CN101776213B - Nano rare-earth luminous lamp and manufacturing method thereof - Google Patents
Nano rare-earth luminous lamp and manufacturing method thereof Download PDFInfo
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- CN101776213B CN101776213B CN 200910036746 CN200910036746A CN101776213B CN 101776213 B CN101776213 B CN 101776213B CN 200910036746 CN200910036746 CN 200910036746 CN 200910036746 A CN200910036746 A CN 200910036746A CN 101776213 B CN101776213 B CN 101776213B
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Abstract
The invention discloses a nano rare-earth luminous lamp and a manufacturing method thereof. The nano rare-earth luminous lamp comprises a lamp holder (10), wherein the lamp holder (10) is provided with a lamp body (13); a luminous layer (30) is arranged outside the lamp body (13); a reflective layer (20) is arranged on the inner side of the luminous layer (30); and the outer surface of the luminous layer (30) is provided with a transparent protective layer (40). The luminous layer (30) comprises the following components in percentage by mass: 15 to 50 percent of luminous powder, 0.08 to 0.5 percent of nano titanium dioxide, 0 to1 percent of anti-aging agent and the balance of mixed glue which consists of a transparent resin and a curing agent. The lower end of the lamp body of the lamp holder (10) is provided with a support pillar (12); and the lower end of the support pillar (12) is provided with a chassis (11). The nano rare-earth luminous lamp of the invention has the characteristics of high intensity, long service life, no toxicity or radioactivity, environment protection and energy conversation, and has the functions of low illumination, indicating, warning and environment beautifying.
Description
Technical field
The present invention relates to a kind of passive night light, particularly a kind of nano rare-earth luminous lamp and manufacture method thereof.
Background technology
Along with progress and the growth in the living standard of society, people's awareness of saving energy, awareness of safety, caution consciousness, environmental consciousness strengthen, and all bring into use energy-saving lamp in many fields such as traffic, fire-fightings for this reason, to warn and indication etc.
For this reason, a kind of passive night light of being made by self-luminescent material has appearred on the market.This luminous lamp is general to be adopted and has the material and the transparent resin that hold light action and make luminescent layer, can absorb light and storage power when light is strong, but self-luminescence again a little less than light the time.Yet the luminescent layer intensity difference of this existing passive luminous lamp easily damages, and the life-span is shorter.
During the luminescent layer of current manufacturing luminous lamp, all be simultaneously curing agent and luminescent powder to be added transparent resin and stir usually; At last the mixture that stirs is added mould and carry out moulding.The luminescent layer intensity difference and the luminosity that adopt the method to make are low.
Summary of the invention
One of main purpose of the present invention is to provide a kind of intensity good for the deficiency that above-mentioned prior art exists, and is not fragile, nano rare-earth luminous lamp that can be life-extending.
Two of main purpose of the present invention provides a kind of manufacture method that improves the nano rare-earth luminous lamp of luminescent layer intensity and brightness.
For one of achieving the above object, nano rare-earth luminous lamp provided by the present invention comprises lamp socket, and lamp socket has the lamp body, and described lamp body is provided with luminescent layer outward; The component of described luminescent layer and the mass content of component be, luminescent powder 10-50%, and nano-titanium oxide 0.08-0.5%, age resister 0-1%, surplus is the epoxy glue that is comprised of transparent resin and curing agent; Be provided with reflector layer between described luminescent layer and the lamp body, the component of described reflector layer and the mass content of component be, nano-titanium oxide 0.5-2%, and surplus is transparent resin; Described luminescent layer contains the fire retardant that mass content is 5-15%; The outer surface of described luminescent layer is coated with protective clear layer; The component of described protective clear layer and the mass content of component be, particle diameter is the nano-cerium oxide 0.05-0.1% of 0.3-0.8 micron, and surplus is the high macromolecule UV gloss oil that solidifies; Be fixed with a pillar below the lamp body of described lamp socket, the pillar middle part has the lug boss that roughly is spheroidal; Described lamp socket has a chassis of being fixed in below the pillar.
Above-mentioned nano rare-earth luminous lamp is owing to containing luminescent powder in the luminescent layer, can be by absorbing sunshine and light accumulation of energy, without power consumption, but self-luminescence just in a little less than light, thereby have the low effect of throwing light on, indicate, warn and beautify the environment, also have certain ornamental value simultaneously; Because increased the nano-titanium oxide of intensity and the hardness that can improve luminescent layer, so nano rare-earth luminous lamp intensity of the present invention is good, the life-span is long, and nontoxic, and is "dead", environmental protection and energy saving.The effect of reflector layer is to increase light emission rate.Fire retardant can improve its fire resistance.Increase the service life that protective clear layer can prolong product.Cerium oxide in the protective clear layer can strengthen the performance of nano rare-earth luminous lamp protective clear layer acid-proof, alkali prevention and antiultraviolet, prolongs the life-span of nano rare-earth luminous lamp, strengthens weatherability.The effect of pillar is convenient to the fixing of nano rare-earth luminous lamp and is placed.
In the above-mentioned nano rare-earth luminous lamp, described transparent resin is unsatured epoxy resin, and described luminescent powder is the rare earth aluminate luminescent powder.
In the above-mentioned nano rare-earth luminous lamp, described lamp socket is made by macromolecular material or metal material.
For achieve the above object two, the manufacture method of nano rare-earth luminous lamp provided by the present invention comprises step:
(1) is that 1: 1 transparent resin and curing agent are mixed and stir with mass ratio, forms epoxy glue; Adding particle diameter in the epoxy glue is the nano-titanium oxide 0.08-0.5% of 0.3-0.8 micron and stirs; Then, add again 10-50% luminescent powder and stirring; At last the mixture that stirs is added mould, can obtain luminescent layer after the mixture moulding;
(2) transparent resin and curing agent is mixed and stir, form mixture; In mixture, add the 0.5-2% nano-titanium oxide, stir; And then the mixture that will be added with nano-titanium oxide is coated in the inboard of luminescent layer, can obtain reflector layer behind the curing molding;
(3) solidify to height that to add particle diameter in the macromolecule UV gloss oil be the nano-cerium oxide 0.05-0.1% of 0.3-0.8 micron, stir, obtain compound gloss oil; Compound gloss oil is coated in the outer surface of luminescent layer, can obtains protective clear layer behind the curing molding;
(4) whole in connection with together protective clear layer, luminescent layer and reflector layer, be adhesively fixed on the lamp body of lamp socket, can obtain the above-mentioned nano rare-earth luminous lamp of moulding.
The manufacture method of above-mentioned nano rare-earth luminous lamp is called in-situ inserted group of connection polymerization, and the method epoxy glue can be coated with nano titania particle better and produce polymerization, thereby not only can play better invigoration effect to luminescent layer; And can improve the luminosity of nano rare-earth luminous lamp, so that the effect that reaches luminous or even give out light; The connected mode of reflector layer and luminescent layer can further improve the bulk strength of the two.
Description of drawings
Fig. 1 is the partial sectional view of a kind of embodiment of nano rare-earth luminous lamp of the present invention.
Fig. 2 is the partial sectional view of the another kind of embodiment of nano rare-earth luminous lamp of the present invention.
The specific embodiment
For describing technology contents of the present invention, structural feature, the purpose of reaching and effect in detail, below in conjunction with embodiment and cooperate accompanying drawing to give in detail explanation.
See also Fig. 1; the first embodiment of nano rare-earth luminous lamp of the present invention comprises the lamp socket 10 of being made by high-intensity macromolecular material (also can be metal material); the upper end of lamp socket 10 has a lamp body 13; lamp body 13 is coated with the reflector layer 20 of one deck white; reflector layer 20 is coated with one deck luminescent layer 30, and luminescent layer 30 is coated with layer of transparent protective layer 40.
Described lamp body 13 roughly is the semicircle hull shape, is fixed with pillar 12 below the lamp body 13, and the middle part of pillar 12 has a lug boss 121 spherical in shape roughly.The lower end of this pillar 12 is fixed with a chassis 11 in the form of annular discs roughly.The effect of this lamp socket 10 is convenient to the fixing of lamp and is placed, and seems attractive in appearance.
The component of described reflector layer 20 and the mass content of component be, particle diameter is the nano-titanium oxide 0.5-2% of 0.3-0.8 micron, and surplus is the mixture that is comprised of transparent resin and curing agent.
The component of described luminescent layer 30 and the mass content of component are, rare earth aluminate luminescent powder 10-50%, fire retardant 5-15%, particle diameter is the nano-titanium oxide 0.08-0.5% of 0.3-0.8 micron, age resister 0-1%, surplus is the epoxy glue that is comprised of with 1: 1 ratio transparent unsatured epoxy resin and curing agent.
The quality percentage composition of the component of above-mentioned luminescent layer 30 and component can be any a group in the following table.
The component of described protective clear layer 40 and the mass content of component be, particle diameter is the nano-cerium oxide 0.05-0.1% of 0.3-0.8 micron, and surplus is the high macromolecule UV gloss oil that solidifies.Protective clear layer 40 is to cover luminescent layer 30 surfaces by the mode of spraying or be coated with.See also Fig. 2, the second embodiment of nano rare-earth luminous lamp of the present invention and above-mentioned the first embodiment are basic identical, and its difference only is that face shaping is different, and the pillar 12 among this embodiment is cylindrical.
Nano rare-earth luminous lamp that the invention described above provides can adopt the manufacturing of in-situ inserted group of connection polymerization, and the method comprises the following steps:
(1) is that 1: 1 transparent resin and curing agent are mixed and stir with mass ratio, forms epoxy glue; Adding particle diameter in the epoxy glue is the nano-titanium oxide 0.08-0.5% of 0.3-0.8 micron and stirs; Then, add again 10-50% luminescent powder and stirring; At last the mixture that stirs is added mould, can obtain luminescent layer 30 after the mixture moulding;
(2) transparent resin and curing agent is mixed and stir, form mixture; In mixture, add the 0.5-2% nano-titanium oxide, stir; And then the mixture that will be added with nano-titanium oxide is coated in the inboard of luminescent layer 30, can obtain reflector layer 20 behind the curing molding;
(3) solidify to height that to add particle diameter in the macromolecule UV gloss oil be the nano-cerium oxide 0.05-0.1% of 0.3-0.8 micron, stir, obtain compound gloss oil; Compound gloss oil is coated in the outer surface of luminescent layer 30, can obtains protective clear layer 40 behind the curing molding;
(4) in connection with together protective clear layer 40, luminescent layer 30 and reflector layer 20 integral body, be adhesively fixed on the lamp body 13 of lamp socket 10, can obtain the above-mentioned nano rare-earth luminous lamp of moulding.
As mentioned above, nano rare-earth luminous lamp of the present invention contains the nano-titanium oxide that can improve intensity and hardness owing in luminescent layer 30 components, so the intensity of luminescent layer 30 and hardness are higher and not fragile.Cerium oxide in the protective clear layer 40 can strengthen the performance of nano rare-earth luminous lamp acid-proof, alkali prevention and antiultraviolet, has simultaneously certain self-cleaning function, thereby can prolong the life-span of nano rare-earth luminous lamp, strengthens weatherability.Fire retardant can improve its fire resistance.The effect of reflector layer 20 is to increase light emission rate, and reflector layer 20 intensity that are comprised of transparent resin and nano-titanium oxide are good.Above-mentioned nano rare-earth luminous lamp is owing to containing luminescent powder in the luminescent layer 30, can be by absorbing sunshine and light accumulation of energy, without power consumption, but self-luminescence just in a little less than light, thereby have the low effect of throwing light on, indicate, warn and beautify the environment, also have certain ornamental value simultaneously; In a word, nano rare-earth luminous lamp intensity of the present invention is good, and the life-span is long, and nontoxic, and is "dead", environmental protection and energy saving.
In the in-situ inserted group of connection polymerization manufacture method of above-mentioned nano rare-earth luminous lamp, epoxy glue can be coated with nano titania particle better and produce polymerization, thereby not only can play better invigoration effect to luminescent layer; And can improve the luminosity of nano rare-earth luminous lamp, so that the effect that reaches luminous or even give out light; The connected mode of reflector layer and luminescent layer can further improve the bulk strength of the two.
Claims (4)
1. nano rare-earth luminous lamp, comprise lamp socket (10), lamp socket (10) has lamp body (13), the outer luminescent layer (30) that is provided with of lamp body (13), it is characterized in that: the component of described luminescent layer (30) and the mass content of component are luminescent powder 10-50%, nano-titanium oxide 0.08-0.5%, age resister 0-1%, surplus is the epoxy glue that is comprised of transparent resin and curing agent; Be provided with reflector layer (20) between described luminescent layer (30) and the lamp body (13), the component of described reflector layer (20) and the mass content of component be, nano-titanium oxide 0.5-2%, and surplus is transparent resin; Described luminescent layer (30) contains the fire retardant that mass content is 5-15%; The outer surface of described luminescent layer (30) is coated with protective clear layer (40); The component of described protective clear layer (40) and the mass content of component be, particle diameter is the nano-cerium oxide 0.05-0.1% of 0.3-0.8 micron, and surplus is the high macromolecule UV gloss oil that solidifies; Be fixed with a pillar (12) below the lamp body (13) of described lamp socket (10), pillar (12) middle part has the lug boss (121) that roughly is spheroidal; Described lamp socket (10) has one and is fixed in the following chassis (11) of pillar (12).
2. nano rare-earth luminous lamp as claimed in claim 1, it is characterized in that: described transparent resin is unsatured epoxy resin, described luminescent powder is the rare earth aluminate luminescent powder.
3. nano rare-earth luminous lamp as claimed in claim 1, it is characterized in that: described lamp socket (10) is made by macromolecular material or metal material.
4. the manufacture method of a nano rare-earth luminous lamp as claimed in claim 1, the method comprising the steps of:
(1) is that 1: 1 transparent resin and curing agent are mixed and stir with mass ratio, forms epoxy glue; Adding particle diameter in the epoxy glue is the nano-titanium oxide 0.08-0.5% of 0.3-0.8 micron and stirs; Then, add again 10-50% luminescent powder and stirring; At last the mixture that stirs is added mould, can obtain luminescent layer (30) after the mixture moulding;
(2) transparent resin and curing agent is mixed and stir, form mixture; In mixture, add the 0.5-2% nano-titanium oxide, stir; And then the mixture that will be added with nano-titanium oxide is coated in the inboard of luminescent layer (30), can obtain reflector layer (20) behind the curing molding;
(3) solidify to height that to add particle diameter in the macromolecule UV gloss oil be the nano-cerium oxide 0.05-0.1% of 0.3-0.8 micron, stir, obtain compound gloss oil; Compound gloss oil is coated in the outer surface of luminescent layer (30), can obtains protective clear layer (40) behind the curing molding;
(4) in connection with together protective clear layer (40), luminescent layer (30) and reflector layer (20) integral body, be adhesively fixed on the lamp body (13) of lamp socket (10), can obtain the above-mentioned nano rare-earth luminous lamp of moulding.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200910036746 CN101776213B (en) | 2009-01-12 | 2009-01-12 | Nano rare-earth luminous lamp and manufacturing method thereof |
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| CN 200910036746 CN101776213B (en) | 2009-01-12 | 2009-01-12 | Nano rare-earth luminous lamp and manufacturing method thereof |
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| CN101776213A CN101776213A (en) | 2010-07-14 |
| CN101776213B true CN101776213B (en) | 2013-02-13 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102305353B (en) * | 2011-03-17 | 2013-03-13 | 浙江中交科技有限公司 | Multi-prism type light-reflecting luminous spike lamp and method for manufacturing same |
| CN104110636A (en) * | 2013-04-22 | 2014-10-22 | 广东纳明新材料科技有限公司 | Multifunctional luminous lamp |
| CN104110642B (en) * | 2013-04-22 | 2017-05-31 | 广东纳明新材料科技有限公司 | A kind of gardening light |
| CN103629621B (en) * | 2013-11-21 | 2018-08-07 | 董绍品 | A kind of spontaneous light scene lamp and its manufacturing method |
| CN103627199A (en) * | 2013-11-21 | 2014-03-12 | 陈奎鹏 | High-temperature resistant self-cleaning self-luminous material and preparation method thereof |
| CN114190236A (en) * | 2021-12-09 | 2022-03-18 | 杨莹 | Vegetation restoration method for northern ecological fragile area |
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| CN1843780A (en) * | 2006-01-26 | 2006-10-11 | 李昌海 | Novel functional decorative material inlaid with luminous material pattern and method for manufacturing the same |
| CN1971124A (en) * | 2006-11-30 | 2007-05-30 | 东莞市明光科技有限公司 | Passive night light |
| CN101231933A (en) * | 2007-01-25 | 2008-07-30 | 台达电子工业股份有限公司 | Cold cathode light tube |
| CN101333357A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Luminous paint and method for preparing same |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843780A (en) * | 2006-01-26 | 2006-10-11 | 李昌海 | Novel functional decorative material inlaid with luminous material pattern and method for manufacturing the same |
| CN1971124A (en) * | 2006-11-30 | 2007-05-30 | 东莞市明光科技有限公司 | Passive night light |
| CN101231933A (en) * | 2007-01-25 | 2008-07-30 | 台达电子工业股份有限公司 | Cold cathode light tube |
| CN101333357A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Luminous paint and method for preparing same |
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