Background technology
Iron silicon aluminum alloy has good soft magnetic property, as far back as last century the '30s just found by the Japanese, particularly special component Si~9.6%, Al~5.4%, surplus is the alloy of Fe, μ m value can reach 160,000, is named as the Sendust alloy.For no other reason than that silicon, aluminium are easy to generate segregation and scaling loss and are not widely used when smelting.Last century, the nineties was because the progress of smelting technology and the growth requirement of electronic industry have promoted the development of iron silicon aluminum alloy magnetic core.Japanese subsequently gold show husband adds neodymium (Nd) in the Sendust alloy, improved its processibility, magnetic (μ
0, μ
m, Hc, Bs), wear resistance all do not reduce.The investigator's addition element that has (Sn, Be, Ti, V, Y, B, Mo, W, Cr etc.) back alloy rigidity has improved, and the wear resistance that has has improved.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum is provided.
The making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum comprises the steps:
1) will smelt in technically pure iron, polysilicon, fine aluminium, cerium-iron alloy or the lanthanum iron alloy input vacuum induction furnace, be smelted into the FeSiAl alloy cast ingot that contains a small amount of rare-earth element cerium or lanthanum, the mass percentage content that its alloy cast ingot is formed is: Si 9.0~9.8%, Al 5.4~6.0%, Ce or La 0.02~0.25%, C 0.006~0.015%, O
20.008~0.010%, S 0.008~0.028%, P 0.03~0.035%, all the other are Fe.
2) alloy cast ingot is become the FeSiAl powdered alloy with Mechanical Crushing; after the protective atmosphere high-temperature heat treatment, sieve; make the mass percentage content of FeSiAl powdered alloy size composition be :-100~+ 140 orders account for 5%;-140~+ 200 orders account for 15%;-200~+ 300 orders account for 45%, and-300 orders account for 35%.
3) after above-mentioned FeSiAl powdered alloy carries out the surface passivation processing with the phosphoric acid spirituous solution, add 0.2% kaolin again, 0.2% lubricant, 0.5% releasing agent mixes; Use the dry powder automatic forming hydraulic press compression molding, pressure is 22~25T/cm
2, compacting is shaped as annular.
4) press-formed product thermal treatment under nitrogen protection, thermal treatment temp is: 640~690 ℃, at last with the soft magnet silumin magnetic core that obtains adding a small amount of rare-earth element cerium or lanthanum after the spraying of Resins, epoxy paint.
Described releasing agent is Zinic stearas or barium stearate.Described lubricant is a moly-sulfide.The present invention compared with prior art has following beneficial effect:
1) improved the specific resistance of iron silicon aluminum alloy magnetic core,, made the specific resistance of alloy can reach 82-85x10 owing to add a small amount of rare-earth element cerium or lanthanum in the alloy
-6Ω m;
2) reduced the power loss of Fe-Si-Al magnetic core, the iron silicon aluminum alloy magnetic core made from this alloy is 125 ± 5 at magnetic permeability, frequency is that 50KHz, magnetic induction density are that power loss unshakable in one's determination under the 500Gs condition can be reduced to 70mw/cm
3Below;
3) improved the temperature stability of magnetic core magnetic permeability, making magnetic permeability with this alloy is 125 Fe-Si-Al magnetic core, and the temperature stability of its magnetic permeability is strong, and the fall of magnetic permeability was less than 3% when working temperature rose to 125 ℃.
Embodiment
Embodiment 1:
1) iron silicon aluminum alloy is smelted the vacuum medium frequency induction furnace of selecting nominal 100Kg for use, earlier technically pure iron is melted, successively polysilicon, fine aluminium, cerium-iron alloy are dropped in the vacuum induction furnace then and smelt, adopt induction stirring to be smelted into the FeSiAl alloy cast ingot, the mass percentage content that its FeSiAl alloy cast ingot is formed is: Si9%, and Al 6.0%, and Ce 0.02%, C 0.015%, O
20.010%, S 0.008%, and P 0.035%, and surplus is Fe.
2) alloy cast ingot is become the FeSiAl powdered alloy with Mechanical Crushing; after the protective atmosphere high-temperature heat treatment, sieve; make the mass percentage content of FeSiAl powdered alloy size composition be :-100~+ 140 orders account for 5%;-140~+ 200 orders account for 15%;-200~+ 300 orders account for 45%, and-300 orders account for 35%.
3) powder being carried out surface passivation handles, extract above-mentioned FeSiAl powdered alloy 1000g, pour with 5g phosphoric acid again that proportioning becomes the phosphoric acid spirituous solution in the 80g alcohol into, the phosphoric acid spirituous solution is poured into to stir in the FeSiAl powdered alloy of this 1000g makes its drying, and then add kaolin 2g, moly-sulfide 2g, Zinic stearas 5g mix; Use the dry powder automatic forming hydraulic press compression molding, pressure is 22T/cm
2, compacting annular size: external diameter Φ 26.90mm, internal diameter Φ 14.70mm, height 11.20mm.;
4) press-formed product is in nitrogen protection thermal treatment, and thermal treatment temp is: 670 ℃, and at last with the soft magnet silumin magnetic core that obtains adding a small amount of rare-earth element cerium after the spraying of Resins, epoxy paint.The resistance alloys coefficient reaches 82.5 * 10
-6Ω m.Sample detects and adopts coiling telefault enameled wire Φ 0.5mm, 26 circles.Its magnetic parameter such as table 1.
Table 1
The corresponding inductance coefficent 159nH/N of inductance value 107.5 μ H
2, meet magnetic permeability 125.
Magnetic permeability varies with temperature as table 2:
Table 2
Embodiment 2:
Making method is with embodiment 1, and alloy composition is Si 9.56%, and Al 5.4%, and Ce 0.125%, C0.012%, O
20.010%, S 0.025%, and P 0.032%, and surplus is Fe, compacting pressure 23T/cm
2, 690 ℃ of thermal treatment temps.
The resistance alloys coefficient is 83.8 * 10
-6Ω m.
The magnetic parameter such as the table 3 of embodiment 2 goods.
Compacting annular size: external diameter Φ 16.50mm, internal diameter Φ 10.15mm, height 6.35mm.Coiling telefault enameled wire Φ 0.5mm, 17 circles.
Table 3
The corresponding inductance coefficent 74nH/N of inductance value 21.4 μ H
2Meet magnetic permeability 125.
Magnetic permeability varies with temperature rate such as table 4
Table 4
Embodiment 3:
Making method is with embodiment 1, and chemical ingredients is Si 9.80%, and Al 5.62%, and Ce 0.250%, and C 0.008%, O
20.008%, S 0.028%, and P 0.030%, and surplus is Fe, compacting pressure 25T/cm
2, 640 ℃ of thermal treatment temps
The resistance alloys coefficient is 85.2 * 10
-6Ω m.
The magnetic parameter such as the table 5 of magnetic core goods
Compacting size: external diameter Φ 33.0mm, internal diameter Φ 19.95mm, height 11.20mm.Coiling telefault enameled wire Φ 0.5mm, 33 circles.
Table 5
The corresponding inductance coefficent 137nH/N of inductance value 149.2 μ H
2Corresponding magnetic permeability 125.
Magnetic permeability varies with temperature rate such as table 6
Table 6
Embodiment 4:
Making method is with embodiment 1, and main chemical compositions such as table 7, remainder are Fe (being mass percent).
Table 7
Suppress annular size with embodiment 1, resistance alloys coefficient such as table 7.
The magnetic parameter such as the table 8 of magnetic core goods
Table 8
DC Bias 20 Oe, 100KHz, all greater than 74%, on show the corresponding magnetic permeability 125 ± 5% of inductance value
Magnetic permeability varies with temperature as table 9
Table 9