CN101948974A - Al-Si-Mg line aluminium alloy and production technique thereof that workability is strong - Google Patents

Al-Si-Mg line aluminium alloy and production technique thereof that workability is strong Download PDF

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Publication number
CN101948974A
CN101948974A CN2010101124978A CN201010112497A CN101948974A CN 101948974 A CN101948974 A CN 101948974A CN 2010101124978 A CN2010101124978 A CN 2010101124978A CN 201010112497 A CN201010112497 A CN 201010112497A CN 101948974 A CN101948974 A CN 101948974A
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China
Prior art keywords
weight
aluminium alloy
workability
line aluminium
strong
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CN2010101124978A
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Chinese (zh)
Inventor
张桂源
金大业
李佑埴
朴相宇
吴介熙
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Hyundai Mobis Co Ltd
Aluko Co Ltd
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Hyundai Mobis Co Ltd
Dongyang Gangchul Co Ltd
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Publication of CN101948974A publication Critical patent/CN101948974A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04Modified aluminium-silicon alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/05Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Extrusion Of Metal (AREA)
  • Forging (AREA)
  • Powder Metallurgy (AREA)

Abstract

The present invention relates to 1.2~1.4 weight % of Si in the aluminium alloy gross weight, Mg 0.6~0.75 weight %, Sn0.8~1.0 weight % and all the other is that Al and impurity are the Al-Si-Mg line aluminium alloy and the production technique thereof of characteristics.Above-mentioned communication is fabulous with the workability of aluminium alloy, adds the chip volume can not take place man-hour stick up or damage problem such as machining tool, can shorten the process-cycle.Simultaneously, can significantly reduce the fraction defective of converted products, improve the converted products quality, and reduce the residual amount of burr (burr), be convenient to the removing and the cleaning of burr (burr).

Description

Al-Si-Mg line aluminium alloy and production technique thereof that workability is strong
Technical field
The present invention relates to workability strong Al-Si-Mg line aluminium alloy and production technique thereof.
Background technology
To be communication be commonly used for the fitment material such as ABS (Anti-lockBreaking system) pump housing, ESC (Electronic Stability Control) pump housing of automobile with aluminium alloy in 6000 common (Al-Mg-Si systems).
But it is unsatisfactory with the workability of aluminium alloy that common 6000 (Al-Mg-Si systems) are communication, adding the existence in man-hour can make the processing chip elongated, thereby its processed instrument volume is stuck up or increasing instrument load, cause processing bad and machining tool is impaired, and the reduction process velocity, the defectives such as quality of reduction processing object.
Therefore, the fitment material such as pump housing of ABS (Anti-lock Breaking system) pump housing or ESC (Electronic StabilityControl) use common 6000 to be to communicate by letter when using alloy, can increase the overall manufacturing cost, and reduce the quality of accessory.
Summary of the invention
The present invention is for solving the problems of the technologies described above proposition, it 6000 is the composition of communication with alloy that its purpose is to provide by changing what generally use in the past, improve its workability, thus avoid adding take place that chip volume sticks up man-hour or the high workability communication of problem such as machining tool is impaired with aluminium alloy and production method thereof.
The invention provides with 1.2~1.4 weight % of Si in the aluminium alloy gross weight, Mg 0.6~0.75 weight %, Sn0.8~1.0 weight %, and all the other are that Al and impurity are the Al-Si-Mg line aluminium alloy of characteristics.
The invention provides and comprise: Si 1.2~1.4 weight %, Mg 0.6~0.75 weight %, Sn 0.8~1.0 weight % in the constituent gross weight, and all the other are the preparatory stage of the Al-Si-Mg line aluminium alloy of Al and impurity with constituent; Above-mentioned aluminium alloy is made into the stage of semifinished product by continuous casting process with constituent; And the semifinished product that above-mentioned stage is made homogenizes the heat treated stage of thermal treatment, extruding, stretching and timeliness, and above-mentioned timeliness thermal treatment is to be processed as the production technique of the Al-Si-Mg line aluminium alloy of characteristics under 130~150 ℃ of environment.
The communication that the present invention relates to is fabulous with the workability of aluminium alloy, adds the chip volume can not take place man-hour stick up or damage problem such as machining tool, can shorten the process-cycle.Simultaneously, can significantly reduce the fraction defective of converted products, improve the converted products quality, and reduce the residual amount of burr (burr), be convenient to the removing and the cleaning of burr (burr).Therefore, the communication that the present invention relates to can significantly promote production efficiency with aluminium alloy adding man-hour, has remarkable cost-effective effect.
Description of drawings
In order to understand essence of the present invention and feature better, be elaborated below with reference to the accompanying drawings, wherein:
Fig. 1 is that the aluminium alloy test piece of producing in embodiment 1 and the reference examples 1~3 is in the situation that adds the chip in man-hour
[(a) reference examples 1, and (b) reference examples 2, and (c) reference examples 3, and (d) embodiment 1].
Embodiment
The present invention relates to 1.2~1.4 weight % of Si in the aluminium alloy gross weight, Mg 0.6~0.75 weight %, Sn0.8~1.0 weight % and all the other is that Al and impurity are the Al-Si-Mg line aluminium alloy and the production technique thereof of characteristics.
The aluminium alloy that the present invention relates to has added low melting point metal Sn to be the processing characteristics of communication aluminium in order to improve 6000, and for material property after preventing to add above-mentioned Sn reduces and the raising rerum natura, optimization Si and Mg content are characteristics.
" impurity " that the present invention relates to is meant the unexpected composition that takes place in the alloy production process.
In the aluminium alloy gross weight that the present invention relates to, the desired contents of Si is 1.2~1.4 weight %.When containing quantity not sufficient 1.2 weight %, can cause alloy rigidity to reduce, surpassing 1.4 weight % then can reduce because of high alloy causes casting speed at the making continuously cast bloom period of the day from 11 p.m. to 1 a.m, thereby reduction production efficiency, and, reduce extrusion speed and surface quality along with the increase of when extruding material stress of fluidity.Simultaneously, influenced by over-drastic Excess-Si, the problem that hardness value rises and causes the tool wear amount to increase can take place.
In the aluminium alloy gross weight that the present invention relates to, the desired contents of Mg is 0.6~0.75 weight %.When containing quantity not sufficient 0.6 weight %, the sticking possibility of the burning of processing chip is higher, and generates Sn and throw out, causes playing the Mg of enhanced physical properties effect 2The Si contents of precipitate reduces relatively, thereby reduces the rerum natura of material; When surpassing 0.75 weight %, basilar fibers shape tissue can be reinforced, and makes the length of processing chip elongated, thereby reduces its workability.
In the aluminium alloy ingredient that the present invention relates to, Sn can generate Mg and Mg-Sn is a throw out, and this throw out can play the effect that destroys chip in the course of processing, thereby improves workability, and this specific character can along with Sn content what too or not enough.When Sn less than 0.8 weight %, the improvement of workability has little effect; When surpassing 1.0 weight %,, strengthened because the burning between the processing chip is sticking and added the impaired possibility of instrument in man-hour though the size of processing chip can diminish.
In the aluminium alloy gross weight that the present invention relates to, the desired contents of Mn is 0.50~0.70 weight %.Mn can suppress compound formation needle-like such as AlFeSi, and to improving the required crystalline particle granular effective elements of intensity.When Mn less than 0.50 weight %, the acicular possibility of compound formation such as AlFeSi is higher, and the crystal grain granular has little effect; When surpassing 0.70 weight %, the problem that intensity reduces can take place on the contrary.
Simultaneously, in the aluminium alloy gross weight that the present invention relates to, can be added on the mentioned component of selecting among the group who forms by Fe 0.001~0.50 weight %, Cu 0.01~0.10 weight %, Cr 0.01~0.25 weight % and Zn 0.01~0.20 weight % more than a kind.When surpassing mentioned component content, the generation of intermetallic compound may cause its rerum natura to reduce, and weakens extruding, from becoming the reason that reduces production efficiency.
In addition, also can relate to other Composition Control outside the composition below 0.15 weight % with above-mentioned.The aluminium alloy that the present invention relates to is for suppressing the generation of other intermetallic compounds, and suggestion is pressed foregoing and regulated content of elements.
In addition, the present invention relates to:
Si 1.2~1.4 weight %, Mg 0.6~0.75 weight %, Sn 0.8~1.0 weight % in the constituent gross weight, and all the other are the preparatory stage of the Al-Si-Mg line aluminium alloy of Al and impurity with constituent;
Above-mentioned aluminium alloy is made into the stage of semifinished product by continuous casting process with constituent; And
The semifinished product that the above-mentioned stage is made homogenizes the heat treated stage of thermal treatment, extruding, stretching and timeliness,
Above-mentioned timeliness thermal treatment is to be processed as the production technique of the Al-Si-Mg line aluminium alloy of characteristics under 130~150 ℃ of environment.
In above-mentioned manufacturing process, except other technologies of Al-Si-Mg line aluminium alloy constituent and timeliness thermal treatment temp all can be utilized disclosed process implementing in this field.
Above-mentioned timeliness thermal treatment can rerum natura as required change thermal treatment temp, because of the characteristic on the above-mentioned composition, for example along with the interpolation of Sn, the precipitation situation of compound is not equal, therefore different with common method, 130~150 ℃ processing environment is adopted in suggestion, it would be desirable under 140 ℃ of environment and carries out heat treatment step, and this is to the precipitate distribution that realizes homogeneous and to prevent that thick throw out from generating very effective.
In above-mentioned production technique, in the aluminium alloy gross weight, Mn0.50~0.70 weight % is added in suggestion to aluminium alloy again with constituent.In addition, the aluminium alloy that the present invention relates to can be added on the mentioned component of selecting among the group who is made up of Fe0.001 in the aluminium alloy gross weight~0.50 weight %, Cu 0.01~0.10 weight %, Cr 0.01~0.25 weight % and Zn 0.01~0.20 weight % more than a kind.
Below, further describe the present invention by embodiment.The following examples are required for the present invention in order to be described in more detail, and the scope that the present invention relates to is not limited to following embodiment.Following embodiment can rationally be revised, be changed by the operator in category of the present invention.
Embodiment 1 and comparative example 1~3: the production of aluminium alloy
For examining the characteristic (tensile strength, yield strength, unit elongation) that the present invention relates to aluminium alloy, according to becoming to be grouped into the aluminium alloy test piece of having produced exemplifying embodiment 1 and reference examples 1~3 shown in the following table 1.
[table 1]
Si Mg Sn Mn Fe Cu Cr Zn Al and impurity
Embodiment 1 1.25 0.68 0.85 0.55 0.20 0.03 0.15 0.02 Other
Reference examples 1 1.0 0.55 1.0 0.55 0.20 0.03 0.15 0.02 Other
Reference examples 2 1.2 0.95 1.0 0.55 0.20 0.03 0.15 0.02 Other
Reference examples 3 1.2 0.55 1.0 0.55 0.20 0.03 0.10 0.02 Other
Unit: weight %
Test case 1: to the evaluation of the workability and the hardness of aluminium alloy
Estimate the workability and the hardness of the aluminium alloy test piece of producing in embodiment 1 and the reference examples 1~3, its result is presented in the following table 2.
[table 2]
Si Mg Sn Workability Hardness
Embodiment 1 1.25 0.65 0.85 It is outstanding that (chipless volume sticks up, no tool failure, burr (burr) surplus are few Outstanding (HB 104~110)
Reference examples 1 1.0 0.55 1.0 Generally (HB 88~90) not up to standard
Reference examples 2 1.2 0.95 1.0 (the chip volume takes place to be stuck up) not up to standard Generally (HB 102~105)
Reference examples 3 1.2 0.55 1.0 (small-bore drilling bit breakage) not up to standard Generally (HB 98~100)
Test case 2: to the evaluation of the tensile strength of aluminium alloy, yield strength, unit elongation
Tensile strength, yield strength and unit elongation to embodiment 1 and aluminium alloy test piece are on the market estimated, and its result has been presented in the following table 2.
[table 3]
Classification Stretch (MPa) Surrender (MPa) Unit elongation (%)
Embodiment 1 371 ?337 14.7
6082 alloys commonly used 357 ?336 13.6
We find out from the data of above-mentioned table 3, the present invention relates to aluminium alloy and be better than 6082 alloys commonly used on tensile strength, yield strength and unit elongation.
Embodiment 3: to the evaluation of aluminium alloy process velocity
Utilize small-bore drill bit that the workability of embodiment 1 and 6082 alloy test pieces commonly used is estimated, its result is presented at down in the tabulation 3.
[table 4]
Figure GSA00000018202500061

Claims (6)

1. the Al-Si-Mg line aluminium alloy that workability is strong is characterized in that, is Al and impurity with 1.2~1.4 weight % of Si in the aluminium alloy gross weight, Mg 0.6~0.75 weight %, Sn 0.8~1.0 weight % and all the other.
2. the Al-Si-Mg line aluminium alloy strong according to the described workability of claim 1 is characterized in that, adds Mn 0.50~0.70 weight % in described aluminium alloy gross weight.
3. the Al-Si-Mg line aluminium alloy strong according to the described workability of claim 1, it is characterized in that, in described aluminium alloy gross weight, add the composition of from the group that Fe 0.001~0.50 weight %, Cu 0.01~0.10 weight %, Cr 0.01~0.25 weight % and Zn 0.01~0.20 weight % form, selecting more than a kind.
4. the production technique of the Al-Si-Mg line aluminium alloy that a workability is strong, it is characterized in that, comprise in the constituent gross weight, Si 1.2~1.4 weight %, Mg 0.6~0.75 weight %, Sn 0.8~1.0 weight %, and all the other are the preparatory stage of the Al-Si-Mg line aluminium alloy of Al and impurity with constituent;
Above-mentioned aluminium alloy is made into the stage of semifinished product by continuous casting process with constituent; And
The semifinished product that the above-mentioned stage is made homogenizes the heat treated stage of thermal treatment, extruding, stretching and timeliness,
Above-mentioned timeliness thermal treatment is to be processed as the production technique of the Al-Si-Mg line aluminium alloy of characteristics under 130~150 ℃ of environment.
5. according to the production technique of the strong Al-Si-Mg line aluminium alloy of the described workability of claim 4, it is characterized in that, described Al-Si-Mg line aluminium alloy with constituent in the constituent gross weight, to add Mn0.50~0.70 weight %.
6. according to the production technique of the strong Al-Si-Mg line aluminium alloy of the described workability of claim 5, it is characterized in that, described Al-Si-Mg line aluminium alloy in the aluminium alloy gross weight, adds the composition of selecting more than a kind with constituent from the group that Fe0.001~0.50 weight %, Cu 0.01~0.10 weight %, Cr 0.01~0.25 weight % and Zn 0.01~0.20 weight % form.
CN2010101124978A 2009-03-03 2010-02-10 Al-Si-Mg line aluminium alloy and production technique thereof that workability is strong Pending CN101948974A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103805817A (en) * 2012-11-13 2014-05-21 现代摩比斯株式会社 Almgsi based aluminum alloy excellent in machinability, method of manufacturing the same and parts of an automobile manufactured from the same
CN106637000A (en) * 2016-12-16 2017-05-10 灏昕汽车零部件制造无锡有限公司 Heat treatment process of vibration absorber inner core
CN108251725A (en) * 2018-01-22 2018-07-06 湖北大旗液压有限公司 Wear-resistant aluminium alloy material for gear pump floating side plate and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102566343B1 (en) 2020-11-12 2023-08-11 주식회사 대우경금속 6xxx series aluminium alloy extruded material with excellent tensile properties and its manufacturing method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001181770A (en) * 1999-11-05 2001-07-03 Otto Fuchs Aluminum-based alloy
JP2006038409A (en) * 2004-07-30 2006-02-09 Tgk Co Ltd Expansion valve
CN1914348A (en) * 2003-12-11 2007-02-14 日本轻金属株式会社 Method for producing Al-Mg-Si alloy excellent in bake-hardenability and hemmability
CN101278067A (en) * 2005-09-02 2008-10-01 美铝公司 Method of press quenching aluminum alloy 6020

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1986825A (en) * 1933-09-18 1935-01-08 Aluminum Co Of America Free cutting alloy
NO312597B1 (en) * 2000-11-08 2002-06-03 Norsk Hydro As A method for forming shaped products of an aluminum alloy and using the same
JP2003119537A (en) * 2001-10-11 2003-04-23 Furukawa Electric Co Ltd:The Aluminum alloy superior in machinability
JP4858966B2 (en) 2006-11-02 2012-01-18 Towa株式会社 Electronic component compression molding method and molding apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001181770A (en) * 1999-11-05 2001-07-03 Otto Fuchs Aluminum-based alloy
CN1914348A (en) * 2003-12-11 2007-02-14 日本轻金属株式会社 Method for producing Al-Mg-Si alloy excellent in bake-hardenability and hemmability
JP2006038409A (en) * 2004-07-30 2006-02-09 Tgk Co Ltd Expansion valve
CN101278067A (en) * 2005-09-02 2008-10-01 美铝公司 Method of press quenching aluminum alloy 6020

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103805817A (en) * 2012-11-13 2014-05-21 现代摩比斯株式会社 Almgsi based aluminum alloy excellent in machinability, method of manufacturing the same and parts of an automobile manufactured from the same
CN106637000A (en) * 2016-12-16 2017-05-10 灏昕汽车零部件制造无锡有限公司 Heat treatment process of vibration absorber inner core
CN108251725A (en) * 2018-01-22 2018-07-06 湖北大旗液压有限公司 Wear-resistant aluminium alloy material for gear pump floating side plate and preparation method thereof

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Application publication date: 20110119