CN108485105A - A kind of factory formula and preparation method thereof of PVC floor print film - Google Patents
A kind of factory formula and preparation method thereof of PVC floor print film Download PDFInfo
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- CN108485105A CN108485105A CN201810218570.6A CN201810218570A CN108485105A CN 108485105 A CN108485105 A CN 108485105A CN 201810218570 A CN201810218570 A CN 201810218570A CN 108485105 A CN108485105 A CN 108485105A
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- pvc floor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention relates to a kind of PVC floor print film and its factory formula and preparation methods.The factory formula of PVC floor print film is the raw material that following weight ratio is put into every 100 parts of polyvinyl chloride resin：35 parts of plasticizer, 24 parts of stabilizers, 0 10 parts of fillers, 0.3 0.8 parts of UV absorbers, 0.3 0.5 parts of antioxidant, 24 parts of processing aids, 36 parts of fire retardants, 4 10 parts of impact modifiers, lubrication prescription, 0.5 1.0 especially lubrication prescription, 8 15 parts of titanium dioxides, 0.05 0.5 parts of colorants in 0.5 1.0 parts.Preparation includes the following steps：Dispensing, the plasticizing of planet machine, the plasticizing of A open mills, filtering, B open mills heat preservation feeding, calendering formation, embossing, cooling, trimming, is batched, is packed at mixing.
Description
Technical field
The present invention relates to jet drawing material field more particularly to a kind of factory formulas and preparation method thereof of PVC floor print film.
Background technology
With the development of society, consumers in general are higher and higher to the quality of home life.In order to build one comfortable, environmental protection,
Beautiful indoor environment.Various new indoor ornament materials come into being.PVC floor is as a kind of novel ground decoration material
Material, has the characteristics that very more, and the scope of application is also very extensive.Generally used in external decorative engineering.Such as Fig. 1 institutes
It states, NEW TYPE OF COMPOSITE PVC floor is formed by 5 layers of structure composite, and first layer is ultraviolet curable coating, it is therefore intended that improve PVC
The glossiness and scraping and wiping resistance performance of composite floor board, the second layer are PVC wearing layers, the wearability of the main composite floor board for improving PVC
And service life；Third layer is that printing layer assigns the different color in floor, decorative pattern, meet different consumers and different productions need
It asks；The 4th layer of product and actual processing for PVC binder layers generally according to different size needs, and formulates thickness.5th layer is on-slip
Layer, it is therefore intended that the friction factor for increasing floor bottoms and construction ground prevents from relatively moving.
Since PVC floor is ground for a long time by the various disruptive environmentals such as weight, friction.As the printing layer on floor, it is closed
It is to the most direct appearance in floor.How development and production it is a kind of pressure resistance, environmental protection, fire-retardant print film, be required for each producer
It solves the problems, such as.
Invention content
In view of the deficiencies of the prior art, the present invention is intended to provide a kind of factory formula and preparation method thereof of PVC floor print film,
The pressure resistance, environmental protection, flame retardant property on floor can be effectively improved.
To achieve the above object, the present invention adopts the following technical scheme that：The factory formula of above-mentioned PVC floor print film, every 100 parts
The raw material that following weight ratio is put into polyvinyl chloride resin is made：3-5 parts of plasticizer, 2-4 parts of stabilizers, 0-10 parts of fillers, 0.3-
0.8 part of UV absorbers, 0.3-0.5 parts of antioxidant, 2-4 parts of processing aids, 3-6 parts of fire retardants, 4-10 parts of impact modifiers,
Lubrication prescription, 0.5-1.0 especially lubrication prescription, 8-15 part titanium dioxide, 0.05-0.5 parts of colorants in 0.5-1.0 parts.
Polyvinyl chloride resin is the ethylene process polyvinyl chloride resin of degree of polymerization 700-1000；The plasticizer is trioctyl trimellitate (TOTM)
(TOTM)；The stabilizer is thiol methyl tin；The filler is nano activated calcium carbonate；The ultra-violet absorber is
UV-P；The antioxidant is 1010；The processing aid is ACR type PVC processing aids；The fire retardant is antimony oxide；
The impact modifier is methyl methacrylate, butadiene, styrene copolymer (MBS) the interior lubrication prescription are G16；Institute
It is G70S to state outer lubrication prescription；The titanium dioxide is rutile titanium white powder；The colorant is ultramarine class colorant.
The preparation method of the PVC floor print film of the present invention, includes the following steps：Dispensing, mixing, the plasticizing of planet machine, A open mills
Plasticizing, B open mills heat preservation feeding, calendering formation, embossing, cooling, trimming, is batched, is packed at filtering.
1. dispensing：In parts by weight；
2. mixing：The formula prepared is put into homogenizer and is mixed, mixing time 200S-300S, stirring temperature
Degree is 100 DEG C -120 DEG C；It is 60 DEG C -80 DEG C that the cold blender cooling temperature of low speed is put into after mixed at high speed；
3. the plasticizing of planet machine is closed plasticizing, the control of plasticization temperature driving screw at 150 DEG C -170 DEG C, M1 controls 155 DEG C -
175℃；
4.A open mills are plasticized：The plasticizing of A open mills is open plasticizing, and control open mill temperature is 150 DEG C -170 DEG C；
5. filtering：Material filtering is carried out after the plasticizing of A open mills, filter screen mesh number is arranged in -150 mesh of 120 mesh, filter temperature
Degree is arranged at 140 DEG C -180 DEG C；
6.B open mills keep the temperature feeding：B open mill temperature is controlled at 130 DEG C -150 DEG C
7. calendering formation：5 roll-ins are carried out through B open mill feedings to prolong, rolling temperature is arranged at 165 DEG C -195 DEG C；
8. embossing：Processing is embossed after calendering formation, light film, the mute film required for different product selects different knurling rolls
It is embossed processing.
9. carrying out cooling to film after being embossed processing, trimming, batching, pack.
PVC floor print film of the present invention can significantly improve the pressure resistance, environmental protection, flame retardant property on floor.Also there is anti-ultraviolet work
With.
Description of the drawings
Fig. 1 is composite PVC floor panel structure figure.
Fig. 2 is flow chart prepared by the present invention.
Specific implementation mode
Embodiment 1：A kind of factory formula of PVC floor print film, in parts by weight：
Embodiment 2：Another factory formula of PVC floor print film, in parts by weight：
As shown in Figure 2：
The production method of the floor printing film of embodiment 1：
It is put into homogenizer and stirs in parts by weight by the raw material of the formula of embodiment 1, mixing time 220S controls temperature
115℃；Stirring in the cold blender of low speed is subsequently placed into then to put into planet machine to temperature 60 C and carry out closed plasticizing, main spiral shell
At 160 DEG C, M1 temperature is controlled at 170 DEG C the control of bar temperature；And then material moves to double roller bundle turbine A and is further plasticized, and controls
Temperature processed is at 160 DEG C, and using filter impurity screening, filtering mesh number is 120 mesh, 170 DEG C of filter temperature.Material after filtering
It is put into double roller to prick turbine B heat preservation storings and calendering host feeding, temperature is given to control at 155 DEG C, material prolongs host into five roll-ins
Calendering formation controls 185 DEG C of temperature, is then embossed after processing and carries out cooling to film, trimming, batches, packs, is made into
Product.
The production method of the PVC floor print film of embodiment 2：
The raw material of the formula of embodiment 2 is put into homogenizer in parts by weight and is stirred, mixing time 280S controls temperature
120℃；Stirring in the cold blender of low speed is subsequently placed into then to put into planet machine to temperature 70 C and carry out closed plasticizing, main spiral shell
At 170 DEG C, M1 temperature is controlled at 175 DEG C the control of bar temperature；And then material moves to double roller bundle turbine A and is further plasticized, and controls
Temperature processed is at 165 DEG C, and using filter impurity screening, filtering mesh number is 150 mesh, 175 DEG C of filter temperature.Material after filtering
It is put into double roller to prick turbine B heat preservation storings and calendering host feeding, temperature is given to control at 160 DEG C, material prolongs host into five roll-ins
Calendering formation controls 191 DEG C of temperature, is then embossed after processing and carries out cooling to film, trimming, batches, packs.It is made into
Product.
Claims (10)
1. a kind of factory formula of PVC floor print film, it is characterised in that：Following weight ratio is put into every 100 parts of polyvinyl chloride resin
Raw material is made：3-5 parts of plasticizer, 2-4 parts of stabilizers, 0-10 parts of fillers, 0.3-0.8 parts of UV absorbers, 0.3-0.5 parts
Antioxidant, 2-4 part processing aid, 3-6 parts of fire retardants, 4-10 parts of impact modifiers, lubrication prescription, 0.5-1.0 be especially in 0.5-1.0 parts
Lubrication prescription, 8-15 part titanium dioxide, 0.05-0.5 parts of colorants.
2. a kind of factory formula of PVC floor print film according to claim 1, it is characterised in that the polyvinyl chloride resin is
The ethylene process polyvinyl chloride resin of degree of polymerization 700-1000；The plasticizer is trioctyl trimellitate (TOTM) (TOTM)；The stabilizer is
Thiol methyl tin；The filler is nano activated calcium carbonate；The ultra-violet absorber is UV-P；The antioxidant is
1010；The processing aid is ACR type PVC processing aids；The fire retardant is antimony oxide；The impact modifier is first
Base methyl acrylate, butadiene, styrene copolymer (MBS) the interior lubrication prescription are G16；The outer lubrication prescription is G70S；Institute
It is rutile titanium white powder to state titanium dioxide；The colorant is ultramarine class colorant.
3. a kind of preparation method of PVC floor print film, it is characterised in that including dispensing, mixing, the plasticizing of planet machine, A open mills
Plasticizing, filtering, B open mills heat preservation feeding, calendering formation, embossing, cooling, the step of trimming, batching, packing, wherein dispensing is
Factory formula according to claim 1 or 2 carries out dispensing.
4. a kind of preparation method of PVC floor print film according to claim 3, it is characterised in that the mixing be by
The formula prepared, which is put into homogenizer, to be mixed, mixing time 200S-300S, and whipping temp is 100 DEG C -120
℃；It is 60 DEG C -80 DEG C that the cold blender cooling temperature of low speed is put into after mixed at high speed.
5. a kind of preparation method of PVC floor print film according to claim 4, it is characterised in that the planet machine modeling
Closed plasticizing is turned to, at 150 DEG C -170 DEG C, M1 is controlled at 155 DEG C -175 DEG C the control of plasticization temperature driving screw.
6. a kind of preparation method of PVC floor print film according to claim 5, it is characterised in that the A open mills
Plasticizing is open plasticizing, and control open mill temperature is 150 DEG C -170 DEG C.
7. a kind of preparation method of PVC floor print film according to claim 6, it is characterised in that the filtering：Through
Material filtering is carried out after crossing the plasticizing of A open mills, filter screen mesh number is arranged in -150 mesh of 120 mesh, and filter temperature setting is 140
℃-180℃。
8. a kind of preparation method of PVC floor print film according to claim 7, it is characterised in that the B open mills
Temperature is controlled at 130 DEG C -150 DEG C.
9. a kind of preparation method of PVC floor print film according to claim 8, it is characterised in that described is rolled into
Type：5 roll-ins are carried out through B open mill feedings to prolong, rolling temperature is arranged at 165 DEG C -195 DEG C.
10. a kind of preparation method of PVC floor print film according to claim 9, it is characterised in that the embossing：Pressure
It is embossed processing after prolonging molding, light film, the mute film required for different product selects different knurling rolls to be embossed processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810218570.6A CN108485105A (en) | 2018-03-16 | 2018-03-16 | A kind of factory formula and preparation method thereof of PVC floor print film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810218570.6A CN108485105A (en) | 2018-03-16 | 2018-03-16 | A kind of factory formula and preparation method thereof of PVC floor print film |
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| Publication Number | Publication Date |
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| CN108485105A true CN108485105A (en) | 2018-09-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810218570.6A Pending CN108485105A (en) | 2018-03-16 | 2018-03-16 | A kind of factory formula and preparation method thereof of PVC floor print film |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110041642A (en) * | 2019-05-05 | 2019-07-23 | 江苏大海塑料股份有限公司 | A kind of PVC film and preparation method thereof of sports health ice bag |
| CN111393766A (en) * | 2020-04-27 | 2020-07-10 | 山东沃尔新材料有限公司 | Production formula and preparation method of middle-layer PVC printing film for SPC floor |
| CN113292803A (en) * | 2021-06-30 | 2021-08-24 | 浙江铭隆装饰设计工程有限公司 | Decorative material and preparation method thereof |
| CN114133679A (en) * | 2021-11-25 | 2022-03-04 | 广东天进新材料有限公司 | PVC film with high glossiness and preparation method thereof |
| CN115521590A (en) * | 2022-10-26 | 2022-12-27 | 浙江鲨威新材料科技有限公司 | Color matching production process of vehicle body film |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110041642A (en) * | 2019-05-05 | 2019-07-23 | 江苏大海塑料股份有限公司 | A kind of PVC film and preparation method thereof of sports health ice bag |
| CN111393766A (en) * | 2020-04-27 | 2020-07-10 | 山东沃尔新材料有限公司 | Production formula and preparation method of middle-layer PVC printing film for SPC floor |
| CN113292803A (en) * | 2021-06-30 | 2021-08-24 | 浙江铭隆装饰设计工程有限公司 | Decorative material and preparation method thereof |
| CN114133679A (en) * | 2021-11-25 | 2022-03-04 | 广东天进新材料有限公司 | PVC film with high glossiness and preparation method thereof |
| CN115521590A (en) * | 2022-10-26 | 2022-12-27 | 浙江鲨威新材料科技有限公司 | Color matching production process of vehicle body film |
| CN115521590B (en) * | 2022-10-26 | 2023-11-24 | 浙江鲨威新材料科技有限公司 | Color mixing production process of car body film |
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Application publication date: 20180904 |
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