CN101796959A - Insecticidal composition containing clothianidin and indoxacarb - Google Patents
Insecticidal composition containing clothianidin and indoxacarb Download PDFInfo
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- CN101796959A CN101796959A CN201010148296A CN201010148296A CN101796959A CN 101796959 A CN101796959 A CN 101796959A CN 201010148296 A CN201010148296 A CN 201010148296A CN 201010148296 A CN201010148296 A CN 201010148296A CN 101796959 A CN101796959 A CN 101796959A
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- indenes
- worm prestige
- prestige
- clothianidin
- indenes worm
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Abstract
The invention relates to an insecticidal composition containing clothianidin and indoxacarb, which is characterized in that effective active ingredients which are the clothianidin and the indoxacarb have the mixture ratio of 1-80:80-1. The insecticidal composition has the advantages that after the clothianidin is compounded with the indoxacarb, the insecticidal composition has remarkable synergia and continuous control effect, expends the insecticidal spectrum, and is higher in the activity for cotton bollworm, cnaphalocrocis medialis, rice planthopper, cabbage caterpillar, plutella xylostella and cabbage beet armyworm; furthermore, the insecticidal composition reduces the pesticide using quantity and the pesticide residual quantity on the crops, relieves the environmental pollution, is safe for people and livestock and good in environmental compatibility, and leads pests not to easily generate drug resistance.
Description
Technical field
The invention belongs to agricultural technology field, relate to the Pesticidal combination that a kind of effective active composition is made up of thiophene worm amine and indenes worm prestige.
Background technology
Thiophene worm amine, English common name clothianidin, molecular formula is C
6H
8ClN
5O
2S, chemical name (E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-2-nitroguanidine.
Thiophene worm amine carries out the world market exploitation jointly by Beyer Co., Ltd and Japanese Takeda Wu Tian company.This kind is used for paddy rice, fruit tree, tealeaves, turf and ornamental crops in Japan.Thiophene worm amine (clothianidin) is that Wu Tian company is after Nitenpyram (nitenpyram), another nicotinic insecticide of finding, belong to the second generation, compare with the nitenpyram of the first generation, the main difference of its molecular structure is: the one, replaced the pyridine group with the chloro thiazolyl group; The 2nd, replaced the Nitromethylene part with nitro-imine.Methyl on 5 has improved the activity of thorn being inhaled insect. and 2 one chlorine, one 5 one thiazolyl heterocycles then produce higher effect to the biting mouth parts insect.Thiophene worm amine is wide spectrum, systemic insecticide, is mainly used in paddy rice, vegetables, fruit tree and other crop, control Semiptera, coleoptera, diptera and some lepidoptera pest.
Indenes worm prestige, English common name indoxacarb, molecular formula is C
22H
17ClF
3N
3O
7, chemical name is a 7-chloro-2,3,4a, 5-tetrahydrochysene-2-[methoxycarbonyl (4-Trifluoromethoxyphen-l) carbamoyl] and indeno [1,2-e] [1,3,4-] oxadiazines-4a-carboxylate methyl ester.
Indenes worm prestige mainly is the sodium channel in the blocking-up insect nerve cell, causes target pest to coordinate poor, paralysis, and is final dead.Medicament enters polypide by tagging and ingesting, and the behavior of insect changes rapidly, causes insect to stop rapidly ingesting, thus fabulous protection the target crop.Test shows with other insecticide not have cross resistance.
In the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.Important insect such as lepidoptera pest are because its breeding cycle is short, and breeding amount is big, and mobility is little on the agricultural, and selfing degree height is easy to generate resistance especially.
Go up the insect that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But, the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than insect.Other method such as crop allocation adjustment, different agricultural chemicals are rotated etc., in the process of practical operation, are difficult to really play obvious effects.
The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor research, find thiophene worm amine and indenes worm prestige can produce good synergistic effect after composite, and still unexposed about the composite relevant report of thiophene worm amine and indenes worm prestige.
Summary of the invention
The objective of the invention is to:, provide a kind of composite thiophene worm amine and indenes worm prestige Pesticidal combination at the practical problem of using thiophene worm amine at present separately and indenes worm prestige pest control dosage is big, cost is high, the repeated use insect easily produces resistance.
The object of the present invention is achieved like this: the Pesticidal combination of a kind of clothianidin-containing and indenes worm prestige comprises effective active component, auxiliary agent and fills out agent that the weight proportion of effective active composition thiophene worm amine and indenes worm prestige is 1～80: 80～1.
The Pesticidal combination of described clothianidin-containing and indenes worm prestige, the percentage by weight of thiophene worm amine and indenes worm prestige is 5～50: 50～5.
The Pesticidal combination of described clothianidin-containing and indenes worm prestige, the percentage by weight of thiophene worm amine and indenes worm prestige is 10～20: 20～10.
Described clothianidin-containing and indenes worm prestige Pesticidal combination, the optimum activity proportioning of thiophene worm amine and indenes worm prestige is 10: 1～1: 10.
The Pesticidal combination of described clothianidin-containing and indenes worm prestige adds conventional auxiliary agent by technology well-known in the art, can be made into wetting powder, water dispersible granules, suspending agent, microcapsule suspending agent, missible oil, aqueous emulsion, microemulsion.
The Pesticidal combination of described clothianidin-containing and indenes worm prestige is mainly used in control vegetables cabbage caterpillar, diamond-back moth, wild cabbage beet armyworm, paddy rice rice leaf roller, striped rice borer, paddy stem borer, cotton aphid, cotton bollworm.
The invention has the advantages that:
(1) thiophene worm amine and indenes worm prestige composite after, have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Application Example one
For the examination insect: pupa of wild cabbage beet armyworm and mature larva all pick up from wild cabbage ground, suburb, Xi'an, turn into adult in the solarium, and mate and oviposit grows to behind 3 instar larvaes standby on potted plant wild cabbage.
Tested medicine: agricultural chemicals Co., Ltd of U.S. nation provides by Shaanxi.
Drugs compared: 50% thiophene worm amine water dispersible granules (commercial); 30% indenes worm prestige water dispersible granules (commercial).
Experimental scheme: effective lethal concentration scope of thiophene worm amine, the two single agent of indenes worm prestige and the two different proportioning mixture is determined in the process preliminary experiment, and each medicament designs five gradient concentrations respectively by active constituent content and handles, and does contrast with the space management that does not contain former medicine.
Test method: respectively the mother liquor of thiophene worm amine, indenes worm prestige and each mixed agent is diluted to above 5 series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the of the same size fresh cabbage leaves that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then, under 25 ℃ of conditions, raise for examination 3 instar larvaes, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
Wild cabbage beet armyworm corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (with thiophene worm amine is the standard medicament, and its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=thiophene worm amine
Thiophene worm amineTI * the P of+indenes worm prestige
Indenes worm prestige
In the formula: M is the mixture of different proportionings
P
Indenes worm prestigeBe indenes worm prestige shared ratio in composition
P
Thiophene worm amineBe thiophene worm amine shared ratio in composition
Table 1 thiophene worm amine and indenes worm prestige and composite toxicity test thereof to the wild cabbage beet armyworm
As shown in Table 1, the composite co-toxicity coefficient to the wild cabbage beet armyworm of thiophene worm amine and indenes worm prestige all has the notable synergistic effect, and is the most obvious with synergistic effect in 1: 1 o'clock.So research and extension of the present invention is significant.
Application Example two
Application example one
The 80% thiophene worm amine indenes worm prestige water dispersible granules control paddy rice rice leaf roller test of pesticide effectiveness:
Add to 100g by thiophene worm amine 50g, indenes worm prestige 30g, two sodium naphthasulfonate 3g, spaonin powder 3g, urea 3g, ammonium sulfate 1g, polyethylene glycol 1g, kaolin, production technology makes 80% thiophene worm amine indenes worm prestige water dispersible granules routinely.This proportioning is by 7500 times of dilution sprayings, 72 hours control paddy rice rice leaf roller effects are 92.34%～95.7% behind the medicine, 50% thiophene worm amine water dispersible granules and 30% indenes worm prestige water dispersible granules are according to same quadrat method, dilute 8000 times and 7000 times of uses respectively, 72 hours preventive effects are respectively 78.3% and 76.1% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example two
The 50% thiophene worm amine indenes worm prestige water dispersible granules control cotton cotton bollworm test of pesticide effectiveness:
Add to 100g by thiophene worm amine 10g, indenes worm prestige 40g, neopelex 2g, sodium lignin sulfonate 0.8g, urea 1g, ammonium sulfate 10g, polyvinylpyrrolidone 0.3g, kaolin, production technology makes 50% thiophene worm amine indenes worm prestige water dispersible granules routinely.This proportioning is by 6500 times of dilution sprayings, 72 hours control cotton cotton bollworm effects are 90.31%～94.2% behind the medicine, 50% thiophene worm amine water dispersible granules and 30% indenes worm prestige water dispersible granules are according to same quadrat method, dilute 8000 times and 7000 times of uses respectively, 72 hours preventive effects are respectively 77.1% and 76.4% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example three
The 80% thiophene worm amine indenes worm prestige wetting powder control wild cabbage beet armyworm test of pesticide effectiveness:
By thiophene worm amine 30g, indenes worm prestige 50g, neopelex 4g, dispersing agent NNO 4g, draw back powder 2g, kaolin adds to 100g, production technology makes 80% thiophene worm amine indenes worm prestige wetting powder routinely.This proportioning is by 7500 times of dilution sprayings, 72 hours control wild cabbage beet armyworm effects are 91.56%～95.6% behind the medicine, 50% thiophene worm amine water dispersible granules and 30% indenes worm prestige water dispersible granules are according to same quadrat method, dilute 8000 times and 7000 times of uses respectively, 72 hours preventive effects are respectively 78.5% and 77.3% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example four
44% thiophene worm amine indenes worm prestige wetting powder is prevented and treated the rice hoppers test of pesticide effectiveness:
Add to 100g by thiophene worm amine 4g, indenes worm prestige 40g, neopelex 2g, alkylnaphthalene sulfonate formaldehyde condensation products 1g, white carbon 2g, kaolin, production technology makes 44% thiophene worm amine indenes worm prestige wetting powder routinely.This proportioning is by 5500 times of dilution sprayings, preventing and treating the rice hoppers effect in 72 hours behind the medicine is 90.95%～95.8%, 50% thiophene worm amine water dispersible granules and 30% indenes worm prestige water dispersible granules are according to same quadrat method, dilute 8000 times and 7000 times of uses respectively, 72 hours preventive effects are respectively 78.2% and 79.5% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example five
The 48% thiophene worm amine indenes worm prestige suspending agent control wild cabbage diamond-back moth test of pesticide effectiveness:
Thiophene worm amine 40g, indenes worm prestige 8g, alkyl benzene sulfonate calcium salt 4g, sodium lignin sulfonate 3g, DBSA 4g, silicone oil 0.1g, xanthan gum 0.3g, deionized water adds to 100g, the mixed 48% thiophene worm amine indenes worm prestige suspending agent that gets.This proportioning is by 4000 times of dilution sprayings, 72 hours control wild cabbage diamond-back moth effects are 92.38%～96.78% behind the medicine, 50% thiophene worm amine water dispersible granules and 30% indenes worm prestige water dispersible granules are according to same quadrat method, dilute 8000 times and 7000 times of uses respectively, 72 hours preventive effects are respectively 77.85% and 76.59% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example six
The 30% thiophene worm amine indenes worm prestige suspending agent control cabbage pieris test of pesticide effectiveness:
Thiophene worm amine 15g, indenes worm prestige 15g, polycarboxylate 4g, soapberry powder 5g, silicone compound 0.1g, hydroxyethylcellulose 0.1g, ethylene glycol 2g, deionized water add to 100g, the mixed 30% thiophene worm amine indenes worm prestige suspending agent that gets.This proportioning is by 3000 times of dilution sprayings, 72 hours control cabbage pieris effects are 93.54%～97.16% behind the medicine, 50% thiophene worm amine water dispersible granules and 30% indenes worm prestige water dispersible granules are according to same quadrat method, dilute 8000 times and 7000 times of uses respectively, 72 hours preventive effects are respectively 81.33% and 82.75% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example seven
The 48% thiophene worm amine indoxacarb aqueous emulsion control tomato Bemisia tabaci test of pesticide effectiveness:
Thiophene worm amine 8%, indenes worm prestige 40%, acetonitrile 18%, toluene 13%, farming breast 400
#4%, 600
#Phosphate 4%, propane diols 4%, polyvinyl alcohol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 48% thiophene worm amine indoxacarb aqueous emulsion.This proportioning is by 2500 times of dilution sprayings, 72 hours control tomato Bemisia tabaci effects are 94.21%～97.74% behind the medicine, 50% thiophene worm amine water dispersible granules and 20% indenes worm prestige missible oil are according to same quadrat method, dilute 8000 times and 6500 times of uses respectively, 72 hours preventive effects are respectively 80.46% and 80.12% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example eight
The 22% thiophene worm amine indoxacarb aqueous emulsion control rice-stem borer test of pesticide effectiveness:
Thiophene worm amine 20%, indenes worm prestige 2%, cyclohexanone 24%, N-pyrrolidones 8%, deionization farming breast 1600
#3%, the farming breast 500
#4%, ethylene glycol 4%, polyethylene glycol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 22% thiophene worm amine indoxacarb aqueous emulsion.This proportioning is by 1500 times of dilution sprayings, 72 hours control rice-stem borer effects are 93.46%～96.72% behind the medicine, 50% thiophene worm amine water dispersible granules and 20% indenes worm prestige missible oil are according to same quadrat method, dilute 7000 times and 6000 times of uses respectively, 72 hours preventive effects are respectively 81.26% and 79.54% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example nine
The 35% thiophene worm amine indenes worm prestige microemulsion control paddy rice paddy stem borer test of pesticide effectiveness:
With thiophene worm amine 10%, indenes worm prestige 25%, N-octylpyrrolidone 17%, toluene 5%, ethylene glycol monomethyl ether 4%, ethyl acetate 4%, farming breast 34
#6%, triethanolamine salt 6%, ethylene glycol 2%, silicone oil 0.4%, deionized water supplies 100%, makes 35% thiophene worm amine indenes worm prestige microemulsion.This proportioning is by 2000 times of dilution sprayings, 72 hours control paddy rice paddy stem borer effects are 94.87%～97.10% behind the medicine, 50% thiophene worm amine water dispersible granules and 20% indenes worm prestige missible oil are according to same quadrat method, dilute 6000 times and 5500 times of uses respectively, 72 hours preventive effects are respectively 81.45% and 79.86% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example ten
The 16% thiophene worm amine indenes worm prestige microemulsion control Chinese cabbage cabbage caterpillar test of pesticide effectiveness:
With thiophene worm amine 6%, indenes worm prestige 10%, N, dinethylformamide 17%, methyl alcohol 8%, N-pyrrolidones 4%, tween 4%, farming breast 600
#3%, Nongru-700
#5%, propane diols 3%, silicone oil 0.4%, deionized water supplies 100%, makes 16% thiophene worm amine indenes worm prestige microemulsion.This proportioning is by 1000 times of dilution sprayings, 72 hours control Chinese cabbage cabbage caterpillar effects are 93.89%～97.34% behind the medicine, 50% thiophene worm amine water dispersible granules and 20% indenes worm prestige missible oil are according to same quadrat method, dilute 6000 times and 5500 times of uses respectively, 72 hours preventive effects are respectively 80.31% and 79.55% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Claims (6)
1. the Pesticidal combination of clothianidin-containing and indenes worm prestige, it is characterized in that: the percentage by weight of effective active composition thiophene worm amine and indenes worm prestige is 1～80: 80～1.
2. the Pesticidal combination of clothianidin-containing according to claim 1 and indenes worm prestige is characterized in that: the percentage by weight of thiophene worm amine and indenes worm prestige is 5～50: 50～5.
3. the Pesticidal combination of clothianidin-containing according to claim 2 and indenes worm prestige is characterized in that: the percentage by weight of thiophene worm amine and indenes worm prestige is 10～20: 20～10.
4. the Pesticidal combination of clothianidin-containing according to claim 1 and indenes worm prestige is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion.
5. the application of the Pesticidal combination of clothianidin-containing according to claim 1 and indenes worm prestige aspect the control crop pests.
6. thiophene worm amine according to claim 5 and indenes worm prestige complex insecticidal composition are mainly used in control cotton bollworm, rice leaf roller, rice fulgorid, cabbage caterpillar, diamond-back moth, wild cabbage beet armyworm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010148296A CN101796959A (en) | 2010-04-16 | 2010-04-16 | Insecticidal composition containing clothianidin and indoxacarb |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016019516A1 (en) | 2014-08-05 | 2016-02-11 | Dow Global Technologies Llc | Emulsifiable concentrates of indoxacarb |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008025542A2 (en) * | 2006-08-31 | 2008-03-06 | Syngenta Participations Ag | Methods for protecting plants and controlling pests and compositions comprising indoxacarb and neonicotinoid |
-
2010
- 2010-04-16 CN CN201010148296A patent/CN101796959A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008025542A2 (en) * | 2006-08-31 | 2008-03-06 | Syngenta Participations Ag | Methods for protecting plants and controlling pests and compositions comprising indoxacarb and neonicotinoid |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016019516A1 (en) | 2014-08-05 | 2016-02-11 | Dow Global Technologies Llc | Emulsifiable concentrates of indoxacarb |
| CN106572651A (en) * | 2014-08-05 | 2017-04-19 | 陶氏环球技术有限责任公司 | Emulsifiable concentrates of indoxacarb |
| EP3177141A4 (en) * | 2014-08-05 | 2018-01-03 | Dow Global Technologies LLC | Emulsifiable concentrates of indoxacarb |
| US9955694B2 (en) | 2014-08-05 | 2018-05-01 | Dow Global Technologies Llc | Emulsifiable concentrates of indoxacarb |
| CN106572651B (en) * | 2014-08-05 | 2021-01-29 | 陶氏环球技术有限责任公司 | Emulsifiable concentrate of indoxacarb |
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Address after: 715500 Shaanxi Pucheng County agricultural base industrial park Applicant after: Shaanxi Meibang Pesticide Co., Ltd. Address before: 710075, Xi'an high tech Zone, Shaanxi hi tech Zone, Jinqiao International C block, 15 Floor Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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Application publication date: 20100811 |