CN101812382A - Environment friendly cleaning agent for breeding and preparation method thereof - Google Patents
Environment friendly cleaning agent for breeding and preparation method thereof Download PDFInfo
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- CN101812382A CN101812382A CN 201010133990 CN201010133990A CN101812382A CN 101812382 A CN101812382 A CN 101812382A CN 201010133990 CN201010133990 CN 201010133990 CN 201010133990 A CN201010133990 A CN 201010133990A CN 101812382 A CN101812382 A CN 101812382A
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Abstract
The invention provides environment friendly cleaning agent for breeding and a preparation method thereof, belonging to the technical field of environment friendly breeding supplies for sterilizing and cleaning. The cleaning agent is prepared from concentrated sulfuric acid, citric acid, hydrogen peroxide, surfactant and water. The cleaning agent is non-poisonous, tasteless, powerful in sterilization and disinfection and capable of thoroughly cleaning black and odor bottoms at a high rate, achieving no residue but lasting effect; when in use, the cleaning agent can prevent the residual chlorine from being generated and cause no phosphorus pollution or marine pollution but seawater eutrophication; moreover, the cleaning agent can reduce the content of ammonia nitrogen and nitrite in the seawater and eliminate the harmful organic substances to purify the seawater; the cleaning agent mainly based on concentrated sulfuric acid, citric acid and hydrogen peroxide and diluted by the ratio of 1:(20-50) when in use is non-corrosive and non-irritant to skin, and the cleaning agent is safe, effective and free from the hazard to aquatic animals; for the cleaning agent contains no corrosive caustic soda and phosphorus residue from washing powder, the cleaning agent is friendly to the breeding environment; and the invention has the advantages of simple preparation process and low cost.
Description
Technical field
The present invention relates to a kind of environment friendly cleaning agent for breeding and preparation method thereof, belong to the environment-protecting cultivation sterilization and clean the articles for use technical field.
Background technology
At present, holothruian cultures have become the mainstay industry of northern China aquaculture, and growth momentum is swift and violent, and Dalian area sea cucumber seedling rearing room scale is big, more than the quantity, have exceeded people's the imagination.The sea cucumber seedling rearing room yellow along ring, that the Bohai Sea is a large amount of cleans the net sheet and cleans nursery pond, and traditional purging method will use hydrochloric acid and clorox to clean, and pollutes to the marine eco-environment.Because hydrochloric acid, clorox contain residual chlorine, grow seedlings and breed brings injury to sea cucumber, sea cucumber is subject to the influence of residual chlorine, the toxicity symptom of swollen mouth occurs, changing skin, tell intestines, more seriously can extended residual in the sea cucumber body, the people eats so poisonous sea cucumber, influences healthyly, has come harm for the food securing band.
About livestock and poultry cultivation, the area, Dalian also is very big, particularly clean the colony house on chicken house, pig farm, the fecal pollution thing on ground, online plastic wire of culturing table poultry, traditional practice all is to clean with caustic soda, washing powder, caustic soda corrodibility is very strong, washing powder has phosphorus residual, and raffinate brings pollution to environment in the cleaning process.
In order to solve the pollution problem of traditional clean-out system hydrochloric acid, clorox, caustic soda, phosphorous washing powder, the cleaning agent for breeding of exploitation environmental protection, safety replaces hydrochloric acid, clorox, caustic soda, phosphorous washing powder.On the one hand, meet the national environmental protection policy, protect the marine environment, protect living environment; On the other hand, also meet country and encourage middle-size and small-size science-and-technology enterprise autonomous innovation, walk the road of development in science and technology.
Summary of the invention
In order to solve above-mentioned problems of the prior art, the invention provides a kind of environment friendly cleaning agent for breeding and preparation method thereof.When this environment friendly cleaning agent for breeding uses, should not produce that chlorine is residual, phosphorus pollutes; Preparation technology is simple, with low cost.
Technical solution of the present invention is: main raw material composition and the mass percent of a kind of environment friendly cleaning agent for breeding is:
Raw material composition mass percent
The vitriol oil 24～36%
Citric acid 0.5～10%
Mass concentration per-cent is 27.5% hydrogen peroxide 24～36%
Tensio-active agent 0.01～0.1%
All the other are water
Described tensio-active agent is selected from one or more in non-ionic type, amino acid pattern, the betaine type.
A kind of preparation method of environment friendly cleaning agent for breeding, the preparation process that it adopts is as follows:
(1) gets 25L blueness or black plastic bucket, earlier the water of certain mass percent is put into plastic tank, the vitriol oil of certain mass percent is slowly joined in the described plastic tank be diluted to dilute sulphuric acid then, leave standstill and be cooled to 30～25 ℃;
(2) citric acid with certain mass percent joins in the described plastic tank, stirs 5 minutes;
(3) hydrogen peroxide with certain mass percent joins in the described plastic tank, stirs 10～20 minutes;
(4) tensio-active agent with certain mass percent joins in the described plastic tank, stirs 10～20 minutes, and capping is labelled and got product.
The invention has the beneficial effects as follows: this environment friendly cleaning agent for breeding is the clean-out system that cleans exploitation for aquaculture, and the main raw material of employing is the vitriol oil, citric acid, hydrogen peroxide, tensio-active agent and water.Overcome the pollution problem of hydrochloric acid, clorox, caustic soda, phosphorous washing powder.Nonpoisonous and tasteless, the environmental protection of this clean-out system, the sterilization and disinfection great efforts, it is totally thorough to clean black matrix, the smelly end, and speed is fast, noresidue, effect are lasting.When this environment friendly cleaning agent for breeding used, it was residual not produce chlorine, and phosphorus pollutes, and Marine Pollution does not cause the seawater eutrophication, and, can also reduce the ammonia nitrogen in the seawater, nitrite is eliminated harmful organic substance, purifies water; With sulfuric acid, citric acid, hydrogen peroxide is the main raw material that cleans, and is diluted in the seawater by 1: 20～50 times during use, does not have corrodibility, and skin is not had pungency, and hydrocoles is not poisoned, safe and efficient; Be used to clean the colony house on chicken house, pig farm, the fecal pollution thing on ground is cultured the plastic wire of table poultry on the net, does not have caustic soda corrodibility strong, and the phosphorus of washing powder is residual, to the breeding environment close friend; Preparation technology is simple, and is with low cost.
Embodiment
Embodiment 1:
(1) dilution of the vitriol oil
Getting 25L blueness or black plastic bucket, earlier is that 39.4% water takes out and puts into plastic tank with mass percent, is that 24% the vitriol oil slowly adds and is diluted to dilute sulphuric acid in the plastic tank then with mass percent, leaves standstill and is cooled to 30～25 ℃.
(2) citric acid
With mass percent is that 0.5% citric acid joins in the plastic tank, stirs 5 minutes.
(3) add hydrogen peroxide
With mass percent is that 36% hydrogen peroxide joins in the above-mentioned plastic tank, stirs 10～20 minutes.
(4) add tensio-active agent
With mass percent is that 0.1% nonionogenic tenside Nonyl pheno (7) ether joins in the above-mentioned plastic tank, stirs 10～20 minutes, and capping is labelled and got product.
The environment friendly cleaning agent for breeding of producing by above-mentioned prescription, in 5 ℃～-10 ℃ environment, non-crystallizable, do not rise turbid, not stratified, do not freeze.
Nonpoisonous and tasteless, the environmental protection of this product, the efficient sterilizing algae is cleaned great efforts, and it is totally thorough to clean black matrix, the smelly end, and the net sheet of cleaning is yellow-white, and cleaning speed is fast, noresidue, effect are lasting.
Embodiment 2:
(1) dilution of the vitriol oil
Getting 25L blueness or black plastic bucket, earlier is that 34.95% water takes out and puts into plastic tank with mass percent, is that 36% the vitriol oil slowly adds and is diluted to dilute sulphuric acid in the plastic tank then with mass percent, leaves standstill and is cooled to 30～25 ℃.
(2) citric acid
With mass percent is that 5% citric acid joins in the plastic tank, stirs 5 minutes.
(3) add hydrogen peroxide
With mass percent is that 24% hydrogen peroxide joins in the above-mentioned plastic tank, stirs 10～20 minutes.
(4) add tensio-active agent
With mass percent is that 0.05% nonionogenic tenside APG (APG) joins in the above-mentioned plastic tank, stirs 10～20 minutes, and capping is labelled and got product.
The environment friendly cleaning agent for breeding of producing by above-mentioned prescription, in 25 ℃～-10 ℃ environment, non-crystallizable, do not rise turbid, not stratified, do not freeze.
Nonpoisonous and tasteless, the environmental protection of this product, the efficient sterilizing algae is cleaned great efforts, and it is totally thorough to clean black matrix, the smelly end, and the net sheet of cleaning is yellow-white, and cleaning speed is fast, noresidue, effect are lasting.
Embodiment 3:
(1) dilution of the vitriol oil
Getting 25L blueness or black plastic bucket, earlier is that 29.99% water takes out and puts into plastic tank with mass percent, is that 30% the vitriol oil slowly adds and is diluted to dilute sulphuric acid in the plastic tank then with mass percent, leaves standstill and is cooled to 30～25 ℃.
(2) citric acid
With mass percent be 10% citric acid by joining in the plastic tank, stirred 5 minutes.
(3) add hydrogen peroxide
With mass percent is 30% hydrogen peroxide, joins in the above-mentioned plastic tank, stirs 10～20 minutes.
(4) add tensio-active agent
With mass percent is that 0.01% betaine type amphoteric surfactant empgen BB joins in the above-mentioned plastic tank, stirs 10～20 minutes, and capping is labelled and got product.
The environment friendly cleaning agent for breeding of producing by above-mentioned prescription, in 25 ℃～-10 ℃ environment, non-crystallizable, do not rise turbid, not stratified, do not freeze.
Nonpoisonous and tasteless, the environmental protection of this product, the efficient sterilizing algae is cleaned great efforts, and it is totally thorough to clean black matrix, the smelly end, and the net sheet of cleaning is yellow-white, and cleaning speed is fast, noresidue, effect are lasting.
Be product introduction below by the foregoing description preparation:
The product effect:
1, sterilization and disinfection effect can be killed the pathogenic micro-organism outside the animal body fast under the normal temperature lower concentration, comprise various virus and bacterias, mould, protozoon (ciliate), fungi, sporeformer, harmful algae etc.
2, clean deodorization: at the bottom of removing the smelly end of black matrix of polluting the cement flooring, harmful algae mud fast and effectively, eliminate peculiar smell, to clean pool wall totally thorough, recover the cement primary colors and do not hinder the cement flooring.
3, the cleaning of the net sheet of breed usefulness, utensil, container.
Products characteristics: this product is the clean-out system that aquaculture is cleaned exploitation, can substitute products such as hydrochloric acid, clorox, potassium permanganate, hydrogen peroxide.Nonpoisonous and tasteless, the environmental protection of this product, the sterilization and disinfection great efforts, it is totally thorough to clean black matrix, the smelly end, and speed is fast, noresidue, effect are lasting.Current with hydrochloric acid, clorox have chlorine residual and the corrosion cement flooring shortcoming; Potassium permanganate has heavy metal residual of manganese; Disinfection is not thorough though hydrogen peroxide is nonpoisonous and tasteless.This product has overcome the above-mentioned shortcoming of hydrochloric acid, clorox, potassium permanganate, hydrogen peroxide, makes brush pond sterilisation effect more perfect.
Product performance: the cleanup action of this product is mainly derived from the oxidisability of peroxide root and the soil release characteristics of tensio-active agent.Therefore, dilute sulphuric acid requires to be converted into permonosulphuric acid and peroxy-disulfuric acid, to reach best cleaning performance.Specifically obtaining best effect by experiment is as the criterion.
End-use:
1, livestock and poultry breeding industry: be used for the cleaning of the livestock and poultry colony house of pig farm, poulty house, minkery etc., the cleaning of cultivation equipment.
2, culture fishery: be used for seedling rearing room: the cement pit of growing seedlings that sea cucumber pond, fishpond, shrimp pond, Bei Chi and all aquaculture need be cleaned, apparatus, container etc.
The product using method: get after 1 kilogram of this product converts 10-20 kilogram dilution, splash and scrub then with brush to the object that will clean, water is rinsed well and is got final product.
Product proterties: the liquid that colorless and odorless is transparent
Technical target of the product:
1, this product persulfate ion (containing permonosulphuric acid root, peroxy-disulfuric acid root summation) will reach more than 20%;
2, cleaning performance will reach surface blot and thoroughly eliminates, and gets back to original clean surface degree;
3, the smell after cleaning pure and fresh, can't smell stink;
4, clean back aerophil and anerobe and be controlled in the reasonable range (minimum inhibitory concentration 500mg/kg), animal is caused a disease;
5, this product requirement environmental protection, environmentally safe, nontoxic to animal;
6, product safety coefficient height does not have pungency to the people, animal mucous membrane;
7, tensio-active agent nonyl phenol polyethenoxy ether reaches 0.1%;
8, surfactant A B35 reaches more than 0.1%;
9, citric acid content reaches 0.5%;
10, the PH index is with 1% solution 1-2;
11, security measures:
(1), the stoste of this product has certain corrodibility, during production, note labour protection, wears the operation of anticorrosion gloves and mask;
(2), pack, be stored in shady and cool dry place, 12 months storage periods with plastic tank.
Claims (3)
1. environment friendly cleaning agent for breeding, it is characterized in that: its main raw material composition and mass percent is:
Raw material composition mass percent
The vitriol oil 24～36%
Citric acid 0.5～10%
Mass concentration per-cent is 27.5% hydrogen peroxide 24～36%
Tensio-active agent 0.01～0.1%
All the other are water.
2. according to the described a kind of environment friendly cleaning agent for breeding of claim 1, it is characterized in that: described tensio-active agent is selected from one or more in non-ionic type, amino acid pattern, the betaine type.
3. according to the preparation method of the described a kind of environment friendly cleaning agent for breeding of claim 1, it is characterized in that: the preparation process that it adopts is as follows:
(1) gets 25L blueness or black plastic bucket, earlier the water of certain mass percent is put into plastic tank, the vitriol oil of certain mass percent is slowly joined in the described plastic tank be diluted to dilute sulphuric acid then, leave standstill and be cooled to 30～25 ℃;
(2) citric acid with certain mass percent joins in the described plastic tank, stirs 5 minutes;
(3) hydrogen peroxide with certain mass percent joins in the described plastic tank, stirs 10～20 minutes;
(4) tensio-active agent with certain mass percent joins in the described plastic tank, stirs 10～20 minutes, and capping is labelled and got product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101339908A CN101812382B (en) | 2010-03-25 | 2010-03-25 | Environment friendly cleaning agent for breeding and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101339908A CN101812382B (en) | 2010-03-25 | 2010-03-25 | Environment friendly cleaning agent for breeding and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN101812382A true CN101812382A (en) | 2010-08-25 |
| CN101812382B CN101812382B (en) | 2011-07-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010101339908A Expired - Fee Related CN101812382B (en) | 2010-03-25 | 2010-03-25 | Environment friendly cleaning agent for breeding and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102719326A (en) * | 2012-07-13 | 2012-10-10 | 河北地邦动物保健科技有限公司 | Pharmaceutical composition for washing and maintaining pipe chase in poultry house |
| CN106520399A (en) * | 2016-10-31 | 2017-03-22 | 佛山市南海东方澳龙制药有限公司 | Cleaning agent for livestock farm and preparation method thereof |
| CN106800984A (en) * | 2015-11-26 | 2017-06-06 | 瑞普（天津）生物药业有限公司 | A kind of acid pipeline cleaning agent and preparation method thereof |
| CN106800978A (en) * | 2016-12-20 | 2017-06-06 | 山东新华医疗器械股份有限公司 | Animal cage scavenger specially, preparation method and its application method |
| CN106833911A (en) * | 2017-02-09 | 2017-06-13 | 合肥隆扬农业科技有限公司 | A kind of pig house cleaning agent |
| CN109266451A (en) * | 2018-11-12 | 2019-01-25 | 河南华美万邦清洗技术有限公司 | A kind of farm's foam cleaning agent |
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| JP2002129197A (en) * | 2000-10-25 | 2002-05-09 | Shikoku Chem Corp | Tablet composition capable of releasing active oxygen in water |
| CN1545883A (en) * | 2003-12-15 | 2004-11-17 | 韶山大北农动物药业有限公司 | Water soluble composite potassium monopersulfate powder disinfectant |
| CN1554239A (en) * | 2003-12-27 | 2004-12-15 | 胡银安 | Superoxide disinfectant |
| US20080145390A1 (en) * | 2006-06-05 | 2008-06-19 | The Dial Corporation | Methods and articles having a high antiviral and antibacterial efficacy |
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2010
- 2010-03-25 CN CN2010101339908A patent/CN101812382B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002129197A (en) * | 2000-10-25 | 2002-05-09 | Shikoku Chem Corp | Tablet composition capable of releasing active oxygen in water |
| CN1545883A (en) * | 2003-12-15 | 2004-11-17 | 韶山大北农动物药业有限公司 | Water soluble composite potassium monopersulfate powder disinfectant |
| CN1554239A (en) * | 2003-12-27 | 2004-12-15 | 胡银安 | Superoxide disinfectant |
| US20080145390A1 (en) * | 2006-06-05 | 2008-06-19 | The Dial Corporation | Methods and articles having a high antiviral and antibacterial efficacy |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102719326A (en) * | 2012-07-13 | 2012-10-10 | 河北地邦动物保健科技有限公司 | Pharmaceutical composition for washing and maintaining pipe chase in poultry house |
| CN106800984A (en) * | 2015-11-26 | 2017-06-06 | 瑞普（天津）生物药业有限公司 | A kind of acid pipeline cleaning agent and preparation method thereof |
| CN106520399A (en) * | 2016-10-31 | 2017-03-22 | 佛山市南海东方澳龙制药有限公司 | Cleaning agent for livestock farm and preparation method thereof |
| CN106800978A (en) * | 2016-12-20 | 2017-06-06 | 山东新华医疗器械股份有限公司 | Animal cage scavenger specially, preparation method and its application method |
| CN106833911A (en) * | 2017-02-09 | 2017-06-13 | 合肥隆扬农业科技有限公司 | A kind of pig house cleaning agent |
| CN109266451A (en) * | 2018-11-12 | 2019-01-25 | 河南华美万邦清洗技术有限公司 | A kind of farm's foam cleaning agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101812382B (en) | 2011-07-06 |
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Granted publication date: 20110706 Termination date: 20120325 |