CN112851119A - Digital carved ceramic glaze - Google Patents
Digital carved ceramic glaze Download PDFInfo
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- CN112851119A CN112851119A CN202110351768.3A CN202110351768A CN112851119A CN 112851119 A CN112851119 A CN 112851119A CN 202110351768 A CN202110351768 A CN 202110351768A CN 112851119 A CN112851119 A CN 112851119A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/06—Frit compositions, i.e. in a powdered or comminuted form containing halogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention relates to the field of ceramic tile production, and provides a digital carved ceramic glaze for improving the mechanical property of a ceramic tile. The invention provides a digital carved ceramic glaze, which comprises the following components: 25-35 parts of albite, 10-20 parts of kaolin, 10-15 parts of dolomite, 1-5 parts of alumina, 2-5 parts of zinc oxide, 1-5 parts of calcined talc, 40-60 parts of fusion cakes and 1-5 parts of calcium carbonate whiskers. The strength of the carved ceramic tile is fully improved, and the service life of the ceramic tile can be prolonged.
Description
Technical Field
The invention relates to the field of ceramic tile production, in particular to a digital carved ceramic glaze.
Background
The digital engraving system precisely engraves four-dimensional patterns required by the three-dimensional layer design requirements of various simulation raw materials on the die surface through high-energy laser beams, the maximum value of the pattern height drop can reach 2.5mm, and the three-dimensional effect is outstanding. Meanwhile, by matching with a forward forging and pressing process, the surface of the biscuit is guaranteed to be deep, shallow, three-dimensional and rich in details, the surface effect of the die can be prevented from being damaged by the surface friction of the blank and the die in the production process, and the service life of the die is prolonged.
How to further improve the performance of the digital carved ceramic tile is a technical problem to be solved urgently.
Disclosure of Invention
The invention solves the technical problem of improving the mechanical property of ceramic tiles and provides a digital carved ceramic glaze.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
a digital finishing impression ceramic glaze, comprising:
25-35 parts of albite, 10-20 parts of kaolin, 10-15 parts of dolomite, 1-5 parts of alumina, 2-5 parts of zinc oxide, 1-5 parts of calcined talc, 40-60 parts of fusion cakes and 1-5 parts of calcium carbonate whiskers.
The calcium carbonate whisker is a material with high strength, high modulus and good thermal stability, and can effectively improve the mechanical property of a glaze layer when being doped into the glaze.
The strength of the carved ceramic tile is fully improved, and the service life of the ceramic tile can be prolonged.
Preferably, the method comprises the following steps:
30-35 parts of albite, 12-20 parts of kaolin, 12-15 parts of dolomite, 3-5 parts of alumina, 3-5 parts of zinc oxide, 4-5 parts of calcined talc, 45-60 parts of fusion cakes and 2-5 parts of calcium carbonate whiskers.
Preferably, the method comprises the following steps:
30 parts of albite, 12 parts of kaolin, 12 parts of dolomite, 3 parts of alumina, 3 parts of zinc oxide, 4 parts of calcined talc, 45 parts of clinker and 2 parts of calcium carbonate whisker.
Preferably, the preparation method of the calcium carbonate whisker comprises the following steps:
taking 2-5 parts by mass of calcium isopropoxide, 0.5-1 part by mass of magnesium ethoxide and 10-25 parts by mass of chitosan;
dispersing calcium isopropoxide in 100-150 parts by mass of anhydrous methanol, performing ultrasonic treatment for 1-2 hours, dissolving magnesium ethoxide in 100-150 parts by mass of deionized water, and mixing the dispersion liquid of calcium isopropoxide with the solution of magnesium ethoxide to obtain a precursor solution;
dissolving chitosan in 100-150 parts by mass of 1-3% acetic acid aqueous solution to obtain a chitosan solution, coating the chitosan solution on a glass substrate, and airing to obtain a chitosan template;
and (3) soaking the chitosan template into the precursor solution, and reacting for 24-48 h in a carbon dioxide atmosphere to obtain the calcium carbonate whisker. The calcium carbonate whisker product has high purity, granular accumulation form on the surface, relatively large specific surface area and special concave-convex micro-morphology, and can enhance the binding capacity with other components, thereby further improving the strength of the ceramic tile.
Preferably, 4-5 parts by mass of calcium isopropoxide, 0.8-1 part by mass of magnesium ethoxide and 20-25 parts by mass of chitosan are taken.
Preferably, 4 parts by mass of calcium isopropoxide, 0.8 part by mass of magnesium ethoxide and 20 parts by mass of chitosan are taken.
Preferably, the chitosan is modified chitosan, and the preparation method of the modified chitosan comprises the following steps:
taking 10-25 parts by mass of chitosan and 4-10 parts by mass of carbon nanotubes;
adding chitosan into 1000-2000 parts by mass of 2% acetic acid solution, stirring for 24-48 h, filtering, and mixing with 3% polyvinyl alcohol solution with the same volume to obtain chitosan solution;
soaking the carbon nano tube into a mixed solution of sulfuric acid and nitric acid, wherein the concentration of the sulfuric acid is 10-12 mol/L, the concentration of the nitric acid is 8-12 mol/L, heating to 60-80 ℃, stirring for 24-48 h, taking out a solid phase, washing with water, and drying to obtain a carboxylated carbon nano tube;
dispersing the carboxylated carbon nanotubes into a 3% polyvinyl alcohol solution, carrying out ultrasonic treatment until the carboxylated carbon nanotubes are fully dispersed, mixing the dispersion liquid of the carboxylated carbon nanotubes with a chitosan solution, stirring for 24-48 h, adjusting the pH value to 5-7, washing with ethanol, centrifuging, and freeze-drying at-100 to-80 ℃ to obtain the modified chitosan. The template formed by the prepared modified chitosan on the glass substrate has uniform pores, and the pore size structure is suitable for the growth and formation of whiskers, so that the bonding effect of the whiskers and other raw materials is further improved, and the strength of the ceramic tile is improved.
Preferably, the frit comprises 4-12 parts by mass of feldspar, 8-15 parts by mass of quartz, 4-10 parts by mass of lepidolite, 2-4 parts by mass of strontium carbonate, 4-8 parts by mass of borax, 2-4 parts by mass of calcium carbonate, 4-6 parts by mass of zirconite, 2-4 parts by mass of sodium fluosilicate and 2-4 parts by mass of zinc oxide.
Preferably, the frit comprises 8-12 parts by mass of feldspar, 9-15 parts by mass of quartz, 6-10 parts by mass of lepidolite, 3-4 parts by mass of strontium carbonate, 5-8 parts by mass of borax, 3-4 parts by mass of calcium carbonate, 5-6 parts by mass of zirconite, 3-4 parts by mass of sodium fluosilicate and 3-4 parts by mass of zinc oxide.
Preferably, the frit comprises 8 parts by mass of feldspar, 9 parts by mass of quartz, 6 parts by mass of lepidolite, 3 parts by mass of strontium carbonate, 5 parts by mass of borax, 3 parts by mass of calcium carbonate, 5 parts by mass of zirconite, 3 parts by mass of sodium fluosilicate and 3 parts by mass of zinc oxide.
Preferably, the frit preparation method comprises:
ball-milling zircon for 40-60 h, and sieving with a 200-300-mesh sieve;
uniformly mixing feldspar, quartz, lepidolite, strontium carbonate, borax, calcium carbonate, zirconite, sodium fluosilicate and zinc oxide with the ball-milled zirconite, and sieving with a sieve of 18-20 meshes for three times;
melting the sieved materials, controlling the temperature to be 1500-1550 ℃, and performing water quenching to obtain a milky white frit;
and crushing the milky white frit again, and ball-milling until the milky white frit can pass through a 120-225-mesh sieve.
Compared with the prior art, the invention has the beneficial effects that: the strength of the carved ceramic tile is fully improved, and the service life of the ceramic tile can be prolonged.
When bearing pressure, because the calcium carbonate whisker and the ceramic matrix have stronger bonding capability, the crack generally extends along the bonding interface of the whisker and the ceramic matrix, and easily extends along the interface and bypasses the calcium carbonate whisker with higher modulus, namely the crack deflects along the whisker. The crack propagation path is invisibly prolonged, the distance is increased, the effective increase of the distance consumes a large amount of damage energy caused by external force, the damage energy is reduced, the reduction of the energy can make the continuous expansion of the crack more difficult, the crack is difficult to continue to expand, the strength of the material is improved, and the purpose of reinforcement is achieved.
Detailed Description
The following examples are further illustrative of the present invention and are not intended to be limiting thereof.
Example 1
A digital finishing impression ceramic glaze, comprising:
300g of albite, 120g of kaolin, 120g of dolomite, 30g of alumina, 30g of zinc oxide, 40g of calcined talc, 450g of clinker and 20g of calcium carbonate whisker.
The preparation method of the calcium carbonate whisker comprises the following steps:
taking 40g of calcium isopropoxide, 8g of magnesium ethoxide and 200g of chitosan;
dispersing calcium isopropoxide in 1200g of anhydrous methanol, performing ultrasonic treatment for 1h, dissolving magnesium ethoxide in 1200g of deionized water, and mixing the dispersion liquid of the calcium isopropoxide with the solution of the magnesium ethoxide to obtain a precursor solution;
dissolving chitosan in 1200g of 2% acetic acid aqueous solution to obtain a chitosan solution, coating the chitosan solution on a glass substrate, and airing to obtain a chitosan template;
and (3) soaking the chitosan template into the precursor solution, reacting for 36h in a carbon dioxide atmosphere, taking out the chitosan template, washing with deionized water, and airing to obtain the calcium carbonate whisker.
The frit comprises 80g of feldspar, 90g of quartz, 60g of lepidolite, 30g of strontium carbonate, 50g of borax, 30g of calcium carbonate, 50g of zirconite, 30g of sodium fluosilicate and 30g of zinc oxide.
The frit preparation method comprises the following steps:
ball-milling zircon for 50h, and sieving with a 200-mesh sieve;
uniformly mixing feldspar, quartz, lepidolite, strontium carbonate, borax, calcium carbonate, zirconite, sodium fluosilicate and zinc oxide with the ball-milled zirconite, and sieving with a 20-mesh sieve for three times;
melting the sieved materials, controlling the temperature to be 1500 ℃, and performing water quenching to obtain milky white frit;
the milky white frit is crushed again and ball milled until the milky white frit can pass through a 200-mesh sieve.
The preparation method of the glaze comprises the following steps:
mixing albite, kaolin, dolomite, alumina, zinc oxide, calcined talc, frit and calcium carbonate whisker, and then carrying out ball milling to obtain the glaze.
The calcium carbonate whisker is a material with high strength, high modulus and good thermal stability, and can effectively improve the mechanical property of a glaze layer when being doped into the glaze.
The strength of the carved ceramic tile is fully improved, and the service life of the ceramic tile can be prolonged. The calcium carbonate whisker product has high purity, granular accumulation form on the surface, relatively large specific surface area and special concave-convex micro-morphology, and can enhance the binding capacity with other components, thereby further improving the strength of the ceramic tile.
Example 2
A digital finishing impression ceramic glaze, comprising:
300g of albite, 120g of kaolin, 120g of dolomite, 30g of alumina, 30g of zinc oxide, 40g of calcined talc, 450g of clinker and 20g of calcium carbonate whisker.
The calcium carbonate whisker is selected from Hebei Hemiguang mineral products Co.
The frit comprises 80g of feldspar, 90g of quartz, 60g of lepidolite, 30g of strontium carbonate, 50g of borax, 30g of calcium carbonate, 50g of zirconite, 30g of sodium fluosilicate and 30g of zinc oxide.
The frit preparation method comprises the following steps:
ball-milling zircon for 50h, and sieving with a 200-mesh sieve;
uniformly mixing feldspar, quartz, lepidolite, strontium carbonate, borax, calcium carbonate, zirconite, sodium fluosilicate and zinc oxide with the ball-milled zirconite, and sieving with a 20-mesh sieve for three times;
melting the sieved materials, controlling the temperature to be 1500 ℃, and performing water quenching to obtain milky white frit;
the milky white frit is crushed again and ball milled until the milky white frit can pass through a 200-mesh sieve.
The preparation method of the glaze comprises the following steps:
mixing albite, kaolin, dolomite, alumina, zinc oxide, calcined talc, frit and calcium carbonate whisker, and then carrying out ball milling to obtain the glaze.
Example 3
A digital finishing impression ceramic glaze, comprising:
300g of albite, 120g of kaolin, 120g of dolomite, 30g of alumina, 30g of zinc oxide, 40g of calcined talc, 450g of clinker and 20g of calcium carbonate whisker.
The preparation method of the calcium carbonate whisker comprises the following steps:
taking 40g of calcium isopropoxide, 8g of magnesium ethoxide and 200g of chitosan;
dispersing calcium isopropoxide in 1200g of anhydrous methanol, performing ultrasonic treatment for 1h, dissolving magnesium ethoxide in 1200g of deionized water, and mixing the dispersion liquid of the calcium isopropoxide with the solution of the magnesium ethoxide to obtain a precursor solution;
dissolving chitosan in 1200g of 2% acetic acid aqueous solution to obtain a chitosan solution, coating the chitosan solution on a glass substrate, and airing to obtain a chitosan template;
and (3) soaking the chitosan template into the precursor solution, reacting for 36h in a carbon dioxide atmosphere, taking out the chitosan template, washing with deionized water, and airing to obtain the calcium carbonate whisker.
The frit comprises 80g of feldspar, 90g of quartz, 60g of lepidolite, 30g of strontium carbonate, 50g of borax, 30g of calcium carbonate, 50g of zirconite, 30g of sodium fluosilicate and 30g of zinc oxide.
The frit preparation method comprises the following steps:
ball-milling zircon for 50h, and sieving with a 200-mesh sieve;
uniformly mixing feldspar, quartz, lepidolite, strontium carbonate, borax, calcium carbonate, zirconite, sodium fluosilicate and zinc oxide with the ball-milled zirconite, and sieving with a 20-mesh sieve for three times;
melting the sieved materials, controlling the temperature to be 1500 ℃, and performing water quenching to obtain milky white frit;
the milky white frit is crushed again and ball milled until the milky white frit can pass through a 200-mesh sieve.
The preparation method of the glaze comprises the following steps:
mixing albite, kaolin, dolomite, alumina, zinc oxide, calcined talc, frit and calcium carbonate whisker, and then carrying out ball milling to obtain the glaze.
The chitosan is modified chitosan, and the preparation method of the modified chitosan comprises the following steps:
taking 200g of chitosan and 80g of carbon nano tubes;
adding chitosan into 15000g of 2% acetic acid solution, stirring for 36h, filtering, and mixing with 3% polyvinyl alcohol solution with the same volume to obtain chitosan solution;
soaking the carbon nano tube into a mixed solution of sulfuric acid and nitric acid, wherein the concentration of the sulfuric acid is 12mol/L, the concentration of the nitric acid is 9mol/L, heating to 70 ℃, stirring for 36 hours, taking out a solid phase substance, washing with water, and drying to obtain a carboxylated carbon nano tube;
dispersing the carboxylated carbon nanotubes into a 3% polyvinyl alcohol solution, carrying out ultrasonic treatment until the carboxylated carbon nanotubes are fully dispersed, mixing the dispersion liquid of the carboxylated carbon nanotubes with a chitosan solution, stirring for 36 hours, adjusting the pH value to 6, washing with ethanol, centrifuging, and freeze-drying at-80 ℃ to obtain the modified chitosan.
Comparative example 1
A digital finishing impression ceramic glaze, comprising:
300g of albite, 120g of kaolin, 120g of dolomite, 30g of alumina, 30g of zinc oxide, 40g of calcined talc and 450g of clinker.
The frit comprises 80g of feldspar, 90g of quartz, 60g of lepidolite, 30g of strontium carbonate, 50g of borax, 30g of calcium carbonate, 50g of zirconite, 30g of sodium fluosilicate and 30g of zinc oxide.
The frit preparation method comprises the following steps:
ball-milling zircon for 50h, and sieving with a 200-mesh sieve;
uniformly mixing feldspar, quartz, lepidolite, strontium carbonate, borax, calcium carbonate, zirconite, sodium fluosilicate and zinc oxide with the ball-milled zirconite, and sieving with a 20-mesh sieve for three times;
melting the sieved materials, controlling the temperature to be 1500 ℃, and performing water quenching to obtain milky white frit;
the milky white frit is crushed again and ball milled until the milky white frit can pass through a 200-mesh sieve.
The preparation method of the glaze comprises the following steps:
mixing albite, kaolin, dolomite, alumina, zinc oxide, calcined talc and frit, and then ball-milling to obtain the glaze.
Examples of the experiments
The glaze materials in the embodiments 1-3 and the comparative example are prepared into ceramic tiles, and the preparation method comprises the following steps:
finely engraving a digital mould by adopting a laser four-dimensional finely engraving system;
performing positive beating and pressing to form a blank body;
controlling the water absorption rate of the adobe before glazing to be 20 percent by controlling the drying temperature of the adobe of the porcelain brick or the biscuit firing temperature of the adobe of the porcelain brick;
applying a base coat on the green body;
ink is jetted on the ground glaze to form an ink layer, and functional ink is adopted in the ink jetting;
and (3) applying a cover glaze on the ink layer, sintering at the temperature of 1190 ℃, and cooling to obtain the digital carved ceramic tile.
The breaking strength and modulus of rupture were tested with reference to GB/T3810.
TABLE 1 Properties of ceramic tiles made with glazes according to the embodiments
Example 1 adopts calcium carbonate whisker, and chitosan is adopted as a template in the preparation process of the whisker; the calcium carbonate crystal whisker adopted in the embodiment 2 does not adopt chitosan as a template; comparative example 1 no calcium carbonate whiskers were used; the crystal whisker prepared by taking the chitosan as the template can effectively improve the strength of the ceramic tile.
In the preparation process of the calcium carbonate whisker adopted in the embodiment 3, the modified chitosan is introduced as the template, so that the strength of the ceramic tile in the embodiment 3 is further improved, and the calcium carbonate whisker prepared by using the modified chitosan as the template can be better fused with a matrix, thereby fully improving the strength of the ceramic tile.
The above detailed description is specific to possible embodiments of the present invention, and the above embodiments are not intended to limit the scope of the present invention, and all equivalent implementations or modifications that do not depart from the scope of the present invention should be included in the present claims.
Claims (10)
1. A digital carved ceramic glaze is characterized by comprising:
25-35 parts of albite, 10-20 parts of kaolin, 10-15 parts of dolomite, 1-5 parts of alumina, 2-5 parts of zinc oxide, 1-5 parts of calcined talc, 40-60 parts of fusion cakes and 1-5 parts of calcium carbonate whiskers.
2. The digital engraving ceramic glaze of claim 1, comprising:
30-35 parts of albite, 12-20 parts of kaolin, 12-15 parts of dolomite, 3-5 parts of alumina, 3-5 parts of zinc oxide, 4-5 parts of calcined talc, 45-60 parts of fusion cakes and 2-5 parts of calcium carbonate whiskers.
3. The digital engraving ceramic glaze of claim 1, comprising:
30 parts of albite, 12 parts of kaolin, 12 parts of dolomite, 3 parts of alumina, 3 parts of zinc oxide, 4 parts of calcined talc, 45 parts of clinker and 2 parts of calcium carbonate whisker.
4. The digital engraving ceramic glaze of claim 1, wherein the preparation method of the calcium carbonate whiskers comprises:
taking 2-5 parts by mass of calcium isopropoxide, 0.5-1 part by mass of magnesium ethoxide and 10-25 parts by mass of chitosan;
dispersing calcium isopropoxide in 100-150 parts by mass of anhydrous methanol, performing ultrasonic treatment for 1-2 hours, dissolving magnesium ethoxide in 100-150 parts by mass of deionized water, and mixing the dispersion liquid of calcium isopropoxide with the solution of magnesium ethoxide to obtain a precursor solution;
dissolving chitosan in 100-150 parts by mass of 1-3% acetic acid aqueous solution to obtain a chitosan solution, coating the chitosan solution on a glass substrate, and airing to obtain a chitosan template;
and (3) soaking the chitosan template into the precursor solution, and reacting for 24-48 h in a carbon dioxide atmosphere to obtain the calcium carbonate whisker.
5. The digital engraving ceramic glaze material of claim 4, wherein the ceramic glaze material comprises, by mass, 4-5 parts of calcium isopropoxide, 0.8-1 part of magnesium ethoxide, and 20-25 parts of chitosan.
6. The digital engraving ceramic glaze of claim 5, wherein 4 parts by mass of calcium isopropoxide, 0.8 part by mass of magnesium ethoxide and 20 parts by mass of chitosan are taken.
7. The digital engraving ceramic glaze of claim 1, wherein the frit comprises 4-12 parts by mass of feldspar, 8-15 parts by mass of quartz, 4-10 parts by mass of lepidolite, 2-4 parts by mass of strontium carbonate, 4-8 parts by mass of borax, 2-4 parts by mass of calcium carbonate, 4-6 parts by mass of zircon, 2-4 parts by mass of sodium fluorosilicate and 2-4 parts by mass of zinc oxide.
8. The digital engraving ceramic glaze of claim 7, wherein the frit comprises 8-12 parts by mass of feldspar, 9-15 parts by mass of quartz, 6-10 parts by mass of lepidolite, 3-4 parts by mass of strontium carbonate, 5-8 parts by mass of borax, 3-4 parts by mass of calcium carbonate, 5-6 parts by mass of zircon, 3-4 parts by mass of sodium fluorosilicate and 3-4 parts by mass of zinc oxide.
9. The digital engraving ceramic glaze of claim 8, wherein the frit comprises 8 parts by mass of feldspar, 9 parts by mass of quartz, 6 parts by mass of lepidolite, 3 parts by mass of strontium carbonate, 5 parts by mass of borax, 3 parts by mass of calcium carbonate, 5 parts by mass of zircon, 3 parts by mass of sodium fluorosilicate and 3 parts by mass of zinc oxide.
10. The digital engraving ceramic glaze of claim 1, wherein the frit is prepared by the following steps:
ball-milling zircon for 40-60 h, and sieving with a 200-300-mesh sieve;
uniformly mixing feldspar, quartz, lepidolite, strontium carbonate, borax, calcium carbonate, zirconite, sodium fluosilicate and zinc oxide with the ball-milled zirconite, and sieving with a sieve of 18-20 meshes for three times;
melting the sieved materials, controlling the temperature to be 1500-1550 ℃, and performing water quenching to obtain a milky white frit;
and crushing the milky white frit again, and ball-milling until the milky white frit can pass through a 120-225-mesh sieve.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114573375A (en) * | 2022-03-29 | 2022-06-03 | 江苏脒诺甫纳米材料有限公司 | Zirconium silicate-containing high-wear-resistance sanitary ceramic and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104876618A (en) * | 2015-05-18 | 2015-09-02 | 青岛国航祥玉技术服务有限公司 | High-hardness ceramic brick |
| CN105908259A (en) * | 2016-05-16 | 2016-08-31 | 陕西师范大学 | Preparation method of calcium carbonate whiskers with concave and convex surface morphology |
| CN108298825A (en) * | 2018-01-31 | 2018-07-20 | 和县晶晶玻璃制品有限公司 | A kind of high intensity pressure resistance glassware and preparation method |
| CN111072284A (en) * | 2020-03-23 | 2020-04-28 | 广东欧文莱陶瓷有限公司 | Carved ceramic tile and production process thereof |
| CN113105116A (en) * | 2021-03-31 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Digital carved ceramic and preparation method thereof |
-
2021
- 2021-03-31 CN CN202110351768.3A patent/CN112851119A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104876618A (en) * | 2015-05-18 | 2015-09-02 | 青岛国航祥玉技术服务有限公司 | High-hardness ceramic brick |
| CN105908259A (en) * | 2016-05-16 | 2016-08-31 | 陕西师范大学 | Preparation method of calcium carbonate whiskers with concave and convex surface morphology |
| CN108298825A (en) * | 2018-01-31 | 2018-07-20 | 和县晶晶玻璃制品有限公司 | A kind of high intensity pressure resistance glassware and preparation method |
| CN111072284A (en) * | 2020-03-23 | 2020-04-28 | 广东欧文莱陶瓷有限公司 | Carved ceramic tile and production process thereof |
| CN113105116A (en) * | 2021-03-31 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Digital carved ceramic and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114573375A (en) * | 2022-03-29 | 2022-06-03 | 江苏脒诺甫纳米材料有限公司 | Zirconium silicate-containing high-wear-resistance sanitary ceramic and preparation method thereof |
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Application publication date: 20210528 |