CN104708234B - Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire - Google Patents

Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire Download PDF

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CN104708234B
CN104708234B CN201310676726.2A CN201310676726A CN104708234B CN 104708234 B CN104708234 B CN 104708234B CN 201310676726 A CN201310676726 A CN 201310676726A CN 104708234 B CN104708234 B CN 104708234B
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iron
flux
powder
cored wire
percent
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CN104708234A (en
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孙昊
付东兴
张彬
杨中元
汪礼敏
张景怀
王磊
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Youyan Powder New Materials Co ltd
Beijing General Research Institute for Non Ferrous Metals
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GRIPM ADVANCED MATERIALS (BEIJING) CO Ltd
Beijing General Research Institute for Non Ferrous Metals
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding
    • B23K35/406Filled tubular wire or rods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting

Abstract

The invention belongs to the field of material machining and welding, and particularly relates to an iron-based self-protection flux-cored wire, a surfacing alloy manufactured with the iron-based self-protection flux-cored wire and a method for manufacturing the iron-based self-protection flux-cored wire. Flux-cored powder is wrapped by a carbon steel strip, and the mass percent of the flux-cored powder in the flux-cored wire ranges from 46 percent to 50 percent. The flux-cored powder comprises, by mass, 50 percent to 64 percent of high carbon ferro chrome, 5.5 percent to 11 percent of ferroboron, 1 percent to 6 percent of ferromolybdenum, 1 percent to 3 percent of electrolytic manganese powder, 3 percent to 8 percent of ferrosilicon, 2 percent to 7 percent of graphite, and the balanced reduced iron powder. According to setting of welding process parameters, the voltage ranges from 30 V to 35 V, the current ranges from 320 V to 380 V, the feeding speed ranges from 430 mm/min to 500 mm/min, and the length of the part, stretching out of a contact tube, of the flux-cored wire ranges from 15 mm to 30 mm. The number of chromium elements in the iron-based self-protection flux-cored wire is lower than that of chromium elements in a traditional grinding roller surfacing welding wire, so that the iron-based self-protection flux-cored wire is an environmentally-friendly welding material; and meanwhile the iron-based self-protection flux-cored wire has the high hardness and high wear resistance, and is good in surfacing welding manufacturability and attractive in formation of weld.

Description

A kind of iron-based self-protection flux-cored wire and its prepared hardfacing alloy and method
Technical field
The invention belongs to materials processing field of welding material, particularly to a kind of iron-based self-protection flux-cored wire and its made Standby hardfacing alloy and method.
Background technology
The mill roll sleeve of coal pulverizer and mill lining tile are one of power plant's workpiece easy to wear, with the demand of modern power consumption Increase, power plant load is increasing, the manufacture of these workpiece easy to wear and reparation problem are more and more prominent.Typically there are two kinds at present Manufacture method, a kind of is entirety or piecemeal another kind by the way of rich chromium cast iron casting is to be carried out by the way of cast steel built-up welding Produce.The workpiece of casting and built-up welding can be repaired original size by the way of flux-cored wire built-up welding upon wear and continue Use.
At present, the widely used flux-cored wire of coal-grinding roller Bead weld repair is mainly the medicated core weldering based on high ferrochrome based alloy Silk, it is wear-resisting that this kind of resurfacing welding material improves wearing layer by the substantial amounts of carbon of addition and chromium formation carbide hard phase Property, but when flux-cored wire kind carbon content >=5% easily causes the deterioration of welding procedure, splashing particle size becomes big, and quantity becomes many, weldering The type that is seamed into is deteriorated, and reduces welding efficiency.Meanwhile, in flux-cored wire the addition of a large amount of chromiums so that meeting in welding process Produce substantial amounts of flue dust and toxic gas, pollution is produced to environment.Therefore, part chromium is replaced to strengthen with boron, molybdenum element Matrix, thus improving the wearability of wearing layer, has adapted to the environmental protection concept of environment sustainable development.
Content of the invention
The technical problem to be solved is to provide a kind of coal pulverizer abrasion-proof overlaying welding flux-cored wire, for the row that generates electricity Large-scale coal-grinding equipment (coal-grinding roller, mill etc.) in industry in the case of long abrasive wear, the surface of parts often by Scrap inefficacy in abrasion, need periodically coal-grinding equipment to be changed and maintenance surface, adapt to power plant large-scale coal-grinding equipment Low stress abrasive wear working condition, have high-hardness, wearable self-shield effect, reduce existing welding material simultaneously and exist Pollution problem to environment during use.
Not enough for prior art, the invention provides a kind of iron-based self-protection flux-cored wire and its prepared heap seam Gold and method.
A kind of coal-grinding roller iron-based self protection pile-up welding flux core welding wire, described flux-cored wire wraps up medicated core powder by carbon steel steel band Constitute, wherein mass fraction in flux-cored wire for the medicated core powder is 46%-50%, and in described medicated core powder, each component and quality are divided Number is as follows:High carbon ferro-chrome:50%-64%;Ferro-boron:5.5%-11%;Molybdenum-iron:1%-6%;Electrolytic manganese powder:1%-3%;Ferrosilicon:3%-8%;Stone Ink:2%-7%, remaining composition is reduced iron powder.
The preparation method of described flux-cored wire is as follows:
A, roll carbon steel steel band so as to form U-lag, then add in gained U-lag and account for prepared flux-cored wire gross weight The medicated core powder of 46%-50%;
B, U-lag is healed up, so that medicated core powder is wrapped in carbon steel steel band, by wire drawing die, by road drawing, tube reducing, After make its diameter reach 2.8mm, obtain final products.
A kind of M containing Dispersed precipitate is prepared with iron-based self protection pile-up welding flux core welding wire using a kind of coal-grinding roller7C3、Fe2B hard The method of the iron-based abrasion resistant overlaying-welding alloy of phase, it comprises the following steps that:
(1)Prepare medicated core powder according to flux-cored wire, together roll with carbon steel steel band, obtain flux-cored wire;
(2)Hardfacing alloy is prepared using direct-current arc Welding.
Described electronic arc welding technological parameter is:Voltage:30V-35V;Electric current:320A-380A;Wire feed rate:430mm/ min-500mm/min;Welding wire stretches out the length of ignition tip:15mm-30mm.
In the hardfacing alloy being obtained, each component and mass fraction are as follows:C:3%-5%;Cr:16%-22%;Mo:0.4%- 1.8%;B:0.4%-1.3%;Mn:0.9%-2.1%;Si:0.4%-1.6%;Remaining composition is Fe.
The each component of medicated core powder in the flux-cored wire being adopted and mass fraction are preferably as follows:High carbon ferro-chrome:52%- 62%;Ferro-boron:6%-10%;Molybdenum-iron:1.5%-5%;Electrolytic manganese powder:1.5%-2.5%;Ferrosilicon:4%-7.5%;Graphite:2.5%-6.5%, Remaining composition is reduced iron powder;In the hardfacing alloy being obtained, each component and mass fraction are as follows:C:3.5%-4.5%;Cr:17%- 21%;Mo:0.5%-1.5%;B:0.5%-1.2%;Mn:1.0%-2.0%;Si:0.5%-1.5%;Remaining composition is Fe.
The each component of medicated core powder in the flux-cored wire being adopted and mass fraction are further preferably as follows:High carbon ferro-chrome: 55%-60%;Ferro-boron:6.5%-9%;Molybdenum-iron:2%-4%;Electrolytic manganese powder:1.75%-2.45%;Ferrosilicon:5%-7%;Graphite:3%-6%, its Remaining composition is reduced iron powder;In the hardfacing alloy being obtained, each component and mass fraction are as follows:C:4%-4.25%;Cr:18%- 20.5%;Mo:0.6%-1.4%;B:0.6%-1.1%;Mn:1.1%-1.9%;Si:0.6%-1.4%;Remaining composition is Fe.
In described medicated core powder, various component effects are as follows:
High carbon ferro-chrome:It is the main source of carbon and chromium in weld metal, be the essential condition generating a large amount of primary carbides, It is the guarantee of high rigidity and high-wearing feature.In the design of resurfacing welding material, carbon is most important intensified element, and it is solid that carbon has gap The effect of molten strengthening, increases the content of the carbon in material, it will increase carbide quantity, obtains high hardness.In matrix It is dispersed with substantial amounts of primary carbide M7C3So that surfacing layer metal hardness is high, wearability is good.
Ferro-boron:To weld metal transition boron element, primarily to obtaining the boride of high rigidity, thus improving heap seam The wearability of gold.Hardfacing alloy hardness and relative wear resistance improve with the increase of Boron contents, but Boron contents are too high easily causes " boron is crisp ", reduces Wear Resistance, and therefore the present invention designs the ferro-boron content adding in flux-cored wire is 5.5wt.%-11wt.%.
Molybdenum-iron:Molybdenum is generally present in solid solution phase or Carbide Phases in the alloy.Molybdenum forms compound oozing with ferrum and carbon Carbon body, meanwhile, molybdenum also has the dissolubility slowing down carbide in austenite, effectively suppression cementite at high temperature poly- Collection, promote disperse the precipitation of alloy carbide the effects such as, thus serving good invigoration effect in the alloy.
Electrolytic manganese powder, ferrosilicon:Using manganese silicon combined deoxidation, improve transfer coefficient of element.
Graphite:Graphite main component is free carbon, mainly makes up the deficiency of carbon in alloying component, and carbon has gap solid solution The effect of strengthening, promotes the formation of twin crystal martensite, increases carbide quantity, reduces carbonization material dot spacing high hard to obtain Degree.Additionally, flake graphite is more beneficial for stablizing of welding arc, reduces and splash.
Reduced iron powder:Fill up surplus.
Coal-grinding roller hardfacing alloy adopts non gas shielded welding technique to prepare, and according to coal-grinding roller working condition requirement, welding current selects 320A-380A;Voltage 30V-35V;Wire feed rate:430mm/min-500mm/min;Welding wire stretches out the length of ignition tip:15mm- 30mm.The wearing layer hardfacing alloy layer meeting coal-grinding roller working condition requirement can be prepared using this technological parameter.
Beneficial effects of the present invention are:
1st, reduce the use of chromium, decrease the pollution to environment, be a kind of environmentally friendly welding material;
2nd, adopt the alloy structure of flux-cored wire built-up welding of the present invention uniformly, the M7C3 hard phase of formation and Fe2B hard phase are more Scattered is distributed on matrix, thus ensure that the combination property of high-wearing feature;
3rd, bead-welding technology is good:Splash in welding process little, appearance of weld is attractive in appearance.
Brief description
Fig. 1 is the metallographic microstructure figure after 500 times of hardfacing alloy amplification in the embodiment of the present invention 3;
Fig. 2 is hardfacing alloy relative wear resistance Changing Pattern figure in the embodiment of the present invention 3.
Specific embodiment
The invention provides a kind of iron-based self-protection flux-cored wire and its prepared hardfacing alloy and method, with reference to The present invention will be further described for the drawings and specific embodiments.
In each embodiment, same section is as described below:
1st, in embodiment, flux-cored wire crust selects specification is 16mm × 0.3mm(Width is 16mm, and thickness is 0.3mm)'s SPCC carbon steel steel band, flux for flux-cored wire composition illustrates in an embodiment, and selected various drug core component powder cross 60 respectively Mesh sieve, selected various drug core component powder is put into and mixes in mixed powder machine 2 hours, then the medicated core obtaining powder is added U In the steel band groove of shape, U-lag is healed up, so that medicated powder is wrapped up wherein.Then respectively through wire drawing die, by road drawing, tube reducing, finally Make its diameter reach 2.8mm, obtain coal-grinding roller flux-cored wire.
2nd, during welding wire built-up welding, technological parameter is all set as:Voltage:30V-35V;Electric current:320A-380A;Wire feed speed Degree:430mm/min-500mm/min;Welding wire stretches out the length of ignition tip:15mm-30mm.
Embodiment 1
Take 5 kilograms of high carbon ferro-chrome, 0.55 kilogram of ferro-boron, 0.1 kilogram of molybdenum-iron, 0.1 kilogram of electrolytic manganese powder, 0.3 kilogram of ferrosilicon, 0.2 kilogram of graphite, 3.75 kilograms of reduced iron powder.The medicated core obtaining powder is added in the steel band groove of U-shaped, U-lag is healed up, obtains To the coal-grinding roller flux-cored wire of a diameter of 2.8mm, filling rate is 48%, prepares hardfacing alloy by above-mentioned technique, is obtained In hardfacing alloy, each composition and mass fraction are respectively:C:3%;Cr:16%;Mo:0.4%;B:0.4%;Mn:0.9%;Si:0.4%; Remaining composition is Fe.
Embodiment 2
Take 5.2 kilograms of high carbon ferro-chrome, 0.6 kilogram of ferro-boron, 0.15 kilogram of molybdenum-iron, 0.15 kilogram of electrolytic manganese powder, ferrosilicon 0.4 thousand Gram, 0.25 kilogram of graphite, 3.25 kilograms of reduced iron powder.The medicated core obtaining powder is added in the steel band groove of U-shaped, U-lag is closed Mouthful, obtain the coal-grinding roller flux-cored wire of a diameter of 2.8mm, filling rate is 48%, prepares hardfacing alloy by above-mentioned technique, institute In the hardfacing alloy obtaining, each composition and mass fraction are respectively:C:3.5%;Cr:17%;Mo:0.5%;B:0.5%;Mn:1.0%; Si:0.5%;Remaining composition is Fe.
Embodiment 3
Take 5.5 kilograms of high carbon ferro-chrome, 0.65 kilogram of ferro-boron, 0.2 kilogram of molybdenum-iron, 0.175 kilogram of electrolytic manganese powder, ferrosilicon 0.5 Kilogram, 0.3 kilogram of graphite, 2.675 kilograms of reduced iron powder.The medicated core obtaining powder is added in the steel band groove of U-shaped, by U-lag Heal up, obtain the coal-grinding roller flux-cored wire of a diameter of 2.8mm, filling rate is 48%, prepares hardfacing alloy by above-mentioned technique, In the hardfacing alloy being obtained, each composition and mass fraction are respectively:C:4%;Cr:18%;Mo:0.6%;B:0.6%;Mn:1.1%; Si:0.6%;Remaining composition is Fe.
Embodiment 4
Take 6 kilograms of high carbon ferro-chrome, 0.9 kilogram of ferro-boron, 0.4 kilogram of molybdenum-iron, 0.245 kilogram of electrolytic manganese powder, ferrosilicon 0.7 thousand Gram, 0.6 kilogram of graphite, 1.155 kilograms of reduced iron powder.The medicated core obtaining powder is added in the steel band groove of U-shaped, U-lag is closed Mouthful, obtain the coal-grinding roller flux-cored wire of a diameter of 2.8mm, filling rate is 48%, prepares hardfacing alloy by above-mentioned technique, institute In the hardfacing alloy obtaining, each composition and mass fraction are respectively:C:4.25%;Cr:20.5%;Mo:1.4%;B:1.1%;Mn: 1.9%;Si:1.4%;Remaining composition is Fe.
Embodiment 5
Take 6.2 kilograms of high carbon ferro-chrome, 1 kilogram of ferro-boron, 0.5 kilogram of molybdenum-iron, 0.25 kilogram of electrolytic manganese powder, ferrosilicon 0.75 thousand Gram, 0.65 kilogram of graphite, 0.65 kilogram of reduced iron powder.The medicated core obtaining powder is added in the steel band groove of U-shaped, U-lag is closed Mouthful, obtain the coal-grinding roller flux-cored wire of a diameter of 2.8mm, filling rate is 48%, prepares hardfacing alloy by above-mentioned technique, institute In the hardfacing alloy obtaining, each composition and mass fraction are respectively:C:4.5%;Cr:21%;Mo:1.5%;B:1.2%;Mn:2.0%; Si:1.5%;Remaining composition is Fe.
Embodiment 6
Take 6.4 kilograms of high carbon ferro-chrome, 1.1 kilograms of ferro-boron, 0.6 kilogram of molybdenum-iron, 0.3 kilogram of electrolytic manganese powder, ferrosilicon 0.8 thousand Gram, 0.7 kilogram of graphite, 0.1 kilogram of reduced iron powder.The medicated core obtaining powder is added in the steel band groove of U-shaped, U-lag is healed up, Obtain the coal-grinding roller flux-cored wire of a diameter of 2.8mm, filling rate is 48%, prepares hardfacing alloy by above-mentioned technique, is obtained Hardfacing alloy in each composition and mass fraction be respectively:C:4.5%;Cr:22%;Mo:1.5%;B:1.2%;Mn:2.0%;Si: 1.5%;Remaining composition is Fe.
Hardfacing alloy performance detection prepared by each embodiment is as described below:
1. as follows to example hardfacing alloy deposited metal hardness test:
Table 1 is Rockwell hardness number, and described hardness is all tested using HR~150A Rockwell hardness machine, and load is 150Kg, Average after making a call to five points.
The each embodiment hardfacing alloy deposited metal hardness number of table 1(HRC)
2. pair hardfacing alloy prepared by each example carries out wear-resistant experiment, using the wheeled abrasive particle of MLS-225 type damp sand rubber Abrasion tester is carried out.Wear specimens a size of 57mm × 25.5mm × 6mm, test parameterss are as follows:Rubber wheel speed:240r/ min;Rubber wheel diameter:178mm;Rubber wheel hardness:60 (continue that hardness);Load 100N;Rubber wheel revolution:1000 turns of pre-grinding, Fine grinding 3000 turns, abrasive material:Granularity 40-70 mesh quartz sand.Material wear-resistant performance is weighed with the weight loss of abrasion.Before experiment, Afterwards, sample is put in the beaker filling acetone soln, in ultrasonic washing instrument, clean 3-5 minute, with 45 quenchings in experiment Steel sample as a comparison, numbering is embodiment 0.Contrast piece weight loss is used for the relative resistance to of this formula with measuring piece weight loss Mill property.
Embodiment 0-6 gained hardfacing alloy relative wear resistance Changing Pattern experimental result is as shown in Figure 2.

Claims (9)

1. a kind of coal-grinding roller with iron-based self protection pile-up welding flux core welding wire it is characterised in that:Described flux-cored wire is by carbon steel steel band bag Wrap up in medicated core powder to constitute, wherein mass fraction in flux-cored wire for the medicated core powder is 46%-50%, each in described medicated core powder Component and mass fraction are as follows:High carbon ferro-chrome:50%-64%;Ferro-boron:5.5%-11%;Molybdenum-iron:1%-6%;Electrolytic manganese powder: 1%-3%;Ferrosilicon:3%-8%;Graphite:2%-7%, remaining composition is reduced iron powder.
2. a kind of coal-grinding roller according to claim 1 with iron-based self protection pile-up welding flux core welding wire it is characterised in that:Described medicine Carbon steel steel band used by core welding wire crust is SPCC carbon steel steel band.
3. a kind of coal-grinding roller according to claim 1 with iron-based self protection pile-up welding flux core welding wire it is characterised in that:Described In medicated core powder, each component and mass fraction are as follows:High carbon ferro-chrome:52%-62%;Ferro-boron:6%-10%;Molybdenum-iron:1.5%- 5%;Electrolytic manganese powder:1.5%-2.5%;Ferrosilicon:4%-7.5%;Graphite:2.5%-6.5%, remaining composition is reduced iron powder.
4. a kind of coal-grinding roller according to claim 1 with iron-based self protection pile-up welding flux core welding wire it is characterised in that:Described In medicated core powder, each component and mass fraction are as follows:High carbon ferro-chrome:55%-60%;Ferro-boron:6.5%-9%;Molybdenum-iron:2%- 4%;Electrolytic manganese powder:1.75%-2.45%;Ferrosilicon:5%-7%;Graphite:3%-6%, remaining composition is reduced iron powder.
5. adopt a kind of coal-grinding roller iron-based self protection pile-up welding flux core welding wire to prepare a kind of M containing Dispersed precipitate7C3、Fe2B hard phase Iron-based abrasion resistant overlaying-welding alloy method it is characterised in that comprising the following steps that:
(1) prepare medicated core powder according to flux-cored wire, together roll with carbon steel steel band, obtain flux-cored wire;
(2) hardfacing alloy is prepared using direct-current arc Welding;
In the flux-cored wire being adopted, each component of medicated core powder and mass fraction are as follows:High carbon ferro-chrome:50%-64%;Ferro-boron: 5.5%-11%;Molybdenum-iron:1%-6%;Electrolytic manganese powder:1%-3%;Ferrosilicon:3%-8%;Graphite:2%-7%, remaining composition is Reduced iron powder;
In the hardfacing alloy being obtained, each component and mass fraction are as follows:C:3%-5%;Cr:16%-22%;Mo:0.4%- 1.8%;B:0.4%-1.3%;Mn:0.9%-2.1%;Si:0.4%-1.6%;Remaining composition is Fe.
6. method according to claim 5 is it is characterised in that the comprising the following steps that of described step (1):
A, roll carbon steel steel band so as to form U-lag, then add in gained U-lag and account for prepared flux-cored wire gross weight 46%- 50% medicated core powder;
B, U-lag is healed up, so that medicated core powder is wrapped in carbon steel steel band, by wire drawing die, by road drawing, tube reducing, finally make Its diameter reaches 2.8mm, obtains final products.
7. method according to claim 5 it is characterised in that:Described electronic arc welding technological parameter is:Voltage:30V- 35V;Electric current:320A-380A;Wire feed rate:430mm/min-500mm/min;Welding wire stretches out the length of ignition tip:15mm- 30mm.
8. using the preparation of claim 5 methods described hardfacing alloy it is characterised in that medicated core powder in the flux-cored wire that adopted The each component in end and mass fraction are as follows:High carbon ferro-chrome:52%-62%;Ferro-boron:6%-10%;Molybdenum-iron:1.5%-5%;Electrolytic manganese Powder:1.5%-2.5%;Ferrosilicon:4%-7.5%;Graphite:2.5%-6.5%, remaining composition is reduced iron powder;
In the hardfacing alloy being obtained, each component and mass fraction are as follows:C:3.5%-4.5%;Cr:17%-21%;Mo: 0.5%-1.5%;B:0.5%-1.2%;Mn:1.0%-2.0%;Si:0.5%-1.5%;Remaining composition is Fe.
9. using the preparation of claim 5 methods described hardfacing alloy it is characterised in that medicated core powder in the flux-cored wire that adopted The each component in end and mass fraction are as follows:High carbon ferro-chrome:55%-60%;Ferro-boron:6.5%-9%;Molybdenum-iron:2%-4%;Electrolytic manganese Powder:1.75%-2.45%;Ferrosilicon:5%-7%;Graphite:3%-6%, remaining composition is reduced iron powder;
In the hardfacing alloy being obtained, each component and mass fraction are as follows:C:4%-4.25%;Cr:18%-20.5%;Mo: 0.6%-1.4%;B:0.6%-1.1%;Mn:1.1%-1.9%;Si:0.6%-1.4%;Remaining composition is Fe.
CN201310676726.2A 2013-12-11 2013-12-11 Iron-based self-protection flux-cored wire, surfacing alloy manufactured with iron-based self-protection flux-cored wire and method for manufacturing iron-based self-protection flux-cored wire Active CN104708234B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045295A1 (en) * 1980-07-25 1982-02-03 Vereinigte Edelstahlwerke Aktiengesellschaft (Vew) Flux-cored wire or strip electrode for hard-facing
EP1209246A2 (en) * 2000-11-07 2002-05-29 OSU Maschinenbau GmbH Method for surface coating resisting to wear and corrosion, and means for performing the method
CN100999042A (en) * 2006-12-18 2007-07-18 燕山大学 Pile up welding flux cored wire used for remanufacturing compound bimetal large special wear resistant parts
CN102069317A (en) * 2010-12-08 2011-05-25 燕山大学 Self-protection flux-cored wire for rare earth type high-chromium cast iron by open arc
CN102416534A (en) * 2011-04-27 2012-04-18 杜荣臻 Gas-protected surfacing flux-cored welding wire for surfacing
CN102513742A (en) * 2011-12-28 2012-06-27 天津大桥金属焊丝有限公司 Flux-cored wire for visible arc overlaying of high-chromium cast iron
CN102554503A (en) * 2011-12-22 2012-07-11 中国船舶重工集团公司第七二五研究所 Abrasion-resisting surfacing flux-cored wire for coal milling roller
CN102873474A (en) * 2012-06-07 2013-01-16 南昌大学 Little slag self-protection hard-surface flux-cored wire for build-up welding
CN101837522B (en) * 2010-06-11 2013-06-19 河海大学常州校区 Vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05337690A (en) * 1992-06-08 1993-12-21 Kobe Steel Ltd Flux cored wire for submerged arc welding having excellent wear resistance and bead mark resistance

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045295A1 (en) * 1980-07-25 1982-02-03 Vereinigte Edelstahlwerke Aktiengesellschaft (Vew) Flux-cored wire or strip electrode for hard-facing
EP1209246A2 (en) * 2000-11-07 2002-05-29 OSU Maschinenbau GmbH Method for surface coating resisting to wear and corrosion, and means for performing the method
CN100999042A (en) * 2006-12-18 2007-07-18 燕山大学 Pile up welding flux cored wire used for remanufacturing compound bimetal large special wear resistant parts
CN101837522B (en) * 2010-06-11 2013-06-19 河海大学常州校区 Vanadium-reinforced wear-resistant submerged-arc surfacing flux-cored welding wire
CN102069317A (en) * 2010-12-08 2011-05-25 燕山大学 Self-protection flux-cored wire for rare earth type high-chromium cast iron by open arc
CN102416534A (en) * 2011-04-27 2012-04-18 杜荣臻 Gas-protected surfacing flux-cored welding wire for surfacing
CN102554503A (en) * 2011-12-22 2012-07-11 中国船舶重工集团公司第七二五研究所 Abrasion-resisting surfacing flux-cored wire for coal milling roller
CN102513742A (en) * 2011-12-28 2012-06-27 天津大桥金属焊丝有限公司 Flux-cored wire for visible arc overlaying of high-chromium cast iron
CN102873474A (en) * 2012-06-07 2013-01-16 南昌大学 Little slag self-protection hard-surface flux-cored wire for build-up welding

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