CN101801339B - Hair shampoo composition - Google Patents
Hair shampoo composition Download PDFInfo
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- CN101801339B CN101801339B CN200880106186.1A CN200880106186A CN101801339B CN 101801339 B CN101801339 B CN 101801339B CN 200880106186 A CN200880106186 A CN 200880106186A CN 101801339 B CN101801339 B CN 101801339B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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Abstract
It is intended to provide a hair shampoo composition which contains dimethylpolysiloxane having a viscosity at 25 DEG C of 5,000,000 mm2/s or above, wherein this dimethylpolysiloxane has a high dispersion stability.
Description
Technical field
The kinematic viscosity that the present invention relates to contain in 25 ℃ is 5,000,000 mm
2The hair shampoo composition of the dimethyl polysiloxane that/s is above at length relates to the excellent hair shampoo composition of dispersion stabilization of this dimethyl polysiloxane.
Background technology
As the technology of stably mixing silicone oil in the hair cosmetic composition, propose to have and with the technology of suspension, pearling agent, glucosan derivative.Yet the kinematic viscosity that mixes in 25 ℃ is 5,000,000 mm
2During the above high polymerization dimethyl polysiloxane of/s, there is the isolating problem of dimethyl polysiloxane under the high temperature in these methods.By above situation, people's expectation is the technology of the high polymerization dimethyl polysiloxane of dispersing and mixing stably.Also have, be exemplified below as the known technology relevant with the present invention.
Patent documentation 1: Japanese Patent Laid is opened clear 62-77311 communique
Patent documentation 2: japanese patent laid-open 4-182417 communique
Patent documentation 3: japanese patent laid-open 5-262625 communique
Patent documentation 4: Japanese Patent Laid is opened the 2003-95887 communique
Summary of the invention
The present invention In view of the foregoing forms, and purpose provides a kind of hair shampoo composition, and the kinematic viscosity that this hair shampoo composition contains in 25 ℃ is 5,000,000 mm
2The dimethyl polysiloxane that/s is above, the dispersion stabilization of this dimethyl polysiloxane is excellent in hair shampoo composition.
The inventor is the result of wholwe-hearted research of achieving the above object, and recognizes: through being 5,000,000 mm at the kinematic viscosity that contains in 25 ℃
2Mixed anion surfactant, amphoteric surfactant, dimethyldiallylammonium salt acrylamide copolymer and ammonium sulfate in the hair shampoo composition of the dimethyl polysiloxane that/s is above; The mass ratio that makes anion surfactant and amphoteric surfactant is specific scope; The dispersion stabilization of above-mentioned dimethyl polysiloxane is improved; Hair shampoo composition demonstrates excellent high temperature storage stability, so that accomplished the present invention.
So the present invention provides:
[1]. a kind of hair shampoo composition, contain: (A) be selected from anion surfactant 5～20 quality % of alkylsulfonate, alkyl sulfate and polyoxyethylene alkyl ether sulfate salt, amphoteric surfactant 1～20 quality %, (C) dimethyldiallylammonium salt that (B) is selected from alkyl dimethyl glycine betanin and alkylamide propyl-betaine: the mol ratio of acrylamide be 10: 90～45: 55 dimethyldiallylammonium salt acrylamide copolymer 0.01～1.0 quality %, (D) ammonium sulfate 0.01～1.0 quality % and (E) kinematic viscosity in 25 ℃ be 5,000,000 mm
2Dimethyl polysiloxane 0.05～1.5 quality % that/s is above, the mass ratio of representing with the composition of (A) composition/(B) is 1～5.
[2]. the hair shampoo composition of [1] record, the mass ratio of representing with the composition of (D) composition/(C) is 0.5～1.5.
Also have, the present invention provides the decentralized stabilization method of above-mentioned (E) composition in a kind of hair shampoo composition, it is characterized in that, the kinematic viscosity in containing (E) 25 ℃ is 5,000,000 mm
2Mix (A) anion surfactant, (B) amphoteric surfactant, (C) dimethyldiallylammonium salt acrylamide copolymer and (D) ammonium sulfate and to make the mass ratio of representing with the composition of (A) composition/(B) be 1～5 in the hair shampoo composition of the dimethyl polysiloxane that/s is above.
According to the present invention, can be 5,000,000 mm at the kinematic viscosity that contains in 25 ℃
2Seek the dispersion stabilization of above-mentioned dimethyl polysiloxane in the hair cosmetic composition of the dimethyl polysiloxane that/s is above.
The specific embodiment
Hair shampoo composition of the present invention contain (A) anion surfactant, (B) amphoteric surfactant, (C) dimethyldiallylammonium salt acrylamide copolymer, (D) ammonium sulfate and (E) kinematic viscosity in 25 ℃ be 5,000,000 mm
2The dimethyl polysiloxane that/s is above, the mass ratio of representing with the composition of (A) composition/(B) is 1～5.
(A) anion surfactant be so long as can be used for hair shampoo composition, do not have especially to limit, and can use a kind separately, or appropriate combination used more than 2 kinds.As anion surfactant, alkylsulfonate, alkyl sulfate, acylated amino salt, polyoxyethylene alkyl ether sulfate salt, alkylbenzenesulfonate, N-acyl group-N methyl taurine salt, alpha-alkene sulfonate, higher fatty acids sulfonated ester, alkyl ether acetate, polyoxyethylene alkyl ether acetate, fatty acid soaps, alkyl phosphate salt, N-lauroyl glutamate, N-palmityl glutamate, Glu, N-lauroyl-Ethylglycocoll salt, N-lauroyl sarcosine salt, N-myristoyl-Beta-alanine salt etc. are arranged for example.This wherein, alkylsulfonate, polyoxyethylene alkyl ether sulfate salt are desirable, the average addition molal quantity of suitable is polyoxyethylene (EO) is 1～5, better be that 1～3 polyoxyethylene alkyl ether sulfate salt is desirable.
(A) combined amount of composition 5～20 quality % in hair shampoo composition are desirable, and from the viewpoint as the performance of hair cleansing composition, 7～15 quality % are better.
(B) amphoteric surfactant be so long as can be used for hair shampoo composition, do not have especially to limit, and can use a kind separately, or appropriate combination used more than 2 kinds.As amphoteric surfactant, the alkyl betaine that alkyl dimethyl glycine betanin etc. is arranged for example is that the amide betaine of activating agent, alkylamide propyl-betaine etc. is that activating agent, sulfobetaines are that activating agent, hydroxyl sulfo betaine are that activating agent, amide sulfo betaine are that activating agent, phospho betanin are that activating agent, imidazoles (imidazolium) betanin are that activating agent, alanine are that activating agent, aminoacid are activating agent etc.This wherein, the alkyl dimethyl glycine betanin of the alkylamide propyl-betaine of lauric amide CAB, fatty acid distribution of coconut oil amido propyl betaine etc., lauryl dimethyl glycine betanin etc. is desirable.
(B) combined amount of composition 1～20 quality % in hair shampoo composition is desirable, and that better is 3～10 quality %.(B) the combined amount less than 1 quality % of composition, then the dispersion stabilization effect of the high polymerization dimethyl polysiloxane of (E) composition possibly become insufficient, mixes to surpass 20 quality %, works the deterioration of steeping oneself-meeting sometimes.
Among the present invention, the mass ratio of representing with the composition of (A) composition/(B) is 1～5,1.5～3.5 ideals.This ratio less than 1 or surpass at 5 o'clock can not get the dispersion stabilization effect of the high polymerization dimethyl polysiloxane of (E) composition.
(C) dimethyldiallylammonium salt acrylamide copolymer is the copolymer of dimethyldiallylammonium salt and acrylamide; Can use a kind separately; Or appropriate combination is used more than 2 kinds, it is desirable to dimethyl diallyl ammonium chloride acrylamide copolymer (CTFA:Polyquaternium-7).Dimethyldiallylammonium salt in the copolymer: the mol ratio of acrylamide it is desirable to 10: 90～40: 60,15: 85～35: 65 scope that better is.
(C) weight average molecular weight of composition it is desirable to 150,000～4,000,000, and better is 1,100,000～3,000,000, further it is desirable to 2,000,000～3,000,000.Also have, weight average molecular weight is measured with gel permeation chromatography/multiple angle laser light scattering detector (GPC-MALLS), and condition is following.Mobile phase: 0.3M NaClO
4, NaN
3Aqueous column: TSKgel α-M2 props up, pre-column (guard column): TSK guard column α.
Also have, (C) of the present invention composition only also can use the powder dissolution of copolymer or be dispersed in the solution of solvent (water, alcohol, polyhydric alcohol etc.).
(C) the commercially available article of dimethyl diallyl ammonium chloride acrylamide copolymer have カ ヤ Network リ Le レ ジ Application M-50A (trade name, Nippon Kayaku K. K) for example; Dimethyl diallyl ammonium chloride: acrylamide, be designated hereinafter simply as DADMAC: AcAm=19: 81 (mol ratios), weight average molecular weight 1,800,000, マ one コ one ト 550 (trade names; Na Le コ ジ ヤ パ Application Co., Ltd.), DADMAC: AcAm=30: 70 (mol ratios), weight average molecular weight 1,600,000, マ one コ one ト S (trade name, Na Le コ ジ ヤ パ Application Co., Ltd.); DADMAC: AcAm=30: 70 (mol ratios), weight average molecular weight 2,600,000, サ Le ケ ア SC11 (trade name, チ バ ス ペ シ ヤ Le テ イ ケ ミ カ Le ズ Co., Ltd.); DADMAC: AcAm=30: 70 (mol ratios), weight average molecular weight 1,500,000, サ Le ケ ア SC10 (trade name, チ バ ス ペ シ ヤ Le テ イ ケ ミ カ Le ズ Co., Ltd.); DADMAC: AcAm=45: 55 (mol ratios), weight average molecular weight 1,000,000, サ Le ケ ア Super7 (trade name; チ バ ス ペ ジ ヤ Le テ イ ケ ミ カ Le ズ Co., Ltd.): DADMAC: AcAm=25: 75 (mol ratios), weight average molecular weight 150,000, マ one コ one ト 2200 (trade name, Na Le コ ジ ヤ パ Application Co., Ltd.): DADMAC: AcAm=30: 70 (mol ratios), weight average molecular weight 900,000 etc.
(C) combined amount of composition 0.01～1.0 quality % in hair shampoo composition is desirable, and that better is 0.03～0.8 quality %, further it is desirable to 0.03～0.5 quality %.Less than 0.01 quality %, then the dispersion stabilization effect of the high polymerization dimethyl polysiloxane of (E) composition possibly become insufficient, surpasses 1.0 quality %, washes the hair aftersensation sometimes and is clamminess.
(D) composition is an ammonium sulfate.Also can mix the salt beyond the ammonium sulfate, for example can be selected from by Na
+, K
+, NH
4+Deng cation and Cl
-, SO
4 2-, CO
3 2-, PO
4 3-Deng the ammonium sulfate that forms of anion beyond the combination more than a kind or 2 kinds of inorganic salt use.
(D) combined amount of composition 0.01～1.0 quality % in hair shampoo composition is desirable, and that better is 0.03～0.5 quality %, further it is desirable to 0.2～0.4 quality %.Less than 0.01 quality % or when surpassing 1.0 quality %, (E) the dispersion stabilization effect of the high polymerization dimethyl polysiloxane of composition possibly become insufficient.
Also have; Among the present invention; When mixing (C) dimethyldiallylammonium salt acrylamide copolymer, it is desirable to use the dispersion liquid that in the aqueous solution of the water-soluble inorganic salt of sodium sulfate, sodium chloride, ammonium sulfate etc., disperses (C) dimethyldiallylammonium salt acrylamide copolymer to form in advance, promptly contain the dispersion liquid of the water-soluble inorganic salt of dimethyldiallylammonium salt acrylamide copolymer.This wherein, the dispersion liquid of ammonium sulfate that contains dimethyldiallylammonium salt acrylamide copolymer is desirable especially.Through mixing this dispersion liquid, can mix above-mentioned (C) composition and (D) composition.In addition, also can in containing other blending constituents of ammonium sulfate, use the dispersion liquid that disperses (C) dimethyldiallylammonium salt acrylamide copolymer to form in advance.
The concentration of the water-soluble inorganic salt in the dispersion liquid of the above-mentioned water-soluble inorganic salt that contains dimethyldiallylammonium salt acrylamide copolymer it is desirable to 5～35 quality %, and that better is 10～30 quality %, further it is desirable to 15～25 quality %.More than 35 quality %, salt may be separated out in low temperature.
In addition, the concentration of the dimethyldiallylammonium salt acrylamide copolymer in the dispersion liquid of the above-mentioned water-soluble inorganic salt that contains dimethyldiallylammonium salt acrylamide copolymer it is desirable to 10～40 quality %, and that better is 15～35 quality %.Less than 10 quality % are difficult to become dispersion liquid sometimes, surpass 40 quality %, and then viscosity rises sometimes, are difficult to operation.
When using above-mentioned dispersion liquid; Following hair shampoo composition can be provided, its contain (A) anion surfactant, (B) amphoteric surfactant, (F) contain dimethyldiallylammonium salt acrylamide copolymer ammonium sulfate dispersion liquid and (E) kinematic viscosity in 25 ℃ be 5,000,000 mm
2The dimethyl polysiloxane that/s is above, the mass ratio of representing with the composition of (A) composition/(B) is 1～5.At this moment, (F) combined amount of composition suitably is mixed into above-mentioned (C) composition and (D) amount of the suitable combined amount of composition.
Among the present invention, the mass ratio of representing with the composition of (D) composition/(C) it is desirable to 0.5～1.5 scope, and better is 0.8～1.3.This ratio less than 0.5 or surpass at 1.5 o'clock, (E) the dispersion stabilization effect of the high polymerization dimethyl polysiloxane of composition possibly become insufficient.
Dimethyl polysiloxane is that the kinematic viscosity in (E) 25 ℃ is 5,000,000 mm
2The dimethyl polysiloxane that/s is above comprises the dimethyl polysiloxane that trimethyl silyl is terminal, and the dimethyl polysiloxane that silanol group is terminal etc. can use a kind or appropriate combination to use more than 2 kinds separately.Dimethyl polysiloxane both can be that oil also can be latex, and emulsifying agent in the latexization or emulsification method are not had special qualification.Also have, other polysiloxane compound such as low viscous dimethyl polysiloxane, cyclic polysiloxanes, EO modified polyorganosiloxane, amino modified polysiloxane etc. can suit, also use in right amount in the scope of not damaging effect of the present invention.
As (E) composition, the kinematic viscosity that it is desirable in 25 ℃ is 8,000,000 mm
2More than/the s.The upper limit of kinematic viscosity does not have special qualification, is 3,000 ten thousand mm
2/ s.The assay method of kinematic viscosity is following: make the toluene solution of the dimethyl polysiloxane of 1g/100mL concentration, try to achieve specific viscosity η sp (25 ℃) according to following formula (1).In the relational expression of Huggins shown in the following formula of substitution (2), try to achieve intrinsic viscosity [η] then.The Huggins constant adopts and tries to gain the field, daily use chemicals, 77588 [1956] are put down in writing.Then, with the formula of the A.Kolorlov shown in the following formula of [η] substitution (3), try to achieve molecular weight M.At last, with the formula of the A.J.Barry shown in the following formula of M substitution (4), try to achieve the viscosities il of dimethyl polysiloxane.
η sp=(η/η 0)-1 is the viscosity, the viscosity (1) of η=solution of η 0=toluene wherein
η sp=[η]+K ' [η]
2K ': Huggins constant (2)
[η]=0.215 * 10
-4M
0.65M: molecular weight (3)
Logη＝1.00+0.0123M
0.5 (4)
Above-mentioned η 0, η measure according to cosmetic material benchmark ordinary test method viscosimetry the 1st method.
(E) combined amount of composition it is desirable to 0.01～2.0 quality % in hair shampoo composition, and that better is 0.05～1.5 quality %.Combined amount less than 0.01 quality %, the effect of the finger comb property of raising hair and smoothness is insufficient after possibly cleaning, and surpasses 2.0 quality %, and then hair possibly become oil, be clamminess.
Can in the scope of not damaging effect of the present invention, suit, also use in right amount composition arbitrarily in the hair shampoo composition of the present invention.Composition arbitrarily; Can add the antioxidant, 2 of non-ionic surface active agent, semi-polarity surfactant, cationic surfactant, anionic property polymer, nonionic polymer, polyalcohols, organic salt, wetting agent, hair care agent, solubilizing agent, BHT or alpha-tocopherol etc. arbitrarily; The scalp of the viscosity modifier of the antibacterial of 4,4 '-three chloro-2 '-dihydroxy diphenyl ethers, triclocarban etc., fatty monoethanol amide, fatty diglycollic amide etc., UV absorbent, antioxidant, protein derivatives, animals and plants extracting solution, octopirox, ZPT etc. prevents pearly-lustre agent, opacifiers, hydrotropic agent, lower alcohol, vitamins, ethereal oil composition, hydrophobic solvent, dilution property solvent, pigment, spice of pH regulator agent, ethylene glycol bisthioglycolate fatty acid ester of antiseptic, citric acid, triethanolamine of antiinflammatory, benzoic acid and salt thereof, p-Hydroxybenzoate, Kazon CG of agent, glycyrrhizic acid dipotassium etc. etc. etc. etc. etc.
Flavor compositions does not have special qualification, opens the spice A of record in 2006-63044 communique [table 5]～[table 10], spice B, spice C, spice D etc. as Japanese Patent Laid is arranged for example.The related flavor compositions of hair shampoo composition of the present invention can mix 0.005～40 quality % in the hair shampoo composition kind, it is desirable to mix 0.01～10 quality %.
Hair shampoo composition of the present invention can make shampoo or clean shampoo and use, and can modulate according to well-established law.For example, can mix must composition, composition and water (nubbin) obtain arbitrarily.The ammonium sulfate dispersion liquid that in addition, can mix (A), (B), (E) composition and contain dimethyldiallylammonium salt acrylamide copolymer obtains.
The pH of hair shampoo composition of the present invention (25 ℃) it is desirable to pH3～7, it is desirable to 4～6.Not enough pH3, then worrying has stimulation to skin, surpasses 7, and efficiency of preservation reduces, and microorganism may be bred.Also have, pH measures according to cosmetic material benchmark ordinary test method viscosimetry.
The viscosity of hair shampoo composition of the present invention (25 ℃) it is desirable to the scope of 1000mPas～6000mPas.Not enough 1000mPas overflows from hands during use, therefore is difficult to use, and surpasses 6000mPas, possibly degenerate from the extrudability meeting of container.Also have, viscosity is measured according to cosmetic material benchmark ordinary test method viscosimetry the 2nd method.
The container of hair shampoo composition of the present invention does not have special qualification; Have for example outside the pipe of aluminum laminated tube, EVAL pipe, aluminum pipe, glass vapor deposition plastics etc., utilize dispenser and squeeze receptacle, laminated film container, suction hose container, lever (stick) container, bottle container of mechanicalness or differential pressure etc. in addition.The laminated film of aluminum laminated tube has the multilamellar more than 2 layers usually, and its material is by the synthetic resin of polyethylene, PETG, polyester, biaxial stretched polypropylene, no extended polypropylene, polyacrylonitrile, ethylene vinyl-acetic ester copolymer etc., paper, aluminium-vapour deposition plastics etc. and constitute.Consider intensity, flexibility, against weather etc., use 2～5 layers material usually.As the material of bottle, can or make up more than 2 layers and use monolayer such as polyethylene, polypropylene, PETG, polystyrene, polrvinyl chloride, ethylene-vinyl alcohol resin, AS resin acrylonitrile styrene resin, ABS resin, polyamide etc. and glass.
According to the present invention, be 5,000,000 mm through the kinematic viscosity in containing (E) 25 ℃
2Mix (A) anion surfactant, (B) amphoteric surfactant, (C) dimethyldiallylammonium salt acrylamide copolymer and (D) ammonium sulfate and to make the mass ratio of representing with the composition of (A) composition/(B) be 1～5 in the hair shampoo composition of the dimethyl polysiloxane that/s is above; Can make the decentralized stabilization of above-mentioned (E) composition in the hair shampoo composition, demonstrate the high temperature storage stability of the excellence of hair shampoo composition.
Embodiment
Below, show that embodiment and comparative example specify the present invention, but the present invention is not limited to following embodiment.Also have, when in following example, not specializing, " % " of composition expression quality %, ratio is represented mass ratio.
[embodiment 1～28, comparative example 1～10]
One-tenth shown in the mixture table 1～6 assigns to modulate hair shampoo composition, carries out following evaluation.The result records and narrates in table in the lump.The amount of each composition in the table only otherwise show that especially just be meant the amount that is converted into pure composition, the amount of copolymer A～G is the amount of copolymer.Also have, the kinematic viscosity of the hair shampoo composition of embodiment and comparative example in 25 ℃ is 1000mPas～5000mPas, and pH is 4.5～6.0.
< dispersion stabilization of high polymerization dimethyl polysiloxane >
Modulated hair shampoo composition is filled into attaching in the scale Clear glass bottles and jars of 100mL, the liquid appearance after visualization preservation 1 month or 3 months thermostatic chambers of 50 ℃ are interior.From the scale of Clear glass bottles and jars according to following benchmark evaluation.
Benchmark
◎: do not have the separation of high polymerization dimethyl polysiloxane
Zero: the separating degree of high polymerization dimethyl polysiloxane (volume of whole liquid is 100 o'clock, is in isolating volumetrical ratio) less than 5 volume %
△: the separating degree of high polymerization dimethyl polysiloxane more than 5 volume %～less than 20 volume %
*: the separating degree of high polymerization dimethyl polysiloxane is more than 20 volume %
[table 1]
*: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
[table 2]
*: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
[table 3]
*: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
[table 4]
*1: (C) composition 20% (D) composition 20%
*2: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
[table 5]
*: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
[table 6]
*1: (C) composition 20% (D) composition 20%
*2: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
[embodiment 29]
Make the shampoo of following composition according to well-established law.Only otherwise special record, combined amount is the pure minute a great deal of (below identical) of composition.
[table 7]
Form %
POE (2) sodium laureth sulfate 12.5
Lauric amide CAB 7.0
The dispersion liquid 1.5 that contains the ammonium sulfate of dimethyl diallyl ammonium chloride acrylamide copolymer
(in the dispersion liquid
Dimethyl diallyl ammonium chloride acrylamide copolymer amount 0.3
Volume of ammonium sulfate 0.3
Purified Water 0.9)
Dimethyl polysiloxane A (latex)
*1 1.7
(0.15)
Lauric acid polyglycerin ester 3.0
JR-125 0.3
1,3 butylene glycol 3.0
POE (20) hardened castor oil 0.3
Diglycol stearate 1.5
Spice C 0.5
Sorbitol 1.0
Citric acid 0.4
The Purified Water balance
Add up to 100.0
*1: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
pH?5.0
Viscosity (25 ℃) 4500mPas
The sense of outward appearance pearly-lustre
(A)/(B)＝1.8、(D)/(C)＝1.0
[embodiment 30]
Make the shampoo of following composition according to well-established law.
[table 8]
Form %
POE (2) sodium laureth sulfate 10.0
Lauric amide CAB 10.0
Dimethyl diallyl ammonium chloride acrylamide copolymer A 0.2
Ammonium sulfate 0.15
Sodium sulfate 0.03
Dimethyl polysiloxane A (latex)
*1 2.0
(0.18)
Poise C-80M 0.1
Diglycol stearate 2.0
Methacryl ethyl betanin methacrylate copolymer 0.2
(ユ カ Off オ one マ one 204WL)
Polyoxyethylene lauric monoethanolamide (2E.O.) 2.0
Spice D 0.5
POE (20) hardened castor oil 1.6
Sorbitol 2.0
Citric acid 0.5
The Purified Water balance
Add up to 100.0
*1: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
pH?4.8
Viscosity (25 ℃) 3500mPas
The sense of outward appearance pearly-lustre
(A)/(B)＝1.0、(D)/(C)＝0.75
[embodiment 31]
Make the shampoo of following composition according to well-established law.
[table 9]
Form %
POE (2) sodium laureth sulfate 12.5
Lauric amide CAB 4.5
The dispersion liquid 0.25 that contains the ammonium sulfate of dimethyl diallyl ammonium chloride acrylamide copolymer
(in the dispersion liquid
Dimethyl diallyl ammonium chloride acrylamide copolymer amount 0.05
Volume of ammonium sulfate 0.05
Purified Water 0.15)
Dimethyl polysiloxane A (latex)
*1 1.7
(0.15)
Lauryl dimethyl amine oxide 0.5
Stearyl trimethyl ammonium chloride 0.5
Methacryl ethyl betanin methacrylate copolymer 0.2
POE (2) lauric monoethanolamide 1.0
Spice A 0.5
POE (20) hardened castor oil 1.6
Methacryl ethyl-trimethyl salmiac N-(2-ethoxy) acrylamide copolymer 0.5
Hydrolyzed-silk (silk) liquid 0.1
Sargassum extract (5) 0.1
Blue No. 1 0.0001
Yellow No. 203 0.0001
Citric acid 0.5
Sodium benzoate 0.68
The Purified Water balance
Add up to 100.0
*1: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
pH 5.2
Viscosity (25 ℃) 3500mPas
The milkiness shape
(A)/(B)＝2.8、(D)/(C)＝1.0
[embodiment 32]
[table 10]
Form %
POE (2) sodium laureth sulfate 9.5
Lauric amide CAB 6.0
The dispersion liquid 0.5 that contains the ammonium sulfate of dimethyl diallyl ammonium chloride acrylamide copolymer
(in the dispersion liquid
Dimethyl diallyl ammonium chloride acrylamide copolymer amount 0.1
Volume of ammonium sulfate 0.1
Purified Water 0.3)
Dimethyl polysiloxane A (latex)
*1 1.7
(0.15)
Isoamyl dimerization methyl polysiloxane latex 0.2
Vinyl-acetic ester vinylpyrrolidone copolymer 0.25
Lauryl dimethyl amine oxide 0.2
Stearyl trimethyl ammonium chloride 2 0.5
Octopirox 0.5
POE (2) lauric monoethanolamide 1.0
Spice B 0.5
POE (20) hardened castor oil 1.6
Methacryl ethyl-trimethyl salmiac N-(2-ethoxy) acrylamide copolymer 0.5
Hydrolyzed soybean protein 0.1
Radix Glycyrrhizae is extracted end (5) 0.001
Red No. 106 0.0001
Yellow No. 203 0.001
Citric acid 0.5
Sodium benzoate 0.7
The Purified Water balance
Add up to 100.0
*1: be that kinematic viscosity is 5,000,000 mm in ()
2The content of the dimethyl polysiloxane that/s is above
pH?5.2
Viscosity 4500mPas
The milkiness shape
(A)/(B)＝1.6、(D)/(C)＝1.0
The dispersion stabilization of the high polymerization dimethyl polysiloxane of synthetic shampoo composite is all excellent among the embodiment 29～32.
The raw material that uses among the embodiment is as follows.
[table 11]
| The raw material name | Trade name | Manufacturer name |
| POE (2) sodium laureth sulfate | シノリンSPE-1250 | New Japan Chem Co., Ltd |
| POE (1) sodium laureth sulfate | シノリンSPE-1150 | New Japan Chem Co., Ltd |
| Four decene sodium sulfonates | Four decene sodium sulfonates | Lion Corporation |
| The lauric amide CAB | エ Na ジ コ one Le L30B | Lion Corporation |
| Lauryl dimethyl glycine betanin | オバゾリンLB-SF | Toho Chemical Industry Co., Ltd. (JP) Tokyo-To, Japan |
| Dimethyldiallylammonium salt acrylamide copolymer A | カ ヤ Network リ Le レ ヅ Application M-50A (aqueous) DADMAC: AcAm=19: 81 (mol ratio) weight average molecular weight 1,800,000 | Nippon Kayaku K. K |
| Dimethyldiallylammonium salt acrylamide copolymer B | マ one コ one ト 550 (aqueous) DADMAC: AcAm=30: 70 (mol ratio) weight average molecular weight 1,600,000 | Na Le コ ジ ヤ パ Application Co., Ltd. |
| Dimethyldiallylammonium salt acrylamide copolymer C | マ one コ one ト S (aqueous) DADMAC: AcAm=30: 70 (mol ratio) weight average molecular weight 2,600,000 | Na Le コ ヅ ヤ パ Application Co., Ltd. |
| Dimethyldiallylammonium salt acrylamide copolymer D | サ Le ケ ア SC11 (aqueous) DADMAC: AcAm=30: 70 (mol ratio) weight average molecular weight 1,500,000 | チ バ ス ペ シ ヤ Le テ イ ケ ミ カ Le ズ Co., Ltd. |
| Dimethyldiallylammonium salt acrylamide copolymer E | サ Le ケ ア SC10 (aqueous) DADMAC: AcAm=45: 55 (mol ratio) weight average molecular weight 1,000,000 | チ バ ス ペ シ ヤ Le テ イ ケ ミ カ Le ズ Co., Ltd. |
| Dimethyldiallylammonium salt acrylamide copolymer F | サ Le ケ ア Super (aqueous) DADMAC: AcAm=25: 75 (mol ratio) weight average molecular weight 150,000 | チ バ ス ペ シ ヤ Le テ イ ケ ミ カ Le ズ Co., Ltd. |
| Dimethyldiallylammonium salt acrylamide copolymer G | マ one コ one ト 2200 DADMAC: AcAm=30: 70 (mol ratio) weight average molecular weight 900,000 | Na Le コ ジ ヤ パ Application Co., Ltd. |
| The dispersion liquid that contains the ammonium sulfate of dimethyl diallyl ammonium chloride acrylamide copolymer | UltimerCG-600 DADMAC: AcAm=30: 70 (mol ratio) weight average molecular weight 2,500,000 (contain dimethyl diallyl ammonium chloride acrylamide copolymer, ammonium sulfate 20% jointly, solvent is a water) | Na Le コ ジ ヤ パ Application Co., Ltd. |
[0207][table 12]
| feedstock name | trade name | Manufacturer Name |
| ? ? ammonium sulfate | ammonium sulfate (a) | pure chemistry |
| sulfate | ? ? neutral thenardite | Japan Chemical Industry Co., Ltd. |
| sodium chloride | refining さ thou ki salt | Sanuki Salt Corporation |
| dimethylpolysiloxane A (latex) | Toray Off-ro a DMS-60 (Note 1) | - Oil Industry Co., Ltd. Fang Club |
| dimethyl polysiloxane B (latex) | KM-903 (Note 2) | Shin-Etsu Chemical Co., Ltd. |
| dimethyl polysiloxane | ji メ チ co nn gum (10 million mm 2 / s) | Toray · a ni da ウ co nn bag Treasury will Club |
| dimethyl polysiloxane mixture | ヅ メ チ co nn (6000000 mm 2 / s/30mm 2 / s) (Note 3) | Toray · ni nn double ウ co a bag Treasury will Club |
| POE (20) hydrogenated castor oil | CW-20 -90 | Aoki Oil Industrial Co., Ltd. |
| lauric acid polyglycerol ester | thermal nn ソ フ Suites M-12J | Sun Chemical |
| lauryl dimethyl amine oxide | ア ro holds an boots ku su DM12D-W | Lion Corporation |
| POE (2) lauric monoethanolamide | ? ? ア mini athlete boots Suites 2L-Y | Kawaken フ ア イ nn Kelly mini Cal shares will Club |
| stearyl trimethyl ammonium chloride | ア a Cal a cloth T800 | Lion Corporation |
| methacryloyl ethyl trimethyl chloride ammonium · N-(2 - hydroxyethyl) acrylamide copolymer | Die ya su re a black C-801 | Mitsubishi Chemical Corporation |
| isoprene poly methyl polysiloxane (ア holds an ヅ メ チ co nn) Latex (aminoethyl aminopropyl siloxane · dimethylsiloxane alkyl copolymer) | SM8904 | Toray double ウ co a bag Corporation ni nn |
| methacryloyl ethyl betaine · A acrylate copolymer | uni grades フ Io a ma a 204WL | Mitsubishi Science Co., Ltd. |
| vinyl acetate, vinyl pyrrolidone copolymer | PVP / VA | ISP ji ya pal nn Corporation |
| cationic guar gum | ji Oh yeah ku ga a Daicel | ro a terrestrial イ ア ji ya pal nn Corporation |
| distearate B glycol ester | ge pts an inner Hikaru PMS | ku ra ri ji ya Suites Ann Parker nn shares will be? ? Club |
| sodium benzoate | Sodium? Benzoate | BFGGoodrich? Kalama? inc. |
| citrate | Kelly Shin ョ ウ black boots thermal Oh nn nn L | Fuso Chemical Industry Co., Ltd. |
| hydrolyzed silk (silk) liquid | Shin Hikaru ku ge nn G ソ Hikaru bulldog | - Pills フ ア Hikaru co su Corporation |
| seaweed extract (5) | ピ pts uni ア Hikaru フ I ra F? AR | Corporation albino |
| hydrolyzed soy protein | pu ro holds an イ su WS | into Kasei Co., Ltd. |
| spices A ~ D | Japanese Patent Laid-open Publication No. 2006-63044 remember set of spices A ~ D | ? |
(annotating 1) contained 1,000 ten thousand mm in latex
2The dimethyl polysiloxane 9% of/s, 4,000,000 mm
2The dimethyl polysiloxane 9% of/s and 1,000 ten thousand mm
2The dimethyl polysiloxane 42% of/s.Combined amount in embodiment and the comparative example representes to comprise the total amount of the latex of water etc.
(annotating 2) contained 2,000 ten thousand mm in latex
2The dimethyl polysiloxane 18% of/s and 2,000,000 mm
2The dimethyl polysiloxane 42% of/s.Combined amount in embodiment and the comparative example representes to comprise the total amount of the latex of water etc.
(annotating 3) 6,000,000 mm
2Dimethyl polysiloxane 9.5% and the 30mm of/s
2The mixture of the dimethyl polysiloxane 90.5% of/s.Combined amount among the embodiment is represented the total amount of dimethyl polysiloxane.
Claims (6)
1. hair shampoo composition, contain anion surfactant 5～20 quality % that (A) be selected from alkylsulfonate, alkyl sulfate and polyoxyethylene alkyl ether sulfate salt, amphoteric surfactant 1～20 quality %, (C) dimethyldiallylammonium salt that (B) is selected from alkyl dimethyl glycine betanin and alkylamide propyl-betaine: the mol ratio of acrylamide be 10: 90～45: 55 dimethyldiallylammonium salt acrylamide copolymer 0.01～1.0 quality %, (D) ammonium sulfate 0.01～1.0 quality % and (E) kinematic viscosity in 25 ℃ be 5,000,000 mm
2Dimethyl polysiloxane 0.05～1.5 quality % that/s is above, the mass ratio of representing with the composition of (A) composition/(B) is 1～5.
2. the hair shampoo composition of claim 1 record, the mass ratio of representing with the composition of (D) composition/(C) is 0.5～1.5.
3. like the hair shampoo composition of claim 1 or 2 records, (C) in the copolymer of composition, dimethyldiallylammonium salt: the mol ratio of acrylamide is in 10: 90～40: 60 scope.
4. like the hair shampoo composition of claim 1 or 2 records, (C) weight average molecular weight of the copolymer of composition is 150,000～4,000,000.
5. like the hair shampoo composition of claim 1 or 2 records, wherein, (B) combined amount of composition is 3～10 quality %.
6. method of making hair shampoo composition, said hair shampoo composition are the hair shampoo compositions of claim 1 record, and said method comprises:
Preparation contains (D) ammonium sulfate dispersion liquid of (C) dimethyldiallylammonium salt/acrylamide copolymer,
With following (A), (B), (E) composition and above-mentioned dispersion liquid-phase mixing,
(A) kinematic viscosity in 25 ℃ of the anion surfactants, (B) amphoteric surfactant, (E) is 5,000,000mm
2The dimethyl polysiloxane that/s is above.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007199281 | 2007-07-31 | ||
| JP2007-199281 | 2007-07-31 | ||
| PCT/JP2008/061826 WO2009016905A1 (en) | 2007-07-31 | 2008-06-30 | Hair shampoo composition |
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| Publication Number | Publication Date |
|---|---|
| CN101801339A CN101801339A (en) | 2010-08-11 |
| CN101801339B true CN101801339B (en) | 2012-12-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880106186.1A Active CN101801339B (en) | 2007-07-31 | 2008-06-30 | Hair shampoo composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5278322B2 (en) |
| KR (1) | KR101411803B1 (en) |
| CN (1) | CN101801339B (en) |
| HK (1) | HK1142531A1 (en) |
| WO (1) | WO2009016905A1 (en) |
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| JP5632392B2 (en) | 2009-12-18 | 2014-11-26 | ライオン株式会社 | Detergent composition and method for separating and stabilizing dimethylpolysiloxane |
| KR101685343B1 (en) | 2010-06-01 | 2016-12-12 | 엘지전자 주식회사 | Image Display Device and Operating Method for the Same |
| JP5740859B2 (en) * | 2010-07-15 | 2015-07-01 | ライオン株式会社 | Hair cleaning composition |
| WO2013089059A1 (en) * | 2011-12-12 | 2013-06-20 | ライオン株式会社 | Hair cleansing agent composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1708286A (en) * | 2002-11-04 | 2005-12-14 | 宝洁公司 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase with improved stability |
| JP2007070469A (en) * | 2005-09-07 | 2007-03-22 | Lion Corp | Cleaner composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3436821B2 (en) * | 1994-03-24 | 2003-08-18 | 花王株式会社 | Hair cosmetics |
| JP2002193789A (en) * | 2000-12-26 | 2002-07-10 | Lion Corp | Cleansing agent composition |
| JP4853602B2 (en) * | 2001-08-31 | 2012-01-11 | ライオン株式会社 | Whitening agent-containing cosmetics |
| JP2003095887A (en) * | 2001-09-27 | 2003-04-03 | Lion Corp | Hair cleanser composition |
| US20060127345A1 (en) * | 2004-12-10 | 2006-06-15 | Hilvert Jennifer E | Conditioning shampoo containing stabilized silicone particles |
-
2008
- 2008-06-30 JP JP2009525310A patent/JP5278322B2/en active Active
- 2008-06-30 CN CN200880106186.1A patent/CN101801339B/en active Active
- 2008-06-30 KR KR1020107004020A patent/KR101411803B1/en active IP Right Grant
- 2008-06-30 WO PCT/JP2008/061826 patent/WO2009016905A1/en active Application Filing
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1708286A (en) * | 2002-11-04 | 2005-12-14 | 宝洁公司 | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase with improved stability |
| JP2007070469A (en) * | 2005-09-07 | 2007-03-22 | Lion Corp | Cleaner composition |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009016905A1 (en) | 2009-02-05 |
| KR20100051825A (en) | 2010-05-18 |
| JPWO2009016905A1 (en) | 2010-10-14 |
| JP5278322B2 (en) | 2013-09-04 |
| CN101801339A (en) | 2010-08-11 |
| KR101411803B1 (en) | 2014-06-24 |
| HK1142531A1 (en) | 2010-12-10 |
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