CN101871071A - Manufacturing method of soft magnet silicon-aluminum alloy magnetic powder core with small amounts of rare earth element cerium or lanthanum - Google Patents

Manufacturing method of soft magnet silicon-aluminum alloy magnetic powder core with small amounts of rare earth element cerium or lanthanum Download PDF

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CN101871071A
CN101871071A CN 201010209014 CN201010209014A CN101871071A CN 101871071 A CN101871071 A CN 101871071A CN 201010209014 CN201010209014 CN 201010209014 CN 201010209014 A CN201010209014 A CN 201010209014A CN 101871071 A CN101871071 A CN 101871071A
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lanthanum
alloy
earth element
cerium
fesial
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CN101871071B (en
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刘志文
王�锋
蔡炳初
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Huizhou Keli Magnetics Co., Ltd.
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HUZHOU WEIKONG ELECTRONIC CO Ltd
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Abstract

The invention discloses a manufacturing method of a soft magnet silicon-aluminum alloy magnetic powder core with small amounts of rare earth element cerium or lanthanum, which comprises the following steps: 1) smelting industrial pure iron, polycrystalline silicon, pure aluminum, cerium-iron alloy or lanthanum-iron alloy in a vacuum induction furnace into FeSiAl alloy cast ingots with small amounts of cerium or lanthanum, wherein the alloy cast ingots comprise the components of 9.0-9.8% of Si, 5.4-6.0% of Al, 0.02-0.25% of Ce or La, 0.006-0.015% of C, 0.008-0.010% of O2, 0.008-0.028% of S, 0.03-0.035% of P and balance of Fe; and mechanically crushing into FeSiAl alloy powder, carrying out high-heat treatment in a shielding gas atmosphere, and then screening; 2) carrying out surface passivation treatment on the FeSiAl alloy powder with phosphoric acid and alcohol, then adding 0.20% of kaolin, 0.20% of lubricant and 0.50% of parting compound, uniformly mixing, and carrying out pressure forming; and 3) carrying out heat treatment and surface spraying. The invention can increase the resistivity of the magnetic core and reduce the high-frequency eddy current loss, and has lower magnetic core loss. Besides, the invention improves the temperature stability of the magnetic permeability, and enables the decline of the magnetic permeability to be less than 3% when the working temperature rises to 125 DEG C.

Description

Add the making method of the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum
Technical field
The present invention relates to the making method of magnetic bodies, relate in particular to a kind of making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum.This magnetic core use range is very extensive, mainly is applicable in PFC inductance and output inductor among LED power supply, switch power supply and the UPS, the electromagnetic interface filter main-transformer and other pulse transformer etc. in differential mode inductance, the anti exciting converter.
Background technology
Iron silicon aluminum alloy has good soft magnetic property, as far back as last century the '30s just found by the Japanese, particularly special component Si~9.6%, Al~5.4%, surplus is the alloy of Fe, μ m value can reach 160,000, is named as the Sendust alloy.For no other reason than that silicon, aluminium are easy to generate segregation and scaling loss and are not widely used when smelting.Last century, the nineties was because the progress of smelting technology and the growth requirement of electronic industry have promoted the development of iron silicon aluminum alloy magnetic core.Japanese subsequently gold show husband adds neodymium (Nd) in the Sendust alloy, improved its processibility, magnetic (μ 0, μ m, Hc, Bs), wear resistance all do not reduce.The investigator's addition element that has (Sn, Be, Ti, V, Y, B, Mo, W, Cr etc.) back alloy rigidity has improved, and the wear resistance that has has improved.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum is provided.
The making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum comprises the steps:
1) will smelt in technically pure iron, polysilicon, fine aluminium, cerium-iron alloy or the lanthanum iron alloy input vacuum induction furnace, be smelted into the FeSiAl alloy cast ingot that contains a small amount of rare-earth element cerium or lanthanum, the mass percentage content that its alloy cast ingot is formed is: Si 9.0~9.8%, Al 5.4~6.0%, Ce or La 0.02~0.25%, C 0.006~0.015%, O 20.008~0.010%, S 0.008~0.028%, P 0.03~0.035%, all the other are Fe.
2) alloy cast ingot is become the FeSiAl powdered alloy with Mechanical Crushing; after the protective atmosphere high-temperature heat treatment, sieve; make the mass percentage content of FeSiAl powdered alloy size composition be :-100~+ 140 orders account for 5%;-140~+ 200 orders account for 15%;-200~+ 300 orders account for 45%, and-300 orders account for 35%.
3) after above-mentioned FeSiAl powdered alloy carries out the surface passivation processing with the phosphoric acid spirituous solution, add 0.2% kaolin again, 0.2% lubricant, 0.5% releasing agent mixes; Use the dry powder automatic forming hydraulic press compression molding, pressure is 22~25T/cm 2, compacting is shaped as annular.
4) press-formed product thermal treatment under nitrogen protection, thermal treatment temp is: 640~690 ℃, at last with the soft magnet silumin magnetic core that obtains adding a small amount of rare-earth element cerium or lanthanum after the spraying of Resins, epoxy paint.
Described releasing agent is Zinic stearas or barium stearate.Described lubricant is a moly-sulfide.The present invention compared with prior art has following beneficial effect:
1) improved the specific resistance of iron silicon aluminum alloy magnetic core,, made the specific resistance of alloy can reach 82-85x10 owing to add a small amount of rare-earth element cerium or lanthanum in the alloy -6Ω m;
2) reduced the power loss of Fe-Si-Al magnetic core, the iron silicon aluminum alloy magnetic core made from this alloy is 125 ± 5 at magnetic permeability, frequency is that 50KHz, magnetic induction density are that power loss unshakable in one's determination under the 500Gs condition can be reduced to 70mw/cm 3Below;
3) improved the temperature stability of magnetic core magnetic permeability, making magnetic permeability with this alloy is 125 Fe-Si-Al magnetic core, and the temperature stability of its magnetic permeability is strong, and the fall of magnetic permeability was less than 3% when working temperature rose to 125 ℃.
Embodiment
Embodiment 1:
1) iron silicon aluminum alloy is smelted the vacuum medium frequency induction furnace of selecting nominal 100Kg for use, earlier technically pure iron is melted, successively polysilicon, fine aluminium, cerium-iron alloy are dropped in the vacuum induction furnace then and smelt, adopt induction stirring to be smelted into the FeSiAl alloy cast ingot, the mass percentage content that its FeSiAl alloy cast ingot is formed is: Si9%, and Al 6.0%, and Ce 0.02%, C 0.015%, O 20.010%, S 0.008%, and P 0.035%, and surplus is Fe.
2) alloy cast ingot is become the FeSiAl powdered alloy with Mechanical Crushing; after the protective atmosphere high-temperature heat treatment, sieve; make the mass percentage content of FeSiAl powdered alloy size composition be :-100~+ 140 orders account for 5%;-140~+ 200 orders account for 15%;-200~+ 300 orders account for 45%, and-300 orders account for 35%.
3) powder being carried out surface passivation handles, extract above-mentioned FeSiAl powdered alloy 1000g, pour with 5g phosphoric acid again that proportioning becomes the phosphoric acid spirituous solution in the 80g alcohol into, the phosphoric acid spirituous solution is poured into to stir in the FeSiAl powdered alloy of this 1000g makes its drying, and then add kaolin 2g, moly-sulfide 2g, Zinic stearas 5g mix; Use the dry powder automatic forming hydraulic press compression molding, pressure is 22T/cm 2, compacting annular size: external diameter Φ 26.90mm, internal diameter Φ 14.70mm, height 11.20mm.;
4) press-formed product is in nitrogen protection thermal treatment, and thermal treatment temp is: 670 ℃, and at last with the soft magnet silumin magnetic core that obtains adding a small amount of rare-earth element cerium after the spraying of Resins, epoxy paint.The resistance alloys coefficient reaches 82.5 * 10 -6Ω m.Sample detects and adopts coiling telefault enameled wire Φ 0.5mm, 26 circles.Its magnetic parameter such as table 1.
Table 1
Figure BSA00000189521700031
The corresponding inductance coefficent 159nH/N of inductance value 107.5 μ H 2, meet magnetic permeability 125.
Magnetic permeability varies with temperature as table 2:
Table 2
Figure BSA00000189521700032
Embodiment 2:
Making method is with embodiment 1, and alloy composition is Si 9.56%, and Al 5.4%, and Ce 0.125%, C0.012%, O 20.010%, S 0.025%, and P 0.032%, and surplus is Fe, compacting pressure 23T/cm 2, 690 ℃ of thermal treatment temps.
The resistance alloys coefficient is 83.8 * 10 -6Ω m.
The magnetic parameter such as the table 3 of embodiment 2 goods.
Compacting annular size: external diameter Φ 16.50mm, internal diameter Φ 10.15mm, height 6.35mm.Coiling telefault enameled wire Φ 0.5mm, 17 circles.
Table 3
Figure BSA00000189521700033
The corresponding inductance coefficent 74nH/N of inductance value 21.4 μ H 2Meet magnetic permeability 125.
Magnetic permeability varies with temperature rate such as table 4
Table 4
Embodiment 3:
Making method is with embodiment 1, and chemical ingredients is Si 9.80%, and Al 5.62%, and Ce 0.250%, and C 0.008%, O 20.008%, S 0.028%, and P 0.030%, and surplus is Fe, compacting pressure 25T/cm 2, 640 ℃ of thermal treatment temps
The resistance alloys coefficient is 85.2 * 10 -6Ω m.
The magnetic parameter such as the table 5 of magnetic core goods
Compacting size: external diameter Φ 33.0mm, internal diameter Φ 19.95mm, height 11.20mm.Coiling telefault enameled wire Φ 0.5mm, 33 circles.
Table 5
Figure BSA00000189521700042
The corresponding inductance coefficent 137nH/N of inductance value 149.2 μ H 2Corresponding magnetic permeability 125.
Magnetic permeability varies with temperature rate such as table 6
Table 6
Figure BSA00000189521700043
Embodiment 4:
Making method is with embodiment 1, and main chemical compositions such as table 7, remainder are Fe (being mass percent).
Table 7
Suppress annular size with embodiment 1, resistance alloys coefficient such as table 7.
The magnetic parameter such as the table 8 of magnetic core goods
Table 8
Figure BSA00000189521700052
DC Bias 20 Oe, 100KHz, all greater than 74%, on show the corresponding magnetic permeability 125 ± 5% of inductance value
Magnetic permeability varies with temperature as table 9
Table 9
Figure BSA00000189521700053

Claims (3)

1. a making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum is characterized in that comprising the steps:
1) will smelt in technically pure iron, polysilicon, fine aluminium, cerium-iron alloy or the lanthanum iron alloy input vacuum induction furnace, be smelted into the FeSiAl alloy cast ingot that contains a small amount of rare-earth element cerium or lanthanum, the mass percentage content that its alloy cast ingot is formed is: Si 9.0~9.8%, Al 5.4~6.0%, Ce or La 0.02~0.25%, C 0.006~0.015%, O 20.008~0.010%, S 0.008~0.028%, P 0.03~0.035%, all the other are Fe.
2) alloy cast ingot is become the FeSiAl powdered alloy with Mechanical Crushing; after the protective atmosphere high-temperature heat treatment, sieve; make the mass percentage content of FeSiAl powdered alloy size composition be :-100~+ 140 orders account for 5%;-140~+ 200 orders account for 15%;-200~+ 300 orders account for 45%, and-300 orders account for 35%.
3) after above-mentioned FeSiAl powdered alloy carries out the surface passivation processing with the phosphoric acid spirituous solution, add 0.2% kaolin again, 0.2% lubricant, 0.5% releasing agent mixes; Use the dry powder automatic forming hydraulic press compression molding, pressure is 22~25T/cm 2, compacting is shaped as annular.
4) press-formed product thermal treatment under nitrogen protection, thermal treatment temp is: 640~690 ℃, at last with the soft magnet silumin magnetic core that obtains adding a small amount of rare-earth element cerium or lanthanum after the spraying of Resins, epoxy paint.
2. a kind of making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum according to claim 1 is characterized in that described releasing agent is Zinic stearas or barium stearate.
3. a kind of making method of adding the soft magnet silumin magnetic core of a small amount of rare-earth element cerium or lanthanum according to claim 1 is characterized in that described lubricant is a moly-sulfide.
CN2010102090146A 2010-06-24 2010-06-24 Manufacturing method of soft magnet silicon-aluminum alloy magnetic powder core with small amounts of rare earth element cerium or lanthanum Expired - Fee Related CN101871071B (en)

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CN102019422A (en) * 2010-12-20 2011-04-20 惠州市科力磁元有限公司 Method for manufacturing soft magnet silicon-aluminum alloy magnetic powder core mu e 60
CN102268605A (en) * 2011-08-11 2011-12-07 广东省钢铁研究所 Iron silicon soft magnetic alloy and method for preparing powder thereof
CN102314986A (en) * 2011-05-19 2012-01-11 浙江科达磁电有限公司 Ferrum-silicon alloy magnetic powder core and manufacturing method thereof
CN102360661A (en) * 2011-05-19 2012-02-22 浙江科达磁电有限公司 Iron-silicon alloy soft magnetic material with permeability mu of 75 and manufacturing method thereof
CN102744403A (en) * 2012-06-19 2012-10-24 同济大学 Preparation method of nanocrystalline magnetic powder cores
CN103310936A (en) * 2013-07-05 2013-09-18 浙江大学 Low-loss Fe-based nanocrystalline soft magnetic powder core and manufacturing method thereof
CN103310937A (en) * 2013-07-05 2013-09-18 浙江大学 High-saturation magnetic induction density iron cobalt-based nanocrystal soft magnetic powder core and preparation method thereof
CN103456479A (en) * 2013-03-24 2013-12-18 广州市德珑电子器件有限公司 Method for manufacturing high-temperature-resistant metal soft magnetic powder core
CN103551565A (en) * 2013-10-30 2014-02-05 武汉欣达磁性材料有限公司 Manufacturing method for soft-magnetic Fe-Si-Al-Ni alloy powder
CN103578736A (en) * 2013-10-28 2014-02-12 任静儿 Soft-magnetic inductive iron core manufacturing method
CN104439234A (en) * 2014-12-20 2015-03-25 陈红 Preparing method for nickel-silicon-aluminum soft magnetic material doped with rare earth elements
CN104981884A (en) * 2013-01-24 2015-10-14 阿莫绿色技术有限公司 Method for manufacturing Fe-based amorphous metal powder and method for manufacturing amorphous soft magnetic cores using same
CN105014065A (en) * 2015-08-12 2015-11-04 湖州南浔闻天磁性材料有限公司 Fe-Si-Al soft magnetic powder
CN107633931A (en) * 2017-09-15 2018-01-26 安徽信息工程学院 A kind of alloy for magnetic composite and preparation method thereof
CN107644722A (en) * 2017-09-15 2018-01-30 安徽信息工程学院 A kind of alloy for permanent-magnet material and preparation method thereof
CN108172358A (en) * 2017-12-19 2018-06-15 浙江大学 A kind of low-power consumption metal soft magnetic composite material and preparation method thereof
CN112233870A (en) * 2020-10-26 2021-01-15 江苏智仁景行新材料研究院有限公司 Nanoscale Fe-Si-Al soft magnetic alloy powder and preparation method thereof
WO2023071226A1 (en) * 2021-10-26 2023-05-04 横店集团东磁股份有限公司 Rare earth ion doped soft magnetic alloy, soft magnetic composite material and preparation method therefor

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JPH0974011A (en) * 1995-09-07 1997-03-18 Tdk Corp Dust core and manufacture thereof
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CN102019422A (en) * 2010-12-20 2011-04-20 惠州市科力磁元有限公司 Method for manufacturing soft magnet silicon-aluminum alloy magnetic powder core mu e 60
CN102314986A (en) * 2011-05-19 2012-01-11 浙江科达磁电有限公司 Ferrum-silicon alloy magnetic powder core and manufacturing method thereof
CN102360661A (en) * 2011-05-19 2012-02-22 浙江科达磁电有限公司 Iron-silicon alloy soft magnetic material with permeability mu of 75 and manufacturing method thereof
CN102268605A (en) * 2011-08-11 2011-12-07 广东省钢铁研究所 Iron silicon soft magnetic alloy and method for preparing powder thereof
CN102268605B (en) * 2011-08-11 2013-10-16 广东省钢铁研究所 Method for preparing iron silicon soft magnetic alloy
CN102744403A (en) * 2012-06-19 2012-10-24 同济大学 Preparation method of nanocrystalline magnetic powder cores
CN104981884A (en) * 2013-01-24 2015-10-14 阿莫绿色技术有限公司 Method for manufacturing Fe-based amorphous metal powder and method for manufacturing amorphous soft magnetic cores using same
CN103456479A (en) * 2013-03-24 2013-12-18 广州市德珑电子器件有限公司 Method for manufacturing high-temperature-resistant metal soft magnetic powder core
CN103310937A (en) * 2013-07-05 2013-09-18 浙江大学 High-saturation magnetic induction density iron cobalt-based nanocrystal soft magnetic powder core and preparation method thereof
CN103310936A (en) * 2013-07-05 2013-09-18 浙江大学 Low-loss Fe-based nanocrystalline soft magnetic powder core and manufacturing method thereof
CN103310936B (en) * 2013-07-05 2016-01-13 浙江大学 A kind of low-loss Fe base nanometer crystal powder core and preparation method thereof
CN103310937B (en) * 2013-07-05 2016-01-13 浙江大学 A kind of high saturated magnetic induction iron cobalt-based nano-crystal soft-magnetic powder core and preparation method thereof
CN103578736A (en) * 2013-10-28 2014-02-12 任静儿 Soft-magnetic inductive iron core manufacturing method
CN103551565B (en) * 2013-10-30 2016-08-17 武汉欣达磁性材料有限公司 The manufacture method of soft magnet silicon, aluminum and nickel alloy powder
CN103551565A (en) * 2013-10-30 2014-02-05 武汉欣达磁性材料有限公司 Manufacturing method for soft-magnetic Fe-Si-Al-Ni alloy powder
CN104439234A (en) * 2014-12-20 2015-03-25 陈红 Preparing method for nickel-silicon-aluminum soft magnetic material doped with rare earth elements
CN105014065B (en) * 2015-08-12 2017-11-10 湖州南浔闻天磁性材料有限公司 A kind of iron-silicon-aluminum soft magnetic powder
CN105014065A (en) * 2015-08-12 2015-11-04 湖州南浔闻天磁性材料有限公司 Fe-Si-Al soft magnetic powder
CN107633931A (en) * 2017-09-15 2018-01-26 安徽信息工程学院 A kind of alloy for magnetic composite and preparation method thereof
CN107644722A (en) * 2017-09-15 2018-01-30 安徽信息工程学院 A kind of alloy for permanent-magnet material and preparation method thereof
CN108172358A (en) * 2017-12-19 2018-06-15 浙江大学 A kind of low-power consumption metal soft magnetic composite material and preparation method thereof
CN108172358B (en) * 2017-12-19 2019-06-04 浙江大学 A kind of low-power consumption metal soft magnetic composite material and preparation method thereof
CN112233870A (en) * 2020-10-26 2021-01-15 江苏智仁景行新材料研究院有限公司 Nanoscale Fe-Si-Al soft magnetic alloy powder and preparation method thereof
WO2023071226A1 (en) * 2021-10-26 2023-05-04 横店集团东磁股份有限公司 Rare earth ion doped soft magnetic alloy, soft magnetic composite material and preparation method therefor
EP4195225A4 (en) * 2021-10-26 2024-01-31 Hengdian Group Dmegc Magnetics Co Ltd Rare earth ion doped soft magnetic alloy, soft magnetic composite material and preparation method therefor

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