CN101961203A - Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof - Google Patents

Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof Download PDF

Info

Publication number
CN101961203A
CN101961203A CN2009101089346A CN200910108934A CN101961203A CN 101961203 A CN101961203 A CN 101961203A CN 2009101089346 A CN2009101089346 A CN 2009101089346A CN 200910108934 A CN200910108934 A CN 200910108934A CN 101961203 A CN101961203 A CN 101961203A
Authority
CN
China
Prior art keywords
microcrystalline
crystallite
resistant
faience
environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2009101089346A
Other languages
Chinese (zh)
Other versions
CN101961203B (en
Inventor
肖绍辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENZHEN KEYKING TECHNOLOGY Co Ltd
Original Assignee
SHENZHEN KEYKING TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENZHEN KEYKING TECHNOLOGY Co Ltd filed Critical SHENZHEN KEYKING TECHNOLOGY Co Ltd
Priority to CN2009101089346A priority Critical patent/CN101961203B/en
Publication of CN101961203A publication Critical patent/CN101961203A/en
Application granted granted Critical
Publication of CN101961203B publication Critical patent/CN101961203B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Abstract

The invention relates to an environmental-friendly heat-resistant microcrystal color ceramic container and a manufacturing method thereof. The ceramic container comprises a blank, an outer microcrystal glaze layer sintered on the outer surface of the blank, and an inner microcrystal glaze layer on the inner surface of the blank, wherein the outer surface of the outer microcrystal glaze layer also comprises a pattern layer formed by sintering patterned carbon fiber film decal attached to the outer surface of the outer microcrystal glaze layer. The environmental-friendly heat-resistant microcrystal color ceramic container is quick on heat conduction and uniform on heating, does not generate lampblack within 250 DEG C, has the advantages of good environmental protection performance, stable physical and chemical performance at high temperature, high surface density and poor viscosity to pans, does not decompose substances harmful to human health, and is superior to the traditional enamel pans on the properties of high density, wear resistance, heat-resistant stability, impact resistance, corrosion resistance and contamination resistance.

Description

Environment-friendly heat-resistant crystallite faience vessel and manufacture method thereof
Technical field
The present invention relates to a kind of kitchen utensils, more particularly, relate to a kind of environment-friendly heat-resistant crystallite faience vessel and manufacture method thereof.
Background technology
Though modern kitchen apparatus kind is a lot, the high-quality frying pan that is suitable for the Chinese cooking mode but seldom.The easy oil smoke that glues pot and can produce the people that chokes when traditional iron pan is cooked.And non-stick pan commonly used in recent years generally all is limited in 250 ℃ to use down owing to contain the Teflon material in the coating, is higher than this temperature, and coating can decomposite the material of harmful health.And Chinese cooking method major part is quick-fried, and temperature usually is higher than 250 ℃, should not use the non-stick pan of Teflon material.In addition, existing enamel ware since raw material and manufacturing process be prone in use and take off porcelain, crackle, cut etc., and heat-resistant stability, wear-resisting, impact resistance is poor.
Thereby, need a kind of heat-resistant stability of exploitation, shock-resistant, wear-resisting, fine corrosion resistance, be difficult for producing oil smoke, durable cooking ware.
Summary of the invention
The technical problem to be solved in the present invention is, at the existing defective of above-mentioned frying pan of prior art, provides a kind of environment-friendly heat-resistant crystallite faience vessel.The present invention also provides a kind of manufacture method of environment-friendly heat-resistant crystallite faience vessel.
The technical solution adopted for the present invention to solve the technical problems is: construct a kind of environment-friendly heat-resistant crystallite faience vessel, comprise base substrate, sintering at the outer microcrystalline glaze layer of described base substrate outer surface and the sintering interior microcrystalline glaze layer at described base substrate inner surface, described outer microcrystalline glaze layer and interior microcrystalline glaze layer mainly comprise the raw material of following parts by weight:
SiO 250-75 part;
B 2O 30-6 part;
Al 2O 30-20 part;
Na 2O and/or K 2O+Li 2O 8-23 part;
CaO and/or MgO 1-5 part;
P 2O 50.8-5.5 part;
TiO 22-15 part;
ZrO 20-8 part;
CeO 20-10 part;
CoO 0-1.25 part;
NiO 0-1.5 part;
MnO 20-1.5 part;
NaSiF 20-3 part.
In environment-friendly heat-resistant crystallite faience vessel of the present invention, described base substrate is made by the cold-rolled steel sheet material, and its thickness is 1.00～1.2mm.
In environment-friendly heat-resistant crystallite faience vessel of the present invention, described base substrate is made by cast iron materials, and its thickness is 2.5～5.0mm.
In environment-friendly heat-resistant crystallite faience vessel of the present invention, described outer microcrystalline glaze layer comprises that thickness is that outer ground-coat enamel microcrystalline coating of 150～200 μ m and thickness are 150～200 μ m cover-coat enamel microcrystalline coatings, and the thickness of described interior microcrystalline glaze layer is 150～200 μ m.
In environment-friendly heat-resistant crystallite faience vessel of the present invention, described outer microcrystalline glaze layer outer surface comprises that also one deck is pasted on the patterned layer that outer microcrystalline glaze layer outer surface forms through sintering by the carbon fiber film that has pattern.
The present invention solves another technical scheme that its technical problem adopts: a kind of manufacture method of environment-friendly heat-resistant crystallite faience vessel is provided, comprises;
The preparation base substrate;
Preparation microcrystalline glaze piece;
The heat-resisting glaze piece of interpolation, mill addition, water mixing and ball milling are made the crystallite glaze slip in the microcrystalline glaze piece;
Outer surface and inner surface coating crystallite glaze slip ground-coat enamel and sintering at described base substrate;
Coating crystallite glaze slip cover-coat enamel and sintering on the ground-coat enamel behind the sintering;
Wherein, described preparation microcrystalline glaze piece comprises:
Following raw materials by weight portion prepared burden and mix:
SiO 250-75 part;
B 2O 30-6 part;
Al 2O 30-20 part;
Na 2O and/or K 2O+Li 2O 8-23 part;
CaO+MgO 1-5 part;
P 2O 50.8-5.5 part;
TiO 22-15 part;
ZrO 20-8 part;
CeO 20-10 part;
CoO 0-1.25 part;
NiO 0-1.5 part;
MnO 20-1.5 part;
NaSiF 20-3 part;
With mixed raw materials at 1250-1350 ℃ of high temperature melting;
Quenching;
Oven dry;
Corase grind;
The crystal coring is handled the back and is become the microcrystalline glaze piece.
In the manufacture method of environment-friendly heat-resistant crystallite faience vessel of the present invention, the temperature that described crystal coring is handled is that 570 ± 10 ℃, time are 60-400 minute.
In the manufacture method of environment-friendly heat-resistant crystallite faience vessel of the present invention, described heat-resisting glaze piece comprises following compositions in portion by weight:
SiO 263-80 part;
Na 2O 8-17 part;
K 2O 0-7 part;
Li 2O 1-5 part;
CaO 0-2 part;
MgO 0-2 part;
TiO 20-2 part;
ZrO 20-8 part;
CoO 0-1.25 part;
NiO 0-1.50 part;
MnO 20-1.50 part;
NaSiF 20-3 part.
In the manufacture method of environment-friendly heat-resistant crystallite faience vessel of the present invention, described sintering temperature is 900 ± 10 ℃, sintering time 1-15 minute.
In the manufacture method of environment-friendly heat-resistant crystallite faience vessel of the present invention, the surface that is included in the outer microcrystalline glaze layer of described vessel attaches and has the carbon fiber film of pattern, and inserts in the sintering furnace at 800-900 ℃ of following decorated fire time 2-4 minute.
Implement environment-friendly heat-resistant crystallite faience vessel of the present invention, have following beneficial effect: heat conduction rapidly, be heated evenly, can not produce oil smoke, good environmental protection at 250 ℃ with interior; And at high temperature have stable physics, chemical property, can not decomposite the material of harmful health; The superficial density height is difficult for sticking pot.
In addition, environment-friendly heat-resistant crystallite faience vessel of the present invention have the mechanical performance higher than common enamel product, and density height, wear-resisting, heat-resistant stability, impact resistance, corrosion-resistant, antifouling property all are better than traditional enamel pan.Hardness: reach Mohs 8-9 level, anti-burning: dry combustion method is 300 ℃-400 ℃ on the electromagnetic oven, and flawless does not take off porcelain, the heatproof acute degeneration: product by heating swashs flawless suddenly with 20 ℃ of water and does not take off porcelain to 325-400 ℃.Product high temperature uses nondiscolouring, and is easy to clean.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples, in the accompanying drawing:
Fig. 1 is the structural representation of environment-friendly heat-resistant crystallite faience vessel one embodiment according to the present invention;
Fig. 2 is the flow chart of environment-friendly heat-resistant crystallite faience vessel manufacture method of the present invention;
Fig. 3 is the flow chart of the microcrystalline glaze method for preparing raw material of the heat-resisting crystallite faience of guarantor's type of the present invention vessel.
The specific embodiment
In the embodiment shown in fig. 1, environment-friendly heat-resistant crystallite faience vessel of the present invention comprise three layers, and to be interior microcrystalline glaze layer 1, the second layer (being the intermediate layer) be outer microcrystalline glaze layer 3 for the green body layer 2 of vessel, the 3rd layer to ground floor.In another embodiment of the present invention, outer microcrystalline glaze layer 3 further comprises outer ground-coat enamel microcrystalline coating and cover-coat enamel microcrystalline coating (not shown).Wherein, the thickness of interior microcrystalline glaze layer can be that the thickness of 150～200 μ m, outer ground-coat enamel microcrystalline coating is that 150～200 μ m and cover-coat enamel microcrystalline coating thickness are 150～200 μ m.The purpose of control porcelain thickness is the physicochemical property that guarantees product, as: resistance to impact, anti-burning, heatproof acute degeneration.Improve adherence, promptly improve the combination degree between ground glaze layer and the metal level.
The intermediate layer base substrate can be made by steel plate materials, and its thickness can be chosen as 1.00～1.2mm.As another selection, the intermediate layer base substrate also can be made by cast iron materials, and thickness can be selected at 2.5～5.0mm as required.
In one embodiment of this invention, outer microcrystalline glaze layer outer surface also comprises a patterned layer, and this patterned layer is that the carbon fiber film that will have pattern is pasted on outer microcrystalline glaze layer outer surface after sintering and forming.
As shown in Figure 2, the flow process of environment-friendly heat-resistant crystallite faience vessel manufacture method of the present invention comprise body preparation 21, crystallite glaze slip preparation 30, be coated with glaze and sintering 22, operations such as design producing 23, the total inspection 24 of back dress.
Wherein:
Body preparation 21 operations comprise: base, base substrate check, pickled surface are handled, base substrate is dried and the check of clean base.
Be coated with glaze and sintering 22 operations comprise: be coated with crystallite ground-coat enamel, ground-coat enamel oven dry, ground-coat enamel burn till, be coated with crystallite cover-coat enamel, cover-coat enamel oven dry, scrape mend powder, cover-coat enamel burns till and the plain color product inspection.In one embodiment of this invention, interior microcrystalline glaze layer 1 coating sintering one deck microcrystalline glaze and outer microcrystalline glaze layer 3 burns one deck cover-coat enamel that reburns behind one deck ground-coat enamels.As selection, interior microcrystalline glaze layer 1 of environment-friendly heat-resistant crystallite faience vessel of the present invention and outer microcrystalline glaze layer 3 be coating sintering one deck microcrystalline glaze all.As another selection, microcrystalline glaze layer 1 and outer microcrystalline glaze layer 3 in the environment-friendly heat-resistant crystallite faience vessel of the present invention all burn one deck cover-coat enamel that reburns behind one deck ground-coat enamel.
In actual fabrication, the composition of the crystallite glaze slip of ground-coat enamel and cover-coat enamel is slightly had any different.Generally, do not contain or only contain a spot of milkiness composition in the ground-coat enamel, like this with base substrate to combine firmness higher.
Design producing 23 operations comprise: applique, drying, decorated fire and check.
The back total inspection of dress 24 operations comprise: bound edge assembles, always examines and pack warehouse-in.
The crystallite glaze slip prepares 30 methods as shown in Figure 3, at first prepare the microcrystalline glaze piece, comprise: feedstock analysis, batching, mixing, the detection uniformity, found, the oven dry of discharging hardening, glaze piece, glaze piece corase grind, glaze piece crystallization are handled, cool off behind the crystallization, obtain the microcrystalline glaze piece.Then, preparation crystallite glaze slip, be included in the microcrystalline glaze piece and add mixing and ball milling after heat-resisting glaze piece, mill addition and the water (by weight umber: microcrystalline glaze piece 40-70 part, heat-resisting glaze piece 30-60 part, mill addition 1-20 part, water 40-60 part) and make the crystallite glaze slip, wherein the composition of microcrystalline glaze piece raw material contains (weight ratio):
SiO 250-75 part;
B 2O 30-6 part;
Al 2O 30-20 part;
Na 2O and/or K 2O+Li 2O 8-23 part;
CaO and/or MgO 1-5 part;
P 2O 50.8-5.5 part;
TiO 22-15 part;
ZrO 20-8 part;
CeO 20-10 part;
CoO 0-1.25 part;
NiO 0-1.5 part;
MnO 20-1.5 part;
NaSiF 20-3 part.
Wherein, heat-resisting glaze piece comprises following compositions in portion by weight:
SiO 263-80 part;
Na 2O 8-17 part;
K 2O 0-7 part;
Li 2O 1-5 part;
CaO 0-2 part;
MgO 0-2 part;
TiO 20-2 part;
ZrO 20-8 part;
CoO 0-1.25 part;
NiO 0-1.50 part;
MnO 20-1.50 part;
NaSiF 20-3 part.
In one embodiment of this invention, microcrystalline glaze piece raw material comprises following compositions in portion by weight:
SiO 250 parts;
B 2O 36 parts;
Al 2O 312 parts;
Na 2O+K 2O+Li 218 parts of O;
3 parts of CaO;
P 2O 54 parts;
TiO 22 parts;
ZrO 21 part;
CeO 22 parts;
0 part of CoO;
0 part of NiO;
MnO 21.5 part;
F 23 parts.
In one embodiment of this invention, microcrystalline glaze piece raw material comprises following compositions in portion by weight:
SiO 275 parts;
B 2O 32 parts;
Al 2O 30 part;
K 2O+Li 28 parts of O;
1 part of CaO+MgO;
P 2O 55.5 part;
TiO 210 parts;
ZrO 20 part;
CeO 210 parts;
1.25 parts of CoO;
1.5 parts of NiO;
MnO 20.5 part;
F 22 parts.
In one embodiment of this invention, microcrystalline glaze piece raw material comprises following compositions in portion by weight:
SiO 260 parts;
B 2O 30 part;
Al 2O 320 parts;
Na 223 parts of O;
5 parts of MgO;
P 2O 50.8 part;
TiO 215 parts;
ZrO 28 parts;
CeO 20 part;
0.7 part of CoO;
0.9 part of NiO;
MnO 20 part;
F 20 part.
In one embodiment of this invention, heat-resisting glaze piece comprises following compositions in portion by weight:
SiO 263 parts;
Na 215 parts of O;
K 22 parts of O;
Li 23 parts of O;
0 part of CaO;
2 parts of MgO;
TiO 21 part;
ZrO 20 part;
1 part of CoO;
0.5 part of NiO;
MnO 20.18 part;
NaSiF 21 part.
In one embodiment of this invention, heat-resisting glaze piece comprises following compositions in portion by weight:
SiO 270 parts;
Na 217 parts of O;
K 27 parts of O;
Li 21 part of O;
2 parts of CaO;
1 part of MgO;
TiO 20 part;
ZrO 28 parts;
0 part of CoO;
1.5 parts of NiO;
MnO 20 part;
NaSiF 23 parts.
In one embodiment of this invention, heat-resisting glaze piece comprises following compositions in portion by weight:
SiO 280 parts;
Na 28 parts of O;
K 20 part of O;
Li 25 parts of O;
1 part of CaO;
0 part of MgO;
TiO 22 parts;
ZrO 24 parts;
1.25 parts of CoO;
0 part of NiO;
MnO 21.5 part;
NaSiF 20 part.
Table one is three embodiment of the weight item ratio of various materials during with microcrystalline glaze piece, heat-resisting glaze piece, mill addition and water mixing and ball milling for preparation crystallite glaze slip.
Table one
Composition First embodiment Second embodiment The 3rd embodiment
The microcrystalline glaze piece 40 55 70
Heat-resisting glaze piece 50 60 30
Mill addition 1 20 10
Water 40 50 60
Among the present invention, produce a kind of crystallization glaze earlier, and make it crystallization and handle (the crystal nucleation temperature generally about 570 ℃, exceeding 35 ℃) and become the microcrystalline glaze piece, and then become the crystallite glaze slip of confession metal body blackening with another heat-resisting glaze piece mixed grinding than its softening point.Metal body can be that steel plate (for example cold-rolled steel sheet) material is made also and can be made by cast iron materials as previously mentioned.
" heat-resisting crystallite faience vessel " are meant with the crystallite glaze slip and are coated on the metal body, form through 900 ℃ of high-temperature firings.Can again on the crystallite porcelain facing, attach carbon fiber pattern marble paper in addition,, carbon fiber pattern and crystallite porcelain facing be fused into one, make the vessel that have different pattern through 800-900 ℃ of high temperature sintering.
The present invention has special character on prescription composition, manufacturing process:
(1) " heat-resisting microcrystalline glaze " is environment-friendly type high-tech enamel new product, and be with common enamel difference: the prescription and the treatment process of enamel are special.Its prescription of the present invention contains TiO in forming 2, ZrO 2, CeO 2, Li 2O, F -Deng the nucleus agent, various composition raw materials mix after 1250-1350 ℃ of high temperature melting, and the oven dry corase grind is that 60-400 minute crystal coring is handled in 570 ± 10 ℃ of temperature, time in the coring stove again behind the quenching.The glaze slip made from heat-resisting microcrystalline glaze is coated on metal body, through 900 ℃ ± 10 ℃ high-temperature firing 1-15 minute (for example plate slab is that 1-3 minute, cast iron base are 4-15 minute), decorate with carbon fiber pattern marble paper again, form through 800-900 ℃ of high temperature, 2-4 branch clock time sintering.Because enamel has passed through coring (crystallization) and handled, vitreum becomes crystal, thereby wear-resisting, the hardness of enamel coating, heat-resistant stability, shock-resistant and decay resistance improve a lot.Hardness: reach Mohs 8-9 level; Anti-burning: dry combustion method is 300 ℃-400 ℃ on the electromagnetic oven, and flawless does not take off porcelain; The heatproof acute degeneration: product by heating swashs flawless suddenly with 20 ℃ of water and does not take off porcelain to 325-400 ℃.Product high temperature uses nondiscolouring, and is easy to clean.All kinds of pot such as available spades, plastic cement shovel, stainless steel shovel wooden dipper comes cooking, and does not stay cut.
(2) porcelain facing of product adopts carbon fiber graphics marble paper, enamel, the additive of environment-friendly type, and ornament materials meets standard, and is nontoxic to human body, adopts to add and sticks the novel uniqueness of flower process decorative effect.
(3) introduce reinforcing material such as alkali-free glass fiber powder in the microcrystalline glaze prescription, introduced good for health, the health environment-friendlies of trace element such as Fe, Se, Zn, Ca in the product internal layer glaze.
Adopt heat-resisting microcrystalline glaze among the present invention, mill addition adopts reinforcing materials such as alkali-free glass fiber powder, adopts environment-friendly type decal paper.The enamel manufacturing is adopted crystal nuclear metallization processes, product decoration to adopt and is sticked flower process.
From outside watch, the microcrystalline glaze layer evenly, continuously, the color and luster unanimity, no glaze knurl, do not have come off, no squama is quick-fried, edge dew is deceived less than 1.0mm.
Environment-friendly heat-resistant crystallite faience vessel base substrate of the present invention adopts steel plate or cast iron materials, in the middle of two-layer crystallite porcelain, form heat carrier, heat evenly is passed to the whole cooker body, the problem of Jiao that the inequality that keeps from heat is caused, burning, paste, oil smoke (can not produce oil smoke with interior) still less at 250 ℃, good environmental protection; And the superficial density height is difficult for sticking pot.And at high temperature have stable physics, chemical property, can not decomposite the material of harmful health.Adopt the present invention, because microcrystalline glaze layer heat conductivility is good, heat conduction is rapid, fully keeps the nutritional labeling of food.And the superficial density height, the superslide sense, high temperature resistant, difficult sticking, easy to clean.

Claims (10)

1. environment-friendly heat-resistant crystallite faience vessel, comprise that base substrate, sintering are at the outer microcrystalline glaze layer of described base substrate outer surface and the sintering interior microcrystalline glaze layer at described base substrate inner surface, it is characterized in that described outer microcrystalline glaze layer and interior microcrystalline glaze layer mainly comprise the raw material of following parts by weight:
SiO 250-75 part;
B 2O 30-6 part;
Al 2O 30-20 part;
Na 2O and/or K 2O+Li 2O 8-23 part;
CaO and/or MgO 1-5 part;
P 2O 50.8-5.5 part;
TiO 22-15 part;
ZrO 20-8 part;
CeO 20-10 part;
CoO 0-1.25 part;
NiO 0-1.5 part;
MnO 20-1.5 part;
NaSiF 20-3 part.
2. environment-friendly heat-resistant crystallite faience vessel according to claim 1 is characterized in that described base substrate is made by the cold-rolled steel sheet material, and its thickness is 1.00～1.2mm.
3. environment-friendly heat-resistant crystallite faience vessel according to claim 1 is characterized in that described base substrate is made by cast iron materials, and its thickness is 2.5～5.0mm.
4. according to claim 2 or 3 described environment-friendly heat-resistant crystallite faience vessel, it is characterized in that, described outer microcrystalline glaze layer comprises that thickness is that outer ground-coat enamel microcrystalline coating and the thickness of 150～200 μ m is 150～200 μ m cover-coat enamel microcrystalline coatings, described in the thickness of microcrystalline glaze layer be 150～200 μ m.
5. environment-friendly heat-resistant crystallite faience vessel according to claim 4 is characterized in that, described outer microcrystalline glaze layer outer surface comprises that also one deck is pasted on the patterned layer that outer microcrystalline glaze layer outer surface forms through sintering by the carbon fiber film that has pattern.
6. the manufacture method of environment-friendly heat-resistant crystallite faience vessel comprises;
The preparation base substrate;
Preparation microcrystalline glaze piece;
The heat-resisting glaze piece of interpolation, mill addition, water mixing and ball milling are made the crystallite glaze slip in the microcrystalline glaze piece;
Outer surface and inner surface coating crystallite glaze slip ground-coat enamel and sintering at described base substrate;
Coating crystallite glaze slip cover-coat enamel and sintering on the ground-coat enamel behind the sintering;
It is characterized in that described preparation microcrystalline glaze piece comprises:
Following raw materials by weight portion prepared burden and mix:
SiO 250-75 part;
B 2O 30-6 part;
Al 2O 30-20 part;
Na 2O and/or K 2O+Li 2O 8-23 part;
CaO+MgO 1-5 part;
P 2O 50.8-5.5 part;
TiO 22-15 part;
ZrO 20-8 part;
CeO 20-10 part;
CoO 0-1.25 part;
NiO 0-1.5 part;
MnO 20-1.5 part;
NaSiF 20-3 part;
With mixed raw materials at 1250-1350 ℃ of high temperature melting;
Quenching;
Oven dry;
Corase grind;
The crystal coring is handled the back and is become the microcrystalline glaze piece.
7. the manufacture method of environment-friendly heat-resistant crystallite faience vessel according to claim 6 is characterized in that, the temperature that described crystal coring is handled is that 570 ± 10 ℃, time are 60-400 minute.
8. the manufacture method of environment-friendly heat-resistant crystallite faience vessel according to claim 6 is characterized in that, described heat-resisting glaze piece comprises following compositions in portion by weight:
SiO 263-80 part;
Na 2O 8-17 part;
K 2O 0-7 part;
Li 2O 1-5 part;
CaO 0-2 part;
MgO 0-2 part;
TiO 20-2 part;
ZrO 20-8 part;
CoO 0-1.25 part;
NiO 0-1.50 part;
MnO 20-1.50 part;
NaSiF 20-3 part.
9. the manufacture method of environment-friendly heat-resistant crystallite faience vessel according to claim 6 is characterized in that, described sintering temperature is 900 ± 10 ℃, sintering time 1-15 minute.
10. the manufacture method of environment-friendly heat-resistant crystallite faience vessel according to claim 6, it is characterized in that, the surface that is included in the outer microcrystalline glaze layer of described vessel attaches and has the carbon fiber film of pattern, and inserts in the sintering furnace at 800-900 ℃ of following decorated fire time 2-4 minute.
CN2009101089346A 2009-07-21 2009-07-21 Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof Expired - Fee Related CN101961203B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009101089346A CN101961203B (en) 2009-07-21 2009-07-21 Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009101089346A CN101961203B (en) 2009-07-21 2009-07-21 Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof

Publications (2)

Publication Number Publication Date
CN101961203A true CN101961203A (en) 2011-02-02
CN101961203B CN101961203B (en) 2012-10-31

Family

ID=43514400

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009101089346A Expired - Fee Related CN101961203B (en) 2009-07-21 2009-07-21 Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof

Country Status (1)

Country Link
CN (1) CN101961203B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086717A (en) * 2011-10-28 2013-05-08 井手和幸 Ovenware for microwave oven
CN103096649A (en) * 2011-10-27 2013-05-08 深圳富泰宏精密工业有限公司 Shell body and preparing method thereof
CN104287643A (en) * 2014-09-17 2015-01-21 湖南嘉盛电陶新材料股份有限公司 Ceramic heating plate for egg fryer and manufacturing method thereof
CN106333609A (en) * 2016-11-15 2017-01-18 河源市源日通能源有限公司 Inner container of electric cooker and manufacturing method thereof
CN108298819A (en) * 2018-02-08 2018-07-20 赵庭玉 A kind of high-temperature enamel for high-chromium white cast iron
CN108558357A (en) * 2018-07-12 2018-09-21 邱楚芳 A kind of devitrified glass ceramics blank and the method that devitrified glass ceramics tableware is prepared using the blank
CN113789514A (en) * 2021-08-23 2021-12-14 江阴硅普搪瓷股份有限公司 Preparation method of high-temperature-resistant, wear-resistant and strong-impact-resistant anticorrosive microcrystalline glaze

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1255047B (en) * 1992-03-31 1995-10-17 Peter Thometzek CERAMIC FRIES OF HIGH BRILLIANCE
US6280863B1 (en) * 1997-06-12 2001-08-28 Ivoclar Ag Translucent apatite glass ceramic
US6132832A (en) * 1998-05-07 2000-10-17 Ferro Corporation Tile glaze
CN1303830A (en) * 1999-10-27 2001-07-18 上海凤喜搪瓷器皿有限公司 Mixed microcrystalline glaze and its baking method
CN101305884A (en) * 2007-05-18 2008-11-19 元亨福泰(天津)医药保健品有限公司 High temperature lead-free glaze health cup and its production technique

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103096649A (en) * 2011-10-27 2013-05-08 深圳富泰宏精密工业有限公司 Shell body and preparing method thereof
CN103086717A (en) * 2011-10-28 2013-05-08 井手和幸 Ovenware for microwave oven
CN104287643A (en) * 2014-09-17 2015-01-21 湖南嘉盛电陶新材料股份有限公司 Ceramic heating plate for egg fryer and manufacturing method thereof
CN104287643B (en) * 2014-09-17 2016-08-24 湖南嘉盛电陶新材料股份有限公司 A kind of egg McMuffin quick cooker ceramic heat dish and preparation method thereof
CN106333609A (en) * 2016-11-15 2017-01-18 河源市源日通能源有限公司 Inner container of electric cooker and manufacturing method thereof
CN108298819A (en) * 2018-02-08 2018-07-20 赵庭玉 A kind of high-temperature enamel for high-chromium white cast iron
CN108298819B (en) * 2018-02-08 2020-07-10 赵庭玉 High-temperature porcelain glaze for high-chromium white cast iron
CN108558357A (en) * 2018-07-12 2018-09-21 邱楚芳 A kind of devitrified glass ceramics blank and the method that devitrified glass ceramics tableware is prepared using the blank
CN113789514A (en) * 2021-08-23 2021-12-14 江阴硅普搪瓷股份有限公司 Preparation method of high-temperature-resistant, wear-resistant and strong-impact-resistant anticorrosive microcrystalline glaze
CN113789514B (en) * 2021-08-23 2023-07-28 江阴硅普搪瓷股份有限公司 Preparation method of high-temperature-resistant, wear-resistant and strong-impact-resistant anti-corrosion microcrystalline glaze

Also Published As

Publication number Publication date
CN101961203B (en) 2012-10-31

Similar Documents

Publication Publication Date Title
CN101961203B (en) Environmental-friendly heat-resistant microcrystal color ceramic container and manufacturing method thereof
EP1294651B1 (en) Enamel composition
CN105731800B (en) A kind of preparation method of anti-sticking ceramic pan
US6511931B1 (en) Easy-to-clean matte acid resistant ground coat
WO2017058418A1 (en) Pyrolytic hybrid enamel
CN107473708A (en) A kind of slow heat conduction, high-strength ceramic product and its manufacturing process
CN108083764A (en) Selenium-rich ceramic utensil and its preparation process
CN104150773A (en) Purple sand glass ceramic bowl and preparation process thereof
KR101047355B1 (en) Heat resistant ceramic ware for induction range and preparation method thereof
CN100580333C (en) Water heater porcelain enamel inner bag and manufacturing method thereof
CN105731799A (en) Copper red reduction transmutation glaze, copper red reduction transmutation glaze ceramic product and preparation method thereof
CN105819690A (en) Preparation method of polychrome enamel decor ware
JP4167015B2 (en) Lead-free enamel composition, corresponding enamel and glass-ceramic products, new lead-free mineral glass
CN103044083A (en) Transparent glaze and manufacturing method thereof
CN107573017A (en) A kind of technique for manufacturing stealthy decorative pattern ceramic
KR101911408B1 (en) Manufacturing method of enamel product
CN101913849A (en) Heat-resistant ceramic for kitchen ware
KR101978393B1 (en) Glaze composition and cooking vessel producted using the same
CN105801097A (en) Preparation method of egg-shell ceramic heat-resisting pot
CN100584793C (en) Technique for producing heat-resistance ceramic non-sticking container
CN110668785A (en) Whole body dry-pressed porcelain heating panel material for induction cooker and preparation method thereof
CN112499969B (en) Glass paste composition and preparation method and application thereof
CN111018489A (en) Bone china material for non-stick cookers, application of bone china material, non-stick cookers and manufacturing method of non-stick cookers
CN106082982A (en) A kind of boccaro polishes drips enameling method
KR102236402B1 (en) Coating method of cooking pot metal material

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20121031

Termination date: 20160721