CN108298825A - A kind of high intensity pressure resistance glassware and preparation method - Google Patents
A kind of high intensity pressure resistance glassware and preparation method Download PDFInfo
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- CN108298825A CN108298825A CN201810095983.XA CN201810095983A CN108298825A CN 108298825 A CN108298825 A CN 108298825A CN 201810095983 A CN201810095983 A CN 201810095983A CN 108298825 A CN108298825 A CN 108298825A
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- whisker
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- pressure resistance
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- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 30
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 29
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 28
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 28
- 239000013078 crystal Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 15
- 239000006004 Quartz sand Substances 0.000 claims abstract description 14
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 14
- 229910021538 borax Inorganic materials 0.000 claims abstract description 14
- 239000010433 feldspar Substances 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 14
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 14
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 14
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 14
- 239000011592 zinc chloride Substances 0.000 claims abstract description 14
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 14
- 238000000137 annealing Methods 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 9
- 238000003723 Smelting Methods 0.000 claims abstract description 8
- 238000000465 moulding Methods 0.000 claims abstract description 7
- 238000005422 blasting Methods 0.000 claims abstract description 6
- 238000005498 polishing Methods 0.000 claims abstract description 6
- 239000011521 glass Substances 0.000 abstract description 26
- 238000000034 method Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000005355 lead glass Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910003978 SiClx Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000004901 spalling Methods 0.000 description 2
- 241000271566 Aves Species 0.000 description 1
- 235000014653 Carica parviflora Nutrition 0.000 description 1
- 241000579895 Chlorostilbon Species 0.000 description 1
- 241000243321 Cnidaria Species 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- GJYLKIZKRHDRER-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca].OS(O)(=O)=O GJYLKIZKRHDRER-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010976 emerald Substances 0.000 description 1
- 229910052876 emerald Inorganic materials 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- YZXCQIOLVHGCFP-UHFFFAOYSA-N lead potassium Chemical compound [K].[Pb] YZXCQIOLVHGCFP-UHFFFAOYSA-N 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000005315 stained glass Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/002—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention discloses a kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：60 65 parts of quartz sand powder, 13 parts of alumina whisker, 0.1 0.3 parts of borax, 0.1 1 parts of zinc chloride, 15 parts of sodium metasilicate, 25 parts of feldspar, 38 parts of calcium carbonate crystal whisker, 25 parts of calcium sulfate crystal whiskers, 23 parts of silicon carbide whisker；Preparation method includes the following steps：(1) raw material is weighed according to weight proportion, crushes, is sieved, is stirred, obtains batch mixing；(2) batch mixing in step (1) is placed in smelting furnace and is heated to melting, kept the temperature, obtain glass melting liquid；(3) molten liquid in step (2) is sent into molding machine and is molded, be prepared into specification, variform glassware；(4) glassware in step (3) is placed into continuous annealing furnace 40 60min that anneal, annealing finishes, and is processed by shot blasting to product, and polishing treatment finishes to obtain finished product.
Description
Technical field
The present invention relates to glass manufacturing area, specifically a kind of high intensity pressure resistance glassware and preparation method.
Background technology
Glassware is exactly the vessel made with glass.Glass art maintains development in thousands of years without stop in China
History.Between Ming Dynasty's Wanli year year, the glassware of Boshan Shandong Province makes very flourishing prosperity, late Ming ＆ early Qing and is passed to Beijing, in clear just health
Prosperous, Yongzheng, Qianrong's period, coloured glaze production were once revived, and large-scale " coloured glaze occurs in clear Kangxu 35 years, Beijing
Factory ", the glassware that production imperial palace is enjoyed.In the meantime, glassware is wide in variety colorful, and moulding is also varied from decoration.
Wherein expect jade, emerald, agate, bottle, bowl, snuffbottle, birds and beasts made of coral etc. etc., color is true to nature, have individual style and
Charm.
Glassware is mostly used soda lime glass and makes, the vessel of water white transparency, and the iron-holder in glass is generally below
0.02%.Colorant is added in glass raw material, coloured glass can be made；Opacifiers is added, emulsion opal glass is made.Manufacture is pondered
The advanced artistic ware such as goblet, scent flask, fruit bowl etc. that vehicle is carved mostly uses potassium lead silicate glass, also known as lead crystal glass.
This glass contains PbO, has high refractive index and a dispersion, especially bright, high specific gravity when mill carves faceted pebble, and when percussion sends out the sound clear and melodious.
It is full lead crystal containing PbO30% or more, is middle lead crystal glass containing PbO24~30%, is low lead containing PbO18% or less
In addition crystal glass also has the barium crystal glass containing BaO.The products such as vessel such as coffee pot of cooking use heat-resisting borosilicate glass
Glass, coefficient of thermal expansion is low, and spalling resistance is strong.Devitrified glass has preferably heat-resisting and spalling resistance, machinery strong
Degree is big, suitable to manufacture the vessel often washed in the restaurants burner Min He hotel of cooking a meal.
Vessel based on glass material have the application more extensively sent out, and one is component formula and work of the class about glassware
The improved research of skill is reported in succession.As China Patent No. is：CN20131025011.3, open " a kind of fluorin environment protection glass ",
By the technical solution, fluorine content in effective relatively low glass plays Environmental Role on a degree of, however is based on
Fluorine element exists with relatively stable combined form in glass, and content is not high, therefore, smaller to the injury of human body and environment.
However the shortcoming of the technical solution is that obtained glass mechanical hardness and crash resistance are weaker, application range is relatively narrow.
In view of the deficienciess of the prior art, not there is a kind of effective mode of implementation to solve so far.
Invention content
(1) the technical issues of solving
In view of the deficiency of the prior art, a kind of high intensity pressure resistance glassware of present invention offer and preparation side
Method, the glassware that technical solution obtains through the invention have high mechanical strength, crash resistance by force, and suitable large-scale production is answered
With.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：60-65 parts of quartz sand powder, oxidation
1-3 parts of al whisker, 0.1-0.3 parts of borax, 0.1-1 parts of zinc chloride, 1-5 parts of sodium metasilicate, 2-5 parts of feldspar, calcium carbonate crystal whisker 3-8
Part, 2-5 parts of calcium sulfate crystal whiskers, 2-3 parts of silicon carbide whisker.
Preferably, the described high intensity pressure resistance glassware, is made of the raw material of following parts by weight：Quartz sand powder 60
Part, 3 parts of alumina whisker, 0.3 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar, 8 parts of calcium carbonate crystal whisker, calcium sulfate are brilliant
It must 5 parts, 3 parts of silicon carbide whisker.
Preferably, the described high intensity pressure resistance glassware, is made of the raw material of following parts by weight：By following parts by weight
Raw material is made：65 parts of quartz sand powder, 1 part of alumina whisker, 0.1 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar,
3 parts of calcium carbonate crystal whisker, 2 parts of calcium sulfate crystal whiskers, 3 parts of silicon carbide whisker.
The preparation method of above-mentioned high intensity pressure resistance glassware, includes the following steps：
(1) raw material is weighed according to the weight proportion of high intensity pressure resistance glassware, crushes, crosses 100-200 mesh sieve, stirring mixes
It closes, obtains batch mixing；
(2) batch mixing in step (1) is placed in 1400-1495 DEG C of smelting furnace and is heated to melting, kept the temperature 6-12h, obtain
Molten liquid；
(3) molten liquid in step (2) is sent into molding machine and is molded, be prepared into specification, variform glassware；
(4) glassware in step (3) is placed into continuous annealing furnace the 40- that anneals under the conditions of 420-480 DEG C
60min, annealing finish, and are processed by shot blasting to product, and polishing treatment finishes to obtain finished product.
Preferably, the batch mixing in step (1) is placed in 1495 DEG C of smelting furnace in the step (2) and is heated to melting
Melt, keeps the temperature 12h, obtain molten liquid.
Preferably, the glassware in step (3) is placed into continuous annealing furnace at 480 DEG C in the step (4)
Under the conditions of anneal 60min.
Advantageous effect
The present invention discloses a kind of high intensity pressure resistance glassware and preparation method, and high intensity pressure resistance glassware is by following heavy
The raw material of amount part is made：Quartz sand powder, alumina whisker, borax, zinc chloride, sodium metasilicate, feldspar, calcium carbonate crystal whisker, sulfuric acid
Calcium pyroborate, silicon carbide whisker.Wherein alumina whisker has high-strength, Gao Mo and high temperature stability performance, physicochemical property more existing
It is stronger that conventional aluminium oxide is added in glass manufacturing techniques；Calcium carbonate crystal whisker, mechanical strength is higher and has damping performance, application
Into glass vessel, it can be effectively increased the anti-seismic performance of glassware, glassware is made to be not easy to break into pieces；Calcium sulfate crystal whiskers have compared with
High toughness, wear-resistant, anticorrosive, the wear-resistant and anticorrosive of glassware can be effectively increased by being applied in glassware
Performance, meanwhile, because it is with higher toughness, therefore, there is the drop resistant performance for improving glass material vessel.Silicon carbide whisker has
There are fairly good high temperature resistant property and mechanical strength, be applied to the fusion temperature for effectively improving glass material vessel in glass vessel,
Make glass material vessel that there is preferable heat-resisting quantity.
Meanwhile above-mentioned whisker, because having certain length and tensile property, being applied in glassware further to carry
The tensile stress and compression stress of high glassware, further increase drop resistant performance.It interacts between above-mentioned component materials, phase
It mutually influences, the common physicochemical property for improving glassware.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：60 parts of quartz sand powder, aluminium oxide are brilliant
3 parts of palpus, 0.3 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar, 8 parts of calcium carbonate crystal whisker, 5 parts of calcium sulfate crystal whiskers, carbonization
Silicon wafer must be 3 parts.
The preparation method of above-mentioned high intensity pressure resistance glassware, includes the following steps：
(1) raw material is weighed according to the weight proportion of high intensity pressure resistance glassware, crushes, crosses 200 mesh sieve, is stirred,
Obtain batch mixing；
(2) batch mixing in step (1) is placed in 1495 DEG C of smelting furnace and is heated to melting, kept the temperature 12h, obtain molten liquid；
(3) molten liquid in step (2) is sent into molding machine and is molded, be prepared into specification, variform glassware；
(4) glassware in step (3) is placed into continuous annealing furnace the 60min that anneals under the conditions of 480 DEG C, moved back
Fire finishes, and is processed by shot blasting to product, and polishing treatment finishes to obtain finished product.
Embodiment 2:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：65 parts of quartz sand powder, aluminium oxide are brilliant
1 part of palpus, 0.1 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar, 3 parts of calcium carbonate crystal whisker, 2 parts of calcium sulfate crystal whiskers, carbonization
Silicon wafer must be 3 parts.
The preparation method of above-mentioned high intensity pressure resistance glassware, includes the following steps：
(1) raw material is weighed according to the weight proportion of high intensity pressure resistance glassware, crushes, crosses 200 mesh sieve, is stirred,
Obtain batch mixing；
(2) batch mixing in step (1) is placed in 1400 DEG C of smelting furnace and is heated to melting, kept the temperature 6h, obtain molten liquid；
(3) molten liquid in step (2) is sent into molding machine and is molded, be prepared into specification, variform glassware；
(4) glassware in step (3) is placed into continuous annealing furnace the 40min that anneals under the conditions of 420 DEG C, moved back
Fire finishes, and is processed by shot blasting to product, and polishing treatment finishes to obtain finished product.
Embodiment 3:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：60 parts of quartz sand powder, aluminium oxide are brilliant
1 part of palpus, 0.1 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar, 3 parts of calcium carbonate crystal whisker, 2 parts of calcium sulfate crystal whiskers, carbonization
Silicon wafer must be 2 parts.
The preparation method of above-mentioned high intensity pressure resistance glassware, includes the following steps：
(1) raw material is weighed according to the weight proportion of high intensity pressure resistance glassware, crushes, sieves with 100 mesh sieve, is stirred,
Obtain batch mixing；
(2) batch mixing in step (1) is placed in 1450 DEG C of smelting furnace and is heated to melting, kept the temperature 8h, obtain molten liquid；
(3) molten liquid in step (2) is sent into molding machine and is molded, be prepared into specification, variform glassware；
(4) glassware in step (3) is placed into continuous annealing furnace the 50min that anneals under the conditions of 460 DEG C, moved back
Fire finishes, and is processed by shot blasting to product, and polishing treatment finishes to obtain finished product.
Embodiment 4:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：65 parts of quartz sand powder, aluminium oxide are brilliant
3 parts of palpus, 0.3 part of borax, 0.1 part of zinc chloride, 1 part of sodium metasilicate, 2 parts of feldspar, 8 parts of calcium carbonate crystal whisker, 5 parts of calcium sulfate crystal whiskers, carbon
3 parts of SiClx whisker.
The preparation method of above-mentioned high intensity pressure resistance glassware is such as embodiment 1.
Embodiment 5:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：62 parts of quartz sand powder, aluminium oxide are brilliant
2 parts of palpus, 0.2 part of borax, 0.5 part of zinc chloride, 4 parts of sodium metasilicate, 4 parts of feldspar, 5 parts of calcium carbonate crystal whisker, 3 parts of calcium sulfate crystal whiskers, carbon
3 parts of SiClx whisker.
The preparation method of above-mentioned high intensity pressure resistance glassware is such as embodiment 2.
Embodiment 6:
A kind of high intensity pressure resistance glassware, is made of the raw material of following parts by weight：65 parts of quartz sand powder, aluminium oxide are brilliant
3 parts of palpus, 0.3 part of borax, 0.1 part of zinc chloride, 1 part of sodium metasilicate, 2 parts of feldspar, 8 parts of calcium carbonate crystal whisker, 5 parts of calcium sulfate crystal whiskers, carbon
3 parts of SiClx whisker.
The preparation method of above-mentioned high intensity pressure resistance glassware is such as embodiment 3.
Glassware carries out physicochemical property test obtained by example 1-6 real-time to the present invention, while choosing same size, shape city
The simple glass vessel sold on field are compared, as a result such as following table：
Glassware performance test
| Experimental group | Compression stress/MPa | Mohs' hardness | Friction coefficient |
| Embodiment 1 | 831.1 | 6.9 | 0.07 |
| Embodiment 2 | 832.4 | 7.0 | 0.06 |
| Embodiment 3 | 831.3 | 6.8 | 0.07 |
| Embodiment 4 | 832.5 | 7.0 | 0.07 |
| Embodiment 5 | 834.5 | 6.9 | 0.07 |
| Embodiment 6 | 831.7 | 7.0 | 0.07 |
| Control group | 740.6 | 5.4 | 0.09 |
By upper table：The glassware of technical solution through the invention, compression stress can reach 830Mpa or more,
Mohs' hardness is between 6.8 and 7.0, and Conventional glass vessel available on the market, compression stress only have 740.6Mpa, Mohs hard
Degree only 5.4, and the glassware of the present invention is relatively smooth compared with simple glass vessel in the market, it is more aesthetically pleasing.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited including sentence "including a ...", it is not excluded that
There is also other identical elements in the process, method, article or apparatus that includes the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations, although with reference to the foregoing embodiments
Invention is explained in detail, it will be understood by those of ordinary skill in the art that:It still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features；And these modification or
It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.
Claims (6)
1. a kind of high intensity pressure resistance glassware, which is characterized in that be made of the raw material of following parts by weight：Quartz sand powder 60-
65 parts, 1-3 parts of alumina whisker, 0.1-0.3 parts of borax, 0.1-1 parts of zinc chloride, 1-5 parts of sodium metasilicate, 2-5 parts of feldspar, calcium carbonate
3-8 parts of whisker, 2-5 parts of calcium sulfate crystal whiskers, 2-3 parts of silicon carbide whisker.
2. high intensity pressure resistance glassware according to claim 1, which is characterized in that by the raw material system of following parts by weight
At：60 parts of quartz sand powder, 3 parts of alumina whisker, 0.3 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar, calcium carbonate
8 parts of whisker, 5 parts of calcium sulfate crystal whiskers, 3 parts of silicon carbide whisker.
3. high intensity pressure resistance glassware according to claim 1, which is characterized in that by the raw material system of following parts by weight
At：65 parts of quartz sand powder, 1 part of alumina whisker, 0.1 part of borax, 1 part of zinc chloride, 5 parts of sodium metasilicate, 5 parts of feldspar, calcium carbonate
3 parts of whisker, 2 parts of calcium sulfate crystal whiskers, 3 parts of silicon carbide whisker.
4. according to the preparation method of any high intensity pressure resistance glasswares of claim 1-3, which is characterized in that including with
Lower step：
(1) raw material is weighed according to the weight proportion of high intensity pressure resistance glassware, crushes, crosses 100-200 mesh sieve, is stirred,
Obtain batch mixing；
(2) batch mixing in step (1) is placed in 1400-1495 DEG C of smelting furnace and is heated to melting, kept the temperature 6-12h, melted
Liquid；
(3) molten liquid in step (2) is sent into molding machine and is molded, be prepared into specification, variform glassware；
(4) glassware in step (3) is placed into continuous annealing furnace the 40- that anneals under the conditions of 420-480 DEG C
60min, annealing finish, and are processed by shot blasting to product, and polishing treatment finishes to obtain finished product.
5. the preparation method of high intensity pressure resistance glassware according to claim 4, which is characterized in that the step (2)
Batch mixing in middle (1) by step, which is placed in 1495 DEG C of smelting furnace, to be heated to melting, and is kept the temperature 12h, is obtained molten liquid.
6. the preparation method of high intensity pressure resistance glassware according to claim 4, which is characterized in that the step (4)
Glassware in middle (3) by step is placed into continuous annealing furnace the 60min that anneals under the conditions of 480 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810095983.XA CN108298825B (en) | 2018-01-31 | 2018-01-31 | High-strength pressure-resistant glassware and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810095983.XA CN108298825B (en) | 2018-01-31 | 2018-01-31 | High-strength pressure-resistant glassware and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108298825A true CN108298825A (en) | 2018-07-20 |
| CN108298825B CN108298825B (en) | 2020-03-31 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111960679A (en) * | 2020-08-31 | 2020-11-20 | 扬州星汉玻璃工艺品有限公司 | Novel composite material for glass artware and preparation method thereof |
| CN111960678A (en) * | 2020-08-31 | 2020-11-20 | 扬州星汉玻璃工艺品有限公司 | Corrosion-resistant composite material for glass artware and preparation method thereof |
| CN112851119A (en) * | 2021-03-31 | 2021-05-28 | 广东欧文莱陶瓷有限公司 | Digital carved ceramic glaze |
| CN113105116A (en) * | 2021-03-31 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Digital carved ceramic and preparation method thereof |
| CN113929301A (en) * | 2021-11-08 | 2022-01-14 | 朱卫星 | Fireproof pressure-resistant glass and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101333074A (en) * | 2008-08-07 | 2008-12-31 | 河南安彩高科股份有限公司 | Sodium-calcium-silicate glass composition, its manufacturing method and use |
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- 2018-01-31 CN CN201810095983.XA patent/CN108298825B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333074A (en) * | 2008-08-07 | 2008-12-31 | 河南安彩高科股份有限公司 | Sodium-calcium-silicate glass composition, its manufacturing method and use |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111960679A (en) * | 2020-08-31 | 2020-11-20 | 扬州星汉玻璃工艺品有限公司 | Novel composite material for glass artware and preparation method thereof |
| CN111960678A (en) * | 2020-08-31 | 2020-11-20 | 扬州星汉玻璃工艺品有限公司 | Corrosion-resistant composite material for glass artware and preparation method thereof |
| CN112851119A (en) * | 2021-03-31 | 2021-05-28 | 广东欧文莱陶瓷有限公司 | Digital carved ceramic glaze |
| CN113105116A (en) * | 2021-03-31 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Digital carved ceramic and preparation method thereof |
| CN113929301A (en) * | 2021-11-08 | 2022-01-14 | 朱卫星 | Fireproof pressure-resistant glass and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN108298825B (en) | 2020-03-31 |
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