CN101921566B - Structural adhesive for steel bonding - Google Patents
Structural adhesive for steel bonding Download PDFInfo
- Publication number
- CN101921566B CN101921566B CN 200910086614 CN200910086614A CN101921566B CN 101921566 B CN101921566 B CN 101921566B CN 200910086614 CN200910086614 CN 200910086614 CN 200910086614 A CN200910086614 A CN 200910086614A CN 101921566 B CN101921566 B CN 101921566B
- Authority
- CN
- China
- Prior art keywords
- component
- structure glue
- epoxy
- resins
- mass ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Working Measures On Existing Buildindgs (AREA)
Abstract
The invention discloses a structural adhesive for steel bonding, which comprises a component A and a component B of which the quality ratio is 100:(15-65), wherein the component A comprises epoxy resin, diluter, plasticizer, toughener and couplant; and the component B comprises modified polyamide resin, modified fatty amine and amino terminated polyether. The structural adhesive has the advantages of favorable bonding property, uniform stress distribution, high shearing strength and good mechanical toughness, has the characteristics of no flow after plate bonding, large anchorage withdrawal resistance and limit of harmful substances far below the national technical index, has the characteristics of high durability, convenient construction and stable strength, and can well soak the concrete and well bond the concrete and steel plates. The invention has high application and popularization values.
Description
Technical field
The present invention relates to a kind of structural adhesive for steel bonding.
Background technology
One, highway in China bridge strengthening present situation
According to national highway statistics annual report in 2004, cut-off to 2003 the end of the year whole nation 10443 of unsafe bridges, 378439 linear meter(lin.m.)s are arranged, wherein the national highway unsafe bridge is 1942,110,000 linear meter(lin.m.)s.It is three classes that the technology status of bridge block more than 1.2 ten thousand (about 470,000 linear meter(lin.m.)s) is arranged on state's provincial highway, has the bridge of obvious potential safety hazard, in case be subjected to the impact of the accidents such as Heavy Traffic and natural disaster, these bridges change unsafe bridge most probably into.Therefore, the need repairing bridge enormous amount of strengthening reconstruction.
Nearly twenty or thirty is over year, and the emphasis of developed countries bridge construction has been put into the strengthening and reforming aspect of old bridge, and newly building bridge has been reduced to back burner.From the last century the eighties, China has just begun the research of highway bridge reinforcement technique, by with exchanging of abroad going together, formed the reinforcement means of multiple comparative maturity now.Day by day heavy along with the strengthening and rehabilitation of old bridges work, the case history that bridge structure is reinforced is more and more, and aspect the Technology Bridge Strengthening transformation, particularly the reinforcement and strengthening of concrete structure has accumulated abundant practical experience.Large quantities of old bridge unsafe bridges have obtained punishment, for have a good transport and communication network, safe operation made major contribution.
1, the purpose of bridge strengthening and type
Disease according to bridge structure detects analysis and lesion assessment result, and bridge strengthening generally can be divided into: reinforcement (reinforcement), use function are reinforced the Four types such as (rigidity reinforcing), weather resistance reinforcing and seismic hardening.
1) reinforcement is the basis of guaranteeing the bridge security operation, is the core content of Bridge Reconstruction Design of Reinforcement, and its content comprises Bend reinforcement and shear Capacity reinforcing two portions.Reinforcement generally is the deficiency that adopts the enlarging section size and increase arrangement of reinforcement or set up the additional bearing capacity of prestressed method, should consider during design that the bridge band carries the stressed characteristics of segmentation of reinforcing, and notes newly adding the common work of supporting material and primary structure.
2) using function to reinforce is the needs of guaranteeing the bridge normal operation, mainly be to the mobile load distortion or vibrate excessive member, and the enlarging section size, increasing section rigidity makes crack closure or restriction crack progressing use functional requirement to satisfy structure.
3) weather resistance is reinforced and to be referred to the structural impairment position is repaired and reinforcement, continues to worsen with the performance that stops the structural impairment part, eliminates damage hidden danger, extending structure work-ing life.
4) seismic hardening is the shock resistance of the structure that suffers eaerthquake damage being repaired, strengthened the ductility of structure and integral working, raising structure.At present, following technical measures are mainly taked in the domestic and abroad bridge seismic hardening: 1. at the expansion joint, the top seam such as hinge and beam-ends adopt pull bar, block or increase the measure such as width of supporting surface, with the generation of restrainer earthquake; 2. increase the lateral confinement of reinforced concrete bridge pier, improve its bending resistance ductility and slip resistance, prevent that bridge pier is crooked and shear earthquake; 3. adopt to subtract seismic isolation technology and special energy-dissipating device, improve the anti-seismic performance of bridge.
2, bridge superstructure Reinforcement Technology
1) external prestressing strengthening method
External prestressing strengthening is the outside that the presstressed reinforcing steel with corrosionproof protection is arranged in the beam body, and the beam body is applied prestress, offsets the internal force that the part external load produces with the recurvation square that pre-tension produces, and reaches the use function of improving beam and the purpose that improves bearing capacity.Because bridge structure generally all adopts band to carry and reinforces, after add supporting material and only bear the internal force that mobile load causes, after add supporting material stress (strain) and lag behind, be difficult to play a role fully.To after add supporting material and apply and add supporting material stress (strain) after prestress can solve and lag behind, add the supporting material utilising efficiency after the raising, case beam inside provides the space for prestressed layout simultaneously, and this method is specially adapted to the reinforcing of prestressed concrete continuous box girder and Continuous Rigid Box beam bridge.
2) reinforcement method of enlarging section
The enlarging section method increases former concrete structure section area with newly watering Steel Concrete exactly, reaches the purpose that improves bearing capacity.The advantages such as the method is a kind of traditional reinforcement means, has construction simply, and is widely applicable.The intensity, rigidity stability and the splitting resistance that adopt the method to reinforce for structure all improve a lot.But shortcoming is also comparatively obvious, and situ wet work operations amount is large, and preserving period is longer, to producing and living certain influence is arranged, so the method is often used for suspending traffic or be subjected to traffic to disturb the reinforcing of less bridge structure.Stress level when the consolidation effect of enlarging section is reinforced with primary structure, new and old structure integral working, the processing of bonding surface structure, construction technology, material property and the factor such as off-load is directly related when reinforcing.
3) affixing steel plate reinforcement method
The affixing steel plate reinforcement method is to adopt structure glue, steel plate is directly sticked on tensile zone or the shearing resistance weak part of the reinforced concrete structures that is reinforced, make it that to form integral body jointly stressed with the reinforced structure thing, to improve the rigidity of structure, improve its strained condition, carrying out of restriction crack improved the bearing capacity of structure.On sticking at the bottom of the beam or the steel plate of plate bottom surface, can significantly improve rigidity and the Bend bearing capacity of former beam.Stick on the steel plate on the beam sides, if consistent with the principal tensile stress trajectory, can limit carrying out of crack, improve the shear Capacity of beam.
4) sticking carbon fiber method for strengthening
Pasting the fiber reinforced method of high-strength compound is to adopt structure glue that high-strength compound cloth (or plate) directly is bonded in to be reinforced the concrete structure vulnerable area, to form integral body jointly stressed with reinforced structure, with the development in restriction crack, improve the bearing capacity of structure.When adopting stickup high-strength compound fibre method to carry out Normal Section Bearing Capacity of Bending Members and Beams Oblique Section Carrying Capacity reinforcement and strengthening, the arrangement of cloth is identical with the affixing steel plate reinforcement method.The high-strength compound fiber of rear stickup can limit the bending resistance of carrying out, improving beam and the shear-carrying capacity in crack.The stress that adds reinforcing fiber after under the ultimate limit state depends on the ratio of reinforcement of former beam.The situation less for former depth of beam, that the ratio of reinforcement is larger, after add reinforcing fiber the high tensile performance can not play one's part to the full.It is fiber reinforced that high-strength compound is pasted in employing, little to the rigidity raising of structure, is unfavorable for be deformed into the reinforcing of main purpose use function with control texture.The high-strength compound layer of fibers of rear stickup can restrict the development in crack, has indirectly improved the crack resistance of structure; The high-strength compound layer of fibers that contains multi-layer resinous glue and protection cover glue of rear stickup can improve concrete anticorrosive and carbonization ability, weather resistance is reinforced adopt this method method for strengthening to suit.
5) distress in concrete enclosure method
The distress in concrete enclosure method is a kind of effective remedial measures.The crack closure method mainly comprise to width less carry out surface-closed, to width larger carry out encapsulating.By aforesaid method, inside concrete is become sealing or continuous, prevent from that extraneous objectionable impurities enters inside concrete behind concrete cracking to cause further infringement, can greatly improve the anti-deteriorated ability of cracked concrete.
6) change structure stress system method
This kind reinforced, remodeling method is by changing the bridge structure stress system, reaching the purpose that improves load carrying capacity of bridge, such as extension supporting under the flexure members such as beam slab, reduces to calculate and strides directly; Or increase external Shu Tigao supporting capacity or freely supported structure vertically is connected to form continuous structure; Or under beam, set up stiff girder or composite beam, to reduce the internal stress of beam, adjust in addition in addition the beam position, strengthen newly-built side bar sectional dimension in modes such as adjustment Transverse Distributions.Certainly, along with the stressed of some member or cross section in the formed new system of the change of system should carry out conscientious checking computations by the new system requirement, and take appropriate measures.The method is the reinforcement measure a kind of commonly used that solves the superload vehicle; This kind method is more applicable for the serious bridge structure of disease of ultimate bearing capacity wretched insufficiency and normal usage function forfeiture in addition.
3, bridge substructure reinforcement technique
Substructure reinforcing aspect can be divided into strengthening of foundation, bridge pier reinforcing and Abutment Reinforcement three classes.
1) strengthening of foundation
Method commonly used has grouting reinforcement method, it is several to enlarge strengthening of foundation method, Steel Concrete cuff method for strengthening and augment pile foundation reinforcement method etc.
2) bridge pier is reinforced
Steel Concrete cuff method for strengthening, cement grout-reinforcement method, chemical grouting method for strengthening are arranged and add stake (post) method for strengthening etc.
3) Abutment Reinforcement
Method commonly used has sets up pull bar after adding hole off-load method for strengthening, platform behind the platform, and buttress or retaining wall reinforcement method and Steel Concrete shroud or stirrup method for strengthening etc. are several.
Two, highway at home and abroad bridge strengthening application and the state of the art of structure glue
Along with the development of concrete component reinforcing technology, the application of the tackiness agent that bridge strengthening is used is more and more extensive.Have great importance at aspects such as improving strengthening quality, saving man-hour and energy consumption, raising speed of application, beautifying constructure.
Though the existing long developing history of the reinforced glue stick take high molecular synthetic material as Main Components, but the member that is used for bridge structure is bonding, appearance and the application of the sqtructural adhesive of Hydraulic and Hydro-Power Engineering reinforcing and repairing and the old and new's structure of modification, only has nearly 50 or six ten years history.
At the beginning of the fifties, Resins, epoxy has obtained to use widely, and the U.S. at first repairs highway pavement fast with epoxy resin structural adhesive.The sixties, some developed countries are widely used in construction structure glue in the engineerings such as highway, bridge, airfield runway, and the reinforcing that is used for hydro project and military installations.Enter the seventies, the construction structure glue of all kinds of excellent propertys occurs in succession, and expands its Application Areas to more aspect, such as reinforcing, the reparation of foundation construction, Highrise buildings and the vehicular bridge etc. of bridge pier, in order to improve the supporting capacity of buildings.For example: the famous super modern theatre of Sydney, AUS is bonding with the assembly unit that building adhesive is used for roof system, is the classics that construction structure glue is used.Enter the eighties, the application of construction structure glue is more general, as: the use construction structure glue steel plate that 6.3mm is thick of Britain Sai Feier university success is adhered to a highway bridge and side, makes the bridge of this original limit for tonnage amount 110t pass through the truck of 500t.This period, some countries are on the basis of generally using, strengthened on the one hand the research of adhesive member load-carrying properties and behavior, as: the transportation of Britain and road institute, Moscow School of Architecture ﹠ Civil Engineering etc. all carry out the reinforcement experiment of lintel, make again on the other hand job specifications, the U.S., Japan have all formulated construction quality standard or the job specifications of construction structure glue, make the new development of having got back of this class glue kind.
Entered since the nineties, various research work are more deep, use more general, as: Japan the big earthquakes in Osaka and Kobe after, the reinforced column of its damage bridge and beam etc. all use epoxy construction structure glue (emulsion two-component-type) to reinforce, repair in a large number; Its glue kind also becomes increasingly abundant, except bonding usefulness, also have anchoring with (as liking sharp moral glue), pour into and leak stopping use etc., make construction structure glue in the development of architecture adhesion agent, have more consequence.
China's construction structure glue comes across the initial stage eighties, helped build the carrier bar in a power transformation building of Liaoyang chemical fibre head factory because designing upper under-reinforced by France in 1978, there are several beam many places crackle to occur, by adopting No. 31 construction structure glues of France west card Dole, with steel sticking at beam bottom reinforcement and strengthening, reach original design intensity, received saving of labor, material-saving, safe and reliable effect.Then formally assigned the research topic of " construction structure glue and application " by the Ministry of Construction in 1980, build the common tackling key problem of institute of section by the Dalian Chemistry and Physics Institute of the Chinese Academy of Sciences and Liaoning, finish problem in nineteen eighty-three, developed the construction structure glue of China's the first practicality, filled up domestic blank in this respect.In the sixties, the aqueduct that also once had some units such as University of Fuzhou building system to break with the epoxyn reparation, the epoxyn wired reinforced concrete members on probation such as institute of section, northeast Railway Bureau are built in Guangzhou.But systematically study with the utilisation technology of releasing construction structure glue and also should first elect the JCN type construction structure glue that Liaoning occurs.
From last century the eighties so far, structure glue just begins to be applied in the bridge strengthening, has obtained certain effect.Mostly the used base-material of structure glue is the reasonable epoxy resin macromolecular compound of ageing-resistant performance, and its initial stage cohesive strength is very high, and effect is fine, can satisfy the each side requirement of design and construction.But organic high molecular compound originally under varying environment condition long term, wears out or the deteriorated phenomenon that is inevitable, and this may cause structural strength, and the especially decline of structure and steel plate interface binding intensity makes steel-bonded reinforcement reinforcement decay or inefficacy.Therefore, the weather resistance research of structure glue is extremely urgent.
At present, before 20th century of China 60, the seventies and the large quantities of civilian and Industrial buildings built of the mid-80 be in maintenance, reinforcing period.With regard to Industrial buildings, three grades of buildings and dangerous factory building are also more.The dangerous caused Serious Accident of hiding in the building structure, " Reinforcement Technology of Concrete Structure standard " draft had been drafted by National Quality ﹠ Technology Inspection Bureau in 1998, comprising the affixing steel plate reinforcement method.And applicable in 2006 nominally issueds.
Steel-bonded reinforcement and bar planting have huge construction market with building structure adhesive in China, and in existing nearly 10,000,000,000 square metres buildings, a large amount of structures and bridge, culvert, the tunnel structure, concrete structure occupies very large proportion.In these concrete structures and structures, a lot of because aging, the damage in the defective of design, construction and the life-time service process and disaster, cause that concrete structure cracking, anti-seismic performance are bad, Lack of support etc. affect the problem that it reaches safely the use function, is badly in need of effective, durable, the new high-tech material of easy construction and the operating technique of reinforcing and repairing.Along with the gradual perfection of steel bonding method and embedding re-bar technique, fast, high-quality, safety, the new variety sqtructural adhesive will more importantly act in the maintenance of reinforced concrete buildings, rebuilding and reinforcement engineering in performance easily, have larger market potential.
Summary of the invention
The purpose of this invention is to provide a kind of structural adhesive for steel bonding.
Structure glue provided by the invention comprises component first and component second; The mass ratio of component first and component second is 100: (15-65); Described component first comprises: Resins, epoxy, thinner, softening agent, toughner and coupling agent; Described component second comprises: modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE).
Described Resins, epoxy can be at least a in bisphenol A type epoxy resin, phenolic aldehyde Resins, epoxy, the aminoepoxy resin; Described thinner can be at least a in propenyl glycidyl ether, butylglycidyl ether and the phenyl glycidyl ether; Described softening agent can be at least a in phthalic ester, phosphoric acid ester and two acid esters; Described toughner can be at least a in thiorubber and the paracril; Described coupling agent can be at least a in organosilane, organic carboxyl acid, polyisocyanates and the titanic acid ester.
Described bisphenol A type epoxy resin specifically can be W-95 Resins, epoxy, F-44 Resins, epoxy or TDE-85 Resins, epoxy etc.Described aminoepoxy resin specifically can be the heatproof aminoepoxy resin, such as VE-3240 Resins, epoxy.Described paracril specifically can be solid nitrile rubber, liquid acrylonitrile butadiene rubber, nbr carboxyl terminal, hydroxy'terminated butadiene nitrile rubber etc.Described phthalic ester specifically can be dibutyl phthalate.
In the described component first, the mass ratio of Resins, epoxy, thinner, softening agent, toughner and coupling agent can be 100: (10-50): (6-40): (10-50): (1-3).In the described component first, the mass ratio of Resins, epoxy, thinner, softening agent, toughner and coupling agent specifically can be 100: 16: 20: 15: 2.
In the described component second, the mass ratio of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE) can be (50-60): (20-50): (30-50).In the described component second, the mass ratio of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE) specifically can be 55: 35: 40.
Described structure glue also can comprise quartz sand.The ratio of the quality sum of described component first and component second and the quality of described quartz sand can be 1: (1.0-2.5).The ratio of the quality sum of described component first and component second and the quality of described quartz sand specifically can be 1: 1.3.
The mass ratio of described component first and described component second specifically can be 4: 1.
During low temperature, for improving the curing speed of structure glue, reduce solidification value, also can comprise curing catalyst in the described component first, such as DMP230.The quality proportioning of described component first and described curing catalyst can be 100: (1-5).
Described component first also can only be comprised of Resins, epoxy, thinner, softening agent, toughner and coupling agent; Described component first also can only be comprised of Resins, epoxy, thinner, softening agent, toughner, coupling agent and quartz sand; Described component first also can only be comprised of Resins, epoxy, thinner, softening agent, toughner, coupling agent and curing catalyst; Described component first also can only be comprised of Resins, epoxy, thinner, softening agent, toughner, coupling agent, quartz sand and curing catalyst.Described component second also can only be comprised of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE); Described component second also can only be comprised of modified polyamide resin, modified fatty amine, Amino Terminated polyether(ATPE) and quartz sand.Described structure glue can only be comprised of component first and component second, also can be comprised of component first, component second and quartz sand, also can add other assistant agent.
The using method of structure glue of the present invention is as follows:
Before the use, bonding component surface (metalwork or concrete adhesive surface) must be cleaned out, and reaches the technology for applying standard.First first, second two components are stirred in this bucket respectively, be mixed in proportion, stir, spread upon on the adherend spare, guarantee to paste position glue amount abundance, slightly overflow with glue and be advisable, used glue must now be joined, and is finished at every turn.Keep adherend spare to fit tightly 24 hours, permanent curing, 72 hours force-applied uses and tests detection.Winter construction, glue want suitable preheating (about 25 ℃) to be advisable, and prolong because of mercury dropped set time.The remaining glue of preparation does not seal preservation in this bucket.
The performance index of structure glue of the present invention see Table 1.
The performance index of table 1 structure glue of the present invention
Structure glue provided by the invention has following advantage:
(1) good adhesive property, stress distribution is even, slip resistance is high, mechanical tenacity is good, can effectively bear the bonding under the multiple situation such as metallic substance and metallic substance, metallic substance and non-metallic material and concrete surface in the engineering structure, sticking anchor reinforcing bar, structure steel bonding, Covered with Angles perfusion reinforcement in the crack member grouting sealing in the solution construction work, the concrete are had good result;
(2) have haftplatte and do not trickle, the characteristics that the bar planting withdrawal resistance is large, limit of harmful substance is far below national technical indicator;
(3) have the characteristics of superpower weather resistance, easy construction and intensity stabilization;
(4) structure glue has good penetrating power to cement, and is superpower with the viscosifying power of concrete.
Structure glue provided by the invention has very strong application and promotional value.
Embodiment
Following embodiment is convenient to understand better the present invention, but does not limit the present invention.Experimental technique among the following embodiment if no special instructions, is ordinary method.Used test materials among the following embodiment if no special instructions, is routine biochemistry reagent shop and purchases available.
The preparation of embodiment 1, structure glue and performance measurement
One, the preparation of structure glue
Form by component first (white), component second (black) with as the quartz sand of filler.
1, the preparation of component first
The component first is comprised of Resins, epoxy, thinner, softening agent, toughner and coupling agent.Resins, epoxy: thinner: softening agent: toughner: coupling agent (mass ratio)=100: 16: 20: 15: 2.
Resins, epoxy: mass ratio is 1: 2 heatproof aminoepoxy resin and bisphenol A epoxide resin;
Heatproof aminoepoxy resin: available from the VE-3240 Resins, epoxy of Wuxi resin processing plant;
Bisphenol A epoxide resin: available from the TDE-85 Resins, epoxy of Wuxi resin processing plant.
Thinner (butylglycidyl ether): model: 501, available from Wuxi resin processing plant.
Softening agent (phthalic ester): dibutyl phthalate, be called for short DBP, model: yh-lbd-2 is available from Wuxi resin processing plant.
Toughner (thiorubber): model: JLY-121, available from Wuxi resin processing plant.
Coupling agent (organosilane): model: KH-560 (γ-Racemic glycidol oxidation propyl trimethoxy silicane) is available from Wuxi resin processing plant.
2, the preparation of component second
Component second is comprised of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE).Polyamide resin: modified fatty amine: Amino Terminated polyether(ATPE) (mass ratio)=55: 35: 40.
Modified polyamide resin: available from Jieshijie Novel Materials Co., Ltd, Shanghai, model: PA, the transparent thick liquid of yellowish brown, the amine value: 400 ± 200, viscosity (40 ℃): 500～2500mPaS.
Modified fatty amine: available from Henan Province's natural selection Industrial Co., Ltd., model: tab-800, the low viscosity transparent liquid, the amine value: 800 ± 50, viscosity (25 ℃): 400-500mPaS.
Amino Terminated polyether(ATPE): available from Yantai people's livelihood chemical company limited, model: T403, colourless or light yellow transparent liquid, viscosity (25 ℃): 9mPaS.
3, the preparation of structure glue
A: filler quartz sand is added in the component first (mass ratio of component first and quartz sand is 1: 1.3).
B: filler quartz sand is added in the component second (mass ratio of component second and quartz sand is 1: 1.3).
Be that 4: 1 A and B packs respectively with mass ratio.
Two, the performance of structure glue
Before the use, bonding component surface (metalwork or concrete adhesive surface) must be cleaned out, and reaches the technology for applying standard.First first, second two components are stirred in this bucket respectively, be mixed in proportion, stir, spread upon on the adherend spare, guarantee to paste position glue amount abundance, slightly overflow with glue and be advisable, used glue must now be joined, and is finished at every turn.Keep adherend spare to fit tightly 24 hours, permanent curing can carry out Performance Detection in 72 hours.
Performance project comprises: colloidal property (tensile strength, tension Young's modulus, elongation, bending strength, ultimate compression strength), viscosifying power (steel-steel stretching slip resistance standard value, the inhomogeneous pull strength of steel-steel, steel-steel adhesion strength, with the concrete cohesive strength of just drawing), aging resistance, non-volatile content (solids content) and freeze-thaw resistance property.
Detected result sees Table 2.
The performance measurement result of table 2 structure glue
The preparation of embodiment 2, structure glue and performance measurement
One, the preparation of structure glue
Form by component first (white), component second (black) with as the quartz sand of filler.
1, the preparation of component first
The component first is comprised of Resins, epoxy, thinner, softening agent, toughner and coupling agent.Resins, epoxy: thinner: softening agent: toughner: coupling agent (mass ratio)=100: 10: 6: 10: 1.
Resins, epoxy (bisphenol A epoxide resin): TDE-85 Resins, epoxy, available from Wuxi resin processing plant.
Thinner (propenyl glycidyl ether): the trade mark: 500, available from Wuxi resin processing plant.
Softening agent (phosphoric acid ester): triphenylphosphate, available from Wuxi resin processing plant.
Toughner (paracril): code name: BNR, available from Wuxi resin processing plant.
Coupling agent (organic carboxyl acid): acetic acid, available from Wuxi resin processing plant.
2, the preparation of component second
Component second is comprised of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE).Polyamide resin: modified fatty amine: Amino Terminated polyether(ATPE) (mass ratio)=50: 20: 30.
Modified polyamide resin: available from Jieshijie Novel Materials Co., Ltd, Shanghai, model: PA, the transparent thick liquid of yellowish brown, the amine value: 400 ± 200, viscosity (40 ℃): 500～2500mPaS.
Modified fatty amine: available from Henan Province's natural selection Industrial Co., Ltd., model: tab-800, the low viscosity transparent liquid, the amine value: 800 ± 50, viscosity (25 ℃): 400-500mPaS.
Amino Terminated polyether(ATPE): available from Yantai people's livelihood chemical company limited, model: T403, colourless or light yellow transparent liquid, viscosity (25 ℃): 9mPaS.
3, the preparation of structure glue
A: filler quartz sand is added in the component first (mass ratio of component first and quartz sand is 1: 1).
B: filler quartz sand is added in the component second (mass ratio of component second and quartz sand is 1: 1).
Be that 100: 15 A and B packs respectively with mass ratio.
Two, the performance of structure glue
Method is with embodiment 1.
Detected result shows that the properties of structure glue is higher than the standard index of A level glue.
The preparation of embodiment 3, structure glue and performance measurement
One, the preparation of structure glue
Form by component first (white), component second (black) with as the quartz sand of filler.
1, the preparation of component first
The component first is comprised of Resins, epoxy, thinner, softening agent, toughner and coupling agent.Resins, epoxy: thinner: softening agent: toughner: coupling agent (mass ratio)=100: 50: 40: 50: 3.
Resins, epoxy (heatproof aminoepoxy resin): model: VE-3240, available from Wuxi resin processing plant.
Thinner (phenyl glycidyl ether): the trade mark: 690, available from Wuxi resin processing plant.
Softening agent (sebate): dioctyl sebacate (DOS), available from Wuxi resin processing plant.
Toughner (thiorubber): model: JLY-121, available from Wuxi resin processing plant.
Coupling agent (polyisocyanates): polymeric polyisocyanate, the trade mark: JQ-1 is available from Wuxi resin processing plant.
2, the preparation of component second
Component second is comprised of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE).Polyamide resin: modified fatty amine: Amino Terminated polyether(ATPE) (mass ratio)=60: 50: 50.
Modified polyamide resin: available from Jieshijie Novel Materials Co., Ltd, Shanghai, model: PA, the transparent thick liquid of yellowish brown, the amine value: 400 ± 200, viscosity (40 ℃): 500～2500mPaS.
Modified fatty amine: available from Henan Province's natural selection Industrial Co., Ltd., model: tab-800, the low viscosity transparent liquid, the amine value: 800 ± 50, viscosity (25 ℃): 400-500mPaS.
Amino Terminated polyether(ATPE): available from Yantai people's livelihood chemical company limited, model: T403, colourless or light yellow transparent liquid, viscosity (25 ℃): 9mPaS.
3, the preparation of structure glue
A: filler quartz sand is added in the component first (mass ratio of component first and quartz sand is 1: 2.5).
B: filler quartz sand is added in the component second (mass ratio of component second and quartz sand is 1: 2.5).
Be that 100: 65 A and B packs respectively with mass ratio.
Two, the performance of structure glue
Method is with embodiment 1.
Detected result shows that the properties of structure glue is higher than the standard index of A level glue.
The preparation of embodiment 4, structure glue and performance measurement
One, the preparation of structure glue
Form by component first (white), component second (black) with as the quartz sand of filler.
1, the preparation of component first
The component first is comprised of Resins, epoxy, thinner, softening agent, toughner and coupling agent.Resins, epoxy: thinner: softening agent: toughner: coupling agent: curing catalyst (mass ratio)=100: 16: 19: 15: 2: 3.
Resins, epoxy (phenolic aldehyde Resins, epoxy): model: F-44, available from Wuxi resin processing plant.
Thinner (butylglycidyl ether): model: 501, available from Wuxi resin processing plant.
Softening agent (phthalic ester): dibutyl phthalate, be called for short DBP, model: yh-lbd-2 is available from Wuxi resin processing plant.
Toughner (paracril): available from Wuxi resin processing plant.
Coupling agent (titanic acid ester): tetrabutyl titanate, available from Wuxi resin processing plant.
Curing catalyst: model: DMP230 is available from Wuxi resin processing plant.
2, the preparation of component second
Component second is comprised of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE).Polyamide resin: modified fatty amine: Amino Terminated polyether(ATPE) (mass ratio)=55: 35: 40.
Modified polyamide resin: available from Jieshijie Novel Materials Co., Ltd, Shanghai, model: PA, the transparent thick liquid of yellowish brown, the amine value: 400 ± 200, viscosity (40 ℃): 500～2500mPaS.
Modified fatty amine: available from Henan Province's natural selection Industrial Co., Ltd., model: tab-800, the low viscosity transparent liquid, the amine value: 800 ± 50, viscosity (25 ℃): 400-500mPaS.
Amino Terminated polyether(ATPE): available from Yantai people's livelihood chemical company limited, model: T403, colourless or light yellow transparent liquid, viscosity (25 ℃): 9mPaS.
3, the preparation of structure glue
A: filler quartz sand is added in the component first (mass ratio of component first and quartz sand is 1: 1.3).
B: filler quartz sand is added in the component second (mass ratio of component second and quartz sand is 1: 1.3).
Be that 4: 1 A and B packs respectively with mass ratio.
Two, the performance of structure glue
Method is with embodiment 1.
Detected result shows that the properties of structure glue is higher than the standard index of A level glue.
Claims (8)
1. a structure glue comprises that the quality proportioning is 100: component first (15-65) and component second;
Described component first comprises: Resins, epoxy, thinner, softening agent, toughner and coupling agent; Described component second comprises: modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE);
Described Resins, epoxy is at least a in phenolic aldehyde Resins, epoxy and the aminoepoxy resin; Described thinner is at least a in propenyl glycidyl ether, butylglycidyl ether and the phenyl glycidyl ether; Described softening agent is at least a in phthalic ester, phosphoric acid ester and two acid esters; Described toughner is at least a in thiorubber and the paracril; Described coupling agent is at least a in organosilane, organic carboxyl acid, polyisocyanates and the titanic acid ester; In the described component first, the mass ratio of Resins, epoxy, thinner, softening agent, toughner and coupling agent is 100: (10-50): (6-40): (10-50): (1-3);
In the described component second, the mass ratio of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE) is (50-60): (20-50): (30-50).
2. structure glue as claimed in claim 1, it is characterized in that: in the described component first, the mass ratio of Resins, epoxy, thinner, softening agent, toughner and coupling agent is 100: 16: 20: 15: 2.
3. structure glue as claimed in claim 1, it is characterized in that: in the described component second, the mass ratio of modified polyamide resin, modified fatty amine and Amino Terminated polyether(ATPE) is 55: 35: 40.
4. such as arbitrary described structure glue in the claims 1 to 3, it is characterized in that: described structure glue also comprises quartz sand.
5. structure glue as claimed in claim 4, it is characterized in that: the ratio of the quality sum of described component first and component second and the quality of described quartz sand is 1: (1.0-2.5).
6. structure glue as claimed in claim 5, it is characterized in that: the ratio of the quality sum of described component first and component second and the quality of described quartz sand is 1: 1.3.
7. such as arbitrary described structure glue in the claims 1 to 3, it is characterized in that: the mass ratio of described component first and described component second is 4: 1.
8. such as arbitrary described structure glue in the claims 1 to 3, it is characterized in that: also comprise curing catalyst in the described component first.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910086614 CN101921566B (en) | 2009-06-12 | 2009-06-12 | Structural adhesive for steel bonding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910086614 CN101921566B (en) | 2009-06-12 | 2009-06-12 | Structural adhesive for steel bonding |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101921566A CN101921566A (en) | 2010-12-22 |
| CN101921566B true CN101921566B (en) | 2013-02-06 |
Family
ID=43336791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910086614 Expired - Fee Related CN101921566B (en) | 2009-06-12 | 2009-06-12 | Structural adhesive for steel bonding |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101921566B (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408862B (en) * | 2011-10-07 | 2013-04-10 | 北京天诚宇新材料技术有限公司 | Antifriction putty |
| CN103450834B (en) * | 2013-08-23 | 2015-01-28 | 吴江华诚复合材料科技有限公司 | Metal adhesive and preparation method thereof |
| CN106700998A (en) * | 2015-11-17 | 2017-05-24 | 中科院广州化学有限公司南雄材料生产基地 | High-performance epoxy anchor adhesive, as well as preparation method and application thereof |
| CN106499065A (en) * | 2016-10-13 | 2017-03-15 | 常州华东人防设备有限公司 | Punch after civil air defense constructions and installations fast plugging device and the steel bonding glue for plugging device |
| CN107216556A (en) * | 2017-06-09 | 2017-09-29 | 金川集团股份有限公司 | A kind of titanium starting sheet bound edge rubber and the method using the rubber bound edge |
| CN107189716A (en) * | 2017-07-05 | 2017-09-22 | 苏州润德新材料有限公司 | A kind of adhesive on metallic article |
| CN107382191B (en) * | 2017-07-24 | 2020-02-07 | 国网山东省电力公司电力科学研究院 | Joint mixture between concrete and steel structure and construction method thereof |
| CN107880832A (en) * | 2017-11-30 | 2018-04-06 | 安徽坤大化学锚固有限公司 | A kind of two-component anchor pole impregnated carbon fiber glue and preparation method thereof |
| CN107987771A (en) * | 2017-11-30 | 2018-05-04 | 安徽坤大化学锚固有限公司 | A kind of two-component anchor pole steel bonding glue and preparation method thereof |
| CN108659789B (en) * | 2018-05-22 | 2020-05-12 | 交通运输部公路科学研究所 | Method for shear reinforcement of reinforced concrete bridge |
| CN108865030A (en) * | 2018-05-30 | 2018-11-23 | 南京天力信科技实业有限公司 | A kind of pouring type steel bonding glue and preparation method thereof |
| CN109111885A (en) * | 2018-07-20 | 2019-01-01 | 吴伟华 | A kind of epoxy resin-matrix steel bonding glue |
| CN109439246B (en) * | 2018-09-11 | 2021-04-23 | 法施达(大连)实业集团有限公司 | Two-component epoxy structural adhesive and preparation method thereof |
| CN110184951A (en) * | 2019-05-23 | 2019-08-30 | 长沙理工大学 | Combined bridge deck structure and reinforced construction method with direction across bridge reinforcing strip |
| CN110205937A (en) * | 2019-05-23 | 2019-09-06 | 长沙理工大学 | Orthotropic plate-ultra-high performance concrete combined bridge deck structure and construction method |
| CN110272697B (en) * | 2019-07-03 | 2020-12-15 | 华东交通大学 | Structural adhesive containing quartz sand, preparation method and application thereof |
| CN110423584A (en) * | 2019-07-11 | 2019-11-08 | 合肥市公路桥梁工程有限责任公司 | A kind of highway bridge distress in concrete surface-closed glue |
| CN110655890A (en) * | 2019-08-30 | 2020-01-07 | 苏州德圣辉新能源科技有限公司 | Waterproof repair adhesive for solar module back plate |
| CN111205523B (en) * | 2020-02-25 | 2021-12-07 | 厦门联博橡胶制品有限公司 | Rubber metal sleeve and preparation process thereof |
| CN112391136A (en) * | 2020-04-17 | 2021-02-23 | 潼灏(上海)材料科技有限公司 | Epoxy resin composition for steel bridge deck pavement bonding layer and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1546589A (en) * | 2003-12-09 | 2004-11-17 | 辽宁大通公路工程有限公司 | Dynamic structural adhesive for bridge |
| CN1570010A (en) * | 2004-04-23 | 2005-01-26 | 阚小勇 | Making method of epoxy resin adhesive for building |
| EP1695990A1 (en) * | 2005-02-28 | 2006-08-30 | Dow Global Technologies Inc. | Two-component epoxy adhesive composition |
| US20090048370A1 (en) * | 2007-08-17 | 2009-02-19 | Dow Global Technologies, Inc. | Two part crash durable epoxy adhesives |
| CN101423358A (en) * | 2008-11-20 | 2009-05-06 | 同济大学 | Method for preparing high impact resistant epoxy resin mortar |
-
2009
- 2009-06-12 CN CN 200910086614 patent/CN101921566B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1546589A (en) * | 2003-12-09 | 2004-11-17 | 辽宁大通公路工程有限公司 | Dynamic structural adhesive for bridge |
| CN1570010A (en) * | 2004-04-23 | 2005-01-26 | 阚小勇 | Making method of epoxy resin adhesive for building |
| EP1695990A1 (en) * | 2005-02-28 | 2006-08-30 | Dow Global Technologies Inc. | Two-component epoxy adhesive composition |
| US20090048370A1 (en) * | 2007-08-17 | 2009-02-19 | Dow Global Technologies, Inc. | Two part crash durable epoxy adhesives |
| CN101423358A (en) * | 2008-11-20 | 2009-05-06 | 同济大学 | Method for preparing high impact resistant epoxy resin mortar |
Non-Patent Citations (4)
| Title |
|---|
| 低黏度慢固化环氧胶粘剂的研究;胡高平等;《粘接》;20080430;25-26页 * |
| 潘荣.环氧结构胶的耐老化性能及改性研究.《中国优秀硕士学位论文全文数据库工程科技Ⅱ辑》.2008,全文. |
| 环氧结构胶的耐老化性能及改性研究;潘荣;《中国优秀硕士学位论文全文数据库工程科技Ⅱ辑》;20081215;全文 * |
| 胡高平等.低黏度慢固化环氧胶粘剂的研究.《粘接》.2008,25-26页. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101921566A (en) | 2010-12-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101921566B (en) | Structural adhesive for steel bonding | |
| Hollaway | A review of the present and future utilisation of FRP composites in the civil infrastructure with reference to their important in-service properties | |
| Hollaway et al. | Progress in the technique of upgrading metallic structures with advanced polymer composites | |
| CN102659369B (en) | Epoxy emulsion modified quick repair mortar for concrete roads and bridges and preparation method for mortar | |
| CN103555245B (en) | Epoxy adhesive for repairing and reinforcing hinge joint and application of epoxy adhesive | |
| CN103498683A (en) | Tunnel early-strength quick strengthening method based on quick-set composite mortar and fiber woven mesh | |
| AU2020103012A4 (en) | Steel fiber polymer concrete composite structure as well as preparation method and application thereof | |
| CN106927364B (en) | The antifatigue connection method of steel crane beam and rail | |
| KR101778210B1 (en) | Expansion joint construction method using elastic polymer concrete joint | |
| CN107558364A (en) | A kind of low drying shrinkage cement-based material bridge deck pavement structure of ultra-tough and construction method | |
| CN104652242A (en) | Derrick connecting structure used for reinforcing PSC (Pre-stressed Concrete) continuous box girder bridge and construction method | |
| CN203890900U (en) | Structure for quickly restoring hollow slab bridge hinge joint | |
| CN203559329U (en) | Steel-RPC (reactive powder concrete) combined bridge | |
| Nordin | Strengthening structures with externally prestressed tendons | |
| CN102505641A (en) | Repair reinforcing structure of steel bridge deck and repair reinforcing method of repair reinforcing structure | |
| CN103556563B (en) | Steel-RPC combined bridge | |
| CN102817318B (en) | Asphalt-free steel-RPC (reactive powder concrete) combined deck structure and construction method thereof | |
| Wu | Structural strengthening and integrity with hybrid FRP composites | |
| Verani et al. | Composite linings: ground support and waterproofing through the use of a fully bonded membrane | |
| CN202755309U (en) | Combined bridge deck structure of asphalt-free steel and reactive powder concrete (RPC) | |
| CN101817662B (en) | DBB concrete pavement crack repair material | |
| Nordin | Strengthening structures with externally prestressed tendons: literature review | |
| CN113774820A (en) | Road and bridge crack repairing and fixing structure | |
| CN112627573A (en) | Rigid FRP grid/high-ductility high-permeability concrete restrained reinforced concrete column and preparation method thereof | |
| CN112430021A (en) | Damaged RC beam reinforced by unidirectional FRP grid/high-ductility high-permeability concrete composite and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: BEIJING GONGKE BRIDGE TECHNOLOGY CO., LTD. Effective date: 20130106 Owner name: RESEARCH INSTITUTE OF HIGHWAY MINISTRY OF TRANSPOR Free format text: FORMER OWNER: BEIJING GONGKE BRIDGE TECHNOLOGY CO., LTD. Effective date: 20130106 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20130106 Address after: 100088 Beijing city Haidian District Xitucheng Road No. 8, room 207, Xiaobailou Patentee after: Research Institute of Highway Ministry of Transport Patentee after: Beijing Gongke Bridge Technology Co., Ltd. Address before: 100088 Beijing city Haidian District Xitucheng Road No. 8, room 207, Xiaobailou Patentee before: Beijing Gongke Bridge Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130206 Termination date: 20180612 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |