CN101107930A - Slow release long-acting worm-expelling material and method for preparing same - Google Patents
Slow release long-acting worm-expelling material and method for preparing same Download PDFInfo
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- CN101107930A CN101107930A CNA2006100990952A CN200610099095A CN101107930A CN 101107930 A CN101107930 A CN 101107930A CN A2006100990952 A CNA2006100990952 A CN A2006100990952A CN 200610099095 A CN200610099095 A CN 200610099095A CN 101107930 A CN101107930 A CN 101107930A
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Abstract
The invention discloses a material for slowly releasing and expelling worms in long-term and its preparation method. The material is composed of the following components: 20 pieces to 50 pieces of porosint, 5 pieces to 15 pieces of insecticide, 3 pieces to 8 pieces of synergistic agent, 10 pieces to 30 pieces of impregnant, 1 piece to 2 pieces of emulsification agent and 1 piece to 2 pieces of antioxidant. The preparation method is that: heating the porosint to the temperature of 120 DEG C. and preserving the porosint for 1h; then cooling the porosint to the temperature ranging from 45 DEG C.to 60 DEG C., adding with the insecticide, the impregnant and other auxiliary agent and stiring for 40min; placing the mixture after stirring out of a reaction kettle, finally cooling and placing it for 12h. The invention has the advantages of short time but slow release and long-term for functioning on mosquito, good compatibility, harmlessness and safety, etc.
Description
Technical field
The present invention relates to the household chemicals technical field, specifically, is a kind of slow release long-acting worm-expelling material and preparation method thereof.
Background technology
Mosquito not only bites health in life, also very easily propagates all kinds of communicable diseases (as encephalitis, malaria, dengue fever, yellow fever etc.), and human health is caused significant damage.Existing kill mosquito method mainly contains insect killer, expelling parasite liquid medicine etc., and effect is relatively poor, and simultaneously long-time use also can produce harmful effect to human body.
Summary of the invention
First purpose of the present invention provides a kind of slow release long-acting worm-expelling material.
Another object of the present invention provides the preparation method of this kind slow release long-acting worm-expelling material.
In order to achieve the above object, the present invention is by the following technical solutions:
Slow release long-acting worm-expelling material is made up of the raw material of following weight portion:
20～50 parts of porous materials
5～15 parts in insecticide
3～8 parts of synergist
10～30 parts of solvents
1～2 part of emulsifier
1～2 part of antioxidant.
Porous material is meant: titanium dioxide, silicon dried soil, sepiolite, burning alumina etc.
Insecticide is meant: pyrethroid (comprises tetramethrin, d-trans Allethrin 93, permethrin, cypermethrin, alpha-cypermethrin, efficient alphamethrin, decis, d-phenothrin, the dextrorotation cyphenothrin, cyfloxylate, methothrin, sumicidin, trifluoro oxygen Cyano chrysanthemate, ether chrysanthemum ester, cycloprothrin), carbamates (carbaryl, bendiocarb, Elacron, Landrin, dimethyl phenyl carbamate, swoop because of, two second prestige, two third prestige, the ethylbenzene prestige, unden, Bassa), organic phosphates (chlorophos, fenthion, Swebate, the malathion, phoxim, diazinon, quinalphos, Ravap, ronnel, bromophos, iodfenphos, sumithion, pirimiphos-methyl and orthene).
The major function of synergist is to mix the usage amount that can improve the drug effect of original insecticide when using and reduce original medicament with insecticide, main kind comprises: and Butacide (piperonyl butoxide or Octachlorodipropyl Ether), Octacide 264 (be synergy spirit MGK-264, molecular formula: C
17H
25NO
2), synergy phosphorus (being SV) etc.
Described solvent is meant organic solvent commonly used such as ethanol, glacial acetic acid etc.
Described emulsifier is NP-10 (polyoxyethylene nonylphenol ether), TX-10 (alkyl phenol and ethylene oxide condensate).
Described antioxidant is RALOX LC (paracresol and dicyclopentadiene butylation polymer), 2,5-ditert-butylhydro quinone, β-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid octadecanol ester.
The preparation method of this kind slow release long-acting worm-expelling material is heated to 120 ℃ with porous material, is incubated 1 hour; Add insecticide, solvent and other auxiliary agents when being cooled to 45-60 ℃ and stirred 40 minutes; Mixture after being mixed is emitted behind the reactor cooling place 12 hours promptly.
Slow release long-acting worm-expelling material has solved the shortcoming of existing worm-expelling material, has characteristics such as efficient, long-acting, safe.This material mainly is made up of porous material and insecticide (comprising other auxiliary agents).In preparation process, insecticide with deinsectization function passes the micropore of these porous materials, be stored in the hole, and form crystal at material surface, in case during insect contact material surface, insecticidal crystal can dissolve the fatty pin of insect, suppress the choline enzyme activity, block normal nerve conduction, cause the imbalance of whole physiological and biochemical procedure, make insect extremely dead by paralysis.This mode of tagging is safer to the people, and insecticidal effect is relatively good, has slow release effect simultaneously, and the lasting medicine phase is long.
Experiment showed, the killing time of 50(KT50) (KT of material of the present invention to mosquitos and flies
50) be 5 minutes, lethality was 100% in 24 hours, the lasting effect of laboratory simulation natural experiment reached more than 5 years.
The present invention can be with reference to the HJBZ 20-1997 number standard about the hygienic biocide aerosol of State Bueau of Environmental Protection's formulation.
Killing time of 50(KT50) (KT
50): refer to that under the experimental condition of certain drug dose the half test down and out time of insect is generally with a minute expression.
24 hours lethality: after referring to normally watch foster 24 hours in the insect immigration cleaning container with tested end (knocking down), dead insects accounts for the percentage of tested insect sum, generally represents with %.
This material is mainly used in the coating, and addition is the 3-5wt% of coating gross weight.Directly add to mix in the coating and get final product, do not change coating property and form substantially.
The present invention has following advantage:
1, fast action time to mosquito, and slow release long-acting;
Get well and do not influence other performances with the other materials system is compatible when 2, using, as coating;
3, good to light, heat, pH value stabilization;
4, human body there is not harm, safety.
Embodiment
Be embodiments of the invention below, described embodiment just is used for illustrating the present invention, and should not be considered to be limitation of the present invention.
Embodiment 1
The accurate following raw material for standby of weighing: silicon dried soil 30kg, d-trans Allethrin 93 10kg, piperonyl butoxide 5kg, ethanol 20kg, 1kg polyoxyethylene nonylphenol ether NP-10,2,5-ditert-butylhydro quinone 2kg.
Silicon dried soil is heated to 120 ℃, is incubated 1 hour; Add other composition when being cooled to 50 ℃ and stirred 40 minutes; Mixture after being mixed is emitted behind the reactor cooling places and promptly got slow release long-acting worm-expelling material 59kg in 12 hours.
Embodiment 2
The accurate following raw material for standby of weighing: titanium dioxide 40kg, carbaryl 15kg, Octachlorodipropyl Ether 3kg, glacial acetic acid 10kg, 2kg alkyl phenol and ethylene oxide condensate TX-10,1kg paracresol and dicyclopentadiene butylation polymer RALOX LC.
Silicon dried soil is heated to 120 ℃, is incubated 1 hour; Add other composition when being cooled to 45 ℃ and stirred 40 minutes; Mixture after being mixed is emitted behind the reactor cooling places and promptly got slow release long-acting worm-expelling material 60kg in 12 hours.
Embodiment 3
The accurate following raw material for standby of weighing: sepiolite 30kg, chlorophos 5kg, 8kg synergy spirit MGK-264, ethanol 30kg, 1kg polyoxyethylene nonylphenol ether NP-10, β-(3,5-di-t-butyl-4-hydroxyphenyl) propionic acid octadecanol ester 2kg.
Sepiolite is heated to 120 ℃, is incubated 1 hour; Add other composition when being cooled to 60 ℃ and stirred 40 minutes; Mixture after being mixed is emitted behind the reactor cooling places and promptly got slow release long-acting worm-expelling material 65kg in 12 hours.
Embodiment 4-6
Get embodiment 1-3 gained worm-expelling material each 4 kilograms, add respectively in 96 kilograms of commercial acrylic acid ester emulsion interior wall coatings, stir.Add the coating behind the worm-expelling material, mechanical property is basicly stable, does not find the phenomenon of mechanical index variation, and good to light, heat, pH value stabilization.
Embodiment 7-9
Get embodiment 1-3 gained worm-expelling material each 3 kilograms, add respectively in 97 kilograms of commercial acrylic acid ester emulsion interior wall coatings, stir.Add the coating behind the worm-expelling material, mechanical property is basicly stable, does not find the phenomenon of mechanical index variation, and good to light, heat, pH value stabilization.
Embodiment 10-12
Get embodiment 1-3 gained worm-expelling material each 5 kilograms, add respectively in 95 kilograms of commercial acrylic acid ester emulsion interior wall coatings, stir.Add the coating behind the worm-expelling material, mechanical property is basicly stable, does not find the phenomenon of mechanical index variation, and good to light, heat, pH value stabilization.
More than slow release long-acting worm-expelling material provided by the present invention and preparation method thereof is described in detail, used specific case herein principle of the present invention and embodiment are set forth, the explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof; Simultaneously, for one of ordinary skill in the art, according to thought of the present invention, the part that all can change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (6)
1. a slow release long-acting worm-expelling material is characterized in that, is made up of the raw material of following weight portion:
20～50 parts of porous materials
5～15 parts in insecticide
3～8 parts of synergist
10～30 parts of solvents
1～2 part of emulsifier
1～2 part of antioxidant.
2. slow release long-acting worm-expelling material as claimed in claim 1 is characterized in that, described insecticide is pyrethroid, carbamates or organophosphorus insecticides.
3. slow release long-acting worm-expelling material as claimed in claim 1 is characterized in that, described porous material is titanium dioxide, silicon dried soil, sepiolite or burns alumina.
4. slow release long-acting worm-expelling material as claimed in claim 1 is characterized in that, described synergist is piperonyl butoxide or Octachlorodipropyl Ether.
5. as the preparation method of any described slow release long-acting worm-expelling material in the claim 1 to 4, it is characterized in that, porous material is heated to 120 ℃, be incubated 1 hour; Add insecticide, solvent and other auxiliary agents when being cooled to 45-60 ℃ and stirred 40 minutes; Mixture after being mixed is emitted behind the reactor cooling place 12 hours promptly.
6. as the using method of any described slow release long-acting worm-expelling material in coating in the claim 1 to 4, it is characterized in that addition is the 3-5wt% of coating gross weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100990952A CN101107930A (en) | 2006-07-19 | 2006-07-19 | Slow release long-acting worm-expelling material and method for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100990952A CN101107930A (en) | 2006-07-19 | 2006-07-19 | Slow release long-acting worm-expelling material and method for preparing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101107930A true CN101107930A (en) | 2008-01-23 |
Family
ID=39040344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006100990952A Pending CN101107930A (en) | 2006-07-19 | 2006-07-19 | Slow release long-acting worm-expelling material and method for preparing same |
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|---|---|
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101779640B (en) * | 2009-01-20 | 2013-06-05 | 江苏扬农化工股份有限公司 | Pesticidal composite |
| CN104621190A (en) * | 2015-02-13 | 2015-05-20 | 南通蛇类治疗研究所 | Natural plant and medicine stone nanometer mosquito-controlling slow-release preparation |
| CN105038461A (en) * | 2015-08-26 | 2015-11-11 | 太仓市金新涂料有限公司 | Environment-friendly pesticidal antibacterial paint |
| CN106190001A (en) * | 2016-07-28 | 2016-12-07 | 合肥毅创钣金科技有限公司 | The polyurethane seal foamed glue that a kind of insect protected Mus bites |
| CN107691449A (en) * | 2017-11-12 | 2018-02-16 | 王龙 | A kind of combined material of the long-acting insect expelling of biology induction, preparation method and purposes |
| CN111066808A (en) * | 2019-12-24 | 2020-04-28 | 佛山欧神诺陶瓷有限公司 | Ceramic tile cockroach-preventing agent, preparation method thereof, ceramic tile cockroach-preventing method and cockroach-preventing ceramic tile |
| CN112568054A (en) * | 2020-11-18 | 2021-03-30 | 安徽年丰珍盛农业发展股份有限公司 | Grape planting frame with insect and bird prevention function |
| CN113912946A (en) * | 2020-07-10 | 2022-01-11 | 万华化学（宁波）有限公司 | Polypropylene composite material with long-acting insect expelling function and preparation method and application thereof |
-
2006
- 2006-07-19 CN CNA2006100990952A patent/CN101107930A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101779640B (en) * | 2009-01-20 | 2013-06-05 | 江苏扬农化工股份有限公司 | Pesticidal composite |
| CN104621190A (en) * | 2015-02-13 | 2015-05-20 | 南通蛇类治疗研究所 | Natural plant and medicine stone nanometer mosquito-controlling slow-release preparation |
| CN105038461A (en) * | 2015-08-26 | 2015-11-11 | 太仓市金新涂料有限公司 | Environment-friendly pesticidal antibacterial paint |
| CN106190001A (en) * | 2016-07-28 | 2016-12-07 | 合肥毅创钣金科技有限公司 | The polyurethane seal foamed glue that a kind of insect protected Mus bites |
| CN107691449A (en) * | 2017-11-12 | 2018-02-16 | 王龙 | A kind of combined material of the long-acting insect expelling of biology induction, preparation method and purposes |
| CN111066808A (en) * | 2019-12-24 | 2020-04-28 | 佛山欧神诺陶瓷有限公司 | Ceramic tile cockroach-preventing agent, preparation method thereof, ceramic tile cockroach-preventing method and cockroach-preventing ceramic tile |
| CN111066808B (en) * | 2019-12-24 | 2021-08-03 | 佛山欧神诺陶瓷有限公司 | Ceramic tile cockroach-preventing agent, preparation method thereof, ceramic tile cockroach-preventing method and cockroach-preventing ceramic tile |
| CN113912946A (en) * | 2020-07-10 | 2022-01-11 | 万华化学（宁波）有限公司 | Polypropylene composite material with long-acting insect expelling function and preparation method and application thereof |
| CN112568054A (en) * | 2020-11-18 | 2021-03-30 | 安徽年丰珍盛农业发展股份有限公司 | Grape planting frame with insect and bird prevention function |
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