CN102283240A - Pesticide composition - Google Patents
Pesticide composition Download PDFInfo
- Publication number
- CN102283240A CN102283240A CN201110178215A CN201110178215A CN102283240A CN 102283240 A CN102283240 A CN 102283240A CN 201110178215 A CN201110178215 A CN 201110178215A CN 201110178215 A CN201110178215 A CN 201110178215A CN 102283240 A CN102283240 A CN 102283240A
- Authority
- CN
- China
- Prior art keywords
- insecticides
- mosquito
- ester
- active component
- adipate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a pesticide composition. The pesticide composition contains 2,3,5,6-tetrafluoro-4-methoxy methyl benzyl-3-(3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cyclopropane carboxylic ester and 1R-2,3,5,6-tetrafluoro-4-methoxy methyl benzyl-3-(2,2-dichloro-1-vinyl)-2,2-dimethyl cyclopropane carboxylic ester serving as pesticidal active ingredients, and at least one of ester substance with carbon atom amount of 16 to 22, phenol substance with carbon atom amount of 16 to 26 and hydrocarbon solvent with carbon atom amount of 6 to 20 serving as a base material. The composition shows stable and sustained pesticidal effect, and particularly is more effective when applied in a form of heating fumigation, gel or aerosol.
Description
Technical field: the present invention relates to a kind of novel pesticide composition, particularly relate to the insecticides that is suitable for heating fumigating, spit of fland agent and aerosol form.
Background technology: Japan Patent JP2002145828A specification discloses has insecticidal activity 2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester.Chinese patent CN00101155.3 announced (2,3,5,6-tetrafluoro-4-methoxyphenyl) methyl trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester also can be used as insecticidal active ingredient.When yet the present inventor discovers the formulation of these two kinds of chrysanthemum ester insecticides of independent use, be difficult to obtain the stable for a long time insecticidal effect that continues.Present inventors study in earnest, found that a kind of insecticides, can well overcome its shortcoming, and dosage is lower than using certain chrysanthemum ester separately.Said composition has 2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester and 1R-2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(2,2-two chloro-1-vinyl)-2,2-dimethyl cyclopropane carboxylic acid ester is as pesticide active ingredient, and at least a the total number of carbon atoms that is selected from is 14～26 Ester, the total number of carbon atoms is that 16～26 phenol type substances or carbon number always are 6～20 the varsol insecticides as material, said composition demonstrates the stable insecticidal effect that continues, particularly with heating fumigating, spit of fland agent and aerosol form are more effective when using.
Summary of the invention: one of purpose of the present invention provides a kind of novel pesticide composition.
Another object of the present invention provides a kind of insecticides that has the insecticidal effect of stable persistent high efficiency when stifling, spit of fland agent or aerosol form are used of being used as.
Another object of the present invention provides a kind of heating fumigating, spit of fland agent or aerosol form and uses the method that above-mentioned insecticides comes Pest Control.
We will be more clearly visible purpose of the present invention and advantage thereof from following description.
According to the present invention, a kind of insecticides is provided, said composition is by containing 2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester is called for short active component (1) and 1R-2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(2,2-two chloro-1-vinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, be called for short active component (2) as active insecticidal components, and with other at least a the total number of carbon atoms that are selected from be 14～26 Ester, the total number of carbon atoms is that 16～26 phenol type substances or carbon number always are the insecticides that 6～20 varsol material is formed.
Active component (1) percetage by weight as active insecticidal components in the composition is that 0.02～0.30wt% and active component (2) percetage by weight are 0.02～0.20wt%, and the overall weight percent of Ester, phenol type substances or varsol is 99.50～99.96wt%.
The total number of carbon atoms is that 14～26 Ester has ATBC; citroflex A-4; triethyl citrate; DOTP; trioctyl trimellitate (TOTM); dioctyl adipate; di-n-octyl sebacate; the nylon acid diisobutyl ester; dioctyl phthalate; dibutyl phthalate; diisobutyl phthalate; diisopropyl phthalate; dipropyl phthalate; dipropyl adipate; diisopropyl adipate; dibutyl adipate; diisobutyl adipate; isopropyl myristate or ethyl stearte.
The total number of carbon atoms is that 16～26 phenol type substances has 2,6 di tert butyl 4 methyl phenol, ditert-butylhydro quinone.
The total number of carbon atoms is that 6～20 varsols have, normal paraffin hydrocarbons, isoparaffin and cycloalkane, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane or their mixture, kerosene, gasoline.
Insecticides of the present invention is prepared into incense coil, vaporizer mosquito liquid, electric mosquito repellent tablet or aerosol insecticide is applied to control mosquito, fly, cockroach, ant and louse insect.
The present composition is prepared into heating fumigating agent, spit of fland agent, aerosol insecticides and is applied to that the control of mosquito, fly, cockroach, ant and louse insect is had tangible insecticidal activity.
The formulation of insecticides of the present invention is directly used the habitat of insect or insect.
Below insecticides of the present invention is prepared into various formulations and application thereof the detailed description of character of giving an example, but does not belong to limit for example:
(1) disc type insecticide (mosquito-repellent incense):
Described disc type disinsecting mosquito repellant incense made is mixed with the present composition to join in the base material behind the liquid form and makes through this area conventional method.
The following technology preparation of specific embodiment: above-mentioned composition active component (1) is that 0.02～0.30wt% and active component (2) are that 0.02～0.20wt% adds other components and adds water when preparation base material (mosquito-repellent incense blank), be mixed to and form the disc type insecticidal incense that contains this active compound component about 0.04-0.50w/w% of concentration in product, oven dry then in the base material.In a preferred embodiment of the invention, use about 10-15cm of diameter and thickness to make two line mosquito-repellent incenses of suit as the conventional coil shape base material of 3-5mm usually.
The disc type insecticide that more than obtains can adopt conventional method to use.That is, light disc type insecticide of the present invention near (for example dwelling house, office, stock barn) or its in the habitat of insect.Compound of the present invention is in burning or temperature can access volatilization during at 40～160 ℃ of states at product, after airborne active ingredient reached certain concentration, promptly insects such as mosquitos and flies, cockroach, louse or acarid being produced stimulated, expels, benumbs, knocks down and lethal effect.
(2) electric mosquito repellent tablet:
Described electric mosquito repellent tablet is that the solution that will contain the present composition drips and/or be coated in the product that makes on the carrier, and it is main base material that this carrier also can be porosity; The content that adds The compounds of this invention in unit (sheet) anti-mosquito incense sheet generally is no more than 30mg, and for example according to the different in kind of active compound component, its content can be 1-20mg/ sheet or composite with other chemicals, makes the mosquito sheet.
The carrier of above-mentioned electric mosquito repellent tablet or porosity are that main base material comprises paper pulp, asbestos, synthetic porous resin, porous, inorganic powder, glass fibre, sulphur thing powder or porous ceramic material; The size of this carrier has determined the size of electric mosquito repellent flake products, and in order to use factors such as convenient, carrier and this product are generally long 30-35mm, wide 20-22mm, the tablet of thick 1.5-2mm.From the viewpoint of absorbability and reservation insecticidal active ingredient, carrier preferably is in natural fiber material.In a preferred embodiment of the invention, this carrier is the sheet material that contains the paper pulp fiber of the cotton fiber of 50%wt and 50%wt.
When near the habitat of insect or its, using electric mosquito repellent tablet of the present invention,, make that the active compound component in the electric mosquito repellent tablet slowly discharges, it is diffusing to wave by the certain temperature of electric boiling plate control.After the active ingredient in space reached certain concentration, just can produce sanitary insect pests such as mosquitos and flies, cockroach, louse or acarids stimulate, expel, benumb, knock down and lethal effect, thereby reaches insecticidal effect.
(3) vaporizer mosquito liquid:
Described vaporizer mosquito liquid is that the present composition is dissolved in the aliphatic hydrocarbon, the aliphatic hydrocarbon of the preferred C12-19 component of this aliphatic hydrocarbon, add the solution that accounts for 0.04-0.50%wt in the antioxidant, preparation cost invention composition product mosquito-repellent incense liquid of 0.1-0.5% greatly then, significantly reduce than conventional formulation dosage.
Vaporizer mosquito liquid is generally used with Electric heating, and this product is also referred to as electric liquid device.Electric liquid device is used principle: by the capillarity of carrier plug, mosquito-repellent incense liquid is taken to the top of new edition from the bottom of plug, under the heat effect of electric heater, active component slowly discharges, and can produce insecticidal action when the effective active composition in space reaches certain concentration.
(4) insect aerosol:
Described insect aerosol is with the present composition and the composition that mixes under room temperature or heating condition of synergist, aromatic, bactericide, the kerosene according to circumstances selected is packed into and had in the container of control valve, and under pressure, in jar, add propellant by this control valve and make preferred liquefied petroleum gas of this propellant or compressed air.
During use, opening controlling valve, under the pressure effect of propellant, produce high velocity air in the container of aerosol, the compound soup that wherein contains active component is disperseed, atomizes, form small liquid particles and be suspended in the air, with the effect that can reach quick kill pests after insects such as mosquitos and flies, cockroach, louse or acarid contact.
Above-mentioned experiment is the part of numerous effect experiments of the present invention, and more experimental data is not enumerated one by one.
The objective of the invention is in order to overcome the existing lower defective of insecticidal materials activity.The inventor by discover insecticide solution of the present invention have that consumption is few, the kill pests kind is many, to advantages such as person poultry harmless.Above-mentioned insecticides can reduce the dose that need use under the prerequisite that does not reduce drug effect, thereby reduces the toxicity to non-target organism, improves safety, reduces the left drug environmental pollution.The present composition has the insecticidal activity that household sanitary insect pests such as mosquito, fly, roach ant, louse is had efficient, the low toxicity of high ability of knocking down and kill capability, is applicable to domestic sanitary product field and is used as domestic pesticide.
Embodiment: following with detailed explanation technical scheme of the present invention of embodiment form and effect, but the present invention is not limited in following examples.
Formulation embodiment 1
With 2 of 0.04 weight portion, 3,5,6-tetrafluoro-4-methoxy benzyl-3-(3,3,3-three fluoro-1-acrylic)-2, the 1R-2 of 2-dimethyl cyclopropane carboxylic acid ester active component (1) and 0.2 weight portion, 3,5,6-tetrafluoro-4-methoxy benzyl-3-(2,2-two chloro-1-vinyl)-2,2-dimethyl cyclopropane carboxylic acid ester active component (2) is dissolved in the deodorized kerosine of 59.76 weight portions, with the gained oil solution aerosol cylinder of packing into, and in the aerosol cylinder of under the pressurization situation liquefied petroleum gas of 40 weight portions being packed into, the valve by the aerosol cylinder can produce the oily aerosol.
Formulation embodiment 2
The active component (1) of 0.12 weight portion and the active component (2) of 0.12 weight portion are dissolved in the deodorized kerosine of 59.76 weight portions, with the gained oil solution aerosol cylinder of packing into, and in the aerosol cylinder of under the pressurization situation liquefied petroleum gas of 40 weight portions being packed into, the valve by the aerosol cylinder can produce the oily aerosol.
Formulation embodiment 3
The active component (1) of 0.24 weight portion is dissolved in the deodorized kerosine of 59.76 weight portions, with the gained oil solution aerosol cylinder of packing into, and in the aerosol cylinder of under the pressurization situation liquefied petroleum gas of 40 weight portions being packed into, the valve by the aerosol cylinder can produce the oily aerosol.
Formulation embodiment 4
The active component (2) of 0.24 weight portion is dissolved in the deodorized kerosine of 59.76 weight portions, with the gained oil solution aerosol cylinder of packing into, and in the aerosol cylinder of under the pressurization situation liquefied petroleum gas of 40 weight portions being packed into, the valve by the aerosol cylinder can produce the oily aerosol.
Application example 1
Formulation embodiment 1,2,3,4 of the present invention is carried out efficacy testing to insect according to GB13917.2-92, adopt airtight drum device.Detailed process is as follows: will put into cylinder for 50 Culex pipiens pallens insects of examination; after waiting to try worm recovery normal activity; metered injection from insect aerosol jar of the present invention; extracting baffle plate behind the 1min out makes the examination worm contact timing immediately, and opening entry with medicament; write down down and out examination borer population at regular intervals; will be all behind the 20min be transferred in the dependent insect cage of cleaning for the examination worm and calculate rate of knockdown, feeding was measured lethality after 24 hours.
In contrast, adopt above-mentioned similar program determination to contain the aerosol of alkynes third chrysanthemum ester or tetramethrin.Display list 1 as a result.
The insect aerosol of table 1 The compounds of this invention preparation is to the insect killing effect of fly, cockroach
The result shows: the aerosol of present composition preparation has excellent insecticidal activity
Formulation embodiment 5
The water and the hybrid shaping that add 120 weight portions in the mixture of corn starch, carbon dust and the wood powder (1: 2～6: 3～5) of 99.9 weight portions, oven dry forms the incense coil base material then.The active component (2) of the active component (1) of 0.1 weight portion and 0.1 weight portion is dissolved in to be configured to concentration in the sweet gasoline be 0.2w/v% solution.Evenly drip the above-mentioned mixed solution of 10ml on above-mentioned incense coil base material, placement got final product in about 2～5 hours under the room temperature, obtained having 0.02w/w% coiled mosquito-repellent incense (1).
Formulation embodiment 6
The water and the hybrid shaping that add 120 weight portions in the mixture of corn starch, carbon dust and the wood powder (1: 2～6: 3～5) of 99.9 weight portions, oven dry forms the incense coil base material then.The active component (1) of 0.2 weight portion is configured to concentration in sweet gasoline be 0.2w/v% solution.Evenly drip the above-mentioned solution of 10ml on above-mentioned incense coil base material, placement got final product in about 2～5 hours under the room temperature, obtained having 0.02w/w% coiled mosquito-repellent incense (2).
Formulation embodiment 7
The water and the hybrid shaping that add 120 weight portions in the mixture of corn starch, carbon dust and the wood powder (1: 2～6: 3～5) of 99.9 weight portions, oven dry forms the incense coil base material then.The active component (2) of 0.2 weight portion is dissolved in to be configured to concentration in the sweet gasoline be 0.2w/v% solution.Evenly drip the above-mentioned solution of 10ml on above-mentioned incense coil base material, placement got final product in about 2～5 hours under the room temperature, obtained having 0.02w/w% coiled mosquito-repellent incense (3).
Test examples 2
The coiled mosquito-repellent incense of formulation embodiment 5,6,7 is carried out kill mosquito evaluation of pesticide effectiveness contrast according to GB13917.4-92, and the examination worm is a Culex pipiens pallens; Detailed process is to draw 20 examination mosquitos with mosquito sucking tube, puts into airtight drum testing arrangement, appoints and gets one section of tested mosquito-repellent incense, put to fragrant frame, light timing, remove mosquito-repellent incense behind the 1min, write down down and out examination mosquito number at set intervals, will all be transferred in the dependent insect cage of cleaning behind the 20min for the examination mosquito.Calculating K T50 value.
As a comparison, adopt the coiled mosquito-repellent incense of above-mentioned similar program determination Es-allethrin.Experimental result sees Table 2
The comparison of table 2. present composition and control compounds effect exterminating mosquito
| Sequence number | Active ingredient | Concentration w/w% | KT50(min) |
| Formulation implements 5 | Composition | 0.02 | 2’34″ |
| Formulation implements 6 | Compound (1) | 0.02 | 8’52″ |
| Formulation implements 7 | Compound (2) | 0.02 | 9’16″ |
| Contrast Es-allethrin | The Es-allethrin | 0.2 | 12’07″ |
The result shows that the relative effectivenes of this compound composition is at more than 40 times of Es-allethrin.Significantly better than allethrin, transfluthrin, the alkynes third chrysanthemum ester, tetrafluoro methothrin.
Formulation embodiment 8
Active component (2) and 15mg 2 with the active component that contains 2mg (1), 2mg, the solution impregnating carrier porous pad of the ATBC of 6-di-tert-butyl-4-methy phenol, 1mg (cotton fiber: about 1: 1 of paper pulp fiber), placed 3 days under the room temperature, make electric mosquito repellent tablet.
Formulation embodiment 9
Solution impregnating carrier porous pad (cotton fiber: about 1: 1 of paper pulp fiber), placed 3 days under the room temperature, make electric mosquito repellent tablet with the ATBC of the active component that contains 4mg (2) and 15mg 2,6 di tert butyl 4 methyl phenol, 1mg.Formulation embodiment 8 of the present invention; ATBC in 9 can be used citroflex A-4; triethyl citrate; DOTP; trioctyl trimellitate (TOTM); dioctyl adipate; di-n-octyl sebacate; the nylon acid diisobutyl ester; dioctyl phthalate; dibutyl phthalate; diisobutyl phthalate; diisopropyl phthalate; dipropyl phthalate; dipropyl adipate; diisopropyl adipate; dibutyl adipate; diisobutyl adipate; isopropyl myristate or ethyl stearte replace; 2,6 di tert butyl 4 methyl phenol can replace with ditert-butylhydro quinone.
Application Example 3
The alkynes third chrysanthemum ester electric mosquito repellent tablet of formulation example 8,9 of the present invention and at present the most frequently used 10mg/ sheet is carried out evaluation of pesticide effectiveness contrast to mosquito according to GB13917.5-92, adopt airtight drum device.Specific as follows: with electric mosquito repellent tablet sample energising preheating 1h, 2h, 4h, 6h, 8h.Draw 20 female Culex pipiens pallens with mosquito sucking tube, put into airtight drum testing arrangement, accurate smoked kill 1min, timing has simultaneously been smoked back segment power supply, and has been removed the electric mosquito repellent tablet device, notes down down and out examination mosquito number at regular intervals.The results are shown in Table 3:
The electric mat of table 3. The compounds of this invention preparation and the effect of the alkynes third chrysanthemum ester electric mat are relatively
The result shows: with at the alkynes third chrysanthemum ester anti-mosquito incense sheet 3～4 times of the electric mat relative effectivenes of present composition preparation.
Formulation embodiment 10
With the active component (1) of 0.1 weight portion and active component (2) and 0.3 part of 2,6 di tert butyl 4 methyl phenol of 0.1 weight portion, the aliphatic hydrocarbon Hybrid Heating of the C14 of surplus is prepared into vaporizer mosquito liquid.This vaporizer mosquito liquid can be become electric liquid device, wherein containing active compound component is 0.04w/w%.
The alkynes third chrysanthemum ester vaporizer mosquito liquid of formulation embodiment 10 of the present invention and 1% is carried out evaluation of pesticide effectiveness contrast according to GB13917.6-92, adopt airtight drum device.With vaporizer mosquito liquid sample energising 2h, 36h, 84h, 168h, draw 20 female Culex pipiens pallens with mosquito sucking tube, put into device, accurate smoked kill 1min, timing simultaneously, smoked object for appreciation is complete cuts off the electricity supply, and removes the vaporizer mosquito liquid device, and record is at regular intervals gone down to such an extent that be examination mosquito number.The results are shown in Table 4:
The vaporizer mosquito liquid of table 4. The compounds of this invention preparation and the alkynes third chrysanthemum ester vaporizer mosquito liquid effect are relatively
The result shows: the relative effectivenes of the vaporizer mosquito liquid of present composition preparation is at about 10 times of the alkynes third chrysanthemum ester vaporizer mosquito liquid.
Claims (7)
1. insecticides, it is characterized in that: contain 2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, be called for short active component (1) and 1R-2,3,5,6-tetrafluoro-4-methoxy benzyl-3-(2,2-two chloro-1-vinyl)-2,2-dimethyl cyclopropane carboxylic acid ester is called for short active component (2) as active insecticidal components, and with other at least a the total number of carbon atoms that are selected from be 14～26 Ester, the total number of carbon atoms is that 16～26 phenol type substances or carbon number always are the insecticides that 6～20 varsol material is formed
Active component (1) percetage by weight as active insecticidal components in the composition is that 0.02～0.30wt% and active component (2) percetage by weight are 0.02～0.20wt%, and the overall weight percent of Ester, phenol type substances or varsol is 99.50～99.96wt%.
2. a kind of insecticides according to claim 1 is characterized in that: described the total number of carbon atoms is that 14～26 Ester has ATBC; citroflex A-4; triethyl citrate; DOTP; trioctyl trimellitate (TOTM); dioctyl adipate; di-n-octyl sebacate; the nylon acid diisobutyl ester; dioctyl phthalate; dibutyl phthalate; diisobutyl phthalate; diisopropyl phthalate; dipropyl phthalate; dipropyl adipate; diisopropyl adipate; dibutyl adipate; diisobutyl adipate; isopropyl myristate or ethyl stearte.
3. a kind of insecticides according to claim 1 is characterized in that: described the total number of carbon atoms is that 16～26 phenol type substances has 2,6 di tert butyl 4 methyl phenol, ditert-butylhydro quinone.
4. a kind of insecticides according to claim 1, it is characterized in that: described the total number of carbon atoms is that 6～20 varsols have toluene, normal paraffin hydrocarbons, isoparaffin and cycloalkane, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane or their mixture, kerosene, gasoline.
5. the application of an insecticides is characterized in that: above-mentioned insecticides is meant and is prepared into incense coil, vaporizer mosquito liquid, electric mosquito repellent tablet or aerial fog pesticide.
6. the application of a kind of insecticides according to claim 5 is characterized in that: the prepared formulation of above-mentioned insecticides is applied to the control of mosquito, fly, cockroach, ant and louse insect.
7. the application of a kind of insecticides according to claim 5 is characterized in that: the formulation of above-mentioned insecticides is used for the habitat of insect or insect and uses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110178215A CN102283240A (en) | 2011-06-29 | 2011-06-29 | Pesticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110178215A CN102283240A (en) | 2011-06-29 | 2011-06-29 | Pesticide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102283240A true CN102283240A (en) | 2011-12-21 |
Family
ID=45330220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110178215A Pending CN102283240A (en) | 2011-06-29 | 2011-06-29 | Pesticide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102283240A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109511656A (en) * | 2018-11-16 | 2019-03-26 | 中山榄菊日化实业有限公司 | A kind of micro-electric heating anti-mosquito incense sheet |
| CN109907067A (en) * | 2017-12-12 | 2019-06-21 | 江苏扬农化工股份有限公司 | It can be used for the ester compounds of desinsection |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100545144C (en) * | 2008-04-29 | 2009-09-30 | 江苏扬农化工股份有限公司 | A kind of optically active pyrethroid coumpound and its production and application |
| CN101543225A (en) * | 2009-05-15 | 2009-09-30 | 江苏扬农化工股份有限公司 | Insecticide mother liquor and use thereof |
| CN101747198A (en) * | 2009-12-30 | 2010-06-23 | 贵阳柏丝特化工有限公司 | Method for preparing trans-pyrethroid and application of trans-pyrethroid |
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
-
2011
- 2011-06-29 CN CN201110178215A patent/CN102283240A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100545144C (en) * | 2008-04-29 | 2009-09-30 | 江苏扬农化工股份有限公司 | A kind of optically active pyrethroid coumpound and its production and application |
| CN101543225A (en) * | 2009-05-15 | 2009-09-30 | 江苏扬农化工股份有限公司 | Insecticide mother liquor and use thereof |
| CN101747198A (en) * | 2009-12-30 | 2010-06-23 | 贵阳柏丝特化工有限公司 | Method for preparing trans-pyrethroid and application of trans-pyrethroid |
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109907067A (en) * | 2017-12-12 | 2019-06-21 | 江苏扬农化工股份有限公司 | It can be used for the ester compounds of desinsection |
| CN109511656A (en) * | 2018-11-16 | 2019-03-26 | 中山榄菊日化实业有限公司 | A kind of micro-electric heating anti-mosquito incense sheet |
| CN109511656B (en) * | 2018-11-16 | 2021-09-10 | 中山榄菊日化实业有限公司 | Miniature electric heating mosquito-repellent incense piece |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100584817C (en) | Pyrethroid compound and uses | |
| CN101473842B (en) | Insecticidal composition | |
| CN101323571B (en) | Pyrethroid compounds, preparation and use thereof | |
| CN101580471B (en) | Pyrethroid compound, preparation method and application thereof | |
| CN101897342A (en) | Preparation of insecticide solution and application thereof | |
| CN102308797A (en) | Liquid fly-killing incense | |
| CN101348437B (en) | Pyrethroid compounds, preparation and use thereof | |
| CN102283240A (en) | Pesticide composition | |
| TWI586274B (en) | Insect pest control product and insect pest control method | |
| CN108601339B (en) | Wick for heat evaporation, method for producing same, and heat evaporation method using same | |
| CN101643414B (en) | Cyclopropane carboxylic ester compound containing chlorine and fluorine and preparation and application thereof | |
| JP5934583B2 (en) | Composition for killing pests | |
| CN101779640B (en) | Pesticidal composite | |
| CN101492393B (en) | Pyrethroid compounds, preparation and use thereof | |
| CN101880260A (en) | Insecticidal ester compound and preparation and application thereof | |
| CN102584710B (en) | Chloric perfluorocyclopropane carboxylic ester type compound as well as preparation and application thereof | |
| CN102976944A (en) | Pyrethroid compound as well as preparation method and application thereof | |
| CN101830805A (en) | Fluoropyrethroid containing compound as well as synthesis method and application thereof | |
| AU2012230844B2 (en) | Pyrethrin based repellant | |
| TW201633919A (en) | Aqueous insecticidal composition for heat-transpiration, and heat-transpiration method of the same | |
| CN102134194B (en) | Ester compound with insecticidal activity | |
| CN101508647A (en) | Fluorine benzyl ethyl cyclopropane dicarboxylate compound, synthesis and uses thereof | |
| CN101878776A (en) | Insecticide composition and preparation method and application thereof | |
| CN101735104B (en) | Pyrethroid compound and application thereof | |
| CN101953372A (en) | Composition containing chlorine fluorine ethofenprox and malathion and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20111221 |