CN101696332A - Ultra-violet curing transfer ink - Google Patents
Ultra-violet curing transfer ink Download PDFInfo
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- CN101696332A CN101696332A CN 200910186408 CN200910186408A CN101696332A CN 101696332 A CN101696332 A CN 101696332A CN 200910186408 CN200910186408 CN 200910186408 CN 200910186408 A CN200910186408 A CN 200910186408A CN 101696332 A CN101696332 A CN 101696332A
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Abstract
The invention relates to ultra-violet curing transfer ink, which comprises the following components in percentage by weight: 30 to 50 percent of resin, 5 to 15 percent of adhesion promoting resin, 20 to 30 percent of acrylate compound monomer, 2 to 6 percent of polymer dispersant, 5 to 9 percent of photo-initiator and 13 to 16 percent of color concentrate, wherein the resin is epoxy acrylate, urethane acrylate or a mixture of the epoxy acrylate and the urethane acrylate in any proportion; the adhesion promoting resin is any hydroxyl acrylate with a viscosity of lower than 3,000cps at below 25 DEG C; and the polymer dispersant is a dicarboxylic ester solution of a polymer of which the molecular weight is between 4,000 and 25,000 and the pigment compatible group is an amine group. The ultra-violet curing transfer ink can replace the conventional solvent type ink, and can be printed on floors, furniture, decorating plates, and the like so as to provide more clear and vivid patterns. Moreover, the ultra-violet curing transfer ink has the advantages of high curing speed, high production efficiency, plate production cost reduction, environmental protection, and the like.
Description
Technical field
The present invention relates to a kind of transfer ink that is printed on floor, furniture, the decorative sheet etc.
Background technology
In the prior art, transfer ink be dyestuff with special property be main make be imprinted on pattern on the special paper, literal etc., can make it to transfer to the printing ink that other base materials get on because of heating.The current two kinds of printing ink that mainly contain that are used for floor, furniture, decorative sheet printing on the market: water color ink and oil-based ink.Both key distinctions are the difference of solvent, and water color ink is solvent with water; Oil-based ink is a solvent with organic solvent (toluene, dimethylbenzene, industrial spirit etc.); The two principle of solidification is basic identical.Wherein, water color ink is owing to be solvent with water, thereby evaporation rate is slow, influences production rate; And oil-based ink is harmful owing to the use of organic solvent, and in addition, these two kinds of printing ink all have solvent resistance poor, and chemical resistance is poor, shortcomings such as weather resistance difference.And owing to be not 100% to contain admittedly, if solvent is failed volatilization in time, then ink printing on ink film, can flow, adhesion, and the printing texture is thickened.
Summary of the invention
Technical problem to be solved by this invention is in order to overcome the deficiencies in the prior art, a kind of ultra-violet curing transfer ink to be provided.
For solving above technical problem, the present invention takes following technical scheme:
A kind of ultra-violet curing transfer ink, this printing ink is made up of following components in weight percentage content: resin 30%～50%; Sticking power promotes resin 5%～15%; Acrylic ester compound monomer 20%～30%; Macromolecule dispersing agent 2%～6%; Light trigger 5%～9%; Toner 13%～16%, wherein said resin is an epoxy acrylate, the mixture of urethane acrylate or their arbitrary proportion, described sticking power promotes that resin is any hydroxy acrylates of 25 ℃ of following viscosity less than 3000cps, described macromolecule dispersing agent be molecular weight between 4000～25000, pigment affinity group is the dicarboxylic ester solution of the polymkeric substance of amine group.
According to the present invention, described resin is preferably epoxy acrylate and urethane acrylate by mass ratio 0.25～0.5: 1 mixture of forming.Described acrylic ester compound monomer is one or more the mixture in 2-EHA, dihydroxy methylpropane diacrylate and the Viscoat 295.The quality percentage composition of polymkeric substance is 20%～40% in the described macromolecule dispersing agent.Described light trigger is 2-hydroxy-2-methyl phenyl-propane-1-ketone, 1-hydroxy-cyclohexyl phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2; 4, the mixture of one or more in 6-trimethylbenzoyl-diphenyl phosphine oxide, the thioxanthone.Described toner can be one or more the mixture in yellow ultramarine, red pigment, black pigment and the white pigment.
Owing to take above technical scheme, the present invention compared with prior art has following advantage:
Ultra-violet curing transfer ink of the present invention can replace traditional solvent type ink to be printed on floor, furniture, the decorative sheet etc. provides pattern more clear and true to nature, has that curing speed is fast, production efficiency is high, reduces advantages such as board materials production cost and environmental protection.
Embodiment
Forming various raw material of the present invention can directly buy from the market, or prepares by the means of prior art.Now in conjunction with specific embodiments the present invention is done further detailed description.
Embodiment 1
According to the ultra-violet curing transfer ink of present embodiment, composition sees Table 1.
Table 1
The transfer ink of present embodiment can prepare by the following method: at first toner, a part of resin, a part of monomer, dispersion agent are stirred, after grinding disperses through three rollers, residual monomer, residual resin and light trigger are added, stir more than the 20min promptly.
Embodiment 2
According to the ultra-violet curing transfer ink of present embodiment, composition sees Table 2.
Table 2
Embodiment 3
According to the ultra-violet curing transfer ink of present embodiment, composition sees Table 3.
Table 3
Embodiment 4
According to the ultra-violet curing transfer ink of present embodiment, composition sees Table 4.
Table 4
Embodiment 5
According to the ultra-violet curing transfer ink of present embodiment, composition sees Table 5.
Table 5
Embodiment 6
According to the ultra-violet curing transfer ink of present embodiment, composed as followsly see Table 6.
Table 6
Printing ink to embodiment 1 to 6 has carried out physical property measurement, the results are shown in Table 7.
Table 7
More than the present invention has been done detailed description; its purpose is to allow the personage that is familiar with this art can understand content of the present invention and is implemented; can not limit protection scope of the present invention with this; all equivalences of doing according to spirit of the present invention change or modify, and all should be encompassed in protection scope of the present invention.
Claims (6)
1. ultra-violet curing transfer ink, it is characterized in that: this printing ink is made up of following components in weight percentage content: resin 30%～50%; Sticking power promotes resin 5%～15%; Acrylic ester compound monomer 20%～30%; Macromolecule dispersing agent 2%～6%; Light trigger 5%～9%; Toner 13%～16%, wherein said resin is an epoxy acrylate, the mixture of urethane acrylate or their arbitrary proportion, described sticking power promotes that resin is any hydroxy acrylates of 25 ℃ of following viscosity less than 3000cps, described macromolecule dispersing agent be molecular weight between 4000～25000, pigment affinity group is the dicarboxylic ester solution of the polymkeric substance of amine group.
2. ultra-violet curing transfer ink according to claim 1 is characterized in that: described resin is epoxy acrylate and urethane acrylate by mass ratio 0.25～0.5: 1 mixture of forming.
3. ultra-violet curing transfer ink according to claim 1 is characterized in that: described acrylic ester compound monomer is one or more the mixture in 2-EHA, dihydroxy methylpropane diacrylate and the Viscoat 295.
4. ultra-violet curing transfer ink according to claim 1 is characterized in that: the quality percentage composition of polymkeric substance is 20%～40% in the described macromolecule dispersing agent.
5. according to ultra-violet curing transfer ink according to claim 1; it is characterized in that: described light trigger is 2-hydroxy-2-methyl phenyl-propane-1-ketone, 1-hydroxy-cyclohexyl phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2; 4, the mixture of one or more in 6-trimethylbenzoyl-diphenyl phosphine oxide, the thioxanthone.
6. according to according to each described ultra-violet curing transfer ink in the claim 1 to 5, it is characterized in that: described toner is one or more the mixture in yellow ultramarine, red pigment, black pigment and the white pigment.
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| CN 200910186408 CN101696332B (en) | 2009-10-28 | 2009-10-28 | Ultra-violet curing transfer ink |
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| CN 200910186408 CN101696332B (en) | 2009-10-28 | 2009-10-28 | Ultra-violet curing transfer ink |
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| CN101696332A true CN101696332A (en) | 2010-04-21 |
| CN101696332B CN101696332B (en) | 2012-05-23 |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948643A (en) * | 2010-09-29 | 2011-01-19 | 安徽光谷新材料科技有限公司 | UV photocuring ink material for printing window lens of digital product |
| CN102702848A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof |
| CN103602142A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业（昆山）有限公司 | Novel ultraviolet-curing transfer printing ink |
| CN103666051A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Quick-drying type UV cured printing ink and preparation method thereof |
| CN103666031A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Printing ink for ultraviolet light curing intaglio printing and preparation method of printing ink |
| CN103666036A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Scratching-resistant antifouling UV cured printing ink and preparation method thereof |
| CN104292970A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | Ultraviolet-curing screen printing ink for acrylic decorative plate |
| CN104672984A (en) * | 2015-03-18 | 2015-06-03 | Ppg涂料(天津)有限公司 | Ink connecting material, ink composition, printing composition, printing method and base material |
| CN104830148A (en) * | 2015-06-03 | 2015-08-12 | 林振坤 | Environment-friendly UV curing silk screen ink and production method thereof |
| CN105315731A (en) * | 2014-07-31 | 2016-02-10 | 杜广清 | UV gloss oil used for laser embossing transfer equipment |
| CN105968942A (en) * | 2016-07-12 | 2016-09-28 | 昆山市曙光照明器材有限公司 | LED-solidified water transfer printing ink and preparation method thereof |
| CN106046408A (en) * | 2016-07-19 | 2016-10-26 | 东莞市纳利光学材料有限公司 | Printable release film and preparation method thereof |
| CN106046927A (en) * | 2016-07-12 | 2016-10-26 | 昆山市曙光照明器材有限公司 | Hydrographic transfer printing ink and preparation method thereof |
| CN106189487A (en) * | 2016-07-12 | 2016-12-07 | 昆山市曙光照明器材有限公司 | A kind of water transfer inking front cover oil of LED solidification and preparation method thereof |
| CN106497237A (en) * | 2016-11-25 | 2017-03-15 | 珠海展辰新材料有限公司 | A kind of curable UV mill bases |
| CN110475827A (en) * | 2017-03-31 | 2019-11-19 | 花王株式会社 | Radiation-curable composition for ink, printing product and its application method |
| CN113072835A (en) * | 2021-03-30 | 2021-07-06 | 中山市中益油墨涂料有限公司 | Ultraviolet light curing glass printing ink and preparation method thereof |
| CN113698092A (en) * | 2020-12-14 | 2021-11-26 | 深圳纤亿通科技有限公司 | Optical fiber and preparation method thereof |
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| CN100577753C (en) * | 2005-06-24 | 2010-01-06 | 上海华明高技术（集团）有限公司 | Ultraviolet light cured printing ink |
| CN100343344C (en) * | 2005-12-26 | 2007-10-17 | 中国化工建设总公司常州涂料化工研究院 | Ultraviolet curing coating for metal plating surface protection |
| CN100567413C (en) * | 2007-11-01 | 2009-12-09 | 凌云剑 | Highly wearable vacuum coating ultraviolet curing coatings |
| CN101250354B (en) * | 2008-03-26 | 2011-04-27 | 中国印钞造币总公司 | UV-oxide hybrid drying type engraving intaglio printing ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948643A (en) * | 2010-09-29 | 2011-01-19 | 安徽光谷新材料科技有限公司 | UV photocuring ink material for printing window lens of digital product |
| CN102702848A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof |
| CN102702848B (en) * | 2012-06-05 | 2015-06-24 | 无锡金桥精细油墨有限公司 | Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof |
| CN103666031A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Printing ink for ultraviolet light curing intaglio printing and preparation method of printing ink |
| CN103666031B (en) * | 2013-11-23 | 2016-05-04 | 铜陵方正塑业科技有限公司 | A kind of ultraviolet light polymerization gravure printing ink and preparation method thereof |
| CN103666051B (en) * | 2013-11-25 | 2016-03-23 | 铜陵方正塑业科技有限公司 | A kind of fast-drying type UV curable ink and preparation method thereof |
| CN103666051A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Quick-drying type UV cured printing ink and preparation method thereof |
| CN103666036A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Scratching-resistant antifouling UV cured printing ink and preparation method thereof |
| CN103602142A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业（昆山）有限公司 | Novel ultraviolet-curing transfer printing ink |
| CN103602142B (en) * | 2013-12-06 | 2016-03-02 | 东周化学工业（昆山）有限公司 | Ultra-violet curing transfer ink |
| CN105315731B (en) * | 2014-07-31 | 2019-02-12 | 杜广清 | UV gloss oil and its application method on laser imprinting transfer equipment |
| CN105315731A (en) * | 2014-07-31 | 2016-02-10 | 杜广清 | UV gloss oil used for laser embossing transfer equipment |
| CN104292970A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | Ultraviolet-curing screen printing ink for acrylic decorative plate |
| CN104672984A (en) * | 2015-03-18 | 2015-06-03 | Ppg涂料(天津)有限公司 | Ink connecting material, ink composition, printing composition, printing method and base material |
| CN104830148A (en) * | 2015-06-03 | 2015-08-12 | 林振坤 | Environment-friendly UV curing silk screen ink and production method thereof |
| CN106046927A (en) * | 2016-07-12 | 2016-10-26 | 昆山市曙光照明器材有限公司 | Hydrographic transfer printing ink and preparation method thereof |
| CN106189487A (en) * | 2016-07-12 | 2016-12-07 | 昆山市曙光照明器材有限公司 | A kind of water transfer inking front cover oil of LED solidification and preparation method thereof |
| CN105968942A (en) * | 2016-07-12 | 2016-09-28 | 昆山市曙光照明器材有限公司 | LED-solidified water transfer printing ink and preparation method thereof |
| CN106046408A (en) * | 2016-07-19 | 2016-10-26 | 东莞市纳利光学材料有限公司 | Printable release film and preparation method thereof |
| CN106497237A (en) * | 2016-11-25 | 2017-03-15 | 珠海展辰新材料有限公司 | A kind of curable UV mill bases |
| CN110475827A (en) * | 2017-03-31 | 2019-11-19 | 花王株式会社 | Radiation-curable composition for ink, printing product and its application method |
| US11193027B2 (en) | 2017-03-31 | 2021-12-07 | Kao Corporation | Radiation curable ink compositions, printed articles, and methods of using the same |
| CN110475827B (en) * | 2017-03-31 | 2022-02-15 | 花王株式会社 | Radiation curable ink compositions, printed articles, and methods of using the same |
| CN113698092A (en) * | 2020-12-14 | 2021-11-26 | 深圳纤亿通科技有限公司 | Optical fiber and preparation method thereof |
| CN113072835A (en) * | 2021-03-30 | 2021-07-06 | 中山市中益油墨涂料有限公司 | Ultraviolet light curing glass printing ink and preparation method thereof |
| CN113072835B (en) * | 2021-03-30 | 2023-09-01 | 中山市中益油墨涂料有限公司 | Ultraviolet light curing glass printing ink and preparation method thereof |
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