CN107880832A - A kind of two-component anchor pole impregnated carbon fiber glue and preparation method thereof - Google Patents
A kind of two-component anchor pole impregnated carbon fiber glue and preparation method thereof Download PDFInfo
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- CN107880832A CN107880832A CN201711239548.1A CN201711239548A CN107880832A CN 107880832 A CN107880832 A CN 107880832A CN 201711239548 A CN201711239548 A CN 201711239548A CN 107880832 A CN107880832 A CN 107880832A
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- component
- epoxy resin
- carbon fiber
- raw material
- anchor pole
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
- C08G59/58—Amines together with other curing agents with polycarboxylic acids or with anhydrides, halides, or low-molecular-weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
- C08G59/60—Amines together with other curing agents with amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A kind of two-component anchor pole impregnated carbon fiber glue, including the raw material of following mass parts are prepared：Component A：E51 epoxy resin 95 105, the epoxy resin 18 22 of CYDF 180, cycloaliphatic epoxy resin 8 12, aerosil 24, coupling agent 24, antioxidant 13, diluent 14 16, nano silicon 13；B component：Amine terminated polyether 20 30, polyamide 10 20, cis-butenedioic anhydride 35, glycerine 0.2 0.4；Described component A and the proportioning of B component are A:B=3:1 (mass parts).Beneficial effects of the present invention are：Inventive formulation is reasonable, processing technology is scientific and normal, not only intensity is high for impregnated carbon fiber glue after preparation, it is and ageing-resistant, its actual radiation resistance is also superior to existing product, when in use, it is directed to water-fast, unholiness and has extremely strong adhesive property with oil meter face, therefore very big convenience is brought to engineering construction.
Description
Technical field
The present invention relates to dipping glue processing technique field, and in particular to a kind of two-component anchor pole with impregnated carbon fiber glue and its
Preparation method.
Background technology
The structural bond that impregnated carbon fiber glue is applied to carbon fiber plate and concrete, steel component, masonry component is constructed
Or the carbon fiber plate bonding construction of reinforced concrete for tension strain component.
Anchor pole, it is the most basic part of roadway support among contemporary colliery, he is by the surrounding rock consolidation in tunnel one
Rise, make country rock itself supporting itself.Present anchor pole is applied not only to mine, is also used in engineering technology, side slope, tunnel, dam body
Carry out main body reinforcing.Anchor pole is connected as the tensional element for going deep into stratum, its one end with engineering structure, and the other end gos deep into stratum
In, whole anchor pole is divided into free segment and anchoring section, and free segment refers to the region that the pulling force at anchor pole head is reached to anchoring body, its work(
Can be that prestressing force is applied to anchor pole.
Anchor pole is carrying out routine in use, because it is directly contacted with media such as concrete, and routine is in use, must use
Corresponding glue is operated, and so as to ensure actual using effect, during normal use, dipping glue is indispensable one
Kind, but its actual formula of glue and processing technology not science are impregnated on existing market, actual use effect can not be ensured
Fruit, so as to result in dipping glue poor performance, using effect is poor, can not obtain comparatively effective use.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of processing technology scientific and normal, and formula is taken rationally, is added
Impregnated carbon fiber glue effect superior performance after work, using effect good two-component anchor pole impregnated carbon fiber glue and its preparation side
Method.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of two-component anchor pole impregnated carbon fiber glue, it is characterised in that the raw material including following mass parts is prepared：
Component A
E51 epoxy resin 95-105, CYDF-180 epoxy resin 18-22, cycloaliphatic epoxy resin 8-12, gas phase titanium dioxide
Silicon 2-4, coupling agent 2-4, antioxidant 1-3, diluent 14-16, nano silicon 1-3；
B component
Amine terminated polyether 20-30, polyamide 10-20, cis-butenedioic anhydride 3-5, glycerine 0.2-0.4；
Described component A and the proportioning of B component are A:B=3:1 (mass parts).
Preferred mass part of above-mentioned each raw material is：
Component A
E51 epoxy resin 100, CYDF-180 epoxy resin 20, cycloaliphatic epoxy resin 10, aerosil 3, coupling
Agent 3, antioxidant 2, diluent 15, nano silicon 2；
B component
Amine terminated polyether 25, polyamide 105, cis-butenedioic anhydride 4, glycerine 0.3；
Described component A and the proportioning of B component are A:B=3:1 (mass parts)
Diluent in the raw material is polypropylene glycol diglycidyl ether；
Described polyamide is 651# polyamide；
The method for preparing above-mentioned two-component anchor pole impregnated carbon fiber glue, it is characterised in that comprise the steps：
1) the E51 epoxy resin in component A raw material, CYDF-180 epoxy resin, cycloaliphatic epoxy resin are merged
Afterwards, stir, it is standby；
2) after merging the aerosil in component A raw material and nano silicon, it is standby to obtain pulvis；
3) compounded after the material in above-mentioned steps 1 and step 2 is merged it is uniform, then by the coupling agent in raw material,
Antioxidant and diluent are added thereto, and after being again stirring for uniformly, are obtained component A and are just expected；
4) after merging the amine terminated polyether in B component raw material, polyamide, cis-butenedioic anhydride and glycerine uniformly, at the beginning of obtaining B component
Material；
5) component A in above-mentioned steps 3 is just expected with B component just to expect according to mass ratio 3:After 1 merges and stirs,
Finished product can be obtained.
Beneficial effects of the present invention are：Inventive formulation is reasonable, and processing technology is scientific and normal, the impregnated carbon fiber after preparation
Not only intensity is high for glue, and ageing-resistant, and its actual radiation resistance is also superior to existing product, when in use, is directed to water-fast, no
It is clean and have extremely strong adhesive property with oil meter face, therefore very big convenience is brought to engineering construction.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of two-component anchor pole impregnated carbon fiber glue, including the raw material of following mass parts are prepared：
Component A
E51 epoxy resin 105, CYDF-180 epoxy resin 22, cycloaliphatic epoxy resin 12, aerosil 4, coupling
Agent 4, antioxidant 3, diluent 16, nano silicon 3；
B component
Amine terminated polyether 30, polyamide 20, cis-butenedioic anhydride 5, glycerine 0.4；
Described component A and the proportioning of B component are A:B=3:1 (mass parts)
The method for preparing above-mentioned two-component anchor pole impregnated carbon fiber glue, comprises the steps：
1) the E51 epoxy resin in component A raw material, CYDF-180 epoxy resin, cycloaliphatic epoxy resin are merged
Afterwards, stir, it is standby；
2) after merging the aerosil in component A raw material and nano silicon, it is standby to obtain pulvis；
3) compounded after the material in above-mentioned steps 1 and step 2 is merged it is uniform, then by the coupling agent in raw material,
Antioxidant and diluent are added thereto, and after being again stirring for uniformly, are obtained component A and are just expected；
4) after merging the amine terminated polyether in B component raw material, polyamide, cis-butenedioic anhydride and glycerine uniformly, at the beginning of obtaining B component
Material；
5) component A in above-mentioned steps 3 is just expected with B component just to expect according to mass ratio 3:After 1 merges and stirs,
Finished product can be obtained.
Embodiment 2
A kind of two-component anchor pole impregnated carbon fiber glue, including the raw material of following mass parts are prepared：
Component A
E51 epoxy resin 95, CYDF-180 epoxy resin 18, cycloaliphatic epoxy resin 8, aerosil 2, coupling agent
2nd, antioxidant 1, diluent 14, nano silicon 1；
B component
Amine terminated polyether 20, polyamide 10, cis-butenedioic anhydride 3, glycerine 0.2；
Described component A and the proportioning of B component are A:B=3:1 (mass parts)
The method for preparing above-mentioned two-component anchor pole impregnated carbon fiber glue, comprises the steps：
1) the E51 epoxy resin in component A raw material, CYDF-180 epoxy resin, cycloaliphatic epoxy resin are merged
Afterwards, stir, it is standby；
2) after merging the aerosil in component A raw material and nano silicon, it is standby to obtain pulvis；
3) compounded after the material in above-mentioned steps 1 and step 2 is merged it is uniform, then by the coupling agent in raw material,
Antioxidant and diluent are added thereto, and after being again stirring for uniformly, are obtained component A and are just expected；
4) after merging the amine terminated polyether in B component raw material, polyamide, cis-butenedioic anhydride and glycerine uniformly, at the beginning of obtaining B component
Material；
5) component A in above-mentioned steps 3 is just expected with B component just to expect according to mass ratio 3:After 1 merges and stirs,
Finished product can be obtained.
Embodiment 3
A kind of two-component anchor pole impregnated carbon fiber glue, including the raw material of following parts by weight are prepared：
Component A
E51 epoxy resin 100kg, CYDF-180 epoxy resin 20kg, cycloaliphatic epoxy resin 10kg, aerosil
3kg, coupling agent 3kg, antioxidant 2kg, polypropylene glycol diglycidyl ether 15kg, nano silicon 2kg；
B component
Amine terminated polyether 25kg, 651# polyamide 105kg, cis-butenedioic anhydride 4kg, glycerine 0.3kg；
Described component A and the proportioning of B component are A:B=3:1 (parts by weight)
The method for preparing above-mentioned two-component anchor pole impregnated carbon fiber glue, comprises the steps：
1) the E51 epoxy resin in component A raw material, CYDF-180 epoxy resin, cycloaliphatic epoxy resin are merged
Afterwards, stir, it is standby；
2) after merging the aerosil in component A raw material and nano silicon, it is standby to obtain pulvis；
3) compounded after the material in above-mentioned steps 1 and step 2 is merged it is uniform, then by the coupling agent in raw material,
Antioxidant and diluent are added thereto, and after being again stirring for uniformly, are obtained component A and are just expected；
4) after merging the amine terminated polyether in B component raw material, polyamide, cis-butenedioic anhydride and glycerine uniformly, at the beginning of obtaining B component
Material；
5) material at the beginning of the component A in above-mentioned steps 3 is merged with material at the beginning of B component after stirring, you can obtain finished product.
It is the examining report of the impregnated carbon fiber glue of preparation in the present invention below：
As can be seen here, the dipping glue produced in the application, its property indices is higher by conventional criteria, and is carrying out phase
It is answering in use, as can be seen here, the application impregnates the performance advantage of glue.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
1. a kind of two-component anchor pole impregnated carbon fiber glue, it is characterised in that the raw material including following mass parts is prepared：
Component A
E51 epoxy resin 95-105, CYDF-180 epoxy resin 18-22, cycloaliphatic epoxy resin 8-12, aerosil 2-
4th, coupling agent 2-4, antioxidant 1-3, diluent 14-16, nano silicon 1-3；
B component
Amine terminated polyether 20-30, polyamide 10-20, cis-butenedioic anhydride 3-5, glycerine 0.2-0.4；
Described component A and the proportioning of B component are A:B=3:1 (mass parts).
2. two-component anchor pole impregnated carbon fiber glue according to claim 1, it is characterised in that the preferred mass of each raw material
Part it is：
Component A
E51 epoxy resin 100, CYDF-180 epoxy resin 20, cycloaliphatic epoxy resin 10, aerosil 3, coupling agent 3,
Antioxidant 2, diluent 15, nano silicon 2；
B component
Amine terminated polyether 25, polyamide 105, cis-butenedioic anhydride 4, glycerine 0.3.
Described component A and the proportioning of B component are A:B=3:1 (mass parts).
3. two-component anchor pole impregnated carbon fiber glue according to claim 1, it is characterised in that：Dilution in the raw material
Agent is polypropylene glycol diglycidyl ether.
4. two-component anchor pole impregnated carbon fiber glue according to claim 1, it is characterised in that：Described polyamide is
651# polyamide.
5. the method for two-component anchor pole impregnated carbon fiber glue in application the claims 1 or 2, it is characterised in that including under
State step：
1) after merging the E51 epoxy resin in component A raw material, CYDF-180 epoxy resin, cycloaliphatic epoxy resin, stir
Mix uniformly, it is standby；
2) after merging the aerosil in component A raw material and nano silicon, it is standby to obtain pulvis；
3) compounded after the material in above-mentioned steps 1 and step 2 is merged uniformly, then by the coupling agent in raw material, antioxygen
Agent and diluent are added thereto, and after being again stirring for uniformly, are obtained component A and are just expected；
4) after merging the amine terminated polyether in B component raw material, polyamide, cis-butenedioic anhydride and glycerine uniformly, obtain B component and just expect；
5) component A in above-mentioned steps 3 is just expected with B component just to expect according to mass ratio 3:After 1 merges and stirs, you can
Obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711239548.1A CN107880832A (en) | 2017-11-30 | 2017-11-30 | A kind of two-component anchor pole impregnated carbon fiber glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711239548.1A CN107880832A (en) | 2017-11-30 | 2017-11-30 | A kind of two-component anchor pole impregnated carbon fiber glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107880832A true CN107880832A (en) | 2018-04-06 |
Family
ID=61776266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711239548.1A Pending CN107880832A (en) | 2017-11-30 | 2017-11-30 | A kind of two-component anchor pole impregnated carbon fiber glue and preparation method thereof |
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| CN (1) | CN107880832A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921566A (en) * | 2009-06-12 | 2010-12-22 | 北京公科固桥技术有限公司 | Structural adhesive for steel bonding |
| CN103756610A (en) * | 2013-05-13 | 2014-04-30 | 湖南柯盛新材料有限公司 | Double-component yellowing resistance epoxy resin adhesive and preparation method thereof |
-
2017
- 2017-11-30 CN CN201711239548.1A patent/CN107880832A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921566A (en) * | 2009-06-12 | 2010-12-22 | 北京公科固桥技术有限公司 | Structural adhesive for steel bonding |
| CN103756610A (en) * | 2013-05-13 | 2014-04-30 | 湖南柯盛新材料有限公司 | Double-component yellowing resistance epoxy resin adhesive and preparation method thereof |
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