CN101898433A - Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus - Google Patents
Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus Download PDFInfo
- Publication number
- CN101898433A CN101898433A CN200910253526XA CN200910253526A CN101898433A CN 101898433 A CN101898433 A CN 101898433A CN 200910253526X A CN200910253526X A CN 200910253526XA CN 200910253526 A CN200910253526 A CN 200910253526A CN 101898433 A CN101898433 A CN 101898433A
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- Prior art keywords
- sheet material
- skin
- central core
- inorfil
- layer
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Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/14—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
- F01N13/148—Multiple layers of insulating material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2853—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2853—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
- F01N3/2864—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing the mats or gaskets comprising two or more insulation layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N1/00—Silencing apparatus characterised by method of silencing
- F01N1/08—Silencing apparatus characterised by method of silencing by reducing exhaust energy by throttling or whirling
- F01N1/10—Silencing apparatus characterised by method of silencing by reducing exhaust energy by throttling or whirling in combination with sound-absorbing materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2310/00—Selection of sound absorbing or insulating material
- F01N2310/02—Mineral wool, e.g. glass wool, rock wool, asbestos or the like
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Exhaust Gas After Treatment (AREA)
- Laminated Bodies (AREA)
- Exhaust Silencers (AREA)
Abstract
The invention provides a sheet member with less fiber dispersion and proper support force when supporting the seal material. A sheet member including inorganic fibers includes a first outer layer; a center layer; and a second outer layer. The first outer layer, the center layer, and the second outer layer are laminated with each other such that both the first and the second outer layers are outermost layers; the center layer includes inorganic fibers having diameters equal to or less than approximately 3 micrometers; and the first and the second outer layers include inorganic fibers having diameters greater than approximately 3 micrometers.
Description
The application divides an application, and the China national application number of its original application is 200810005324.9, and the applying date is on January 28th, 2008, and denomination of invention is " sheet material and manufacture method thereof, emission-control equipment and a silencing means ".
Technical field
The present invention relates to a kind of sheet material that contains inorfil and manufacture method thereof, with this sheet material as the emission-control equipment that supports with sealing material or heat insulation material.In addition, the invention still further relates to a kind of with the silencing means of this sheet material as sound absorber.
Background technology
The quantity of automobile leaps growth after entering this century, meanwhile, the exhausted air quantity that car combustion engine is discharged is also in rapid increase.The various materials that particularly contain in the diesel engine exhaust have become the reason that causes pollution, produce serious influence over against world environments at present.
Under these circumstances, proposed various emission-control equipments, and be practical.General emission-control equipment be the blast pipe that is connected to enmgine exhaust the casing that is made of metal etc. is set midway, wherein dispose the exhaust-gas treatment body, this exhaust-gas treatment body has most grid of being divided by the grid wall, extend along its length.As an example of exhaust-gas treatment body, the discharge filter of catalyst carrier and diesel particulate filter (DPF) etc. is arranged.For example, if DPF, an end of each grid is sealed as alternate grid-like, and before waste gas was discharged by the exhaust-gas treatment body by each grid, particulate (particulate) was caught by the grid wall, can remove particulate like this from waste gas.The constituent material of exhaust-gas treatment body has metal, alloy, also has pottery etc.As the representation example of the exhaust-gas treatment body that is made of pottery, the amplifier case of cordierite (cordierite) system is widely known.Recently, from viewpoints such as hear resistance, mechanical strength, chemical stabilities, porous matter carborundum sintered body also uses as the material of exhaust-gas treatment body.
In general, be provided with support between above-mentioned exhaust-gas treatment body and the casing with sealing material.Support when being used for preventing vehicle to run etc. with the sealing material generation, owing to the damage that causes that contacts of exhaust-gas treatment body and interior, in addition, be used for also preventing that waste gas is unprocessed just reveals from the slit between casing and the exhaust-gas treatment body.In addition, support with the sealing material and can also play the effect that prevents that exhaust-gas treatment body position that the discharge pressure owing to waste gas causes is offset.In addition, the exhaust-gas treatment body is because will keep its reactivity, so need to keep high temperature, this just requires to support with the sealing material also will have heat-proof quality.The member that can satisfy these conditions is the sheet materials that are made of inorfils such as alumina series fibers.
This sheet material is wound onto at least a portion of the outer surface outside the opening surface of exhaust-gas treatment body, for example, the joint portion at its two ends is entrenched togather, and with adhesive tape etc. itself and exhaust-gas treatment body is fixed into one again and uses.Afterwards, these incorporate parts are arranged in the casing, constitute emission-control equipment.
But, comprise the fiber of various diameters in the inorfil that common this sheet material contained, such as also there being extremely fine fiber.This microfibre disperses in use easily, operating difficulties, and from operating environment health aspect, also also unsatisfactory.For example, have report to claim the part of the inorfil that diameter 3 μ m are following to contain and be unfavorable for healthy material, and this abroad inorfil is listed in restriction object (for example, Germany technology guide lineTRGS905).
Therefore, for fear of the problem that fiber disperses, a kind of sheet material (Japanese Patent Application Publication " spy opens the 2005-120560 communique ") that does not comprise the following inorfil of diameter 3 μ m has been proposed
But the sheet material that does not comprise small diameter fibers (for example, containing diameter is the following fibers of 3 μ m) lacks enough support forces to the exhaust-gas treatment body usually as supporting with the sealing material.This is because the sheet material that only is made of large-diameter fiber, and most in use fibers are fractureed and impaired, and the resistance of outside compression stress is reduced.Therefore, for sheet material as supporting with the sealing material, need make sheet material contain to a certain degree small diameter fibers (for example, diameter is the following fibers of 3 μ m), but the problem that above-mentioned fiber disperses still exists.
The problems referred to above not merely are present in the emission-control equipment with catalyst carrier or diesel particulate filter (DPF).Such as, identical problem also may take place in the silencing means such as silencer that are used for two wheels automobile or four-wheel automobile.
Summary of the invention
The present invention proposes in order to address the above problem, and its purpose is to provide that a kind of fiber disperses less, operability and operating environment are good and be used for and support the sheet material that has suitable support force when sealing material.And, the object of the present invention is to provide a kind of emission-control equipment that supports with sealing material or heat insulation material that this sheet material is used for.In addition, the object of the present invention is to provide a kind of silencing means that above-mentioned sheet material is used for sound absorber.
Sheet material of the present invention contains inorfil, and have first skin, central core and second outer these three layers at least, described first skin, described central core and the described second outer tegillum build up described first skin and described second skin is in the outer surface side, described central core contains the inorfil that diameter is less than or equal to 3 μ m, and described first skin and second skin are made of the inorfil that minimum diameter surpasses 3 μ m.
Sheet material of the present invention can suppress dispersing of inorfil, can improve the operability and the operating environment of sheet material.
Sheet material of the present invention contains inorfil, and have first skin, central core and second outer these three layers at least, described first skin, described central core and the described second outer tegillum build up described first skin and described second skin is in the outer surface side, described central core contains the inorfil that diameter is less than or equal to 3 μ m, and described first skin and second skin are made of the inorfil that the A value of calculating according to formula (1) surpasses 6 μ m.
A=(the formula (1) of M-2 * e)
Here, M is the average diameter of the inorfil that contains in the skin, and e is the standard error of following formula (2) expression, and wherein, σ is that standard deviation, n measure number.
Sheet material of the present invention contains inorfil, and have first skin, central core and second outer these three layers at least, described first skin, described central core and the described second outer tegillum build up described first skin and described second skin is in the outer surface side, described central core contains the inorfil that diameter is less than or equal to 3 μ m, and described first skin or second skin are made of the bio-soluble inorganic fibers.
At this, the average diameter of the described first outer inorfil and minimum diameter can be identical with the described second outer field average diameter and minimum diameter respectively.
And described first skin and second skin can be in fact identical layer.
In addition, described first skin and second skin are preferably in the scope of 0＜W≤50wt% than W with respect to the gross weight of sheet material.
And described first skin and second skin are preferably in the scope of 0＜t≤50% than t with respect to the thickness of sheet material.
At least a portion of end face outside described two outer surfaces of the side formation sheet material of described central core, at least a portion in this side can be provided with coating.
At this moment, described coating can cover the whole side of described central core.
Described coating can be made of or second outer identical layer outer with described first.
Sheet material can also contain in conjunction with material.
Sheet material can also comprise the adhesive linkage that is located between described first skin and described central core or second skin and the described central core.
Sheet manufacturing method of the present invention, this sheet material contains inorfil, and described manufacture method comprises step: make by minimum diameter and surpass first skin that the inorfil of 3 μ m constitutes; Making contains the central core that diameter is less than or equal to the inorfil of 3 μ m; Making surpasses second skin that the inorfil of 3 μ m constitutes by minimum diameter; And stacked at least described first skin, described central core and described second outer these three layers make described first skin and described second skin be in the outer surface side, and engage each layer.
Sheet manufacturing method of the present invention, this sheet material contains inorfil, and described manufacture method comprises step: make first skin that is surpassed the inorfil formation of 6 μ m by the A value of calculating according to formula (1); Making comprises the central core that diameter is less than or equal to the inorfil of 3 μ m; Making is surpassed second skin of the inorfil formation of 6 μ m by the A value of calculating according to formula (1); And stacked at least described first skin, described central core and described second outer these three layers make described first skin and described second skin be in the outer surface side, and engage each layer.
A=(the formula (1) of M-2 * e)
Here, M is the average diameter of the inorfil that contains in the skin, and e is the standard error of following formula (2) expression, and wherein σ is that standard deviation, n measure number.
Sheet manufacturing method of the present invention, this sheet material contains inorfil, and described manufacture method comprises step: make first skin that is made of the first bio-soluble inorganic fibers; Making comprises the central core that diameter is less than or equal to the inorfil of 3 μ m; Second skin that making is made of the second bio-soluble inorganic fibers; And stacked at least described first skin, described central core and described second outer these three layers make described first skin and described second skin be in the outer surface side, and engage each layer.
At this, the step that engages described each layer comprises the step that engages each layer with adhesive linkage.
Sheet manufacturing method of the present invention, this sheet material contains inorfil, and described manufacture method comprises step: will only contain the first former slip that minimum diameter surpasses the inorfil of 3 μ m and be injected in the former; The first former slip is dewatered, obtain first formed body; To contain the second former slip that diameter is less than or equal to the inorfil of 3 μ m is injected on the first former slip that has dewatered; The second former slip is dewatered, on described first formed body, form second formed body; Be injected in the former only containing the 3rd former slip of minimum diameter above the inorfil of 3 μ m; The 3rd former slip is dewatered, on described first formed body and second formed body, form the 3rd formed body; The formed body that has formed the three-decker of the 3rd formed body on described first formed body and second formed body is carried out compression drying, form the sheet material of three-decker.
Described the whole bag of tricks of the present invention can further comprise the step of impregnation in conjunction with material.
Emission-control equipment of the present invention, the support that comprises exhaust-gas treatment body and at least a portion that is wound on the external side face of this exhaust-gas treatment is with sealing material, and described support is made of described any one sheet material with the sealing material.
Emission-control equipment of the present invention comprises exhaust gas entrance pipe and outlet, is arranged on the exhaust-gas treatment body between described inlet tube and the outlet, and at least a portion of described inlet tube is provided with heat insulation material, and this heat insulation material is made of described any one sheet material.
At this, described exhaust-gas treatment body can be catalyst carrier or waste gas filter.
Silencing means of the present invention, comprise interior pipe, cover pipe periphery in this shell, be arranged on described in sound absorber between pipe and the shell, described sound absorber is made of described any one sheet material, and this sheet material makes first skin be positioned at the outside when being arranged between described interior pipe and the shell.
Sheet material of the present invention can suppress fiber and disperse, improves operability and operating environment.And, when this sheet material is used for the support usefulness sealing material of emission-control equipment, suppress to descend at the support force of exhaust-gas treatment body.And, when this sheet material is used for the sound absorber of silencing means, the decline of the surface pressure in can suppressing between pipe and the shell.
Therefore, the invention provides a kind of with described sheet applications in the emission-control equipment that supports with sealing material and/or heat insulation material, and the method for making this emission-control equipment.And, the invention provides a kind of with the silencing means of above-mentioned sheet applications in sound absorber.
Description of drawings
Fig. 1 is an example of sheet form of the present invention.
The concept map of the state when Fig. 2 is mounted to casing in the exhaust-gas treatment body sheet material of the present invention for expression.
Fig. 3 is an example of another sheet structure of the present invention.
Fig. 4 is the sectional view along the A-A line intercepting of Fig. 3.
Fig. 5 is the structural representation of an example of emission-control equipment of the present invention.
Fig. 6 is the structural representation of an example of silencing means of the present invention.
Fig. 7 is a method flow diagram of making sheet material of the present invention with " laminating type ".
Fig. 8 is a method flow diagram of making sheet material of the present invention with " manufacture 1 ".
Fig. 9 is the schematic diagram of the part of fiber dustability experimental rig.
Figure 10 is for compressing the rough schematic of the experimental rig that sets up.
The curve map that Figure 11 concerns than the recovery surface pressure with 1000 all after dates for the outer field gross weight of expression.
The curve map that Figure 12 concerns than the surface pressure rate of descent with 1000 all after dates for the outer field gross weight of expression.
Figure 13 for expression with respect to the outer layer thickness of sheet material integral thickness than and the curve map of the recovery surface pressure relation of 1000 all after dates.
Figure 14 for expression with respect to the outer layer thickness of sheet material integral thickness than and the curve map of the surface pressure rate of descent relation of 1000 all after dates.
Main symbol description:
2 is inlet tube, and 4 is outlet, and 10 is emission-control equipment, 12 is casing, and 20 is the exhaust-gas treatment body, and 24 for supporting with the sealing material, 26 is heat insulation material, and 30,31 is sheet material, and 50 for cooperating the portion of telling, 60 is cooperating recesses, and 82 is first skin, and 84 is central core, 86 is second skin, and 88 is coating, and 110 is fiber dustability experimental rig, 120 is plastic bag, 130 is pressing plate, and 140 is arm, and 150 is vertical wall, 160 is sample, 310 for compressing the experimental rig that sets up, and 700 is silencing means, and 720 is interior pipe, 740 is sound absorber, and 760 is shell.
Preferred forms of the present invention
Below with reference to description of drawings preferred forms of the present invention.
[first embodiment]
Fig. 1 is an example of first embodiment of sheet material of the present invention.But sheet material of the present invention is not limited to shape shown in Figure 1.In addition, Fig. 2 is as the decomposition chart that supports with the emission-control equipment of sealing material with sheet material of the present invention.
Be wound onto when sheet material 30 of the present invention on the exhaust-gas treatment body 20 such as catalyst carrier when using with sealing material 24 as the support of emission-control equipment, as shown in Figure 1, one group of chimeric protuberance 50 and chimeric with recess 60 of using is set on two end faces 70,71 vertical with the coiling direction (directions X) of sheet material 30.When sheet material 30 was wound onto on the exhaust-gas treatment body 20, as shown in Figure 2, chimeric with protuberance 50 and chimeric chimeric with recess 60, sheet material 30 was fixed on the exhaust-gas treatment body 20.Afterwards, the exhaust-gas treatment body 20 of the sheet material 30 of having reeled by as the mode that is pressed into be pressed in the tubular casing of making by metal etc. 12, form emission-control equipment 10.
Sheet material of the present invention 30 is that main body constitutes with the inorfil, but as described below, can also contain in conjunction with material.
The central core 84 of central authorities is the sheet materials that comprise the inorfil (hereinafter referred to as " microfibre ") that diameter is less than or equal to 3 μ m.In addition, first outer 82 and second skin 86 is made of the inorfil that does not comprise " microfibre ".
The sheet material of this three-decker is in when operation, because " microfibre " that central core 84 comprised is subjected to being arranged on sheet material two the most surperficial first outer and second skin, 82,86 restrictions and can not moving freely up and down.Therefore, " microfibre " that can suppress sheet material disperses, and improves the operability and the operating environment of sheet material.In view of the above, the present invention can provide operation good sheet material.
When using with the sealing material as the support of emission-control equipment as the sheet material that will only constitute in the prior art by the large-diameter fiber that does not contain " microfibre ", in when operation when being installed on casing (be wound on the exhaust-gas treatment body or) or when using emission-control equipment, the many fibers that contained in the sheet material are fractureed and are impaired, resistance to outside compression stress reduces, at the support force decline of exhaust-gas treatment body.But sheet material of the present invention comprises " microfibre " that improves support force.Therefore, when this sheet material is used with the sealing material as the support of emission-control equipment, can suppress to use not comprise the decline of the sheet material of " microfibre ", can keep the enough support forces of exhaust-gas treatment body to the support force of exhaust-gas treatment body.
In the present invention, be not particularly limited first skin and second skin higher limit with respect to the weight ratio W of sheet material, still, W is preferably W≤50wt%, is preferably W≤20wt%.In addition, the lower limit of W can adopt any value that satisfies 0＜W in theory.Just, if the W value is too small, a part of microfibre in the central core 84 may run through first outer 82 or second skin 86 and disperse to the outside.Therefore, from practical angle, the lower limit of W is preferably W 〉=2wt%.The weight of first outer 82 and second skin 86 can be the same or different, and for example both weight ratios can be 1: 9～9: 1 scope.
First outer and second skin than t, for example can be 0＜t≤70% with respect to the gross thickness of whole sheet material, is preferably 0＜t≤50%, is preferably 0＜t≤20%.Such as, the thickness of the whole sheet material of horizontal stationary state can be 5～20mm.The thickness of first outer 82 and second skin 86 can be the same or different, and for example both thickness ratios can be 1: 9～9: 1 scope.
But if the t value is too small, a part of microfibre in the central core 84 may run through first outer 82 or second skin 86 and disperse to the outside.Therefore, from practical angle, the minimum of a value of t is preferably t 〉=1%.
First weight per unit area outer and second skin and central core is not specially limited, and for example first skin and the second outer field weight per unit area are 60g/m
2～1500g/m
2, the weight per unit area of central core is 500g/m
2～3000g/m
2Weight per unit area is meant the total weight of fiber that unit are contained of sheet material, when sheet material comprises in conjunction with material, and the gross weight that the representation unit area is contained in conjunction with material and fiber.In addition, the bulk density of each layer (bulk density) is not specially limited, and for example can be 0.07g/cm
3～0.30g/cm
3
The bulk density of the unqualified whole sheet material of the present invention and weight per unit area, for example the bulk density of whole sheet material is 0.07g/cm
3～0.30g/cm
3, weight per unit area is 500g/m
2～3000g/m
2
The average diameter of the inorfil that unqualified first skin and second skin are contained in the present embodiment is the fiber of 5 μ m～10 μ m such as using as average diameter.But, should be noted that first skin and second skin do not comprise " microfibre ".For this reason, the minimum diameter of the common first outer and inorfil that second skin is contained is at 3.1 μ m～5.0 mu m ranges.In the present invention, first skin and the second outer field various characteristics (fiber diameter, minimum fiber diameter, preparation method) can be the same or different.
In addition, the average diameter of the inorfil that central core contained is in the scope of 3.0 μ m～8.0 μ m.But central core can comprise " microfibre ".
The no myofibrillar average diameter that each layer contained is measured according to following method.At first, will put into cylinder, and use the 20.6MPa pressurization to pulverize from the alumina series fiber of any one layer extraction.Then, this test portion is placed on the screen cloth, test portion that will be by sieve is as the sample of observing with electron microscope.After surperficial gold evaporation of this sample etc., take with the electron microscope that magnifying power is about about 1500 times.At least can measure the diameter of 40 fibers from the photo that photographed.Repeat this operation at 5 samples, and with the mean value of the measured value average diameter as this layer inorfil.
The minimum diameter of the fiber that each layer contained is obtained according to following method.Take the electron micrograph (magnifying power is about about 1500 times) of the suitable part of skin and central core respectively.In the photo of taking (about 50 fibers), select the fiber of diameter minimum and measure its diameter.Six photos that extract at the diverse location from each layer carry out identical operations, and with the minimum fiber diameter of the minimum diameter in the diameter that obtains as this layer.
When sheet material was made by " acupuncture (needling) facture " described later, the pin of each layer (needle) mark density was preferably in 2.0/cm
2～20.0/cm
2Scope in.This be since when the stitch density of each layer less than 2.0/cm
2The time, intensity is descended.In addition, surpass 20.0/cm when stitch density
2The time, even increase stitch density again, bulk density also changes hardly, and sheet material is caused operability to descend by hardization.
In this application, " needle tracking " is meant, in the sheet material of making by " acupuncture facture ", when pin or other fiber interweaving instrument were extracted in insertion, the full-size that generates on sheet material was 3mm
2Following fiber interweaving vestige.
[second embodiment]
The following describes second embodiment of the invention.
The sheet material of present embodiment is identical with sheet material 30 among above-mentioned Fig. 1, is made of first skin, central core and the second outer sequential cascade.But first skin and second skin of this sheet material are made of the inorfil that the A value surpasses 6 μ m, and described A value is calculated by following formula (1):
A=(the formula (1) of M-2 * e)
At this, M is the average diameter of the outer inorfil that is contained, and e is the standard error of following formula (2) expression, and wherein σ is that standard deviation, n measure number.
Healthy and safe property regulation (EU directive97/69/EC according to the relevant glass fibre in Europe, on December 5th, 1997 came into force) (below be called " Europe instruction "), the inorfil that the A of above-mentioned formula (1) satisfies A＞6 μ m belongs to so-called " Note-R ", is listed in outside the restriction object.
Therefore, have the sheet material of above-mentioned first skin and the second outer field present embodiment, even first skin and second skin self dispersing of inorfil are taken place, this inorfil causes that to human body dysgenic possibility is also very little.And as mentioned above, because two surfaces of sheet material are provided with first outer and second skin, " microfibre " that therefore can effectively suppress central core when operation disperses.Therefore, when adopting this sheet material, as mentioned above, also can improve the operability and the operating environment of sheet material.And, because this sheet material contains " microfibre " that improves support force, therefore can reduce the decline of support force.
The sheet material of second embodiment only need satisfy the relation of above-mentioned A＞6 μ m, needn't limit the average diameter of first skin and the second outer field inorfil.Should be noted that differently with first embodiment, first outer and second skin can contain some " microfibre " in the sheet material of second embodiment.In addition, central core is identical with first embodiment, comprises " microfibre ", and the average diameter of inorfil is preferably in the scope of 3.0 μ m～8.0 μ m.
[the 3rd embodiment]
According to the aforesaid way of sheet material of the present invention, first skin and second skin surpass the inorfil of 3 μ m by minimum diameter or surpass the inorfil formation of 6 μ m according to the A value that formula (1) is calculated.With respect to this, the 3rd embodiment of sheet material of the present invention is characterised in that its first skin and/or second skin are made of " bio-soluble inorganic fibers ".
At this, " bio-soluble inorganic fibers " is meant, is excluded general name outside inorfil restriction object, that satisfy the inorfil of so-called " Note-Q " benchmark in above-mentioned " Europe instruction ".At this,, listed following condition in " Note-Q " of " Europe instruction " as the inorfil that is excluded outside the restriction object:
A) in the organism that sucks according to short-term in the anelasticity test, length has half life less than 10 days greater than the inorfil of 20 μ m;
Anelasticity test in the organism of the short-term of injecting in B) during basis, length has load half life less than 40 days greater than the inorfil of 20 μ m;
C) in suitable abdominal cavity, throw and give in the test, do not have the evidence of high carcinogenic;
D) in suitable long-term inhalation test, can not produce relevant pathogenicity variation or tumprigenicity and change.
This " bio-soluble inorganic fibers " also can dissolve in vivo even be inhaled into human body, and be therefore very little to the influence of human body, is safe.Therefore, when first skin that is made of sheet material " bio-soluble inorganic fibers " and second skin, the inorfil that disperses from these layers itself does not have at all influence to human body.And, " microfibre " that central core contained of sheet material central portion, it disperses by first outer and second outer the inhibition to the outside.Therefore, also can improve operability and operating environment, the especially operating environment of sheet material intentionally by the sheet material of this 3rd embodiment.
[the 4th embodiment]
The sheet material of above-mentioned three embodiments is that two " first type surfaces " at central core 84 are provided with first outer 82 and second skin 86.But sheet material of the present invention is not limited to this structure.
Example according to the sheet structure of four embodiment of the invention has been shown among Fig. 3 and Fig. 4.Fig. 4 is the sectional view along the A-A line intercepting of Fig. 3.This sheet material 31 is also identical with the sheet material 30 shown in above-mentioned Fig. 1, is made of first skin 82, central core 84 and second outer 86 sequential cascades.But different with the sheet material 30 shown in Fig. 1, sheet material 31 also comprises the coating 88 that covers whole sheet material side 40.
Though coating 88 has covered the whole side 40 of sheet material 31 among Fig. 3, should be noted that coating 88 also can only be arranged on the part of side 40.At this moment, though compare with the sheet material 31 shown in Fig. 3, the inhibition effect of dispersing of its " microfibre " descends to some extent, compares with the sheet material 30 shown in Fig. 1, still can suppress dispersing of " microfibre " effectively.
In the example of Fig. 3, first skin and second skin can be made of the inorfil that does not contain " microfibre ".But inorfil or " bio-soluble inorganic fibers " that first skin and second skin also can be surpassed 6 μ m by the A value of formula (1) definition constitute.
The example of one of structure of emission-control equipment 10 of the present invention shown in Fig. 5.Emission-control equipment 10 comprises exhaust gas entrance pipe 2 and the outlet 4 of periphery coiling support with exhaust-gas treatment body 20, the casing 12 that is used to hold this exhaust-gas treatment body, the arrival end that is connected to this casing and the port of export of sealing material 24.In the example shown in Fig. 5, support with sealing material 24 and use the sheet material 30 shown in Fig. 1.But, support with sealing material 24 and also can use the sheet material 31 shown in Fig. 3.Inlet tube 2 and outlet 4 form taper, and bore becomes big in the position that is connected with casing 12.But present embodiment is not limited to a kind of taper.Part (being tapered portion in the example of Fig. 5) at inlet tube 2 is provided with heat insulation material 26, and the heat that can suppress emission-control equipment 10 inside in view of the above passes to the outside by inlet tube 2.
In the example of this figure, exhaust-gas treatment body 20 is catalyst carriers, and it has the opening surface as exhaust gas entrance and outlet, has a plurality of grid (or through hole) in the direction that is parallel to air-flow.Catalyst carrier is by the formations such as porous matter carborundum of honeycomb (honeycomb) shape.But emission-control equipment 10 of the present invention is not limited to this structure.For example, exhaust-gas treatment body 20 also can be sealed and form alternate grid-like diesel particulate filter (DPF:Diesel Particulate Filter) and constitute by an end of each grid.
In this emission-control equipment,, when sheet material is wound on exhaust-gas treatment body 20, can suppress dispersing of inorfil effectively as the effect of above-mentioned sheet material.And, support with the sealing material and can provide suitable support force to the exhaust-gas treatment body.
In addition, also available sheet material of the present invention constitutes heat insulation material 26.
The following describes other application examples of sheet material of the present invention.Fig. 6 represents to have the sketch plan of the silencing means of sheet material of the present invention.This silencing means is arranged in the exhaust pipe of engine of two wheels automobile or four-wheel automobile etc.Pipe 720 (for example, by metals such as stainless steel make) in silencing means 700 comprises, cover in the pipe periphery shell 760 (for example, making) by metals such as stainless steels, be arranged in sound absorber 740 between pipe and the shell.Usually, the surface of interior pipe 720 is provided with a plurality of little perforation.Waste gas is when interior pipe 720 internal flows, and this silencing means 700 can be by the noise composition that is contained in the noise reduction material 740 decay waste gas.
The following describes the manufacture method of sheet material of the present invention.Following description is an example with the sheet material 30 of above-mentioned first embodiment, and its manufacture method is described.
The typical method of making sheet material 30 of the present invention has " laminating type " and " manufacture " dual mode.
Fig. 7 represents to make by " laminating type " method flow diagram of sheet material 30 of the present invention.This mode is made two layers not containing " microfibre " (that is, first outer 82 and second skin 86) respectively and is contained the central core of " microfibre ", then with these folded layer by layer its integrated and sheet materials manufacturing three-decker that makes.
At first, make first skin that does not contain " microfibre " at step S100.First is outer as described below, by making as " acupuncture facture " or " copying method for making ".The term that it should be noted that " acupuncture facture " among the application comprises, and has on sheet material to insert the manufacture method of extracting as the various sheet materials of the pin treatment process of fiber interweaving instruments such as pin.In addition, it is noted that " copying method for making " among the application refers to comprise the sheet manufacturing method of opening fibre, pulp, moulding and each operation of compression drying of fiber.
Then, make second skin that does not contain " microfibre " at step S110.Second is outer outer identical with first, also adopts " acupuncture facture " or " copying method for making " to make.
Then, make the central core that contains " microfibre " at step S120.Identical with first skin and second skin, central core also adopts " acupuncture facture " or " copying method for making " to make.At this, the preparation method of these three layers (" acupuncture facture " or " copying method for making ") can be identical, also can be different.And the operation of step S100～S120 might not be carried out in proper order according to this, for example can make central core at first, and then makes first outer and second skin.
Then, in step S130,, and engage each layer with first skin, central core, second outer these three layer sequential cascades.It is first outer and second skin/central core surface is provided with pressure sensitive adhesive double coated or bonding agent etc. " adhesive linkage " makes its bonding method that the method that engages each layer is included in, and perhaps the surface between each layer sewed up the method that engages etc.The above-mentioned method that engages by " adhesive linkage ", except directly engaging by " adhesive linkage " the method for each layer, also have on the two sides of central core and with 140 ℃ of temperature heat bonding thermoplastic films (for example with respect to each superficies on this two sides, PE film, CLAF (registration mark) etc.), and any two sides in these films is provided with the method that adhesive tape or bonding agent etc. engage three layers.It is that bonding agent, acrylates (acrylate) are latex (latex) etc. that bonding agent can use propylene.The thickness of pressure sensitive adhesive double coated, bonding agent and thermoplastic film is not specially limited, and for example is 0.02mm～0.20mm.
In this application, " adhesive linkage " refers to be arranged in order to engage central core and two skins as pressure sensitive adhesive double coated or bonding agent etc. the layer on each surface, if the centre is provided with above-mentioned thermoplastic film, then comprises this film.Therefore, for the structure that accompanies above-mentioned thermoplastic film, the thickness of one " adhesive linkage " is the thickness of the thickness * 2+ of thermoplastic film pressure sensitive adhesive double coated (or bonding agent).The thickness of " adhesive linkage " is for example in the scope of 0.02mm～0.60mm.
" laminating type " makes sheet material of the present invention through this operation.
In addition, " manufacture " is different with above-mentioned " laminating type ", forms by three layers of sheet material that constitutes in series of processes usually.In " manufacture ", also make sheet material by in " acupuncture facture " or " copying method for making " any one.Just, " manufacture " need not to prepare separately each layer, can use another kind of simple manufacturing installation, therefore has the advantage that can simplify production process.
Specify use " laminating type " below and reach one of the method example that " manufacture " makes sheet material of the present invention.In the following description, the sheet material with the mixture that contains aluminium oxide (alumina) as inorfil and silica (silica) is that example describes.Just, fibrous material is not limited thereto, and can be only be made of a kind of in aluminium oxide or the silica.Perhaps, also can use other inorfil.
(laminating type 1)
As mentioned above, this mode need be prepared each layer at first.Each layer uses " acupuncture facture ", makes in conjunction with each operation of material through ovennodulation spinning solution, air blowing (blowing) processing, acupuncture (needle) processing, roasting (burning), impregnation.
(operation of modulation spinning solution)
At the aluminium amount is that to add aluminium oxide and silica ratio of components in the basic aluminium chloride aqueous solution of 70g/l, Al/Cl=1.8 (atomic ratio) be 60～97: 40～3 Ludox (silica sol), the precursor of modulation inorfil.Especially, the alumina silica ratio of components is preferably 70～97: 30～3.This be since when the aluminium oxide ratio of components 60% when following, mullite (mullite) composition ratio that is generated by aluminium oxide and silica descends, and has the thermal conductivity raising of each layer, the tendency of thermal insulation decline after therefore finishing.In addition, when the aluminium oxide ratio of components surpasses 97%, can damage the flexibility of inorfil.
Then, the precursor at this alumina series fiber adds polyvinyl alcohol organic polymers such as (polyvinylalcohol).Then, concentrate this liquid modulation spinning solution.
(air blowing treatment process)
Then, use the spinning solution that obtains to handle and carry out spinning by blowing.It is the method for carrying out spinning according to the spinning solution stream that the carrier stream and the spinning solution supply nozzle of the ejection of carrier wave nozzle are extruded that air blowing is handled.This processing method can be by the flow and the spinning solution supply rate of control carrier wave gas (air), the average diameter and the minimum diameter of control alumina fibre precursor.Therefore, the average diameter and the minimum diameter of the inorfil that skin and central core contained after this operation is determined to finish.
Usually, the diameter of spinning-nozzle is 0.1～0.5mm.Make when outer, be generally 30～150m/s, be generally 1～120ml/h by the spinning solution supply rate of spinning solution supply nozzle by the air velocity of carrier wave nozzle ejection.In addition, when making central core, the air velocity that is sprayed by the carrier wave nozzle is generally 40～200m/s.And, be generally 1～60ml/h by the spinning solution supply rate of spinning solution supply nozzle.
Then, make material piece by the stacked precursor of finishing spinning.
(acupuncture treatment process)
Then, carrying out acupuncture at material piece handles.Acupuncture is handled and is used needling device usually.
Usually, needling device comprises a pair of gripper shoe that can come and go needle plate, the surface that is located at material piece and the two sides, the back side of moving along needling direction (being generally above-below direction).On the needle plate with about 25～5000/100cm
2Density a plurality of pins that are used to thrust material piece are housed.Each gripper shoe is provided with a plurality of through holes that acupuncture is used.Therefore, pushing down under the state on material piece two sides with a pair of gripper shoe, make needle plate near or insert to material piece away from material piece and to extract pin, form the material piece of fiber interweaving with this.At this, needling device can also be provided with by the conveyance unit of certain handover speed (for example, about 20mm/ second) towards certain orientation (direction that is parallel to the material piece surfaces externally and internally approximately) conveyance material piece.At this moment, can under the state that moves material piece by certain speed, carry out pin and handle, therefore need not when needle plate of every crimping, to move material piece.
In addition, as another kind of structure, it is one group needle plate that needling device also can have two.Each needle plate has gripper shoe respectively.By two needle plates being separately positioned on the surface and the back side of material piece, thus by each gripper shoe from the two sides fixing material piece.At this, the card clothing of a needle plate is changed to and carries out can not overlapping with the living position of pin mass-sending of another needle plate when pin is handled.Each gripper shoe considers that the card clothing situation of putting of both sides needle plate is provided with a plurality of through holes, to be used for carrying out from the two sides of material piece can not causing when pin is handled pin contact gripper shoe.By this device, can use two gripper shoes to clamp material piece, and use two needle plates to carry out pin and handle by the both sides of material piece from the two sides of material piece.Extract pin according to this method insertion, can easily form high skin of stitch density or central core.
(calcining process)
Then, heat resulting material piece,, can obtain being used for the skin and the central core of sheet material thus about 1250 ℃ continuous roastings of maximum temperature 0.5～2 hour from normal temperature.
(operation in conjunction with material is adhered in impregnation)
Can carry out as required adhering to processing in conjunction with the material impregnation, make skin and central core impregnation such as organic resin in conjunction with material.In view of the above, the volume that can prevent skin and central core becomes big.And, can further prevent the disengaging of fiber from the sheet material made.But, adhere to processing in conjunction with the material impregnation and might not carry out in this stage.For example, also can after central core as described below and two outer joints (that is, after the formation sheet material), carry out adhering to processing in conjunction with the material impregnation.
Adhere in the processing in impregnation, be preferably in the scope of 1.0～10.0 percentage by weights in conjunction with the adhesion amount of material.If be lower than 1.0 percentage by weights, prevent that the effect that inorfil breaks away from from can reduce.If surpass 10.0 percentage by weights, the organic component of discharging when then using emission-control equipment (in conjunction with the decomposition gas of material) amount increases
Can use epoxy (epoxy) resin, allyl resin, rubber in conjunction with material is that organic systems such as resin, phenylethylene resin series are in conjunction with material.Also can use propylene system (ACM), acrylonitrile butadiene rubber (NBR), styrene butadiene ribber (SBR) resin etc.
Use is carried out spray application by this aqueous dispersions in conjunction with material and water modulation, makes skin and central core impregnation in conjunction with material.Add unnecessary solid constituent and the moisture of adhering in skin and the central core to by this processing, remove by following method.
When removing unnecessary solid constituent, undertaken by the attraction method of using suction devices such as vavuum pump.When removing redundant moisture, compress at 90～160 ℃ of temperature heating sheet materials and/or with the pressure of 40kPa～100kPa.
Through this operation, make skin and the central core of impregnation in conjunction with material.
(the joint operation of skin and central core)
Then, at the stacked skin in the surface and the back side of central core and engage these three layers.Engage three layers method as mentioned above, have use " adhesive linkage " method, sew up method that the surface between each layer engages etc.Pass through this operation, make sheet material of the present invention.
(laminating type 2)
In another example of laminating type, use when making each layer " copying method for making ".Each layer made through each operation of opening fibre, pulp, moulding and compression drying of fiber in " copying method for making ".
(fiber open fibre)
At first, carry out the fine processing of opening of inorfil.Open fine processing and can only implement dry type separately and open fine the processing, also can implement dry type and open fine handle and wet type is opened fine two phase process of handling.Open in fine the processing in dry type, use slurry mill (feather mill) device to wait device that raw fibre is opened fibre.On the other hand, open in fine the processing, will open the fine dry type of handling the continuous shape of gained by above-mentioned dry type and open long and slender dimension and put in the wet type fiber-opening apparatus, open fibre again in wet type.Open in fine the processing in wet type, use beater wet type fiber-opening apparatus such as (pulper).Fine processing of opening through such just can obtain out fine raw fibre.
(pulp operation)
Afterwards, drop in the mixer and for example stir 1～5 minute, so that the weight of this raw fibre is 1～2wt% with respect to the ratio of water.Next, in this liquid, add the combination material of 4wt%～8wt%, stirred 1～5 minute.In addition, adding with respect to raw fibre in this liquid again is the inorganic in conjunction with material of 0.5wt%～1.0wt%, stirs 1～5 minute.Then, adding with respect to raw fibre again in this liquid is flocculating agent about 0.5wt%, and being about most is stirring about 2 minutes, the brewable material slurry.
In conjunction with material, for example, can use alumina sol and/or Ludox as inorganic.In addition, as organically combining material, for example, can use rubber based material, water-soluble organic macromolecule compound, thermoplastic resin, thermosetting resin etc., as flocculating agent, for example, can use the pakol292 of Ciba Specialty Chemicals company product etc.
(molding procedure)
Next, the former slip that obtains is added in the former of the shape of wanting, dewaters again.Usually, screen pack (for example, net is of a size of 30 orders) is set in the bottom of former, the moisture in the former slip that adds in the former sees through this screen pack and is discharged from.Therefore, by using such former, can carry out shaping and dehydration simultaneously from former slip to plate shape.In addition, if necessary, can also use suction pump, vavuum pump etc., from the downside of former, by screen pack, the pressure of carrying out moisture attracts.
(dry compression section)
Afterwards, the formed body that obtains is taken out from former, use compressor reducer etc. compresses it, its thickness is become original 0.3～0.5 times, simultaneously, just can obtain skin with for example 90～150 ℃ temperature to its heating and drying of carrying out 5 minutes～1 hour.
Central core also can be made by same operation.
In addition, use the skin that obtains, can also carry out handling described in " laminating type 1 " in conjunction with the material impregnation.But as mentioned above, in " laminating type ", such handles also and can engage back enforcement at three layers in conjunction with the material impregnation.
Then, with three layers carry out stacked after, engage by said method (pressure sensitive adhesive double coated, bonding agent or stitching), obtain sheet material of the present invention.
(manufacture 1)
Even in " manufacture ", also can use " acupuncture facture " and " copying method for making ".In " manufacture 1 ", " manufacture " based on " copying method for making " described.
Fig. 8 is the flow chart according to manufacture 1 a manufacturing sheet material of the present invention.In this mode, use " copying method for making " in a series of operation, to form the sheet material of three-decker.
In this mode, the fiber of step S200 to open fine operation～pulp operation identical with above-mentioned " laminating type 2 ".But in this mode, the operation after the step S210 is different with foregoing.
Specifically, this mode is added into former with the first former slip in step S210, before implementing the dehydration back and taking out tablet raw material (promptly, under the partial desiccation state), the formed body (to call " first formed body " in the following text) that the second former slip is added into after the dehydration is gone up (step S220).At this, it is noted that the inorfil that comprises in the first former slip does not contain " microfibre ", the inorfil that comprises in the second former slip contains " microfibre ".
Next, the moisture that the second former slip contains is discharged from the downside of former via first formed body and screen pack, carries out the dehydration of the second former slip, to modulate second formed body.As mentioned above, also can implement the pressure attraction of moisture from the downside of former this moment if necessary.
Then, in step S230,, the 3rd former slip is added on described " two-layer formed body " taking out " two body " layer by layer (that is, under the partial desiccation state) before that forms by this first formed body and second formed body.And the moisture that the 3rd former slip contains is discharged from the downside of former via " two-layer formed body " and screen pack, carries out the dehydration of the 3rd former slip.As mentioned above, also can implement the pressure attraction of moisture from the downside of former this moment if necessary.At this, it is noted that the inorfil that comprises in the 3rd former slip does not contain " microfibre ".The 3rd former slip can be identical or inequality with the first former slip.
Through this operation, obtain three folded layer by layer " being laminated into body ".
Then, take out " being laminated into body " from former, and use compressor reducer etc. that it is compressed, its thickness is become original 0.3～0.5 times, simultaneously, it is carried out 5 minutes～1 hour heating and drying with for example 90～150 ℃ temperature at step S240.By this method, in continuous treatment process, once form the sheet material of three-decker.At this, also can use the sheet material that obtains further to carry out above-mentioned handling in conjunction with the material impregnation.
The sheet material that obtains by this method has the high feature of surface engagement intensity with respect to the above-mentioned sheet material that obtains by the operation of using each layers of joint such as bonding agent.This be because, before a layer is completed on this layer directly stacked adjacent layer, each layer contact area become obtains greatly.
(manufacture 2)
" manufacture 2 " is based on " acupuncture facture " " manufacture ".
In this mode, also adopt basically with the same operation of above-mentioned " laminating type 1 " and make sheet material.But, this manufacture 2, in the modulating process～air blowing spinning treatment process of spinning solution, the once stacked precursor that is made of three layers is made material piece.Then, in the acupuncture treatment process, handle, obtain three-decker and get material piece by carrying out acupuncture at this three folded layer by layer material piece.At this, it should be noted that the precursor that constitutes by three layers, the layer in the middle of being made in the air blowing spinning process contains " microfibre ", and two other layer does not contain " microfibre ".
Operation afterwards is identical with above-mentioned " laminating type 1 ", and just clearly, this mode need not to engage the operation of three layers.
In each above-mentioned manufacture method, the sheet material of making three-decker is illustrated.But the present invention needs only two layers that do not contain " microfibre " that are provided with the most surperficial of sheet material, and the stepped construction that then has more than four layers also is conspicuous.This multi-layer sheet by reach stacked layer more than four layers in " laminating type 2 " as " laminating type 1 ", perhaps adds the 4th former slip again on the 3rd formed body in " manufacture 1 ", just can easily make.
Though above-mentioned record is that example has illustrated its manufacture method with first sheet material.But, it will be recognized by those skilled in the art that the method for being put down in writing also can be applied to the sheet material of second to the 4th above-mentioned embodiment basically.
[embodiment]
Below by embodiment effect of the present invention is described.
In order to verify effect of the present invention, use above-mentioned " laminating type " to make first sheet material of the present invention, and carry out various tests.Sheet material is made by following order.
(embodiment 1)
Make first skin by " acupuncture facture ".At first, in being the basic aluminium chloride aqueous solution of 70g/l, Al/Cl=1.8 (atomic ratio), the aluminium amount mixes silicon emulsion, so that the composition of alumina series fiber becomes Al
2O
3: SiO
2=72: 28, the precursor of formation alumina series fiber.Then, in the precursor of alumina series fiber, add polyvinyl alcohol.Next, with this liquid concentration,, use this spinning solution to handle and carry out spinning with the air blowing spinning as spinning solution.Carrier wave gas (air) flow is 52m/s, and the supply rate of spinning solution is 5.3ml/h.
Then, the material of the precursor of folding alumina series fiber is stacked, make the material piece of alumina series fiber.
Next, this material piece being carried out acupuncture handles.Acupuncture is handled will be with 80/100cm
2The density needle plate that is provided with pin only be configured in a side of material piece, handle from a side of material piece.In addition, the total length of pin is longer than the thickness of material piece, carries out crimping by the side from needle plate, and pin can run through material piece fully.
Afterwards, the material piece that obtains is begun to be heated to the continuous roasting of 1250 degree one hour from normal temperature.Next, make the first outer impregnation that obtains in conjunction with material.In conjunction with using propylene in the material is rubber latex, and the impregnation amount is the 5wt% of gross weight.
Making uses the same method obtains second skin.First average diameter outer and the second outer field alumina series fiber is that 7.2 μ m, minimum diameter are 3.2 μ m.The thickness of layer is 0.3mm, and weight per unit area is 60g/m
2
Make the making central core that uses the same method.At this, when making central core, the air mass flow in the air blowing spinning process is 63m/s, and the supply rate of spinning solution is 4.3ml/h.The average diameter of the alumina series fiber of central core is 5.1 μ m, and minimum diameter is 2.4 μ m.And the thickness of central core and weight per unit area are 6.8mm and 1080g/m
2
Then, by pressure sensitive adhesive double coated (thickness is 100 μ m, and Beiersdorf company makes) first skin/central core/second skin of fitting in proper order, make the sheet material of three-decker.First skin: central core: the second outer field weight ratio (wt%) is 5: 90: 5.With this as embodiment 1.
(embodiment 2)
Make the sheet material of three-decker according to the method identical with embodiment 1.But first skin and the second outer used thickness are 0.7mm in this embodiment, and weight per unit area is 120g/m
2Layer, the central core used thickness is 6.0mm, weight per unit area is 960g/m
2Layer.First skin: central core: the second outer field weight ratio (wt%) is 10: 80: 10.With this as embodiment 2.
(embodiment 3)
Make the sheet material of three-decker according to the method identical with embodiment 1.But first skin and the second outer used thickness are 0.9mm in this embodiment, and weight per unit area is 180g/m
2Layer, the central core used thickness is 5.6mm, weight per unit area is 840g/m
2Layer.First skin: central core: the second outer field weight ratio (wt%) is 15: 70: 15.With this as embodiment 3.
(embodiment 4)
Make the sheet material of three-decker according to the method identical with embodiment 1.But first skin and the second outer used thickness are 1.4mm in this embodiment, and weight per unit area is 240g/m
2Layer, the central core used thickness is 4.6mm, weight per unit area is 720g/m
2Layer.First skin: central core: the second outer field weight ratio (wt%) is 20: 60: 20.With this as embodiment 4.
(embodiment 5)
Make the sheet material of three-decker according to the method identical with embodiment 1.But first skin and the second outer used thickness are 1.8mm in this embodiment, and weight per unit area is 300g/m
2Layer, the central core used thickness is 3.8mm, weight per unit area is 600g/m
2Layer.First skin: central core: the second outer field weight ratio (wt%) is 25: 50: 25.With this as embodiment 5.
(embodiment 6)
Make the sheet material of three-decker according to the method identical with embodiment 1.But first skin and the second outer used thickness are 2.2mm in this embodiment, and weight per unit area is 360g/m
2Layer, the central core used thickness is 3.0mm, weight per unit area is 480g/m
2Layer.First skin: central core: the second outer field weight ratio (wt%) is 30: 40: 30.With this as embodiment 6.
(embodiment 7)
Make the sheet material of three-decker according to the method identical with embodiment 1.But first skin and the second outer used thickness are 2.6mm in this embodiment, and weight per unit area is 420g/m
2Layer, the central core used thickness is 2.2mm, weight per unit area is 360g/m
2Layer.First skin: central core: the second outer field weight ratio (wt%) is 35: 30: 35.With this as embodiment 7.
(embodiment 8)
Use " copying method for making " to make first skin.
At first, carry out the fine processing of opening of inorfil.As opening fine the processing, only carried out using the dry type of pulpifier to open fine the processing.Put into mixer with opening fine raw fibre, making its weight is 1～2wt% with respect to water, and stirs about one minute.Then, in this liquid, add the combination material about 5wt%, stirred about one minute.Add inorganic about 0.5wt% to this liquid again, stirred about one minute in conjunction with material.Flocculating agent to about this liquid interpolation 0.5wt% stirs the time that is about most about 2 minutes, the brewable material slurry again.
In conjunction with material, use alumina sol as inorganic.In addition, as organically combining material, using propylene is latex, as flocculating agent, uses pakol292.
Then, the former slip that obtains is added to the former (size of mesh: 30 orders), dewater of 800mm * 500mm size.
Then, take out the formed body obtain, and use compressor reducer etc. that it is compressed, its thickness is become about original 0.5 times, simultaneously, carried out drying in 5 minutes, obtain first skin with 150 ℃ temperature heating from formed body.
The identical method of the second outer use is made.First average diameter outer and the second outer field alumina series fiber is 7.2 μ m, and minimum diameter is 3.2 μ m.The thickness of layer is 0.8mm, and weight per unit area is 120g/m
2
Making central core again uses the same method.At this, when making central core, in opening fine the processing, implement to use the dry type of pulpifier to open fibre.The average diameter of the alumina series fiber of central core is 5.1 μ m, and minimum diameter is 2.4 μ m.The thickness of layer is 6.4mm, and weight per unit area is 960g/m
2
Then, by pressure sensitive adhesive double coated (thickness is 100 μ m, and Beiersdorf company makes) first skin/central core/second skin of fitting in proper order, make the sheet material of three-decker.First skin: central core: the second outer field weight ratio (wt%) is 10: 80: 10.With this as embodiment 8.
(comparative example 1)
Use the method making central core identical with embodiment 1.The weight per unit area of central core is 1200g/m
2, thickness is 7.4mm.But, in this example, outer field, as to have only central core individual layer will be set as sheet material.With this sheet material as a comparative example 1.
(comparative example 2)
Use the method identical to make first skin and second skin with embodiment 1.First skin and the second outer field weight per unit area are 600g/m
2, thickness is 3.7mm.But, in this example, do not use central core, outer back by pressure sensitive adhesive double coated (thickness is 100 μ m, and Beiersdorf company makes) first skin/second of fitting as sheet material.First skin and the second outer field weight ratio (wt%) are 50: 50.With this sheet material as a comparative example 2.
In table 1, put the weight per unit area separately, thickness, weight ratio of two skins in embodiment 1～8, the comparative example 1,2 and central core in order and with respect to the first outer and second outer field gross thickness ratio of sheet material.
[table 1]
Use each above-mentioned sheet material to carry out the test of fiber dustability.The situation of dispersing of " microfibre " that takes place in the time of in this test, can predicting the practical operation sheet material.
Fig. 9 illustrates a part of device of fiber dustability experimental rig.As described below the carrying out of fiber dustability test.At first, each sheet material is cut into the shape (the length 83.5mm of the maximum length 262mm of directions X * Y direction) of Fig. 1, with it as sample 160.This sample 160 is encased in the plastic bag 120 of size greater than this sample, as shown in Figure 9, uses pressing plate 130 sample 160 to be fixed on one side of plastic bag 120.In plastic bag 120, fill after an amount of air sealing plastic bag 120.Then, by above-mentioned or other pressing plate plastic bag 120 is fixed to by on the outstanding arm 140 (total length 80cm) of experimental rig 110.The other end of arm 140 is connected in the vertical wall 150 of experimental rig 110.Vertical wall 150 is made of metal, and first type surface extends on the XZ plane of Fig. 9, and thickness (length of Y direction) is 25mm.Arm 140 is a fulcrum with the end that is connected in vertical wall 150, can with the perpendicular plane (YZ) of vertical wall first type surface on be rotated.This rotation at least can be more than the half-twist with respect to the first type surface of vertical wall angle.But arm 140 passes through buckle (not shown) keeps 90 ° with respect to vertical direction angle (that is level) before test.When removing buckle under this state, towards direction of arrow half-twist, and plastic bag 120 is also thereupon towards direction of arrow rotation and vertical wall 150 collisions along the YZ plane for arm 140.Because collision this moment, from sheet material sample 160 inorfil that disperses, the inorfil that disperses is trapped in the plastic bag 120.Then, open plastic bag 120 lightly, and (1cm * 1cm) reclaims the fiber that disperses attached to plastic bag 120 by adhesive tape.Then, take about about 1500 times photo in the appropriate location of adhesive tape, and measure the diameter of inorfil by scanning electron microscope.About 300 inorfils are measured, are obtained the rate of dispersing of " microfibre " by following formula:
" microfibre " rate (%)=(radical of the inorfil that diameter 3 μ m are following)/(mensuration radical) * 100 of dispersing
The result who obtains with respect to each sheet material shown in the table 1.From this table as can be known, the rate of dispersing of comparative example 1 is 1.2%, and with respect to this, the rate of dispersing of the sheet material among the embodiment 1～8 is below 0.3%, can significantly reduce the rate of dispersing of " microfibre " according to the sheet material of 3-tier architecture of the present invention.
(compression set up test)
Use each above-mentioned sheet material to carry out compressing the test that sets up.This test repeats 1000 times at most and carries out the compression and the recovery of sheet material, and the surface pressure of measuring sheet material changes.This test can relative evaluation sheet material support force the decline tendency.
Show among Figure 10 and be used for compressing the device 310 that sets up and test.The door t shore 330 of the test portion support platform 320 of level constitutes device 310 by having slightly.The central authorities of this device 310 top of platform 320 (test portion support) are provided with the T-head 340 that possesses load measurement function and oscilaltion, are provided with the top briquetting 350 of semicircle tubular of the about 103mm of diameter of stainless steel below this T-head 340.Extensometer 360 is installed on this top briquetting 350.Test portion supports platform 320 to be provided with the lower support thing 370 of semicircle tubular of the about 111mm of diameter of stainless steel.The inside of this lower support thing 370 is scraped out the semicircular cylinder shape, so that the outer shape of inner surface and top briquetting 350 matches, and is set to this inner surface that is excavated in the face of top briquetting 350.When testing, the inner surface of lower support thing 370 is provided with sample 380 (size, the 50cm * 50cm) of each known sheet material of weight.
Use this device 310 to measure by following method.At first, the T-head 340 that descends in advance is so that can't see big gap between sample 380 and the top briquetting 350.Under this state, the speed decline T-head 340 that divides with 1mm/ is with compression sample 380, when the bulk density of sample 380 becomes 0.4g/mm
3The time, measure the load that occurs on the sample 380.At this, the area/top briquetting 350 of weight/sample 380 that the bulk density of sample 380 can be by sample 380 and the interval of lower support thing 370 are obtained.The load that obtains divided by the sample area, is calculated compressing area (kPa).
Then, the speed of dividing with 1mm/ promotes T-head 340, recovers sample 380, when the bulk density of sample 380 becomes 0.367g/mm
3The time, measure the load that occurs on the sample 380, and will calculate and recover surface pressure (kPa) by load conversion surface pressure according to said method.Should operate and repeat 1000 circulations, measure the compressing surface pressure of sheet material and the variation that recovers surface pressure.Carry out same mensuration three times for each sample, obtain mean value as its result.
To be presented in Figure 11～Figure 14 and the table 1 by the result that each sample obtains.Among Figure 11 and Figure 12, transverse axis is represented the outer field weight ratio (wt%) with respect to sheet material, and the longitudinal axis is represented the recovery surface pressure (kPa) after 1000 circulations, presentation surface pressure rate of descent (%) in Figure 12 in Figure 11.This surface pressure rate of descent can be expressed from the next: surface pressure rate of descent (%)=100 * (the recovery surface pressure after recovery surface pressure-1000 circulation after 1 circulation)/(the recovery surface pressure after 1 circulation).In Figure 13 and Figure 14, transverse axis is represented outer field thickness with respect to the sheet material integral thickness than (%), and the longitudinal axis is represented the recovery surface pressure (kPa) after 1000 circulations, presentation surface pressure rate of descent (%) in Figure 14 in Figure 13.
As seen from the experiment, the sheet material of comparative example 2 recovers surface pressure decline 68.8% in 1000 circulation backs.And the sheet material in the embodiments of the invention 1～8 recovers surface pressure in 1000 circulation backs to keep high state, and rate of descent is 66.3% to the maximum.
Especially, embodiment 1～5 and 8 sheet material (outer field gross weight is than 10wt%～50wt%, and outer field gross thickness is than 8%～50%) recover surface pressures in 1000 circulation backs and descend below 62.6%, are approved to have sufficient inhibition surface pressure decline effect.And the sheet material of embodiment 1,2 and 8 (outer field gross weight is than 10wt%～20wt%, outer field gross thickness is than 8%～20%), its rate of descent reaches 51.3% to 53.6%, and 50.4% suitable with existing sheet material (comparative example 1) can learn to have low rate of descent.
At this, from the result of Figure 12 as can be known, first outer and second skin with respect to the gross weight of sheet material than W in the scope of W＞50%, the surface pressure rate of descent has near maximum (68.8%: tendency comparative example 2).And above-mentioned W is in the scope of W≤20wt%, and the surface pressure rate of descent has near minimum of a value (50.4%: tendency comparative example 1).
Equally, from the result of Figure 14 as can be known, first outer and second skin with respect to the gross thickness of sheet material than t in the scope of t＞50%, the surface pressure rate of descent has near maximum (68.8%: tendency comparative example 2).And above-mentioned t is in the scope of t≤20%, and the surface pressure rate of descent has near minimum of a value (50.4%: tendency comparative example 1).
According to above result as can be known, first skin and second skin are preferably in than W in the scope of 0＜W≤50% with respect to the gross weight of sheet material, preferably in the scope of 0＜W≤20%.And first skin and second skin are preferably in than t in the scope of 0＜t≤50% with respect to the gross thickness of sheet material, preferably in the scope of 0＜t≤20%.But as mentioned above, from practical angle, outer field gross weight should be at W 〉=2wt% than W, and outer field gross thickness should be at t 〉=1% than t.
[industrial application]
Sheet material of the present invention can be applied to the support usefulness sealing material of vehicle usefulness emission-control equipment and the sound absorber of heat insulation material and silencing means etc.
Claims (17)
1. a sheet material contains inorfil, it is characterized in that:
At least have first skin, central core and second outer these three layers,
Described first skin, described central core and the described second outer tegillum build up described first skin and described second skin is in the outer surface side,
Described central core contains the inorfil that diameter is less than or equal to 3 μ m,
Described first skin or second skin are made of the bio-soluble inorganic fibers.
2. sheet material according to claim 1 is characterized in that, the average diameter of the described first outer field inorfil and minimum diameter average diameter and the minimum diameter with the described second outer field inorfil respectively are identical.
3. sheet material according to claim 1 is characterized in that, described first skin and second skin are essentially identical layer.
4. sheet material according to claim 1 is characterized in that, described first outer and second skin with respect to the gross weight of described sheet material than W in the scope of 0＜W≤50wt%.
5. sheet material according to claim 1 is characterized in that, described first outer and second skin with respect to the thickness of described sheet material than t in the scope of 0＜t≤50%.
6. sheet material according to claim 1 is characterized in that,
The side of described central core constitutes at least a portion of the end face outside described two outer surfaces of this sheet material,
At least a portion in this side is provided with coating.
7. sheet material according to claim 6 is characterized in that, described coating covers the whole side of described central core.
8. sheet material according to claim 6 is characterized in that, described coating is made of or the second outer identical layer outer with described first.
9. sheet material according to claim 1 is characterized in that described sheet material also contains in conjunction with material.
10. sheet material according to claim 1 is characterized in that, described sheet material also comprises the adhesive linkage that is located between described first skin and described central core or second skin and the described central core.
11. a sheet manufacturing method, this sheet material contains inorfil, and described method is characterised in that and comprises step:
First skin that making is made of the first bio-soluble inorganic fibers;
Making comprises the central core that diameter is less than or equal to the inorfil of 3 μ m;
Second skin that making is made of the second bio-soluble inorganic fibers; And
At least stacked described first skin, described central core and described second outer these three layers make described first skin and described second skin be in the outer surface side, and engage each layer.
12. sheet manufacturing method according to claim 11 is characterized in that the step that engages described each layer comprises the step that engages each layer with adhesive linkage.
13. sheet manufacturing method according to claim 11, described method are characterised in that, also comprise the step of impregnation in conjunction with material.
14. an emission-control equipment, the support usefulness that comprises exhaust-gas treatment body and at least a portion that is wound on the external side face of this exhaust-gas treatment seals material, it is characterized in that,
Described support is made of any described sheet material in the described claim 1 to 10 with the sealing material.
15. an emission-control equipment comprises exhaust gas entrance pipe and outlet, is arranged on the exhaust-gas treatment body between described inlet tube and the outlet, it is characterized in that,
At least a portion at described inlet tube is provided with heat insulation material,
This heat insulation material is made of any described sheet material in the described claim 1 to 10.
16., it is characterized in that described exhaust-gas treatment body is catalyst carrier or waste gas filter according to claim 14 or 15 described emission-control equipments.
17. a silencing means, comprise interior pipe, cover the periphery of pipe in this shell, be arranged on described in sound absorber between pipe and the shell, it is characterized in that,
Described sound absorber is made of any described sheet material in the claim 1 to 10,
This sheet material is arranged between described interior pipe and the shell, makes described first skin be positioned at the outside.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-016773 | 2007-01-26 | ||
| JP2007016773 | 2007-01-26 | ||
| JP2007-337554 | 2007-12-27 | ||
| JP2007337554A JP5014113B2 (en) | 2007-01-26 | 2007-12-27 | Sheet material, method for manufacturing the same, exhaust gas treatment device, and silencer |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100053249A Division CN101229697B (en) | 2007-01-26 | 2008-01-28 | Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101898433A true CN101898433A (en) | 2010-12-01 |
Family
ID=39779084
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009102535240A Expired - Fee Related CN101758649B (en) | 2007-01-26 | 2008-01-28 | Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus |
| CN2008100053249A Expired - Fee Related CN101229697B (en) | 2007-01-26 | 2008-01-28 | Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus |
| CN200910253526XA Pending CN101898433A (en) | 2007-01-26 | 2008-01-28 | Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009102535240A Expired - Fee Related CN101758649B (en) | 2007-01-26 | 2008-01-28 | Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus |
| CN2008100053249A Expired - Fee Related CN101229697B (en) | 2007-01-26 | 2008-01-28 | Sheet member, forming method of the same, exhaust gas treatment apparatus, and muffling apparatus |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8262764B2 (en) |
| EP (3) | EP2289697B1 (en) |
| JP (1) | JP5014113B2 (en) |
| KR (1) | KR100916890B1 (en) |
| CN (3) | CN101758649B (en) |
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| TWI825473B (en) * | 2020-10-20 | 2023-12-11 | 日商山田尖端科技股份有限公司 | Resin sealing device |
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Also Published As
| Publication number | Publication date |
|---|---|
| US20080178566A1 (en) | 2008-07-31 |
| JP5014113B2 (en) | 2012-08-29 |
| EP1950035B1 (en) | 2013-12-18 |
| EP2289697A1 (en) | 2011-03-02 |
| CN101758649A (en) | 2010-06-30 |
| KR100916890B1 (en) | 2009-09-09 |
| US20100115931A1 (en) | 2010-05-13 |
| CN101758649B (en) | 2012-12-26 |
| US8308837B2 (en) | 2012-11-13 |
| EP2052854A1 (en) | 2009-04-29 |
| EP2052854B1 (en) | 2013-09-18 |
| EP2289697B1 (en) | 2012-10-17 |
| CN101229697B (en) | 2010-07-14 |
| EP1950035A1 (en) | 2008-07-30 |
| US8262764B2 (en) | 2012-09-11 |
| KR20080070574A (en) | 2008-07-30 |
| CN101229697A (en) | 2008-07-30 |
| JP2008201126A (en) | 2008-09-04 |
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