CN101851454A - Environmentally friendly high polymer composite coating material - Google Patents

Environmentally friendly high polymer composite coating material Download PDF

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Publication number
CN101851454A
CN101851454A CN 201010173392 CN201010173392A CN101851454A CN 101851454 A CN101851454 A CN 101851454A CN 201010173392 CN201010173392 CN 201010173392 CN 201010173392 A CN201010173392 A CN 201010173392A CN 101851454 A CN101851454 A CN 101851454A
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agent
coating material
environmentally friendly
polymer composite
composite coating
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CN101851454B (en
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王至润
栾宏先
栾永红
王仲华
周铁
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QINGDAO GEERMEI ENVIRONMENTAL PAINT CO Ltd
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QINGDAO GEERMEI ENVIRONMENTAL PAINT CO Ltd
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Abstract

The invention discloses an environmentally friendly high polymer composite coating material which comprises silicone-acrylate construction emulsion, elastic emulsion, a thickening agent, a flatting agent, a wetting agent, a dispersing agent, a defoaming agent, an enzyme prevention agent, a water repellent agent, an antifreeze agent, a film forming aid, titanium white powder, NTB emission powder, ceramic powder, kaolin, hollow glass microspheres and water, wherein the thickening agent is an alkali swelling thickening agent; the antifreeze agent is propylene glycol; the film forming aid is a Texanol ester alcohol film forming aid; the ceramic powder is 800-1,250 meshes; and the kaolin is 800-1,250 meshes. The environmentally friendly high polymer composite coating material has good visible light and near-infrared light reflectivity, higher thermal infrared emissivity, excellent high-temperature stability, high strength, high temperature resistance, wear resistance, high toughness, environmental protection, flame retardance, self-cleaning, heat insulation, convenient construction and cost saving.

Description

Environmentally friendly high polymer composite coating material
Technical field
The present invention relates to a kind of coated material, be specifically related to a kind of environmentally friendly high polymer composite coating material.
Background technology
Modern society's energy consumption increases day by day, has consumed the electric power resource and the coal resources of a large amount of preciousnesses.Along with people recognize the finiteness of resource and the ecocrisis that energy consumption causes gradually, energy-conservationly become environment protection and one of the important content that economizes on resources, thermal insulation technology is widely applied in each field, as various lagging materials, reflective insulation coating etc.Yet traditional heat preserving and insulating material is that the fiber-like lagging material will be given full play to the effect of transmission of heat by convection and radiative transfer in environment for use based on reduction thermal conductivity and transmissibility factor, must use thick and heavy coating; And section bar class lagging material assembling construction is loaded down with trivial details, seam influence more attractive in appearance, work-ing life is shorter.
At present, the problem that there is function singleness in the homemade thermal insulating coating on the market, effect is limited and validity period is short is difficult to widespread use; The import composite coating material is effective, purposes is wide, but price is higher, has increased production cost.
Polymeric coating material has been penetrated into the industry-by-industry department of national economy now, and it has superior physicochemical properties such as good visible light and infrared reflectivity, higher thermal infrared emittance, high-temperature stability.Therefore, a kind of energy-conserving and environment-protective, high strength are developed in design, high temperature resistant, the effective low-cost environment-friendly high polymer composite coating material of insulation thermal insulation is the technical problem that needs to be resolved hurrily.
Summary of the invention
Deficiency at the prior art existence, technical problem to be solved by this invention is, a kind of environmentally friendly high polymer composite coating material is provided, make it have good visible light, near infrared light reflectivity, higher thermal infrared emittance, superior high-temperature stability, high strength, wear-resisting, high tenacity, environmental protection, fire-retardant, self-cleaning, insulation, cost is saved in easy construction simultaneously.
For solving the problems of the technologies described above, the technical solution used in the present invention is, a kind of environmentally friendly high polymer composite coating material, and the weight part of its each component consists of: organosilicon crylic acid latex, 245-260 part; Elastic emulsion, 95-110 part; Thickening material, 3-5 part; Flow agent, 1-2 part; Wetting agent, 0.5-1.5 part; Dispersion agent, 3-5 part; Defoamer, 1-2 part; Anti-enzyme agent, 0.5-1.5 part; Hydrophobizing agent, 20-30 part; Frostproofer, 20-30 part; Film coalescence aid, 15-20 part; Titanium dioxide, 145-155 part; NTB launches powder, 8-12 part; Ceramics powder, 65-75 part; Kaolin, 45-55 part; Hollow glass micropearl, 75-85 part; Water, 220-240 part.
Above-mentioned environmentally friendly high polymer composite coating material, its thickening material are alkali swelling class thickening material.
Above-mentioned environmentally friendly high polymer composite coating material, its frostproofer are propylene glycol.
Above-mentioned environmentally friendly high polymer composite coating material, its film coalescence aid are Texanol ester alcohol film coalescence aid.
Above-mentioned environmentally friendly high polymer composite coating material, its ceramics powder granularity is the 800-1250 order; Its kaolin granularity is the 800-1250 order.
The present invention compared with prior art has following advantage and beneficial effect:
1, physicochemical property aspect is added with the emission powder in the environmentally friendly high polymer composite coating material of the present invention, the luminous reflectance of this material and heat-reflecting physicals are higher than national standard.It is good that the vacuum glass microballon of polymer emulsion and specified particle diameter compound makes this coated material have a heat insulation and preservation effect, characteristics with low cost, in addition, environmentally friendly high polymer composite coating material of the present invention is a kind of low radiative transfer coating, the thin layer of holding concurrently heat insulation and anticorrosion be one, high temperature resistant, also be improved on the wear resisting property, also has anti-flaming function, enlarged the use range of coated material, can be applicable to offshore drilling platform, oil tank, petroleum pipe line, mechanical means, grain storage warehouse, vehicle and shipping industry, armament equipment, the interior exterior wall of construction industry, steel construction roofs etc. have very wide industrialization and development prospect.
2, environmental protection and energy saving aspect, environmentally friendly high polymer composite coating material of the present invention is except the advantage with aqueous coating material, its raw material all adopts environment-friendly materials, and does not add any objectionable constituent in making processes, has realized good result of use nontoxic, clean environment firendly, simultaneously, has superior high-temperature stability, high strength, wear-resisting, high tenacity, environmental protection, fire-retardant, self-cleaning, insulation, cost is saved in easy construction.
Embodiment
Embodiment 1
A kind of environmentally friendly high polymer composite coating material of present embodiment, its weight part consists of: 245 parts of organosilicon crylic acid latexs; 95 parts of elastic emulsions; 3 parts of thickening materials; 1 part of flow agent; 0.5 part of wetting agent; 3 parts of dispersion agents; 1 part of defoamer; 0.5 part of anti-enzyme agent; 20 parts of hydrophobizing agents; 20 parts of propylene glycol; 15 parts of Texanol ester alcohol film coalescence aid; 145 parts of titanium dioxides; 8 parts in NTB emission powder; 65 parts of 800 order ceramics powders; 45 parts of 1250 order kaolin; 75 parts of hollow glass micropearls; 205 parts in water.
Above-mentioned organosilicon crylic acid latex is that sunshine is vast by 5001; Elastic emulsion is sunshine vast by 2638 (Tg=-22); Thickening material adopts the molten type of German 301 alkali; Flow agent adopts this molten type of 278 alkali that associates of hamming; Wetting agent adopts Henkel PE1000; Dispersion agent adopts the Central Asia, Taiwan 5040; Defoamer adopts the Central Asia, Taiwan NXZ; ROHM AND HAAS is adopted in anti-enzyme agent; Hollow glass micropearl adopts U.S. baud 34P30.
The method of the environmentally friendly high polymer composite coating material of preparation present embodiment may further comprise the steps:
(1) gets the raw materials ready: each component is got all the ready according to above-mentioned prescription, and water and defoamer are divided into two parts according to weight respectively;
(2) preparation of slurry: thickening material, flow agent, wetting agent, dispersion agent, anti-enzyme agent, hydrophobizing agent, frostproofer, film coalescence aid, 1/2 water and 1/2 defoamer are added disperse in the cylinder earlier, under 800 rev/mins middling speed state, stirred 15 minutes, and made uniform sizing material;
(3) adding of filler: in the slurry for preparing, add titanium dioxide, under 450 rotating speed, disperse, add remaining 1/2 water, elastic emulsion, NTB emission powder, ceramics powder, kaolin, hollow glass micropearl then, stir, add 1/2 defoamer at last, ultra-sonic dispersion, froth breaking gets final product fully.
Embodiment 2
A kind of environmentally friendly high polymer composite coating material of present embodiment consists of by weight: 260 parts of organosilicon crylic acid latexs; 110 parts of elastic emulsions; 5 parts of thickening materials; 2 parts of flow agents; 1.5 parts of wetting agents; 5 parts of dispersion agents; 2 parts of defoamers; 1.5 parts of anti-enzyme agent; 30 parts of hydrophobizing agents; 30 parts of propylene glycol; 20 parts of Texanol ester alcohol film coalescence aid; 155 parts of titanium dioxides; 12 parts in NTB emission powder; 75 parts of 1250 order ceramics powders; 55 parts of 800 order kaolin; 85 parts of hollow glass micropearls; 215 parts in water.
Above-mentioned silicon third building emulsion adopts sunshine vast by 5001; Elastic emulsion adopts sunshine vast by 2638 (Tg=-22); Thickening material adopts the molten type of German 301 alkali; Flow agent adopts this molten type of 278 alkali that associates of hamming; Wetting agent adopts Henkel PE1000; Dispersion agent adopts the Central Asia, Taiwan 5040; Defoamer adopts the Central Asia, Taiwan NXZ; ROHM AND HAAS is adopted in anti-enzyme agent; Hollow glass micropearl adopts U.S. baud 34P30.
The method of the environmentally friendly high polymer composite coating material of preparation present embodiment may further comprise the steps:
(1) gets the raw materials ready: each component is got all the ready according to above-mentioned prescription, and water and defoamer are divided into two parts according to weight respectively;
(2) preparation of slurry: thickening material, flow agent, wetting agent, dispersion agent, anti-enzyme agent, hydrophobizing agent, frostproofer, film coalescence aid, 1/2 water and 1/2 defoamer are added disperse in the cylinder earlier, under 1000 rev/mins middling speed state, stirred 10 minutes, and made uniform sizing material;
(3) adding of filler: in the slurry for preparing, add titanium dioxide, under 550 rev/mins rotating speed, disperse, add remaining 1/2 water, elastic emulsion, NTB emission powder, ceramics powder, kaolin, hollow glass micropearl then, stir, add 1/2 defoamer at last, ultra-sonic dispersion, froth breaking gets final product fully.
Embodiment 3
A kind of environmentally friendly high polymer composite coating material of present embodiment consists of by weight: 250 parts of silicon third building emulsions; 100 parts of elastic emulsions; 4 parts of thickening materials; 1.5 parts of flow agents; 1 part of wetting agent; 4 parts of dispersion agents; 1.5 parts of defoamers; 1 part of anti-enzyme agent; 25 parts of hydrophobizing agents; 25 parts of propylene glycol; 17 parts of Texanol ester alcohol film coalescence aid; 150 parts of titanium dioxides; 10 parts in NTB emission powder; 70 parts of 1000 order ceramics powders; 50 parts of 1000 order kaolin; 80 parts of hollow glass micropearls; 210 parts in water.
Above-mentioned silicon third building emulsion adopts sunshine vast by 5001; Elastic emulsion adopts sunshine vast by 2638 (Tg=-22); Thickening material adopts the molten type of German 301 alkali; Flow agent adopts this molten type of 278 alkali that associates of hamming; Wetting agent adopts Henkel PE1000; Dispersion agent adopts the Central Asia, Taiwan 5040; Defoamer adopts the Central Asia, Taiwan NXZ; ROHM AND HAAS is adopted in anti-enzyme agent; Hollow glass micropearl adopts U.S. baud 34P30.
The method of the environmentally friendly high polymer composite coating material of preparation present embodiment may further comprise the steps:
(1) gets the raw materials ready: each component is got all the ready according to above-mentioned prescription, and water and defoamer are divided into two parts according to weight respectively;
(2) preparation of slurry: thickening material, flow agent, wetting agent, dispersion agent, anti-enzyme agent, hydrophobizing agent, frostproofer, film coalescence aid, 1/2 water and 1/2 defoamer are added disperse in the cylinder earlier, under 900 rev/mins middling speed state, stirred 13 minutes, and made uniform sizing material;
(3) adding of filler: in the slurry for preparing, add titanium dioxide, under 500 rev/mins rotating speed, disperse, add remaining 1/2 water, elastic emulsion, NTB emission powder, ceramics powder, kaolin, hollow glass micropearl then, stir, add 1/2 defoamer at last, ultra-sonic dispersion, froth breaking gets final product fully.
The paint film physicochemical property of the embodiment of the invention sees the following form:
Figure GSA00000125902500041
The above only is preferred embodiment of the present invention, is not to be the restriction of the present invention being made other form, and any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the equivalent embodiment of equivalent variations.But every technical solution of the present invention content that do not break away to any simple modification, equivalent variations and remodeling that above embodiment did, still belongs to the protection domain of technical solution of the present invention according to technical spirit of the present invention.

Claims (5)

1. environmentally friendly high polymer composite coating material, the weight part of its each component consists of: organosilicon crylic acid latex, 245-260 part; Elastic emulsion, 95-110 part; Thickening material, 3-5 part; Flow agent, 1-2 part; Wetting agent, 0.5-1.5 part; Dispersion agent, 3-5 part; Defoamer, 1-2 part; Anti-enzyme agent, 0.5-1.5 part; Hydrophobizing agent, 20-30 part; Frostproofer, 20-30 part; Film coalescence aid, 15-20 part; Titanium dioxide, 145-155 part; NTB launches powder, 8-12 part; Ceramics powder, 65-75 part; Kaolin, 45-55 part; Hollow glass micropearl, 75-85 part; Water, 205-215 part.
2. environmentally friendly high polymer composite coating material according to claim 1, its thickening material are alkali swelling class thickening material.
3. environmentally friendly high polymer composite coating material according to claim 1, its frostproofer are propylene glycol.
4. environmentally friendly high polymer composite coating material according to claim 1, its film coalescence aid are Texanol ester alcohol film coalescence aid.
5. environmentally friendly high polymer composite coating material according to claim 1, its ultrafine ceramic powder granularity is the 800-1250 order; Its ultrafine kaolin granularity is the 800-1250 order.
CN2010101733923A 2010-05-14 2010-05-14 Environmentally friendly high polymer composite coating material Expired - Fee Related CN101851454B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229770A (en) * 2011-05-30 2011-11-02 青岛格尔美环保涂料有限公司 Environmentally-friendly macromolecular coating material with high self-cleaning performance and preparation method thereof
CN102304965A (en) * 2011-05-30 2012-01-04 青岛格尔美环保涂料有限公司 High self-cleaning inorganic heat insulation composite system
CN103382341A (en) * 2013-07-08 2013-11-06 吴江市物华五金制品有限公司 Heat insulation and insect prevention coating for inner walls and its preparation method
CN104031509A (en) * 2014-06-26 2014-09-10 无锡市崇安区科技创业服务中心 Exterior wall coating for old wall reconstruction and preparation method thereof
CN104312356A (en) * 2014-10-08 2015-01-28 安徽真信涂料有限公司 High-temperature-resistant anti-aging coating
CN107476520A (en) * 2017-08-07 2017-12-15 万卓(江苏)新材料有限公司 A kind of orienting reflex light porcelain tendre ornament materials and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004339038A (en) * 2003-05-19 2004-12-02 Asahi Kasei Chemicals Corp Civil engineering building material treated to prevent water absorption
CN1984969A (en) * 2004-05-28 2007-06-20 Ppg工业俄亥俄公司 Hydrophilic compositions, methods for their production, and substrates coated with such compositions.
JP4128243B2 (en) * 1996-03-14 2008-07-30 関西ペイント株式会社 Water-based paint and paint finishing method using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4128243B2 (en) * 1996-03-14 2008-07-30 関西ペイント株式会社 Water-based paint and paint finishing method using the same
JP2004339038A (en) * 2003-05-19 2004-12-02 Asahi Kasei Chemicals Corp Civil engineering building material treated to prevent water absorption
CN1984969A (en) * 2004-05-28 2007-06-20 Ppg工业俄亥俄公司 Hydrophilic compositions, methods for their production, and substrates coated with such compositions.

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229770A (en) * 2011-05-30 2011-11-02 青岛格尔美环保涂料有限公司 Environmentally-friendly macromolecular coating material with high self-cleaning performance and preparation method thereof
CN102304965A (en) * 2011-05-30 2012-01-04 青岛格尔美环保涂料有限公司 High self-cleaning inorganic heat insulation composite system
CN103382341A (en) * 2013-07-08 2013-11-06 吴江市物华五金制品有限公司 Heat insulation and insect prevention coating for inner walls and its preparation method
CN104031509A (en) * 2014-06-26 2014-09-10 无锡市崇安区科技创业服务中心 Exterior wall coating for old wall reconstruction and preparation method thereof
CN104312356A (en) * 2014-10-08 2015-01-28 安徽真信涂料有限公司 High-temperature-resistant anti-aging coating
CN107476520A (en) * 2017-08-07 2017-12-15 万卓(江苏)新材料有限公司 A kind of orienting reflex light porcelain tendre ornament materials and preparation method thereof

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Effective date of registration: 20151201

Address after: Chengyang District of Shandong city in Qingdao province 266106 Xifu street community Cianjin Wang Road North

Patentee after: QINGDAO JINMEI CULTURAL COMMUNICATION Co.,Ltd.

Address before: 266107, Shandong province Qingdao city Chengyang District Xia Zhuang Street Qin small water community

Patentee before: Qingdao Geermei Environmental Paint Co.,Ltd.

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Patentee after: QINGDAO GEERMEI ENVIRONMENTAL PAINT Co.,Ltd.

Address before: Chengyang District of Shandong city in Qingdao province 266106 Xifu street community Cianjin Wang Road North

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