CN101779640A - Pesticidal composite - Google Patents
Pesticidal composite Download PDFInfo
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- CN101779640A CN101779640A CN200910000868A CN200910000868A CN101779640A CN 101779640 A CN101779640 A CN 101779640A CN 200910000868 A CN200910000868 A CN 200910000868A CN 200910000868 A CN200910000868 A CN 200910000868A CN 101779640 A CN101779640 A CN 101779640A
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- mosquito
- rynaxypyr
- pesticidal combination
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Abstract
The invention provides a pesticidal composite for preventing sanitary pests like mosquitoes, flies, Blattella germanica and the like. The pesticidal composite contains chlorantraniliprole which serves as pesticidal active ingredient and piperonyl butoxide or octacide 264 which serves as synergist, and the amount of the piperonyl butoxide or octacide 264 is 1-20 times that of the chlorantraniliprole by weight. The pesticidal composite can be prepared to be pest-repellent incense coils, electrothermal mosquito mats, electrothermal liquid mosquito repellent and pest aerosol to be used where mosquitoes, flies, Blattella germanica and the like haunt so as to achieve the effects of preventing and killing the pests.
Description
Technical field
The invention provides a kind of Pesticidal combination of preventing and treating sanitary insect pests such as mosquito, fly, Groton bug, comprising Rynaxypyr as active insecticidal components, and as the Butacide or the Octacide 264 of synergist.
Background technology
Rynaxypyr, chemical name 3-bromo-N-[4-chloro-2-methyl-6-(amino-carbonyl phenyl)-1-3 chloro-2-pyridine]-1H-pyrazoles-5-carboxylic acid amides, be the ryania acceptor inhibitor insecticides that a new generation has unique effect mechanism.Calcium channel effect in the body of its directional jamming target pest causes that the internal calcium ion unrestrictedly discharges, and stops contraction of muscle, thereby makes insect stop to get food rapidly, muscular paralysis, vigor disappearance, paralysis occur, until thorough death.Just because of the mechanism of action of this uniqueness, Rynaxypyr all shows low toxicity to mammal, bird, fish and useful insect; Simultaneously there is not cross resistance with traditional organic phosphor, pyrethroid, anabasine insecticide.The Rynaxypyr insecticidal spectrum is very wide, has been used to prevent and treat pest such as mythimna separata (subtropics mythimna separata, meadow mythimna separata, yellow bar mythimna separata), cotton bollworm, cabbage caterpillar, maize borer, striped rice borer, paddy stem borer, pink rice borer, rice leaf roller.(WO2003015519，WO2005107468，WO2006108553，WO2007039080)
On the other hand, traditional health that is used for exists fish, honeybee, the highly toxic shortcoming of silkworm with the pyrethroid insecticides of desinsection product always, and growth along with service time, mosquitos and flies has produced pesticide resistance (Gao Xiwu etc. in various degree to some pyrethroid products, Chinese media biology and control magazine, 2004,15 (2), 105).
Thus, the present invention uses Rynaxypyr to be used to prepare hygienic insecticide as active ingredient, not only can overcome beneficial organism high toxicity shortcoming, also can not produce cross resistance.In the screening formula process, finding can significantly increase the insecticidal effect of Rynaxypyr by adding Butacide or Octacide 264, thereby greatly reduces drug cost.Butacide or Octacide 264 are preferably 2-5 doubly by weight for the 1-20 of Rynaxypyr doubly is advisable.With this Rynaxypyr that comprises as active insecticidal components, and be used to prepare disc type insecticidal incense, electric mosquito repellent tablet, electric liquid device, insect aerosol as the Butacide of synergist or the Pesticidal combination of Octacide 264, it is stable to have obtained a collection of volatilization, drug effect is good, long-lasting hygienic biocide product.
Summary of the invention
The invention provides a kind of Pesticidal combination of preventing and treating sanitary insect pests such as mosquito, fly, Groton bug, comprising Rynaxypyr as active insecticidal components, and as the Butacide or the Octacide 264 of synergist, the amount of Butacide or Octacide 264 be by mass Rynaxypyr 1-20 doubly.Use this Pesticidal combination to prepare disc type insecticidal incense, electric mosquito repellent tablet, electric liquid device and insect aerosol product, be used for sanitary insect pests such as mosquito, fly, Groton bug and haunt the effect of reach control, killing.
Below the application in preparation various forms insecticide is described in detail to this Pesticidal combination:
(1) preparation disc type insecticidal incense
Described disc type insecticidal incense is mixed with Pesticidal combination to join behind the liquid form and makes in the base material, and wherein Rynaxypyr content is 0.005-2.0w/w%.
The liquid form that Pesticidal combination of the present invention is mixed with is missible oil or is the solution of solvent with kerosene.
Described missible oil can add water and admix in the disc type insecticidal incense base material when preparation base material (fragrant base), forms the disc type insecticidal incense of the The compounds of this invention that contains above-mentioned concentration, then oven dry.Also contain surfactant and other auxiliary agents in the described missible oil; The example of described surfactant comprises one or more mixtures in alkyl sulfate, alkylsulfonate, alkylaryl sulfonates, polyoxyalkylene alkyl, polyoxyalkylene alkyl aryl ether, polyoxyalkylene styryl phenyl ether, polyol ethers or the sugar alcohol derivant; The example of described other auxiliary agents comprises one or more the mixture in aromatic, colouring agent or the bactericide.
The base material of described disc type insecticidal incense is made up of one or more inflammable substances and one or more adhesives, and wherein the weight ratio of inflammable substance and adhesive is 90: 10 to 99.9: 0.1.The example of inflammable substance comprises the plant drymeal that is selected from wood powder, Dalmatian chrysanthemum extraction powder, citrus peel meal, palm oil-bound distemper, coconut shell powder or walnut parting, or is selected from the carbon dust of charcoal powder, activated carbon powder or coal dust, or their mixture; The example of adhesive comprises the polymer of starch, casein, methylcellulose, carboxymethyl cellulose or polyvinyl alcohol of being selected from tapioca, corn starch or wheaten starch and composition thereof.
Described disc type insecticidal incense base material normally by mixing inflammable substance and adhesive, is mediated with water, moulding and oven dry preparation.The shape of disc type insecticidal incense base material can be plate-like or strip without limits.The present invention uses about 12cm of diameter and the thickness conventional coil shape base material as 3-5mm usually in two line spices of a cover.
(2) preparation electric mosquito repellent tablet
Described electric mosquito repellent tablet is will contain the solution dropping of Pesticidal combination and/or be coated on the porosity base material to make, and the content of Rynaxypyr is the 0.5-20mg/ sheet in the described anti-mosquito incense sheet.Also contain the additive that is selected from antioxidant, stifling conditioning agent, spices or dyestuff in the described solution that contains Pesticidal combination.
The example of the porous substrate of described electric mosquito repellent tablet comprises paper pulp, asbestos, synthetic porous resin, porous, inorganic powder, glass fibre, mineral dust or porous ceramic material; Described porous substrate is long 30-35mm, wide 20-22mm, the sheet of thick 1.5-2mm.An example that is used for porous pad of the present invention is the sheet that contains the paper pulp fiber of the cotton fiber of 50% weight and 50% weight, from absorbability with keep the viewpoint of insecticidal active ingredient, preferably uses the natural fiber material film-making.
(3) preparation electric liquid device
Described electric liquid device is that Pesticidal combination is dissolved in the aliphatic hydrocarbon, adds the antioxidant of optional 0.1-0.5w/w% then, and 0.1-1w/w% spices is mixed with the solution that contains the 0.05-2w/w% Rynaxypyr and makes; The aliphatic hydrocarbon of the preferred C14 component of described aliphatic hydrocarbon.
Electric liquid device liquid is by the capillarity of plug, mosquito-repellent incense liquid is taken to the top of plug from the bottom of plug, under the electrical heating effect of ring heater, after making the active ingredient in space reach certain concentration, just can be to mosquito, fly, sanitary insect pests such as Groton bug produce to be stimulated, drives and lethal effect, thereby reach mosquito, fly, the control of sanitary insect pests such as Groton bug.
(4) preparation insect aerosol
Described insect aerosol is that the composition that Pesticidal combination, kerosene and synergist, aromatic and/or the bactericide according to circumstances selected mix under room temperature or heating condition is added in the jar that a valve is housed, and under pressure, in jar, add propellant by this valve and make, the content of final Rynaxypyr is 0.001-0.5w/w%; Described propellant accounts for the 20-60% of composition total weight; Preferred liquefied petroleum gas, third butane, dimethyl ether or compressed air, further preferred third butane.
When insect aerosol of the present invention is used in the habitat of insect, by-pass valve control is opened, under the pressure effect of propellant, produce high velocity air, jar is included the soup aerosol dispersion of active ingredient and the gasification of propellant, the small liquid pearl that contains effective insecticidal constituent of formation is suspended in the air, with mosquito, fly, sanitary insect pests such as Groton bug contact, and reach the purpose of quick kill pests.
Based on above-mentioned achievement in research, the present invention proposes the Rynaxypyr that comprises as active insecticidal components, and killing mosquito, fly as the Butacide of synergist or the Pesticidal combination of Octacide 264, the application of sanitary insect pest aspects such as Groton bug, and concrete application mode has been proposed.Through experiment, proved that the various insecticides of Pesticidal combination preparation of the present invention have remarkable prevention effect to housefly, Culex pipiens pallens, Groton bug etc., be kind for resistance especially, preventive effect substantially exceeds traditional pyrethroid series products.
Embodiment
Explain the present invention in detail with the form of embodiment below, but the present invention is not limited to following examples.
Application Example 1
Add the water of 120 weight portions and mediate in the mixture of corn starch, carbon dust and the wood powder (1: 5: 4) of 99.96 weight portions and be shaped, oven dry forms line spices shape disc type insecticidal incense base materials (diameter 12.0cm, thick 4mm, a counterweight 40g) then.
On the other hand, the 0.4w/v% solution of preparation Rynaxypyr in kerosene.
On this cover disc type insecticidal incense base material, evenly drip the above-mentioned solution of 4ml, at room temperature place then and had a disc type insecticidal incense I of 0.04w/w% Rynaxypyr to obtain a cover in 3 hours with microsyringe.
Application Example 2
Add the water of 120 weight portions and mediate in the mixture of corn starch, carbon dust and the wood powder (1: 5: 4) of 99.88 weight portions and be shaped, oven dry forms line spices shape disc type insecticidal incense base materials (diameter 12.0cm, thick 4mm, a counterweight 40g) then.
On the other hand, the Octacide 264 of the Rynaxypyr of 0.4 weight portion, 0.8 weight portion is dissolved in obtains Rynaxypyr 0.4w/v% solution in the kerosene.
On this cover disc type insecticidal incense base material, evenly drip the above-mentioned solution of 4ml, at room temperature place then and had a disc type insecticidal incense II of 0.04w/w% Rynaxypyr, 0.08w/w% Octacide 264 to obtain a cover in 3 hours with microsyringe.
Application Example 3
Add the water of 120 weight portions and mediate in the mixture of corn starch, carbon dust and the wood powder (1: 5: 4) of 99.88 weight portions and be shaped, oven dry forms line spices shape disc type insecticidal incense base materials (diameter 12.0cm, thick 4mm, a counterweight 40g) then.
On the other hand, the Butacide of the Rynaxypyr of 0.4 weight portion, 0.8 weight portion is dissolved in obtains Rynaxypyr 0.4w/v% solution in the kerosene.
On this cover disc type insecticidal incense base material, evenly drip the above-mentioned solution of 4ml, at room temperature place then and had a disc type insecticidal incense III of 0.04w/w% Rynaxypyr, 0.08w/w% Butacide to obtain a cover in 3 hours with microsyringe.
Application Example 4
Add the water of 120 weight portions and kneaded and formed in the mixture of corn starch, carbon dust and the wood powder (1: 5: 4) of 99.6 weight portions, oven dry forms line spices shape disc type insecticidal incense base materials (diameter 12.0cm, thick 4mm, a counterweight 40g) then.
On the other hand, the 4.0w/v% solution of preparation Es-allethrin in kerosene.
On this cover disc type insecticidal incense base material, evenly drip the above-mentioned solution of 4ml, at room temperature place then and had a disc type insecticidal incense IV of 0.4w/w%Es-allethrin to obtain a cover in 3 hours with microsyringe.
Application Example 5
Is that Culex pipiens pallens carry out kill mosquito evaluation of pesticide effectiveness contrast according to GB13917.4-92 to sensitivity with the disc type insecticidal incense of Application Example 1-4, and the examination worm is made a living and surveys the conventional raising in chamber, and the 2-3 days female mosquitos of not sucking blood in back sprout wings; Detailed process is to draw 20 examination mosquitos with mosquito sucking tube, put into airtight drum testing arrangement, appoint and get one section of tested mosquito-repellent incense, put to fragrant frame, light timing, remove mosquito-repellent incense behind the 1min, write down down and out examination mosquito number at set intervals, to all be transferred in the dependent insect cage of cleaning behind the 20min, check dead examination mosquito number behind the 24h for the examination mosquito.
Experimental result sees Table 1:
Table 1. insecticidal incense of the present invention and control compounds are the comparison of mosquito control efficiency to sensitivity
| Active ingredient | Concentration w/w% | ?KT50(min) | 24h lethality (%) | |
| The insecticidal incense I | Rynaxypyr | ??0.04 | ?6.03 | ?100 |
| The insecticidal incense II | Rynaxypyr+Octacide 264 | ??0.04??+0.08 | ?3.44 | ?100 |
| The insecticidal incense III | Rynaxypyr+Butacide | ??0.04??+0.08 | ?3.85 | ?100 |
| The insecticidal incense IV | The Es-allethrin | ??0.4 | ?5.25 | ?100 |
The result shows, Pesticidal combination of the present invention have a very high mosquito activity of killing, and Octacide 264 and Butacide have significant synergy to the insecticidal action of Rynaxypyr.
Application Example 6
Is that Culex pipiens pallens carries out kill mosquito evaluation of pesticide effectiveness contrast with the disc type insecticidal incense of Application Example 1-4 according to the GB13917.4-92 antagonism, culex pipiens pallens larvae selectively the Yangzhou East, West, South, North, in the river embankment, irrigation canals and ditches, sewer, cesspit etc. of 5 points locate to gather, take back and get the 2-3 days female mosquitos of not sucking blood in back that sprout wings after receptacle is raised a generation; Detailed process is to draw 20 examination mosquitos with mosquito sucking tube, put into airtight drum testing arrangement, appoint and get one section of tested mosquito-repellent incense, put to fragrant frame, light timing, remove mosquito-repellent incense behind the 1min, write down down and out examination mosquito number at set intervals, to all be transferred in the dependent insect cage of cleaning behind the 20min, check dead examination mosquito number behind the 24h for the examination mosquito.
Experimental result sees Table 2:
Table 2. insecticidal incense of the present invention and control compounds antagonism are the comparison of mosquito control efficiency
| Active ingredient | Concentration w/w% | ??KT50(min) | 24h lethality (%) | |
| The insecticidal incense I | Rynaxypyr | ??0.04 | ??6.22 | ?95 |
| Active ingredient | Concentration w/w% | ??KT50(min) | 24h lethality (%) | |
| The insecticidal incense II | Rynaxypyr+Octacide 264 | ??0.04??+0.08 | ??3.48 | ?100 |
| The insecticidal incense III | Rynaxypyr+Butacide | ??0.04??+0.08 | ??3.75 | ?100 |
| The insecticidal incense IV | The Es-allethrin | ??0.4 | ??17.66 | ?75 |
The result shows that the relative effectivenes that Pesticidal combination antagonism of the present invention is a mosquito is at more than 40 times of Es-allethrin.
Application Example 7
With containing the 2mg Rynaxypyr, the 6mg Octacide 264,15mg BHT (2, the 6-di-tert-butyl-4-methy phenol) and the long 35mm of the preparation of 0.5mg dyestuff dipping, wide 22mm, the porous pad of thick 2mm (cotton fiber: 50% percentage by weight, paper pulp fiber: 50% percentage by weight), placed 3 days under the room temperature, make electric mosquito repellent tablet, the content of Rynaxypyr is the 2mg/ sheet in the electric mosquito repellent tablet.
Application Example 8
Under heating with the Octacide 264 of 0.2 part of Rynaxypyr and 0.4 part, 0.3 part of BHT, 0.3 part spices, 98.8 parts n-tetradecane lump together and are prepared into mosquito liquid.Can becomes electric liquid device then, wherein chloride worm benzamide 0.2w/w%, Octacide 264 0.4w/w%.
Application Example 9
Under heating, the Octacide 264 of 0.3 weight portion Rynaxypyr, 0.6 weight portion and the kerosene of 59.1 weight portions are mixed a kind of insecticidal preparation of preparation.The preparation that obtains is put into the aerosol jar, on jar a valve is housed, and inject 40.0 weight portions, third butane adding to depress, to obtain a kind of insect aerosol, wherein chloride worm benzamide 0.3w/w%, Octacide 264 0.6w/w% by this valve.
Application Example 10
The alkynes third chrysanthemum ester electric mosquito repellent tablet of Application Example of the present invention 7 and at present the most frequently used 10mg/ sheet is carried out evaluation of pesticide effectiveness contrast to mosquito according to GB13917.5-92, adopt airtight drum device.Detailed process is as follows.
With electric mosquito repellent tablet sample energising preheating 1h, 2h, 4h, 6h, 8h draws 20 female culex pipiens fatigans with mosquito sucking tube, puts into airtight drum testing arrangement, accurately smoked kill 1min, clock simultaneously, cut off the electricity supply after smoking, and remove the electric mosquito repellent tablet device, write down down and out examination mosquito number at regular intervals.The results are shown in Table 3:
The electric mat of table 3. the present invention preparation and the comparison of the alkynes third chrysanthemum ester electric mat effect exterminating mosquito
The result shows: with the relative effectivenes of the electric mat of Pesticidal combination preparation of the present invention at more than 5 times of the alkynes third chrysanthemum ester chrysanthemum ester anti-mosquito incense sheet.
Application Example 11
The alkynes third chrysanthemum ester electric liquid device of Application Example of the present invention 8 and at present the most frequently used 1w/w% is carried out evaluation of pesticide effectiveness contrast according to GB13917.6-92, adopt airtight drum device.Detailed process is as follows: with electric liquid device sample energising 2h, 36h, 84h, 168h, 336h, draw 20 female culex pipiens fatigans with mosquito sucking tube, put into airtight drum testing arrangement, accurately smoked kill 1min, clock simultaneously, cut off the electricity supply after smoked, and remove the electric liquid device device, write down down and out examination mosquito number at regular intervals.The results are shown in Table 4:
The vaporizer mosquito liquid of table 4. the present invention preparation and the comparison of the alkynes third chrysanthemum ester vaporizer mosquito liquid effect exterminating mosquito
The result shows: the relative effectivenes of the vaporizer mosquito liquid of Pesticidal combination preparation of the present invention is at more than 5 times of the alkynes third chrysanthemum ester chrysanthemum ester vaporizer mosquito liquid.
Application Example 12
Application Example 9 of the present invention is carried out mosquito according to GB13917.2-92, fly, the efficacy testing of Groton bug adopts airtight drum device.Detailed process is as follows: will put into cylinder for the examination insect; after waiting to try worm recovery normal activity; metered injection 1g medicament from insect aerosol jar of the present invention; extracting baffle plate behind the 1min out makes the examination worm contact with medicament; down and out examination borer population is write down in timing immediately, and opening entry at regular intervals; to all be transferred in the dependent insect cage of cleaning behind the 20min, check dead examination borer population behind the 24h for the examination worm.Wherein Groton bug is checked the 72h lethality.The results are shown in Table 5:
The insect aerosol of table 5. Pesticidal combination of the present invention preparation is to mosquito, fly, the insect killing effect of Groton bug
| Insect | KT50 (mosquito/fly/cockroach) | 24 hours lethality |
| Mosquito | 4.64 minute | ??100％ |
| Fly | 5.22 minute | ??100％ |
| Groton bug | 6.14 minute | ??100％(72h) |
The result shows: the aerosol of the present invention's preparation is to mosquito, and fly, Groton bug have good insect killing effect.
Claims (9)
1. Pesticidal combination, it comprises the Rynaxypyr as active insecticidal components, and as the Butacide or the Octacide 264 of synergist.
2. Pesticidal combination according to claim 1, wherein the amount of Butacide or Octacide 264 be by weight Rynaxypyr 1-20 doubly.
3. Pesticidal combination according to claim 1 is applied to prevent and treat mosquito, fly or Groton bug.
4. the application of control mosquito, fly or Groton bug according to claim 3 is characterized in that: Pesticidal combination is prepared into various forms of insecticides, comprises disc type insecticidal incense, electric mosquito repellent tablet, electric liquid device or insect aerosol.
5. disc type insecticidal incense according to claim 4 is characterized in that: Pesticidal combination is mixed with to join behind the liquid form makes in the base material, wherein Rynaxypyr content is 0.005-2.0w/w%; The liquid form that described Pesticidal combination is mixed with is missible oil or is the solution of solvent with the hydro carbons; Described base material is made up of one or more inflammable substances and one or more adhesives, and wherein the weight ratio of inflammable substance and adhesive is 90: 10 to 99.9: 0.1.
6. electric mosquito repellent tablet according to claim 4 is characterized in that: the solution that will contain Pesticidal combination drips and/or is coated in and makes on the porosity base material, and the content of Rynaxypyr is the 0.5-20mg/ sheet in the described anti-mosquito incense sheet; Described porous substrate comprises paper pulp, asbestos, synthetic porous resin, porous, inorganic powder, glass fibre, mineral dust or porous ceramic material; Described porous substrate is long 30-35mm, wide 20-22mm, the sheet of thick 1.5-2mm; Also contain the additive that is selected from stifling conditioning agent, spices or dyestuff in the described solution that contains Pesticidal combination.
7. electric liquid device liquid according to claim 4, it is characterized in that: Pesticidal combination is dissolved in the aliphatic hydrocarbon, the antioxidant and/or the 0.1-1w/w% spices that add 0.1-0.5w/w% then are mixed with the solution that contains the 0.05-2w/w% Rynaxypyr and make; Described aliphatic hydrocarbon is the aliphatic hydrocarbon of C14 component.
8. insect aerosol according to claim 4, it is characterized in that: one of the composition adding that Pesticidal combination, kerosene and synergist, aromatic and/or bactericide mix under room temperature or heating condition is equipped with in the jar of a valve, and under pressure, in jar, add propellant by this valve and make, wherein the content of Rynaxypyr is 0.001-0.5w/w%; Described propellant accounts for 20～60% of composition total weight, is selected from liquefied petroleum gas, third butane, dimethyl ether or compressed air.
9. according to the described application that prevents and treats mosquito, fly, Groton bug of claim 4, it is characterized in that: light the disc type insecticidal incense in the habitat of mosquito, fly, Groton bug or the place of haunting, heating electric mosquito repellent tablet, electric liquid device or sprinkling insect aerosol, the volatilization of active ingredient Rynaxypyr is diffused in the air, to reach the purpose of preventing and kill off sanitary insect pest.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101971802A (en) * | 2010-10-20 | 2011-02-16 | 华南理工大学 | Chlorantraniliprole pesticidal microemulsion and preparation method thereof |
| CN103704279A (en) * | 2013-12-13 | 2014-04-09 | 青岛安信医疗器械有限公司 | Electric heated liquid mosquito-repellent incense |
| CN113647397A (en) * | 2021-09-16 | 2021-11-16 | 江苏功成生物科技有限公司 | Sanitary insecticidal composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1625950A (en) * | 2003-12-10 | 2005-06-15 | 李鹏飞 | Pyrolytic pieces of mosquito-repellent incense |
| CN101107930A (en) * | 2006-07-19 | 2008-01-23 | 华子昂 | Slow release long-acting worm-expelling material and method for preparing same |
| CN100586282C (en) * | 2008-05-08 | 2010-02-03 | 国家农药创制工程技术研究中心 | Insecticidal composition containing chlorantraniliprole and monosultap |
| CN101305726B (en) * | 2008-07-11 | 2010-07-28 | 湖南农业大学 | Synergetic pesticide composition |
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2009
- 2009-01-20 CN CN 200910000868 patent/CN101779640B/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101971802A (en) * | 2010-10-20 | 2011-02-16 | 华南理工大学 | Chlorantraniliprole pesticidal microemulsion and preparation method thereof |
| CN101971802B (en) * | 2010-10-20 | 2013-04-17 | 华南理工大学 | Chlorantraniliprole pesticidal microemulsion and preparation method thereof |
| CN103704279A (en) * | 2013-12-13 | 2014-04-09 | 青岛安信医疗器械有限公司 | Electric heated liquid mosquito-repellent incense |
| CN113647397A (en) * | 2021-09-16 | 2021-11-16 | 江苏功成生物科技有限公司 | Sanitary insecticidal composition |
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