WO2007083910A1 - Method for manufacturing artificial jewelry by adding gold to soda lime glass or crystal glass - Google Patents
Method for manufacturing artificial jewelry by adding gold to soda lime glass or crystal glass Download PDFInfo
- Publication number
- WO2007083910A1 WO2007083910A1 PCT/KR2007/000258 KR2007000258W WO2007083910A1 WO 2007083910 A1 WO2007083910 A1 WO 2007083910A1 KR 2007000258 W KR2007000258 W KR 2007000258W WO 2007083910 A1 WO2007083910 A1 WO 2007083910A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass
- added
- powder
- gold
- soda lime
- Prior art date
Links
- 239000010931 gold Substances 0.000 title claims abstract description 44
- 239000005361 soda-lime glass Substances 0.000 title claims abstract description 26
- 239000005355 lead glass Substances 0.000 title claims abstract description 23
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims description 27
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 22
- 229910003771 Gold(I) chloride Inorganic materials 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 4
- 239000004571 lime Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 4
- 241001122767 Theaceae Species 0.000 abstract description 2
- 235000013334 alcoholic beverage Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 238000010583 slow cooling Methods 0.000 description 3
- 238000004040 coloring Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 2
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/006—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of microcrystallites, e.g. of optically or electrically active material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C27/00—Making jewellery or other personal adornments
- A44C27/001—Materials for manufacturing jewellery
- A44C27/002—Metallic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B1/00—Preparing the batches
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/102—Glass compositions containing silica with 40% to 90% silica, by weight containing lead
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0028—Compositions for glass with special properties for crystal glass, e.g. lead-free crystal glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/16—Microcrystallites, e.g. of optically or electrically active material
Definitions
- the present invention relates to a method of manufacturing artificial jewelry by adding gold to soda lime glass or crystal glass.
- an object of the present invention is to provide a method of manufacturing artificial jewelry, in which gold is added to typical soda lime glass or crystal glass to thus realize artificial jewelry having various colors of high quality, which can then be used as material for various accessories and vessels, such as wine glasses, tea cups, punch bowls, and dishes.
- the present invention provides a method of manufacturing artificial jewelry by adding gold to soda lime glass, in which, in a material composition of a material mixing process for producing artificial jewelry comprising typical soda (alkali) lime silica glass (soda lime glass) and gold added thereto, in the case where gold chloride (AuCl ) is added to the soda (alkali) silica glass
- the present invention provides a method of manufacturing artificial jewelry by adding gold to crystal glass, in which, in a material composition of a material mixing process for producing artificial jewelry, comprising typical crystal glass and gold added thereto, in the case where gold chloride (AuCl 4 ) is added to the crystal glass, 0.2-5 wt% of gold chloride and 0.01-2 wt% of Sb O are added thereto, and in the case where Au powder is added to the crystal glass, 0.2-5 wt% of Au powder and 0.01-2 wt% of Sb O are added thereto.
- Au chloride AuCl 4
- FIG. 1 is a schematic view illustrating the process of the present invention.
- a first process - a mixing process 1 in which, when the Au (gold) is added, the addition of Au is performed in the same manner as in a general glass production process, and when the gold chloride is added, the addition of gold chloride (AuCl, AuCl 2 , AuCl 3 , AuCl 4 , HAuCl 4 ) is performed by adding materials which have already been blended, except gold chloride, manually stirring them, and then adding gold chloride to the materials which have already been blended.
- a second process - a melting process 2 in which the material composition obtained in the previous process is heated to 1300 ⁇ 1500°C at 2a to thus melt it.
- a third process - a molding process 3 in which the melt obtained in the second process is loaded into a mold to thus obtain a product having a predetermined shape.
- the molding process may be performed manually or automatically.
- a fourth process - a slow cooling process 4, the temperature required therefor being set in the range of 450 ⁇ 500°C.
- the color of the molded product becomes much more vivid, and furthermore, a new color is represented, thus making it possible to use the product as artificial jewelry.
- the technical characteristic of the present invention resides in that, in the material mixing process, ® when gold chloride (AuCl, AuCl , AuCl , Aucl , HAuCl ) or Au powder (gold powder) is added to soda (alkali) lime silica glass (soda lime glass), in the case of gold chloride, 0.2-5 wt% of gold chloride and 0.1-2 wt% of SnO is added to the soda lime silica glass, and in the case of Au powder, 0.2-5 wt% of Au powder and 0.1- 2 wt% of SnCl is added to the soda lime silica glass.
- AuCl , AuCl , Aucl , HAucl ) and SnO or Sb O is such a wide range is that artificial
- Au Powder or gold chloride is added to material for soda lime silica glass or crystal glass, thereby producing material for artificial jewelry having a beautiful color.
- the glass products obtained using the materials in the composition ratio according to the present invention, represent beautiful colors which are different from those of products made from conventional soda lime silica glass or crystal glass. This is believed to be due to interactions between gold powder or gold chloride and SnO or Sb O , as the added materials.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Disclosed is a method of manufacturing artificial jewelry by adding gold to typical soda lime glass or crystal glass, which thus differs from the case of conventional glass. In detail, the present invention provides a method of manufacturing artificial jewelry having a beautiful color, including ® adding soda (alkali) lime silica glass (soda lime glass) with gold chloride (AuCl, AuCl, AuCl, Aucl, HAuCl ) or Au powder (gold powder), in which, in the case of gold chloride, the soda lime silica glass is added with 0.2-5 wt% of gold chloride and 0.1-2 wt% of SnO, and in the case of Au powder, the soda lime silica glass is added with 0.2-5 wt% of Au powder and 0.1-2 wt% of SnCl, or © adding crystal glass with Au powder or gold chloride, in which, in the case of gold chloride, the crystal glass is added with 0.2-5 wt% of gold chloride and 0.01-2 wt% of Sb O, and, in the case of adding Au powder, the crystal glass is added with 0.2-5 wt% of Au powder and 0.01-2 wt% of Sb O. Thereby, artificial jewelry having various colors (pink, red, yellow, violet) of high quality can be realized, and thus can be used as material for various accessories and tableware or vessels, such as wine glasses, alcoholic drink cups, tea cups, punch bowls, dishes, etc.
Description
Description
METHOD FOR MANUFACTURING ARTIFICIAL JEWELRY BY ADDING GOLD TO SODA LIME GLASS OR CRYSTAL
GLASS
Technical Field
[1] The present invention relates to a method of manufacturing artificial jewelry by adding gold to soda lime glass or crystal glass. Background Art
[2] Conventional methods of manufacturing various artificial jewelry products are known. Among these artificial jewelry products, crystal glass products to which PbO
(lead oxide) has been added are commercially popular. However, according to the increase in cultural lifestyle of people living in increasingly economically developed areas, the demand for artificial jewelry having a beautiful color of higher quality is increasing.
Disclosure of Invention
Technical Problem
[3] Accordingly, the present invention has been made keeping in mind the above problems occurring in the related art, and an object of the present invention is to provide a method of manufacturing artificial jewelry, in which gold is added to typical soda lime glass or crystal glass to thus realize artificial jewelry having various colors of high quality, which can then be used as material for various accessories and vessels, such as wine glasses, tea cups, punch bowls, and dishes. Technical Solution
[4] In order to accomplish the above object, the present invention provides a method of manufacturing artificial jewelry by adding gold to soda lime glass, in which, in a material composition of a material mixing process for producing artificial jewelry comprising typical soda (alkali) lime silica glass (soda lime glass) and gold added thereto, in the case where gold chloride (AuCl ) is added to the soda (alkali) silica glass
4
(soda lime glass), 0.2-5 wt% of gold chloride and 0.1-2 wt% of SnO are added thereto, and in the case where Au powder is added to the soda (alkali) silica glass (soda lime glass), 0.2-5 wt% of Au powder and 0.1-2 wt% of SnCl 4 are added thereto.
[5] In addition, the present invention provides a method of manufacturing artificial jewelry by adding gold to crystal glass, in which, in a material composition of a material mixing process for producing artificial jewelry, comprising typical crystal glass and gold added thereto, in the case where gold chloride (AuCl 4 ) is added to the
crystal glass, 0.2-5 wt% of gold chloride and 0.01-2 wt% of Sb O are added thereto, and in the case where Au powder is added to the crystal glass, 0.2-5 wt% of Au powder and 0.01-2 wt% of Sb O are added thereto.
Advantageous Effects
[6] According to the present invention, typical soda lime glass or crystal glass is added with gold and then processed, thus obtaining artificial jewelry having various colors (pink, red, yellow, violet) of the highest quality, which can then be used as material for various accessories and tableware or vessels, such as wine glasses, juice glasses, coffee cups, punch bowls and dishes, and therefore the method of the present invention is regarded as very useful in contributing to industrial development. Brief Description of the Drawings
[7] FIG. 1 is a schematic view illustrating the process of the present invention.
[8] <Description of the Reference Numerals in the Drawing>
[9] 1: mixing Ia: addition of Au
[10] Ib: addition of gold chloride 2: melting
[11] 2a: heating 3: molding
[12] 3 a: automatic molding 3b: manual molding
[13] 4: slow cooling 5: cutting and polishing
[14] 6: heat treatment 7: inspection
Best Mode for Carrying Out the Invention
[15] Hereinafter, a detailed description of the present invention will be given with reference to the appended drawing.
[16] The process of manufacturing artificial jewelry exhibiting a clear and transparent pink, red, yellow, or violet color is described.
[17] A first process - a mixing process 1, in which, when the Au (gold) is added, the addition of Au is performed in the same manner as in a general glass production process, and when the gold chloride is added, the addition of gold chloride (AuCl, AuCl 2 , AuCl 3 , AuCl 4 , HAuCl 4 ) is performed by adding materials which have already been blended, except gold chloride, manually stirring them, and then adding gold chloride to the materials which have already been blended. [18] A second process - a melting process 2, in which the material composition obtained in the previous process is heated to 1300~1500°C at 2a to thus melt it. [19] A third process - a molding process 3, in which the melt obtained in the second process is loaded into a mold to thus obtain a product having a predetermined shape.
The molding process may be performed manually or automatically. [20] A fourth process - a slow cooling process 4, the temperature required therefor being set in the range of 450~500°C.
[21] A fifth process - a cutting and polishing process 5, in which the molded product is subjected to finishing treatment.
[22] A sixth process - a heat treatment process 6, in which the product is subjected to final heat treatment at 500~550°C. When the heat treatment is performed, the color of the molded product becomes much more vivid, and furthermore, a new color is represented, thus making it possible to use the product as artificial jewelry.
[23] A seventh process - an inspection process 7, in which the finished product is selected.
[24]
[25] Specifically, the technical characteristic of the present invention resides in that, in the material mixing process, ® when gold chloride (AuCl, AuCl , AuCl , Aucl , HAuCl ) or Au powder (gold powder) is added to soda (alkali) lime silica glass (soda lime glass), in the case of gold chloride, 0.2-5 wt% of gold chloride and 0.1-2 wt% of SnO is added to the soda lime silica glass, and in the case of Au powder, 0.2-5 wt% of Au powder and 0.1- 2 wt% of SnCl is added to the soda lime silica glass.
[26] In addition, ® when Au powder or gold chloride is added to crystal glass, in the case of Au powder, 0.2-5 wt% of Au powder and 0.01-2 wt% of Sb O is added to the crystal glass, and in the case where gold chloride is added to the crystal, 0.2-5 wt% of gold chloride and 0.01-2 wt% of Sb O are added.
[27] JX- The reason why the composition ratio of Au Powder or gold chloride (AuCl,
AuCl , AuCl , Aucl , HAucl ) and SnO or Sb O is such a wide range is that artificial
2 3 4 4 2 2 3 jewelry is to be processed and produced within a range suitable for economic benefits and changes in color and temperature.
[28] According to the method of manufacturing artificial jewelry of the present invention, Au Powder or gold chloride is added to material for soda lime silica glass or crystal glass, thereby producing material for artificial jewelry having a beautiful color.
[29] The glass products, obtained using the materials in the composition ratio according to the present invention, represent beautiful colors which are different from those of products made from conventional soda lime silica glass or crystal glass. This is believed to be due to interactions between gold powder or gold chloride and SnO or Sb O , as the added materials.
2 3
[30] In particular, in the case where crystal glass material is used, only when Sb O is added along with Au powder or gold chloride can a beautiful color suitable for jewelry appear. [31] Also, in the case of using the soda lime silica glass material, SnO should be used along with Au powder or gold chloride. [32] Below, the technical superiority of the present invention is intended to be proven with reference to the results of various specific tests.
[33] [34] <Case of using Crystal Glass Material> [35] In order to evaluate the effectiveness of Sb O , the test was conducted as shown in
2 3
Table 1 below.
[36] Table 1
[37] As is apparent from Table 1, when a molding process and a slow cooling process were performed without the addition of Sb O , a vivid color did not appear even when using either Au Powder or AuCl 4. Further, even if a subsequent heat treatment process was performed at 55O0C for 3 hr or 10 hr, the product was not colored. Thus, in order to realize a beautiful color, the addition of Sb O was confirmed to be essential.
[38] In addition, the test was conducted with changes in the amount of Au Powder. The results are shown in Table 2 below. [39] Table 2
[40] As is apparent from Table 2, when the amount of Sb O was set at 1.0 wt% and the amount of Au was gradually increased from 0.05 wt% to 1, 3, and 5 wt%, the color of the finally heat treated product was gradually deepened from pink to red. As in Code No. GG3, also in the case where the amount of Au was set at 0.05 wt% and the amount of Sb O was increased from 1 wt% to 2 wt%, the product was seen to be a red color.
2 3
[41] In addition, the test was conducted with changes in the amount of Sb O in the state in which the amount of Au was not changed. The results are shown in Table 3 below. [42] Table 3
[43] As is apparent from Table 3, when a product made in a state in which the amount of
Au was set at 0.5 wt% and the amount of Sb O was changed was finally heat treated, the color thereof was gradually deepened from transparent pink to violet in direct proportion with the increase in the amount of Sb O . In Code No. GG35, the color of the product was changed to be pink. This means that the color of the product can be relatively lightened when the amount of Sb O is too large. Therefore, it is found that a critical point for attaining an optimal color exists.
[44] The results of the test in which AuCl was added are given in Table 4 below.
[45] Table 4
[46] As is apparent from the above table, when the amount of Sb O was not changed and the amount of AuCl was increased, the product was colored a deeper red.
4
[47] In addition, the test results when the amount of AuCl was not changed and the
4 amount of Sb O was changed are given in Table 5 below.
[48] Table 5
[49] As is apparent from Table 5, when the amount of AuCl was not changed and the
4 amount of Sb O was increased, the products were colored deep purple, purple, and
2 3 pink.
[50] [51] <Case of using Soda Lime Silica Glass Material> [52] In the case of crystal glass, Sb O was confirmed to greatly affect the coloring of the product. On the other hand, in the case of soda lime silica glass, SnO functioned as the main variable, which can be confirmed with reference to the following test results.
[53] Table 6
[54] As is apparent from Table 6, in the case where the soda lime silica glass material was used, the degree of coloring was confirmed to vary depending on the amount of SnO , in addition to gold chloride or gold powder.
Claims
[1] A method of manufacturing artificial jewelry by adding gold to soda lime glass, in which, in a material composition of a material mixing process for producing artificial jewelry comprising typical soda (alkali) lime silica glass (soda lime glass) and gold added thereto, in a case where gold chloride (AuCl 4 ) is added to the soda (alkali) silica glass (soda lime glass), 0.2-5 wt% of gold chloride and 0.1-2 wt% of SnO are added thereto, and in a case where Au powder is added to the soda (alkali) silica glass (soda lime glass), 0.2-5 wt% of Au powder and 0.1-2 wt% of SnCl 4 are added thereto.
[2] A method of manufacturing artificial jewelry by adding gold to crystal glass, in which, in a material composition of a material mixing process for producing artificial jewelry comprising typical crystal glass and gold added thereto, in a case where gold chloride (AuCl ) is added to the crystal glass, 0.2-5 wt% of gold
4 chloride and 0.01-2 wt% of Sb O are added thereto, and in a case where Au
2 3 powder is added to the crystal glass, 0.2-5 wt% of Au powder and 0.01-2 wt% of Sb O are added thereto.
2 3
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020060005214A KR100750635B1 (en) | 2006-01-18 | 2006-01-18 | Manufacturing process of alkali glass wares and crystal glass wares added gold |
KR10-2006-0005214 | 2006-01-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007083910A1 true WO2007083910A1 (en) | 2007-07-26 |
Family
ID=37122027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2007/000258 WO2007083910A1 (en) | 2006-01-18 | 2007-01-16 | Method for manufacturing artificial jewelry by adding gold to soda lime glass or crystal glass |
Country Status (2)
Country | Link |
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KR (1) | KR100750635B1 (en) |
WO (1) | WO2007083910A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ302143B6 (en) * | 2009-07-09 | 2010-11-10 | Moravské sklárny Kvetná s.r.o. | Gold-colored ruby-red glass |
CZ302144B6 (en) * | 2009-07-09 | 2010-11-10 | Moravské sklárny Kvetná s.r.o. | Colored glass free of lead and barium compounds |
WO2011147945A3 (en) * | 2010-05-26 | 2012-04-26 | Nanopartica Gmbh | Method for producing colored glass |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4476090A (en) * | 1981-09-04 | 1984-10-09 | Degussa Aktiengesellschaft | Material for jewelry and commodities and process for its production |
US5559061A (en) * | 1993-07-21 | 1996-09-24 | D. Swarovski & Co. | Gem comprised of a glass based on silicon oxide and calcium oxide |
US5578383A (en) * | 1994-04-13 | 1996-11-26 | Degussa Aktiengesellschaft | Precious-metal material for articles of jewelry and a method of manufacturing them |
KR20040064535A (en) * | 2003-01-13 | 2004-07-19 | 조인철 | Preparation method of crystal rhinestone for hot fix of cloths and its preparation method |
-
2006
- 2006-01-18 KR KR1020060005214A patent/KR100750635B1/en not_active IP Right Cessation
-
2007
- 2007-01-16 WO PCT/KR2007/000258 patent/WO2007083910A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4476090A (en) * | 1981-09-04 | 1984-10-09 | Degussa Aktiengesellschaft | Material for jewelry and commodities and process for its production |
US5559061A (en) * | 1993-07-21 | 1996-09-24 | D. Swarovski & Co. | Gem comprised of a glass based on silicon oxide and calcium oxide |
US5578383A (en) * | 1994-04-13 | 1996-11-26 | Degussa Aktiengesellschaft | Precious-metal material for articles of jewelry and a method of manufacturing them |
KR20040064535A (en) * | 2003-01-13 | 2004-07-19 | 조인철 | Preparation method of crystal rhinestone for hot fix of cloths and its preparation method |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CZ302143B6 (en) * | 2009-07-09 | 2010-11-10 | Moravské sklárny Kvetná s.r.o. | Gold-colored ruby-red glass |
CZ302144B6 (en) * | 2009-07-09 | 2010-11-10 | Moravské sklárny Kvetná s.r.o. | Colored glass free of lead and barium compounds |
WO2011147945A3 (en) * | 2010-05-26 | 2012-04-26 | Nanopartica Gmbh | Method for producing colored glass |
Also Published As
Publication number | Publication date |
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KR20060012337A (en) | 2006-02-07 |
KR100750635B1 (en) | 2007-08-20 |
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