CN101837522B - Vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire - Google Patents

Vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire Download PDF

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Publication number
CN101837522B
CN101837522B CN 201010197412 CN201010197412A CN101837522B CN 101837522 B CN101837522 B CN 101837522B CN 201010197412 CN201010197412 CN 201010197412 CN 201010197412 A CN201010197412 A CN 201010197412A CN 101837522 B CN101837522 B CN 101837522B
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China
Prior art keywords
vanadium
welding wire
cored
flux
powder
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Expired - Fee Related
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CN 201010197412
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CN101837522A (en
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杨可
包晔峰
蒋永锋
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Changzhou Campus of Hohai University
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Changzhou Campus of Hohai University
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Abstract

The invention discloses a vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire which comprises a low carbon steel hollow welding wire and a powder flux core arranged in the hollow welding wire, and is mainly characterized in that the powder flux core comprises the following components in percentage (%) by weight: 30-55 percent of high carbon ferro chrome, 8-20 percent of ferro vanadium, 3-8 percent of deoxidizing agent and 25-55 percent of ferrous powder. By using a surfacing welding layer of the invention, the vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire has the characteristics of uniform rigidity distribution, high wearing resistance and the like, and has good welding process performance.

Description

Vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire
Technical field
The present invention relates to a kind of vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire, belong to technical field of welding materials.
Background technology
Flux-cored wire is that alloying element (powder medicine core) is wrapped in sheetmetal the flux-cored wire that forms through being drawn into different-diameter.
Flux-cored wire forms the alloy solder layer with the property such as wear-resistant, corrosion-resistant and high temperature resistant after welding fusing.Flux-cored wire submerged-arc welding occupies an important position in reparation and composite manufacturing, is widely used in the compound position of the mechanical structured members such as high wear resistance of mechanical engineering structure.
The wear-resisting welding wire with flux core that built-up welding is at present repaired generally all contains the alloying elements such as carbon, chromium, silicon, manganese, seldom or hardly contains carbide.
It is generally acknowledged, reinforcing material surface strength and the effective way of improving wearability are to provide case hardness and the obdurability of material, and comparatively desirable layer institutional framework is the particle of equally distributed high-melting-point on tough and tensile, continuous matrix, high rigidity, good stability.The wearability of built-up welding layer is mainly decided by kind, distribution and the Area Ratio of carbide.Contained chromium in wear-resisting powder medicine core forms double carbide (Cr, Fe) with carbon and iron in weld deposit process 7C 3The hexagonal prism structure, its case hardness is HV1200~1800, the hardness ratio front surface of side is slightly low.This shows, the existing flux-cored wire of repairing for built-up welding far can not satisfy the roll of steel plant, the demand that the composite manufacturing of the coal-grinding roller of firepower electrical plant and engineering excavation machinery etc. and maintenance are reproduced etc.
Summary of the invention
The present invention is intended in powder medicine core, by adding v element, and vanadium in the built-up welding molten pool metal with the preferential combination of carbon, form the core of the non-spontaneous nucleation of vanadium carbide, and remarkable crystal grain thinning, and because vanadium carbide can separately exist in hardfacing alloy, play the effect of wear-resisting particle, wearability is further improved, and a kind of vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire is provided.
The present invention realizes that the technical scheme of its purpose is:
A kind of vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire comprises the mild steel cored solder wire and is located at the interior powder medicine core of described cored solder wire; The component of described powder medicine core is: high carbon ferro-chrome, vanadium iron, deoxidier and iron powder; The filling rate of described powder medicine core in described cored solder wire is characterized in that in 30~50% scopes:
The weight percentage of described each component of powder medicine core is (%):
High carbon ferro-chrome 30~55;
Vanadium iron 8~20;
Iron powder 25~55;
In 2 kinds of metallic elements of deoxidier silicon and manganese a kind or 2 kind 3~8.
The Main Function of each component is in above-mentioned drug core component:
High carbon ferro-chrome: its composition is 62.0~72.0%Cr ,≤6.0%C, and remaining is Fe.By its transition alloy elements in the hardfacing alloy.
Vanadium iron: its composition is 35.0~50.0%V, and remaining is Fe.Preferentially be combined with carbon in the built-up welding layer by it and form vanadium carbide hard, wear-resistant phase.
Deoxidier: be ferrosilicon or ferromanganese or ferrosilicon and ferromanganese.The ferrosilicon composition is 40.0~47.0%Si, and remaining is Fe; The ferromanganese composition is 75.0~85.0%Mn, and remaining is Fe.By the deoxidation of described deoxidier, increase intensity and the hardness of overlay cladding.
Iron powder: replenish alloying element to hardfacing alloy.
The filling rate of above-mentioned powder medicine core in cored solder wire can according to actual operation requirements and operating mode, be adjusted between 30%~50%.
Describe and to understand by above given technical scheme and the effect of each component of powder medicine core, the present invention is owing to adopting this carbide of vanadium, in built-up welding high temperature molten bath carbon preferential with vanadium reaction generation VC hard phase, and can even dispersion be distributed in hardfacing alloy, thereby when crystal grain thinning improves obdurability, improve the hardness of overlay cladding, strengthened anti-wear performance, realized purpose of the present invention.
In technique scheme, the present invention advocates that described mild steel cored solder wire is the H08A steelwork, or the H10 steelwork.But be not limited to this.Result of the test shows phosphorus content at the mild steel product below 0.2%, all can be used for preparing cored solder wire of the present invention.
In technique scheme, described deoxidier is a kind or 2 kinds in silicon and 2 kinds of metallic elements of manganese.Silicon and manganese are all that wherein the deoxidizing capacity of silicon is higher than manganese than the strong deoxidier lower than aluminium.If adopt the silicomanganese combined deoxidation, its deoxidation effect is more desirable.For this reason, the present invention is recommended.Here should be noted that SiO 2The deslagging situation of-MnO product in hardfacing alloy.
After technique scheme is implemented, its result on trial shows: flux-cored wire welding technological properties of the present invention is good, the overlay cladding case hardness is evenly distributed, average hardness is in HRC42~65 scopes, wearability is 10-30 times of Q235 carbon steel, and have the strong and alloying uniformity coefficient advantages of higher of anti-pore ability, realized original intention of the present invention.
Description of drawings
Fig. 1 is preparation technology's flow chart of a kind of specific embodiment of the present invention.
The specific embodiment
Below contrast accompanying drawing, by the description of the specific embodiment, invention that the invention will be further described.
One of specific embodiment, as shown in Figure 1.
A kind of vanadium is strengthened submerged-arc overlaying welding flux-cored wire, comprises H08A mild steel cored solder wire and is located at the interior powder medicine core of described cored solder wire, and the proportioning of described powder medicine core is: described high carbon ferro-chrome 37%, described vanadium iron 9%, the described ferrosilicon 7% of deoxidier, iron powder 47%.Filling rate 35%.Flux-cored wire overlay cladding average hardness HRC52.
Two of the specific embodiment, as shown in Figure 1.
A kind of vanadium is strengthened submerged-arc overlaying welding flux-cored wire, comprises H10 mild steel cored solder wire and is located at the interior powder medicine core of described cored solder wire, and the proportioning of described powder medicine core is: described high carbon ferro-chrome 44%, described vanadium iron 12%, the described ferromanganese 8% of deoxidier, iron powder 34%.Filling rate 43%.Flux-cored wire overlay cladding average hardness HRC60.
Can be understood by above-mentioned two examples, effect of the present invention is very good.

Claims (2)

1. a vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire, comprise the mild steel cored solder wire and be located at the interior powder medicine core of described cored solder wire; The component of described powder medicine core is: high carbon ferro-chrome, vanadium iron, deoxidier and iron powder; The filling rate of described powder medicine core in described cored solder wire is characterized in that in 30~50% scopes:
The weight percentage of described each component of powder medicine core is (%):
High carbon ferro-chrome 30~55;
Vanadium iron 8~20;
Iron powder 25~55;
Deoxidier, in 2 kinds of metallic elements of silicon and manganese a kind or 2 kind 3~8.
2. vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire according to claim 1, is characterized in that, described mild steel weldinmg rod is the H08A steelwork, or the H10 steelwork.
CN 201010197412 2010-06-11 2010-06-11 Vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire Expired - Fee Related CN101837522B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104708234A (en) * 2013-12-11 2015-06-17 北京有色金属研究总院 Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102079021B (en) * 2011-01-26 2013-08-14 江西恒大高新技术股份有限公司 Tubular welding wire for anti-cavitation overlaying of rotating wheel of hydraulic turbine
CN106141484B (en) * 2016-07-28 2018-07-06 江苏科技大学 A kind of very high content vanadium is modified self-protecting flux-cored wire for overlaying welding and preparation method thereof
CN106271225B (en) * 2016-08-30 2018-11-02 四川大西洋焊接材料股份有限公司 Hardfacing electrode and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1413793A (en) * 2002-10-09 2003-04-30 天津大学 Repairing cold-rolled intermediat roll working lining build-up welding agent core welding stick
CN1714987A (en) * 2005-07-06 2006-01-04 湘潭大学 High chromium rust free, wear resistance cored welding wire
CN101181766A (en) * 2007-12-17 2008-05-21 徐龙江 High-wearing high performance-cost ratio flux-cored wire
CN101224527A (en) * 2008-02-04 2008-07-23 湘潭大学 High hardness ferritic stainless steel wearable surfacing flux-cored wire

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60162594A (en) * 1984-02-02 1985-08-24 Fuji Kogyosho:Kk High-hardness submerged arc welding material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1413793A (en) * 2002-10-09 2003-04-30 天津大学 Repairing cold-rolled intermediat roll working lining build-up welding agent core welding stick
CN1714987A (en) * 2005-07-06 2006-01-04 湘潭大学 High chromium rust free, wear resistance cored welding wire
CN101181766A (en) * 2007-12-17 2008-05-21 徐龙江 High-wearing high performance-cost ratio flux-cored wire
CN101224527A (en) * 2008-02-04 2008-07-23 湘潭大学 High hardness ferritic stainless steel wearable surfacing flux-cored wire

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP昭60-162594A 1985.08.24

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104708234A (en) * 2013-12-11 2015-06-17 北京有色金属研究总院 Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire
CN104708234B (en) * 2013-12-11 2017-02-08 北京有色金属研究总院 Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire

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