CN101646560A - The composite of directly decoratable, its manufacture method and uses thereof - Google Patents
The composite of directly decoratable, its manufacture method and uses thereof Download PDFInfo
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- CN101646560A CN101646560A CN200880005756A CN200880005756A CN101646560A CN 101646560 A CN101646560 A CN 101646560A CN 200880005756 A CN200880005756 A CN 200880005756A CN 200880005756 A CN200880005756 A CN 200880005756A CN 101646560 A CN101646560 A CN 101646560A
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- fabric face
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/02—Cellular or porous
- B32B2305/024—Honeycomb
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/07—Parts immersed or impregnated in a matrix
- B32B2305/076—Prepregs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/10—Fibres of continuous length
- B32B2305/18—Fabrics, textiles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/744—Non-slip, anti-slip
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
- B32B2315/18—Plaster
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/02—Cork
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/12—Paper, e.g. cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/16—Wood, e.g. woodboard, fibreboard, woodchips
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- Laminated Bodies (AREA)
Abstract
A kind of composite, it comprises: a) carrier, b) at least one fabric face structure, it is laminated at least one side in two sides of described carrier, this fabric face structure has the B-stage binding agent of at least a final sclerosis and can choose wantonly and is provided at least a functional material, it is characterized in that, be equipped with the surface quality that one or more side had of the composite of described fabric face structure to make described side directly to be printed or japanning.These composites are particularly suitable as material and are used for upholstery, are used for liner, construct and are used to making furniture and similar products.
Description
Technical field
The present invention relates to the composite of directly decoratable and/or printing, it is particularly suitable as material and is used for upholstery, is used for liner, constructs and is used to making furniture and similar products.
Background technology
Composite substitutes traditional building material just more and more as building material, and must be suitable for multiple application.Therefore, on the one hand, need sufficient mechanical stability and on the other hand, good machinability and low weight are essential.Therefore, improve the never interruption of effort of existing composite.
Therefore, be known that described wood materials is by the timber of pulverizing and use binding agent to make with wood materials and other combination of materials.For this reason, usually described two kinds of materials are carried out lamination and form composite.Select and make up described material and can improve mechanical performance, and can realize for example reduction of weight simultaneously.
In process, often experience further decoration step, for example japanning or the printing of aforementioned composite.This is being for treating that processed lip-deep flatness and allowable limit have proposed high requirement, therefore, for make subsequently decoration fully may, describedly treat that processed surface must carry out preliminary treatment in the mode of costliness, and often will carry out several.
The composite based on wood materials and adhesive-bonded fabric that is strengthened by " B " stage binding agent is disclosed in WO2006/031522.Described basic adhesive-bonded fabric is for example at US-A-5, and is open in 837,620, US-A-303,207 and US-A-6,331,339.
In WO2006/031522, disclose and other additive can have been added in described binding agent or the described adhesive-bonded fabric, but do not provided about subsequently the application and the more detailed data of processing.
Therefore, need to seek following composite, it can experience further decoration step, for example japanning or printing, and need not and will treat that processed surface carries out often will carrying out preliminary treatment for several times in the mode of costliness.
In addition, need to seek following composite, it has above-mentioned character, and these materials can be decorated degree as much as possible with known processing method and system.
Summary of the invention
The composite that themes as of the present invention, it comprises:
1. carrier,
2. at least one fabric face structure, it is laminated at least one side in two sides of described carrier, and this fabric face structure has the B-stage binding agent of at least a final sclerosis and its can be chosen wantonly and be provided at least a functional material,
It is characterized in that be equipped with the surface quality that one or more side had of the composite of described fabric face structure to make described side can directly be printed or japanning or static japanning, described japanning is undertaken by the powder japanning.
Composite of the present invention has the extraordinary surface quality of representing with varied in thickness being equipped with on one or more sides of described fabric face structure.The varied in thickness of composite of the present invention is preferably less than 0.1mm, preferably less than 0.01mm.
Known composite materials can be printed and/or japanning, but treats that processed surface must be at first by suitable means preparation.For this reason usually with described surface by the abrasion measure, for example grind and smoothing.Composite of the present invention is useful at this.To such an extent as to be equipped with described fabric face structure carrier the side surface quality so good its have direct machinability.Therefore, can save described abrasion measure.
Other pre-measure is to treating that processed surface provides with so-called prime coat in the printing of composite or japanning.Filler, especially water soluble filler can be understood that prime coat or primer material on meaning of the present invention.Have low surface quality if treat processed surface, one or more layers then thick relatively prime coat is necessary.
Have only by these measures (grinding and/or the priming paint coating) and could print and/or the described surface of japanning.
By means of composite of the present invention, these measures (priming paint coating) can be omitted fully or at least in part.This means the remarkable simplification in the printing/japanning of composite, particularly comprise under the situation of carrier of wood materials at composite.
Depend on described japanning or printing technology, also so-called priming coat be applied on one or more sides for the treatment of processed composite that described side is equipped with described fabric face structure.Priming coat that these apply separately or that repeatedly apply has formed compacting supporter (pressuresupport) and has been known in the prior art.Depend on application, described priming coat can also contain pigment.
According to the carrier that a) uses preferably wood materials, paper, cork, cardboard, mineral board and/or so-called cellular thing.Cellular thing is to have the construction package that three-dimensional strengthens structure, the feasible structure (honeybee honeycomb) of described three-dimensional enhancing structure owing to them, and under the situation of low weight, may have superpower stability and intensity simultaneously.Cellular thing has so been used a period of time in many applications, especially also in the structure field or in the furniture as the inside reinforce of plate shape element.
Described wood materials is by different wood substance grain shape things are mixed the wood materials of making plate shape or microscler wood shavings shape (strand-shaped) with binding agent natural and/or that synthesize in the hot pressing process.The used wood materials of the present invention preferably includes glued board or laminate, the wood floral material, particularly particieboard and OSB (oriented structure chipboard), wood fiber material, particularly porous wood-fiber board, opening spread wood-fiber board (open diffusionwood fiber board), hard (high density) wood-fiber board (HDF) and middle density wood-fiber board (MDF), and Arboform.But Arboform is the thermoplasticity material processed of lignin and other wooden composition.
In addition, carrier of the present invention comprises the material of following material and thermoplastic adhesive, and described material is wood fiber material, cellulose fibre, natural fiber or their mixture, and the ratio of described binding agent is greater than 15wt%.Described material is preferably strengthened by glass fibre, basalt fibre or synthetic fibers.
Described paper is preferably the paper based on following material, and described material is natural, synthetic, mineral or ceramic fiber or the mixture that also has these fiber types.
Described cardboard is preferably the cardboard based on natural and/or synthetic fiber, and it also comprises the mixture of mineral and/or ceramic fibre and these fiber types.
Described mineral board is preferably commercially available mineral cardboard, and it all has pressboard coating in both sides, plaster board, ceramic beaverboard, cement plate or lime plate.These plates can be chosen wantonly with natural and/or synthetic fiber reinforcement, and it can also comprise fiber mineral and/or pottery.Described fortifying fibre can long fibre, the form of monofilament exists or exist as staple fiber.
Except described material, described carrier can also be made up of cork or other vegetable material.
The per unit area weight that is included in the carrier in the described composite is relevant with final application, and without any particular restriction.
According to the used fabric face structure of step b) is all structures of being made by fiber, and produces fabric face by means of the shaping surface technology by this structure.
The fabric face structure of waiting to be provided to described B-stage binding agent can also be used under the situation of binding agent not having basically, and described binding agent is Chemical Felter particularly.
Yet,, also can introduce binding agent and/or can use known needle-punching method in order to ensure required intensity in the further processing of described surface texture.Except the possibility that the machinery that is for example undertaken by calendering or acupuncture strengthens, especially also mention waterpower acupuncture at this.Chemical and/or thermoplastic binding agent is suitable as binding agent.
Yet, wait that the fabric face structure optimization that is provided to described B-stage binding agent strengthens in advance with Chemical Felter.Used binding agent can be identical or different, but must be selected from can with the compatible binder system of described B-stage binding agent.The addition of binding agent is 25wt% to the maximum, preferred 10wt% or lower; Minimum content is 0.5wt%, and preferred minimum is 1wt%.
Described fiber forming material is preferably the fiber of natural fiber and/or synthetic or natural polymer, ceramic fibre, and mineral fibres or glass fibre, the form that they also can mixture is used.Fabric face is considered to fabric, lay thing (layings), braid, knitted fabric and adhesive-bonded fabric, preferred adhesive-bonded fabric.
The fabric face of mineral and ceramic fibre is alumina silicate fibre, ceramic fibre, dolomite fiber, wollastonite fibre or vulcanie fiber, preferred basalt fibre, diabase fiber and/or melaphyre fiber, especially basalt fibre.Diabase and melaphyre are combined and are appointed as paleobasalts and diabase also through being often specified to greenstone.
Described mineral fibres adhesive-bonded fabric can form by long fibre or by staple fiber, and described long fibre is the endless fiber.The average length of the staple fiber in the adhesive-bonded fabric of used in the present invention mineral fibres is 5 to 120mm, and preferred 10 to 90mm.In other embodiments of the present invention, described mineral fibres adhesive-bonded fabric contains the mixture of circular fiber and staple fiber.The fiber diameter of described mineral fibres is 5 to 30 μ m, preferred 8 to 24 μ m, especially preferred 8 to 15 μ m.
The per unit area weight of the fabric face structure of mineral fibres is 15 to 500g/m
2, preferred 40 to 250g/m
2, wherein these data relate to the surface texture that does not have binding agent.
Under the situation of the fabric face of glass fibre, preferred especially adhesive-bonded fabric.They are by long fibre or by the staple fiber structure, described long fibre is the endless fiber.The average length of described staple fiber is 5 to 120mm, and preferred 10 to 90mm.In the preferred embodiment of the invention, described fiberglass nonwoven contains the mixture of circular fiber and staple fiber.
The average diameter of described glass fibre is 5 to 30 μ m, preferred 8 to 24 μ m, especially preferred 10 to 21 μ m.
Except above-mentioned diameter, even can also use so-called glass microfiber.The preferred average diameter of described glass microfiber is 0.1 to 5 μ m.The microfibre that forms described fabric face also may reside in the mixture with other fiber, described other fiber preferred glass fibers.In addition, the bedded structure of microfibre and glass fibre also is possible.
The per unit area weight of the fabric face structure of glass fibre is 15 to 500g/m
2, preferred 40 to 250g/m
2, wherein these data relate to the surface texture that does not have binding agent.
Suitable glass fibre comprises those that made by A-glass, E-glass, S-glass, T-glass or R-glass.
Described fabric face can be according to any known method manufacturing.For the glass adhesive-bonded fabric, preferred dry method or wet-laying method.
In the fabric face of the fiber of synthetic polymer, preferred adhesive-bonded fabric, especially so-called spunbond cloth (spun bonds), the i.e. spunbond adhesive-bonded fabric for preparing by the deposition melt-spun long fibre that tangles.But they are made up of the annular synthetic fibers of the polymeric material of melt-spun.The suitable polymers material is for example polyamide, for example polyhexamethylene two adipamides, polycaprolactam, the polyamide of armaticity or part armaticity (" aromatic polyamides "), fatty polyamide, nylon for example, the part armaticity or the polyester of armaticity fully, polyphenylene sulfide (PPS), polymer with ether and ketone groups, for example polyether-ketone (PEK) and polyether-ether-ketone (PEEK), polyolefin, for example polyethylene or polypropylene, cellulose or polybenzimidazoles.Except above-mentioned synthetic polymer, even spun those polymer also are suitable from solution.
But described spunbond adhesive-bonded fabric preferably is made up of the polyester of melt-spun.In principle, the polyester material that is suitable for making fiber of all known types all is considered to polyester material.Particularly preferred polyester contains the PETG (PET) of at least 95 moles of %, especially those unmodified PET.
If composite of the present invention should have fire retardation in addition, advantageously they are spun from the polyester with fire-retardant mode modification.The polyester of these fire-retardant mode modifications is known.
The long stapled independent fiber number of polyester in described spunbond adhesive-bonded fabric is 1 to 16 dtex, preferred 2 to 10 dtexs.
In other embodiments of the present invention, described spunbond adhesive-bonded fabric can also be the binder fibre fabric by the sclerosis of melt binding agent, and it contains carrier fibre and merges fiber.Described carrier fibre and fusion fiber can form the property polymer derived from any thermoplastic fibre.These spunbond adhesive-bonded fabrics by melt binding agent sclerosis are described in EP-A-0, in 446,822 and EP-A-0,590,629.
Except annular long fibre (spun-bond process), described fabric face can also be by staple fiber or staple fiber and annular long stapled mixture structure.The independent fiber number of the staple fiber in described adhesive-bonded fabric is 1 to 16 dtex, preferred 2 to 10 dtexs.Fibre length is 1 to 100mm, and preferred 2 to 500mm, and especially preferred 2 to 30mm.Described fabric face structure can also be by the fibrous structure of different materials, can obtain special performances.
Construct the long fibre of described binder fibre fabric and/or cross section or other shape that staple fiber can have actual circle, for example cross section of dumb-bell shape, kidney shape, triangle or trilobal or leafy shape.Even can use fiber and the two components or the multicomponent fibre of hollow.In addition, described fusion fiber can use with the form of two components or multicomponent fibre.
Form additive agent modified that the fiber of described fabric face structure can be by routine, for example by the antistatic additive modification, described antistatic additive is carbon black for example.
The per unit area weight of the fabric face structure of the fiber of synthetic polymer is 10 to 500g/m
2, preferred 20 to 250g/m
2
Described natural fiber is a string, is derived from the fiber of grass, straw, timber, bamboo, reed and bast, perhaps zoogenous fiber.String is a total notion and representative species subbundle, for example cotton, kapok or poplar fine hair, bast fiber is bamboo fiber, hemp, jute, flax or ramie, hart fiber for example, for example sisal hemp or abaca, perhaps fruit fiber, for example coconut.Zoogenous fiber is wool, animal hair, feather and silk.
The per unit area weight of the fabric face structure of natural fiber is 20 to 500g/m
2, preferred 40 to 250g/m
2
The fabric face of the fiber of natural polymer is a cellulose fibre, for example viscose glue or vegetalitas or animal protein fiber.
In the fabric face of cellulose fibre, adhesive-bonded fabric is particularly preferred.They are by long fibre and/or staple fiber structure, and described long fibre is the endless fiber.The average length of described staple fiber is 1 to 25mm, and preferred 2 to 5mm.
The average diameter of described cellulose fibre is 5 to 50 μ m, preferred 15 to 30 μ m.
If composite of the present invention will be decorated by powder japanning or static, pending composite should have sufficient electric conductivity.Maybe advantageously contained pigment or the particle that is useful on raising electric conductivity according to a) used carrier for this, described pigment or particle have brought such raising.
Above-mentioned electric conductivity can also present as the functional material in the fabric face structure that is equipped with B-stage binding agent.For this reason, these functional materials can mix with described B-stage binding agent and apply, and perhaps make to be equipped with the fabric construction of described B-stage binding agent to be equipped with described functional material.Above-mentioned material is metallic particles normally, carbon black or conduction organic resin, for example phenol resin or inorganic or organic salt.These additives are open in DE-A-3639816.In addition even can use the salt that is disclosed among DE-A-10232874 and the EP-A-1659146, especially alkali metal or alkali salt, for example lithium nitrate and sodium nitrate.Yet above-mentioned material should be compatible with other material.
On at least one side of described carrier, apply according to b) the fabric face structure of using comprises the binding agent of at least a B-of being in stage condition.B-stage binding agent is meant only partial reinforment or sclerosis, and the binding agent that still can for example experience final sclerosis by hot post processing.These B-stage binding agents are described in detail in US-A-5, in 837,620, US-A-6,303,207 and US-A-6,331,339.The B-stage binding agent that is disclosed in wherein also is the theme of this specification.B stage binding agent is preferably the binding agent based on furfuryl alcohol formaldehyde, phenol formaldehyde (PF), melamino-formaldehyde, ureaformaldehyde and their mixture.Preferably, water-based system receives publicity.Other preferred binder system is not for containing the binding agent of formaldehyde.B-stage binding agent is characterised in that they can experience the multistage sclerosis, and promptly they still have enough cementations after one or many at first hardens, so they can be used to further processing.
These binding agents in a step, under about 350 temperature, are hardened after adding catalyst usually.
In order to form the described B-stage, optional with the sclerosis after adding catalyst of these binding agents.The amount of hardening catalyst is for being up to 10wt%, preferred 1 to 10wt% (with respect to total binder content).For example, ammonium nitrate and organic aromatic acid, for example maleic acid and p-methyl benzenesulfonic acid are suitable as hardening catalyst, because it makes described B-stage condition more promptly reach.Except ammonium nitrate, outside maleic acid and the p-methyl benzenesulfonic acid, all materials that are suitable as hardening catalyst all have suitable acid function.In order to reach the described B-stage, will under the temperature action that does not produce sclerosis fully, carry out drying with the fabric face structure of binder-impregnated.Necessary technological parameter depends on selected binder system.
Lowest temperature can be by selecting the duration or being affected by adding more or stronger acid hardening catalyst.
Described B-stage binding agent is applied at b) in can carry out by means of all known methods on the fabric face structure of appointment.Except being sprayed on it, flooding and being pressed into wherein, described binding agent can also be by applying or applying by the swivel nozzle head.
Other preferable methods is to apply described B-stage binding agent by applying foam.In the applying of foam, the binding agent foam generates by means of the blowing agent in foam mixture, promptly is applied on the described adhesive-bonded fabric by suitable coating aggregate.At this, described applying can also be undertaken by the swivel nozzle head.
In may foam coating, basically without limits about described blowing agent for the binding agent in B-stage.Preferred blowing agent is for joining ammonium stearate or the succinate in the described binding agent with the amount of 1wt% to 5wt% under the dry state.In addition, if desired, the catalyst mix of having described is arrived wherein.The solid content of described foam is at least 40%, preferably at least 50%.
The technology that foam applies makes that technology controlling and process can be very flexible, and makes it possible to achieve multiple different product property.Except be penetrated into the length of penetration in the described fabric face as the described foam of the conciliation of target, described binding agent charging and viscosity can change in grace period.In addition, foam apply the advantage that provides very big aspect technology controlling and process, especially at dipping or apply aspect the constancy of solid content in the described fabric face process, and required compatibility demand in described binding agent upper surface manufacturing process.
According to b) functional material that uses can for example apply simultaneously as mixture or apply as component separately, perhaps apply before or after applying described binding agent with described B-stage binding agent.If described B-stage binding agent applies method by foam and applies, so advantageously with described foam, perhaps be distributed in and apply described functional material in the described foam, perhaps described functional material is applied on the foam of still new system.
Except above-mentioned feature, composite of the present invention can even comprise the further decoration that carries out with functional material.For this purpose, use the functional material on the top that is applied to the fabric face structure that is equipped with described B-stage binding agent, perhaps be incorporated into the functional material in the described fabric face structure.
The preferred flame-proofing agent of functional material of the present invention is used to control the material of electrostatic charge, and the pigment of organic or inorganic is particularly with pigment, conductive pigment or the particle of look.
In the variant of described method, add other binding agent so that described functional material is fixed on the described fabric face structure.Preferably select and the identical binding agent that in described fabric face structure, exists (B-stage binding agent) at this.The content of functional material is by the decision of subsequently purposes.
Described flame-proofing agent is inorganic flame-proofing agent, organophosphor flame-proofing agent, nitrogen base flame-proofing agent or intumescent flame-proofing agent.Can also use (bromination with chlorination) flame-proofing agent of halogenation, but because their risk assessment and more not preferred.The example of the flame-proofing agent of these halogenations is Polybrominated diphenyl ether, ten BDE for example, tetrabromobisphenol A and HBCD (HBCD).
Be used to increase and/or control the reagent of electric conductivity, the performance that can obtain anti-electrostatic effect and/or can regulate the powder japanning by use.These reagent are conventional conductive particles.Suitable material is a conductive carbon, for example carbon black, graphite and CNT (C nanotube), the particle of the conductive plastics of fiber or metal or metal component.Except these, can also use the electric conductivity organic resin, phenolic resins for example, perhaps inorganic or organic salt.These additives are known in DE-A-3639816.In addition, even can also use disclosed salt, especially alkali metal or alkali salt in DE-A-10232874 and EP-A-1659146, for example lithium nitrate and sodium nitrate.Yet above-mentioned material should can be compatible with other material.
The application that is used to improve and/or controls the reagent of described electric conductivity has reduced the sheet resistance of composite of the present invention.This makes to have and is up to 10
10Ω (ohm) preferably is up to 10
8The composite of the present invention of the sheet resistance of Ω (ohm) is suitable for the powder japanning very much.
In other embodiments, composite of the present invention can even also comprise other layer and auxiliary layer, and these layers should promote or support directly compacting.These other layer and auxiliary layers for example are the layers of priming coat and/or adhesion promoters and/or so-called adhesion bridge.Preferably, only apply basal layer as the compacting supporter, its form is one or more other layer and auxiliary layers.These layers are necessary as assisting only.Because the surface quality of composite of the present invention, so-called prime coat can fully or at least in part omit.In addition, can reduce the layer thickness of described priming coat and the cost that therefore can also reduce material.In addition, avoided expensive multilayer priming coat and reduced total expense.
Other theme of the present invention is a method of making composite of the present invention, and this method comprises following measure:
A) provide carrier,
B) the fabric face structure is applied at least one surface of described carrier, wherein said fabric face structure has the binding agent of at least a B-of being in stage condition, and at least a functional material of optional introducing,
C) under the effect of pressure and heat, lamination makes the binding agent in the described B of being in stage reach its final sclerosis according to the structure that step c) obtains,
D) optional will be at least a for direct printing or directly needed other layer and/or one or more layers auxiliary layer of japanning be applied on one or more sides of the composite that is equipped with described fabric face structure.
In step c), under the effect of pressure and heat, to carry out as follows carrying out lamination with obtain structure according to step b), described mode reaches its final sclerosis for the binding agent that exists with the B stage.Described lamination can be by discontinuous or compacting or undertaken by roll-in continuously.According to used B-stage binding agent, these parameters of pressure, temperature and the time of staying are selected.Because described surface quality should be selected the surface of pressing element or roller as follows, described mode is for can keep described allowable limit.
In variant, applying the fabric face structure can even carry out according to step b) in the manufacture process of described carrier.In other words, replace carrier final in step a), up in step a), just forming described carrier.
The compacting of the carrier that forms is carried out with the fabric face structure that is equipped with, and described fabric face structure correspondingly is introduced in pressing element and/or the drying equipment that is used for described carrier.Making carrier-adhesive-bonded fabric composite can continuous or discrete mode carry out.
In variant, the fabric face structure that applies according to step b) can comprise the decoration with functional material.
The layer that applies according to step d) is other layer and auxiliary layer, and it should make direct compacting oversimplify or support directly compacting, and layer that this is other and auxiliary layer be priming coat and/or adhesion promoters or so-called adhesion bridge layer for example.Preferably, only priming coat and/or adhesion promoters are applied as the compacting supporter, its form is one or more layers other layer and auxiliary layer.These layers are necessary as assisting only.Because the surface quality of composite of the present invention, so-called prime coat can directly or at least in part omit.In addition, can reduce the layer thickness of described priming coat and the cost that therefore can also reduce described material.In addition, avoided expensive multilayer priming coat and reduced total expense.
The applying and dry undertaken of layer that in step d) these are other and/or auxiliary layer by known technology.
With the condition that is configured to of composite of the present invention, can obtain and utilize multiple special function:
Barrier layer between carrier and skin stops H
2O and other solvent
Electric conductivity
Adhesion promoter between carrier and priming coat
When being used for direct typography, reduce described layer structure
Improve impact strength (charpy impact)
Omit other grinding technics.
The direct printing of wood materials needs the multi-ply construction on surface to be printed usually.In addition, except one or more prime coats (priming coat), one or more priming coats that can directly print thereon then are necessary.At this, directly be printed on one or even a plurality of independent print steps in carry out.Coated outside makes described system complete.In order to obtain suitable surface quality and to be used to prevent diffusion process and to improve the barrier layer character of press quality, described multi-ply construction is necessary.
Application according to the fabric face of the B-of containing stage binding agent of the present invention has produced excellent surface quality.Simultaneously, may produce needed barrier layer character, therefore it make that the direct printing of oversimplifying becomes possibility.Therefore the application of fabric face of the present invention makes and is reduced by at least one deck prime coat and/or is reduced by at least one deck priming coat, perhaps makes to substitute these layers fully, and particularly described prime coat becomes possibility.Prime coat can preferably omit by fabric face of the present invention fully.Can also choose the quantity that reduces needed priming coat wantonly.
When using conductive additive, fabric face of the present invention also can carry out japanning by means of the powder japanning.In addition, can also use static japanning method, itself otherwise need not other means be impossible.
Impact strength can significantly rise owing to the mechanical performance of fabric face of the present invention.
Because the special nature of the fabric face of lamination, can reduce or avoid the necessary post processing in described surface fully.Usually necessary is, particularly in the manufacturing of MDF, removes skin by means of process of lapping, the soft formation that destroys owing to manufacture method.This step can be omitted when using fabric face of the present invention, perhaps reduces cost at least.
Other theme of the present invention is the purposes of composite of the present invention, and described composite comprises:
A) carrier,
B) at least one fabric face structure, it is applied at least one side in two sides of described carrier, and this surface texture has the B-stage binding agent of at least a final sclerosis,
Described purposes applies with paper tinsel printing or japanning for being used for japanning, perhaps is used for printing, and it directly carries out on the side that the described fabric face structure of the usefulness of composite applies.
Notion " directly " is meant that described surface needn't experience any mechanical post-treatments before printing, japanning or coated foils, particularly how to denude post processing without successively holding.Decoration with prime coat or priming coat is not precluded within outward, preferably composite of the present invention is handled under the situation that does not apply prime coat.If the decoration with prime coat (filler) is omitted, auxiliary layer, for example priming coat and/or adhesion promoters layer or adhesion bridge layer still can be applied in, it has especially brought following process better to adhere, described process is japanning, uses the coating of paper tinsel printing or japanning, or prints on described surface.
Described printing is undertaken by known technology.Particularly ink-jet of suitable printing technique, silk screen and/or digital printed.Powder coated also can be undertaken by known technology.According to selected system, carry out the drying of printed layers or powder bed.
Composite of the present invention for example is used in particular for furniture, wall covering, ceiling covering and floor covering at printing, japanning or after applying as building material after incrustation.
Because choose wantonly after decorating with protective layer, the high surface quality of composite of the present invention can also be used in particular for furniture, wall covering, ceiling covering and floor covering directly as building material.Preferred situation is that described carrier has had required decorative appearance.
Therefore, composite printing or japanning is the other theme of the present invention, and described composite comprises:
A) carrier,
B) at least one fabric face structure, it is applied at least one side in two sides of described carrier, and this surface texture has the B-stage binding agent of at least a final sclerosis,
C) optionally at least aly be present in the described carrier and/or the functional material in the described fabric face,
D) priming coat that on side, applies in described fabric face structure of Ren Xuan one or more layers away from described carrier,
E) layer of one deck lacquer or printing and/or one deck paper tinsel printing or japanning at least,
F) Ren Xuan other layer, it is used to protect the layer of described lacquer or printing,
It is characterized in that, will be according to e) layer be applied directly on the described fabric face structure, wherein according to e) layer and described fabric face or according to c) and according to d) between the priming coat that applies on the described fabric face structure, do not use prime coat.
Be used to protect the layer of described enamelled coating or printed layers to be generally for example lacquer of powder paints, cover lacquer or transparency lacquer, preferred scratch-resistant lacquer, its protection is not subjected to mechanical influence or prevents that UV is aging.
Other theme of the present invention is to be used to print or the method for japanning composite, it is characterized in that described composite is directly printed or japanning, and on described fabric face, perhaps at described fabric face with according to d) to choose wantonly between the priming coat that applies and do not use prime coat, described composite comprises:
A) carrier,
B) at least one fabric face structure, it is applied at least one side in two sides of described carrier, and this surface texture comprises the B-stage binding agent of at least a final sclerosis,
C) optionally at least aly be present in the described carrier and/or the functional material in the described fabric face,
D) priming coat that on side, applies in described fabric face structure of Ren Xuan one or more layers away from described carrier.
Furniture, wall covering, ceiling covering and the floor covering that adopts composite manufacturing of the present invention also is theme of the present invention.
Claims (46)
1. composite, it comprises:
A) carrier,
B) at least one fabric face structure, it is laminated at least one side in two sides of described carrier, and this fabric face structure has the B-stage binding agent of at least a final sclerosis and can choose wantonly and is provided at least a functional material,
It is characterized in that, be equipped with the surface quality that one or more side had of the composite of described fabric face structure to make described side directly to be printed or japanning.
2. composite according to claim 1 is characterized in that, the surface quality of the composite on one or more sides of the composite that is equipped with described fabric face structure is represented with varied in thickness, for less than 0.1mm.
3. composite according to claim 1 and 2 is characterized in that, described carrier is wood materials, paper, cork, cardboard, mineral board and/or cellular thing.
4. composite according to claim 3 is characterized in that, described wood materials is the wood materials of wood shavings shape plate shape or microscler.
5. composite according to claim 4, it is characterized in that, described wood materials is a glued board, laminate, the wood floral material, preferred particieboard and OSB (oriented structure chipboard), wood fiber material, preferred porous wood-fiber board, opening diffusion wood-fiber board, hard (high density) wood-fiber board (HDF) and middle density wood-fiber board (MDF), and Arboform.
6. composite according to claim 1 and 2, it is characterized in that, described carrier is the material of following material and thermoplastic adhesive, and described material is wood fiber material, cellulose fibre, natural fiber or their mixture, and the amount of wherein said binding agent is greater than 15wt%.
7. composite according to claim 3 is characterized in that described paper and cardboard are based on the material of following material, and described material is natural, synthetic, mineral or the fiber of pottery or the mixture of these fiber types.
8. composite according to claim 3, it is characterized in that, described mineral board is the plate that all has pressboard coating two sides, especially plaster board, ceramic beaverboard, cement plate or lime plate, it is optional with natural and/or synthetic fiber reinforcement, and wherein said fiber natural and/or that synthesize can also comprise fiber mineral and/or pottery.
9. composite according to claim 1 and 2 is characterized in that, described fabric face structure is fabric, lay thing, braid, knitted fabric and/or adhesive-bonded fabric.
10. according to claim 1,2 or 9 described composites, it is characterized in that, described fabric face structure is that fiber, ceramic fibre, mineral fibres or the glass fibre by natural fiber and/or synthetic or natural polymer forms, and wherein these fibers can also be with the form use of mixture.
11., it is characterized in that described fabric face structure is the mineral fibres of long fibre and/or staple fiber according to claim 1,2 or 9 described composites.
12. composite according to claim 11 is characterized in that, the average length of described staple fiber is 5 to 120mm.
13. composite according to claim 11 is characterized in that, the fiber diameter of described mineral fibres is 5 to 30 μ m.
14., it is characterized in that described fabric face structure is the fiberglass nonwoven of long fibre and/or staple fiber according to claim 1,2 or 9 described composites.
15. composite according to claim 14 is characterized in that, the average length of described staple fiber is 5 to 120mm.
16. composite according to claim 14 is characterized in that, the average diameter of described glass fibre is 5 to 30 μ m.
17. composite according to claim 14 is characterized in that, described fiberglass nonwoven comprises glass microfiber, and the average diameter of this glass microfiber is 0.1 to 5 μ m.
18. composite according to claim 14 is characterized in that, the per unit area weight that described fiberglass nonwoven has is 15 to 500g/m
2, wherein these data relate to the surface texture that does not have binding agent.
19. composite according to claim 14 is characterized in that, described fiberglass nonwoven is by dry method or wet-laying manufactured.
20., it is characterized in that described fabric face structure has the fiber of synthetic polymer according to claim 1,2 or 9 described composites.
21. composite according to claim 20 is characterized in that, described fabric face structure comprises adhesive-bonded fabric, particularly spunbond adhesive-bonded fabric.
22. composite according to claim 21 is characterized in that, described spunbond adhesive-bonded fabric also comprises staple fiber, preferably has independent fiber number between 1 to 16 dtex and/or the staple fiber of staple length between 1 to 100mm.
23. composite according to claim 20, it is characterized in that, described adhesive-bonded fabric comprises the fiber of following material, and described material is polyester, polyphenylene sulfide (PPS), the polymer with ether and ketone groups, polyolefin, cellulose or the polybenzimidazoles of polyamide (" aromatic polyamides "), fatty polyamide, part armaticity or the complete armaticity of polyamide, polycaprolactam, armaticity or part armaticity.
24., it is characterized in that described fabric face structure has natural fiber according to claim 1,2 or 9 described composites.
25., it is characterized in that described fabric face structure has cellulose fibre according to claim 1,2 or 9 described composites, preferred form is to have the cellulose fibre that average length is 1 to 25mm staple fiber.
26. composite according to claim 1 and 2 is characterized in that, described B-stage binding agent still can for example experience final sclerosis by hot post processing.
27. composite according to claim 26 is characterized in that, described binding agent is the binding agent based on furfuryl alcohol formaldehyde, phenol formaldehyde (PF), melamino-formaldehyde and their mixture.
28. composite according to claim 1 is characterized in that, described binding agent comprises the additive that is used to improve electric conductivity.
29. composite according to claim 1 is characterized in that, following material is used as functional material, described material is a flame-proofing agent, is used to control and/or improve the material of electrostatic charge, organic or inorganic pigment, particularly, be used to control and/or improve the material of electric conductivity with the pigment of look.
30. composite according to claim 29 is characterized in that, this composite contain the material that is useful on control and/or improves electric conductivity as functional material and according to the sheet resistance of composite of the present invention for being up to 10
10Ω (ohm).
31. composite according to claim 1 is characterized in that, this composite further comprises other layer and auxiliary layer in described fabric face structure on away from the side of described carrier.
32. composite according to claim 31 is characterized in that, these other layer and auxiliary layers are priming coat and/or adhesion promoters layer or adhesion bridge material layer.
33. composite according to claim 31 is characterized in that, these other layer and auxiliary layers are priming coats.
34. be used to make the method for composite, this method comprises following measure:
A) provide carrier,
B) the fabric face structure is applied at least one surface of described carrier, wherein said fabric face structure has the binding agent of at least a B-of being in stage condition, and at least a functional material of optional introducing,
C) under the effect of pressure and heat, lamination makes the binding agent in the described B of being in stage reach its final sclerosis according to the structure that step c) obtains,
D) optional will be at least a for direct printing or directly needed other layer and/or one or more layers auxiliary layer of japanning be applied on one or more sides of the composite that is equipped with described fabric face structure.
35. method according to claim 31 is characterized in that, is to carry out in the manufacture process of described carrier according to the fabric face structure that applies of step b).
36. be used for direct printing, japanning and/or apply described fabric face structure towards purposes away from the side of described carrier according to each described composite in the claim 1 to 33.
37. purposes according to claim 36 is characterized in that, prime coat is not applied to described fabric face structure and treats on the processed side.
38. purposes according to claim 36 is characterized in that, described fabric face structure treats that processed side must any abrasion post processing of experience.
39., it is characterized in that described printing is by ink-jet, silk screen and/or digital printed carrying out according to claim 36,37 or 38 described purposes.
40. composite printing or japanning, it comprises:
A) carrier,
B) at least one fabric face structure, it is applied at least one side in two sides of described carrier, and this fabric face structure has the B-stage binding agent of at least a final sclerosis,
C) optionally at least aly be present in the described carrier and/or the functional material in the described fabric face,
D) priming coat that on side, applies in described fabric face structure of Ren Xuan one or more layers away from described carrier,
E) layer of one deck lacquer or printing and/or one deck paper tinsel printing or japanning at least,
F) Ren Xuan other layer, it is used to protect the layer and the paper tinsel described printing or japanning of described lacquer or printing,
It is characterized in that, will be according to e) layer be applied directly on the described fabric face structure, wherein according to e) layer and described fabric face or according to c) or according to d) between the priming coat that applies on the described fabric face structure, do not use prime coat.
41., it is characterized in that the paper tinsel of described printing or described printing is by ink-jet, silk screen and/or digital printed the printing according to the described composite of claim 40.
42., it is characterized in that, according to f according to the described composite of claim 40) layer protection according to e) enamelled coating or the layer of printing prevent to be subjected to mechanical influence or prevent that UV is aging.
43. be used to print or the method for japanning composite, it is characterized in that, will comprise following a) to d) composite directly printing or japanning,
A) carrier,
B) at least one fabric face structure, it is laminated at least one side in two sides of described carrier, and this fabric face structure has the B-stage binding agent of at least a final sclerosis,
C) optionally at least aly be present in the described carrier and/or the functional material in the described fabric face,
D) priming coat that on side, applies in described fabric face structure of Ren Xuan one or more layers away from described carrier,
Wherein on the described fabric face and at described fabric face and according to d) choose wantonly between the priming coat that applies and do not use prime coat.
44., it is characterized in that after printing or japanning, applying at least, the other layer of one deck is used to protect the layer of described japanning or the layer of described printing to prevent to be subjected to mechanical influence or prevent that UV is aging according to the described method of claim 43.
45. in claim 1 to 33 and at the composite described in the claim 40 to 42 as building material, especially be used for upholstery in the furniture industry neutralization, be used to make furniture surface, wall covering, ceiling covering and floor covering and the purposes that is used as gasket material.
46. contain at least a in claim 1 to 33 and at furniture and wall, ceiling and the floor covering of the composite described in the claim 40 to 42.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007008423.6 | 2007-02-21 | ||
| DE102007008424.4 | 2007-02-21 | ||
| DE102007008423A DE102007008423A1 (en) | 2007-02-21 | 2007-02-21 | Making composite for use e.g. in furniture or floor covering, involves applying textile sheet containing a B-stage binder to one side of a support, applying functional material to the textile and then curing the binder |
| DE102007012651.6 | 2007-03-16 | ||
| DE102007028531.2 | 2007-06-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101646560A true CN101646560A (en) | 2010-02-10 |
Family
ID=39645786
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880005756A Pending CN101646560A (en) | 2007-02-21 | 2008-02-20 | The composite of directly decoratable, its manufacture method and uses thereof |
| CN200880005755A Pending CN101636265A (en) | 2007-02-21 | 2008-02-20 | New composite, their manufacture method and application thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880005755A Pending CN101636265A (en) | 2007-02-21 | 2008-02-20 | New composite, their manufacture method and application thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (2) | CN101646560A (en) |
| DE (1) | DE102007008423A1 (en) |
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| CN103397762A (en) * | 2013-08-02 | 2013-11-20 | 宁波华缘复合新材料有限公司 | Ceiling pinch plate |
| CN103717368A (en) * | 2011-07-07 | 2014-04-09 | 佛吉亚内饰系统有限公司 | Moulded part and method for producing the moulded part |
| CN109322455A (en) * | 2017-08-01 | 2019-02-12 | 尹永植 | It is formed with the thistle board of coat of plaster |
| CN114929959A (en) * | 2020-01-10 | 2022-08-19 | 安德里茨库斯特斯有限责任公司 | Composite nonwoven fabric web manufacturing method and composite nonwoven fabric web manufacturing apparatus |
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| GB2471096A (en) * | 2009-06-16 | 2010-12-22 | Eco Mats Ltd | Laminated composites based on natural materials |
| EP2380731B1 (en) * | 2010-02-26 | 2018-01-03 | Korea Institute of Energy Research | Eco-friendly incombustible biocomposite and method for preparing the same |
| DE102010018110A1 (en) * | 2010-04-24 | 2011-10-27 | Bema Invest Gmbh | Multi-layer material for use in composite construction for panels and moldings, has carrier layer of consolidated froth, which comprises two side surfaces |
| CN101987591B (en) * | 2010-08-09 | 2012-04-25 | 无锡吉兴汽车声学部件科技有限公司 | Production method of automobile trunk carpet |
| DE102011076873A1 (en) | 2011-06-01 | 2012-12-06 | Thermoplast Composite Gmbh | Support structure and component with such a support structure |
| ITMI20120906A1 (en) * | 2012-05-24 | 2013-11-25 | Luca Egidio De | CONSTRUCTION ELEMENT FOR WALLS AND WALL COVERINGS AND METHOD OF REALIZING THE ELEMENT |
| CN103507372A (en) * | 2012-06-27 | 2014-01-15 | 中国科学院高能物理研究所 | Laminated resistive plate and manufacturing method thereof |
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| CN103061473B (en) * | 2012-12-19 | 2015-08-19 | 山东安勒特生态陶瓷纤维有限公司 | The manufacturing process of refractory fibre interior wall thermal-insulating decorative plate |
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| CN103397762A (en) * | 2013-08-02 | 2013-11-20 | 宁波华缘复合新材料有限公司 | Ceiling pinch plate |
| CN109322455A (en) * | 2017-08-01 | 2019-02-12 | 尹永植 | It is formed with the thistle board of coat of plaster |
| CN114929959A (en) * | 2020-01-10 | 2022-08-19 | 安德里茨库斯特斯有限责任公司 | Composite nonwoven fabric web manufacturing method and composite nonwoven fabric web manufacturing apparatus |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN101636265A (en) | 2010-01-27 |
| DE102007008423A1 (en) | 2008-08-28 |
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Application publication date: 20100210 |