CN102584278A - Forsterite seating brick and production method of forsterite seating brick - Google Patents

Forsterite seating brick and production method of forsterite seating brick Download PDF

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Publication number
CN102584278A
CN102584278A CN2012100086060A CN201210008606A CN102584278A CN 102584278 A CN102584278 A CN 102584278A CN 2012100086060 A CN2012100086060 A CN 2012100086060A CN 201210008606 A CN201210008606 A CN 201210008606A CN 102584278 A CN102584278 A CN 102584278A
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forsterite
brick
raw material
seating brick
fine powder
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CN102584278B (en
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虞畅
吴开道
严培忠
翁小燕
唐宁
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ZHEJIANG MINGDE HIGH-TECH MATERIAL Co Ltd
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ZHEJIANG MINGDE HIGH-TECH MATERIAL Co Ltd
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Abstract

The invention discloses a forsterite seating brick and a production method of the forsterite seating brick. The forsterite seating brick comprises the following components in percentage by weight: 50-70% of forsterite raw material, 17-27% of forsterite clinker, 4-14% of 90# magnesite fine powder, 0-3% of refined quartz sand fine powder and 6-9% of water glass. The production method of the forsterite seating brick comprises the steps of uniformly mixing the components, compression molding, baking for 24 h at the temperature of 180 DEG C, naturally cooling and drawing to obtain the forsterite seating brick. According to the forsterite seating brick, a cheap forsterite is adopted as a main material and the traditional tundish seating brick produced by using rare and precious alumina and magnesite as main materials is replaced, so that the production cost of the tundish seating brick is greatly reduced and the product quality is improved; and the normal-temperature compression strength, the high-temperature change rate and the compression strength index of the forsterite seating brick all reach or exceed the quality indexes of the traditional tundish seating brick through a detection.

Description

Forsterite brick cup and working method thereof
Technical field
the present invention relates to a kind of fire-resistant brick cup at the mouth of a river under the continuous casting tundish internal fixing.
Background technology
Mostly original continuous casting tundish brick cup is high alumina matter or magnalium matter; Its production technique is divided into 2 kinds substantially: a kind of is to be main raw material with each grade bauxite clinker and magnesia; Add a small amount of graphite; Adopt combinations such as water glass,, make finished product through baking again through high-pressure molding behind the batch mixing; Another kind is to be main raw material with each grade bauxite clinker and magnesia, and cement, micro mist etc. is wedding agent, and the pug that mixes is added mould internal vibration moulding, and the demoulding after the normal temperature health makes finished product through baking again.
along with the development rapidly of aluminum smelting industry and refractories industry in recent years, the sharp increase of bauxite clinker and magnesia market demand, and cost of material presents the trend that rises steadily; Also when the river rises the boat goes up for the production cost of tundish brick cup, thereby, there are many tundish brick cup products to use inferior materials and turn out substandard goods at present for reducing cost; Cause tundish brick cup downgrade; Hot strength is low, and volume stability is poor, causes the blast furnace number to connect and is prone to infiltrate molten steel when watering around the brick cup; What the tundish brick cup was too early is etched, so that leads to the steel accident of wearing at brick cup position.
Summary of the invention
One of the object of the invention, provide a kind of raw material sources fully, price is cheaper and continuous casting tundish brick cup quality that process reaches or be superior to the forsterite brick cup of currently available products.Two of the object of the invention provides a kind of method for preparing said forsterite brick cup.
Technical solution of the present invention is:
A kind of forsterite brick cup is characterized in that its composition and proportion of composing by weight percentage are: forsterite raw material 50~70%, forsterite grog 17~27%, 90 Magnesia powder 4~14%, refining silica sand fine powder 0~3%, water glass 6~9%.
The component optimum ratio of said forsterite brick cup is: forsterite raw material 60%, forsterite grog 20%, 90 Magnesia powder 10%, refining silica sand fine powder 2%, water glass 8%.
As preferably, the quality index of said forsterite raw material raw material is: volume density>=2.70 g/cm 3 , MgO>=45%, SiO 2 ≤45%, Fe 2 O 3 ≤10%, igloss≤3%.
As preferably, the quality index of said forsterite grog raw material is: volume density>=2.70 g/cm 3 , MgO>=50%, SiO 2 ≤40%, Fe 2 O 3 ≤8%, igloss≤1%.
As preferably, said 90 The quality index of magnesia powder raw material is: volume density>=3.15g/cm 3 , MgO>=90%, SiO 2 ≤4%, CaO≤2%, igloss≤0.5%.
As preferably, the quality index of said refining silica sand fine powder raw material is: SiO 2 >=98%, Fe 2 O 3 ≤0.2%, igloss≤0.5%.
as preferred, the quality index of said water glass raw material is: SiO2%>=26%, Na2O%>=8.5%, modulus 3.1~3.4.
A kind of working method of aforesaid forsterite brick cup comprises following process step:
In the component ratio; Earlier particle level forsterite raw material 5~3mm, 3~1mm, 1~0mm are added in the high speed muller of belt wheel stone roller; Stirred 2 minutes, and slowly added water glass then and stir 8 minutes, add through 8 minutes forsterite grog, 90 of pre-mixing again to evenly Magnesia and refining silica sand fine powder stir and obtain the work in-process pug after 10 minutes; The pug ageing mixture was pinched agglomerating in 2~24 hours to hand, touch promptly open after, be formed into the size of requirement through friction press, at 180 ℃ of bakings 24 hours down, kiln discharge behind the naturally cooling.
Said 90 The fineness of magnesia and refining silica sand powder is 200 orders.
said pug is 1000 tons through the pressure of high brick pressing machine moulding.
the invention has the beneficial effects as follows: be that continuous casting tundish brick cup that main raw material is made greatly reduces with the alumina with the forsterite be the production cost of traditional continuous casting tundish brick cup of making of main raw material; Product is through detecting, and its cold crushing strength, higher temperature line velocity of variation and compressive strength index all meet or exceed the quality index of existing tundish brick cup.
Embodiment
Embodiment 1, a kind of forsterite brick cup, and its concrete composition and proportion of composing by weight percentage are: forsterite raw material 70%, forsterite grog 17%, 90 Magnesia powder 4%, refining silica sand fine powder 3%, water glass 6%.
Preparing method: in the component ratio; Earlier in the high speed muller with particle level forsterite raw material 5~3mm 30%, 3~1mm 40%, 30% adding belt wheel stone roller below the 1mm; Stirred 2 minutes; Slowly add water glass then and stir 8 minutes, add through 8 minutes forsterite grog, 90 of pre-mixing again to evenly Magnesia and refining silica sand fine powder stir and obtain the work in-process pug after 10 minutes; The pug ageing mixture was pinched agglomerating in 2~24 hours to hand, touch promptly open after, be formed into the size of requirement through 1000 tons of friction presses, at 180 ℃ of bakings 24 hours down, kiln discharge behind the naturally cooling.
Product is through physical detection: cold crushing strength 47.8MPa, volume density 2.70g/cm 3 1400 ℃ * 3h burns back intensity line velocity of variation-0.40%, and compressive strength is 40.3MPa.
Compare original brick cup production cost of said product production cost descends 50%.Prepare 50 and send Baosteel continuous casting tundish actual use, on average connect and water several 9 stoves of stove, every stove even waters about 50 minutes of time.Through on probation: the product normal temperature strength is good, does not have in the carrying and installation process and damages, and high the company when watering stove and counting uses synchronously with coating, and no brick cup is worn the generation of steel phenomenon; See that from the brick cup that turns over behind the bag volume stability is good, strength retention is high, no obvious erosion vestige.
Embodiment 2, a kind of forsterite brick cup, and its concrete composition and proportion of composing by weight percentage are: forsterite raw material 60 %, forsterite grog 20%, 90 Magnesia powder 10%, refining silica sand fine powder 2%, water glass 8%.
Preparing method: in the component ratio; Earlier in the high speed muller with forsterite raw material 5~3mm 35%, 3~1mm 40%, 25% adding belt wheel stone roller below the 1mm; Stirred 2 minutes; Slowly add water glass then and stir 8 minutes, add through 8 minutes forsterite grog, 90 of pre-mixing again to evenly Magnesia and refining silica sand fine powder stir and obtain the work in-process pug after 10 minutes; The pug ageing mixture was pinched agglomerating in 2~24 hours to hand, touch promptly open after, be formed into the size of requirement through 1000 tons of friction presses, at 180 ℃ of bakings 24 hours down, kiln discharge behind the naturally cooling.
Product is through physical detection: cold crushing strength 55.8MPa, volume density 2.72g/cm 3 1400 ℃ * 3h burns back intensity line velocity of variation-0.12%, and compressive strength is 43.9MPa.
Compare original brick cup production cost of said product production cost descends 50%.Prepare 100 and send Hangzhou Steel Company continuous casting tundish actual use, on average connect and water several 8 stoves of stove, every stove even waters about 45 minutes of time.Through on probation: the product normal temperature strength is good, does not have in the carrying and installation process and damages, and high the company when watering stove and counting uses synchronously with coating, and no brick cup is worn the generation of steel phenomenon; See that from the brick cup that turns over behind the bag volume stability is good, strength retention is high, no obvious erosion vestige.
Embodiment 3, a kind of forsterite brick cup, and its concrete composition and proportion of composing by weight percentage are: forsterite raw material 50 %, forsterite grog 27%, 90 Magnesia powder 14%, water glass 9%.
Preparing method: in the component ratio; Earlier in the high speed muller with forsterite raw material 5~3mm 40%, 3~1mm 40%, 20% adding belt wheel stone roller below the 1mm; Stirred 2 minutes; Slowly add water glass then and stir 8 minutes, add through 8 minutes forsterite grog, 90 of pre-mixing again to evenly Magnesia and refining silica sand fine powder stir and obtain the work in-process pug after 10 minutes; The pug ageing mixture was pinched agglomerating in 2~24 hours to hand, touch promptly open after, be formed into the size of requirement through 1000 tons of friction presses, at 180 ℃ of bakings 24 hours down, kiln discharge behind the naturally cooling.
Product is through physical detection: cold crushing strength 51.1MPa, volume density 2.70g/cm 3 1400 ℃ * 3h burns back intensity line velocity of variation-0.22%, and compressive strength is 41.4MPa.
Compare original brick cup production cost of said product production cost descends 40%.Prepare 50 and send Handan Iron and Steel Co continuous casting tundish actual use, on average connect and water several 10 stoves of stove, every stove even waters about 45 minutes of time.Through on probation: the product normal temperature strength is good, does not have in the carrying and installation process and damages, and high the company when watering stove and counting uses synchronously with coating, and no brick cup is worn the generation of steel phenomenon; See that from the brick cup that turns over behind the bag volume stability is good, strength retention is high, no obvious erosion vestige

Claims (10)

1. a forsterite brick cup is characterized in that its composition and proportion of composing by weight percentage are: forsterite raw material 50~70%, forsterite grog 17~27%, 90 Magnesia powder 4~14%, refining silica sand fine powder 0~3%, water glass 6~9%.
2. by the described forsterite brick cup of claim 1, it is characterized in that the component optimum ratio of said forsterite brick cup is: forsterite raw material 60%, forsterite grog 20%, 90 Magnesia powder 10%, refining silica sand fine powder 2%, water glass 8%.
3. by claim 1 or 2 described forsterite brick cups, it is characterized in that the quality index of said forsterite raw material raw material is: volume density>=2.70 g/cm 3, MgO>=45%, SiO 2≤45%, Fe 2O 3≤10%, igloss≤3%.
4. by claim 1 or 2 described forsterite brick cups, it is characterized in that the quality index of said forsterite grog raw material is: volume density>=2.70 g/cm 3, MgO>=50%, SiO 2≤40%, Fe 2O 3≤8%, igloss≤1%.
5. by claim 1 or 2 described forsterite brick cups, it is characterized in that said 90 The quality index of magnesia powder raw material is: volume density>=3.15g/cm 3, MgO>=90%, SiO 2≤4%, CaO≤2%, igloss≤0.5%.
6. by claim 1 or 2 described forsterite brick cups, it is characterized in that the quality index of said refining silica sand fine powder raw material is: SiO 2>=98%, Fe 2O 3≤0.2%%, igloss≤0.5%.
7. by claim 1 or 2 described forsterite brick cups, it is characterized in that the quality index of said water glass raw material is: SiO 2%>=26%, Na 2O%>=8.5%, modulus 3.1~3.4.
8. the working method of a forsterite brick cup as claimed in claim 1 is characterized in that comprising following process step:
In the component ratio, just forsterite raw material 5~3mm, 3~1mm, 1~0mm add in the high speed muller of belt wheel stone roller earlier, stir 2 minutes, slowly add water glass then and stir 8 minutes to evenly, add 8 minutes forsterite grog, 90 of process pre-mixing again Magnesia and refining silica sand fine powder stir and obtain the work in-process pug after 10 minutes; The pug ageing mixture was pinched agglomerating in 2~24 hours to hand, touch promptly and open, and was formed into the size of requirement through friction press, at 180 ℃ of bakings 24 hours down, kiln discharge behind the naturally cooling.
9. by the method for the said forsterite brick cup of the described preparation of claim 8, it is characterized in that said 90 The fineness of magnesia and refining silica sand fine powder is 200 orders.
10. by the method for the said unburned magnesia chrome brick of the described preparation of claim 8, it is characterized in that said pug is 1000 tons through the pressure of high brick pressing machine moulding.
CN 201210008606 2012-01-12 2012-01-12 Forsterite seating brick and production method of forsterite seating brick Active CN102584278B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103183515A (en) * 2013-04-02 2013-07-03 辽宁科技大学 Synthetic olivine brick for permanent linings of converter and magnesia shaft kiln, and preparation method thereof
CN108002847A (en) * 2016-10-28 2018-05-08 河南智联寰宇知识产权运营有限公司 Refractory brick containing forsterite and preparation method thereof
CN108017397A (en) * 2016-10-28 2018-05-11 河南智联寰宇知识产权运营有限公司 Refractory brick containing quartz sand and preparation method thereof
CN110950669A (en) * 2019-11-05 2020-04-03 泰州市旺鑫耐火材料有限公司 Formula and preparation method of forsterite brick cup
CN115974541A (en) * 2023-01-30 2023-04-18 马鞍山利尔开元新材料有限公司 Carbon-free magnesium bottom nozzle brick and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1267652A (en) * 1999-03-23 2000-09-27 四川省威远特种耐火材料实业公司 Draining sand
CN1509827A (en) * 2002-12-26 2004-07-07 首钢总公司 Alkali inducing sand for ladle and production thereof
CN102114534A (en) * 2011-03-15 2011-07-06 武汉科技大学 Chromium-containing diversion sands for steel ladle and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1267652A (en) * 1999-03-23 2000-09-27 四川省威远特种耐火材料实业公司 Draining sand
CN1509827A (en) * 2002-12-26 2004-07-07 首钢总公司 Alkali inducing sand for ladle and production thereof
CN102114534A (en) * 2011-03-15 2011-07-06 武汉科技大学 Chromium-containing diversion sands for steel ladle and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103183515A (en) * 2013-04-02 2013-07-03 辽宁科技大学 Synthetic olivine brick for permanent linings of converter and magnesia shaft kiln, and preparation method thereof
CN108002847A (en) * 2016-10-28 2018-05-08 河南智联寰宇知识产权运营有限公司 Refractory brick containing forsterite and preparation method thereof
CN108017397A (en) * 2016-10-28 2018-05-11 河南智联寰宇知识产权运营有限公司 Refractory brick containing quartz sand and preparation method thereof
CN110950669A (en) * 2019-11-05 2020-04-03 泰州市旺鑫耐火材料有限公司 Formula and preparation method of forsterite brick cup
CN115974541A (en) * 2023-01-30 2023-04-18 马鞍山利尔开元新材料有限公司 Carbon-free magnesium bottom nozzle brick and preparation method thereof
CN115974541B (en) * 2023-01-30 2023-12-22 马鞍山利尔开元新材料有限公司 Carbon-free magnesium sewer nozzle brick and preparation method thereof

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