CN101693819A - Polypropylene wire-beam forming water-based emulsion bond for cigarettes and production method thereof - Google Patents
Polypropylene wire-beam forming water-based emulsion bond for cigarettes and production method thereof Download PDFInfo
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- CN101693819A CN101693819A CN200910044251A CN200910044251A CN101693819A CN 101693819 A CN101693819 A CN 101693819A CN 200910044251 A CN200910044251 A CN 200910044251A CN 200910044251 A CN200910044251 A CN 200910044251A CN 101693819 A CN101693819 A CN 101693819A
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Abstract
The invention relates to a polypropylene wire-beam forming water-based emulsion bond for cigarettes and a production method thereof. The polypropylene wire-beam forming water-based emulsion bond is prepared by uniformly mixing a main emulsion, a tackification emulsion, an emulsion humectant, an emulsion deformer, an emulsion film-forming additive and a sorbent for smoke of cigarettes, wherein vinyl acetate homopolymerisation emulsion, vinyl propionate homopolymerisation emulsion, crylic acid copolymerization emulsion, vinyl acetate-acrylic ester copolymerization emulsion, cinnamene-acrylic ester copolymerization emulsion, vinyl acetate-vinyl versatate copolymerization emulsion and vinyl acetate-ethylene copolymerization emulsion are mixed to prepare the main emulsion; the tackification emulsion comprises hydrogenated rosin glycerol ester emulsion and rosin glycerol ester emulsion; the emulsion humectant comprises propylene glycol, glycerine, diglycol and tirethylene glycol; the emulsion film-forming additive comprises 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate; and the sorbent for smoke of cigarettes comprises one or two of extractives FA02, FM801 of Angel yeast. The bond does not contain a volatile, flammable and combustible organic solvent, and a formed water-based polypropylene filter tip stick is firmly bonded and has pure and mild mouthfeel of the smoke taste.
Description
Technical field
The present invention relates to the cigarette raw and auxiliary material, promptly a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes and production method thereof.
Background technology
The cigarette polypropylene fiber tow forming adhesive is to be external phase with the solvent oil all the time, dissolving elastic resin such as styrene-butadiene-styrene block resin (SBS), matrix resin such as petroleum resin, terpine resin, the hydrogenated wood rosin glycerol ester resin, softening agent such as whiteruss, dibutyl phthalate etc. are made Solvent Adhesive.This type of tackiness agent belongs to non-polar material, the filter tip stick of its bonding cigarette polypropylene fiber tow moulding, and it is insecure to bond, and mouth is stung easy snuff; The tipping cigarette is difficult for cutting, Workflow's powder when propping up, glues cutter, and it is low that cigarette props up the tipping rate; Cigarette after the tipping props up, and inhaling flavor has pungency sharp flavor, and filter tip stick tar adsorption ability can't guarantee that the smoker's is healthy; And because the inflammable and explosive and easy volatile of solvent oil, there is serious fire safety evaluating hidden danger in solvent cement in production, storage, transportation, use, unfriendly to environment.
Summary of the invention
The object of the present invention is to provide a kind of safety, environmental protection, bonding cigarette polypropylene fiber tow firm, filter tip stick is easy to be hinged with cigarette and props up, can improve cigarette odor-absorbing, strengthens the adsorption function of filter tip stick to harmful ingredients in flue gas, alleviates a kind of cigarette polypropylene fiber tow moulding use emulsion binding agent and the production method thereof of smoking to the harm of smoker's health.
This polypropylene wire-beam forming water-based emulsion bond for cigarettes is characterized in that, by following component by weight proportion uniform mixing constitute:
A. by vinyl acetate homopolymerization emulsion, be called for short the equal emulsion of vinegar, vinyl propionate homopolymerization emulsion, be called for short the third equal emulsion, acrylate copolymer emulsion, be called for short pure-acrylic emulsion, vinyl acetate-acrylate copolymer emulsion, be called for short vinyl acetate emulsion, interpolymer latex of polystyrene and acrylic ester, be called for short benzene emulsion, vinyl acetate-tertiary ethylene carbonate copolymer emulsion, be called for short vinegar uncle emulsion, vinyl acetate-ethylene copolymerization emulsions, main body emulsion, weight part 60-90 are formed in one or several mixing that are called for short in the EVA emulsion;
B. form Tackified emulsion, weight part 5-30 by a kind of in hydrogenated rosin glyceride emulsion, the ester gum emulsion or two kinds;
C. form the emulsion wetting Agent for Printing Inks, weight part 1-6 by in propylene glycol, glycerol, a condensed ethandiol, the tirethylene glycol one or several;
D. emulsion defoamer, weight part 0.0025;
Emulsion defoamer can be made up of a kind of in the X-4050 froth breaking king of the upright strange auxiliary chemicals in Shanghai company limited, the LT-201 water-borne coatings dedicated defoamer or two kinds.
E, by 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate form the emulsion film forming auxiliary agent, weight part 0.5-4;
F, form the sorbent material of cigarette smoke, weight part 0.5～2 by yeast extract.
Flue gas adsorbent is a kind of or two kinds of compositions among Angel Yeast extract FA02, the FM801.
Its production method may further comprise the steps, and following each raw material is a weight ratio:
1. one or several in the equal emulsion of 60-90 part vinegar, the third equal emulsion, pure-acrylic emulsion, vinyl acetate emulsion, benzene emulsion, vinegar uncle emulsion, VAE emulsion mix in the main body emulsion of forming, under at the uniform velocity stirring, slowly add 5-30 part by a kind of or two kinds of Tackified emulsions formed in hydrogenated rosin glyceride emulsion, the ester gum emulsion;
2. 1-6 part is formed the emulsion wetting Agent for Printing Inks by in propylene glycol, glycerol, a condensed ethandiol, the tirethylene glycol one or several, 0.5-4 part by 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate form the emulsion film forming auxiliary agent, 0.0025 part emulsion defoamer, under agitation slowly add in the emulsion respectively, and emulsion is stirred;
3. with 0.5～2 part of cigarette smoke sorbent material of forming by yeast extract, after stirring with 90 ℃-95 ℃ suitable quantity of water, slowly add in the above-mentioned emulsion that is stirring;
4. after continuing to stir, stop to stir, emulsion filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
By the polypropylene wire-beam forming water-based emulsion bond for cigarettes that above component constitutes, water is external phase, the inflammable and explosive organic solvent of non-volatility, and no inflammable and explosive potential safety hazard, and also environmentally friendly; Water-based acrylic fiber filter tip after the moulding is through behind the baking-curing, and bonding is firm, hardness is good; When propping up, be easy to cutting, do not fly powder with its tipping cigarette; The cigarette that the cigarette of its tipping props up solvent cement acrylic fiber filter tip tipping on year-on-year basis props up, and the absorption taste port sense is pure and mild, nonirritant sharp flavor; Every cigarette can reduce about 0.5 milligram to 1.5 milligrams of tar contents, has reduced the smoking harm healthy to the smoker.
Embodiment
Embodiment 1:
1. in 2 liters enamelled vessel, add the mixture of 700 gram benzene emulsions and 50 gram VAE emulsions, the normal temperature constant speed stirs down, slowly adds 150 gram hydrogenated rosin glyceride emulsions.
2. in 200 milliliters glass cylinder, take by weighing 45 gram propylene glycol respectively, 5 grams 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, the X-4050 froth breaking king of 0.025 gram Shanghai upright strange auxiliary chemicals company limited, after preliminary the mixing, slowly splash in the above-mentioned water-based emulsion that is stirring.
3. take by weighing 10 gram Angel Yeast extract FA02 and 40 gram distilled water, be heated to 90 ℃-95 ℃, behind the back that stirs, add in the above-mentioned water-based emulsion that is stirring.
4. continue to stir 30 minutes, and stopped to stir, emulsion is filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
With the water-based acrylic fiber filter tip of the forming water-based tackiness agent moulding of this cigarette polypropylene fiber tow, tipping is after cigarette props up, solvent cement acrylic fiber filter tip on year-on-year basis, and every cigarette can reduce about 1.0 milligrams of tar contents.
Embodiment 2:
1. in 2 liters enamelled vessel, add the mixture of 800 gram benzene emulsions and 100 gram VAE emulsions, the normal temperature constant speed stirs down, slowly adds 50 gram hydrogenated rosin glyceride emulsions.
2. in 200 milliliters glass cylinder, take by weighing 10 gram propylene glycol respectively, 5 grams 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, the X-4050 froth breaking king of 0.025 gram Shanghai upright strange auxiliary chemicals company limited, after preliminary the mixing, slowly splash in the above-mentioned water-based emulsion that is stirring.
3. take by weighing 5 gram Angel Yeast extract FA02 and 30 gram distilled water, be heated to 90 ℃-95 ℃, after stirring, add in the above-mentioned water-based emulsion that is stirring.
4. continue to stir 30 minutes, and stopped to stir, emulsion is filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
With the water-based acrylic fiber filter tip of the forming water-based tackiness agent moulding of this cigarette polypropylene fiber tow, tipping is after cigarette props up, solvent cement acrylic fiber filter tip on year-on-year basis, and every cigarette can reduce about 0.5 milligram of tar content.
Embodiment 3:
1. in 2 liters enamelled vessel, add the mixture of 500 gram benzene emulsions and the equal emulsion of 50 gram vinegar, 50 gram vinegar uncle emulsions, under the stirring at normal temperature, slowly add 250 gram hydrogenated rosin glyceride emulsions and 50 gram ester gum emulsions.
2. in 200 milliliters glass cylinder, take by weighing 15 gram propylene glycol respectively, 5 gram glycerol, 5 grams 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, 0.025 the LT-201 water-borne coatings dedicated defoamer of gram Shanghai upright strange auxiliary chemicals company limited, after preliminary the mixing, slowly splash in the above-mentioned water-based emulsion that is stirring.
3. take by weighing Angel Yeast extract 10 gram FA02,10 gram FM801 and 65 gram distilled water, be heated to 90 ℃-95 ℃, after stirring, add in the above-mentioned water-based emulsion that is stirring.
4. continue to stir 30 minutes, and stopped to stir, emulsion is filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
With the water-based acrylic fiber filter tip of this polypropylene wire-beam forming water-based emulsion bond for cigarettes moulding, tipping is after cigarette props up, solvent cement acrylic fiber filter tip on year-on-year basis, and every cigarette can reduce about 1.0 milligrams of tar contents.
Embodiment 4:
1. in 2 liters enamelled vessel, add 500 gram benzene emulsions, the mixture of 100 grams, the third equal emulsion, 50 gram pure-acrylic emulsions, 50 gram vinyl acetate emulsions under the stirring at normal temperature, slowly adds 120 gram hydrogenated rosin glyceride emulsions.
2. in 200 milliliters glass cylinder, take by weighing 40 gram propylene glycol respectively, 5 gram glycerol, 3 grams, one condensed ethandiol, 2 gram tirethylene glycols, 10 grams 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, 0.015 the LT-201 water-borne coatings dedicated defoamer of gram Shanghai upright strange auxiliary chemicals company limited and 0.010 gram X-4050 froth breaking king, after preliminary the mixing, slowly splash in the above-mentioned water-based emulsion that is stirring.
3. take by weighing Angel Yeast extract 20 gram FA02 and 100 gram distilled water, be heated to 90 ℃-95 ℃, after stirring, add in the above-mentioned water-based emulsion that is stirring.
4. continue to stir 30 minutes, and stopped to stir, emulsion is filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
With the water-based acrylic fiber filter tip of the forming water-based tackiness agent moulding of this cigarette polypropylene fiber tow, tipping is after cigarette props up, solvent cement acrylic fiber filter tip on year-on-year basis, and every cigarette can reduce about 1.5 milligrams of tar contents.
Embodiment 5:
1. in 2 liters enamelled vessel, add 700 gram benzene emulsions, under the stirring at normal temperature, slowly add 110 gram hydrogenated rosin glyceride emulsions.
2. in 200 milliliters glass cylinder, take by weighing 30 gram propylene glycol respectively, 40 grams 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, the X-4050 froth breaking king of 0.025 gram Shanghai upright strange auxiliary chemicals company limited, after preliminary the mixing, slowly splash in the above-mentioned water-based emulsion that is stirring.
3. take by weighing Angel Yeast extract 20 gram FA02 and 100 gram distilled water, be heated to 90 ℃-95 ℃, after stirring, add in the above-mentioned water-based emulsion that is stirring.
4. continue to stir 30 minutes, and stopped to stir, emulsion is filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
With the water-based acrylic fiber filter tip of the forming water-based tackiness agent moulding of this cigarette polypropylene fiber tow, tipping is after cigarette props up, solvent cement propene fibre filter stick on year-on-year basis, and every cigarette can reduce about 1.5 milligrams of tar contents.
Embodiment 6:
1. in 2 liters enamelled vessel, add 600 gram benzene emulsions, under the stirring at normal temperature, slowly add 180 gram hydrogenated rosin glyceride emulsions.
2. in 200 milliliters glass cylinder, take by weighing 60 gram propylene glycol respectively, 10 grams 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, the X-4050 froth breaking king of 0.025 gram Shanghai upright strange auxiliary chemicals company limited, after preliminary the mixing, slowly splash in the above-mentioned water-based emulsion that is stirring.
3. take by weighing Angel Yeast extract 20 gram FM801 and 130 gram distilled water, be heated to 90 ℃-95 ℃, after stirring, add in the above-mentioned water-based emulsion that is stirring.
4. continue to stir 30 minutes, and stopped to stir, emulsion is filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
With the water-based acrylic fiber filter tip of the forming water-based tackiness agent moulding of this cigarette polypropylene fiber tow, tipping is after cigarette props up, solvent cement propene fibre filter stick on year-on-year basis, and every cigarette can reduce about 1.3 milligrams of tar contents.
Claims (4)
1. a polypropylene wire-beam forming water-based emulsion bond for cigarettes is characterized in that, by following component by weight proportion uniform mixing constitute:
A. by vinyl acetate homopolymerization emulsion, be called for short the equal emulsion of vinegar, vinyl propionate homopolymerization emulsion, be called for short the third equal emulsion, acrylate copolymer emulsion, be called for short pure-acrylic emulsion, vinyl acetate-acrylate copolymer emulsion, be called for short vinyl acetate emulsion, interpolymer latex of polystyrene and acrylic ester, be called for short benzene emulsion, vinyl acetate-tertiary ethylene carbonate copolymer emulsion, be called for short vinegar uncle emulsion, vinyl acetate-ethylene copolymerization emulsions, main body emulsion, weight part 60-90 are formed in one or several mixing that are called for short in the EVA emulsion;
B. form Tackified emulsion, weight part 5-30 by a kind of in hydrogenated rosin glyceride emulsion, the ester gum emulsion or two kinds;
C. form the emulsion wetting Agent for Printing Inks, weight part 1-6 by in propylene glycol, glycerol, a condensed ethandiol, the tirethylene glycol one or several;
D. emulsion defoamer, weight part 0.0025;
E, by 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate form the emulsion film forming auxiliary agent, weight part 0.5-4;
F, form the cigarette smoke sorbent material by yeast extract, weight part 0.5～2.
2. a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes according to claim 1, it is characterized in that emulsion defoamer is made up of a kind of in the X-4050 froth breaking king of the upright strange auxiliary chemicals in Shanghai company limited, the LT-201 water-borne coatings dedicated defoamer or two kinds
3. a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes according to claim 1 is characterized in that, flue gas adsorbent is made up of a kind of among Angel Yeast extract FA02, the FM801 or two kinds.
4. the production method of a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes according to claim 1 is characterized in that, its production method may further comprise the steps, and following each raw material is a weight ratio:
1. one or several in the equal emulsion of 60-90 part vinegar, the third equal emulsion, pure-acrylic emulsion, vinyl acetate emulsion, benzene emulsion, vinegar uncle emulsion, VAE emulsion mix in the main body emulsion of forming, under at the uniform velocity stirring, slowly add 5-30 part by a kind of or two kinds of Tackified emulsions formed in hydrogenated rosin glyceride emulsion, the ester gum emulsion;
2. 1-6 part is formed the emulsion wetting Agent for Printing Inks by in propylene glycol, glycerol, a condensed ethandiol, the tirethylene glycol one or several, 0.5-4 part by 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate form the emulsion film forming auxiliary agent, 0.0025 part emulsion defoamer, under agitation slowly add in the emulsion respectively, and emulsion is stirred;
3. with 0.5～2 part of cigarette smoke sorbent material of forming by yeast extract, after stirring with 90 ℃-95 ℃ suitable quantity of water, slowly add in the above-mentioned emulsion that is stirring;
4. after continuing to stir, stop to stir, emulsion filtered with 150 purpose nylon leaching nets, a kind of polypropylene wire-beam forming water-based emulsion bond for cigarettes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100442519A CN101693819B (en) | 2009-09-01 | 2009-09-01 | Polypropylene wire-beam forming water-based emulsion bond for cigarettes and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100442519A CN101693819B (en) | 2009-09-01 | 2009-09-01 | Polypropylene wire-beam forming water-based emulsion bond for cigarettes and production method thereof |
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| Publication Number | Publication Date |
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| CN101693819A true CN101693819A (en) | 2010-04-14 |
| CN101693819B CN101693819B (en) | 2011-04-20 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103720046A (en) * | 2014-01-15 | 2014-04-16 | 湖北金叶玉阳化纤有限公司 | Tobacco filter tip stick of sugar alcohol sweetening agent and production process thereof |
| CN105852195A (en) * | 2015-01-22 | 2016-08-17 | 于杰 | Functional tobacco shreds |
| CN106332891A (en) * | 2016-08-26 | 2017-01-18 | 安徽久易农业股份有限公司 | Weed killer containing fluthiacet-methyl and pendimethalin |
| CN109456717A (en) * | 2018-09-29 | 2019-03-12 | 漳州市天辰纸品包装有限公司 | A kind of environment-protecting and non-poisonous food packaging corrugated board |
-
2009
- 2009-09-01 CN CN2009100442519A patent/CN101693819B/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103720046A (en) * | 2014-01-15 | 2014-04-16 | 湖北金叶玉阳化纤有限公司 | Tobacco filter tip stick of sugar alcohol sweetening agent and production process thereof |
| CN103720046B (en) * | 2014-01-15 | 2015-04-08 | 湖北金叶玉阳化纤有限公司 | Tobacco filter tip stick of sugar alcohol sweetening agent and production process thereof |
| CN105852195A (en) * | 2015-01-22 | 2016-08-17 | 于杰 | Functional tobacco shreds |
| CN106332891A (en) * | 2016-08-26 | 2017-01-18 | 安徽久易农业股份有限公司 | Weed killer containing fluthiacet-methyl and pendimethalin |
| CN109456717A (en) * | 2018-09-29 | 2019-03-12 | 漳州市天辰纸品包装有限公司 | A kind of environment-protecting and non-poisonous food packaging corrugated board |
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| Publication number | Publication date |
|---|---|
| CN101693819B (en) | 2011-04-20 |
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