CN101679924A - Transparent solid soap - Google Patents

Transparent solid soap Download PDF

Info

Publication number
CN101679924A
CN101679924A CN200880018983.4A CN200880018983A CN101679924A CN 101679924 A CN101679924 A CN 101679924A CN 200880018983 A CN200880018983 A CN 200880018983A CN 101679924 A CN101679924 A CN 101679924A
Authority
CN
China
Prior art keywords
composition
solid soap
soap
carbonatoms
lipid acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN200880018983.4A
Other languages
Chinese (zh)
Other versions
CN101679924B (en
Inventor
细川久美子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Publication of CN101679924A publication Critical patent/CN101679924A/en
Application granted granted Critical
Publication of CN101679924B publication Critical patent/CN101679924B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0095—Solid transparent soaps or detergents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/14—Shaping
    • C11D13/16—Shaping in moulds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/007—Soaps or soap mixtures with well defined chain length
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06—Inorganic compounds
    • C11D9/08—Water-soluble compounds
    • C11D9/10—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/267—Organic compounds, e.g. vitamins containing oxygen containing free fatty acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Abstract

The invention provides a transparent solid soap which contains (A) C12-18 linear saturated fatty acids and/or salts thereof and contains substantially neither any branched fatty acid salt nor any unsaturated fatty acid salt. The transparent solid soap further contains (B) one or more members selected among nonionic surfactants, amphoteric surfactants, polyhydric alcohols which are liquid at ordinary temperature, and saccharides, (C) an inorganic salt, and (D) water. The content of the fatty acids constituting the ingredient (A) is 20-40 mass% based on the whole solid soap, and the proportion of the fatty acids constituting the ingredient (A) to the ingredient (B) is from 30/70 to 45/55 by mass. The content of the ingredient (C) is 0.5-5 mass%, and the ingredient (D) constitutes the remainder. In the ingredient (A), the proportion of the C12 fatty acid to the sum of the C16 fatty acid and the C18 fatty acid is from 30/70 to 60/40 by mass, and the proportion of the C12 fatty acid to theC14 fatty acid is from 20/80 to 80/20 by mass. The total amount of the C12 fatty acid and the C14 fatty acid is 14-22 mass% based on the whole solid soap. This transparent solid soap is highly transparent and lathers well especially in hard water. It has the moderate hardness required of solid soaps, is free from problems concerning deterioration in odor with time and sogginess. The solid soap hashigh productivity and can be easily molded into a desired shape.

Description

Transparent solid soap
Technical field
The present invention relates to transparent solid soap and manufacture method thereof.
Background technology
Known, in the fatty acid soaps of sodium salt, suppress figging of soap by adding transparentizing agents such as glycerine, Sorbitol Powder, sucrose as host with higher fatty acid, make its fine crystallineization, thereby make the transparent solid soap of appearance transparent.Because this transparent solid soap contains a large amount of polyvalent alcohol or carbohydrates as wetting Agent for Printing Inks, therefore have outstanding skin care effect, usability gentleness, be mainly used in the purposes that washes one's face.
All the time, transparent solid soap is by cooperate transparentizing agent in fatty acid soaps, heating for dissolving in the mixed solvent of rudimentary alcohol and waters such as ethanol after, inject mold frame, through tens of days solvent slowly being volatilized and solidifying, promptly so-called frame method for making is made (opening clear 57-30798 communique and Te Kai 2002-80896 communique with reference to the spy).The transparent solid soap that obtains according to this method has the high advantage of transparency, also has the shortcoming of producing rate variance but then.And, because the frame method for making is will solidify the soap that form according to the shape of mold frame to cut off, and be to carry out molded and make product according to the shape of product, therefore, having needs independent forming process, and produces shortcoming such as soap disintegrating slag.
On the other hand, a kind of machine-processed transparent solid soap composition (opening flat 8-283795 communique with reference to the spy) that has cooperated ionogen and specific nonionogenic tenside in fatty acid soaps has been proposed.According to this invention, can improve dissolving when using and after using and lose shape, obtain the outstanding transparent solid soap of the transparency.But, in the method, since be difficult to make the nonionogenic tenside uniform mixing, abundant inadequately aspect transparency, and, in method by mechanism, owing to be squeezed into bar-shaped shaping earlier usually, further molded and commercialization again with it, therefore, have and the independent forming process of above-mentioned same needs, and produce the problem of soap disintegrating slag etc.
In addition, a kind of frame system type solid cleaner (with reference to TOHKEMY 2004-143114 communique) that contains saturated branched fatty acid salt and/or unsaturated fatty acid salt and epoxy alkane derivative has been proposed.According to this invention, it is good to access whipability, detergency, usability, has the skin clean-out system as the sufficient hardness and the stability of solid soap.But, this frame system type solid cleaner and common lipid acid nature of soap ratio, hardness is abundant inadequately.And, owing to be the framed soap kui method, expend time in when therefore making, low these problems of productivity are still unresolved, but also exist the problem of the smell that used branched chain fatty acid or unsaturated fatty acids cause.
Summary of the invention
The present invention is directed to these problems, aim to provide that the transparency is high, whipability well, good to the whipability of hard water especially, have as the hardness of the appropriateness of solid soap, do not exist smell as time passes and the transparent solid soap of the problem that worsens, and make the manufacture method that obtains this transparent solid soap according to desirable shape high productivity ground.
The inventor finds, substantially do not contain branched fatty acid salt and unsaturated fatty acid salt and contain the transparent solid soap that carbonatoms is 12～18 salts of straight-chain saturated fatty acids, the cooperation ratio by control lipid acid and the cooperation ratio of reagent with hyalinization are in specific scope, and make it to contain the inorganic salt of specified quantitative, can address the above problem.
Promptly, the invention provides a kind of transparent solid soap, be that to contain carbonatoms be 12～18 linear saturated fatty acids and/or its salt (A) and the transparent solid soap that does not contain branched fatty acid salt and unsaturated fatty acid salt substantially, it contains and is selected from nonionogenic tenside, amphoterics, be the polyalcohols of liquid state and the material more than a kind or 2 kinds (B) in the carbohydrate at normal temperatures, inorganic salt (C) and water (D), with respect to the solid soap total amount, the content that constitutes the lipid acid of (A) composition is 20～40 quality %, constitute the lipid acid of (A) composition and (B) mass ratio of composition be 30: 70～45: 55, (C) content of composition is 0.5～5 quality %, and (D) content of composition is surplus, carbonatoms in constituting the lipid acid of (A) composition be 12 lipid acid and carbonatoms be 16 and carbonatoms be that the mass ratio of the total amount of 18 lipid acid is 30: 70～60: 40 a scope, carbonatoms is that 12 lipid acid and carbonatoms are that the mass ratio of 14 lipid acid is 20: 80～80: 20 a scope, and carbonatoms is that 12 lipid acid and carbonatoms are that the total amount of 14 lipid acid is 14～22 quality % with respect to the total amount of solid soap.
And, the invention provides a kind of manufacture method of transparent solid soap, be to be 12～18 linear saturated fatty acids and/or its salt (A) by containing carbonatoms, be selected from nonionogenic tenside, amphoterics, be the polyalcohols of liquid state and the material more than a kind or 2 kinds (B) in the carbohydrate at normal temperatures, the soap composition of inorganic salt (C) and water (D) is made the method for transparent solid soap, wherein, described soap composition is: the content of the lipid acid of formation (A) composition is 20～40 quality % with respect to the total amount of soap composition, carbonatoms in constituting the lipid acid of (A) composition be 12 lipid acid and carbonatoms be 16 and carbonatoms be that the mass ratio of the total amount of 18 lipid acid is 30: 70～60: 40 a scope, carbonatoms is that 12 lipid acid and carbonatoms are that the mass ratio of 14 lipid acid is 20: 80～80: 20 a scope, carbonatoms is that 12 lipid acid and carbonatoms are that the total amount of 14 lipid acid is 14～22 quality % with respect to the total amount of soap composition, the mass ratio that constitutes the lipid acid of above-mentioned (A) composition and above-mentioned (B) composition is 30: 70～45: 55 a scope, (C) content of composition is 0.5～5 quality %, and (D) content of composition is surplus, described manufacture method is: after becoming above-mentioned soap composition heating and melting evenly, in the mould that injection molding is used, cooling, solidify the solid soap that obtains being shaped.
The transparent solid soap of the present invention transparency is high, whipability well, particularly good to the whipability of hard water, have hardness as the appropriateness of solid soap, do not exist smell as time passes and the problem that worsens.And, the fused soap composition being injected the mould of desired shape, only just can easily make by cooling, therefore can high productivity ground make product according to desirable shape shaping.
Embodiment
Transparent solid soap of the present invention is that 12～18 linear saturated fatty acids and/or its salt (A) are host with carbonatoms, does not contain branched fatty acid salt and unsaturated fatty acid salt substantially.By selecting this formation, only just need cool off and can harden the short period of time, can greatly boost productivity.And transparent solid soap of the present invention owing to the enough injection molding manufacturings of energy, is made mould the shape of the finished product earlier, again to wherein injecting the fused soap composition, by cooling, curing, can make the solid soap of desired shape expeditiously.
Branched fatty acid salt and unsaturated fatty acid salt owing to have the effect that improves the transparency, are used in the existing solid soap composition, and but then, hardness is deliquescing but.For this, transparent solid soap of the present invention does not contain branched fatty acid salt and unsaturated fatty acid salt substantially, and hardness is good.And, owing to do not contain branched fatty acid salt and unsaturated fatty acid salt, also outstanding aspect smell stable.In addition, so-called " not containing branched fatty acid salt and unsaturated fatty acid salt substantially " be meant that the content in transparent solid soap composition of the present invention is below the 2 quality %.
Transparent solid soap of the present invention, the lipid acid that constitutes (A) composition consists of: (1) carbonatoms be 12 lipid acid with carbonatoms be 16 and carbonatoms be that the mass ratio of the total amount of 18 lipid acid (is represented the quality ratio as lipid acid.Below the record of quality of relevant (A) composition, be based on the record of quality of the lipid acid of formation (A) composition) (C 12: (C 16+ C 18)) be 30: 70～60: 40 scope; (2) carbonatoms is that 12 lipid acid and carbonatoms are the mass ratio (C of 14 lipid acid 12: C 14) be 20: 80～80: 20 scope; And (3) carbonatoms is that 12 lipid acid and carbonatoms are that the total amount of 14 lipid acid is 14～22 quality % with respect to the total amount of solid soap.
The present invention has carried out the control of (1)～(3) as mentioned above to the chain length distribution of linear saturated fatty acids, thereby reaches high transparent and sufficient whipability.
In addition, so-called " constituting the lipid acid of (A) composition " is meant that at (A) composition be under the situation of salt, and this salt is used in the alkali and preceding lipid acid.
About above-mentioned prerequisite (1), carbonatoms is 12 lipid acid (lauric acid) and carbonatoms is that 16 (palmitinic acids) and carbonatoms are more preferably 30: 70～50: 50 the scope of mass ratio of the total amount of 18 lipid acid (stearic acid).
About above-mentioned prerequisite (2), carbonatoms is that 12 lipid acid and carbonatoms are more preferably 30: 70～80: 20 the scope of mass ratio of 14 lipid acid (tetradecanoic acid), more preferably 50: 50～75: 25 scope.
About above-mentioned prerequisite (3), carbonatoms is that 12 lipid acid and carbonatoms are total amount 16～22 quality % more preferably of 14 lipid acid.
The content of the lipid acid of the formation in the transparent solid soap of the present invention (A) composition with respect to the total amount of solid soap, is preferably the scope of 20～40 quality %, is preferably the scope of 25～35 quality % especially.If in this scope, then to suppress the balance of (B) composition, (C) composition of giving stability in hard water and then neutralizing agent and the necessary water of dissolving of fatty acid soaps crystallization effect good with having of following detailed description, thereby can reach purpose of the present invention effectively.
In the present invention, above-mentioned linear saturated fatty acids becomes salt by normally used alkali neutralization, for example, can enumerate an alkali metal salt, ammonium salt, alkanolamine, alkaline amino acid salt etc.Wherein, an alkali metal salts such as particular certain cancers or sylvite, special particular certain cancers.The addition of neutralizing agent is almost in 100% and the amount of lipid acid as used herein.
(B) composition in the transparent solid soap of the present invention contains and is selected from nonionogenic tenside, amphoterics, is liquid polyalcohols and the material more than a kind or 2 kinds in the carbohydrate at normal temperatures.These compositions are by cooling, when solidifying the manufacturing solid soap, have the function that suppresses the fatty acid soaps crystallization, give the composition of the transparency.
As nonionogenic tenside, for example, can enumerate that to have the average addition mole number of oxyethane be 6～150, be preferably 10～50 polyoxyethylene groups compound as hydrophilic group.In such compound, can enumerate that to have carbonatoms be 10～18, be preferably 12～14 alkyl as hydrophobic group, and HLB value (Hydrophile Lipophile Balance) is more than 8, be preferably the compound more than 10.
For example, as preference, can enumerate HLB and be 14 polyoxyethylene (20) sorbitan laurate (RHEODOL SUPER TW-L120 (trade name), Kao Corp makes), HLB is 13 polyoxyethylene (20) octyl group lauryl ether (EMULGEN2020G (trade name), Kao Corp makes, or EMALEX OD-20 (trade name), NIHON EMULSION Co., Ltd. makes), HLB is 13.7 polyethylene glycol monolaurate (EMANON 1112 (trade name), Kao Corp makes), HLB is 16.9 polyoxyethylene (23) lauryl ether (EMULGEN 123P (trade name), Kao Corp makes), HLB is 18 polyoxyethylene (a 30) lauryl ether (EMALEX730 (trade name), NIHON EMULSION Co., Ltd. makes) etc.In addition, HLB value described herein is the goods catalogue value that manufacturers provides.
As amphoterics, can enumerate betaine type amphoteric surfactant, amino acid type surfactant, Imidazoline Surfactants, amine oxide type tensio-active agent etc., from improving the viewpoint of the whipability and the transparency, preferred betaine type amphoteric surfactant.
The content of above-mentioned nonionogenic tenside in transparent solid soap is preferably 3～15 quality %.If content is in this scope, both can give the good transparency, can obtain hardness again as the appropriateness of solid soap.From same viewpoint, the content of nonionogenic tenside is the scope of 5～10 quality % more preferably.
And, the content of above-mentioned amphoterics in transparent solid soap, based on the same reason of nonionogenic tenside, be preferably the scope of 0～10 quality %, more preferably the scope of 0～5 quality %.
And situation with above-mentioned nonionogenic tenside and amphoterics under, the content of these tensio-active agents in transparent solid soap with both quantifiers that closes, is preferably the scope of 5～20 quality %.If content is in this scope, can give full play to effect as tensio-active agent, obtain hardness as the appropriateness of solid soap.From same viewpoint, and situation with above-mentioned nonionogenic tenside and amphoterics under, more preferably nonionogenic tenside and the amphoterics content in transparent solid soap is the scope of 5～15 quality %.
So-called " being liquid polyalcohols at normal temperatures " is meant the polyalcohols that comprises polyvalent alcohol and glycol ethers, is preferably glycols (glycol or glycol ethers) especially.Particularly, from the viewpoint of the transparency of the solid soap that obtains with improve the viewpoint of whipability, preferred isoamyl glycol (IOB:2.00), dipropylene glycol (IOB:1.83), ethoxydiglycol (diethylene glycol monoethyl ether) are (IOB:1.63), 1,3 butylene glycol IOB such as (IOB:2.50) is the polyalcohols below 3.
In addition, so-called " IOB (Inorganic Organic Balance) " is that expression is based on organic conceptional diagram (Tentianmu, the prediction of organic compound and organic conceptional diagram, the field Vol.11 of chemistry, No.10 (1957) 719-725) inorganic value of obtaining and the ratio of organic value, (I) obtains according to following formula.
IOB=inorganic value/organic value (I)
Be preferably the scope of 5～50 quality % at normal temperatures for the liquid content of polyalcohols in transparent solid soap.If content in this scope, is improving whipability, the transparency of resulting solid soap, and the crystallization by suppressing carbohydrate and to reduce the aspect that the viscosity of the soap composition when making boosts productivity be favourable.And, keep and also be favourable aspect whipability improves in the hardness of resulting solid soap.From same viewpoint, be the content scope of 10～40 quality % more preferably of liquid polyalcohols at normal temperatures.In addition, in the scope that does not influence the transparency and whipability, can be the polyvalent alcohol more than 3 also with propylene glycol (IOB:3.33), glycerine IOB such as (IOB:5.00).
As carbohydrate, preferably be the solid carbohydrate at normal temperatures, the monose of 4～6 carbon sugar such as preferred N.F,USP MANNITOL, Xylitol, maltose alcohol, erythritol, Sorbitol Powder or the sugar alcohol of disaccharides.Carbohydrate has the effect of good restraining crystallization in soap, give solid soap very high transparence.And, preferred because have the effect that improves whipability.Other carbohydrates, in the manufacturing processed of solid soap in and in the operation, also have the painted effect that is difficult to produce that caramel reaction is caused.These carbohydrates can use a kind or make up more than 2 kinds and to use separately.
The content of these carbohydrates in transparent solid soap is preferably the scope of 10～30 quality %.If content in this scope, can be brought into play above-mentioned additive effect, make solid soap inside in the preservation process be difficult to produce crystallization, do not influence the transparency.From same viewpoint, the content of carbohydrate is the scope of 10～20 quality % more preferably.
The compound of enumerating as (B) composition in the transparent solid soap of the present invention has the function of giving this solid soap transparency, and has all different character.Therefore,, except the transparence degree, bring into play the characteristic of each compound, control whipability, hardness, usability etc. jointly, thereby obtain suitably the suitableeest cooperation as required by making up these different types of compounds.(B) composition is preferably under the normal temperature and is liquid polyalcohols and surfactant-based combination, and perhaps for normal temperature is the liquid polyalcohols and the combination of carbohydrate down, further preferred normal temperature is the combination of the polyalcohols of liquid state, surfactant-based and carbohydrate down.
Above-mentioned (A) composition (as the quality of lipid acid) and (B) mass ratio of composition be 30: 70～45: 55 scope.If mass ratio is in this scope, solid soap can obtain the sufficient transparency, and in use, it is abundant that the whipability of solid soap becomes.From same viewpoint, (A) composition (as the quality of lipid acid) and (B) mass ratio of composition be preferably 40: 60～45: 55 scope.
The content of (B) composition in the transparent solid soap of the present invention is preferably the scope of 20～50 quality %, is preferably the scope of 30～45 quality % especially.If content in this scope, with (C) composition of above-mentioned (A) composition, following detailed description and then neutralizing agent and to dissolve the balance of necessary Purified Water good, thereby can reach purpose of the present invention effectively.
Transparent solid soap of the present invention contains inorganic salt (C), and its content is 0.5～5 quality %.If content in this scope, can improve stability in hard water,, and obtain the sufficient transparency even for example also can give sufficient whipability for the hard water of 4 degree.From same viewpoint, its content is preferably 1～3 quality %.
Kind as inorganic salt is not particularly limited, and can enumerate sodium-chlor, Repone K, sodium sulfate, yellow soda ash, SODIUMNITRATE etc.Wherein, from obtaining sufficient hardness, the viewpoint of acquisition and processing ease is set out easily, preferred sodium-chlor.
And transparent solid soap of the present invention in order to improve whipability and the foam dispersion under the low temperature, can contain the anion surfactant of non-soap kind.As this anion surfactant, can use alkanal base isethionate, polyoxyethylene alkyl ether sulfate salt, N-acyl methyl taurine salt, N-acyl sarcosinate, N-acylated amino acid salt, (two) alkyl sulfo succinate, MAP etc.
And transparent solid soap of the present invention for the stabilization of smell, can contain the organic acid except lipid acid.As this organic acid, can enumerate lactic acid, gluconic acid etc.The content of organic acid in transparent solid soap is preferably 0.01～3 quality %, more preferably 0.1～1 quality %.
In addition, transparent solid soap of the present invention contains (D) water, as being used to make above-mentioned neccessary composition and as required and other one-tenth that use are divided into the medium of uniform melt.Its content is about 10～40 quality %.In addition, because soap composition of the present invention solidifies rapidly, in just making good transparent solid soap product, also contain this water with roughly the same ratio.
And transparent solid soap of the present invention except mentioned component, can also contain employed composition in existing framed soap kui, for example, and antiseptic-germicide, spices, pigment, dyestuff, finish, low thorn stimulator etc.At this, as antiseptic-germicide, can enumerate triclosan or triclocarban (Trichlorocarbanilide) etc., its content is generally 0.01～2 quality %.And the content of spices, pigment or dyestuff etc. is generally 0.02～5 quality %.As finish, can enumerate lanolin, paraffin, Vaseline, tetradecanoic acid isopropyl esters etc., general content is 0.05～5 quality %.
The manufacture method of transparent solid soap of the present invention, be to contain above-mentioned (A) composition, (B) composition, (C) composition and (D) the soap compound of the molten state of composition, injection has the mould of the shaping usefulness of shape of product, the transparent solid soap that is configured as this shape of product is made in cooling, curing.
Though water-soluble soap is the meeting salting-out crystallizationization in the presence of inorganic salt, under the situation that constitutes the such composition ratio of the present invention, lipid acid becomes metastable state and does not carry out crystallization.But, under this state, under the situation that (B) composition exists, in the refrigerative process, will impel (A) composition at (B) composition periphery crystallization quickly.Therefore, think the crystallization miniaturization of (A) composition, can make the high solid soap of the transparency.Therefore, can make at short notice.And the result is can access very fine tight structure, thereby can solve expansion and not enough these problems of hardness for water.
In existing frame method for making, must carry out the soap composition of molten state is injected the mould frame, the operation that makes ethanol or water volatilize and enhance the transparency, and need about 2 months time so that its curing, but in manufacture method of the present invention, do not need these operations.
It is 12～18 linear saturated fatty acids that in accordance with regulations amount is mixed carbonatoms, be selected from nonionogenic tenside, amphoterics, be liquid polyalcohols and the material more than a kind or 2 kinds (B) in the carbohydrate, inorganic salt (C) and water (D), heating for dissolving at normal temperatures.Add with the water-reducible alkali of part, in and lipid acid.Confirm to have become homogeneous transparent.Perhaps, in accordance with regulations amount is mixed carbonatoms and is 12～18 linear saturated fatty acids, is selected from nonionogenic tenside, amphoterics and is material more than a kind or 2 kinds (B) and water (D) in the liquid polyalcohols, heating for dissolving at normal temperatures.Add with the water-reducible alkali of part, in and lipid acid.Confirm to have become homogeneous transparent, add again with portion water dissolved inorganic salt (C) and carbohydrate (B), uniform dissolution.
In the modulation process of the soap composition of molten state, under heating, mix the composition of regulation, its Heating temperature is generally about 60～90 ℃.
Modulation forms soap composition and can be shaped by the same mould frame of enough and existing framed soap kui, and still, the soap composition among the present invention is characterised in that, only just can obtain solid soap in the very short time by cooling, curing.
Therefore,, cool off, solidify and be shaped, therefore can obtain the transparent solid soap of desired shape at short notice owing to the fused soap composition directly can be injected the mould of shaping usefulness with the finished product shape.In addition, about cooling, set time, by forming and the suitably decisions such as use level of use level, transparentizing agent of lipid acid.And, according to size and loading level, the outside air temperature of the material of shaping dies and temperature, mould, have no-cooling-water etc. to change, usually about 10～60 minutes.
Embodiment
Embodiment 1
The lipid acid of being put down in writing in the mixture table 1, at normal temperatures for liquid polyalcohols and tensio-active agent, make it 80 ℃ of following fusions.48% aqueous sodium hydroxide solution to slowly dripping wherein that water dilution with 5 quality % forms neutralizes.Become transparent evenly after, in this neutralization solution, add additionally mixed sodium-chlor, carbohydrate and Purified Water, and be heated to 80 ℃ of solution that form, mixed 15 minutes down at 80 ℃ again, obtain the soap composition of molten state.
Use resulting soap composition, estimate according to following method.The result is displayed in Table 1.
(evaluation method)
1. transparent
The soap composition 5mL of molten state is injected into balance weighing disk (Balance Dish) under 80 ℃ (in 35 * 35 * 10mm), place the cooling back and take out the cured solid soap.Be approximately 20 minutes in room temperature (25 ℃) placement cooling down, required time of curing.This solid soap is placed on the lining paper of black photo, adopts the colored colour-difference meter (MINOLTA CR-200) of Konica Minolta Holdings Co., Ltd. to measure.With L *a *b *In L *Value (lightness) is estimated the transparency.If L *Value is below 38, and then the transparency is good, sees through solid soap and can see literal below 5 pounds, and it is good to be judged as the transparency.In addition, the L that measures according to same procedure of commercially available frame system transparent soap *Value is 33, the L of commercially available solid soap (for example, Kao Corp " White ", White-opalescent) *Value is 70.
2. whipability
Use MgCl 2Modulate the 4 degree hard water that form, obtain 1% aqueous solution of above-mentioned soap composition.This aqueous solution 5g is packed in the graduated cylinder of 200mL, under 30 ℃, measures the foamy height (mm) after the vibration 50 times.In addition, the bubble amount that this test produced is carried out sensory evaluation by the personnel of professional group, concerns as follows: if more than 20mm, it is good then to be judged as whipability.
More than the 25mm: have 9～10 to think that whipability is good among 10 of the personnel of professional group.
20mm is above and less than 25mm: have 6～8 to think that whipability is good among 10 of the personnel of professional group.
More than the 15mm and less than there being 2～5 to think that whipability is good in the 20mm:10 name.
Less than think in the 15mm:10 name whipability good be below 1.
3. the hardness of solid soap
In the mould that the soap composition injection molding of molten state is used, cooling, solidify after, from mould, take out solid soap.Cooling, required time of curing are about 60 minutes.For the thick central part of 15mm of the solid soap after solidifying, adopt sclerometer (polymer gauge Co., Ltd. makes, ASKER durometer Type C, JIS K 7312) to measure the hardness of solid soap.In addition, (for example, Kao Corp " White ") hardness is 85～95 to the general soap that records according to this method, and the hardness of soft soap (for example, Kao Corp " PURE WHIP SOAP ") is 70～75.Therefore, if this hardness is about 70～95, judge that then it has the appropriate hardness as solid soap.
4. curing speed
Behind the mould that will use with the solid soap injection molding that " the 3. hardness of solid soap " is made equally, when being determined at 25 ℃ of following air coolings and beginning, after 30 minutes, after 60 minutes and the hardness after 90 minutes.With the hardness in the above-mentioned moment, there was not the A that counts of variation since 30 minutes to 60 minutes, there was not the B that counts of variation since 60 minutes to 90 minutes, there was not the C that counts of variation since 90 minutes to 120 minutes.For efficient manufacturing, preferably in 60 minutes, solidify.
5. the stability of smell
From mould, take out cooling, the solid soap after solidifying, after the foil sealing, rest in the thermostatic bath of 5 ℃ and 50 ℃.From thermostatic bath, take out after 1 month, the variation of smell is judged by the professional group of smell.Will be under 5 ℃ and 50 ℃, smell have only slight variations and do not produce foreign odor, the situation in tolerable limit is counted A, change greatly but do not produce foreign odor, the situation in tolerable limit is counted B, change big and produce foreign odor, the situation that exceeds tolerable limit counts C.
6. be difficult to expand
From mould, take out cooling, the solid soap after solidifying, place it on the soap ware, rest in 40 ℃, the thermostatic bath of 75%RH.Take out 2 week backs, judges from the outward appearance of the solid soap of firm taking-up.The situation that outward appearance does not have to change is counted A, and the situation that will occur slight expansion in allowed band is counted B, counts C with expansion and solid soap occurring attached to the situation on the soap ware.
Embodiment 2～5 and comparative example 1～9
Except using the composition shown in the table 1, operation obtains soap composition similarly to Example 1.The result who adopts method similarly to Example 1 to estimate is displayed in Table 1.
Table 1
Embodiment 6～15
Operate similarly to Example 1, obtain the soap composition of following composition.Show good similarly to Example 1 evaluation result.
Embodiment 6
Transparent soap quality %
Lauric acid (C 12) 2.8
Tetradecanoic acid (C 14) 11.2
Palmitinic acid (C 16) 0.9
Stearic acid (C 18) 0.9
48% sodium hydroxide 5.8
Isoamyl glycol 10
Xylitol 9.3
Sodium-chlor 1.1
The Purified Water surplus
Add up to 100
Embodiment 7
Transparent soap quality %
Lauric acid (C 12) 2.8
Tetradecanoic acid (C 14) 11.2
Palmitinic acid (C 16) 3.5
Stearic acid (C 18) 3
48% sodium hydroxide 7.2
Isoamyl glycol 10
Propylene glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
Dodecyl hydroxyl sulfo betaine 7.8
Sodium-chlor 1.2
The Purified Water surplus
Add up to 100
Embodiment 8
Transparent soap quality %
Lauric acid (C 12) 2.8
Tetradecanoic acid (C 14) 11.2
Palmitinic acid (C 16) 3.5
Stearic acid (C 18) 3
48% sodium hydroxide 7.2
Isoamyl glycol 10
Xylitol 10
POE (20) sorbitan laurate 5
Sodium-chlor 1.4
The Purified Water surplus
Add up to 100
Embodiment 9
Transparent soap quality %
Lauric acid (C 12) 11.2
Tetradecanoic acid (C 14) 2.8
Palmitinic acid (C 16) 6.1
Stearic acid (C 18) 6
48% sodium hydroxide 9.4
Isoamyl glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
Dodecyl hydroxyl sulfo betaine 1.9
Sodium-chlor 1.3
The Purified Water surplus
Add up to 100
Embodiment 10
Transparent soap quality %
Lauric acid (C 12) 11.2
Tetradecanoic acid (C 14) 2.8
Palmitinic acid (C 16) 6.1
Stearic acid (C 18) 6
48% sodium hydroxide 9.4
Isoamyl glycol 10
Propylene glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
POE (20) octyl group lauryl ether 10.9
Dodecyl hydroxyl sulfo betaine 10
Sodium-chlor 1.2
The Purified Water surplus
Add up to 100
Embodiment 11
Transparent soap quality %
Lauric acid (C 12) 5.5
Tetradecanoic acid (C 14) 16.5
Palmitinic acid (C 16) 6.1
Stearic acid (C 18) 6
48% sodium hydroxide 9.4
Isoamyl glycol 10
Propylene glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
POE (20) octyl group lauryl ether 10.9
Dodecyl hydroxyl sulfo betaine 10
Sodium-chlor 1.2
The Purified Water surplus
Add up to 100
Embodiment 12
Transparent soap quality %
Lauric acid (C 12) 5.5
Tetradecanoic acid (C 14) 16.5
Palmitinic acid (C 16) 6
Stearic acid (C 18) 6.8
48% sodium hydroxide 12.2
Isoamyl glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
POE (20) octyl group lauryl ether 10
Dodecyl hydroxyl sulfo betaine 2
Sodium-chlor 1.3
The Purified Water surplus
Add up to 100
Embodiment 13
Transparent soap quality %
Lauric acid (C 12) 16.5
Tetradecanoic acid (C 14) 5.5
Palmitinic acid (C 16) 5.5
Stearic acid (C 18) 5.5
48% sodium hydroxide 12.2
Isoamyl glycol 10
Propylene glycol 3
Xylitol 10
POE (20) sorbitan laurate 10
POE (20) octyl group lauryl ether 10
Sodium-chlor 1.5
The Purified Water surplus
Add up to 100
Embodiment 14
Transparent soap quality %
Lauric acid (C 12) 4
Tetradecanoic acid (C 14) 12
Palmitinic acid (C 16) 4.5
Stearic acid (C 18) 4.5
48% sodium hydroxide 8.8
Isoamyl glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
Sodium-chlor 1.3
The Purified Water surplus
Add up to 100
Embodiment 15
Transparent soap quality %
Lauric acid (C 12) 9
Tetradecanoic acid (C 14) 9
Palmitinic acid (C 16) 8
Stearic acid (C 18) 6
48% sodium hydroxide 12.2
Isoamyl glycol 10
Xylitol 10
POE (20) sorbitan laurate 10
Dodecyl hydroxyl sulfo betaine 2.7
Sodium-chlor 1.4
The Purified Water surplus
Add up to 100
Utilizability on the industry
According to the present invention, can access such transparent solid soap, its transparency is high, foaming characteristic Well, particularly good to the foaming characteristic of hard water, have the appropriate hardness as the solid soap, no The problem that exists smell to worsen along with passage of time. And, in the manufacturing of this transparent solid soap In, utilize injection molding method etc., the soap composition of dissolving is injected the mould of desired shape, Only just can make easily and in short time by cooling, therefore, can make on high production rate ground Be configured as the product of desirable shape.

Claims (5)

1. a transparent solid soap is characterized in that,
Be that to contain carbonatoms be 12～18 linear saturated fatty acids and/or its salt (A), and do not contain the transparent solid soap of branched fatty acid salt and unsaturated fatty acid salt substantially,
Contain and be selected from nonionogenic tenside, amphoterics, be liquid polyalcohols and the material more than a kind or 2 kinds (B) in the carbohydrate, inorganic salt (C) and water (D) at normal temperatures,
Total amount with respect to solid soap, the content that constitutes the lipid acid of (A) composition is 20～40 quality %, constitute the lipid acid of (A) composition and (B) mass ratio of composition be 30: 70～45: 55, (C) content of composition is 0.5～5 quality %, and (D) content of composition is surplus, carbonatoms in constituting the lipid acid of (A) composition be 12 lipid acid and carbonatoms be 16 and carbonatoms be that the mass ratio of the total amount of 18 lipid acid is 30: 70～60: 40 a scope, carbonatoms is that 12 lipid acid and carbonatoms are that the mass ratio of 14 lipid acid is 20: 80～80: 20 a scope, and carbonatoms is that 12 lipid acid and carbonatoms are that the total amount of 14 lipid acid is 14～22 quality % with respect to the total amount of solid soap.
2. transparent solid soap according to claim 1 is characterized in that,
The content of described (B) composition is 20～50 quality % with respect to the total amount of solid soap.
3. transparent solid soap according to claim 1 and 2 is characterized in that,
The content of described (D) composition is 10～40 quality % with respect to the total amount of solid soap.
4. the manufacture method of a transparent solid soap is characterized in that,
Be be 12～18 linear saturated fatty acids and/or its salt (A) by containing carbonatoms, be selected from nonionogenic tenside, amphoterics, make the method for transparent solid soap for the soap composition of liquid polyalcohols and the material more than a kind or 2 kinds (B) in the carbohydrate, inorganic salt (C) and water (D) at normal temperatures
Described soap composition is: the fatty acid content that constitutes described (A) composition is 20～40 quality % with respect to the total amount of soap composition, carbonatoms in constituting the lipid acid of (A) composition be 12 lipid acid and carbonatoms be 16 and carbonatoms be that the mass ratio of the total amount of 18 lipid acid is 30: 70～60: 40 a scope, carbonatoms is that 12 lipid acid and carbonatoms are that the mass ratio of 14 lipid acid is 20: 80～80: 20 a scope, carbonatoms is that 12 lipid acid and carbonatoms are that the total amount of 14 lipid acid is 14～22 quality % with respect to the total amount of soap composition, the mass ratio that constitutes the lipid acid of described (A) composition and described (B) composition is 30: 70～45: 55 a scope, (C) content of composition is 0.5～5 quality %, and (D) content of composition is surplus
Described manufacture method is: after becoming described soap composition heating and melting evenly, and in the mould that injection molding is used, cooling, curing, the solid soap that obtains being shaped.
5. the manufacture method of transparent solid soap according to claim 4 is characterized in that,
The content of described (D) composition is 10～40 quality % with respect to the total amount of soap composition.
CN200880018983.4A 2007-06-06 2008-06-05 Transparent solid soap Expired - Fee Related CN101679924B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2007150543 2007-06-06
JP150543/2007 2007-06-06
PCT/JP2008/060393 WO2008149951A1 (en) 2007-06-06 2008-06-05 Transparent solid soap

Publications (2)

Publication Number Publication Date
CN101679924A true CN101679924A (en) 2010-03-24
CN101679924B CN101679924B (en) 2013-06-05

Family

ID=40093761

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880018983.4A Expired - Fee Related CN101679924B (en) 2007-06-06 2008-06-05 Transparent solid soap

Country Status (5)

Country Link
EP (1) EP2154234B1 (en)
JP (1) JP5342809B2 (en)
CN (1) CN101679924B (en)
MY (1) MY154388A (en)
WO (1) WO2008149951A1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013131307A1 (en) * 2012-03-07 2013-09-12 南京华狮化工有限公司 Transparent beauty soap composition
CN103562398A (en) * 2011-03-22 2014-02-05 Opx生物工艺学公司 Microbial production of chemical products and related compositions, methods and systems
CN104017674A (en) * 2014-06-20 2014-09-03 益海（东莞）油化工业有限公司 Anti-freezing soap grain and production method thereof
CN106029860A (en) * 2014-02-28 2016-10-12 乌瑞斯化妆品有限公司 Soap composition
CN106473948A (en) * 2015-09-02 2017-03-08 花王株式会社 Cleanser compositions
US10047383B2 (en) 2013-03-15 2018-08-14 Cargill, Incorporated Bioproduction of chemicals
US10337038B2 (en) 2013-07-19 2019-07-02 Cargill, Incorporated Microorganisms and methods for the production of fatty acids and fatty acid derived products
US10465213B2 (en) 2012-08-10 2019-11-05 Cargill, Incorporated Microorganisms and methods for the production of fatty acids and fatty acid derived products
US10494654B2 (en) 2014-09-02 2019-12-03 Cargill, Incorporated Production of fatty acids esters
US11345938B2 (en) 2017-02-02 2022-05-31 Cargill, Incorporated Genetically modified cells that produce C6-C10 fatty acid derivatives
US11408013B2 (en) 2013-07-19 2022-08-09 Cargill, Incorporated Microorganisms and methods for the production of fatty acids and fatty acid derived products

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5342809B2 (en) * 2007-06-06 2013-11-13 花王株式会社 Transparent soap bar
CN102459553A (en) * 2009-06-04 2012-05-16 花王株式会社 Framed soap composition
JP5525837B2 (en) * 2010-01-28 2014-06-18 株式会社ピーアンドピーエフ Solid cleaning composition
EA024736B1 (en) * 2011-04-06 2016-10-31 Юнилевер Нв Transparent soap comprising fluorescer
MX360835B (en) * 2014-05-08 2018-11-20 Unilever Nv Transparent extruded toilet soap.
JP6365225B2 (en) * 2014-10-21 2018-08-01 日油株式会社 Solid soap
EP3328981B1 (en) 2015-07-29 2022-01-26 Unilever Global IP Limited Cleansing composition with improved availability of benefit agent
JP6649910B2 (en) * 2017-03-02 2020-02-19 花王株式会社 Skin cleansing composition

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3793214A (en) * 1971-10-22 1974-02-19 Avon Prod Inc Transparent soap composition
JPH0813999B2 (en) * 1987-05-30 1996-02-14 株式会社愛麗 Transparent soap composition
FR2707300B1 (en) * 1993-07-09 1995-09-22 Oreal Solid, transparent soap composition, based on fatty acid salts containing isoprene glycol.
JP4920816B2 (en) * 2000-09-01 2012-04-18 資生堂ホネケーキ工業株式会社 Transparent solid detergent composition
DE60003116T2 (en) * 2000-09-01 2004-04-08 Shiseido Co. Ltd. Transparent solid detergent
JP2002080896A (en) * 2000-09-06 2002-03-22 P & P F:Kk Transparent bar soap composition
JP3609768B2 (en) * 2000-12-25 2005-01-12 資生堂ホネケーキ工業株式会社 Transparent bar soap composition
JP4578144B2 (en) * 2004-04-27 2010-11-10 花王株式会社 Method for producing soap composition
JP5342809B2 (en) * 2007-06-06 2013-11-13 花王株式会社 Transparent soap bar

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103562398A (en) * 2011-03-22 2014-02-05 Opx生物工艺学公司 Microbial production of chemical products and related compositions, methods and systems
WO2013131307A1 (en) * 2012-03-07 2013-09-12 南京华狮化工有限公司 Transparent beauty soap composition
US10465213B2 (en) 2012-08-10 2019-11-05 Cargill, Incorporated Microorganisms and methods for the production of fatty acids and fatty acid derived products
US10047383B2 (en) 2013-03-15 2018-08-14 Cargill, Incorporated Bioproduction of chemicals
US10155937B2 (en) 2013-03-15 2018-12-18 Cargill, Incorporated Acetyl-CoA carboxylases
US10815473B2 (en) 2013-03-15 2020-10-27 Cargill, Incorporated Acetyl-CoA carboxylases
US10337038B2 (en) 2013-07-19 2019-07-02 Cargill, Incorporated Microorganisms and methods for the production of fatty acids and fatty acid derived products
US11408013B2 (en) 2013-07-19 2022-08-09 Cargill, Incorporated Microorganisms and methods for the production of fatty acids and fatty acid derived products
CN106029860A (en) * 2014-02-28 2016-10-12 乌瑞斯化妆品有限公司 Soap composition
CN104017674B (en) * 2014-06-20 2017-05-17 丰益油脂化学(东莞）有限公司 Anti-freezing soap grain and production method thereof
CN104017674A (en) * 2014-06-20 2014-09-03 益海（东莞）油化工业有限公司 Anti-freezing soap grain and production method thereof
US10494654B2 (en) 2014-09-02 2019-12-03 Cargill, Incorporated Production of fatty acids esters
CN106473948A (en) * 2015-09-02 2017-03-08 花王株式会社 Cleanser compositions
CN106473948B (en) * 2015-09-02 2021-08-27 花王株式会社 Detergent composition
US11345938B2 (en) 2017-02-02 2022-05-31 Cargill, Incorporated Genetically modified cells that produce C6-C10 fatty acid derivatives

Also Published As

Publication number Publication date
MY154388A (en) 2015-06-15
WO2008149951A1 (en) 2008-12-11
EP2154234A4 (en) 2011-05-25
EP2154234B1 (en) 2014-10-15
JP2009013404A (en) 2009-01-22
CN101679924B (en) 2013-06-05
JP5342809B2 (en) 2013-11-13
EP2154234A1 (en) 2010-02-17

Similar Documents

Publication Publication Date Title
CN101679924B (en) Transparent solid soap
KR100235691B1 (en) Process for making a transparent personal cleaning bar
KR100235692B1 (en) Transparent personal cleansing bar
JP3227694B2 (en) Framed soap composition
US5529714A (en) Transparent soap formulations and methods of making same
JP5763310B2 (en) Frame kneaded soap and method for producing the same
JP3828547B2 (en) Frame kneaded soap composition
TWI598438B (en) Frame-made soap and method for making a frame-made soap
EP1445306B1 (en) Framed soap compositions
KR101460256B1 (en) The method of liquid soap
JP5577366B2 (en) Soap bar
WO1992019712A1 (en) Cast cleaning and/or deodorizing composition
JP4578144B2 (en) Method for producing soap composition
JP2003082394A (en) Flame blend transparent solid soap
JP2006045437A (en) Framed soap composition
JP5919855B2 (en) Soap bar
JP2005002255A (en) Framed soap composition
JP3616313B2 (en) Soap bar
JP2019048979A (en) Fatty acid magnesium-containing soap composition and method for producing the same
JPH11131099A (en) Composition used for transparent solid washing agent suitable for frame molding method
JP2004352997A (en) Transparent solid soap composition
JP2015199854A (en) Aliphatic acid magnesium-containing soap composition and manufacturing method therefor
JP2012087252A (en) Framed soap
JP2000309795A (en) Bar soap
JP2002080897A (en) Transparent soliddetergent composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130605

Termination date: 20170605

CF01 Termination of patent right due to non-payment of annual fee