CN101684017B - Water-quality activating ball special for health preserving cups and preparation method thereof - Google Patents

Water-quality activating ball special for health preserving cups and preparation method thereof Download PDF

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Publication number
CN101684017B
CN101684017B CN2008102230426A CN200810223042A CN101684017B CN 101684017 B CN101684017 B CN 101684017B CN 2008102230426 A CN2008102230426 A CN 2008102230426A CN 200810223042 A CN200810223042 A CN 200810223042A CN 101684017 B CN101684017 B CN 101684017B
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China
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water
health preserving
activating ball
ball special
quality activating
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CN101684017A (en
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卢子标
李敬
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Li Jing
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Abstract

The invention relates to a water-quality activating ball special for health preserving cups and a preparation method thereof. The water-quality activating ball special for health preserving cups is sintered by 45% of Brazilian tourmaline, 5% of mordenite, 25% of Chinese medical stone, 5% of selenolite, 5% of germanite, 5% of Muyu stone and 10% of adhesive together, wherein the Brazilian tourmaline, the mordenite, the Chinese medical stone, the selenolite and the germanite are respectively pulverized to more than 6000 meshes, and the Muyu stone and the adhesive are pulverized to more than 2000 meshes. The water-quality activating ball special for health preserving cups has the advantages of favorable activity, high mineralized degree and long service life; and the water activated by the water-quality activating ball special for health preserving cups can reach the standard of high-quality drinking water, and is easy for human bodies to absorb and beneficial for human health.

Description

Water-quality activating ball special for health preserving cups and preparation method thereof
Technical field
The present invention relates to a kind of interior activated material of preserving cup and preparation method thereof that is exclusively used in, be specifically related to a kind of water-quality activating ball special for health preserving cups and preparation method thereof with purification and mineralized water function.
Background technology
Water is lifespring, and the people is only second to oxygen to the needs of water, and modern medicine finds that people's slight illness 80% is relevant with water, 30% death be because of water extremely.The investigation of the World Health Organization shows: the whole world has 20% people to suffer from various diseases because of drinking the water that is polluted every year at present; 50% cancer is with to drink unclean water relevant; 50% death of child causes owing to tap water is contaminated; The whole world surpasses 5,000,000 because of the number that water pollutes the cholera, dysentery and the malaria that cause.Another investigation of this tissue also shows: the tap water of the people in the countryside of developing country 75%, 1/3 urban population does not reach the safety and Health standard.In China, there is 79% population drinking water deleterious, that polluted, wherein there are 700,000,000 people drinking approximately and have the colibacillary water that exceeds standard, 300,000,000 people are drinking contains the iron amount water that exceeds standard, 1.1 hundred million people are drinking high hardness water, 7,000 ten thousand people are drinking water of high fluorine content, and 5,000 ten thousand people are drinking high nitric acid salt solution.With regard to China, there are 532 rivers in the whole nation, and wherein 82% is polluted, do not polluted often exclusion areas such as Xinjiang, Tibet.
Can which type of water is drunk be more relieved, more healthy? the World Health Organization (WTO) is according to analyzing the long-lived geographic a large amount of investigation results in the world, and 6 standards that propose drink water are:
1. do not pollute, do not contain pathogenic bacterium, heavy metal and harmful chemical;
2. the natural mineral matter and the trace element that contain needed by human body;
3. pH value is weakly alkaline, pH value between 7.2-8.5;
4. small-micelle water is advisable with 5-6;
5. have negative potential, can remove unnecessary free radical in the body;
6. contain an amount of oxygen.
And at present generally adopt water factory to handle for processing China of tap water, and central water supply, the way among water supply pipe is transported to resident family is supplied with tap water again.Yet the contaminated water source that industrial development causes is on the rise, and is subjected to the restriction of technology, technology, economic dispatch condition, and the waterworks is powerless to some pollution.Tap water uses a certain amount of chlorinated product (chlorinated lime) in sterilizing process, caused the residual of chlorine in the water, and with water in the organism reaction generate trichloromethane.Existing known, trichloromethane is a carcinogenic substance main in the tap water, under the cold water state, the trichloromethane many places are in specialized range, but tap water is the hurried rising of the content of trichloromethane after heating, and especially content is the highest in the time of 95 ℃ to 100 ℃, boils residual minimizing more than five minutes.Except chemical pollution, Corrosion of Pipeline, solubilize calcium not in the water, the water storage tanks of organism and Highrise buildings etc. are also relatively more serious to the secondary pollution of tap water.
In order to obtain the fine tap water, various water-purifying machines, water filter and preserving cup are arisen at the historic moment.But the pH values that adopt the functional materials of grinding particle size between the 200-350 order to come the key water saving in the existing preserving cup more, these functional materialss chance water are instant, chance water is promptly changed, if soak when long (was the boundary with one hour), water that forms or pH value can exceed standard and become alkaline water or strong alkaline water, the negative potential that perhaps forms water reaches-and more than the 250mv, it is very harmful to health often to drink this water.Along with the increase of cup access times, its function also can progressively reduce simultaneously, and the usage period is about 3 months only, and the life-span is shorter.And do not reach at all and make water form the function and the effect of small moleculesization.How to obtain pollution-free, to be rich in that several mineral materials and pH value, small-micelle water, negative potential stablize, meet the drink water standard, make the drink water of the health that people can relievedly drink be present industry problem demanding prompt solution.
Summary of the invention
The objective of the invention is provides a kind of water-quality activating ball special for health preserving cups and preparation method thereof at deficiency of the prior art, and the tap water after this activating ball is handled can reach the standard of drink water.
For reaching above-mentioned purpose, the present invention has adopted following technical scheme:
A kind of water-quality activating ball special for health preserving cups, it is fired by following material and forms, and the weight percent of each component is:
Brazil's tourmaline: 45%;
Mordenite: 5%;
Maifanitum: 25%;
Selenium stone: 5%;
Germanite: 5%;
MUSYUSHI: 5%;
Binding agent: 10%;
It is more than 6000 orders that wherein Brazilian tourmaline, mordenite, Maifanitum, selenium stone and germanite are all pulverized, and it is more than 2000 orders that MUSYUSHI and binding agent are pulverized.
Wherein said binding agent is a kaolin.
A kind of preparation method of above-mentioned water-quality activating ball special for health preserving cups comprises the steps:
(1) selection of ore and dedusting:
Select fine Brazil tourmaline, mordenite, Maifanitum, selenium stone, germanite and MUSYUSHI, wash dedusting, then natural air drying or dry in the mode of blower dedusting, tap water flushing;
(2) pulverize
Respectively with Brazilian tourmaline, mordenite, Maifanitum, selenium stone, germanite and MUSYUSHI, cover pulverizer with thunder earlier and tentatively be crushed to 100-200 purpose particle, particle is moved in the air flow super machine then, under the cold gas airflow strikes, respectively Brazilian tourmaline, mordenite, Maifanitum, selenium stone and germanite are ground into 6000 purpose powder, MUSYUSHI is ground into 200 purpose powder;
(3) mixing moulding
After above-mentioned mineral dust after pulverizing taken by weighing uniform mixing respectively according to the weight percent of Brazilian tourmaline 45%, mordenite 5%, Maifanitum 25%, selenium stone 5%, germanite 5%, MUSYUSHI 5%, again with the mineral dust that mixes be crushed to 2000 purpose binding agents and mix, put into the moulding of intelligent mode nodulizer, the diameter of ball is controlled between the 1mm-20mm;
(4) sintering
After ball after the moulding dried, put into intelligent electric dual-purpose shuttle kiln sintering, sintering temperature is the 600-1200 degree, and the time is 5 hours, and naturally cooling dries gained and is water-quality activating ball special for health preserving cups behind the sintering.
During use, water-quality activating ball special for health preserving cups can be pressed the capacity packaging of cup, consumption is 300 milliliters cup configuration 30 gram water-quality activating balls usually, the water-quality activating ball of 400 milliliters cup configuration 40 grams, and the rest may be inferred.Water-quality activating ball can be encapsulated in the spheroid of two-sided punching, as the filter core punching press or be installed in water tumbler the cup end.
The proterties and the function of the used ore of the present invention are as follows:
Mordenite: chemical formula is: Na2Ca[AlSi5012] 412H20.Be a kind of aqueous alkali or alkaline earth metal aluminosilicate mineral, it is fibrous, hair-like that rhombic system, crystal are, and aggregate is pencil, granospherite shape hinge shape.Be in " open system ", to form with lake water infiltration underground water or the hydrothermal reaction in volcanicity later stage by landing or the volcanic glass in basin, freshwater lake or land volcanic ash, ash flow and slag of spraying and spoiling over, has unique internal structure and crystal chemistry character, and natural mystery effect, as: have physical property characteristics such as electrostatic adhesion power, extremely strong absorption property, catalytic performance, cation exchange property, stronger thermostability and acid resistance, also having far infrared performance etc. simultaneously, is molecular sieve ideal in a kind of drinking water treatment.
Maifanitum: likeness in form spot shape, yellow or white, quite like wheat.Form by greyish white, ground rice, several colors such as dark brown.Matter is heavy, and is harder, is difficult for smashing.The fragment fracture is coarse, but also smooth, and the bright star point is arranged, and section has colorful alternate decorative pattern, and texture is thicker.Streak is a beige, the visible light flash point, and gas is little, and is lightly seasoned.Discuss in the Chinese classics " Bencao Tujing ": Maifanitum has significant pharmacological action: cancer-resisting, enhance immunity function, antifatigue, hypoxia tolerance, control alcoholic liver damage, promote bone mineralization, shorten healing time, anti-fluorine, to the adsorption of bacterium.Through Shenyang geological sciences institute, medicine stone study group of Shenyang geological and mineral institute the mineralogical study result of Maifanitum is shown: it contains the 59 kinds of elements of having an appointment, and comprises 18 kinds of mineral substance and trace elements that human nutrition is required.People's long-term drinking medical stone mineral water can replenish needed by human body mineral substance and various trace elements, for organism provides the inorganic nutrients composition.Medical stone has certain adsorption simultaneously, and through repeatedly experiment showed, medical stone to some virus and harmful microorganism and heavy metal element, organic substance has certain detergent power.
Brazil's tourmaline: with the boracic aluminium, iron, sodium, the magnesium of feature, the ring texture silicate minerals of lithium, trigonal system, multiple trigonal pyramidal class.Crystal is column, crystal two ends crystal face difference, and longitudinal grin often appears in cylinder, and the transverse section is spherical triangle, no cleavage, high rigidity.Bar-shaped, radial, bundle needle-like that aggregate is also becomes compact mass or cryptocrystal block.Main component has more than 10 kind of trace elements favourable to human body such as magnesium, aluminium, iron, boron, is that mankind nowadays is suitable for human survival most and the important natural life source of the procreation of living in history.
Selenium stone: a kind of non-metallic ore, crystalline structure and form are rhombic system, the transverse section is longitudinal grin.Selenium is requisite trace element in the humans and animals vital movement.Chinese Soclety of Nutrition classifies selenium as one of the dietary nutrients that must take in 15 kinds of every days, suggestion additional 50 microgram to 200 micrograms every day.
Germanite: a kind of non-metallic ore, crystalline structure and form are rhombic system, the transverse section presents longitudinal grin.Has the far infrared irradiation about wavelength 10 μ m.Standard far infrared rays wavelength to the human body beneficial is 8-12 μ m, and germanium is just radiating the far infrared rays that is near the mark most.Life-time service can increase the cell quantity of human body, and blood viscosity is descended, and not only has effect anticancer and increase immunizing power, and also to respiratory system, diseases such as skin have tangible assisting therapy effect.In addition, germanite contains the mineral substance of silicon (Si) oxygen (O) sodium (Na) potassium (K) magnesium (Mg) iron (Fe) aluminium multiple needed by human body such as (Al), therefore to preventing that adult diseasess such as hypertension, diabetes, cycle penalty, neurological disorder from having very big effect.
MUSYUSHI: be the red sandalwood look, wood grain is arranged, belong to the marine facies precipitation, claim it in the Compendium of Material Medica: sweet flat nontoxic, cough with dyspnea, podomere is unfavorable, and eliminating pathogenic factor for supporting vital QI holds essence and consolidates, beneficial spleen, peace visceral-qi is decided six internal organs, and word is called " Taiyi surplus ".Technical evaluation through brainstrusts such as Country Geological Experimental Testing Center and China Preventive Medicial Science Institute, MUSYUSHI contains multiple human body trace elements necessary and mineral substance, soak through tap water, distilled water, boiled water, can separate out multiple elements such as calcium, strontium, zinc, manganese, magnesium, cobalt, phosphorus, selenium, iron, brill, the gill, metasilicic acid.
Owing to adopted above-mentioned technique means, made the present invention have following technique effect:
(1) activation: the raw material that the present invention adopts is a fine natural energy ore, and through after the 6000 order ultra-fine grindings, its activity obtains modification, and mineral structure generation radical change makes it have stronger vitality, can discharge a large amount of negative electrode negative ions; Its energising property, piezoelectricity, and the performance of frictional electricity all very remarkable; Also have stronger reductive action simultaneously, can suppress the corruption of food, the de-odorised effect is six times of gac; Can be well away from infrared rays and enhance metabolism, thereby make the water that loses function of degenerating return to order state, realize activation to water;
(2) purify: activating ball of the present invention adopts normal temperature to pulverize, the quality and the function that have effectively kept ore itself, thereby the function that makes it have kill bacteria, eliminate virus, purify water, after testing, 30 gram preserving cup water-quality activating balls are soaked one hour in normal temperature 300mL water after, its toxicologic index: arsenic (As) is determined as 0.0008mg/L (country limit the quantity of 0.05mg/L), plumbous (Pb) is determined as 0.0008mg/L (country limit the quantity of 0.05mg/L), and mercury (Hg) is determined as 0.0001mg/L (country limit the quantity of 0.05mg/L);
(3) mineralising: detect through Laboratory Accreditation unit of the authorized by state council-Beijing Pu Ni test center, 30 gram preserving cup water-quality activating balls are soaked one hour in normal temperature 300mL municipal tap water after, its index determining result is: potassium (K) 1.66mg/L, sodium (N) 109mg/L, calcium (Ca) 20.2mg/L, magnesium (Mg) 10.5mg/L, iron (Fe) 0.0080mg/L, lithium (Li) 0.002mg/L, strontium (Si) 0.36mg/L, total hardness 95.0mg/L, dissolved oxygen 5.84mg/L,, metasilicic acid 17.5mg/L;
(4) weak baseization: the water ph value after the modification of preserving cup water-quality activating ball can remain on 7.2-8.5, is weakly alkaline, meets human body requirements comprehensively, can effectively promote human body metabolism, improve autoimmunity.Detect through Laboratory Accreditation unit of the authorized by state council-Beijing Pu Ni test center, the preserving cup water-quality activating ball soaked in the pure water of normal temperature 300mL after one hour, and the script pH value is that 6.3 pure water pH value changes to 8.1; In 1-4 days, the pH value of water all can remain between the 7.2-8.5 relatively.
(5) anti-oxidant: water-quality activating ball special for health preserving cups has negative potential, can improve the redox ability of water, after tested, can make water ORP index (negative potential) after its activation remain on-50--200mV, thereby effectively eliminate interior free yl, play oxidation resistant effect;
(6) small moleculesization: detect through Laboratory Accreditation unit of the authorized by state council-national drug and meta-bolites analysis and research center, water after the water-quality activating ball special for health preserving cups activation, its 017-NMP spectrum peak width is 52Hz (common municipal tap water 017-NMP spectrum peak width is 138Hz), is made up of 5-8 water molecules;
(7) to adopt the high-quality ore be raw material in the present invention, adopts kaolin as binding agent, and long service life generally can be used about 2 years;
In sum, adopt the water-quality activating ball special for health preserving cups of above-mentioned raw materials and preparation method preparation, activity is good, salinity is high, long service life, and the water after its activation can reach the standard of drink water, easier being absorbed by the body, useful HUMAN HEALTH.
Embodiment
Used machine is the commercially available prod among the present invention, and wherein pulverizer adopts the 3R1410 type raymond mill that Zhengzhou heavy equipment limited-liability company produces; The air flow super machine adopts Qing Daohai to receive the multi-functional ultra-fine oscillating mill that micro mist Engineering Co., Ltd produces; Mixer adopts common commercially available mixer; Shaper adopts the intelligent mode nodulizer; Adopt intelligent electric dual-purpose shuttle kiln during sintering.
Embodiment 1:
A kind of water-quality activating ball special for health preserving cups, it is fired by following material and forms, and the weight percent of each component is:
Brazil's tourmaline: 45%;
Mordenite: 5%;
Maifanitum: 25%;
Selenium stone: 5%;
Germanite: 5%;
MUSYUSHI: 5%;
Kaolin: 10%;
It is more than 6000 orders that wherein Brazilian tourmaline, mordenite, Maifanitum, selenium stone and germanite are all pulverized, and it is that kaolin is as binding agent more than 2000 orders that MUSYUSHI and kaolin are pulverized.
The preparation method of above-mentioned water-quality activating ball special for health preserving cups is:
(1) selection of ore and dedusting:
Select fine Brazil tourmaline, mordenite, Maifanitum, selenium stone, germanite and MUSYUSHI, wash dedusting, then natural air drying or dry in the mode of blower dedusting, tap water flushing;
(2) pulverize
Respectively with Brazilian tourmaline, mordenite, Maifanitum, selenium stone, germanite and MUSYUSHI, cover pulverizer with thunder earlier and tentatively be crushed to 100-200 purpose particle, particle is moved in the air flow super machine then, under the cold gas airflow strikes, respectively Brazilian tourmaline, mordenite, Maifanitum, selenium stone and germanite are ground into 6000 purpose powder, MUSYUSHI is ground into 200 purpose powder.After testing, the degree of planting of powder throws under Electronic Speculum, the X-ray diffraction, epigranular, and chemical quality is constant;
(3) mixing moulding
After above-mentioned mineral dust after pulverizing taken by weighing uniform mixing respectively according to the weight percent of Brazilian tourmaline 45%, mordenite 5%, Maifanitum 25%, selenium stone 5%, germanite 5%, MUSYUSHI 5%, again with the mineral dust that mixes be crushed to 2000 purpose kaolin and mix, put into the moulding of intelligent mode nodulizer, the diameter of ball is controlled between the 1mm-20mm;
(4) sintering
After ball after the moulding dried, put into intelligent electric dual-purpose shuttle kiln sintering, sintering temperature is the 600-1200 degree, and the time is 5 hours, and naturally cooling dries gained and is water-quality activating ball special for health preserving cups behind the sintering.
During use, water-quality activating ball can be encapsulated by weight, be configured with the capacity of cup, general consumption is: 300 milliliters cup is equipped with 30 gram water-mineralizing balls; 400 milliliters cup is equipped with 40 gram water-mineralizing balls; The rest may be inferred.
30 gram water-quality activating ball special for health preserving cups are positioned in 300 milliliters of pure water, detect to such an extent that mineral trace element increases kind more than 20 after 10 minutes.Mainly contain: potassium 1.66mg/L, sodium 109mg/L, calcium 20.2mg/L, magnesium 10.5mg/L, iron 0.0080mg/L, lithium 0.002mg/L, strontium 0.36mg/L, total hardness 95mg/L, dissolved oxygen 5.84mg/L metasilicic acid 17.5mg/L.30 gram water-quality activating ball special for health preserving cups are positioned in 300 milliliters of municipal tap water, and after 10 minutes, performance is compared as follows shown in the table:
Project PH Small molecules Negative potential Dissolved oxygen
The municipal tap water 6.5 017-NMP spectrum peak width 138Hz, i.e. 13 water moleculess +230mv 3-4mg/L
After the mineralization ball processing 8.1 Below the 017-NMP spectrum peak width 80Hz, promptly 8 below the water molecules -80mv 5-9mg/L

Claims (2)

1. water-quality activating ball special for health preserving cups, it is characterized in that: it is fired by following material and forms, and the weight percent of each component is:
Brazil's tourmaline: 45%;
Mordenite: 5%;
Maifanitum: 25%;
Selenium stone: 5%;
Germanite: 5%;
MUSYUSHI: 5%;
Binding agent: 10%;
It is more than 6000 orders that wherein Brazilian tourmaline, mordenite, Maifanitum, selenium stone and germanite are all pulverized, and it is more than 2000 orders that MUSYUSHI and binding agent are pulverized.
2. water-quality activating ball special for health preserving cups according to claim 1, it is characterized in that: described binding agent is a kaolin.
CN2008102230426A 2008-09-26 2008-09-26 Water-quality activating ball special for health preserving cups and preparation method thereof Expired - Fee Related CN101684017B (en)

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CN101891264B (en) * 2010-07-15 2012-07-04 上海家康医疗器械有限公司 Multi-dimensional composite energy active material and preparation method thereof
CN102101773B (en) * 2010-11-26 2013-01-09 新时代健康产业(集团)有限公司 Activating ceramic core, preparation method thereof, container having same and preparation method of container
CN103241823B (en) * 2013-05-17 2014-01-01 江苏宝润科技有限公司 Manufacturing method of rock glacier activation ball
JP6495482B2 (en) * 2015-05-12 2019-04-03 景煥粒子能科技発展有限公司 Composite material, preparation method and apparatus for preparing particle energy multifunctional active water
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CN108558349A (en) * 2018-05-25 2018-09-21 苗霞明 A kind of preparation method of negative ion type function artificial stone
CN108975573A (en) * 2018-08-10 2018-12-11 安徽碧云湖食品科技发展有限公司 A kind of preparation method of small-micelle water
CN112110534B (en) * 2020-09-30 2023-11-28 杭州亦灵科技有限公司 Drinking water activating material, cup, activated water and preparation method thereof
CN114230367A (en) * 2022-01-11 2022-03-25 谢春合 Purple sand pug composition for softening water quality and preparation method and application thereof
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