CN101850642A - Method for preparing ball leather-emulated high-molecular decorative film - Google Patents
Method for preparing ball leather-emulated high-molecular decorative film Download PDFInfo
- Publication number
- CN101850642A CN101850642A CN 201010123384 CN201010123384A CN101850642A CN 101850642 A CN101850642 A CN 101850642A CN 201010123384 CN201010123384 CN 201010123384 CN 201010123384 A CN201010123384 A CN 201010123384A CN 101850642 A CN101850642 A CN 101850642A
- Authority
- CN
- China
- Prior art keywords
- plasticizing
- controlled
- refining
- cooling
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 25
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 238000003490 calendering Methods 0.000 claims abstract description 14
- 238000005187 foaming Methods 0.000 claims abstract description 14
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000006260 foam Substances 0.000 claims abstract description 13
- 230000000694 effects Effects 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 52
- 238000003756 stirring Methods 0.000 claims description 30
- 230000001815 facial effect Effects 0.000 claims description 27
- 238000007670 refining Methods 0.000 claims description 24
- -1 dioctyl ester Chemical class 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 15
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 15
- 239000004800 polyvinyl chloride Substances 0.000 claims description 15
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 238000007493 shaping process Methods 0.000 claims description 12
- 229920002521 macromolecule Polymers 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 claims description 9
- 238000001179 sorption measurement Methods 0.000 claims description 9
- 235000010215 titanium dioxide Nutrition 0.000 claims description 9
- 241000209094 Oryza Species 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 6
- 238000003851 corona treatment Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 235000009566 rice Nutrition 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004604 Blowing Agent Substances 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 231100000252 nontoxic Toxicity 0.000 claims description 3
- 230000003000 nontoxic effect Effects 0.000 claims description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 3
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 230000002708 enhancing effect Effects 0.000 abstract 3
- 238000005299 abrasion Methods 0.000 abstract 1
- 238000010030 laminating Methods 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000007812 deficiency Effects 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a method for preparing a ball leather-emulated high-molecular decorative film. The decorative film is composed of a substrate, a surface film and granular bulges which project from the substrate surface and are coated by the surface film. The method comprises the following steps of: (1) calendering the substrate; (2) preparing the surface film; (3) laminating; (4) foaming; (5) sucking foams; and (6) cooling to set. In the invention, in the aspect of inflaming retarding application, flame retardant is added into the surface film, thereby enhancing the flame-retardant effect and lowering the cost; after using the foaming and foam suction techniques, the projecting shape of the foams coated by the surface film can be mastered by people, thereby enhancing the stereoscopic impression; and the foam is protected by the surface film inside and outside the substrate, thereby enhancing the reinforcing indexes, such as wear resistance, abrasion resistance, pressure resistance and the like of the ball leather-emulated high-molecular decorative film.
Description
(1) technical field
The present invention relates to a kind of preparation method of ball leather-emulated high-molecular decorative film.The metal surface decorative materials technology.
(2) background technology
Before the present invention made, ball leather-emulated high-molecular decorative film had following deficiency in the past:
1, also there is not the surface to protrude the very strong product of the three-dimensional sight of band rounded grain shape.
2, can not be foamed into project grain shape base material film owing to also add azodicarbonamide foaming agent on the market in the rolled base material.
3, adopt the hard concave-convex surface shape that extrudes of concavo-convex dandy roll to water on the market, more stiff, and lack three-dimensional the sight.
4, also the suction of employing bubble technology on the market in the polymeric membrane manufacturing procedure.
5, former flame retardant type polymeric membrane all is to add fire retardant in base material, causes consumption many, the cost height.
(3) summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, a kind of have surface imperfection and the three-dimensional sight of rubber-like project grain shape are provided, make all preparation methods of extraordinary ball leather-emulated high-molecular decorative film of high-molecular decorative film inherent quality and appearance.
The object of the present invention is achieved like this: a kind of preparation method of ball leather-emulated high-molecular decorative film, it is characterized in that described decorating film forms by substrate, facial mask and protrusion and described substrate surface and by the rounded grain shape projection that facial mask is wrapped in, described method comprises following technical process:
Step 1, calendering substrate
A) batching
Adopt the polyvinyl chloride resin of 90 weight portions and the PP mix particles of 10 weight portions to become the macromolecule material, add dioctyl ester and Celogen Az by proportioning again, described macromolecule material and dioctyl ester and Celogen Az weight portion proportioning are:
100 parts in macromolecule material
15～25 parts of dioctyl esters
1 part of Celogen Az.
B) stir
Material by proportioning weighs up adds mixer with PVC and PP particle earlier, adds dioctyl ester after 3 minutes, adds Celogen Az after 7 minutes, stirs 5 minutes again, heats during stirring to 110 ℃～120 ℃.
C) plasticizing
The compound that fully stirs is entered banbury be heated to 170 ℃-180 ℃, rotating speed with per minute 110～120 plastifies while overturning, this process is 15 minutes, entering mill then turns refining, the temperature that turns refining adds to 175 ℃-190 ℃, two rollers evenly turned refining 5-15 minute with 35-45 rev/min of speed, made the material plasticizing.
D) refining is filtered
The material of plasticizing is delivered into extruder, and extruder is controlled temperature at 180-195 ℃, and screw speed 75-90 rev/min, push the stirring refining, push then to the filtration of die orifice screen pack, screen pack 120 orders.
E) calendering
Be extruded into the plasticizing and the grog of impurity elimination fully of strip, be conveyed into five roll calendars, roll into the base material of all size according to a thickness and a width of cloth, the calender line temperature is controlled at 180 ℃-190 ℃, rotating speed 35-40 rev/min.
F) sided corona treatment
For making substrate backside strengthen fastness with any applying thing from now on, and reach dizzy the processing by the static shock film.Electrostatic pressure 120V, speed is synchronous with calendering.
G) cooling
The base material that rolls also needs through five roller cooling cylinder rolling after cooling standby after sided corona treatment.
Step 2, preparation facial mask
A) batching
Select for use nontoxic level polyvinyl chloride resin to add dioctyl ester, titanium dioxide, fire-retardant N H1197 and mill base, the weight portion proportioning of each component is:
100 parts of polyvinyl chloride resins
20～25 parts of dioctyl esters
3～7 parts of titanium dioxides
1 part of fire-retardant N H1197
1 part of mill base
B) stir
Material by proportioning weighs up adds mixer with polyvinyl chloride resin earlier, and then adds titanium dioxide, add dioctyl ester again through stirring in 3 minutes, add fire-retardant N H1197 and mill base again, stirred through 5 minutes again through stirring in 7 minutes, warm during this time to 115 ℃～125 ℃, mixing speed 140-150 rev/min.
C) plasticizing
The material that fully stirs is added banbury be heated to 175 ℃-185 ℃, rotating speed with per minute 105-125 plastifies in upset, through adding the two roller mills plasticizing that turns refining after the preliminary plasticizing in 15 minutes again, 35-45 rev/min of two roller mill rotating speed, temperature was controlled at 180 ℃-195 ℃, made material reach plasticizing through 5-15 minute.
D) refining is filtered
The material that has plastified is delivered into extruder, and temperature is controlled at 180-195 ℃ in the extruder barrel, and 75-90 rev/min of extruder screw rotating speed pushes the stirring refining, pushes to die orifice filtration, screen pack 200 orders through screw rod then.
E) calendering
Be extruded into columned fully the plasticizing grog, be conveyed into five roll calendars, according to facial mask specification requirement calendering the into facial masks such as thickness, width, five roll calendar roller temperatures are controlled at 185 ℃-195 ℃, speed be controlled at 80-90 rice/minute.
F) cooling
Facial mask rolling behind five roller cooling cylinder cooling and shapings of moulding is standby.
Step 3, applying
With rolled base material and facial mask totally two layers through the make-up machine pressurizing attaching of heating, heating roller temperature is controlled at 160 ℃-170 ℃, 0.25 kilogram of pressure, speed be controlled at 80-90 rice/minute.
Step 4, foaming
The film that has fit together is heated to 195 ℃-205 ℃ through baking oven, makes the blowing agent in the base material produce bubble because of being subjected to high temperature to produce chemical reaction suddenly, impels in the base material to go out air bubble-shaped to evagination, and is wrapped in by facial mask.
Step 5, suction bubble
To enter foam adsorption apparatus through the film of foaming, utilize the outer suction effect of foam adsorption apparatus negative pressure, impel the requirement up to specification of foaming evagination.
Step 6, cooling and shaping
After foam adsorption apparatus absorption, reach and protrude the three-dimensional shaping membrane that requires, rolling behind jacket water (J.W.) chill roll cooling and shaping.
The invention has the beneficial effects as follows:
The present invention adopts in fire-retardant application facet and add fire retardant in facial mask, has also reduced cost and improved flame retardant effect; After employing foaming, the suction bubble technology, make the foaming under the facial mask parcel can artificially grasp its protrusion shape and improve three-dimensional sight; In addition because foaming has facial mask protection inside and outside base material, wear-resisting, the anti-wiping of ball leather-emulated high-molecular decorative film, the index of strengthening such as withstand voltage have been guaranteed.
(4) specific embodiment
The preparation method of the ball leather-emulated high-molecular decorative film that the present invention relates to, described decorating film is formed by substrate, facial mask and protrusion and described substrate surface and by the graininess projection that facial mask is wrapped in, and described method comprises following technical process:
Step 1, calendering substrate
A) batching
Adopt the polyvinyl chloride resin of 90 weight portions and the PP mix particles of 10 weight portions to become the macromolecule material, add dioctyl ester and Celogen Az by proportioning again, described macromolecule material and dioctyl ester and Celogen Az weight portion proportioning are:
100 parts in macromolecule material
15～25 parts of dioctyl esters
1 part of Celogen Az
B) stir
By the material that proportioning weighs up, the macromolecule material that PVC is become with the PP mix particles adds mixer earlier, adds dioctyl ester after 3 minutes, adds Celogen Az after 7 minutes, stirs 5 minutes again, heat during stirring to 110 ℃～120 ℃,
C) plasticizing
The compound that fully stirs is entered banbury be heated to 170 ℃-180 ℃, rotating speed with per minute 110～120 plastifies while overturning, this process is 15 minutes, entering mill then turns refining, the temperature that turns refining adds to 175 ℃-190 ℃, two rollers evenly turned refining 5-15 minute with 35-45 rev/min of speed, made the material plasticizing
D) refining is filtered
The material of plasticizing is delivered into extruder, and extruder is controlled temperature at 180-195 ℃, and screw speed 75-90 rev/min, push the stirring refining, push then to the filtration of die orifice screen pack, screen pack 120 orders,
E) calendering
Be extruded into the plasticizing and the grog of impurity elimination fully of strip, be conveyed into five roll calendars, roll into the base material of all size according to a thickness and a width of cloth, the calender line temperature is controlled at 180 ℃-190 ℃, and rotating speed 35-40 rev/min,
F) sided corona treatment
G) cooling
The base material that rolls is standby through five roller cooling cylinder rolling after cooling again after sided corona treatment;
Step 2, preparation facial mask
A) batching
Select for use nontoxic level polyvinyl chloride resin to add dioctyl ester, titanium dioxide, fire-retardant N H1197 and mill base, the weight portion proportioning of each component is:
100 parts of polyvinyl chloride resins
20～25 parts of dioctyl esters
3～7 parts of titanium dioxides
1 part of fire-retardant N H1197
1 part of mill base
B) stir
Material by proportioning weighs up adds mixer with polyvinyl chloride resin earlier, and then adds titanium dioxide, add dioctyl ester again through stirring in 3 minutes, add fire-retardant N H1197 and mill base again, stirred through 5 minutes again through stirring in 7 minutes, warm during this time to 115 ℃～125 ℃, mixing speed 140-150 rev/min
C) plasticizing
The material that fully stirs is added banbury be heated to 175 ℃-185 ℃, rotating speed with per minute 105-125 plastifies in upset, through adding the two roller mills plasticizing that turns refining after the preliminary plasticizing in 15 minutes again, 35-45 rev/min of two roller mill rotating speed, temperature is controlled at 180 ℃-195 ℃, made material reach plasticizing through 5-15 minute
D) refining is filtered
The material that has plastified is delivered into extruder, and temperature is controlled at 180-195 ℃ in the extruder barrel, and 75-90 rev/min of extruder screw rotating speed pushes the stirring refining, push to the die orifice filtration through screw rod then, and screen pack 200 orders,
E) calendering
Be extruded into columned fully the plasticizing grog, be conveyed into five roll calendars, according to facial mask specification requirement calendering the into facial masks such as thickness, width, five roll calendar roller temperatures are controlled at 185 ℃-195 ℃, speed be controlled at 80-90 rice/minute,
F) cooling
Facial mask rolling behind five roller cooling cylinder cooling and shapings of moulding is standby;
Step 3, applying
With rolled base material and facial mask totally two layers through the make-up machine pressurizing attaching of heating, heating roller temperature is controlled at 160 ℃-170 ℃, 0.25 kilogram of pressure, speed be controlled at 80-90 rice/minute;
Step 4, foaming
The film that has fit together is heated to 195 ℃-205 ℃ through baking oven, makes the blowing agent in the base material produce bubble because of being subjected to high temperature to produce chemical reaction suddenly, impels in the base material to go out air bubble-shaped to evagination, and is wrapped in by facial mask;
Step 5, suction bubble
To enter foam adsorption apparatus through the film of foaming, utilize the outer suction effect of foam adsorption apparatus negative pressure, impel the requirement up to specification of foaming evagination;
Step 6, cooling and shaping
After foam adsorption apparatus absorption, reach and protrude the three-dimensional shaping membrane that requires, rolling behind jacket water (J.W.) chill roll cooling and shaping.
Claims (1)
1. the preparation method of a ball leather-emulated high-molecular decorative film is characterized in that described decorating film forms by substrate, facial mask and protrusion and described substrate surface and by the graininess projection that facial mask is wrapped in, and described method comprises following technical process:
Step 1, calendering substrate
A) batching
Adopt the polyvinyl chloride resin of 90 weight portions and the PP mix particles of 10 weight portions to become the macromolecule material, add dioctyl ester and Celogen Az by proportioning again, described macromolecule material and dioctyl ester and Celogen Az weight portion proportioning are:
100 parts in macromolecule material
15～25 parts of dioctyl esters
1 part of Celogen Az
B) stir
By the material that proportioning weighs up, the macromolecule material that PVC is become with the PP mix particles adds mixer earlier, adds dioctyl ester after 3 minutes, adds Celogen Az after 7 minutes, stirs 5 minutes again, heat during stirring to 110 ℃～120 ℃,
C) plasticizing
The compound that fully stirs is entered banbury be heated to 170 ℃-180 ℃, rotating speed with per minute 110～120 plastifies while overturning, this process is 15 minutes, entering mill then turns refining, the temperature that turns refining adds to 175 ℃-190 ℃, two rollers evenly turned refining 5-15 minute with 35-45 rev/min of speed
Make the material plasticizing,
D) refining is filtered
The material of plasticizing is delivered into extruder, and extruder is controlled temperature at 180-195 ℃, and screw speed 75-90 rev/min, push the stirring refining, push then to the filtration of die orifice screen pack, screen pack 120 orders,
E) calendering
Be extruded into the plasticizing and the grog of impurity elimination fully of strip, be conveyed into five roll calendars, roll into the base material of all size according to a thickness and a width of cloth, the calender line temperature is controlled at 180 ℃-190 ℃, and rotating speed 35-40 rev/min,
F) sided corona treatment
G) cooling
The base material that rolls is standby through five roller cooling cylinder rolling after cooling again after sided corona treatment;
Step 2, preparation facial mask
A) batching
Select for use nontoxic level polyvinyl chloride resin to add dioctyl ester, titanium dioxide, fire-retardant N H1197 and mill base, the weight portion proportioning of each component is:
100 parts of polyvinyl chloride resins
20～25 parts of dioctyl esters
3～7 parts of titanium dioxides
1 part of fire-retardant N H1197
1 part of mill base
B) stir
Material by proportioning weighs up adds mixer with polyvinyl chloride resin earlier, and then adds titanium dioxide, add dioctyl ester again through stirring in 3 minutes, add fire-retardant N H1197 and mill base again, stirred through 5 minutes again through stirring in 7 minutes, warm during this time to 115 ℃～125 ℃, mixing speed 140-150 rev/min
C) plasticizing
The material that fully stirs is added banbury be heated to 175 ℃-185 ℃, rotating speed with per minute 105-125 plastifies in upset, through adding the two roller mills plasticizing that turns refining after the preliminary plasticizing in 15 minutes again, 35-45 rev/min of two roller mill rotating speed, temperature is controlled at 180 ℃-195 ℃, made material reach plasticizing through 5-15 minute
D) refining is filtered
The material that has plastified is delivered into extruder, and temperature is controlled at 180-195 ℃ in the extruder barrel, and 75-90 rev/min of extruder screw rotating speed pushes the stirring refining, push to the die orifice filtration through screw rod then, and screen pack 200 orders,
E) calendering
Be extruded into columned fully the plasticizing grog, be conveyed into five roll calendars, according to facial mask specification requirement calendering the into facial masks such as thickness, width, five roll calendar roller temperatures are controlled at 185 ℃-195 ℃, speed be controlled at 80-90 rice/minute,
F) cooling
Facial mask rolling behind five roller cooling cylinder cooling and shapings of moulding is standby;
Step 3, applying
With rolled base material and facial mask totally two layers through the make-up machine pressurizing attaching of heating, heating roller temperature is controlled at 160 ℃-170 ℃, 0.25 kilogram of pressure, speed be controlled at 80-90 rice/minute;
Step 4, foaming
The film that has fit together is heated to 195 ℃-205 ℃ through baking oven, makes the blowing agent in the base material produce bubble because of being subjected to high temperature to produce chemical reaction suddenly, impels in the base material to go out air bubble-shaped to evagination, and is wrapped in by facial mask;
Step 5, suction bubble
To enter foam adsorption apparatus through the film of foaming, utilize the outer suction effect of foam adsorption apparatus negative pressure, impel the requirement up to specification of foaming evagination;
Step 6, cooling and shaping
After foam adsorption apparatus absorption, reach and protrude the three-dimensional shaping membrane that requires, rolling behind jacket water (J.W.) chill roll cooling and shaping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101233848A CN101850642B (en) | 2010-03-08 | 2010-03-08 | Method for preparing ball leather-emulated high-molecular decorative film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101233848A CN101850642B (en) | 2010-03-08 | 2010-03-08 | Method for preparing ball leather-emulated high-molecular decorative film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101850642A true CN101850642A (en) | 2010-10-06 |
| CN101850642B CN101850642B (en) | 2012-06-27 |
Family
ID=42802399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101233848A Active CN101850642B (en) | 2010-03-08 | 2010-03-08 | Method for preparing ball leather-emulated high-molecular decorative film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101850642B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532752A (en) * | 2011-12-27 | 2012-07-04 | 浙江博泰塑胶有限公司 | High brightness flame retardant decorative film |
| CN105778341A (en) * | 2016-04-05 | 2016-07-20 | 江阴华东装饰材料有限公司 | Wall-like brick high-molecular hard wall decorative material and preparation method thereof |
| CN107415271A (en) * | 2017-06-19 | 2017-12-01 | 江苏大海塑料股份有限公司 | A kind of production technology of anti-flammability PVC plastic Wallpaper film |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201334614Y (en) * | 2008-12-02 | 2009-10-28 | 厦门朝富人造革有限公司 | Artificial leather |
-
2010
- 2010-03-08 CN CN2010101233848A patent/CN101850642B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201334614Y (en) * | 2008-12-02 | 2009-10-28 | 厦门朝富人造革有限公司 | Artificial leather |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532752A (en) * | 2011-12-27 | 2012-07-04 | 浙江博泰塑胶有限公司 | High brightness flame retardant decorative film |
| CN105778341A (en) * | 2016-04-05 | 2016-07-20 | 江阴华东装饰材料有限公司 | Wall-like brick high-molecular hard wall decorative material and preparation method thereof |
| CN107415271A (en) * | 2017-06-19 | 2017-12-01 | 江苏大海塑料股份有限公司 | A kind of production technology of anti-flammability PVC plastic Wallpaper film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101850642B (en) | 2012-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104611942B (en) | Thermoplastic polyurethane (TPU) physical foaming synthetic leather as well as production technology and application thereof | |
| CA2031780C (en) | Method and product for extruding plastic with accent color pattern | |
| CN107627687A (en) | A kind of PVC stone plastic floors and its manufacture method | |
| CN103738035B (en) | Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof | |
| CN106499153A (en) | Stone modeling lightweight VCP floor and preparation method thereof | |
| CN107877892A (en) | The preparation method of imitative engraving UV scratch resistance graining films | |
| CN104149448A (en) | PVC laminated composite cloth comprising films formed through extrusion method and preparation method thereof | |
| CN101850689B (en) | Method for preparing clinquant high molecular decorative film | |
| CN101850642B (en) | Method for preparing ball leather-emulated high-molecular decorative film | |
| CN107186996A (en) | A kind of preparation method of flame retardant type PVC wallpaper | |
| CN102634269A (en) | Wood grain powder coating for aluminum profile and preparation method of wood grain powder coating | |
| CN108485105A (en) | A kind of factory formula and preparation method thereof of PVC floor print film | |
| CN106113519A (en) | A kind of without the process of preparing of light PVC film in shadow | |
| CN104309253A (en) | Super wide fold-resistant projection curtain and production technology thereof | |
| CN106639248A (en) | Light VCP floor and preparation method thereof | |
| CN201721234U (en) | Ball-leather imitating decorative film | |
| CN106894241B (en) | A kind of clean preparation method of WPU/TPU composite synthesis leather | |
| CN102189884A (en) | Imitation ball leather decorative film | |
| CN201665123U (en) | Ball leather-imitated macromolecule decorative film | |
| CN102729480A (en) | Method for producing low-foaming PVC (polyvinyl chloride) crust board | |
| CN104448507B (en) | Method for using polypropylene fiber for enhancing highly-filled environment-friendly paper | |
| US10569519B2 (en) | Low cost surface covering tiles and the process for their manufacture | |
| CN102189886A (en) | Ball leather-simulated polymer decorative film | |
| CN102191840A (en) | Method for preparing silver foil-like high polymer decorating film | |
| CN103818091A (en) | Method for preparing polymer decoration film through blending imitated silver foil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Yan Inventor after: Li Xianghua Inventor after: Xu Wenya Inventor after: Fei Chunyan Inventor after: Xu Wei Inventor after: Xia Jingxia Inventor before: Zhu Guanghe Inventor before: Xu Wenya Inventor before: Li Xianghua Inventor before: Wang Yan Inventor before: Chen Qiongna Inventor before: Fei Chunya Inventor before: Xu Wei Inventor before: Xia Jingxia |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHU GUANGHE XU WENYA LI XIANGHUA WANG YAN CHEN QIONGNA FEI CHUNYA XU WEI XIA JINGXIA TO: WANG YAN LI XIANGHUA XU WENYA FEI CHUNYAN XU WEI XIA JINGXIA |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGYIN HUADONG DECORATIVE MATERIAL CO., LTD. Free format text: FORMER OWNER: XU WENYA Effective date: 20140725 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20140725 Address after: 214421 Jiangsu city of Wuxi province Jiangyin Huashi Town Industrial Park Patentee after: Jiangyin Huadong Decorative Material Co., Ltd. Address before: Hua Zhen Tian 214421 Jiangsu city of Jiangyin province by industrial park of Zhen Road No. 9 Patentee before: Xu Wenya |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20181218 Address after: 214421 No. 58 Haida Road, Huashizhen, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Jiangsu Econess Energy Co.,Ltd. Address before: 214421 Huashi Town Industrial Park, Jiangyin City, Wuxi City, Jiangsu Province Patentee before: Jiangyin Huadong Decorative Material Co., Ltd. |
|
| TR01 | Transfer of patent right |