-aeration; a combined packing is set in the pool, and the combined packing is composed of plastic semi-soft packing and Composed of fiber soft filler. Through the action of microorganisms, it plays a certain role in hydrolysis and acidification.
污水在水解酸化池内通过进水提升泵提升到初沉池,进行泥水分离,污泥在污泥斗内沉积浓缩,依靠液体压力通过污泥阀排入储泥池。上部澄清液通过溢流堰自流进入缺氧生化池;自初沉池来的污水与从好氧生化池回流的硝化液,在缺氧生化池中发生反硝化反应,出水自流进入好氧生化池。自缺氧生化池来的污水在好氧生化池内曝气进行好氧生化反应,出水一部分作为硝化液通过回流泵回流至缺氧生化池,进行反硝化反应;另一部分通过溢流堰自流进入二沉池。自好氧生化池来的污水在二沉池内进行泥水分离,污泥在二沉池的污泥斗内沉积浓缩,依靠液体压力通过污泥阀排入储泥池。上部澄清液通过溢流堰自流进入清水池。储泥池内的部分污泥回流到水解酸化池,进行水解,使剩余污泥减量化,同时增加剩余污泥的沉降性能。储泥池可定期排泥,污泥经脱水后,以绿化用土的方式回归自然。The sewage in the hydrolysis acidification tank is lifted to the primary sedimentation tank through the inflow lift pump, and the sludge and water are separated. The sludge is deposited and concentrated in the sludge hopper, and is discharged into the sludge storage tank through the sludge valve by the liquid pressure. The upper clarified liquid flows into the anoxic biochemical tank by itself through the overflow weir; the sewage from the primary sedimentation tank and the nitrifying liquid returned from the aerobic biochemical tank undergo denitrification reaction in the anoxic biochemical tank, and the effluent flows into the aerobic biochemical tank by gravity . The sewage from the anoxic biochemical tank is aerated in the aerobic biochemical tank for aerobic biochemical reaction, and part of the effluent is returned to the anoxic biochemical tank as nitrification liquid through the reflux pump for denitrification; the other part flows into the secondary tank through the overflow weir. Shenchi. Sewage from the aerobic biochemical tank is separated from mud and water in the secondary settling tank, and the sludge is deposited and concentrated in the sludge hopper of the secondary settling tank, and is discharged into the sludge storage tank through the sludge valve relying on liquid pressure. The upper clarified liquid flows into the clear water tank by itself through the overflow weir. Part of the sludge in the sludge storage tank is returned to the hydrolysis acidification tank for hydrolysis to reduce the excess sludge and increase the settling performance of the excess sludge. The sludge storage tank can discharge sludge regularly, and after dehydration, the sludge returns to nature in the form of greening soil.
缺氧生化池和好氧生化池内均设置组合填料。组合填料由塑料半软性填料与纤维软性填料组成,综合了半软性填料布气、布水均匀和软性填料比表面积大、挂膜快的优点。Both the anoxic biochemical pool and the aerobic biochemical pool are provided with combined fillers. The combined filler is composed of plastic semi-soft filler and fiber soft filler, which combines the advantages of semi-soft filler with air distribution, uniform water distribution and soft filler with large specific surface area and fast film formation.
自二沉池来的出水自流到清水池,然后用过滤泵输送到生物活性炭反应器,水从生物活性炭反应器的底部进入,两个生物活性炭反应器并联,内置活性碳,出水通过顶部溢流堰自流到臭氧接触池。The effluent from the secondary settling tank flows to the clear water tank by itself, and then is transported to the biological activated carbon reactor by a filter pump. The water enters from the bottom of the biological activated carbon reactor. The two biological activated carbon reactors are connected in parallel, with built-in activated carbon, and the effluent flows through the top overflow. The weir flows to the ozone contact tank.
自生物活性炭反应器来的清水在臭氧接触池内,与从臭氧发生器里产生的臭氧气体通过消毒气体分配器在臭氧接触池内充分混合接触,消毒达标后进行回用。回用范围为冲洗厕所、冲洗汽车、绿化以及景观水体等。The clean water from the biological activated carbon reactor is fully mixed and contacted with the ozone gas generated from the ozone generator in the ozone contact tank through the disinfection gas distributor in the ozone contact tank, and reused after the disinfection reaches the standard. The scope of reuse includes toilet flushing, car flushing, greening and landscape water bodies, etc.
本装置采用的深度处理是生物活性炭反应器,内置活性碳,污水经传统的二级处理以后,虽然绝大部分悬浮物和有机物被去除了,但还残留微量的悬浮固体和溶解的有害物,如氮和磷等化合物。采用底部曝气运行方式进一步去除COD、N、P等化合物,使出水达到回用的标准。活性炭可为颗粒状活性炭和柱状活性炭,优选颗粒状活性炭。The advanced treatment adopted by this device is a biological activated carbon reactor with built-in activated carbon. After the sewage is treated through the traditional secondary treatment, although most of the suspended solids and organic matter are removed, there are still traces of suspended solids and dissolved harmful substances. compounds such as nitrogen and phosphorus. The bottom aeration operation mode is adopted to further remove COD, N, P and other compounds, so that the effluent can meet the reuse standard. Activated carbon can be granular activated carbon and columnar activated carbon, preferably granular activated carbon.
本装置采用的消毒剂是臭氧,臭氧是一种强氧化剂,能与废水中大多数有机物及微生物迅速作用,对除臭、脱色、杀菌、除酚、氰、铁、锰、降低COD、BOD5等具有显著的效果。The disinfectant used in this device is ozone. Ozone is a strong oxidant that can quickly react with most organic matter and microorganisms in wastewater to deodorize, decolorize, sterilize, remove phenol, cyanide, iron, manganese, and reduce COD and BOD 5 etc. have a significant effect.
本发明的有益效果:(1)操作简单,维护费用低,较易实现自动化运行;(2)处理效果稳定,产泥量少,剩余污泥采用回归自然的处理方法用于绿化用土。(3)与环境协调性好,处理后的污水可以回用景观用水和绿化用水。不仅节约大量的排污费,又减少环境污染,具有较高的经济效益和环境效益。Beneficial effects of the invention: (1) simple operation, low maintenance cost, and easy automatic operation; (2) stable treatment effect, less sludge production, and the remaining sludge is used for greening soil by returning to nature. (3) It is well coordinated with the environment, and the treated sewage can be reused for landscape water and green water. It not only saves a lot of sewage charges, but also reduces environmental pollution, and has high economic and environmental benefits.
附图说明 Description of drawings
图1工艺流程简图。Figure 1 is a schematic diagram of the process flow.
具体实施方式 Detailed ways
实施例1Example 1
某疗养院废水水质见表1,采用本发明的图1工艺流程系统进行处理,处理结果如表1所示。The water quality of certain nursing home wastewater is shown in Table 1, and the process flow system of Fig. 1 of the present invention is adopted for processing, and the processing results are as shown in Table 1.
表1某疗养院污水水质特征及处理效果(mg/L)Table 1 Water quality characteristics and treatment effect of sewage in a sanatorium (mg/L)
实施例2Example 2
某酒店餐饮废水,其处理前水质指标和处理后出水效果见表2。Table 2 shows the water quality index before treatment and the effluent effect after treatment of a hotel's catering wastewater.
表2某酒店餐饮废水污水水质特征及处理效果(mg/L)Table 2 Water quality characteristics and treatment effect of catering wastewater in a hotel (mg/L)
实施例3Example 3
某旅游渡假区餐饮废水,其处理前水质指标和处理后出水效果见表3。Table 3 shows the water quality index before treatment and the effluent effect after treatment of catering wastewater in a tourist resort.
表3某旅游渡假区餐饮废水水质特征及处理效果(mg/L)Table 3 Water quality characteristics and treatment effect of catering wastewater in a tourist resort area (mg/L)
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