CN101948350A - Composite fertilizer and preparation method thereof - Google Patents
Composite fertilizer and preparation method thereof Download PDFInfo
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- CN101948350A CN101948350A CN2010102577301A CN201010257730A CN101948350A CN 101948350 A CN101948350 A CN 101948350A CN 2010102577301 A CN2010102577301 A CN 2010102577301A CN 201010257730 A CN201010257730 A CN 201010257730A CN 101948350 A CN101948350 A CN 101948350A
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Abstract
The invention discloses a composite fertilizer which is mainly prepared from amino acid mixture, various nutrient elements, phytosterol dispersant powder, synergist, stabilizer and penetrating agent. The composite fertilizer is a novel phytosterol foliar fertilizer which has the advantages of high efficiency, no toxicity and environment friendliness, not only can promote the growth of plants by over 10 percent, but also causes no environmental pollution.
Description
Technical field
The present invention relates to a kind of medicine fertilizer and preparation method thereof, particularly a kind of composite fertilizer with pesticide and preparation method thereof.
Background technology
Because characteristics such as foliage fertilizer has instant effect, utilization ratio height, consumption is few, using method is easy and effect of increasing production is obvious, and be widely used in the agriculture production.In recent years, all take much count of the production and the application of foliage fertilizer both at home and abroad, only have thousands of kinds at the Chinese commodity foliage fertilizer.But, still do not have preferably, have nutrition, coordinate plant growth, desinsection and multi-functional compound Pesticidal foliage fertilizer such as antibacterial.So we have researched and developed the compound Pesticidal foliage fertilizer of a series of multifunctionality, farming No. 3 foliage fertilizers in north are wherein a kind of, and the research and development application of this kind has been enriched the kind of foliage fertilizer and offered the multiple possible selection of peasant.
Summary of the invention
The object of the present invention is to provide a kind of composite fertilizer with pesticide; The present invention also aims to provide the preparation method of this medicine fertilizer.
The invention provides a kind of composite fertilizer with pesticide, make (weight part) by following raw material:
Aminoacid mixture: 20-50 part
Various nutrient elements 2-20 part
Phytosterol dispersion agent powder: 1-10 part
Synergistic agent: 0.1-2 part
Stablizer 0.1-2 part
Permeate agent: 0.1-2 part
Described composite fertilizer with pesticide, preferably make by following raw material:
Aminoacid mixture: 20-30 part
Various nutrient elements 5-10 part
Phytosterol dispersion agent powder: 1-5 part
Synergistic agent: 1-2 part
Stablizer 0.1-1 part
Permeate agent: 1.5-2 part
Described composite fertilizer with pesticide, preferably make by following raw material:
Aminoacid mixture: 30-35 part
Various nutrient elements 5-10 part
Phytosterol dispersion agent powder: 1-5 part
Synergistic agent: 1-2 part
Stablizer 1-2 part
Permeate agent: 1-2 part
Described composite fertilizer with pesticide, preferably make by following raw material:
Aminoacid mixture: 30 parts
10 parts of various nutrient elements
Phytosterol dispersion agent powder: 5 parts
Synergistic agent: 1 part
1.5 parts of stablizers
Permeate agent: 0.5 part
The present invention stipulates that the composite foliage fertilizer preparation method is as follows: get aminoacid mixture, be dissolved in the 300 parts by volume water, add the various nutrient elements aqueous solution 50 parts by volume, add the phytosterol dispersion agent powder of 1-5 part, take the circumstances into consideration to add synergistic agent, stablizer, the permeate agent of 0.1-2 part again, behind the mixing, add water, promptly obtain novel amino acid foliage fertilizer to 1000 parts by volume.Weight part/parts by volume of the present invention is the relation of g/ml.
Described aminoacid mixture is prepared by following any one method:
A adopts chemical reaction kettle, with technical gelatine powder and (3-9M) hydrochloric acid (preferred 5,6 or 7M) volume ratio is 1: 1-5 (preferred 1: 1.5,1: 2 or 1: 3), at 110-113 ℃ to its hydrolysis 10-24 hour (preferred 12 hours), with the acid hydrolysis liquid vacuum concentration, thickening temperature 60-90 ℃ (preferred 70 ℃), be diluted with water between the Ph1-2, use activated carbon decolorizing, activated carbon dosage be the technical gelatine powder 10%-50% (being preferably 15-25%), 70-100 ℃ (preferred 100 ℃) decolouring 0.5-5 hour (preferred 1 hour), after the cooling, warm filtration.Filtrate is used (KOH, NaOH, NH
3OH any one) regulate the pH value between the 5-7, promptly obtain the mixing solutions of multiple amino acids and polypeptide.
B adopts chemical reaction kettle, with technical gelatine powder and (3-9M) hydrochloric acid (preferred 5,6 or 7M) volume ratio is 1: 1-5 (preferred 1: 1.5,1: 2 or 1: 3), 110-113 ℃ to its continuous backflow hydrolysis 10-24 hour (preferred 12 hours), cooling back is 40-50 ℃ of disposable adding or be added dropwise to (being added dropwise in preferred the stirring) 50%NaNO
2(consumption is 1-2 a times of jelly powder consumption), be warmed up to 60-90 ℃ of (preferred 65-70 ℃) reaction 0.5-3 hour (preferred 1-2 hour), add isopyknic dense HCl again, with the acid liquid vacuum concentration to 1/5 of original volume, thickening temperature 60-90 ℃ (preferred 70 ℃), filter with glass fibre, filtrate is diluted with water between the Ph1-2 again, use activated carbon decolorizing, activated carbon dosage be the technical gelatine powder 10%-50% (being preferably 15-25%), 70-100 ℃ (preferred 100 ℃) decolouring 0.5-5 hour (preferred 1 hour), after the cooling, warm filtration.Filtrate is used (KOH, NaOH, NH
3OH any one) regulate the pH value between the 5-7, promptly obtain the mixing solutions of multiple amino acids and polypeptide.
Described technical gelatine is a hide glue, gelatine, the thermosol rubber powder, the albumen special adhesive, the feed special adhesive, any one of match special adhesive, obtain the mixed solution of 20 kinds of dissimilar a-amino acids behind the gelatin hydrolysis, comprise glycine (Glycine), L-Ala (Alanine), Xie Ansuan (Valine), leucine (Leucine), Isoleucine (Isoleucine), phenylalanine (Phenylalanine), tryptophane (Tryptophan), tyrosine (Tyrosine), aspartic acid (Aspartic acid), Histidine (Histidine), l-asparagine (Asparagine), L-glutamic acid (Glutamic acid), Methionin (Lysine), glutamine (Glutamine), methionine(Met) (Methionine), arginine (Arginine), Serine (Serine), Threonine (Threonine), halfcystine (Cysteine), proline(Pro) (Proline).
Biological activitys such as another functional additive is a plant sterol in the composite fertilizer, and plant sterol has desinsection, kills mite, antibacterial, but because plant sterol is a lipid-soluble substance, its water-soluble extreme difference has limited the application of plant sterol in agricultural.Phytosterin compound is any one or a few the combination in the following plant sterol, comprise that β-Gu Zaichun, Stigmasterol, campesterol, brassicasterol, avenasterol, ergosterol, this sterol of standing grain, citrostadienol, Lip river fly enol, ring jackfruit alcohol, cycloartenol, 2,4-methylene basic ring jackfruit alcohol.
In order to solve the problem of plant sterol poorly water-soluble, the invention provides the water dispersant of plant sterol, become water dispersant for 1-10% plant sterol adding dispersion agent, wetting agent, tamanori, disintegrating agent through conventional prepared by weight ratio; The used dispersion agent class of plant sterol can be the alkaline sodium lignosulfonate A of improvement, improve alkaline sodium lignosulfonate B, desugar sodium lignosulfonate (M-9), desugar condensation sodium lignosulfonate (M series), methanonaphthalene sulfonic acid class dispersion agent is (as dispersion agent NNO (the 2-naphthene sulfonic acid that the naphthalene sulfonation is made and the product of formaldehyde condensation), Dispersant MF (1-methyl naphthalene sulfonate formaldehyde condensate), dispersing agent C NF (condenses of benzyl naphthalene sulfonic acid and formaldehyde), super dispersion agent 550S (styrene acrylic), the Di Sier economic benefits and social benefits) a kind of in, ratio is 1-40% (preferred 5-25%); Wetting agent is a kind of in Saponin/TSM, lignosulfite, the animal protein factor digest, and usage ratio is 1-30% (preferred 2-10%); Filler is: potter's clay, clay, kaolin, diatomite, talcum powder, pyrophyllite, a kind of in the white carbon black, usage ratio is 1-5%, tamanori is: vegetable and animals oils, starch paste, natural gum, bean powder, animal gelatine, carboxymethyl cellulose, polyvinyl alcohol, the polyethylene butyl ether, a kind of in the polyvinyl acetate, ratio is 1-10% (preferred 1-2%), disintegrating agent is a starch, low-substituted hydroxypropyl cellulose, calcium carboxymethylcellulose, croscarmellose sodium, polyvinylpolypyrrolidone, sodium alginate, a kind of in the Lalgine, usage ratio is 1-10% (preferred 1-2%).
Among the present invention, optionally added auxiliary materials such as synergistic agent, permeate agent and stablizer, its usage ratio is 0.1-2%, and synergistic agent is any in tea saponin, root of langdu chromone, methylenedioxy benzene derivative, the 6-vinyl capraldehyde; Permeate agent is any in emulsifier BP, azone, the triphen phosphorus.Stablizer is a kind of in sodium alkyl benzene sulfonate, the Soxylat A 25-7.
Nutritive element described in the present invention is grouped into by following one-tenth, urea 10-40 weight part, potassium primary phosphate 10-40 weight part, boric acid 0.2-1 weight part; Disodium ethylene diamine tetraacetate 0.1-1 weight part, Manganous chloride tetrahydrate 0.2-2 weight part, calcium chloride 0.2-8 weight part, sal epsom 0.2-8 weight part, ferrous sulfate 0.2-2 weight part, zinc sulfate 0.2-2 weight part, copper sulfate 0.2-2 weight part.
Characteristic of the present invention is massive planting thing foliar nutrition, controlling plant harmful organism multiple functions such as (desinsections, antibacterial), gelatin hydrolysis technical process, plant sterol water dispersant manufacturing technology are the uniqueness invention of this research, cheap for manufacturing cost, its various components are nontoxic composition, environmentally safe, long-term application can be improved soil regime, the Sustainable Production of useful agricultural.
The present invention adopts this stay-in-grade amino acid source of technical gelatine, utilizes the acid hydrolysis technology to obtain amino acid source.Characteristic of the present invention has been developed a kind of new purposes of technical gelatine for (1), and has determined best preparation technology's flow process and technical essential; (2) plant sterol water-dispersion formulation and preparation technology have been researched and developed.(3) technical gelatine cheaply is easy to get, steady quality, and plant sterol is nontoxic, human body is had nourishing function and has the killing pests and suppressing bacteria effect, and various technology maturations also help suitability for industrialized production.The invention provides a kind of efficient, nontoxic, to environment-friendly novel amino acid foliage fertilizer, the growth that it not only can promote plant is more than 10%, and do not have any problem of environmental pollution, is a kind of very outstanding foliage fertilizer.
Following enforcement or experimental example are used to further specify, but are not limited to the present invention.
Experimental example 1 pharmacodynamic study data
By pot experiment, studied of the influence of northern agricultural No. 3 (embodiment 1) foliage fertilizers to growth of rape characteristic in seedling stage.4 processing are established in test, handle 1: contrast (clear water); Handle 2: 100 times of liquid of No. 3 nutritive medium dilutions of north farming; Handle 3: 200 times of liquid of No. 3 nutritive medium dilutions of north farming; Handle 4: 400 times of liquid of No. 3 nutritive medium dilutions of north farming.Adopt pot experiment: the basin alms bowl is black plastic keg (internal diameter 10cm, high 10cm), and soil is that flower nutrition soil mixing after is adorned basin with sole of the foot stone at 1: 1, adds water, sowing, and every basin sowing 3-5 grain, the back thinning of emerging keeps 1 strain, and each handles the water and fertilizer management unanimity.The spring sowing rape was emerged on November 20th, 2009, and on January 20th, 2010 gathered.Foliage-spray 3 times, each 10 days at interval, the solution amount that each every basin sprays was 150mL, made the positive and negative blade face of plant moistening evenly.Spray the 1st time on December 20th, 2009 (rape 4 leaves 1 heart), spray respectively on December 30, January 10 the 2nd time, the 3rd time.During results, every basin plant is all gathered.
Gather behind the seedling, measure leaf area, gross weight, over-ground part weight, root weight respectively, relatively the clear water control group calculates the per-cent that each position of plant increases.Calculation formula is as follows:
Increase the observed value of percentage=(sample measurement value-control group observed value) * 100%/sample
Experimental result is as follows:
1. rape leave area:
North No. 3 200,300 times of diluents of farming have the effect of obvious increase rape leave area, and increasing amount increases with concentration dilution.
2. rape gross weight
Farming No. 3 100,200,300 times of diluents in north are significantly increased the effect of rape gross weight, and increasing amount increases with concentration dilution.
3. rape over-ground part
Farming No. 3 100,200,300 times of diluents in north are significantly increased the effect of rape over-ground part weight, and increasing amount increases with concentration dilution.
4. the rape root is heavy
400 times of diluents that No. 3, the north farming can obviously increase the weight of root, and increasing amount increases with concentration dilution.
Experimental result shows that the north farming can obviously increase the weight of leaf area, gross weight, over-ground part weight and the root of rape for No. 3, and increasing amount increases with the increase of extension rate, and north No. 3 effects of farming of 400 times of concentration are best.Illustrate that the north farming is a reasonable rape leave leaven No. 3, its application concentration is good with 400 times.
Embodiment
Embodiment 1:
With technical gelatine 100g, place chemical reaction kettle, with 300mL, 6M hydrochloric acid, 110-113 ℃ of continuous backflow 12 hours, the cooling back was added dropwise to 100mL, 50%NaNO at 45 ℃
2Be warmed up to 70 ℃ of reactions 1 hour 1, add 100mL, 6M HCl again, to 1/5 of original volume, thickening temperature is 70 ℃, filters with glass fibre with the acid liquid vacuum concentration, filtrate is diluted with water between the Ph1-2 again, added 20g activated carbon dosage, boiling decoloring 0.5 hour, after the cooling, warm filtration.Filtrate is regulated the pH value between the 5-7 with KOH, and vacuum concentrates for following 70 ℃, promptly obtains the mixing solutions of multiple amino acids and polypeptide.Add the multiple element mixed powder of 20g (dry weight) (urea 5g, potassium primary phosphate 2g, boric acid 2g again; Disodium ethylene diamine tetraacetate 1.8g; Manganous chloride tetrahydrate 2g; calcium chloride 1g; sal epsom 2g; ferrous sulfate 2g; zinc sulfate 1g; copper sulfate 0.2g; mixing; be dissolved in an amount of water; spraying drying, vacuum-packed getting final product); (β-Gu Zaichun 8g adds 2-naphthalene sulfonic acidformaldehyde condensation product 1g to 10g plant sterol water dispersant; Saponin/TSM 0.5g; filled potter's clay is to 10g, above each component is dissolved in 1: 2 the ethanol of volume ratio mix, and reclaims ethanol at 70 ℃ under the vacuum; 45 ℃ of oven dry; pulverize with pulverizer, cross the 200-300 mesh sieve, in nodulizer, granulate then by tackiness agent and disintegrating agent; cross 60 mesh sieves; drying, packing, promptly); 1g root of langdu chromone mixing gets final product.
Embodiment 2:
With technical gelatine 100g, place chemical reaction kettle, with 200mL, 3M hydrochloric acid, 110-113 ℃ of continuous backflow 18 hours, the cooling back added 25g activated carbon dosage, boiling decoloring 1 hour, after the cooling, warm filtration.Filtrate is regulated the pH value between the 5-7 with ammoniacal liquor, and vacuum concentrates for following 70 ℃, promptly obtains the mixing solutions of multiple amino acids and polypeptide.Adding the multiple element mixed powder of 15g (dry weight) (with embodiment 1), 5g plant sterol water dispersant powder (with embodiment 1), 0.5g root of langdu chromone mixing again gets final product.
Embodiment 3:
With technical gelatine 100g, place chemical reaction kettle, with 200mL, 6M hydrochloric acid, 110-113 ℃ of continuous backflow 10 hours, the cooling back added the 50g activated carbon dosage, 80 ℃ of reactions were decoloured in 2 hours, after the cooling, warm filtration.Filtrate is regulated the pH value between the 5-7 with the KOH aqueous solution, and vacuum concentrates for following 70 ℃, promptly obtains the mixing solutions of multiple amino acids and polypeptide.Adding the multiple element mixed powder of 10g (dry weight) (with embodiment 1), 10g plant sterol water dispersant powder (with embodiment 1), 1g root of langdu chromone mixing again gets final product.
Embodiment 4:
With technical gelatine 100g, place chemical reaction kettle, with 300mL, 6M hydrochloric acid, 110-113 ℃ of continuous backflow 12 hours, the cooling back was added dropwise to 100mL, 50%NaNO at 45 ℃
2Be warmed up to 70 ℃ of reactions 1 hour 1, add 100mL, 6M HCl again, to 1/5 of original volume, thickening temperature is 70 ℃, filters with glass fibre with the acid liquid vacuum concentration, filtrate is diluted with water between the Ph1-2 again, added 20g activated carbon dosage, boiling decoloring 0.5 hour, after the cooling, warm filtration.Filtrate is regulated the pH value between the 5-7 with KOH, and vacuum concentrates for following 70 ℃, promptly obtains the mixing solutions of multiple amino acids and polypeptide.Add the multiple element mixed powder of 20g (dry weight) (urea 5g, potassium primary phosphate 2g, boric acid 2g again; Disodium ethylene diamine tetraacetate 1.8g; Manganous chloride tetrahydrate 2g; calcium chloride 1g; sal epsom 2g; ferrous sulfate 2g; zinc sulfate 1g; copper sulfate 0.2g; mixing; be dissolved in an amount of water; spraying drying; vacuum-packed getting final product); 10g plant sterol water dispersant (Stigmasterol 4g; campesterol 4g; add 2-naphthalene sulfonic acidformaldehyde condensation product 1g; Saponin/TSM 0.5g; add potter's clay to 10g, above each component is dissolved in 1: 2 the ethanol of volume ratio mixes, reclaim ethanol at 70 ℃ under the vacuum; 45 ℃ of oven dry; pulverize with pulverizer, cross the 200-300 mesh sieve, in nodulizer, granulate then by tackiness agent and disintegrating agent; cross 60 mesh sieves; drying, packing, promptly); 1g root of langdu chromone mixing gets final product.
Claims (8)
1. composite fertilizer with pesticide is characterized in that mainly being made by the raw material of following weight part:
Aminoacid mixture 20-50 part
Various nutrient elements 2-20 part
Phytosterol dispersion agent powder 1-10 part
Synergistic agent 0.1-2 part
Stablizer 0.1-2 part
Permeate agent 0.1-2 part;
Described aminoacid mixture is by following any one method preparation: A, employing chemical reaction kettle, with technical gelatine powder and 3-9M hydrochloric acid volume ratio is 1: 1-5 at 110-113 ℃ to its hydrolysis 10-24 hour, with the acid hydrolysis liquid vacuum concentration, thickening temperature 60-90 ℃, be diluted with water between the Ph1-2, use activated carbon decolorizing, activated carbon dosage be the technical gelatine powder 10%-50%, 70-100 ℃ the decolouring 0.5-5 hour, after the cooling, warm filtration; Filtrate is regulated the pH value between the 5-7, promptly obtains the multiple amino acids mixing solutions; B, adopt chemical reaction kettle, with technical gelatine powder and 3-9M hydrochloric acid volume ratio is 1: 1-5, at 110-113 ℃ to its continuous backflow hydrolysis 10-24 hour, the cooling back is 40-50 ℃ of disposable adding or be added dropwise to 50%NaNO, consumption is 1-2 a times of jelly powder consumption, be warmed up to 60-90 ℃ of reaction 0.5-3 hour, add isopyknic dense HCl again, with the acid liquid vacuum concentration to 1/5 of original volume, thickening temperature 60-90 ℃, filter with glass fibre, filtrate is diluted with water between the Ph1-2 again, uses activated carbon decolorizing, and activated carbon dosage is the 10%-50% of technical gelatine powder, 70-100 ℃ of decolouring 0.5-5 hour, after the cooling, warm filtration; Filtrate promptly obtains the multiple amino acids mixing solutions with regulating the pH value between the 5-7;
Described nutritive element is made up of the raw material of following weight part: urea 10-40 part, potassium primary phosphate 10-40 part, boric acid 0.2-1 part; Disodium ethylene diamine tetraacetate 0.1-1 part, Manganous chloride tetrahydrate 0.2-2 part, calcium chloride 0.2-8 part, sal epsom 0.2-8 part, ferrous sulfate 0.2-2 part, zinc sulfate 0.2-2 part, copper sulfate 0.2-2 part;
The water dispersant of described plant sterol becomes water dispersant for 1-10% plant sterol adding dispersion agent, wetting agent, tamanori, disintegrating agent, filler through conventional prepared by weight ratio; Plant sterol is that β-Gu Zaichun, Stigmasterol, campesterol, brassicasterol, avenasterol, ergosterol, this sterol of standing grain, citrostadienol, Lip river fly enol, ring jackfruit alcohol, cycloartenol, 2, any one or a few the combination of 4-methylene basic ring jackfruit alcohol; The used dispersion agent class of plant sterol is a kind of in the alkaline sodium lignosulfonate A of improvement, improvement alkaline sodium lignosulfonate B, desugar sodium lignosulfonate, desugar condensation sodium lignosulfonate, methanonaphthalene sulfonic acid class dispersion agent, the styrene acrylic, and ratio is 1-40%; Wetting agent is a kind of in Saponin/TSM, lignosulfite, the animal protein factor digest, and ratio is 1-30%; Filler is: a kind of in potter's clay, clay, kaolin, diatomite, talcum powder, pyrophyllite, the white carbon black, usage ratio is 1-5%, tamanori is: a kind of in vegetable and animals oils, starch paste, natural gum, bean powder, animal gelatine, carboxymethyl cellulose, polyvinyl alcohol, polyethylene butyl ether, the polyvinyl acetate, ratio is 1-10%, disintegrating agent is a kind of in starch, low-substituted hydroxypropyl cellulose, calcium carboxymethylcellulose, croscarmellose sodium, polyvinylpolypyrrolidone, sodium alginate, the Lalgine, and usage ratio is 1-10%;
Described synergistic agent is any one in tea saponin, root of langdu chromone, methylenedioxy benzene derivative, the 6-vinyl capraldehyde; Permeate agent is any one in emulsifier BP, azone, the triphen phosphorus; Stablizer is a kind of in sodium alkyl benzene sulfonate, the Soxylat A 25-7.
2. composite fertilizer with pesticide as claimed in claim 1 is characterized in that mainly being made by the raw material of following weight part:
Aminoacid mixture: 20-30 part
Various nutrient elements 5-10 part
Phytosterol dispersion agent powder: 1-5 part
Synergistic agent: 1-2 part
Stablizer 0.1-1 part
Permeate agent: 1.5-2 part.
3. composite fertilizer with pesticide as claimed in claim 1 is characterized in that mainly being made by the raw material of following weight part:
Aminoacid mixture: 30-35 part
Various nutrient elements 5-10 part
Phytosterol dispersion agent powder: 1-5 part
Synergistic agent: 1-2 part
Stablizer 1-2 part
Permeate agent: 1-2 part.
4. composite fertilizer with pesticide as claimed in claim 1 is characterized in that mainly being made by the raw material of following weight part:
Aminoacid mixture: 30 parts
10 parts of various nutrient elements
Phytosterol dispersion agent powder: 5 parts
Synergistic agent: 1 part
1.5 parts of stablizers
Permeate agent: 0.5 part.
5. the preparation method of a composite fertilizer with pesticide is characterized in that this method comprises the steps: to choose following raw material:
Aminoacid mixture: 20-50 part
Various nutrient elements 2-20 part
Phytosterol dispersion agent powder: 1-10 part
Synergistic agent: 0.1-2 part
Stablizer 0.1-2 part
Permeate agent: 0.1-2 part;
Described aminoacid mixture is by following any one method preparation: A, employing chemical reaction kettle, with technical gelatine powder and 3-9M hydrochloric acid volume ratio is 1: 1-5 at 110-113 ℃ to its hydrolysis 10-24 hour, with the acid hydrolysis liquid vacuum concentration, thickening temperature 60-90 ℃, be diluted with water between the Ph1-2, use activated carbon decolorizing, activated carbon dosage be the technical gelatine powder 10%-50%, 70-100 ℃ the decolouring 0.5-5 hour, after the cooling, warm filtration; Filtrate is regulated the pH value between the 5-7, promptly obtains the multiple amino acids mixing solutions; B, adopt chemical reaction kettle, with technical gelatine powder and 3-9M hydrochloric acid volume ratio is 1: 1-5, at 110-113 ℃ to its continuous backflow hydrolysis 10-24 hour, the cooling back is 40-50 ℃ of disposable adding or be added dropwise to 50%NaNO2, consumption is 1-2 a times of jelly powder consumption, be warmed up to 60-90 ℃ of reaction 0.5-3 hour, add isopyknic dense HCl again, with the acid liquid vacuum concentration to 1/5 of original volume, thickening temperature 60-90 ℃, filter with glass fibre, filtrate is diluted with water between the Ph1-2 again, uses activated carbon decolorizing, and activated carbon dosage is the 10%-50% of technical gelatine powder, 70-100 ℃ of decolouring 0.5-5 hour, after the cooling, warm filtration; Filtrate promptly obtains the multiple amino acids mixing solutions with regulating the pH value between the 5-7;
Described nutritive element is made up of the raw material of following weight part: urea 10-40 part, potassium primary phosphate 10-40 part, boric acid 0.2-1 part; Disodium ethylene diamine tetraacetate 0.1-1 part, Manganous chloride tetrahydrate 0.2-2 part, calcium chloride 0.2-8 part, sal epsom 0.2-8 part, ferrous sulfate 0.2-2 part, zinc sulfate 0.2-2 part, copper sulfate 0.2-2 part;
The water dispersant of described plant sterol becomes water dispersant for 1-10% plant sterol adding dispersion agent, wetting agent, tamanori, disintegrating agent, filler through conventional prepared by weight ratio; Plant sterol is that β-Gu Zaichun, Stigmasterol, campesterol, brassicasterol, avenasterol, ergosterol, this sterol of standing grain, citrostadienol, Lip river fly enol, ring jackfruit alcohol, cycloartenol, 2, any one or a few the combination of 4-methylene basic ring jackfruit alcohol; The used dispersion agent class of plant sterol is a kind of in the alkaline sodium lignosulfonate A of improvement, improvement alkaline sodium lignosulfonate B, desugar sodium lignosulfonate, desugar condensation sodium lignosulfonate, methanonaphthalene sulfonic acid class dispersion agent, the styrene acrylic, and ratio is 1-40%; Wetting agent is a kind of in Saponin/TSM, lignosulfite, the animal protein factor digest, and ratio is 1-30%; Filler is: a kind of in potter's clay, clay, kaolin, diatomite, talcum powder, pyrophyllite, the white carbon black, usage ratio is 1-5%, tamanori is: a kind of in vegetable and animals oils, starch paste, natural gum, bean powder, animal gelatine, carboxymethyl cellulose, polyvinyl alcohol, polyethylene butyl ether, the polyvinyl acetate, ratio is 1-10%, disintegrating agent is a kind of in starch, low-substituted hydroxypropyl cellulose, calcium carboxymethylcellulose, croscarmellose sodium, polyvinylpolypyrrolidone, sodium alginate, the Lalgine, and usage ratio is 1-10%;
Described synergistic agent is any one in tea saponin, root of langdu chromone, methylenedioxy benzene derivative, the 6-vinyl capraldehyde; Permeate agent is any one in emulsifier BP, azone, the triphen phosphorus; Stablizer is a kind of in sodium alkyl benzene sulfonate, the Soxylat A 25-7;
Get aminoacid mixture, be dissolved in the 300 parts by volume water, add the various nutrient elements aqueous solution 50 parts by volume, add the phytosterol dispersion agent powder of 1-5 part, take the circumstances into consideration to add synergistic agent, stablizer, the permeate agent of 0.1-2 part again, behind the mixing, add water, promptly obtain novel amino acid foliage fertilizer to 1000 parts by volume.
6. the preparation method of composite fertilizer with pesticide as claimed in claim 5 is characterized in that the weight proportion of described raw material is:
Aminoacid mixture: 20-30 part
Various nutrient elements 5-10 part
Phytosterol dispersion agent powder: 1-5 part
Synergistic agent: 1-2 part
Stablizer 0.1-1 part
Permeate agent: 1.5-2 part.
7. the preparation method of composite fertilizer with pesticide as claimed in claim 5 is characterized in that the weight proportion of described raw material is:
Aminoacid mixture: 30-35 part
Various nutrient elements: 5-10 part
Phytosterol dispersion agent powder: 1-5 part
Synergistic agent: 1-2 part
Stablizer: 1-2 part
Permeate agent: 1-2 part.
8. composite fertilizer with pesticide as claimed in claim 5 is characterized in that the weight proportion of described raw material is:
Aminoacid mixture: 30 parts
Various nutrient elements: 10 parts
Phytosterol dispersion agent powder: 5 parts
Synergistic agent: 1 part
Stablizer: 1.5 parts
Permeate agent: 0.5 part.
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584407A (en) * | 2012-03-19 | 2012-07-18 | 广西壮族自治区林业科学研究院 | Special fertilizer for leaf surfaces at oil-tea camellia seedling stage and preparing method thereof |
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| CN102643124A (en) * | 2011-02-17 | 2012-08-22 | 潍坊市云涛有机肥料有限公司 | Preparation method of liquid fertilizer |
| CN102674961A (en) * | 2012-05-05 | 2012-09-19 | 管天球 | Organic fertilizer produced from tea cakes |
| CN102826898A (en) * | 2012-07-31 | 2012-12-19 | 马鞍山科邦生态肥有限公司 | Special rapeseed fertilizer and preparation method of special rapeseed fertilizer |
| CN102976854A (en) * | 2012-12-13 | 2013-03-20 | 浙江久晟茶业发展有限公司 | Plant leaf fertilizer prepared by natural tea saponin powder |
| WO2013159708A1 (en) * | 2012-04-28 | 2013-10-31 | 天津丰润园精细化工科技有限公司 | Floral-use slow release organic fertilizer and preparation method therefor |
| CN103848683A (en) * | 2014-02-26 | 2014-06-11 | 成都新柯力化工科技有限公司 | Method for preparing water-soluble fertilizer |
| CN103980042A (en) * | 2014-04-23 | 2014-08-13 | 河南科技大学 | Duplex controlled-release fertilizer used for alkaline soil and preparation method thereof |
| CN104355837A (en) * | 2014-11-11 | 2015-02-18 | 山东省农作物种质资源中心 | Traditional Chinese medicine compound leaf fertilizer for winter wheat and preparation method thereof |
| CN104430609A (en) * | 2014-11-19 | 2015-03-25 | 沈阳化工研究院有限公司 | Botanic pesticide water dispersant, preparation method and application thereof |
| CN104860748A (en) * | 2015-04-15 | 2015-08-26 | 芜湖市丹洋现代农业科技发展有限公司 | Agent for controlling oil-use peony pests and diseases, and preparation method thereof |
| CN105175117A (en) * | 2015-08-26 | 2015-12-23 | 迪斯科科技集团（宜昌）有限公司 | Insectproof and disease-control foliar fertilizer containing bioactive silicon and preparation method thereof |
| CN105399532A (en) * | 2015-12-21 | 2016-03-16 | 上海永通化工有限公司 | Water-soluble amino acid fertilizer and preparation method thereof |
| CN103782848B (en) * | 2013-12-19 | 2016-06-15 | 广西大学 | A kind of method preventing and treating Fructus Ananadis comosi blight |
| CN105801275A (en) * | 2016-04-28 | 2016-07-27 | 云南归北农业发展有限公司 | Special organic fertilizer for purple rice and preparation method thereof |
| CN107353122A (en) * | 2017-08-21 | 2017-11-17 | 佛山市三水区嘉信农业技术研究院（普通合伙） | A kind of foliar fertilizer for inducing melon vegetables powder mildew resistance and preparation method thereof |
| CN107488060A (en) * | 2017-07-29 | 2017-12-19 | 刘振 | A kind of foliar fertilizer stable regulation agent for increasing tealeaves freshness |
| CN109095986A (en) * | 2018-08-28 | 2018-12-28 | 潍坊康恩地生物技术有限公司 | A kind of compound plant source Water-solubility foliar fertilizer and preparation method thereof with sterilizing function |
| CN109369270A (en) * | 2018-11-26 | 2019-02-22 | 烟台富康生物科技有限公司 | A kind of environment-friendly fertilizer and its preparation process containing functional components of chlorella vulgaris |
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| CN1110673A (en) * | 1995-06-30 | 1995-10-25 | 胡国光 | Compound fertilizer for plant growing and disease resistance |
| CN1242353A (en) * | 1998-07-20 | 2000-01-26 | 叶中良 | Soluble compounding powder agent used as fertilizer and pesticide |
| CN1273959A (en) * | 1999-05-14 | 2000-11-22 | 张书申 | Plastic cyclocels for full growth period of wheat |
| US7608126B1 (en) * | 2006-04-04 | 2009-10-27 | Starcher Robert C | Method for horticulture plant rejuvenation |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643124A (en) * | 2011-02-17 | 2012-08-22 | 潍坊市云涛有机肥料有限公司 | Preparation method of liquid fertilizer |
| CN102584407A (en) * | 2012-03-19 | 2012-07-18 | 广西壮族自治区林业科学研究院 | Special fertilizer for leaf surfaces at oil-tea camellia seedling stage and preparing method thereof |
| CN102633559A (en) * | 2012-04-06 | 2012-08-15 | 苏州安德鲁尹生物技术咨询有限公司 | Activated carbon slow-release zinc fertilizer and preparation method thereof |
| WO2013159708A1 (en) * | 2012-04-28 | 2013-10-31 | 天津丰润园精细化工科技有限公司 | Floral-use slow release organic fertilizer and preparation method therefor |
| CN102674961A (en) * | 2012-05-05 | 2012-09-19 | 管天球 | Organic fertilizer produced from tea cakes |
| CN102826898A (en) * | 2012-07-31 | 2012-12-19 | 马鞍山科邦生态肥有限公司 | Special rapeseed fertilizer and preparation method of special rapeseed fertilizer |
| CN102976854A (en) * | 2012-12-13 | 2013-03-20 | 浙江久晟茶业发展有限公司 | Plant leaf fertilizer prepared by natural tea saponin powder |
| CN103782848B (en) * | 2013-12-19 | 2016-06-15 | 广西大学 | A kind of method preventing and treating Fructus Ananadis comosi blight |
| CN103848683A (en) * | 2014-02-26 | 2014-06-11 | 成都新柯力化工科技有限公司 | Method for preparing water-soluble fertilizer |
| CN103848683B (en) * | 2014-02-26 | 2015-05-27 | 成都新柯力化工科技有限公司 | Method for preparing water-soluble fertilizer |
| CN103980042A (en) * | 2014-04-23 | 2014-08-13 | 河南科技大学 | Duplex controlled-release fertilizer used for alkaline soil and preparation method thereof |
| CN103980042B (en) * | 2014-04-23 | 2016-07-06 | 河南科技大学 | Duplexing Controlled Release Fertilizer that a kind of basic soil uses and preparation method thereof |
| CN104355837A (en) * | 2014-11-11 | 2015-02-18 | 山东省农作物种质资源中心 | Traditional Chinese medicine compound leaf fertilizer for winter wheat and preparation method thereof |
| CN104355837B (en) * | 2014-11-11 | 2015-07-08 | 山东省农作物种质资源中心 | Traditional Chinese medicine compound leaf fertilizer for winter wheat and preparation method thereof |
| CN104430609A (en) * | 2014-11-19 | 2015-03-25 | 沈阳化工研究院有限公司 | Botanic pesticide water dispersant, preparation method and application thereof |
| CN104860748A (en) * | 2015-04-15 | 2015-08-26 | 芜湖市丹洋现代农业科技发展有限公司 | Agent for controlling oil-use peony pests and diseases, and preparation method thereof |
| CN105175117A (en) * | 2015-08-26 | 2015-12-23 | 迪斯科科技集团（宜昌）有限公司 | Insectproof and disease-control foliar fertilizer containing bioactive silicon and preparation method thereof |
| CN105399532A (en) * | 2015-12-21 | 2016-03-16 | 上海永通化工有限公司 | Water-soluble amino acid fertilizer and preparation method thereof |
| CN105801275A (en) * | 2016-04-28 | 2016-07-27 | 云南归北农业发展有限公司 | Special organic fertilizer for purple rice and preparation method thereof |
| CN107488060A (en) * | 2017-07-29 | 2017-12-19 | 刘振 | A kind of foliar fertilizer stable regulation agent for increasing tealeaves freshness |
| CN107353122A (en) * | 2017-08-21 | 2017-11-17 | 佛山市三水区嘉信农业技术研究院（普通合伙） | A kind of foliar fertilizer for inducing melon vegetables powder mildew resistance and preparation method thereof |
| CN109095986A (en) * | 2018-08-28 | 2018-12-28 | 潍坊康恩地生物技术有限公司 | A kind of compound plant source Water-solubility foliar fertilizer and preparation method thereof with sterilizing function |
| CN109369270A (en) * | 2018-11-26 | 2019-02-22 | 烟台富康生物科技有限公司 | A kind of environment-friendly fertilizer and its preparation process containing functional components of chlorella vulgaris |
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