CN101803081A - 用于固体氧化物燃料电池装置的复合阴极 - Google Patents
用于固体氧化物燃料电池装置的复合阴极 Download PDFInfo
- Publication number
- CN101803081A CN101803081A CN200880107266A CN200880107266A CN101803081A CN 101803081 A CN101803081 A CN 101803081A CN 200880107266 A CN200880107266 A CN 200880107266A CN 200880107266 A CN200880107266 A CN 200880107266A CN 101803081 A CN101803081 A CN 101803081A
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- CN
- China
- Prior art keywords
- zirconia
- electrode
- combination electrode
- yttria
- stabilized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000446 fuel Substances 0.000 title claims abstract description 28
- 239000007787 solid Substances 0.000 title claims abstract description 27
- 239000002131 composite material Substances 0.000 title claims description 29
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000000203 mixture Substances 0.000 claims abstract description 55
- 239000002253 acid Substances 0.000 claims abstract description 31
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 27
- PACGUUNWTMTWCF-UHFFFAOYSA-N [Sr].[La] Chemical compound [Sr].[La] PACGUUNWTMTWCF-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000001301 oxygen Substances 0.000 claims description 41
- 229910052760 oxygen Inorganic materials 0.000 claims description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 18
- 230000008021 deposition Effects 0.000 claims description 13
- 230000006641 stabilisation Effects 0.000 claims description 13
- 238000005245 sintering Methods 0.000 claims description 12
- 229910052746 lanthanum Inorganic materials 0.000 claims description 6
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 5
- 229910002075 lanthanum strontium manganite Inorganic materials 0.000 description 30
- 229910002080 8 mol% Y2O3 fully stabilized ZrO2 Inorganic materials 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 21
- 239000003792 electrolyte Substances 0.000 description 20
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 14
- 238000007639 printing Methods 0.000 description 13
- 239000002585 base Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000010304 firing Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
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- 238000001035 drying Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000000137 annealing Methods 0.000 description 5
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- 239000003054 catalyst Substances 0.000 description 5
- 239000010987 cubic zirconia Substances 0.000 description 5
- 239000007772 electrode material Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- -1 oxygen ions Chemical class 0.000 description 5
- 230000010287 polarization Effects 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
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- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 3
- 238000005284 basis set Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
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- 238000005516 engineering process Methods 0.000 description 3
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- 229940126062 Compound A Drugs 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
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- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- BQENXCOZCUHKRE-UHFFFAOYSA-N [La+3].[La+3].[O-][Mn]([O-])=O.[O-][Mn]([O-])=O.[O-][Mn]([O-])=O Chemical compound [La+3].[La+3].[O-][Mn]([O-])=O.[O-][Mn]([O-])=O.[O-][Mn]([O-])=O BQENXCOZCUHKRE-UHFFFAOYSA-N 0.000 description 1
- FVROQKXVYSIMQV-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Mn]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])=O FVROQKXVYSIMQV-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
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- 238000005034 decoration Methods 0.000 description 1
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- 238000002003 electron diffraction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US96393207P | 2007-08-08 | 2007-08-08 | |
| US60/963,932 | 2007-08-08 | ||
| PCT/US2008/009425 WO2009020608A1 (en) | 2007-08-08 | 2008-08-06 | Composite cathode for use in solid oxide fuel cell devices |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101803081A true CN101803081A (zh) | 2010-08-11 |
Family
ID=39989814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880107266A Pending CN101803081A (zh) | 2007-08-08 | 2008-08-06 | 用于固体氧化物燃料电池装置的复合阴极 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20110229794A1 (https=) |
| EP (1) | EP2183806A1 (https=) |
| JP (1) | JP2010536146A (https=) |
| CN (1) | CN101803081A (https=) |
| TW (1) | TW200926486A (https=) |
| WO (1) | WO2009020608A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108134100A (zh) * | 2017-12-28 | 2018-06-08 | 成都新柯力化工科技有限公司 | 一种铁酸镧/镍酸镧系燃料电池膜电极材料及其制备方法 |
| CN113330613A (zh) * | 2019-01-30 | 2021-08-31 | 日本碍子株式会社 | 电化学电池 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101429944B1 (ko) * | 2012-11-22 | 2014-08-14 | 한국과학기술연구원 | 후열처리된 복합체 공기극을 포함하는 고체산화물 연료전지 및 그 제조방법 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3522097A (en) * | 1967-06-12 | 1970-07-28 | Gen Electric | Silver-palladium cathodic current collector for high temperature fuel cells |
| US7595127B2 (en) * | 2001-06-29 | 2009-09-29 | Nextech Materials, Ltd. | Nano-composite electrodes and method of making the same |
| KR100538555B1 (ko) * | 2003-08-25 | 2005-12-23 | 한국에너지기술연구원 | 연료극 지지체식 평관형 고체산화물 연료전지 스택과 그제조 방법 |
| DE10351955A1 (de) * | 2003-11-07 | 2005-06-16 | Forschungszentrum Jülich GmbH | Kathodenwerkstoff für eine Hochtemperatur-Brennstoffzelle (SOFC) sowie eine daraus herstellbare Kathode |
| US20060234855A1 (en) * | 2004-10-12 | 2006-10-19 | Gorte Raymond J | Preparation of solid oxide fuel cell electrodes by electrodeposition |
| CN101147285A (zh) * | 2005-03-23 | 2008-03-19 | 株式会社日本触媒 | 用于固态氧化物型燃料电池的燃料极材料和使用该材料的燃料极以及燃料电池组 |
| US20070141435A1 (en) * | 2005-12-20 | 2007-06-21 | Hasz Wayne C | Fuel cell with a brazed interconnect and method of assembling the same |
-
2008
- 2008-08-06 US US12/671,746 patent/US20110229794A1/en not_active Abandoned
- 2008-08-06 CN CN200880107266A patent/CN101803081A/zh active Pending
- 2008-08-06 JP JP2010519974A patent/JP2010536146A/ja not_active Ceased
- 2008-08-06 TW TW097129976A patent/TW200926486A/zh unknown
- 2008-08-06 EP EP08795056A patent/EP2183806A1/en not_active Withdrawn
- 2008-08-06 WO PCT/US2008/009425 patent/WO2009020608A1/en not_active Ceased
Non-Patent Citations (2)
| Title |
|---|
| LUTZ KINDERMANN ET AL.: ""Chemical Interactions between La-Sr-Mn-Fe-O-Based Perovskites and Yttria-Stabilized Zirconia"", 《JOURNAL OF THE AMERICAN CERAMIC SOCIETY》 * |
| S.P.SIMNER ETC.: ""Development of lanthanum ferrite SOFC cathodes"", 《JOURNAL OF POWER SOURCES》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108134100A (zh) * | 2017-12-28 | 2018-06-08 | 成都新柯力化工科技有限公司 | 一种铁酸镧/镍酸镧系燃料电池膜电极材料及其制备方法 |
| CN108134100B (zh) * | 2017-12-28 | 2020-06-23 | 成都新柯力化工科技有限公司 | 一种铁酸镧/镍酸镧燃料电池膜电极材料及其制备方法 |
| CN113330613A (zh) * | 2019-01-30 | 2021-08-31 | 日本碍子株式会社 | 电化学电池 |
| CN113330613B (zh) * | 2019-01-30 | 2024-02-02 | 日本碍子株式会社 | 电化学电池 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110229794A1 (en) | 2011-09-22 |
| EP2183806A1 (en) | 2010-05-12 |
| TW200926486A (en) | 2009-06-16 |
| WO2009020608A1 (en) | 2009-02-12 |
| JP2010536146A (ja) | 2010-11-25 |
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Application publication date: 20100811 |