CN101872741A - Dominant wavelength distribution convergent light emitting element and manufacturing method thereof - Google Patents

Dominant wavelength distribution convergent light emitting element and manufacturing method thereof Download PDF

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Publication number
CN101872741A
CN101872741A CN200910136885A CN200910136885A CN101872741A CN 101872741 A CN101872741 A CN 101872741A CN 200910136885 A CN200910136885 A CN 200910136885A CN 200910136885 A CN200910136885 A CN 200910136885A CN 101872741 A CN101872741 A CN 101872741A
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light beam
dominant wavelength
light
wavelength conversion
luminous
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CN200910136885A
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CN101872741B (en
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吕志强
徐舒婷
陈彦文
王健源
刘如熹
谢明勋
郭政达
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Epistar Corp
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Epistar Corp
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Abstract

The invention discloses a dominant wavelength distribution convergent light emitting element and a manufacturing method thereof. The light emitting element at least comprises a substrate, a plurality of light emitting laminates arranged on the substrate and a wavelength conversion convergence layer positioned on the light emitting laminates, wherein the plurality of light emitting laminates emit first light beams with a first dominant wavelength variance; and the wavelength conversion convergence layer absorbs the first light beams and emits second light beams with a second dominant wavelength variance. In the light emitting element, the first dominance wavelength variance is greater than the second dominant wavelength variance of the second light beams.

Description

The light-emitting component of dominant wavelength distribution convergent and manufacture method thereof
Technical field
The present invention relates to a kind of wafer scale light-emitting component and manufacture method thereof, particularly relate to a kind of dominant wavelength (dominant wavelength) that comprises on it and be LED wafer and a kind of emission light dominant wavelength of LED wafer that makes that convergence distributes and be the method that convergence distributes.
Background technology
Light-emitting diode (light-emitting diode, LED) principle of luminosity is the energy difference that utilizes electronics to move between n N-type semiconductor N and p N-type semiconductor N, form with light discharges energy, such principle of luminosity is different from the principle of luminosity of incandescent lamp heating, so light-emitting diode is called as cold light source.In addition, light-emitting diode has advantages such as high-durability, the life-span is long, light and handy, power consumption is low, and therefore illumination market is now placed high hopes for light-emitting diode, and it is considered as the illuminations of a new generation.
Figure 1A to Fig. 1 E is the manufacturing process schematic diagram of known light-emitting component.
At first, shown in Figure 1A, provide substrate 10; Shown in Figure 1B, form a plurality of epitaxial loayers 12 on substrate 10 for another example; Then, shown in Fig. 1 C, utilize the photoengraving lithography to carry out etching, on substrate 10, to make a plurality of luminous laminations 14 at a plurality of epitaxial loayers 12; Subsequently, shown in Fig. 1 D, on luminous lamination 14, form electrode 16, to form LED wafer (wafer) 100; At last, shown in Fig. 1 E, LED wafer 100 is cut, to form LED core 18.
Yet, in fact numerous luminous lamination 16 emitted light dominant wavelengths distribute also inhomogeneous on the LED wafer 100, its gap can reach 15nm to 20nm or bigger, and it is also big that therefore above-mentioned luminous lamination 16 forms LED core 18 back emitted light dominant wavelength differences.The uneven problem of these LED core 18 emission light dominant wavelengths has influenced the consistency of using its product performance of product of LED core further.Being mixed into white light with known dominant wavelength 460nm blue LED chip collocation yellow fluorescence powder is example, if distributing, the dominant wavelength of the blue LED tube core on the same LED wafer reaches 20nm, be that its dominant wavelength distributes by 450nm to 470nm, its collocation excitation wavelength also is affected by the composite white light color temperature distribution of light that the yellow wavelengths transformational substance of 570nm is excited.
As shown in Figure 2, because the dominant wavelength distributional difference of each luminous lamination on the LED wafer, institute's its colour temperature of composite white light (color temperature) is distributed between the 6500K to 9500K behind its formed tube core collocation transformational substance, have the colour temperature variation about about 3000K, the consistency of product quality is caused very big influence.
For solving luminous lamination 16 dominant wavelengths problem pockety on the above-mentioned same LED wafer, in known LED core 18 manufacture processes, often as shown in Figure 3, the program that adds some survey, classification (Sorting) and screening (Binning), screen at numerous LED core 18, to pick out the close LED core 18 of dominant wavelength distribution, with application in response to different wave length characteristic demand.
Though can reducing the dominant wavelength skewness, the program that point is surveyed, classified and screens shows conforming influence to using product quality, but when LED core 18 is applied to dominant wavelength is evenly distributed when requiring harsh product, the back light source in LED element of large-sized monitor for example, spendable LED core 18 ratios are on the low side on the LED wafer 100.In addition, classification is wasted time and energy with the operation of screening, and has also increased the cost and the required time of production LED core.
Summary of the invention
Purpose of the present invention is providing a kind of LED wafer of dominant wavelength distribution convergent, comprise substrate, a plurality of luminous lamination is positioned on the substrate, and the wavelength Conversion convergence layer, be positioned on a plurality of luminous laminations, in order to the dominant wavelength that restrains and the conversion luminescence lamination is sent.
Another object of the present invention is to disclose a kind of method that LED wafer dominant wavelength distributes that restrains, its step comprises provides substrate, form a plurality of luminous being stacked on the substrate, and form the wavelength Conversion convergence layer on a plurality of luminous laminations, make the dominant wavelength that each luminous lamination emits beam on the LED wafer present the convergence distribution.
Another purpose of the present invention is to provide method of manufacturing luminescent device, by forming the wavelength Conversion convergence layer, to restrain the wavelength variation of luminous lamination emitted light, improves the utilization rate of LED core thus.
A further object of the present invention is to provide method of manufacturing luminescent device, by forming the wavelength Conversion convergence layer, to restrain the dominant wavelength variation of luminous lamination emitted light, reduces classification and the operation of screening in the LED core production process thus.
Under cooperate appended accompanying drawing to illustrate in detail by specific embodiment, when the effect that is easier to understand purpose of the present invention, technology contents, characteristics and is reached.
Description of drawings
Figure 1A to Fig. 1 E is known LED core manufacturing process schematic diagram.
Fig. 2 is the CIE 1931 hue coordinate figure of known blue LED tube core collocation yellow fluorescence powder.
Fig. 3 is that known LED core point is surveyed schematic diagram.
Fig. 4 A to Fig. 4 F is the manufacturing process schematic diagram of the embodiment of the invention.
Fig. 5 is the structural representation of another embodiment of the present invention.
Fig. 6 is the CIE 1931 hue coordinate figure of the embodiment of the invention.
Fig. 7 is the structural representation of further embodiment of this invention.
Fig. 8 A and Fig. 8 B are yet another embodiment of the invention structural representation.
Fig. 9 is the structural representation of cutting step of the present invention.
Description of reference numerals
10~substrate, 12~epitaxial loayer
14~luminous lamination 16~electrode
18~LED core, 100~LED wafer
20~substrate, 22~epitaxial loayer
220~the first conductive-type semiconductor layers, 222~active layer
224 second conductive-type semiconductor layers 24~luminous lamination
26~electrode, 200~LED wafer
210~the first light beams, 28~wavelength Conversion convergence layer
220~the second light beams, 30~LED core
32~wavelength conversion layer 230~the 3rd light beam
240~the 4th light beam 500~LED wafer
50~substrate 52,52 '~luminous lamination
520~the first conductive-type semiconductor layers, 522~luminescent layer
524~the second conductive-type semiconductor layers, 54~the first electrodes
56~the second electrodes, 58~wavelength Conversion convergence layer
60~electric connection structure, 62~insulating barrier
64~metal level, 70~light emitting diode array chips
Embodiment
Following conjunction with figs. explanation embodiments of the invention.
Fig. 4 A to Fig. 4 F is the manufacturing process schematic diagram of the embodiment of the invention, shown in Fig. 4 A, substrate 20 is provided, wherein substrate 20 can be an electrically-conductive backing plate, and shown in Fig. 4 B, on substrate 20, form a plurality of epitaxial loayers 22, wherein a plurality of epitaxial loayers 22 from top to bottom comprise first conductive-type semiconductor layer 220 at least, the active layer 222 and second conductive-type semiconductor layer 224, and the material of a plurality of epitaxial loayers 22 can be selected from and comprise aluminium (Al), gallium (Ga), indium (In), nitrogen (N), the semiconductor substance of phosphorus (P) or arsenic (As), for example gallium nitride (GaN) series material or AlGaInP (AlGaInP) series material, following present embodiment is that example describes with gallium nitride series material.
Subsequently, shown in Fig. 4 C, utilize a plurality of epitaxial loayers 22 of photoengraving lithography etching for another example to form a plurality of luminous laminations 24 on substrate 20; Shown in Fig. 4 D, utilize evaporation coating technique respectively at forming electrode 26 on a plurality of luminous laminations 24, to obtain LED wafer (wafer) 200.
This luminous lamination 24 can send first light beam 210, and the dominant wavelength of first light beam can be between between the 390nm to 430nm, has the first dominant wavelength difference between wherein optional 2 first light beams 210, in this LED wafer 200, the maximum of the first dominant wavelength difference is the first dominant wavelength variation value V 1
Then, after the step that forms electrode 26, shown in Fig. 4 E, further in the surface coverage wavelength Conversion convergence layer 28 of luminous lamination 24, its material can be fluorescent material or phosphorus, and wavelength Conversion convergence layer 28 is made of fluorescent powder in the present embodiment, and its material can be selected from Si 3MgSi 2O 8: Eu, BaMgAl 10O 17: Eu, (SrBaCa) 5(PO 4) 3Cl:Eu, Sr 3(Al 2O 5) Cl 2: Eu 2+And Sr 4Al 14O 25: any one or more than one the material of blue-fluorescence groups that powder constitutes such as Eu, and above-mentioned fluorescent powder is coated the surface of luminous lamination 24 equably or partly; Wherein, this wavelength Conversion convergence layer 28 absorbs first light beam 210 that luminous lamination 24 sent haply fully and is converted to second light beam 220.
In present embodiment, these second light beam, 220 dominant wavelengths are between long wavelength's blue light of 450nm to 470nm, have the second dominant wavelength difference between wherein optional 2 second light beams 220, in this LED wafer 200, the maximum of the second dominant wavelength difference is the second dominant wavelength variation value V 2At last, shown in Fig. 4 F, a plurality of luminous lamination 24 on the LED wafer 200 is cut, to form a plurality of LED core 30.
In the foregoing description, the first dominant wavelength variation value V 1Between between the 15nm to 20nm, and the second dominant wavelength variation value V 2Then less than 10nm, preferred person is less than 5nm; By on luminous lamination 24, forming wavelength Conversion convergence layer 28, to reduce the dominant wavelength difference that optional two luminous laminations 24 emit beam in the LED wafer 200, make the dominant wavelength distribution of same LED wafer 200 formed LED core 30 be the convergence distribution, improve the In-commission Rate of luminous lamination 24 on the LED wafer 200; Moreover, the foregoing description more can omit classification and the operation of screening in the known luminescence diode chip manufacture process, reduces production costs further.
In addition, the present invention also can be as shown in Figure 5, after the step that forms wavelength Conversion convergence layer 28, form wavelength conversion layer 32 on wavelength Conversion convergence layer 28, wherein, wavelength conversion layer 32 comprises one or more fluorescent powder, and its material can be selected from yellow fluorescence powder, BaMgAl such as yttrium-aluminium-garnet, alkaline earth halogen aluminate 10O 17: Eu, MnBa 2SiO 4: Eu, (Sr, Ca) SiO 4: Eu, CaSc 2O 4: Eu, Ca 8Mg (SiO 4) 4Cl 2: Eu, Mn, SrSi 2O 2N 2: Eu, LaPO 4: Tb, Ce, Zn 2SiO 4: Mn, ZnS:Cu, YBO 3: Ce, Tb, (Ca, Sr, Ba) Al 2O 4: Eu, Sr 2P 2O 7: Eu, Mn, SrAl 2S 4: Eu, BaAl 2S 4: Eu, Sr 2Ga 2S 5: Eu, SiAlON:Eu, KSrPO 4: Tb, Na 2Gd 2B 2O 7: Ce, green fluorescence powders such as Tb are with Y 2O 3: Eu, YVO 4: Eu, CaSiAlN 3: Eu, (Sr, Ca) SiAlN 3: Eu, Sr 2Si 5N 8: Eu, CaSiN 2: Eu, (Y, Gd) BO 3: Eu, (La, Y) 2O 2S:Eu, La 2TeO 6: Eu, SrS:Eu, Gd 2MoO 6: Eu, Y 2WO 6: Eu, Bi, Lu 2WO 6: Eu, Bi, (Ca, Sr, Ba) MgSi 2O 6: Eu, Mn, Sr 3SiO 5: Eu, SrY 2S 4: Eu, CaSiO 3: Eu, Ca 8MgLa (PO 4) 7: Eu, Ca 8MgGd (PO 4) 7: Eu, Ca 8MgY (PO 4) 7: Eu, CaLa 2S 4: red fluorescence powders such as Ce constitute at least a material in the group, and wherein above-mentioned fluorescent powder is coated on the wavelength convergence conversion layer 28 equably or partly.
In present embodiment, wavelength conversion layer 32 comprises at least a yellow fluorescence powder, this wavelength conversion layer 32 meeting absorption portion second light beam 220, and be converted to the 3rd yellow light beam 230, the dominant wavelength of wherein above-mentioned the 3rd light beam 230 is 570nm; Subsequently, above-mentioned yellow the 3rd light beam 230 mixes the 4th light beam 240 that produces white with second light beam 220 that is not absorbed by wavelength conversion layer 32.
Because the dominant wavelength of second light beam is 460nm, and the second dominant wavelength maximum difference is less than 10nm, and preferred person be less than 5nm, thus in present embodiment the second light beam dominant wavelength distribution between between the 455nm to 465nm; Fig. 6 is the CIE 1931 chromaticity coordinate figure of the embodiment of the invention the 4th light beam, as shown in Figure 6, above-mentioned second light beam 220 mixes gained the 4th light beam 240 with the 3rd light beam 230, its colour temperature approximately is distributed in (intersection point of blackbody curve and solid line among the figure) between the 6500K to 8500K, its color temperature difference is less than 2000K, and preferred person is less than 1000K.
Directly the blue LED chip collocation yellow fluorescence powder of utilization dominant wavelength distribution 15nm to 20nm is mixed into have the 3000K color temperature difference white light of (intersection point of blackbody curve and dotted line among the figure) in the known technology, has promoted the uniformity of each luminous lamination emitted light on the LED wafer in the embodiment of the invention significantly.
Moreover, in the above-described embodiments,, do not mean that scope of the present invention is confined to the light-emitting diode of vertical stratification though explain with the light emitting diode with vertical structure tube core; Fig. 7 is the another embodiment of the present invention structural representation, as shown in Figure 7, LED wafer 500 comprises substrate 50, a plurality of luminous laminations 52 that place on the substrate 50, first electrode 54 and second electrode 56, and wavelength Conversion convergence layer 58, wherein luminous lamination 52 from top to bottom comprises first conductive-type semiconductor layer 520 at least, active layer 522, and second conductive-type semiconductor layer 524, the plane that all has exposed second conductive-type semiconductor layer 524 on each luminous lamination 52, first electrode 54 and second electrode 56 then lay respectively on first conductive-type semiconductor layer 520 and second conductive-type semiconductor layer 524, and 58 of wavelength Conversion convergence layer are covered on a plurality of luminous laminations 52.
In addition, Fig. 8 A and Fig. 8 B are further embodiment of this invention structural representation, and the present invention also can comprise electric connection structure 60 as shown in the figure, in order to the adjacent luminous lamination 52/52 ' of connecting; Shown in Fig. 8 A, the electric connection structure 60 of present embodiment is a metal wire, utilize lead-in wire (wire bonding) technology to make first electrode 54 of second electrode 56 and adjacent another luminous lamination 52 ' on the luminous lamination 52 produce and electrically connect, allow form series circuit between different luminous lamination 52/52 '; Also can be shown in Fig. 8 B, its electrically connect structure 60 comprises insulating barrier 62 and metal level 64, form earlier insulating barrier 62 between luminous lamination 52 and adjacent luminous lamination 52 ', then form metal level 64 again, make first electrode 54 of second electrode 56 and adjacent another luminous lamination 52 ' on the luminous lamination 52 produce and electrically connect, make between different luminous lamination 52/52 ' and form series circuit.
Moreover, in the step of cutting LED wafer, as shown in Figure 9, except cutting as line of cut A, each luminous lamination 52 is cut into outside the LED core, also can cut, a plurality of luminous laminations 52/52 ' that utilize electric connection structure 60 to form series connection are cut into chip-scale light emitting diode matrix 70 according to line of cut B.Under the general situation, the pressure drop of single luminous lamination 52/52 ' is about 3.5V, and therefore the luminous lamination 52/52 ' with 14 series connection is cut into light emitting diode array chips (chip) 70, just can directly apply to the automobile-used AC-powered of 48V; Also the luminous lamination 52/52 ' of 30 series connection can be cut into light emitting diode array chips 70, make it to directly apply in the 100V family expenses alternating current; Wherein, in the above-mentioned light emitting diode array chips 70, owing to all have the wavelength Conversion convergence layer on each luminous lamination 52/52 ', therefore the dominant wavelength of each luminous lamination 52/52 ' emitted light is more consistent, omit the operation of arranging again according to dominant wavelength distributive sorting and screening earlier in the known luminescence diode array tube core manufacture process thus, to reduce production costs.
The foregoing description only is explanation technological thought of the present invention and characteristics, its purpose makes those skilled in the art can understand content of the present invention and is implementing according to this, when can not with the qualification scope of the invention, promptly equivalent variations or the modification of doing according to disclosed spirit generally must be contained within the scope of the present invention.

Claims (18)

1. the method for manufacturing luminescent device of a dominant wavelength distribution convergent comprises the following steps: at least
Substrate is provided;
Form a plurality of luminous being stacked on this substrate, wherein these a plurality of luminous laminations send first light beam, and this first light beam has the first dominant wavelength variation value; And
Form the wavelength Conversion convergence layer on these a plurality of luminous laminations, this wavelength Conversion convergence layer absorbs this first light beam and sends second light beam, and this second light beam has the second dominant wavelength variation value, and wherein this first dominant wavelength variation value is greater than this second light beam dominant wavelength variation value.
2. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1, wherein the material of these a plurality of luminous laminations is selected from the semiconductor substance that comprises aluminium, gallium, indium, nitrogen, phosphorus or arsenic.
3. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1, wherein the dominant wavelength of this first light beam is between between the 390nm to 430nm.
4. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1, wherein this first light beam is absorbed by this wavelength Conversion convergence layer fully.
5. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1, this wavelength Conversion convergence layer comprises phosphorescence powder or fluorescent powder at least, and wherein the fluorescent powder of this wavelength Conversion convergence layer is selected from Si 3MgSi 2O 8: Eu, BaMgAl 1oO 17: Eu, (SrBaCa) 5(PO 4) 3Cl:Eu, Sr 3(Al 2O 5) Cl 2: Eu 2+And Sr 4Al 14O 25: Eu constitutes at least a material in the group.
6. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1, also comprise and form at least one wavelength conversion layer on this wavelength Conversion convergence layer, this second light beam of this wavelength conversion layer absorption portion and send the 3rd light beam, and this second light beam mixes generation the 4th light beam with the 3rd light beam, wherein the material of this wavelength conversion layer is selected from yellow fluorescence powder, BaMgAl such as yttrium-aluminium-garnet, alkaline earth halogen aluminate 10O 17: Eu, MnBa 2SiO 4: Eu, (Sr, Ca) SiO 4: Eu, CaSc 2O 4: Eu, Ca 8Mg (SiO 4) 4Cl 2: Eu, Mn, SrSi 2O 2N 2: Eu, LaPO 4: Tb, Ce, Zn 2SiO 4: Mn, ZnS:Cu, YBO 3: Ce, Tb, (Ca, Sr, Ba) Al 2O 4: Eu, Sr 2P 2O 7: Eu, Mn, SrAl 2S 4: Eu, BaAl 2S 4: Eu, Sr 2Ga 2S 5: Eu, SiAlON:Eu, KSrPO 4: Tb, Na 2Gd 2B 2O 7: Ce, green fluorescence powders such as Tb are with Y 2O 3: Eu, YVO 4: Eu, CaSiAlN 3: Eu, (Sr, Ca) SiAlN 3: Eu, Sr 2Si 5N 8: Eu, CaSiN 2: Eu, (Y, Gd) BO 3: Eu, (La, Y) 2O 2S:Eu, La 2TeO 6: Eu, SrS:Eu, Gd 2MoO 6: Eu, Y 2WO 6: Eu, Bi, Lu 2WO 6: Eu, Bi, (Ca, S r, Ba) MgSi 2O 6: Eu, Mn, Sr 3SiO 5: Eu, SrY 2S 4: Eu, CaSiO 3: Eu, Ca 8MgLa (PO 4) 7: Eu, Ca 8MgGd (PO 4) 7: Eu, Ca 8MgY (PO 4) 7: Eu, CaLa 2S 4: red fluorescence powders such as Ce constitute at least a material in the group.
7. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 6, wherein the color temperature distribution of the 4th light beam is less than 2000K.
8. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1 also comprises a plurality of electric connection structures of formation, with these a plurality of luminous laminations of series connection.
9. the method for manufacturing luminescent device of dominant wavelength distribution convergent as claimed in claim 1 also comprises the step of cutting this substrate.
10. the light-emitting component of a dominant wavelength distribution convergent comprises at least:
Substrate;
A plurality of luminous laminations are positioned on this substrate, and wherein this luminous lamination sends first light beam, and this first light beam has the first dominant wavelength variation value;
A plurality of electrodes lay respectively on these a plurality of luminous laminations, form with this luminous lamination to electrically connect; And
A plurality of wavelength Conversion convergence layer are covered in respectively on these a plurality of luminous laminations, absorb this first light beam and be converted to second light beam, and this second light beam has the second dominant wavelength variation value, and wherein this first dominant wavelength variation value is greater than this second dominant wavelength variation value.
11. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 10, wherein this first light beam is absorbed by this wavelength Conversion convergence layer fully.
12. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 10, wherein the dominant wavelength of this first light beam can be between between the 390nm to 430nm.
13. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 10, this wavelength Conversion convergence layer comprises phosphorescence powder or fluorescent powder at least, and wherein the fluorescent powder material of this wavelength Conversion convergence layer can be selected from Si 3MgSi 2O 8: Eu, BaMgAl 1oO 17: Eu, (SrBaCa) 5(PO 4) 3Cl:Eu, Sr 3(Al 2O 5) Cl 2: Eu 2+And Sr 4Al 14O 25: Eu constitutes at least a material in the group.
14. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 10, wherein this luminous lamination is selected from the semiconductor substance that comprises aluminium, gallium, indium, nitrogen, phosphorus or arsenic.
15. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 10, also comprising wavelength conversion layer is positioned on this wavelength Conversion convergence layer, this second light beam of this Wavelength conversion substance absorption portion, and launch the 3rd light beam, and the 3rd light beam mixes generation the 4th light beam with this second light beam, wherein this Wavelength conversion substance is selected from yellow fluorescence powder, BaMgAl such as yttrium-aluminium-garnet, alkaline earth halogen aluminate 1oO 17: Eu, MnBa 2SiO 4: Eu, (Sr, Ca) SiO 4: Eu, CaSc 2O 4: Eu, Ca 8Mg (SiO 4) 4Cl 2: Eu, Mn, SrSi 2O 2N 2: Eu, LaPO 4: Tb, Ce, Zn 2SiO 4: Mn, ZnS:Cu, YBO 3: Ce, Tb, (Ca, Sr, Ba) Al 2O 4: Eu, Sr 2P 2O 7: Eu, Mn, SrAl 2S 4: Eu, BaAl 2S 4: Eu, Sr 2Ga 2S 5: Eu, SiAlON:Eu, KSrPO 4: Tb, Na 2Gd 2B 2O 7: Ce, green fluorescence powders such as Tb are with Y 2O 3: Eu, YVO 4: Eu, CaSiAlN 3: Eu, (Sr, Ca) SiAlN 3: Eu, Sr 2Si 5N 8: Eu, CaSiN 2: Eu, (Y, Gd) BO 3: Eu, (La, Y) 2O 2S:Eu, La 2TeO 6: Eu, SrS:Eu, Gd 2MoO 6: Eu, Y 2WO 6: Eu, Bi, Lu 2WO 6: Eu, Bi, (Ca, Sr, Ba) MgSi 2O 6: Eu, Mn, Sr 3SiO 5: Eu, SrY 2S 4: Eu, CaSiO 3: Eu, Ca 8MgLa (PO 4) 7: Eu, Ca 8MgGd (PO 4) 7: Eu, Ca 8MgY (PO 4) 7: Eu, CaLa 2S 4: red fluorescence powders such as Ce constitute at least a material in the group.
16. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 15, wherein the color temperature distribution of the 4th light beam is less than 2000K.
17. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 10 also comprises a plurality of electric connection structures, electrically connects these a plurality of electrodes and makes these a plurality of luminous laminations form series circuit.
18. the light-emitting component of dominant wavelength distribution convergent as claimed in claim 17, wherein this electric connection structure comprises the insulating barrier that is positioned between this luminous lamination, and the metal level that is connected with these a plurality of electrodes, is positioned on this insulating barrier.
CN 200910136885 2008-07-16 2009-04-24 Dominant wavelength distribution convergent light emitting element and manufacturing method thereof Active CN101872741B (en)

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CN103289687A (en) * 2012-02-28 2013-09-11 海洋王照明科技股份有限公司 Cerium-doped sulphoaluminate luminescent film, preparation method and application of same
CN107464869A (en) * 2017-06-07 2017-12-12 东莞中之光电股份有限公司 A kind of LED light source preparation method with special photochromic wave band
CN108305930A (en) * 2018-03-20 2018-07-20 澳洋集团有限公司 Phosphor gel, high power LED device and preparation method thereof
CN112877070A (en) * 2021-01-18 2021-06-01 威海长和光导科技有限公司 Eu for W-LED3+/Tb3+Doped LiSrPO4Fluorescent powder and preparation method thereof

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WO2005038935A1 (en) * 2003-10-15 2005-04-28 Nichia Corporation Light-emitting device
CN101140967B (en) * 2006-09-08 2010-05-19 晶元光电股份有限公司 High efficient phosphor conversion light emitter and its making process

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289687A (en) * 2012-02-28 2013-09-11 海洋王照明科技股份有限公司 Cerium-doped sulphoaluminate luminescent film, preparation method and application of same
CN103289687B (en) * 2012-02-28 2015-10-28 海洋王照明科技股份有限公司 Cerium dopping sulphoaluminate light-emitting film, preparation method and application thereof
CN107464869A (en) * 2017-06-07 2017-12-12 东莞中之光电股份有限公司 A kind of LED light source preparation method with special photochromic wave band
CN108305930A (en) * 2018-03-20 2018-07-20 澳洋集团有限公司 Phosphor gel, high power LED device and preparation method thereof
CN112877070A (en) * 2021-01-18 2021-06-01 威海长和光导科技有限公司 Eu for W-LED3+/Tb3+Doped LiSrPO4Fluorescent powder and preparation method thereof

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