CN101921119A - Environmental-friendly dry type vibrating material - Google Patents

Environmental-friendly dry type vibrating material Download PDF

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Publication number
CN101921119A
CN101921119A CN 201010219596 CN201010219596A CN101921119A CN 101921119 A CN101921119 A CN 101921119A CN 201010219596 CN201010219596 CN 201010219596 CN 201010219596 A CN201010219596 A CN 201010219596A CN 101921119 A CN101921119 A CN 101921119A
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parts
environment
dry type
type vibrating
vibrating material
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CN101921119B (en
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傅水明
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Deqing Kerry high temperature materials Limited by Share Ltd
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KAIRUI NEW MATERIAL Ltd Co
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Abstract

The invention discloses an environment-friendly dry type vibrating material which is characterized by comprising the following raw materials in parts by weight: 45 parts of magnesium stone sand, 51 parts of fused magnesia, 2-5 parts of sodium metasilicate pentahydrate, 2 parts of phenolic resin and 0.2 part of urotropin. The environment-friendly dry type vibrating material has improved bending resistance and pressure resistant strength and favorable high-temperature service performance; through the experiment, the environment-friendly dry type vibrating material has the following performances: at a stage of 220DEG C*24 hours, the volume density is not less than 2.10g/cm<3>, the bending resistant strength is not less than 5.1MPa and the pressure resistant strength is not less than 7.45MPa; and at a stage of 1500DEG C*3 hours, the bending resistant strength is not less than 7.6MPa, the pressure resistant strength is not less than 12MPa and the linear change percentage is -1.9 percent, which can effectively meet the use requirement of refining. In addition, by using the sodium metasilicate pentahydrate, compared with the prior art, the invention can effectively reduce the content of the phenolic resin, that is to say, the invention reduces the content of carbon, thus the environment-friendly dry type vibrating material is more environment-friendly.

Description

Environment-protection dry type vibrating material
Technical field
The present invention relates to a kind of amorphous refractory, especially a kind of environment-protection dry type vibrating material.
Background technology
Existing refractory materials is divided into setting and unsetting two classes, and unshape refractory comprises metallurgical with tundish paint, dry-type vibration material, electric furnace spraying and repairing material and various refractory castablies etc.Existing dry-type vibration material is a main raw material with the magnesia raw material, is made up of the additive and the wedding agent of some amount and proportioning, and this series products adopts the prescription of the dry-type vibration material nineties, the normal usually AL that adopts 2O 3Perhaps micro mist such as SiO2 and solid phenolic resin be as wedding agent, ubiquity that intensity is low, work-ing life not high situation.
Because not only working temperature is higher for each element in the furnace, and bearing molten steel and slag stronger wash away erosion, therefore anti-folding and compressive strength and high temperature use properties are two important indicators of dry-type vibration material, and existing dry-type vibration material can not effectively satisfy the service requirements of furnace.
Summary of the invention
A kind of anti-folding that provides for the deficiency that solves above-mentioned technology and the environment-protection dry type vibrating material that compressive strength increases, the high temperature use properties is good are provided.
In order to achieve the above object, the environment-protection dry type vibrating material that the present invention is designed, it is characterized in that it is made up of the following raw materials in parts by weight proportioning: magnesium is pressed against 45 parts in sand; 51 parts of electrosmelted magnesite clinkers; 2 parts~5 parts of metasilicate pentahydrate sodiums;
2 parts in resol; 0.2 part of urotropine.
As preferably, comprise 20 parts of 5-0mm electrosmelted magnesite clinkers, 31 parts of 180 order electrosmelted magnesite clinkers in described 51 parts of electrosmelted magnesite clinkers.
As preferably, described metasilicate pentahydrate sodium is 4 parts.
As preferably, described magnesium is pressed against sand and is pressed against sand for 5-0mm magnesium.
As preferably, described magnesium is pressed against sand and is pressed against sand for useless magnesium, can further save cost, and described electrosmelted magnesite clinker is 96 electrosmelted magnesite clinkers.
The resulting environment-protection dry type vibrating material of the present invention, anti-folding increases with compressive strength, the high temperature use properties is good, through overtesting, during 220 ℃ * 24h: volume density 〉=2.10g/cm 3, folding strength 〉=5.1Mpa, compressive strength 〉=7.45Mpa; During 1500 ℃ * 3h: folding strength 〉=7.6Mpa, compressive strength 〉=12Mpa, linear change % are-1.9%, can effectively satisfy the service requirements of furnace.In addition, adopted metasilicate pentahydrate sodium,, can effectively reduce the content of resol, promptly reduced carbon content, so the more environmental protection of the resulting environment-protection dry type vibrating material of the present invention than prior art.
Embodiment
The present invention is further described by the following embodiment.
Embodiment 1
The described environment-protection dry type vibrating material of present embodiment, it is made up of the following raw materials in parts by weight proportioning:
It is made up of the following raw materials in parts by weight proportioning: magnesium is pressed against 45 parts in sand; 51 parts of electrosmelted magnesite clinkers; 2 parts of metasilicate pentahydrate sodiums; 2 parts in resol; 0.2 part of urotropine.
The production technique of the described environment-protection dry type vibrating material of present embodiment is: after the weighing according to the above ratio of each raw material, earlier magnesium being pressed against sand, electrosmelted magnesite clinker mixed in planetary-type mixer 7 minutes, again remaining material is added in the planetary-type mixer and mixed 5 minutes, make finished product coating, carry out weighing, packing.(planetary-type mixer is the efficient whipping device to multiple powder mixing stirring, dispersion, homogeneous commonly used in a kind of industry.)
The performance of the described environment-protection dry type vibrating material of present embodiment (actual measurement) is as following table:
Figure BDA0000023090050000021
Embodiment 2
The described environment-protection dry type vibrating material of present embodiment, it is made up of the following raw materials in parts by weight proportioning:
Magnesium is pressed against 45 parts in sand; 20 parts of 96 electrosmelted magnesite clinkers of 5-0mm; 31 parts of 180 order electrosmelted magnesite clinkers;
3 parts of metasilicate pentahydrate sodiums; 2 parts in resol; 0.2 part of urotropine.
The production technique of the described environment-protection dry type vibrating material of present embodiment is: after the weighing according to the above ratio of each raw material, earlier magnesium being pressed against sand, electrosmelted magnesite clinker mixed in planetary-type mixer 6 minutes, again remaining material is added in the planetary-type mixer and mixed 5 minutes, make finished product coating, carry out weighing, packing.
The performance of the described environment-protection dry type vibrating material of present embodiment (actual measurement) is as following table:
Figure BDA0000023090050000031
Embodiment 3
The described environment-protection dry type vibrating material of present embodiment, metasilicate pentahydrate sodium is 4 parts as different from Example 2, and its performance (actual measurement) is as following table:
Figure BDA0000023090050000032
Embodiment 4
The described environment-protection dry type vibrating material of present embodiment, metasilicate pentahydrate sodium is 5 parts as different from Example 2, and its performance (actual measurement) is as following table:
As seen from the above-described embodiment, when 4 parts of metasilicate pentahydrate sodiums, the high-temperature behavior of product is best, can obtain higher tropical intensity.In order to save cost, described magnesium is pressed against sand can press against sand for useless magnesium.

Claims (5)

1. environment-protection dry type vibrating material is characterized in that it is made up of the following raw materials in parts by weight proportioning:
Magnesium is pressed against 45 parts in sand; 51 parts of electrosmelted magnesite clinkers; 2 parts~5 parts of metasilicate pentahydrate sodiums;
2 parts in resol; 0.2 part of urotropine.
2. environment-protection dry type vibrating material according to claim 1 is characterized in that comprising in described 51 parts of electrosmelted magnesite clinkers 20 parts of 5-0mm electrosmelted magnesite clinkers, 31 parts of 180 order electrosmelted magnesite clinkers.
3. environment-protection dry type vibrating material according to claim 1 and 2 is characterized in that described metasilicate pentahydrate sodium is 4 parts.
4. environment-protection dry type vibrating material according to claim 3 is characterized in that described magnesium presses against sand and press against sand for 5-0mm magnesium.
5. environment-protection dry type vibrating material according to claim 4 is characterized in that it is that useless magnesium is pressed against sand that described magnesium is pressed against sand, and described electrosmelted magnesite clinker is 96 electrosmelted magnesite clinkers.
CN 201010219596 2010-07-07 2010-07-07 Environmental-friendly dry type vibrating material Active CN101921119B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467113A (en) * 2013-08-22 2013-12-25 长兴攀江冶金材料有限公司 Baking-free magnesian vibration material
CN105236994A (en) * 2015-08-26 2016-01-13 北京利尔高温材料股份有限公司 Dry vibration material used in tundish, and preparation method thereof
CN107445629A (en) * 2017-08-31 2017-12-08 云南濮耐昆钢高温材料有限公司 A kind of environment-friendly type composite dry material bonding agent and its application method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1821178A (en) * 2006-03-09 2006-08-23 武汉科技大学 Method for preparing middle ladle dry vabrative material
CN101613216A (en) * 2009-04-09 2009-12-30 北京利尔高温材料股份有限公司 A kind of environment-friendly flowing tundish dry material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1821178A (en) * 2006-03-09 2006-08-23 武汉科技大学 Method for preparing middle ladle dry vabrative material
CN101613216A (en) * 2009-04-09 2009-12-30 北京利尔高温材料股份有限公司 A kind of environment-friendly flowing tundish dry material and preparation method thereof

Non-Patent Citations (1)

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Title
《炼钢》 20070831 王健东等 RH炉用高级镁铬砖的研究与侵蚀机理分析 第46页结论部分 1-5 , 第04期 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467113A (en) * 2013-08-22 2013-12-25 长兴攀江冶金材料有限公司 Baking-free magnesian vibration material
CN105236994A (en) * 2015-08-26 2016-01-13 北京利尔高温材料股份有限公司 Dry vibration material used in tundish, and preparation method thereof
CN105236994B (en) * 2015-08-26 2018-05-22 北京利尔高温材料股份有限公司 It is a kind of for dry-type vibration material of tundish and preparation method thereof
CN107445629A (en) * 2017-08-31 2017-12-08 云南濮耐昆钢高温材料有限公司 A kind of environment-friendly type composite dry material bonding agent and its application method

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Address after: 313200 Deqing County Province, Huzhou City, the town of bell hill road, No., No. 130

Patentee after: Deqing Kerry high temperature materials Limited by Share Ltd

Address before: 313220 Deqing County bell Industrial Zone, Huzhou, Zhejiang

Patentee before: Kairui New Material Limited Company

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Denomination of invention: Environment friendly dry vibrating material

Effective date of registration: 20201209

Granted publication date: 20130605

Pledgee: Zhejiang Deqing Rural Commercial Bank Co.,Ltd. Zhongguan sub branch

Pledgor: DEQING KAIRUI HIGH TEMPERATURE MATERIALS Corp.

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