CN101717190A - Moderate-borosilicate scarlet glass and preparation method - Google Patents
Moderate-borosilicate scarlet glass and preparation method Download PDFInfo
- Publication number
- CN101717190A CN101717190A CN200910155219A CN200910155219A CN101717190A CN 101717190 A CN101717190 A CN 101717190A CN 200910155219 A CN200910155219 A CN 200910155219A CN 200910155219 A CN200910155219 A CN 200910155219A CN 101717190 A CN101717190 A CN 101717190A
- Authority
- CN
- China
- Prior art keywords
- glass
- parts
- borosilicate
- bright red
- red glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims description 17
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 238000000137 annealing Methods 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 9
- 238000007669 thermal treatment Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000005352 clarification Methods 0.000 claims description 4
- 230000004927 fusion Effects 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract description 4
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005355 lead glass Substances 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 239000011669 selenium Substances 0.000 description 10
- 230000005540 biological transmission Effects 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000010979 ruby Substances 0.000 description 2
- 229910001750 ruby Inorganic materials 0.000 description 2
- 101100220616 Caenorhabditis elegans chk-2 gene Chemical group 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000005391 art glass Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- JLATXDOZXBEBJX-UHFFFAOYSA-N cadmium(2+);selenium(2-);sulfide Chemical compound [S-2].[Se-2].[Cd+2].[Cd+2] JLATXDOZXBEBJX-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000005315 stained glass Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
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Abstract
The invention relates to a composite prescription of a moderate-borosilicate scarlet glass and a preparation method. The scarlet glass is prepared by modifying the prescription of lead-bearing crystal glass and using organic pigments of cadmium yellow and selenium powder as colorants, and has the advantages of simple production process and operation procedure, stable glass product quality, even glass coloring without color difference phenomenon, high quality and low cost.
Description
(1) technical field
The present invention relates to the glass production field, particularly relate to a kind of prescription and preparation method of middle borosilicate bright red glass.
(2) background technology
Middle borosilicate bright red glass is a kind of artistic glassware of preciousness and the manufacturing matrix of glass ornaments.The preparation of middle borosilicate bright red glass is difficulty relatively, also not industrialized production now.It is big that middle borosilicate bright red glass has hardness, and color is more bright-coloured, and specific refractory power is big, sparkling and crystal-clear bright characteristics, and color and hardness and ruby are closely similar, can be used as ruby imitation as various artistic decorations.
In coloured glass is made, use the tinting material of selenium, sulphur and compound thereof can obtain color clear, broad-spectrum a series of goods, especially cadmium sulphoselenide glass occupies an important position, and is the glass that color is the purest, absorption curves is the most precipitous in making yellow, red glass at present.It is widely used in art glass, building glass, signal glass and filter glass.But this class glass requires strict on manufacturing process, could obtain the fine goods so must tighten control.In the borosilicate bright red glass because its prescription, the technology of preparation is special, does not also have technology sophisticated, the bright red glass that can commercially produce so far.
The characteristics of this glass are that tone is attractive in appearance pleasing, and chromatic dispersion is bigger, is suitable for cold and hot working, the combination that all kinds of colors form series, be convenient to carry out in the artwork processing tone with cooperate.
(3) summary of the invention
Middle borosilicate bright red glass is because technology of its prescription, preparation is special, so far also there is not sophisticated, business-like production technique, the technical problem to be solved in the present invention provides a kind of prescription and preparation technology thereof of middle borosilicate bright red glass, contain the lead crystal glass prescription by improvement, with mineral dye cadmium yellow and selenium powder is tinting material, again by thermal treatment obtain a kind of high quality, cheaply in the borosilicate bright red glass.
Technical scheme of the present invention is as follows:
A kind of in the borosilicate bright red glass, it is characterized in that described in the borosilicate bright red glass mainly form by the raw material of following weight part:
SiO
265-75 part;
Na
2O 3-10 part;
B
2O
35-15 part;
K
2O 2-7 part;
BaO 1-10 part;
ZnO 5-10 part;
CdS 0.5-1.5 part;
Se 0.1-1.0 part;
NaSiF
60.5-1.2 part.
The borosilicate bright red glass preferably is made up of the raw material of following weight part in described:
SiO
267-72 part;
Na
2O 3-8 part;
B
2O
37-12 part;
K
2O 4-6 part;
BaO 1-5 part;
ZnO 6-8 part;
CdS 0.3-1.0 part;
Se 0.1-0.75 part;
NaSiF6 0.5-1.0 part.
The borosilicate bright red glass more preferably is made up of the raw material of following weight part in of the present invention:
SiO
270 parts;
Na
24.2 parts of O;
B
2O
310.3 part;
K
24.7 parts of O;
1.6～3.7 parts of BaO;
7.0 parts of ZnO;
0.5～1.0 part of CdS;
0.2～0.5 part of Se;
NaSiF
61.0 part.
The borosilicate bright red glass also recommends to be made up of the raw material of following weight part in of the present invention:
SiO
265 parts;
Na
24.5 parts of O;
B
2O
312～15 parts;
K
24.7 parts of O;
2.9～3.8 parts of BaO;
7.0～8.0 parts of ZnO;
1～1.5 part of CdS;
0.5～1 part of Se;
NaSiF
60.5～1.0 parts.
The method of borosilicate bright red glass in a kind of preparation as described in the present invention, described middle borosilicate bright red glass is made up of following materials of weight proportions: SiO
265-75 part; Na
2O 3-10 part; B
2O
35-15 part; K
2O 2-7 part; BaO 1-10 part; ZnO 5-10 part; CdS 0.5-1.5 part; Se 0.1-1.0 part; NaSiF
60.5～1.0 parts; Described preparation method is:
(1) above-mentioned all raw materials is mixed by proportioning;
(2) raw material that mixes is formed glass metal in 1200～1300 ℃ of covered pots that drop into fusion cast glass, with glass metal glass metals after 1350～1450 ℃ of clarifications must be clarified in 3～7 hours under agitation; In clarifying process, need constantly to stir;
(3) after the glass metal after will clarifying is poured into mould molding, puts into annealing furnace and anneal, the control annealing temperature is 450～500 ℃, and annealing time is to obtain the moulding sample in 0.5～2 hour at once;
(4) with the moulding sample polishing that obtains in the step (3), put into resistance furnace and heat-treat colour developing, the thermal treatment colour temp of glass is controlled at 500 ℃-650 ℃, heat treatment time 5-60 minute, produces up to glass till the large red of expection.
Beneficial effect of the present invention is embodied in: containing the lead crystal glass prescription by improvement, is tinting material with mineral dye cadmium yellow and selenium powder, prepare a kind of high quality, cheaply in the borosilicate bright red glass; The production technique operating process is simple, the steady quality of glassy product, and the uniform coloring of glass the aberration phenomenon can not occur.
(4) description of drawings
Fig. 1 is a process flow sheet of the present invention.
Fig. 2 is the transmission curve of the middle borosilicate bright red glass sample that makes of the embodiment of the invention 1.
Fig. 3 is the transmission curve of the middle borosilicate bright red glass sample that makes of the embodiment of the invention 2.
Fig. 4 is the transmission curve of the middle borosilicate bright red glass sample that makes of the embodiment of the invention 3.
Fig. 5 is the transmission curve of the middle borosilicate bright red glass sample that makes of the embodiment of the invention 4.
(5) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
(1) raw material is according to following portions by weight proportioning: SiO
270 parts; Na
24.2 parts of O; B
2O
310.3 part; K
2O4.7 part; 1.6 parts of BaO; 7.0 parts of ZnO; 1.0 parts of CdS; 0.2 part of Se; NaSiF
61.0 part.
(2) various raw materials are required to mix in proportion, in the crucible of 1200 ℃ of input fusion cast glass, the clarifying temp of glass is controlled at 1450 ℃, settling time 3 hours, and during the clarification of glass, continuous stirred glass, the glass metal after obtaining clarifying.
(3) glass metal after the clarification, is put into annealing furnace and is annealed after the moulding through being poured into the mould of choosing in advance, and the control annealing temperature is 500 ℃, and annealing time is 0.5 hour, obtains the sample of moulding at once.
(4) sample of the moulding that described step (3) is obtained polishing is put into resistance furnace and is heat-treated colour developing, 550 ℃ of the thermal treatment temps of feed glass, and heat treatment time 60 minutes obtains large red glass.
(5) transmission curve of the bright red glass that obtains of step (4) as shown in Figure 2, wherein the thickness of bright red glass is 2mm.
Embodiment 2:
Difference from Example 1 is that raw material is pressed following weight proportion:
SiO
270 parts; Na
24.2 parts of O; B
2O
310.3 part; K
24.7 parts of O; 3.7 parts of BaO; 7.0 parts of ZnO; 0.5 part of CdS; 0.5 part of Se; NaSiF
61.0 part.Preparation process is identical with the method for embodiment 1.The transmission curve of the bright red glass that obtains as shown in Figure 3, wherein the thickness of bright red glass is 2mm.
Embodiment 3:
Difference from Example 1 is that raw material is pressed following weight proportion:
SiO
265 parts; Na
24.5 parts of O; B
2O
315 parts; K
24.7 parts of O; 2.9 parts of BaO; 7.0 parts of ZnO; 1.5 parts of CdS; 1.0 parts of Se; NaSiF
61.0 part.
Preparation process is identical substantially with the method for embodiment 1, and difference from Example 1 is that step (4) thermal treatment temp is 600 ℃, heat treatment time 30 minutes.The transmission curve of the bright red glass that obtains as shown in Figure 4, wherein the thickness of bright red glass is 2mm.
Embodiment 4:
Difference from Example 1 is that raw material is pressed following weight proportion:
SiO
265 parts; Na
24.5 parts of O; B
2O
312 parts; K
24.7 parts of O; 3.8 parts of BaO; 8 parts of ZnO; CdS1 part; 0.5 part of Se; NaSiF
60.5 part.
Preparation process is identical substantially with the method for embodiment 1, and difference from Example 1 is that step (4) thermal treatment temp is 650 ℃, heat treatment time 10 minutes.The transmission curve of the bright red glass that obtains as shown in Figure 5, wherein the thickness of bright red glass is 2mm.
Claims (5)
1. borosilicate bright red glass in a kind, it is characterized in that described in the borosilicate bright red glass mainly form by the raw material of following weight part:
SiO
265-75 part;
Na
2O 3-10 part;
B
2O
35-15 part;
K
2O 2-7 part;
BaO 1-10 part;
ZnO 5-10 part;
CdS 0.5-1.5 part;
Se 0.1-1.0 part;
NaSiF
60.5-1.0 part.
2. according to claim 1 in the borosilicate bright red glass, it is characterized in that described in the borosilicate bright red glass form by the raw material of following weight part:
SiO
267-72 part;
Na
2O 3-8 part;
B
2O
37-12 part;
K
2O 4-6 part;
BaO 1-5 part;
ZnO 6-8 part;
CdS 0.3-1.0 part;
Se 0.1-0.75 part;
NaSiF
60.5-1.0 part.
3. according to claim 1 in the borosilicate bright red glass, it is characterized in that described in the borosilicate bright red glass form by the raw material of following weight part:
SiO
270 parts;
Na
24.2 parts of O;
B
2O
310.3 part;
K
24.7 parts of O;
1.6～3.7 parts of BaO;
7.0 parts of ZnO;
0.5～1.0 part of CdS;
0.2～0.5 part of Se;
NaSiF
61.0 part.
4. according to claim 1 in the borosilicate bright red glass, it is characterized in that described in the borosilicate bright red glass form by the raw material of following weight part:
SiO
265 parts;
Na
24.5 parts of O;
B
2O
312～15 parts;
K
24.7 parts of O;
2.9～3.8 parts of BaO;
7.0～8.0 parts of ZnO;
1～1.5 part of CdS;
0.5～1 part of Se;
NaSiF
60.5～1.0 parts.
One kind prepare as claimed in claim 1 in the method for borosilicate bright red glass, it is characterized in that described in the borosilicate bright red glass form by following materials of weight proportions: SiO
265-75 part; Na
2O 3-10 part; B
2O
35-15 part; K
2O 2-7 part; BaO 1-10 part; ZnO 5-10 part; CdS 0.5-1.5 part; Se 0.1-1.0 part; NaSiF
60.5～1.0 parts; Described preparation method is:
(1) above-mentioned all raw materials is mixed by proportioning;
(2) raw material that mixes is formed glass metal in 1200～1300 ℃ of covered pots that drop into fusion cast glass, with glass metal glass metals after 1350～1450 ℃ of clarifications must be clarified in 3～7 hours under agitation;
(3) after the glass metal after will clarifying is poured into mould molding, puts into annealing furnace and anneal, the control annealing temperature is 450～500 ℃, and annealing time is to obtain the moulding sample in 0.5～2 hour at once;
(4) with the moulding sample polishing that obtains in the step (3), put into resistance furnace and heat-treat colour developing, the thermal treatment colour temp of feed glass is 500 ℃-650 ℃ simultaneously, heat treatment time 5-60 minute, produces up to glass till the large red of expection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101552198A CN101717190B (en) | 2009-12-08 | 2009-12-08 | Moderate-borosilicate scarlet glass and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101552198A CN101717190B (en) | 2009-12-08 | 2009-12-08 | Moderate-borosilicate scarlet glass and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101717190A true CN101717190A (en) | 2010-06-02 |
| CN101717190B CN101717190B (en) | 2011-12-21 |
Family
ID=42431838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101552198A Expired - Fee Related CN101717190B (en) | 2009-12-08 | 2009-12-08 | Moderate-borosilicate scarlet glass and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101717190B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320747A (en) * | 2011-06-27 | 2012-01-18 | 浙江伟兴水晶有限公司 | Preparation method of shallow crystal and yellow crystal bead blank |
| CN104692658A (en) * | 2015-02-27 | 2015-06-10 | 武汉理工大学 | Method for fixing CdS and Se in borosilicate glass |
| CN106186671A (en) * | 2016-07-15 | 2016-12-07 | 湖北戈碧迦光电科技股份有限公司 | A kind of bright red glass and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1316984A1 (en) * | 1985-12-13 | 1987-06-15 | Самостоятельное конструкторско-технологическое бюро по проектированию приборов и аппаратов из стекла | Red opacified glass |
| SU1669881A1 (en) * | 1989-08-07 | 1991-08-15 | Чернятинский стекольный завод | Red glass |
| CN101215088B (en) * | 2007-12-31 | 2010-06-09 | 浙江工业大学 | Copper ruby glass products and preparation method thereof |
| CN101215090B (en) * | 2007-12-31 | 2011-02-02 | 浙江工业大学 | Formulation of bright red crystal glass and manufacturing technology thereof |
-
2009
- 2009-12-08 CN CN2009101552198A patent/CN101717190B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320747A (en) * | 2011-06-27 | 2012-01-18 | 浙江伟兴水晶有限公司 | Preparation method of shallow crystal and yellow crystal bead blank |
| CN102320747B (en) * | 2011-06-27 | 2013-07-17 | 浙江伟兴水晶有限公司 | Preparation method of shallow crystal and yellow crystal bead blank |
| CN104692658A (en) * | 2015-02-27 | 2015-06-10 | 武汉理工大学 | Method for fixing CdS and Se in borosilicate glass |
| CN106186671A (en) * | 2016-07-15 | 2016-12-07 | 湖北戈碧迦光电科技股份有限公司 | A kind of bright red glass and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101717190B (en) | 2011-12-21 |
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| PB01 | Publication | ||
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Granted publication date: 20111221 |