CN101695345B - 一种蔬菜水果中农药残留的消降方法 - Google Patents
一种蔬菜水果中农药残留的消降方法 Download PDFInfo
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- CN101695345B CN101695345B CN2009101540650A CN200910154065A CN101695345B CN 101695345 B CN101695345 B CN 101695345B CN 2009101540650 A CN2009101540650 A CN 2009101540650A CN 200910154065 A CN200910154065 A CN 200910154065A CN 101695345 B CN101695345 B CN 101695345B
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- Prior art keywords
- vegetables
- medium
- fruits
- eliminating
- residues
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- 238000000034 method Methods 0.000 title claims abstract description 23
- 235000013311 vegetables Nutrition 0.000 title claims abstract description 17
- 235000013399 edible fruits Nutrition 0.000 title claims abstract description 16
- 239000000447 pesticide residue Substances 0.000 title claims abstract description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 230000005587 bubbling Effects 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 238000004140 cleaning Methods 0.000 claims abstract description 5
- 239000000575 pesticide Substances 0.000 claims description 21
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 claims description 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims description 2
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 claims description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 10
- 239000003905 agrochemical Substances 0.000 description 6
- 235000012055 fruits and vegetables Nutrition 0.000 description 6
- 239000005946 Cypermethrin Substances 0.000 description 5
- 239000005949 Malathion Substances 0.000 description 5
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 5
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 5
- 229960005424 cypermethrin Drugs 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 5
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 5
- 229960000453 malathion Drugs 0.000 description 5
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 5
- RLBIQVVOMOPOHC-UHFFFAOYSA-N parathion-methyl Chemical group COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1 RLBIQVVOMOPOHC-UHFFFAOYSA-N 0.000 description 5
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 5
- 229960000490 permethrin Drugs 0.000 description 5
- 239000005916 Methomyl Substances 0.000 description 4
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 4
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 4
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 4
- 229940113124 polysorbate 60 Drugs 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- AFCIMSXHQSIHQW-UHFFFAOYSA-N [O].[P] Chemical group [O].[P] AFCIMSXHQSIHQW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- -1 sucrose ester Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Pretreatment Of Seeds And Plants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2009101540650A CN101695345B (zh) | 2009-10-23 | 2009-10-23 | 一种蔬菜水果中农药残留的消降方法 |
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CN2009101540650A CN101695345B (zh) | 2009-10-23 | 2009-10-23 | 一种蔬菜水果中农药残留的消降方法 |
Publications (2)
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CN101695345A CN101695345A (zh) | 2010-04-21 |
CN101695345B true CN101695345B (zh) | 2013-04-24 |
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CN2009101540650A Expired - Fee Related CN101695345B (zh) | 2009-10-23 | 2009-10-23 | 一种蔬菜水果中农药残留的消降方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018153613A1 (en) | 2017-02-22 | 2018-08-30 | Unilever N.V. | Device and method for cleaning surface of objects |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103637031B (zh) * | 2013-11-29 | 2016-02-17 | 北京农学院 | 一种去除蔬菜水果中农药残留的方法 |
CN104431662A (zh) * | 2014-11-14 | 2015-03-25 | 江苏天康食品有限公司 | 去除蔬菜表面农药的方法 |
CN104496005B (zh) * | 2014-12-30 | 2016-03-02 | 河海大学常州校区 | 超声协同臭氧降解乙酰甲胺磷的降解方法 |
CN107412813A (zh) * | 2017-05-03 | 2017-12-01 | 文山学院 | 一种利用臭氧去除三七中农药残留的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101224033A (zh) * | 2007-01-15 | 2008-07-23 | 许绍聪 | 瓜果蔬菜全效净化技术 |
CN101279129A (zh) * | 2008-06-04 | 2008-10-08 | 河南省商业科学研究所有限责任公司 | 蔬菜中残留农药的动态脱除方法及装置 |
-
2009
- 2009-10-23 CN CN2009101540650A patent/CN101695345B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101224033A (zh) * | 2007-01-15 | 2008-07-23 | 许绍聪 | 瓜果蔬菜全效净化技术 |
CN101279129A (zh) * | 2008-06-04 | 2008-10-08 | 河南省商业科学研究所有限责任公司 | 蔬菜中残留农药的动态脱除方法及装置 |
Non-Patent Citations (3)
Title |
---|
张宁.臭氧降解蔬菜中农药残留机理与效果研究.《食品与机械》.2006,第22卷(第4期),57-59,66. * |
李莉等.蔬菜中农药残留的去除方法.《农药》.2005,第44卷(第8期),347-351. * |
龙万凯等.蔗糖酯洗涤剂去除农药残留的试验.《化工技术与开发》.2002,第31卷(第4期),17-18. * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018153613A1 (en) | 2017-02-22 | 2018-08-30 | Unilever N.V. | Device and method for cleaning surface of objects |
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CN101695345A (zh) | 2010-04-21 |
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C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Ding Yuting Inventor after: Lv Fei Inventor after: Liu Jianhua Inventor after: Wang Wenbiao Inventor after: Zhao Peicheng Inventor after: Feng Chaohui Inventor after: Luo Guoliang Inventor before: Ding Yuting Inventor before: Wang Wenbiao Inventor before: Zhao Peicheng Inventor before: Liu Shulai Inventor before: Lv Fei Inventor before: Zhang Jianyou |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: DING YUTING WANG WENBIAO ZHAO PEICHENG LIU SHULAI LV FEI ZHANG JIANYOU TO:DING YUTING LV FEI LIU JIANHUA WANG WENBIAO ZHAO PEICHENG FENG CHAOHUI LUO GUOLIANG |
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Application publication date: 20100421 Assignee: HAOFENG (QINGDAO) FOOD CO.,LTD. Assignor: Zhejiang University of Technology Contract record no.: 2014990000371 Denomination of invention: Method for eliminating pesticide residues on vegetables and fruits Granted publication date: 20130424 License type: Exclusive License Record date: 20140604 |
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