CN101643683A - Environmentally-friendly barium-free thixotropic antirust oil - Google Patents
Environmentally-friendly barium-free thixotropic antirust oil Download PDFInfo
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- CN101643683A CN101643683A CN200810012720A CN200810012720A CN101643683A CN 101643683 A CN101643683 A CN 101643683A CN 200810012720 A CN200810012720 A CN 200810012720A CN 200810012720 A CN200810012720 A CN 200810012720A CN 101643683 A CN101643683 A CN 101643683A
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Abstract
The invention discloses an environmentally-friendly barium-free thixotropic antirust oil, which is characterized by comprising the following components in percentage by weight: antirusting agent 4.0-25.0, thixotropic agent 0.1-5.0, antioxidant 0.1-3.0 and base oil 72.0-94.0. The preparation method of the environmentally-friendly barium-free thixotropic antirust oil comprises: firstly, adding the base oil into a reaction kettle, stirring the base oil, heating the base oil to 110 to 120 DEG C, adding the antirusting agent, stirring the mixture for continuous dehydration for 1 hour, and cooling the mixture to 50 to 60 DEG C; and secondly, adding the antioxidant, stirring the mixture for 3 hours at a constant temperature of 50 to 60 DEG C, adding the thixotropic agent, stirring the mixture for1 hour at 50 to 60 DEG C, cooling the resulting product to 40 DEG C, filtering the resulting product and discharging the resulting product. For obtaining antirust oil films that are insusceptible toflow and free from heavy metal barium, the antirust oil selects a proper barium-free corrosion inhibiter to ensure excellent antirust performance besides the thixotropic agent added for quickly forming stable oil films of antirust oil.
Description
Technical field
The present invention relates to a kind of slushing oil that is used for steel corrosion protection, particularly relate to a kind of have thixotropic property and not the baric element have the slushing oil of Environmental Safety, belong to field of metal surface treatment technology.
Background technology
Slushing oil is owing to have effectively, easy to use, with low cost, and it is easy and be easy to advantage such as removal, widespread use at home and abroad to be easy to constructing operation.Because the baric inhibiter is (as barium mahogany sulfonate, dinonyl naphthalene sulfonate barium) has outstanding rustless property, therefore in existing slushing oil, substantially all classify the baric inhibiter as preferred ingredient, for example, publication number is the Chinese invention patent application " a kind of electrostatic painting anticorrosive oil " that the Chinese invention patent application " a kind of preparation method of slushing oil " of CN1629264, Chinese invention patent application " manufacture method of long-acting antirust oil " that publication number is CN101144046 and publication number are CN101016497.And according to the data record, the compound of barium can cause brain and Leptomeningeal inflammatory disease thereof, and acute poisoning can cause that cessation of growth cessation, white corpuscle and RBC number reduce and content of hemoglobin reduces, but the causing death that seriously poisons.The toxicity of barium salt is by its solubleness decision, and barium sulfate is actual to be nontoxic, but bariumchloride, nitrate of baryta, barium chlorate, barium acetate, barium carbonate and barium sulphide are hypertoxic.The used oil soluble barium salt of slushing oil is an organic compound, itself is nontoxic, but it is scattered in the physical environment, can resolve into the soluble barium salt, generates toxic substance.Therefore, the slushing oil that contains the barium element all exists serious harm to environment and human body.Developed country just progressively substitutes, and the strict restriction of American-European countries is used.
In addition, in slushing oil, lubricating type slushing oil accounts for very big proportion.It has safety (flash-point height), be easy to construction, film forming has from renaturation, advantage such as removal easily.But,, cause waste, the pollution construction environment of oil plant so the shortcoming of easy trickling is arranged because its formation is oil film.
Summary of the invention
The objective of the invention is to overcome the prior art above shortcomings, improve by research, provide a kind of environmentally-friendly barium-free thixotropic antirust oil, in order to make the slushing oil oil film be difficult for trickling and not contain heavy metal barium, the present invention removes the adding thixotropic agent makes it form stable oil film fast, also selecting suitable no barium inhibiter to guarantee good rustless property, is a kind of high-performance special environmental protection and safety type slushing oil that has high technology content and be different from existing slushing oil.
The technical scheme that the present invention provides is: this environmentally-friendly barium-free thixotropic antirust oil, be characterized in its component by weight percentage ratio be:
A. rust-preventive agent 4.0～25.0,
B. thixotropic agent 0.1～5.0,
C. antioxidant 0.1～3.0,
D. base oil 72.0～94.0,
Wherein percentage composition is all in the environmentally-friendly barium-free thixotropic antirust oil gross weight.
Described component A is selected from the following substances two or more: the alkenyl succinate of petroleum sodium sulfonate, calcium mahogany sulfonate, zinc naphthenate, dodecenylsuccinic acid salt, dodecenylsuccinic acid, dodecenylsuccinic acid half ester, lanolin, sulfonation lanolin calcium soap, 17 alkenyl imidazolines, aluminum stearate, N-oleoyl sarcosine, N-oleoyl sarcosine stearylamine salt, sorbitol monooleate, benzotriazole, dodecyl benzotriazole.Preferably: the alkenyl succinate of calcium mahogany sulfonate, dodecenylsuccinic acid salt, 17 alkenyl imidazolines, N-oleoyl sarcosine, N-oleoyl sarcosine stearylamine salt, sorbitol monooleate, benzotriazole.This component preferred content is 4.0～12.0 weight %.
Described B component is for being scattered in the thixotropic agent in the oil, as machine wilkinite, hydrogenated castor oil, modified hydrogenated Viscotrol C, aerosil, double stearic acid aluminium etc.This component preferred content is 0.3～2.0 weight %.
Described component C is selected from sulfo-phosphorus alkylphenol zinc, organic boride and the phenol antioxidant one or more, as 2.6-ditertbutylparacresol, sulfo-phosphorus alkylphenol zinc.This component preferred content is 0.1～2.0 weight %.
Described component D is that 40 ℃ of viscosity are 5～30mm
2The neutral mineral oil of/s is as 25
#Transformer oil, N22 base oil, N15 base oil, or their temper, preferred: N22, N15, this component preferred content are 85.0～94.0 weight %.
The preparation method of this environmentally-friendly barium-free thixotropic antirust oil that the present invention provides is:
(1) base oil is added in the reactor, stir, heat up and be heated to 110～120 ℃;
(2) add rust-preventive agent, start stirring, continuously dehydrating at least 1 hour is cooled to 50～60 ℃;
(3) add antioxidant, 50～60 ℃ of insulated and stirred at least 3 hours;
(4) add thixotropic agent,, be cooled to 40 ℃ and filter discharging in 50～60 ℃ of stirrings at least 1 hour.
The purposes of environmentally-friendly barium-free thixotropic antirust oil of the present invention is:
1) is used for the antirust of iron and steel finished product, half-finished storage and transportation, comprises seagoing transport, also can adopt dip-coating, roller coat, brushing mode to use generally speaking; Because this product has thixotropy, few than other slushing oil tricklings, rust-preventing characteristic is good.
2) it is antirust to be used for various sheet materials such as cold-rolled steel sheet, galvanized sheet, aluminium sheet, and best using method is to adopt the electrostatic sprayer spraying, and temperature is not less than 40 ℃, and quantity for spray is adjustable, is generally 0.5-2g/m
2
Compared with prior art, the invention has the beneficial effects as follows:
1) has excellent wet-hot aging performance and good rustless properties such as salt spray resistance;
2) have the thixotropy function, can form stable oil film fast, reduce trickling at facade;
3) no barium does not contain human body and environmentally hazardous substance, belongs to environmentally friendly;
4) have high breakdown voltage, can be used for electrostatic spraying; Pre-lubrication is arranged, be used for the steel plate protection, need not additionally add lubricant, just can finish follow-up extrusion operation; Performance capable of washing is good, and oil film is easy to remove with neutrality or alkaline water-based cleaning agent.
Embodiment
Embodiment 1
| Material name | Consumption (weight %) |
| Base oil N15 | ??87.3 |
| The alkenyl succinate of 17 alkenyl imidazolines | ??3 |
| The dodecenylsuccinic acid half ester | ??5 |
| Dodecenylsuccinic acid salt | ??3.5 |
| Benzotriazole | ??0.5 |
| 2,6 ditertiary butyl p cresol | ??0.1 |
| Thixotropic agent | ??0.6 |
Base oil N15 with 87.3% adds in the reactor, stirs, and is heated to 110～120 ℃; The alkenyl succinate of 17 alkenyl imidazolines of adding 3%, 5% dodecenylsuccinic acid half ester, 3.5% dodecenylsuccinic acid salt dewatered 1 hour; Add 0.1% 2,6 ditertiary butyl p cresol, 0.5% benzotriazole, insulated and stirred 3 hours when being cooled to 50～60 ℃; The thixotropic agent of adding 0.6% disperses to stir 1 hour in 50～60 ℃, is cooled to 40 ℃ and filters dischargings.Inspection by sampling, its testing performance index is as follows:
| Project | Detected result | Test method |
| Kinematic viscosity (40 ℃) mm/2s | ??36.60 | ??GB/T11137 |
| Flash-point (opening) ℃ | ??180 | ??GB/T3536 |
| Humid heat test (the 10# steel, the A level, h) | ??720 | ??GB/T2361 |
| Salt-fog test (the 10# steel, the A level, h) | ??168 | ??SH/T0081 |
| Thixotropy, Ti | ??3.1 | Make by oneself |
| Voltage breakdown KV | ??52.0 | ??GB/T507 |
| The clanability test | Cleaning rate 96% | With reference to JB/T4323.2 |
Embodiment 2:
| Material name | Consumption (weight %) |
| Base oil N22 | ??89.3 |
| Calcium mahogany sulfonate | ??4 |
| The dodecenylsuccinic acid half ester | ??2 |
| The alkenyl succinate of 17 alkenyl imidazolines | ??3.5 |
| Sulfo-phosphorus alkylphenol zinc | ??0.2 |
| Thixotropic agent | ??1.0 |
Base oil N22 with 89.3% adds in the reactor, be heated to 110～120 ℃, the calcium mahogany sulfonate of adding 4%, dewatered 1 hour, the alkenyl succinate of 17 alkenyl imidazolines of adding 3.5%, 2% dodecenylsuccinic acid half ester when being cooled to 50～60 ℃, 0.2% sulfo-phosphorus alkylphenol zinc, insulated and stirred 3 hours.The thixotropic agent of adding 1.0% stirred 1 hour in Scattered Kettle in 50～60 ℃, was cooled to 40 ℃ and filtered dischargings, inspection by sampling.
Embodiment 3:
| Material name | Consumption (weight %) |
| Base oil N15 | ??90.3 |
| The alkenyl succinate of 17 alkenyl imidazolines | ??3 |
| The N-oleoyl sarcosine | ??3 |
| Dodecenylsuccinic acid salt | ??3 |
| 2,6 ditertiary butyl p cresol | ??0.1 |
| Thixotropic agent | ??0.6 |
Base oil N15 with 93.3% adds in the reactor, stirs, and is heated to 110～120 ℃, and the alkenyl succinate of 17 alkenyl imidazolines of adding 3%, 3% dodecenylsuccinic acid salt dewatered 1 hour; The 2,6 ditertiary butyl p cresol of adding 0.1% when being cooled to 50～60 ℃, insulated and stirred 3 hours.The thixotropic agent of adding 0.6% disperses to stir 1 hour in 50～60 ℃, is cooled to 40 ℃ and filters dischargings, inspection by sampling.
Embodiment 4:
| Material name | Consumption (weight %) |
| Base oil N22 | ??92.3 |
| Calcium mahogany sulfonate | ??4 |
| The N-oleoyl sarcosine | ??1 |
| The alkenyl succinate of 17 alkenyl imidazolines | ??2 |
| 2,6 ditertiary butyl p cresol | ??0.1 |
| Sulfo-phosphorus alkylphenol zinc | ??0.1 |
| Thixotropic agent | ??0.5 |
Base oil N22 with 92.3% adds in the reactor, stirs, and is heated to 110～120 ℃, adds 4% calcium mahogany sulfonate, 1% N-oleoyl sarcosine, dewaters 1 hour; The alkenyl succinate of 17 alkenyl imidazolines of adding 2%, 0.1% 2,6 ditertiary butyl p cresol, 0.1% sulfo-phosphorus alkylphenol zinc when being cooled to 50～60 ℃, insulated and stirred 3 hours.The thixotropic agent of adding 0.5% stirred 1 hour in Scattered Kettle in 50～60 ℃, was cooled to 40 ℃ and filtered dischargings, inspection by sampling.
Claims (6)
1, a kind of environmentally-friendly barium-free thixotropic antirust oil, it is characterized in that each component by weight percentage ratio be:
A. rust-preventive agent 4.0～25.0,
B. thixotropic agent 0.1～5.0,
C. antioxidant 0.1～3.0,
D. base oil 72.0～94.0,
Wherein percentage composition is all in the environmentally-friendly barium-free thixotropic antirust oil gross weight,
Described component A is selected from the following substances two or more: the alkenyl succinate of petroleum sodium sulfonate, calcium mahogany sulfonate, zinc naphthenate, dodecenylsuccinic acid salt, dodecenylsuccinic acid, dodecenylsuccinic acid half ester, lanolin, sulfonation lanolin calcium soap, 17 alkenyl imidazolines, aluminum stearate, N-oleoyl sarcosine, N-oleoyl sarcosine stearylamine salt, sorbitol monooleate, benzotriazole, dodecyl benzotriazole;
Described B component is to be selected from the following substances one or more: machine wilkinite, hydrogenated castor oil, modified hydrogenated Viscotrol C, aerosil, double stearic acid aluminium;
Described component C is selected from the following substances one or more: sulfo-phosphorus alkylphenol zinc, organic boride and phenol antioxidant;
Described component D is that 40 ℃ of viscosity are 5～30mm
2The neutral mineral oil of/s.
2, according to the described environmentally-friendly barium-free thixotropic antirust oil of claim 1, it is characterized in that described each component by weight the preferred value of percentage ratio be:
A. rust-preventive agent 4.0～12.0,
B. thixotropic agent 0.3～2.0,
C. antioxidant 0.1～2.0,
D. base oil 85.0～94.0.
3, according to the described environmentally-friendly barium-free thixotropic antirust oil of claim 1, it is characterized in that described component A is preferably: the alkenyl succinate of calcium mahogany sulfonate, dodecenylsuccinic acid salt, 17 alkenyl imidazolines, N-oleoyl sarcosine, N-oleoyl sarcosine stearylamine salt, sorbitol monooleate, benzotriazole.
4, according to the described environmentally-friendly barium-free thixotropic antirust oil of claim 1, it is characterized in that described component C is preferably: 2.6-ditertbutylparacresol, sulfo-phosphorus alkylphenol zinc.
5,, it is characterized in that described component D is preferably N22 base oil, N15 base oil according to the described environmentally-friendly barium-free thixotropic antirust oil of claim 1.
6,, it is characterized in that including following steps according to the preparation method of the described environmentally-friendly barium-free thixotropic antirust oil of claim 1:
(1) base oil is added in the reactor, stir, heat up and be heated to 110～120 ℃;
(2) add rust-preventive agent, start stirring, continuously dehydrating at least 1 hour is cooled to 50～60 ℃;
(3) add antioxidant, 50～60 ℃ of insulated and stirred at least 3 hours;
(4) add thixotropic agent,, be cooled to 40 ℃ and filter discharging in 50～60 ℃ of stirrings at least 1 hour.
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