CN101935498B - Heat-resisting organic silicon antiseptic inner tank coating - Google Patents
Heat-resisting organic silicon antiseptic inner tank coating Download PDFInfo
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- CN101935498B CN101935498B CN201010290484A CN201010290484A CN101935498B CN 101935498 B CN101935498 B CN 101935498B CN 201010290484 A CN201010290484 A CN 201010290484A CN 201010290484 A CN201010290484 A CN 201010290484A CN 101935498 B CN101935498 B CN 101935498B
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Abstract
The invention discloses a heat-resisting organic silicon antiseptic inner tank coating which comprises the following components in part by mass: 5-30 parts of organic silicon resin, 5-15 parts of modified organic silicon resin, 1-5 parts of amino resin, 0-18 parts of epoxy resin, 0-8 parts of phenolic resin, 11-43 parts of antiseptic pigment, 8-20 parts of filling material and 4-22 parts of solvent. The heat-resisting organic silicon antiseptic inner tank coating has good heat resistance and can work for long term at the high temperature of 350 DEG C; the coating has good adhesion force, good corrosion resistance and excellent performance; and a coating film still has good corrosion resistance after working at high temperature.
Description
Technical field
The present invention relates to a kind of protective system, particularly a kind of resistant to elevated temperatures organosilicon anticorrosion paint.
Background technology
Fire-resistant anticorrosion paint is widely used in chimney, high-temperature pipe, petrochemical equipment, High Temperature Furnaces Heating Apparatus, heat exchanger and aspects such as mover and vapor pipe thereof.
Interior filling coating is speciality coating, and its preparation technology and construction technology are special.How effectively japanning is a difficult point always in interior filling construction technology.
The protective system that uses in the sourdine is irritated coating in being.When engine start was opened, sourdine caused compositions such as condensed water because of internal-external temperature difference, needed problems such as solution is corrosion-resistant, acidproof, antirust, the flushing of gasproof stream; Paint film needs to solve problems such as corrosion-resistant, acidproof through behind the high temperature, and therefore, the specification processing requirement of internally irritating coating is increasingly high.
Irritate in the domestic existing noise eliminator of motorcycle and mainly occupy by imported product with organosilicon fire-resistant anticorrosion paint market; These coating can only be in long term operation under 300 ℃ or the following heat-resisting condition; Paint film comes off and loses provide protection when temperature surpasses 300 ℃; The noise eliminator of motorcycle that loses protection is prone to pitting corrosion takes place, and influences the work-ing life of noise eliminator of motorcycle.
Summary of the invention
The object of the present invention is to provide the anticorrosion interior coating of irritating of a kind of resistant to elevated temperatures organosilicon.
Technical scheme that the present invention takes is:
Irritate coating in a kind of high temperature resistant organosilicon is anticorrosion; Contain following mass parts: 5～30 parts of silicone resins, 5～15 parts of modified organic silicone resins, 1～5 part in aminoresin, 0～18 part of epoxy resin, 0～8 part in resol, 11～43 parts of anti-corrosion paints, 8～20 parts of fillers, 4～22 parts of solvents; Wherein, modified organic silicone resin is epoxy modified silicone resin, acryl-modified silicone resin resin or polyester modification silicone resin.
Silicone resin is preferably the aminomethyl phenyl silicone resin.
Aminoresin is preferably methyl-etherified terpolycyantoamino-formaldehyde resin or butylated melamine-formaldehyde resin.
Epoxy resin is preferably E-44 or E-12 epoxy resin.
Resol is preferably the natural rosin modified phenolic resins.
Anti-corrosion paint is at least a in metal-powder, chromic salt, iron mica or the aluminium triphosphate.
Filler is at least a in glass powder, mica powder or the talcum powder.
Solvent is at least a in YLENE, heavy aromatics, butyl ester, butanols or the pimelinketone.
Irritate coating in high temperature resistant organosilicon of the present invention is anticorrosion, resistance to elevated temperatures is good, can long term operation under 350 ℃ high temperature; Paint adhesion is good, solidity to corrosion is good, and coating performance is good; Paint film behind the hot operation still keeps good solidity to corrosion.
Embodiment
Irritate coating in a kind of high temperature resistant organosilicon is anticorrosion; Contain following mass parts: 5～30 parts of silicone resins, 5～15 parts of modified organic silicone resins, 1～5 part in aminoresin, 0～18 part of epoxy resin, 0～8 part in resol, 11～43 parts of anti-corrosion paints, 8～20 parts of fillers, 4～22 parts of solvents; Wherein, modified organic silicone resin is epoxy modified silicone resin, acryl-modified silicone resin resin or polyester modification silicone resin.
Preferably; General knowledge according to those skilled in the art; In coating, also be added with auxiliary agent, auxiliary agent comprises one or more in dispersion agent, anti-settling agent, the silane coupling agent, and its kind and addition are well-known to those skilled in the art; Can easily confirm also that through the limited number of time experiment addition of auxiliary agent is preferably 1～3 part.
Silicone resin is preferably the aminomethyl phenyl silicone resin.
Aminoresin is preferably methyl-etherified terpolycyantoamino-formaldehyde resin or butylated melamine-formaldehyde resin.
Epoxy resin is preferably E-44 or E-12 epoxy resin.
Resol is preferably the natural rosin modified phenolic resins.
Anti-corrosion paint is at least a in metal-powder, chromic salt, iron mica or the aluminium triphosphate, and wherein, metal-powder can be conventional silver powder, zinc powder or Stainless Steel Powder, and chromic salt can be zinc chromium or strontium yellow.Various anti-corrosion paints can use separately, also can mix use.The fineness of anti-corrosion paint preferably is no more than 15 μ m.
Filler is at least a in glass powder, mica powder or the talcum powder.
Solvent is at least a in YLENE, heavy aromatics, butyl ester, butanols or the pimelinketone, and all kinds of SOLVENTS can mix with arbitrary proportion and uses.
Various raw materials mix evenly can be obtained the anticorrosion interior coating of irritating of high temperature resistant organosilicon of the present invention.
Below in conjunction with embodiment, further specify the present invention.
If no special instructions, following umber all refers to mass parts.
Embodiment 1
System component is:
30 parts of aminomethyl phenyl silicone resins, 5 parts of epoxy modified silicone resins, 1 part of methyl-etherified terpolycyantoamino-formaldehyde resin, 6 parts of E-44 epoxy resin, 3 parts of natural rosin modified phenolic resinss, 1.2 parts of 108 dispersion agents, 0.8 part of M-5 anti-settling agent, 5 parts in silver powder, 6 parts of zinc powders, 4 parts of zinc chromiums, 12 parts in glass powder, 8 parts of mica powders, 7 parts of talcum powder, 7 parts of YLENE, 3 parts of butyl esters, 1 part in butanols.
Embodiment 2
System component is:
15 parts of aminomethyl phenyl silicone resins, 15 parts of acryl-modified silicone resin resins, 3 parts of butylated melamine-formaldehyde resins, 8 parts of E-12 epoxy resin, 4 parts of natural rosin modified phenolic resinss, 1 part of 108 dispersion agent, 1 part of M-5 anti-settling agent, 6 parts of zinc powders, 8 parts of Stainless Steel Powders, 6 parts of zinc chromiums, 5 parts of mica iron oxide reds, 8 parts in glass powder, 8 parts of mica powders, 4 parts of talcum powder, 5 parts of YLENE, 2 parts of butyl esters, 1 part of pimelinketone.
Embodiment 3
System component is:
20 parts of aminomethyl phenyl silicone resins, 13 parts of polyester modification silicone resins, 5 parts of butylated melamine-formaldehyde resins, 6 parts of E-44 epoxy resin, 1 part of 963 dispersion agent, 1 part of M-5 anti-settling agent, 1 part of KH570 silane coupling agent, 6 parts in silver powder, 4 parts of zinc powders, 2 parts of Stainless Steel Powders, 7 parts of strontium yellows, 5 parts of micaceous iron oxide grays, 10 parts in glass powder, 9 parts of mica powders, 5 parts of YLENE, 2 parts of heavy aromaticss, 2 parts of butyl esters, 1 part of pimelinketone.
Embodiment 4
System component is:
25 parts of aminomethyl phenyl silicone resins, 10 parts of polyester modification silicone resins, 3 parts of methyl-etherified terpolycyantoamino-formaldehyde resins, 8 parts in resol, 1 part of 108 dispersion agent, 1 part of M-5 anti-settling agent, 4 parts in silver powder, 15 parts of zinc powders, 5 parts of mica iron oxide reds, 7 parts in glass powder, 3 parts of mica powders, 7 parts of talcum powder, 5 parts of YLENE, 2 parts of heavy aromaticss, 2 parts of butyl esters, 2 parts in butanols.
Embodiment 5
System component is:
20 parts of aminomethyl phenyl silicone resins, 13 parts of epoxy modified silicone resins, 3 parts of butylated melamine-formaldehyde resins, 4 parts of E-12 epoxy resin, 8 parts of natural rosin modified phenolic resinss, 1.2 parts of 963 dispersion agents, 0.8 part of MP100 anti-settling agent, 5 parts in silver powder, 20 parts of zinc powders, 4 parts of mica iron oxide reds, 5 parts in glass powder, 8 parts of mica powders, 7 parts of YLENE, 1 part of butyl ester.
Embodiment 6
System component is:
10 parts of aminomethyl phenyl silicone resins, 8 parts of polyester modification silicone resins, 5 parts of butylated melamine-formaldehyde resins, 12 parts of E-12 epoxy resin, 4 parts of natural rosin modified phenolic resinss, 0.2 part of 108 dispersion agent, 0.8 part of MP100 anti-settling agent, 5 parts in silver powder, 20 parts of zinc powders, 10 parts of mica iron oxide reds, 5 parts in glass powder, 3 parts of mica powders, 15 parts of YLENE.
Embodiment 7
System component is:
5 parts of aminomethyl phenyl silicone resins, 15 parts of acryl-modified silicone resin resins, 5 parts of methyl-etherified terpolycyantoamino-formaldehyde resins, 18 parts of E-12 epoxy resin, 6 parts in resol, 5 parts in silver powder, 6 parts of mica iron oxide reds, 5 parts in glass powder, 10 parts of talcum powder, 3 parts of pimelinketone, 1 part of butyl ester.
Embodiment 8
System component is:
20 parts of aminomethyl phenyl silicone resins, 11 parts of epoxy modified silicone resins, 2 parts of methyl-etherified terpolycyantoamino-formaldehyde resins, 14 parts of E-12 epoxy resin, 1 part of natural rosin modified phenolic resins, 1.2 parts of 963 dispersion agents, 0.8 part of SD-1 anti-settling agent, 1 part of KH560 silane coupling agent, 5 parts of aluminium triphosphates, 17 parts of zinc powders, 11 parts of mica iron oxide reds, 5 parts in glass powder, 5 parts of mica powders, 7 parts of YLENE, 1 part of butyl ester, 10 parts of heavy aromaticss.
Embodiment 9
System component is:
20 parts of aminomethyl phenyl silicone resins, 9 parts of epoxy modified silicone resins, 4 parts of butylated melamine-formaldehyde resins, 16 parts of E-12 epoxy resin, 2 parts of natural rosin modified phenolic resinss, 1.0 parts of 108 dispersion agents, 0.9 part of SD-1 anti-settling agent, 1.1 parts of KH560 silane coupling agents, 10 parts of Stainless Steel Powders, 18 parts of zinc powders, 15 parts of micaceous iron oxide grays, 4 parts in glass powder, 6 parts of mica powders, 7 parts of YLENE, 7 parts of butyl esters, 8 parts in butanols.
Get the protective system of embodiment 1～5, interior filling is coated on silencer internal wall and carries out performance test, and detected result is as shown in table 1.
Table 1, protective system Performance Detection table
Irritate coating in high temperature resistant organosilicon of the present invention is anticorrosion, resistance to elevated temperatures is good, can long term operation under 350 ℃ high temperature; Paint adhesion is good, solidity to corrosion is good, and coating performance is good; Paint film behind the hot operation still keeps good solidity to corrosion.
Claims (3)
1. a high temperature resistant organosilicon is irritated coating in anticorrosion; Contain following mass parts: 5～30 parts of silicone resins, 5～15 parts of modified organic silicone resins, 1～5 part in aminoresin, 0～18 part of epoxy resin, 0～8 part in resol, 11～43 parts of anti-corrosion paints, 8～20 parts of fillers, 4～22 parts of solvents; Wherein, Modified organic silicone resin is epoxy modified silicone resin, acryl-modified silicone resin resin or polyester modification silicone resin; Said silicone resin is the aminomethyl phenyl silicone resin; Said aminoresin is methyl-etherified terpolycyantoamino-formaldehyde resin or butylated melamine-formaldehyde resin, and said anti-corrosion paint is at least a in metal-powder, chromic salt, iron mica or the aluminium triphosphate, and said filler is at least a in glass powder, mica powder or the talcum powder.
2. irritate coating in a kind of high temperature resistant organosilicon according to claim 1 is anticorrosion, it is characterized in that: epoxy resin is E-44 or E-12 epoxy resin.
3. irritate coating in a kind of high temperature resistant organosilicon according to claim 1 is anticorrosion, it is characterized in that: resol is the natural rosin modified phenolic resins.
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| CN201010290484A CN101935498B (en) | 2010-09-25 | 2010-09-25 | Heat-resisting organic silicon antiseptic inner tank coating |
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| CN201010290484A CN101935498B (en) | 2010-09-25 | 2010-09-25 | Heat-resisting organic silicon antiseptic inner tank coating |
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| CN101935498B true CN101935498B (en) | 2012-10-17 |
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