CN101705142A - Emulsified oil - Google Patents

Emulsified oil Download PDF

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Publication number
CN101705142A
CN101705142A CN200910193808A CN200910193808A CN101705142A CN 101705142 A CN101705142 A CN 101705142A CN 200910193808 A CN200910193808 A CN 200910193808A CN 200910193808 A CN200910193808 A CN 200910193808A CN 101705142 A CN101705142 A CN 101705142A
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CN
China
Prior art keywords
oil
water emulsion
sterilant
benzotriazole
trolamine
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Granted
Application number
CN200910193808A
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Chinese (zh)
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CN101705142B (en
Inventor
舒凡
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Dongguan City Yinxing Technology Development Co Ltd
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Dongguan City Yinxing Technology Development Co Ltd
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Priority to CN 200910193808 priority Critical patent/CN101705142B/en
Publication of CN101705142A publication Critical patent/CN101705142A/en
Application granted granted Critical
Publication of CN101705142B publication Critical patent/CN101705142B/en
Expired - Fee Related legal-status Critical Current
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  • Lubricants (AREA)
  • Colloid Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses emulsified oil, which is characterized by comprising the following components in percentage by mass: engine oil No.10 50-80, refined lard oil 1-5, octyl phenol polyoxyethylene ether 1-5, triethanolamine 1-5, emulsifier S-80 5-15, triethanolamine 0.5-5, sodium alkylsulfonate 0.5-5, benzotriazole 0.5-5, absolute alcohol 0.5-5 and bactericide 0-2. The emulsified oil is simple in formula and convenient in use and, when use in nonferrous metals, can improve the oxidation resistance and rust-proof performance of the nonferrous metals and prolong the service life of nonferrous metal equipment.

Description

A kind of oil in water emulsion
Technical field
The present invention relates to oil in water emulsion, be suitable for metal processing, particularly non-ferrous metal adds the water-soluble biological stable form oil in water emulsion of using man-hour.
Background technology
At present, the oil in water emulsion kind that is applicable to non-ferrous metal processing usefulness on the market is more, and its materials used is vegetable and animals oils or synthetic fat mostly, and demixing phenomenon appears in its less stable easily, is easy to smelly going bad, and is not suitable for prolonged preservation.In addition, in use, also make the non-ferrous metal oxidation easily, variable color causes infringement to a certain degree.
Summary of the invention
At the problems referred to above, the invention provides a kind of oil in water emulsion, be used for metal processing, particularly non-ferrous metal and add and improved the antirust ability of non-ferrous metal effectively man-hour, thereby make non-ferrous metal exempt from damage.
The present invention is achieved through the following technical solutions: a kind of oil in water emulsion, composed of the following components by mass percentage:
10# machine oil 50~80%
Prepared lard 1~5%
Sim alkylphenol Soxylat A 25-7 1~5%
Triethanolamine oleate 1~5%
Span-80 5~15%
Trolamine 0.5~5%
Petroleum sodium sulfonate 0.5~5%
Benzotriazole 0.5~5%
Dehydrated alcohol 0.5~5%
Sterilant 0~2%.
Described oil in water emulsion, composed of the following components by mass percentage:
10# machine oil 79%
Prepared lard 3%
Sim alkylphenol Soxylat A 25-7 4.2%
Triethanolamine oleate 3.86%
Span-80 6.84%
Trolamine 1.5%
Petroleum sodium sulfonate 0.4%
Benzotriazole 0.5%
Dehydrated alcohol 0.5%
Sterilant 0.2%.
Described sterilant is the oxazolidine derivative.
When described oil in water emulsion was used to cut, usage ratio was 5%~8%.
When described oil in water emulsion was used for drilling-tapping, usage ratio was 8%~12%.
When described oil in water emulsion was used for grinding, usage ratio was 3%~5%.
When described oil in water emulsion was used to pull out drawing process, usage ratio was 8%~12%.
The preparation method of the described oil in water emulsion of described oil in water emulsion, its concrete steps are as follows:
1) with 10# machine oil, prepared lard, sim alkylphenol Soxylat A 25-7, triethanolamine oleate, Span-80 is in trolamine and the petroleum sodium sulfonate adding system successively, after adding each component, add another kind of component again after all need mixing and dissolve, get mixture I;
2) get benzotriazole and dehydrated alcohol, mix, get mixtures II;
3) get mixture I, mixtures II and sterilant, thorough mixing promptly gets oil in water emulsion.
Oil in water emulsion of the present invention, it has added benzotriazole in prescription, benzotriazole can with non-ferrous metal complexings such as copper, silver, form stable chelate, thereby improved the resistance of oxidation of non-ferrous metal, avoided non-ferrous metal to get rusty, thereby prolonged its work-ing life.
Described oil in water emulsion directly mixes with clear water in use, stirs and can use.
Oil in water emulsion of the present invention should be noted carrying out care and maintenance from following several respects when using as water-soluble metalworking liquid: 1) regularly detect working concentration, and low excessively as concentration, in time add new liquid.2) the pH value with water-soluble metalworking liquid is controlled between 8.3~9.3, and the pH value is too high, causes allergicly to a certain extent, and the pH value is low excessively, then can influence the antirust ability and the antibacterial ability of cutting fluid.3) test set oil slick amount and graining amount are too much as the oil slick amount, and in time whether monitoring device oil leakage fault occurs, and in time handle; Too much as the graining amount, then may be that water hardness is higher.4) the regular microbial biomass on the test set replenishes sterilant in case of necessity in water-soluble metalworking liquid, prolong water-soluble metalworking liquid work-ing life.
Beneficial effect of the present invention is: oil in water emulsion of the present invention, prescription is simple, and is easy to use, when being applied to non-ferrous metal, improved the resistance of oxidation and the antirust ability of non-ferrous metal, prolonged the work-ing life of non-ferrous metal equipment.
Embodiment
Essence for a better understanding of the present invention illustrates the present invention below with reference to concrete experiment and result.
Embodiment 1
A kind of oil in water emulsion, composed of the following components by mass percentage:
10# machine oil 79%
Prepared lard 3%
Sim alkylphenol Soxylat A 25-7 4.2%
Triethanolamine oleate 3.86%
Span-80 6.84%
Trolamine 1.5%
Petroleum sodium sulfonate 0.4%
Benzotriazole 0.5%
Dehydrated alcohol 0.5%
Sterilant 0.2%,
Described sterilant is the oxazolidine derivative.
The preparation method of described oil in water emulsion is: the 10# machine oil of 1) getting above-mentioned dosage, prepared lard, the sim alkylphenol Soxylat A 25-7, triethanolamine oleate, Span-80, trolamine and petroleum sodium sulfonate, add successively in the container, after adding each component, add another kind of component again after all need mixing and dissolve, get mixture I; 2) get the benzotriazole and the dehydrated alcohol of above-mentioned dosage, mix, mixtures II; 3) get mixture I, mixtures II and oxazolidine derivative, thorough mixing promptly gets oil in water emulsion.
Embodiment 2:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, promptly get water-soluble metalworking liquid by 5%.
Embodiment 3:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, promptly get water-soluble metalworking liquid by 7.5%.
Embodiment 4:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, be used for drilling-tapping by 11.5%.
Embodiment 5:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, be used for drilling-tapping by 8.5%.
Embodiment 6:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, be used for grinding by 3%.
Embodiment 7:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, be used for grinding by 5%.
Embodiment 8:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, be used to pull out drawing process (wire drawing) by 8%.
Embodiment 9:
Get embodiment 1 gained oil in water emulsion, mix with clear water, stir, be used to pull out drawing process (wire drawing) by 11.5%.
Embodiment 8:
10# machine oil 55%
Prepared lard 5%
Sim alkylphenol Soxylat A 25-7 5%
Triethanolamine oleate 5%
Span-80 14%
Trolamine 3%
Petroleum sodium sulfonate 3%
Benzotriazole 4%
Dehydrated alcohol 4%
Sterilant 2%.
Embodiment 9:
10# machine oil 70%
Prepared lard 3%
Sim alkylphenol Soxylat A 25-7 3%
Triethanolamine oleate 3%
Span-80 10%
Trolamine 2%
Petroleum sodium sulfonate 2%
Benzotriazole 3%
Dehydrated alcohol 3%
Sterilant 1%.
The foregoing description is preferred embodiment of the present invention, is not to be used for limiting the scope of the present invention, so all equivalences of being done with described feature of claim of the present invention and principle change or modify, all should be included within the claim scope of the present invention.

Claims (8)

1. an oil in water emulsion is characterized in that, and is composed of the following components by mass percentage:
10# machine oil 50~80%
Prepared lard 1~5%
Sim alkylphenol Soxylat A 25-7 1~5%
Triethanolamine oleate 1~5%
Span-80 5~15%
Trolamine 0.5~5%
Petroleum sodium sulfonate 0.5~5%
Benzotriazole 0.5~5%
Dehydrated alcohol 0.5~5%
Sterilant 0~2%.
2. oil in water emulsion as claimed in claim 1 is characterized in that, and is composed of the following components by mass percentage:
10# machine oil 79%
Prepared lard 3%
Sim alkylphenol Soxylat A 25-7 4.2%
Triethanolamine oleate 3.86%
Span-80 6.84%
Trolamine 1.5%
Petroleum sodium sulfonate 0.4%
Benzotriazole 0.5%
Dehydrated alcohol 0.5%
Sterilant 0.2%.
3. oil in water emulsion as claimed in claim 1 or 2 is characterized in that: described sterilant is the oxazolidine derivative.
4. oil in water emulsion as claimed in claim 1 or 2 is characterized in that: when described oil in water emulsion was used to cut, usage ratio was 5%~8%.
5. oil in water emulsion as claimed in claim 1 or 2 is characterized in that: when described oil in water emulsion was used for drilling-tapping, usage ratio was 8%~12%.
6. oil in water emulsion as claimed in claim 1 or 2 is characterized in that: when described oil in water emulsion was used for grinding, usage ratio was 3%~5%.
7. oil in water emulsion as claimed in claim 1 or 2 is characterized in that: when described oil in water emulsion was used to pull out drawing process, usage ratio was 8%~12%.
8. the preparation method of the described oil in water emulsion of oil in water emulsion as claimed in claim 1 or 2 is characterized in that, its concrete steps are as follows:
1) with 10# machine oil, prepared lard, sim alkylphenol Soxylat A 25-7, triethanolamine oleate, Span-80 is in trolamine and the petroleum sodium sulfonate adding system successively, after adding each component, add another kind of component again after all need mixing and dissolve, get mixture I;
2) get benzotriazole and dehydrated alcohol, mix, get mixtures II;
3) get mixture I, mixtures II and sterilant, thorough mixing promptly gets oil in water emulsion.
CN 200910193808 2009-11-11 2009-11-11 Emulsified oil Expired - Fee Related CN101705142B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN101705142A true CN101705142A (en) 2010-05-12
CN101705142B CN101705142B (en) 2013-05-22

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102041150A (en) * 2011-01-14 2011-05-04 上海锦海特种润滑油厂 Anti-rust emulsified oil and preparation method thereof
CN102676134A (en) * 2012-05-02 2012-09-19 陆明富 Preparation method for vegetable oil anti-jamming lubricant
CN103232885A (en) * 2013-05-13 2013-08-07 富通集团有限公司 Emulsified oil composition and preparation method thereof
CN104403746A (en) * 2014-10-22 2015-03-11 安徽荣达阀门有限公司 Emulsified cutting oil for metal processing and with reinforced rust resistance and preparation method thereof
CN104450100A (en) * 2014-12-25 2015-03-25 常熟市江南锻造有限公司 Anti-oxidation metal working fluid
CN105238517A (en) * 2015-10-19 2016-01-13 无锡贺邦金属制品有限公司 Anti-rust cutting oil for machining non-ferrous metal
CN105238518A (en) * 2015-10-19 2016-01-13 无锡贺邦金属制品有限公司 Emulsion cutting oil suitable for metal drilling
CN106929131A (en) * 2017-04-20 2017-07-07 合肥浦尔菲电线科技有限公司 A kind of machining emulsion type lubricant
CN107287009A (en) * 2017-06-24 2017-10-24 山东天力润滑油有限公司 Hydraulic support oil emulsion and its production technology
CN108531271A (en) * 2018-04-11 2018-09-14 江苏捷达油品有限公司 A kind of energy saving self-cleaning type anticorrosive emulsified oil and its preparation method and application
CN108641784A (en) * 2018-04-11 2018-10-12 江苏捷达油品有限公司 A kind of comprehensive anticorrosive emulsified oil and its preparation method and application for taking into account lubrication and refrigerating function

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004060039A1 (en) * 2004-12-14 2006-07-06 Görlach, Bernd, Dr. Lubricant (preferably grease) comprises a basic oil, a thickener and an additive (polyamide/imide additive and a metal salt)
CN101029268B (en) * 2007-04-09 2010-12-29 大连三达奥克化学有限公司 Lubricating and cooling emulsified oil of copper-alloy fine drawing and its production
CN101240218B (en) * 2008-02-29 2011-12-07 益田润石(北京)化工有限公司 Emulsification type metal cutting liquor composition
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石(北京)化工有限公司 Micro-emulsion type metal cutting liquor composition

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102041150A (en) * 2011-01-14 2011-05-04 上海锦海特种润滑油厂 Anti-rust emulsified oil and preparation method thereof
CN102041150B (en) * 2011-01-14 2013-05-01 上海锦海特种润滑油厂 Anti-rust emulsified oil and preparation method thereof
CN102676134A (en) * 2012-05-02 2012-09-19 陆明富 Preparation method for vegetable oil anti-jamming lubricant
CN103232885A (en) * 2013-05-13 2013-08-07 富通集团有限公司 Emulsified oil composition and preparation method thereof
CN103232885B (en) * 2013-05-13 2014-06-11 富通集团有限公司 Emulsified oil composition and preparation method thereof
CN104403746A (en) * 2014-10-22 2015-03-11 安徽荣达阀门有限公司 Emulsified cutting oil for metal processing and with reinforced rust resistance and preparation method thereof
CN104450100A (en) * 2014-12-25 2015-03-25 常熟市江南锻造有限公司 Anti-oxidation metal working fluid
CN105238517A (en) * 2015-10-19 2016-01-13 无锡贺邦金属制品有限公司 Anti-rust cutting oil for machining non-ferrous metal
CN105238518A (en) * 2015-10-19 2016-01-13 无锡贺邦金属制品有限公司 Emulsion cutting oil suitable for metal drilling
CN106929131A (en) * 2017-04-20 2017-07-07 合肥浦尔菲电线科技有限公司 A kind of machining emulsion type lubricant
CN107287009A (en) * 2017-06-24 2017-10-24 山东天力润滑油有限公司 Hydraulic support oil emulsion and its production technology
CN108531271A (en) * 2018-04-11 2018-09-14 江苏捷达油品有限公司 A kind of energy saving self-cleaning type anticorrosive emulsified oil and its preparation method and application
CN108641784A (en) * 2018-04-11 2018-10-12 江苏捷达油品有限公司 A kind of comprehensive anticorrosive emulsified oil and its preparation method and application for taking into account lubrication and refrigerating function
CN108531271B (en) * 2018-04-11 2021-01-22 江苏捷达油品有限公司 Energy-saving self-cleaning antirust emulsified oil and preparation method and application thereof

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