CN101575136B - Micro-electrolysis particle composition and preparation method thereof, micro-electrolysis generator and cup - Google Patents
Micro-electrolysis particle composition and preparation method thereof, micro-electrolysis generator and cup Download PDFInfo
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- CN101575136B CN101575136B CN2009100868460A CN200910086846A CN101575136B CN 101575136 B CN101575136 B CN 101575136B CN 2009100868460 A CN2009100868460 A CN 2009100868460A CN 200910086846 A CN200910086846 A CN 200910086846A CN 101575136 B CN101575136 B CN 101575136B
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Abstract
The invention provides a micro-electrolysis particle composition and a preparation method thereof, a micro-electrolysis generator applying same and a cup applying same. The micro-electrolysis particlecomposition comprises components with the following weight content: 20 to 50 portions of tourmalines, 2 to 15 portions of magnesium powder, 1 to 3 portions of rare earth oxides and/or zirconia, 5 to 15 portions of medical stones, 2 to 15 portions of calcined magnets, and 1 to 5 portions of wooden activated carbon. The micro-electrolysis particle composition also comprises components with the following weight content: 1 to 3 portions of germanium powder, 1 to 5 portions of radium powder, and 1 to 5 portions of wooden fish stone powder.
Description
Technical field
The present invention relates to water treatment field, specifically, relate to a kind of little electrolysis particle and preparation method thereof, use its micro-electrolysis generator, use the water tumbler of this micro-electrolysis generator.
Background technology
People use electrolysis water generator to produce the weakly alkaline brine electrolysis usually, but because electrolysis water generator needs electricity consumption, also will get rid of sour water, so people begin to consider to use little electrolysis particle to produce the weakly alkaline brine electrolysis.
Disclose a kind of micro electrolytic energy water treatment element in correlation technique, this micro electrolytic energy water treatment element mainly comprises tourmalinite, ferromagnetic material, calcium ion powder, binchotan, zinc powder, copper powder, magnesium powder, titanium oxide, rare earth oxide.
In realizing process of the present invention, thereby the contriver finds the little electrolysis particle in the correlation technique and reduces the acidity of water by make a return journey chlorine in dewatering of tourmalinite and binchotan, it can only make water reach neutral at most, and can not reach the weakly alkaline of expectation, and make the number of the water clusters in the treating water reach six, described in Chinese patent application No.200610060848.9.So be desirable to provide a kind of desirable weakly alkaline that can realize in the treating water, and make little electrolysis particle that molecule number in the water clusters in the treating water further reduces, and preparation method thereof, use its micro-electrolysis generator, use the water tumbler of this micro-electrolysis generator.
Summary of the invention
For this reason, the invention provides a kind of micro-electrolysis particle composition and preparation method thereof, use its micro-electrolysis generator, use the water tumbler of this micro-electrolysis generator.
According to an aspect of the present invention, provide a kind of micro-electrolysis particle composition, mainly comprised the component of following weight content:
The tourmalinite of 20 weight parts-50 weight part; The magnesium powder of 2 weight parts-15 weight part; The rare earth oxide and/or the zirconium white of 1 weight part-3 weight part; The medical stone of 5 weight parts-15 weight part; The calcined MAGNETITUM of 2 weight parts-15 weight part; The wooden shell gac of 1 weight part-5 weight part; And the germanium powder of 1 weight part-3 weight part; The radium powder of 1 weight part-5 weight part; Wooden fish stone flour with 1 weight part-5 weight part.
In micro-electrolysis particle composition of the present invention, described germanium powder comprises organic germanide and inorganic germanide.
In micro-electrolysis particle composition of the present invention, described organic germanium compounds is sesquioxide, spiral shell germanium and the derivative thereof of organic germanium, and described inorganic germanide is the oxide compound of germanium.
In micro-electrolysis particle composition of the present invention, described rare earth oxide comprises one or more in yttrium oxide, europium sesquioxide, the yttrium europium oxide.
In micro-electrolysis particle composition of the present invention, described little electrolysis particle is mixed by the particle of following each component, and described tourmalinite particle diameter is a 1-2mm magnesium powder, and the magnesium powder directly is 1-2mm; Rare earth oxide and/or zirconium white particle diameter are 2-3mm; The medical stone particle diameter is 1-3mm; Calcined MAGNETITUM, particle diameter are 2-3mm; Wood shell gac, particle diameter is 1-3mm, the particle diameter of germanium powder, radium powder and wooden fish powder is 1-2mm.
In micro-electrolysis particle composition of the present invention, described little electrolysis particle grain size is 2-3mm, and described little electrolysis particle mixes by weight by with each component ball mill pulverizing, and the mixture with gained manufactures particle again, and it is discoid perhaps to be shaped to a porous.
Another aspect of the present invention also provides a kind of method that is used to prepare according to micro-electrolysis particle composition of the present invention, this method comprises each component ball mill pulverizing, mix by weight, the mixture with gained manufactures particle again, and it is discoid perhaps to be shaped to a porous.
Another aspect of the present invention also provides a kind of micro-electrolysis generator that holds according to micro-electrolysis particle composition of the present invention, and this micro-electrolysis generator comprises:
First housing;
Second housing has the bottom, and its upper end is extended and joined with the lower end of described first housing to the side;
Serve as a contrast net, be arranged at the bottom of described first housing, place described micro-electrolysis particle composition in the space that described lining net and described second housing form,
Wherein, the bottom of described second housing is a reticulated structure, and described first housing is provided with to the shell fragment of outer lug so that described micro-electrolysis generator is fixed to container.
Preferably, in micro-electrolysis generator of the present invention, the top of described second hull outside is provided with screw thread so that described micro-electrolysis generator is fixed in the container, described lining network edge has projection will serve as a contrast the bottom that net removably snaps fit onto first housing, and the bottom of described lining net and described second housing is 40 orders-80 purpose reticulated structure.
Another aspect of the present invention also provides a kind of water tumbler that is equipped with according to micro-electrolysis generator of the present invention in cup.
Adopt method of the present invention, by adding germanium powder, radium powder and wooden fish powder, combine with other components among the present invention, make the present invention can obtain to be fit to more the alkalescent water of human body, the scope of its weakly alkaline value is 7.5 to 8.5; And make that the molecular grouping in treating water is a 4-5 water molecules; And reach the higher effect of nutritive value.
Description of drawings
Accompanying drawing described herein is used to provide further understanding of the present invention, constitutes the application's a part, and illustrative examples of the present invention and explanation thereof are used to explain the present invention, do not constitute improper qualification of the present invention.In the accompanying drawings:
Fig. 1 shows the stereographic map of micro-electrolysis generator according to an embodiment of the invention;
Fig. 2 shows another stereographic map of micro-electrolysis generator shown in Figure 1;
Fig. 3 shows the side-view according to the micro-electrolysis generator of further embodiment of this invention;
Fig. 4 shows the sectional view of water tumbler according to another embodiment of the present invention;
Fig. 5 shows the sectional view according to the water tumbler of further embodiment of this invention; And
Fig. 6 shows the sectional view according to the water tumbler of further embodiment of this invention;
Fig. 7 shows according to the compositions-treated water of preparation embodiment of the present invention 1 preparation
17The O-NMR spectrogram;
Fig. 8 shows according to the compositions-treated water of preparation embodiment of the present invention 3 preparations
17The O-NMR spectrogram;
Fig. 9 shows according to the compositions-treated water of preparation embodiment of the present invention 4 preparations
17The O-NMR spectrogram;
Figure 10 shows according to the compositions-treated water of preparation comparative example of the present invention 2 preparations
17The O-NMR spectrogram;
Figure 11 shows tap water
17The O-NMR spectrogram.
Embodiment
Analyze advantage of the present invention and characteristics below with reference to specific embodiments of the invention.
The invention provides a kind of micro-electrolysis particle composition, comprise the component of following weight content: the tourmalinite of 20 weight parts-50 weight part; The magnesium powder of 2 weight parts-15 weight part; The rare earth oxide and/or the zirconium white of 1 weight part-3 weight part; The medical stone of 5 weight parts-15 weight part; The calcined MAGNETITUM of 2 weight parts-15 weight part; The wooden shell gac of 1 weight part-5 weight part; And at least a in the wooden fish stone flour of the radium powder of the germanium powder of 1 weight part-3 weight part, 1 weight part-5 weight part and 1 weight part-5 weight part, preferred three kinds.Said composition also can mainly comprise mentioned component, and the implication of " mainly comprising " is for example not comprise other activeconstituents the bonding agent (if necessary) except that necessary ancillary component.In a distortion embodiment, described micro-electrolysis particle composition is made of the particle of mentioned component.In another distortion embodiment, described micro-electrolysis particle composition is made of mentioned component and an amount of bonding agent.
The following describes function and effectiveness according to little each component of electrolysis particle of the present invention:
The germanium powder is an important component of the present invention, and its raw material is organic germanium ore or other inorganic base, in a few class organic germanium compounds of biologically active, preferably adopts organic germanium sesquioxide, spiral shell germanium and derivative thereof.Organic germanium is many-sided for the mankind's benefit, and it has the dehydrogenation ability, makes it possible to keep sufficient oxygen.This inorganic Ge is the oxide compound of germanium.The germanium powder helps to adjust biological ionic equilibrium, has the effect of preventing and improving the sense of discomfort of health, and the function that can also regulate the undesired current potential of human body.The weight range of germanium powder is the 1-3 weight part, preferred 2-3 weight part; The particle diameter of germanium powder particles is 1-2mm.
Radium powder (radium stone flour) also is an important component of the present invention, and radium stone produces radon and micro-radioactive rays, has the natural curability and the sensitization effect of immunizing power, i.e. " hormone of radioactive rays is regulated effect " that stimulate human body self.The micro-radioactive rays of radium stone produce a large amount of negative ions according to ionizing event, and therefore, the negative ion burst size of radium stone is very high: impel blood usually, stimulate circulation, stabilizing blood pressure, the nerve that normally contains oneself, Ginkgo Biloba; Can play and purify air, brine electrolysis, dwindle the effect of water molecules bundle.Content is in this scope, is beneficial to reach to dwindle the water molecules bundle and realize the effect that negative ion discharges, and is beneficial to and kills bacterium in the water, increases the dissolved oxygen in the water.The weight range of radium powder is the 1-5 weight part, preferred 2-4 weight part; The particle diameter of radium powder particles is 1-2mm.
The wooden fish stone flour also is an important component of the present invention, and MUSYUSHI contains multiple necessary for human body trace element and mineral substance, as calcium, selenium, strontium, zinc, manganese, magnesium, cobalt, iron and phosphorus etc.The physical structure of MUSYUSHI is also very special simultaneously.Facts have proved that MUSYUSHI has very strong fresh-keeping function to water, can make the common white boiling water reach the function of mineral water in a short time.The weight content of the MUSYUSHI content in the composition of the present invention is the 1-5 weight part, preferred 2-4 weight part; The particle diameter of MUSYUSHI powder particles is 1-2mm.Contain at least a in three kinds in the germanium powder, radium powder, wooden fish stone flour in the composition, preferably contain three kinds.
Tourmalinite (powder) is a kind of borosilicate mineral, is the non-metallic minerals of natural multielement.Its chemical ingredients is boron (B), magnesium (Mg), aluminium (Al), silicate, and its chemical formula is: (Na, and Ca) (Mg, Fe)
3B
3Al
6Si
6(0, OH, F)
31And a-SiO
2And contain trace V, Cr, Zr, Mn, Ti, Sr, Ga
2O
3Deng element to the human body beneficial.The hardness of tourmalinite is generally about 7.3-7.6, and tool fragility, relative density are 3.03-3.25.Tourmaline powder is made the tourmalinite haydite, can be used for making in the purification, mineralization container tap water activation, purify, can remove the chlorine in the tap water, make macromolecular mass water become small-micelle water, make water that faint electrolysis take place, have the effect that the water body redox potential is reduced, generate alkaline anion water, thereby change the acidity of water.Little through tourmalinite treated water molecular beam, mouthfeel is sweet.Tourmalinite particle diameter 1-2mm, content are 20 weight parts-50 weight parts.
Calcined MAGNETITUM is a kind of magnetite, and major ingredient is Fe
3O
4, it can grow Yang Na gas, tranquilizing and allaying excitement, uses after the forging usually.It can magnetize softening the processing to water, and water quality is purified.Particle diameter 2-3mm, content are 2 weight parts-15 weight parts.
Medical stone is a kind of natural monzonite class porphyry stone with biological effect and medical functions.It is the aggregate of multi mineral, contains 18 kinds of trace elements such as the necessary potassium of human body, sodium, calcium, magnesium, phosphorus major element and zinc, iron, selenium, copper, strontium, iodine, fluorine, metasilicic acid.Under usual conditions, four kinds of trace elements (metasilicic acid, Sr, Zn, F) content reaches or approaching national beverage mineral water standard in the medical stone dissolution fluid.Modern science analytical proof, medical stone are rich in multiple element, and biologically active can improve the effect of the physiological function and the two-ways regulation potential of hydrogen of body; Hazardous and noxious substances and airborne peculiar smell in the planar water forcefully can the stripping various trace elements, are a kind of natural nutrition sources.Particle diameter 1-3mm, content are 5 weight parts-15 weight parts.
Wood shell gac can be removed SYNTHETIC OPTICAL WHITNER or the chlorine in the tap water.The water quality sweetness is drunk well.And it has stronger adsorptive power, can adsorb harmful ion, removes the chlorine in the water, makes water quality become weakly alkaline, helps health.Particle diameter 1-3mm, content are 1 weight part-5 weight part.
Rare earth oxide comprises one or more in yttrium oxide, europium sesquioxide, the yttrium europium oxide, rare earth oxide and/or zirconium white can replenish the far-infrared functional of tourmalinite, wherein, zirconium white is a kind of structural ceramics of excellent performance, these materials be added with the bonding that helps strengthen between each component, composition middle-weight rare earths oxide compound and/or zirconic weight content are the 1-3 weight part, and particle diameter is 2-3mm.The magnesium powder content is 2 weight parts-15 weight parts, particle diameter 1-2mm.
In the present invention, micro-electrolysis particle composition has two kinds of constituted modes, and first kind is that particle with above-mentioned each composition simply mixes, and second kind is that each component is pulverized the back uniform mixing, make 1-5mm (preferred 2-3mm) particle with existing prilling process again, each particle contains all compositions.
The starting material of being put down in writing in the technical solution of the present invention are matured product, and sale is all arranged on market.Tourmalinite, magnesium powder, rare earth oxide, zirconium white, medical stone, calcined MAGNETITUM, wooden shell gac, germanium powder, radium powder, wooden fish stone flour have different specifications.If particulate product also can be by thinner particulate, as common flour (ten or hundred order levels), ultra-fine, particle that nano level (preferably ultra-fine, nano level) is made, this particle is used for first kind of constituted mode of micro-electrolysis particle composition.For second kind of constituted mode, can directly buy fine powder (common flour, ultra-fine, nano level) or macrobead is pulverized, and then the mixing granulation moulding.Granulating and forming is not limited to make granular particle, also can make container-like (micro-electrolysis generator) or filtrable material (sheet, plate-like or bulk) as required, uses it can avoid producing a lot of fragments.
The present invention also provides a kind of micro-electrolysis generator, is used to hold micro-electrolysis particle composition.
Fig. 1 shows the sectional view of micro-electrolysis generator according to an embodiment of the invention.Fig. 2 shows another stereographic map of micro-electrolysis generator shown in Figure 1.Fig. 3 shows the side-view of micro-electrolysis generator shown in Figure 1.
See figures.1.and.2, micro-electrolysis generator 100 comprises according to an embodiment of the invention: first housing 102; Second housing 104 has bottom 1042, and its upper end is extended and joined with the lower end of first housing 102 to the side; Lining net 106, be arranged at the bottom of first housing 102, in the space of lining net 106 and the formation of second housing 104 placement can with the particle (being aforesaid micro-electrolysis particle composition) of water generation micro-electrolysis reaction, wherein, the bottom 1042 of second housing 104 is a reticulated structure.In a preferred embodiment, it is discoid micro-electrolysis particle composition can be utilized prior art be shaped to a porous, puts into the space (not shown) that the lining net 106 and second housing 104 form.Can reduce or avoid fragment to enter water tumbler like this.
Because the top and the bottom of second housing are reticulated structure, so in the process of in water tumbler, injecting water, water enters micro-electrolysis generator and can micro-electrolysis reaction take place with the particle (micro-electrolysis particle composition) of water generation micro-electrolysis reaction by serving as a contrast online hole, the weakly alkaline brine electrolysis that generates passes the bottom and enters in the cup, in addition, when injecting more water in the cup, water can also contact with abundant reaction with little electrolysis particle by the bottom.
Preferably, the material of micro-electrolysis generator 100 is a stainless material in case acid and alkali corrosion, preferred 304 stainless steels.
Preferably, described first housing 102 outsides are provided with the shell fragment 112 of projection.When the outside of first housing leans against on the water tumbler inwall, the shell fragment 112 of projection is squeezed, shell fragment produces opposition to the inwall (depressed part correspondingly is set alternatively) of water tumbler, makes micro-electrolysis generator firm with cooperating of water tumbler, avoids it to slide along inwall.Shown in the figure is the situation of 4 shell fragments, and the number of shell fragment also can be other any suitable number.
According to the micro-electrolysis generator of the embodiment of the invention by on first housing, shell fragment being set, so overcome the technical problem that is not easy to the particulate integral replacing that the little electrolysis particle seepage in the micro-electrolysis generator in the correlation technique causes in the water, and then fixedly reached the technique effect that prevents particle seepage in the micro-electrolysis generator.
In a kind of replacement embodiment, second hull outside is provided with screw thread 108 (perfect thread, part screw thread all can) so that micro-electrolysis generator is fixed to water tumbler, the water tumbler inwall corresponding screw thread is set or have the flange of opening (constituting screw thread or part screw thread) so as with the thread fit of second hull outside, fixedly micro-electrolysis generator.
Preferably, the lining network edge can have a plurality of projectioies will serve as a contrast the bottom that net removably snaps fit onto first housing.In addition, the lining net also can adopt such as be spirally connected or other dismountable mode be connected to first housing bottom so that change this and the particle of water generation micro-electrolysis reaction to reach the purpose of recycling.
Alternatively, just also have trim ring 110 is fixed to first housing, 102 bottoms will serve as a contrast net 106 to lining on the net.
Preferably, the bottom 1042 of lining net 106 and second housing is 40 orders-80 purpose reticulated structure, particle be diameter be 1-5mm germanium powder, radium powder, wooden fish stone flour, calcined MAGNETITUM, magnesium powder and medical stone in one or more.
Preferred, the bottom of lining net and second housing can be 60 purpose reticulated structures.More preferably, these particulate diameters are 3mm.If mesh is excessive, then when little electrolysis particle after the long-time and water generation electrolytic reaction, its smaller volume will cause little electrolysis particle to spill from mesh; If mesh is too small, then will cause current not smooth, influence is drunk.
Being included in according in the micro-electrolysis generator of the present invention and particle water generation micro-electrolysis reaction also can be water treatment element of the prior art.The weakly alkaline micro electrolytic energy water treatment element has the advantage of (not electricity consumption) simple and easy to use, energy-conservation, water saving (needn't acid discharge water), use manpower and material resources sparingly (not needing subsequent installation and maintenance and after sale service).
Alternatively, micro-electrolysis generator can also comprise draw ring 404, is arranged on first housing 102 of micro-electrolysis generator to carry out integral replacing or cleaning so that take out this micro-electrolysis generator.
In addition, first housing and second housing can be respectively cylindrical shell as shown in Figure 1, also can for the housing of other shape (as taper) to be suitable for putting into water tumbler.
Micro-electrolysis generator according to the above embodiment of the present invention can reach the technique effect of being convenient to integral replacing.
Fig. 4 shows the sectional view of water tumbler 400 according to another embodiment of the present invention.
As shown in Figure 4, be provided with Fig. 1, Fig. 2 and micro-electrolysis generator 100 shown in Figure 3 in the water tumbler 400 according to another embodiment of the present invention.
Water tumbler is by being provided with the micro-electrolysis generator that can produce the weakly alkaline brine electrolysis within it according to another embodiment of the present invention, can solve the technical problem of little electrolysis particle seepage of the little electrolytic vessel existence in the correlation technique, thereby reach the purpose of being convenient to integral replacing.In addition, micro-electrolysis generator is set in water tumbler, also has portable advantage.
Preferably, water tumbler 400 inboards are provided with the depressed part 406 that matches with shell fragment 112 on first housing 102.So that micro-electrolysis generator is fixed in the water tumbler.
Prior art only fixes micro-electrolysis generator by the reactive force between shell fragment and the container inner wall, and after shell fragment elasticity dies down, shell fragment will die down to the fixing of micro-electrolysis generator, thereby cause micro-electrolysis generator landing from container easily.And according to having the depressed part that can shell fragment matches in the water tumbler of the present invention to block shell fragment, so the problem of the easy landing of micro-electrolysis generator that causes after not existing shell fragment elasticity to die down.
Preferably, the water tumbler inwall is provided with collar flange 402, and the diameter of collar flange 402 is greater than the diameter of second housing 104 and less than the diameter of first housing 102.So that micro-electrolysis generator 100 can be positioned at the middle part of water tumbler and top so that take out.
Preferably, collar flange 402 has opening.Because the effect of flange is to support micro-electrolysis generator,, flange just can realize that this function is to reach the purpose of saving material so needing not be whole ring-type.Alternatively, this opening is that symmetric opening is to keep attractive in appearance.Certainly, this opening also can be for asymmetric.
Preferably, has the screw 408 that matches with the screw thread 108 on the top of second hull outside on the flange 402.So that micro-electrolysis generator 100 is fixed in the water tumbler 400.By the cooperation of screw thread 108 and screw 408, micro-electrolysis generator is more solid reliable with cooperating of water tumbler.Replace in the embodiment one, the flange 402 that has opening can be made the part screw thread, with the thread fit of flange itself with second hull outside.Under by situation about being threaded, the structure of shell fragment can be omitted.
Alternatively, micro-electrolysis generator also can be positioned at the bottom of 400 glasss of the water tumblers, as shown in Figure 5.In the process of in water tumbler, injecting water, water enters micro-electrolysis generator and little electrolysis particle generation micro-electrolysis reaction by serving as a contrast online hole, the weakly alkaline brine electrolysis that generates, because micro-electrolysis generator places at the bottom of the water tumbler cup, so even the water in the cup amount is less, also can fully carry out micro-electrolysis reaction to produce the weakly alkaline brine electrolysis.Under the situation at the bottom of micro-electrolysis generator is placed on the water tumbler cup, the structure of screw thread can be omitted.
Alternatively, as shown in Figure 6, in the time of at the bottom of micro-electrolysis generator 100 is placed on the water tumbler cup, comprise draw ring 404, change or clean by extract part taking-up micro-electrolysis generator 100 such as the outside of long handle hook 602 to make things convenient for the user.
In addition, because the lining net and second housing are for removably connecting, so also can take off the lining net to change little electrolysis particle wherein after taking out micro-electrolysis generator.
In addition, the shape of water tumbler 400 is not limited to the shape shown in the figure.
The above embodiment of the present invention is by being provided with shell fragment on first housing above second housing of built-in little electrolysis material, so overcome the technical problem that is not easy to the particulate integral replacing that the little electrolysis particle seepage in the micro-electrolysis generator in the correlation technique causes in the water, and then reached the technique effect of being convenient to integral replacing.
Below with reference to the accompanying drawings and in conjunction with the embodiments, describe the present invention in detail.
The preparation embodiment of micro-electrolysis particle composition and preparation comparative example
Preparation embodiment 1:
The tourmalinite of 20 weight parts; The magnesium powder of 2 weight parts; The zirconium white of the yttrium europium oxide of 1 weight part and 2 weight parts; The medical stone of 15 weight parts; The calcined MAGNETITUM of 12 weight parts; The wooden shell gac of 2 weight parts; The germanium powder of 3 weight parts; The radium powder of 5 weight parts; And the wooden fish stone flour of 1 weight part.
Tourmalinite, medical stone, calcined MAGNETITUM, magnesium powder are crushed to 70-90 μ m, yttrium europium oxide, zirconium white, wooden shell gac, germanium powder, radium powder and wooden fish stone flour are crushed to 40-70 μ m, by each ingredients weight parts uniform mixing, manufacture the granulated material of 2-3mm at last then.
Preparation embodiment 2:
The tourmalinite of 50 weight parts; The magnesium powder of 15 weight parts; The yttrium oxide of 1 weight part; The medical stone of 5 weight parts; The calcined MAGNETITUM of 15 weight parts; The wooden shell gac of 1 weight part; The germanium powder of 1 weight part; 5 weight part radium powder; And the wooden fish stone flour of 1 weight part.
Tourmalinite, medical stone, calcined MAGNETITUM, magnesium powder are crushed to 80-100 μ m, yttrium oxide, wooden shell gac, germanium powder, radium powder and wooden fish stone flour are crushed to 40-80 μ m,, manufacture the granulated material of 2-3mm at last then by each ingredients weight parts uniform mixing.
Preparation embodiment 3:
The tourmalinite of 40 weight parts; The magnesium powder of 7 weight parts; 1.5 the zirconium white of the europium sesquioxide of weight part and 1 weight part; The medical stone of 8 weight parts; The calcined MAGNETITUM of 6 weight parts; 3.5 the wooden shell gac of weight part; And the germanium powder of 1.5 weight parts; 2.5 weight part radium powder; And the wooden fish stone flour of 5 weight parts.
Tourmalinite, medical stone, calcined MAGNETITUM, magnesium powder are crushed to 70-100 μ m, europium sesquioxide, zirconium white, wooden shell gac, germanium powder, radium powder and wooden fish stone flour are crushed to 40-70 μ m, then by each ingredients weight parts uniform mixing, utilize moulding at last with the similar mould of micro-electrolysis generator shape, and the reprocessing porous, thereby be shaped to the porous disc shape material that is complementary with container.
Preparation embodiment 4:
The tourmalinite of 35 weight parts; The magnesium powder of 5 weight parts; The zirconium white of the europium sesquioxide of the yttrium oxide of 1 weight part and 1 weight part and 0.5 weight part; The medical stone of 12 weight parts; The calcined MAGNETITUM of 8 weight parts; The wooden shell gac of 4 weight parts; The germanium powder of 2 weight parts; 4.5 the radium powder of weight part; And the wooden fish stone flour of 2.5 weight parts.
Tourmalinite, medical stone, calcined MAGNETITUM, magnesium powder are crushed to 80-100 μ m, yttrium oxide, europium sesquioxide, zirconium white, wooden shell gac, germanium powder, radium powder and wooden fish stone flour are crushed to 40-80 μ m, by each ingredients weight parts uniform mixing, manufacture the granulated material of 2-3mm at last then.
Preparation embodiment 5:
The tourmalinite of 25 weight parts; The magnesium powder of 12 weight parts; The zirconium white of the yttrium europium oxide of the yttrium oxide of 1 weight part, 1 weight part and 1.5 weight parts; The medical stone of 8 weight parts; The calcined MAGNETITUM of 12 weight parts; 2.5 the wooden shell gac of weight part; And the wooden fish stone flour of the radium powder of 3 weight parts and 3 weight parts.
With each component by its separately weight part carry out simple and mix equably, forming the particle diameter that mixes is the granulated material of 1-3mm.
Preparation comparative example 1:
Tourmalinite 15 weight part ferric oxide 5 weight parts
Ferric oxide 3 weight part Z 250s 5 weight parts
Calcium ion powder 15 weight part binchotans 15 weight parts
Zinc powder 15 weight part copper powders 15 weight parts
Magnesium powder 5 parts by weight of titanium oxide 5 weight parts
Zirconium white 2 weight parts.
Be 50-60 μ m with each component starting material separated pulverizing, ball milling tourmalinite, titanium oxide, zirconium white particle diameter earlier, binchotan, ferric oxide, ferric oxide, Z 250, zinc powder, copper powder, magnesium powder and calcium ion powder particle diameter are 80-100 μ m, press each component weight content uniform mixing then, can manufacture particulate state at last.
Preparation comparative example 2:
Tourmalinite 40 weight part ferric oxide 5 weight parts
Sepiolite 1.5 weight part medical stones 3 weight parts
Calcium ion powder 10 weight part zinc powders 10 weight parts
Copper powder 10 weight part magnesium powder 2 weight parts
Titanium oxide 3 weight part yttrium oxide 5 weight parts.
Earlier each component starting material separated pulverizing, ball milling tourmalinite, titanium oxide, zirconium white particle diameter are about 80 μ m, binchotan, ferric oxide, ferric oxide, Z 250, zinc powder, copper powder, magnesium powder and calcium ion powder particle diameter are about 100 μ m, press each component weight content uniform mixing then, can manufacture particulate state at last.
The Performance Detection embodiment of micro-electrolysis particle composition
The Performance Detection embodiment 1 of micro-electrolysis particle composition: under the condition of 23 ℃ of room temperatures and humidity 30%, utilize 50g to soak the 200ml tap water according to preparation embodiment 1 prepared little electrolysis particle of the present invention, carry out NMR test (detecting unit is national drug and meta-bolites analysis and research center), according to " Modern Analytical Instrument analytical procedure general rule and measurement verification regulations ", all appts is " VARIAN INOVA-500 type HIGH RESOLUTION SUPERCONDUCTING nuclear magnetic resonance spectrometer ", obtains treating water
17The O-NMR spectrogram is as accompanying drawing 7.
The Performance Detection embodiment 2 of micro-electrolysis particle composition: according to the mode identical, replaced the prepared little electrolysis particle of preparation embodiment 1, obtained treating water with preparation embodiment 2 prepared little electrolysis particles with Performance Detection embodiment 1
17The O-NMR spectrogram, the spectrogram among this spectrogram and the embodiment 1 is similar.
The Performance Detection embodiment 3 of micro-electrolysis particle composition: according to the mode identical, replaced the prepared little electrolysis particle of preparation embodiment 1, obtained treating water with preparation embodiment 3 prepared little electrolysis particles with Performance Detection embodiment 1
17The O-NMR spectrogram is as accompanying drawing 8.
The Performance Detection embodiment 4 of micro-electrolysis particle composition: according to the mode identical, replaced the prepared little electrolysis particle of preparation embodiment 1, obtained treating water with preparation embodiment 4 prepared little electrolysis particles with Performance Detection embodiment 1
17The O-NMR spectrogram is as accompanying drawing 9.
The Performance Detection embodiment 5 of micro-electrolysis particle composition: according to the mode identical, replaced the prepared little electrolysis particle of preparation embodiment 1, obtained treating water with preparation embodiment 5 prepared little electrolysis particles with Performance Detection embodiment 1
17The O-NMR spectrogram, the spectrogram of this spectrogram and embodiment 3 gained is similar.
The Performance Detection comparative example 1 of micro-electrolysis particle composition: according to the mode identical, replaced the prepared little electrolysis particle of preparation embodiment 1, obtained treating water with preparation comparative example 1 prepared little electrolysis particle with Performance Detection embodiment 1
17The O-NMR spectrogram, the spectrogram of gained is similar among this spectrogram and the embodiment 4.
The Performance Detection comparative example 2 of micro-electrolysis particle composition: according to the mode identical, replaced the prepared little electrolysis particle of preparation embodiment 1, obtained treating water with preparation comparative example 2 prepared little electrolysis particles with Performance Detection embodiment 1
17The O-NMR spectrogram is as accompanying drawing 10.
The Performance Detection comparative example 3 of micro-electrolysis particle composition: according to the mode identical, make sample, obtain tap water with tap water with Performance Detection embodiment 1
17The O-NMR spectrogram is as accompanying drawing 11.
Above sample utilizes precision acidity meter (model: PHS-4cT is available from Shanghai precision instrumentation company limited) to measure its pH value.And, calculate the intrafascicular sub-number of average moisture of water molecules in each sample according to the peak width at half height in the spectrogram of NMR measurement.
Effect is relatively listed in the following table 1,
Table 1
| The peak width at half height value | The mean molecule number that water molecules is intrafascicular | The pH value | |
| Performance Detection embodiment 1 | 45.44 | 4 | 7.58 |
| Performance Detection embodiment 2 | 46.23 | 4 | 7.82 |
| Performance Detection embodiment 3 | 58.42 | 5 | 8.24 |
| Performance Detection embodiment 4 | 63.58 | 6 | 8.43 |
| Performance Detection embodiment 5 | 59.21 | 5 | 8.28 |
| Performance Detection comparative example 1 | 63.99 | 6 | 8.37 |
| Performance Detection comparative example 2 | 69.05 | 7 | 8.58 |
| Performance Detection comparative example 3 | 100.27 | 13 | 7.97 |
Conclusion: the data in the comparison sheet 1 as can be known, adopt method of the present invention,, combine with other components among the present invention by adding germanium powder, radium powder and wooden fish powder, make the present invention can obtain to be fit to more the alkalescent water of human body, the scope of its weakly alkaline pH value is 7.5 to 8.5; And make that the molecular grouping in treating water is a 4-5 water molecules; And reach the higher effect of nutritive value.
The above is the preferred embodiments of the present invention only, is not limited to the present invention, and for a person skilled in the art, the present invention can have various changes and variation.Within the spirit and principles in the present invention all, any modification of being done, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. a micro-electrolysis particle composition is characterized in that, the preparation method of described little electrolyte composition comprises each component ball mill pulverizing, mix by certain weight part then, the mixture with gained manufactures particle again, and it is discoid perhaps to be shaped to a porous, wherein, described component is:
The tourmalinite of 20 weight parts-50 weight part;
The magnesium powder of 2 weight parts-15 weight part;
The rare earth oxide and/or the zirconium white of 1 weight part-3 weight part;
The medical stone of 5 weight parts-15 weight part;
The calcined MAGNETITUM of 2 weight parts-15 weight part;
The wooden shell gac of 1 weight part-5 weight part; And
The germanium powder of 1 weight part-3 weight part;
The radium powder of 1 weight part-5 weight part; With
The wooden fish stone flour of 1 weight part-5 weight part.
2. micro-electrolysis particle composition according to claim 1 is characterized in that, described germanium powder comprises organic germanide and inorganic germanide.
3. micro-electrolysis particle composition according to claim 2 is characterized in that, described organic germanium compounds is sesquioxide, spiral shell germanium and the derivative thereof of organic germanium, and described inorganic germanide is the oxide compound of germanium.
4. according to each described micro-electrolysis particle composition among the claim 1-3, it is characterized in that described rare earth oxide comprises one or more in yttrium oxide, europium sesquioxide, the yttrium europium oxide.
5. micro-electrolysis particle composition according to claim 4 is characterized in that, described little electrolysis particle is mixed by the particle of following each component, and described tourmalinite particle diameter is 1-2mm, and the magnesium powder directly is 1-2mm; Rare earth oxide and/or zirconium white particle diameter are 2-3mm; The medical stone particle diameter is 1-3mm; Calcined MAGNETITUM, particle diameter are 2-3mm; Wood shell gac, particle diameter is 1-3mm, the particle diameter of germanium powder, radium powder and wooden fish stone flour is 1-2mm.
6. micro-electrolysis particle composition according to claim 4 is characterized in that, described little electrolysis particle grain size is 2-3mm, described little electrolysis particle passes through each component ball mill pulverizing, mix by weight, the mixture with gained manufactures particle again, and it is discoid perhaps to be shaped to a porous.
7. method that is used to prepare micro-electrolysis particle composition according to claim 6, described method comprises each component ball mill pulverizing, mix by certain weight part then, the mixture with gained manufactures particle again, and it is discoid perhaps to be shaped to a porous.
8. micro-electrolysis generator that holds according to each described micro-electrolysis particle composition among the claim 1-7, described micro-electrolysis generator comprises:
First housing (102);
Second housing (104) has bottom (1042), and its upper end is extended and joined with the lower end of described first housing to the side;
Lining net (106) is arranged at the bottom of described first housing, the described micro-electrolysis particle composition of placement in the space that described lining net and described second housing form, and described lining net is detachably connected to the bottom of described first housing with clamping or the mode of being spirally connected,
Wherein, the bottom of described second housing is a reticulated structure, and described first housing is provided with shell fragment (112) to outer lug so that described micro-electrolysis generator is fixed to container.
9. micro-electrolysis generator according to claim 8, it is characterized in that, the top of described second hull outside is provided with screw thread (108) so that described micro-electrolysis generator is fixed in the container, described lining network edge has projection will serve as a contrast the bottom that net removably snaps fit onto first housing, and the bottom of described lining net and described second housing is 40 orders-80 purpose reticulated structure.
10. one kind is equipped with in cup according to Claim 8 or the water tumbler of 9 described micro-electrolysis generators.
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| CN101781047B (en) * | 2009-12-07 | 2012-05-23 | 洪清盾 | Preparation method of active water |
| CN102920260A (en) * | 2011-08-08 | 2013-02-13 | 林杰贤 | Inner container of healthcare insulation cup and manufacturing method of inner container |
| KR101497514B1 (en) * | 2013-10-16 | 2015-03-02 | 김동헌 | Generation and supply device of Germanium water. |
| CN105084470A (en) * | 2014-05-09 | 2015-11-25 | 广州桑尼环保科技有限公司 | Spherical catalytic microelectrolytic environment-friendly material and preparation method therefor |
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| CN100378009C (en) * | 2006-05-31 | 2008-04-02 | 北京水宜生科技发展有限公司 | Micro electrolytic energy water treatment element and its preparation method |
| CN201160726Y (en) * | 2008-03-05 | 2008-12-10 | 张庆权 | Micro-electrolysis activated water container |
| CN201167797Y (en) * | 2008-03-21 | 2008-12-24 | 孙友 | Health cup for generating alkalescent activated water |
| CN201192233Y (en) * | 2007-06-08 | 2009-02-11 | 秦荣 | Tourmaline wooden-fish stone cup |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100378009C (en) * | 2006-05-31 | 2008-04-02 | 北京水宜生科技发展有限公司 | Micro electrolytic energy water treatment element and its preparation method |
| CN201192233Y (en) * | 2007-06-08 | 2009-02-11 | 秦荣 | Tourmaline wooden-fish stone cup |
| CN201160726Y (en) * | 2008-03-05 | 2008-12-10 | 张庆权 | Micro-electrolysis activated water container |
| CN201167797Y (en) * | 2008-03-21 | 2008-12-24 | 孙友 | Health cup for generating alkalescent activated water |
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