CN101647765B - 凹凸棒海滩防晒霜 - Google Patents
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Abstract
本发明公开了一种凹凸棒海滩防晒霜，其技术方案的要点是，凹凸棒海滩防晒霜由膏状凹凸棒石粘土、橄榄油、核桃油、二甲基对氨基苯甲酸辛酯、纳米二氧化硅、纳米氧化锌、纳米金红石型钛白粉、棕榈酸异辛酯、三甲基硅烷氧基硅酸酯、超细聚乙烯醇粉、改性羧甲基羟丙基纤维素、甲基葡萄糖苷倍半硬脂酸酯(TC-SS)、甲基葡萄糖苷倍半硬脂酸酯聚氧乙烯(20)醚(TC-SS-E 20)、尼泊金甲酯、尼泊金丙酯和去离子水组成。凹凸棒海滩防晒霜质地柔软，手感好，附着力强，防水防汗性能好，在肌肤表层迅速生成一层薄膜，可以长时间反射和吸收紫外线，以防护紫外线对皮肤的伤害，凹凸棒海滩防晒霜适用于涂抹在海上作业和海滩度假者皮肤的表层。
Description
技术领域
本发明涉及化妆品，具体涉及一种凹凸棒海滩防晒霜。
背景技术
夏日海滩阳光充足，紫外线照射十分强烈，人们若长时间暴晒于阳光下会晒黑皮肤，严重者还可引起晒伤和皮肤慢性损伤，导致皮肤红斑，色素沉着，皮肤老化并形成皱纹。
在海水中游泳除了暴露在水面外的身体部分易受太阳直射外，水面还能折射或反射大量的紫外线，使皮肤受伤。皮肤长时间被阳光照射后会出现变红、变黑甚至脱皮等情况。海滩的空气也比较湿热，人们往往觉得皮肤不透气，发不出汗。
防晒剂分为物理防晒剂和化学防晒剂，物理防晒剂的优点是可以长时间反射紫外线，物理防晒剂的缺点是皮肤触感不好，太厚重，不容易涂开，会堵塞毛孔，影响肌肤呼吸，引起粉刺；化学防晒剂的成分主要是紫外线吸收剂，避免紫外线直接损伤人体的皮肤，但是化学防晒剂有一定的刺激性，可能会引起敏感肌肤的过敏现象发生。
在防晒剂中常用到纳米金红石型钛白粉和纳米氧化锌，由于纳米颗粒尺寸小，易于凝聚，影响它在水溶液中的分散性。
发明内容
本发明的目的是克服现有技术中不足之处，提供一种凹凸棒海滩防晒霜。
凹凸棒海滩防晒霜由膏状凹凸棒石粘土、橄榄油、核桃油、二甲基对氨基苯甲酸辛酯、纳米二氧化硅、纳米氧化锌、纳米金红石型钛白粉、棕榈酸异辛酯、三甲基硅烷氧基硅酸酯、超细聚乙烯醇粉、改性羧甲基羟丙基纤维素、甲基葡萄糖苷倍半硬脂酸酯(TC-SS)、甲基葡萄糖苷倍半硬脂酸酯聚氧乙烯(20)醚(TC-SS-E 20)、尼泊金甲酯、尼泊金丙酯和去离子水组成。
凹凸棒海滩防晒霜的生产方法是：配料、粉碎、搅拌、分散、溶解、均质、乳化、消泡、研磨、罐装为凹凸棒海滩防晒霜的成品。
凹凸棒石粘土是一种含水富镁纳米级多孔纤维状硅酸盐粘土矿物，当凹凸棒石粘土中的凹凸棒含量≥80％以上时，其比表面积较大，可达500m2/g以上，大部分的阳离子、水分子和一定大小的有机分子均可直接被吸附进孔道中，其吸水性可达150％以上。
使用凹凸棒矿造浆生产工艺，将凹凸棒石粘土中的水云母、石英、蛋白石和碳酸盐等矿物筛选去除掉，得到一种膏状凹凸棒石粘土，具有超细微粒、摩擦硬度小、无砂粒感和柔软细腻无异味的特点。
膏状凹凸棒石粘土经过高速强力搅拌，成为一种分散性、触变性和胶黏性特好的天然凝胶体，粘度高达10000mPa·s以上，附着力、吸附性能和保湿性能都得到了进一步的提高。
橄榄油含有丰富的脂溶性维生素，不饱和脂肪酸含量高达88％以上，容易被皮肤吸收，起到保湿、抗氧化、防过敏、防紫外线、抑菌等功效。
核桃油富含维生素E、叶酸、蛋白质和矿物质，核桃油是最天然的保湿因子，因为和皮肤的特性很接近，所以容易被皮肤所吸收，可保护皮肤，防止强烈日光灼伤及有害电磁波辐射和紫外线损伤，还可用于修复暴晒后的皮肤。
二甲基对氨基苯甲酸辛酯是强有力的油溶性UVB吸收剂，提供出色的防晒效果而具有较低的成本，不溶于水，具有较滑爽的润肤感觉，低嗅味。
纳米二氧化硅俗称“超微细白炭黑”，易于与化妆品其它组分配伍，无毒、无味，反射紫外能力强、稳定性好，被紫外线照射后不分解，不变色，也不会与配方中其它组分起化学反应。纳米二氧化硅加入凹凸棒海滩防晒霜中，可以在纳米级二氧化钛和纳米级氧化锌的颗粒表面形成保护层，填补其不均匀的表面，减弱颗粒之间的吸引力，降低团聚的可能性，使体系更均匀、更稳定；同时额外获得的触变性能可以帮助产品在皮肤表面均匀铺展，改善涂抹时的肤感和手感，全面提高产品性能。
纳米氧化锌是一种广谱的无机紫外线屏蔽剂，能吸收紫外线，在凹凸棒海滩防晒霜中添加氧化锌能提高其分散性、透明性和耐光性，可全面抵御紫外线对人体的伤害。
纳米金红石型钛白粉耐光性非常强，遮盖力好，当阳光照到皮肤上时，能将损害皮肤的紫外线折射、反射和散射回去，有利于减少了紫外线直接接触到人体的皮肤。
棕榈酸异辛酯对皮肤的亲和性好，具有优越的分散性和铺展性，可有效降低膏体堵塞毛孔的可能性。
三甲基硅烷氧基硅酸酯是抗水性液体硅，可作为疏水膜或防水剂，清爽性不黏腻，安全性高。
改性羧甲基羟丙基纤维素能迅速溶解于冷水或热水，具有良好的触变性性能，耐盐性和耐酸性性能优越，粘度高，增稠剂效果好，加入凹凸棒海滩防晒霜中能使膏体均匀细腻。
超细聚乙烯醇粉末易溶于水，粘度稳定，不受弱酸、弱碱或有机溶剂的影响，耐油性高，易成膜，形成的薄膜无色透明，具有良好的机械强度，表面光洁而不发粘。
甲基葡萄糖苷倍半硬脂酸酯(TC-SS)与甲基葡萄糖苷倍半硬脂酸酯聚氧乙烯(20)醚(TC-SS-E 20)是性能独特的非离子乳化剂，，TC-SS具有油包水乳化活性，而TC-SS-E 20是一种水包油乳化剂，二者合并使用，会产生高质量的乳化作用，其性能优越于其它普通乳化剂。
尼泊金甲酯具有广谱抑菌作用，对革兰氏阳性，阴性细菌，酵母菌和霉菌有很强的抑制作用，使用浓度低并且安全经济，使用有效期长。尼泊金甲酯容易与各种化学物质相配伍，尼泊金甲酯和尼泊金丙酯复配使用，以达到更佳的防腐效果。
本发明通过下述技术方案予以实现：
1、凹凸棒海滩防晒霜的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土25～65％、橄榄油1～12％、核桃油1～10％、二甲基对氨基苯甲酸辛酯1～8％、纳米二氧化硅0.5～8％、纳米氧化锌0.5～6％、纳米金红石型钛白粉0.5～5％、棕榈酸异辛酯0.5～5％、三甲基硅烷氧基硅酸酯0.05～5％、超细聚乙烯醇0.05～5％、改性羧甲基羟丙基纤维素0.05～5％、甲基葡萄糖苷倍半硬脂酸酯0.05～1％、甲基葡萄糖苷倍半硬脂酸酯聚氧乙烯(20)醚0.05～1％、尼泊金甲酯0.01～0.5％、尼泊金丙酯0.01～0.5％和去离子水1～35％。
2、凹凸棒海滩防晒霜的生产方法是：(1)将凹凸棒海滩防晒霜的配料加入搅拌机内进行低速搅拌混合均匀后，输入粉碎打浆机中进行粉碎打浆为凹凸棒海滩防晒霜的混合物；(2)将步骤(1)获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.005毫米；(3)将步骤(2)获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；(4)将步骤(3)获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒海滩防晒霜的成品。
所述膏状凹凸棒石粘土的生产工艺：将凹凸棒矿输入搅拌机内搅拌，经挤出机挤压成片状后，再次输入搅拌机内搅拌，经挤出机挤压成片状后自然晾晒，晾干的凹凸棒矿输送到原料池中浸泡，用气泵冲翻，沉淀后放出浸泡水，筛去杂质，输入半成品池中，重新加水浸泡，用气泵冲翻，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，即为膏状凹凸棒石粘土。
本生产工艺是采用由本发明人于2004年1月6日申请的“凹凸棒矿造浆生产工艺”，中国专利授权公告号：CN1287965C，授权公告日：2006年12月6日。
所述膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土25～45％，水55～75％。
二氧化硅、氧化锌和金红石型钛白粉添加在凹凸棒海滩防晒霜中，经过搅拌、分散、均质、乳化、消泡和研磨后能够长期静置不沉降，有利于提高凹凸棒海滩防晒霜的分散性和稳定性。
凹凸棒海滩防晒霜质地柔软，手感好，附着力强，防水防汗性能好，在肌肤表层迅速生成一层薄膜，可以长时间反射和吸收紫外线，以防护紫外线对皮肤的伤害，减少皮肤色素的加深，延缓皮肤衰老，防止皮肤干裂，增强皮肤弹性。做到既防止皮肤晒黑，又保护皮肤免受其他外界因素的伤害。
凹凸棒海滩防晒霜性质温和，不会堵塞毛孔，无不良反应，具有抗菌消炎、抗过敏的疗肤功效。
凹凸棒海滩防晒霜适用于涂抹在海上作业和海滩度假者皮肤的表层。
具体实施方式
下面结合实施例对本发明作进一步的描述：
1、凹凸棒海滩防晒霜的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土42％、橄榄油6％、核桃油5％、二甲基对氨基苯甲酸辛酯5％、纳米二氧化硅4％、纳米氧化锌3％、纳米金红石型钛白粉2％、棕榈酸异辛酯2％、三甲基硅烷氧基硅酸酯1％、超细聚乙烯醇0.5％、改性羧甲基羟丙基纤维素0.5％、甲基葡萄糖苷倍半硬脂酸酯0.5％、甲基葡萄糖苷倍半硬脂酸酯聚氧乙烯(20)醚0.4％、尼泊金甲酯0.06％、尼泊金丙酯0.04％和去离子水28％。
2、凹凸棒海滩防晒霜的生产方法是：(1)将凹凸棒海滩防晒霜的配料加入搅拌机内进行低速搅拌混合均匀后，输入粉碎打浆机中进行粉碎打浆为凹凸棒海滩防晒霜的混合物；(2)将步骤(1)获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.005毫米；(3)将步骤(2)获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；(4)将步骤(3)获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒海滩防晒霜的成品。
所述膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土40％，水60％。
Claims (1)
1.一种凹凸棒海滩防晒霜，其特征在于，凹凸棒海滩防晒霜的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土25～65％、橄榄油1～12％、核桃油1～10％、二甲基对氨基苯甲酸辛酯1～8％、纳米二氧化硅0.5～8％、纳米氧化锌0.5～6％、纳米金红石型钛白粉0.5～5％、棕榈酸异辛酯0.5～5％、三甲基硅烷氧基硅酸酯0.05～5％、超细聚乙烯醇0.05～5％、改性羧甲基羟丙基纤维素0.05～5％、甲基葡萄糖苷倍半硬脂酸酯0.05～1％、甲基葡萄糖苷倍半硬脂酸酯聚氧乙烯(20)醚0.05～1％、尼泊金甲酯0.01～0.5％、尼泊金丙酯0.01～0.5％和去离子水1～35％；
所述膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土25～45％，水55～75％；
所述凹凸棒海滩防晒霜的生产方法是：(1)将凹凸棒海滩防晒霜的配料加入搅拌机内进行低速搅拌混合均匀后，输入粉碎打浆机中进行粉碎打浆为凹凸棒海滩防晒霜的混合物；(2)将步骤(1)获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.005毫米；(3)将步骤(2)获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；(4)将步骤(3)获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒海滩防晒霜的成品；
所述膏状凹凸棒石粘土的生产工艺：将凹凸棒矿输入搅拌机内搅拌，经挤出机挤压成片状后，再次输入搅拌机内搅拌，经挤出机挤压成片状后自然晾晒，晾干的凹凸棒矿输送到原料池中浸泡，用气泵冲翻，沉淀后放出浸泡水，筛去杂质，输入半成品池中，重新加水浸泡，用气泵冲翻，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，即为膏状凹凸棒石粘土。
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| CN101367960A (zh) * | 2008-09-12 | 2009-02-18 | 江苏工业学院 | 一种纳米凹凸棒石/二氧化硅复合材料的制备方法 |
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