CN103911206A - Electrostatic spraying anti-rust oil free of barium and sulfonate - Google Patents
Electrostatic spraying anti-rust oil free of barium and sulfonate Download PDFInfo
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- CN103911206A CN103911206A CN201410168119.XA CN201410168119A CN103911206A CN 103911206 A CN103911206 A CN 103911206A CN 201410168119 A CN201410168119 A CN 201410168119A CN 103911206 A CN103911206 A CN 103911206A
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Abstract
The invention discloses electrostatic spraying anti-rust oil free of barium and sulfonate. The electrostatic spraying anti-rust oil is characterized by comprising the following components by weight percent: 80-90% of No.15 machine oil, 2-10% of zinc naphthenate, 1-6% of N-oleoyl sarcosine octadecylamine, 2-10% of dodecenylsuccinic acid, and 1-5% of 2,6-butylated hydroxytoluene. The anti-rust oil disclosed by the invention is free of a strong pungent smell, does not contain barium or sulfonate, is healthy and environment-friendly, and has excellent anti-rust property, stable performance and good lubricating property.
Description
Technical field
The present invention relates to guard technology field, concrete refer to a kind of without barium without sulfonate electrostatic painting anticorrosive oil.
Background technology
The automobile developing rapidly, especially Car Manufacturing and household appliances manufacturing, not only require mechanical property and the surface quality of cold-rolled steel sheet to reach corresponding standard, and the slushing oil that requires product surface coating is coated with oil mass in the time of 0.5～2.0g/m2, must there is good rust-preventing characteristic, rust removability, stampability and the consistency with electrophoretic painting technique, some automobile works is even included this in the terms of delivery of auto sheet, and therefore, cold-rolled steel sheet adopts more advanced Electrostatic Spray Technology.
Due to low cost, easy and simple to handle, be easy to construction, the advantage such as be easy to remove, result of use is good, slushing oil obtains widespread production and use at home and abroad.At present, slushing oil product is towards stdn, seriation, environmental protection future development.Barium salt and sulfonate favorable rust preventing effect, the rust-preventive agent that electrostatic painting anticorrosive oil is conventional is substantially all take barium salt and sulfonate as main, but barium salt and sulfonate pollutes the environment, and do not conform to environmental requirement, and can produce huge injury to human body.Thereby, adopt meet environmental requirement rush-resisting material, develop the not electrostatic painting anticorrosive oil product of baric and sulfonate and become very urgent and important.
Summary of the invention
For slushing oil product environmental protection problem, object of the present invention to provide exactly a kind of without barium without sulfonate electrostatic painting anticorrosive oil, this slushing oil is baric and sulfonate not, belongs to environmentfriendly products, rustless property excellence is applicable to electrostatic spraying.
For achieving the above object, provided by the invention without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: 80～90% No. 15 machinery oil, 2～10% zinc naphthenate, 1～6% KORANTIN SH stearylamine, 2～10% dodecenylsuccinic acid, 1～5% 2,6 ditertiary butyl p cresol.
As a kind of preferred version, its constituent mass per-cent is as follows: 85～81% No. 15 machinery oil, 3～6% zinc naphthenate, 2～5% KORANTIN SH stearylamine, 4～7% dodecenylsuccinic acid, 2～3% 2,6 ditertiary butyl p cresol.
As another preferred version, its constituent mass per-cent is as follows: 85% No. 15 machinery oil, 6% zinc naphthenate, 2% KORANTIN SH stearylamine, 4% dodecenylsuccinic acid, 3% 2,6 ditertiary butyl p cresol.
The effect of the each component of environmental protection of the present invention zinc-plated plate as thin as a wafer cold rolling oil is as follows:
No. 15 machinery oil are as base oil; it is the carrier of inhibiter; can use multiple corrosion inhibition additive mutually to mix, dissolve and disperse sufficiently uniformly; base oil molecules can be deep between the inhibitor molecular of oriented adsorption; make the adsorption film of hydrophobic tightr; also make the not firm polar molecule of absorption be difficult for desorption, thereby more effectively protect metal, generally account for more than 80%.
Zinc naphthenate, KORANTIN SH stearylamine, dodecenylsuccinic acid are as rust-inhibiting additive, when multiple additives compound use, play additive effect, can form in metallic surface very thin tectum, metal and corrosive medium are completely cut off, the anodic dissolution processes of metal can not be carried out, effectively prevent that metal from producing corrosion, reaches good rust-proof effect.
2,6 ditertiary butyl p cresol is as antioxidant.Because organism all contains unsatisfied chemical bond, can react with other compound generation number of chemical, as oxidizing reaction and polyreaction, the oxidizing reaction of oil makes oil thinning, and acid number increases, reduced viscosity,, there is the phenomenon such as muddy and cannot use in oil film attenuation, is unfavorable for transportation and standing storage, polyreaction causes grease to solidify, and easily makes strip produce mottling.
Tool of the present invention has the following advantages: slushing oil of the present invention is without intense stimulus smell, not baric and sulfonate, health environment-friendly; There is good rust-preventing characteristic, stable performance, and there is good lubricity.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment mono-:
Get by mass percentage machinery oil 80% No. 15, zinc naphthenate 10%, KORANTIN SH stearylamine 6%, dodecenylsuccinic acid 2%, 2,6 ditertiary butyl p cresol 2%, these raw materials are evenly mixed and made into electrostatic painting anticorrosive oil, this slushing oil all has good rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment bis-:
Get by mass percentage machinery oil 80% No. 15, zinc naphthenate 4%, KORANTIN SH stearylamine 1%, dodecenylsuccinic acid 10%, 2,6 ditertiary butyl p cresol 5%, these raw materials are evenly mixed and made into electrostatic painting anticorrosive oil, this slushing oil all has good rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment tri-:
Get by mass percentage machinery oil 90% No. 15, zinc naphthenate 2%, KORANTIN SH stearylamine 3%, dodecenylsuccinic acid 4%, 2,6 ditertiary butyl p cresol 1%, these raw materials are evenly mixed and made into electrostatic painting anticorrosive oil, this slushing oil all has good rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment tetra-:
Get by mass percentage machinery oil 85% No. 15, zinc naphthenate 6%, KORANTIN SH stearylamine 2%, dodecenylsuccinic acid 4%, 2,6 ditertiary butyl p cresol 3%, these raw materials are evenly mixed and made into electrostatic painting anticorrosive oil, this slushing oil all has good rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment five:
Get by mass percentage machinery oil 81% No. 15, zinc naphthenate 3%, KORANTIN SH stearylamine 5%, dodecenylsuccinic acid 7%, 2,6 ditertiary butyl p cresol 4%, these raw materials are evenly mixed and made into electrostatic painting anticorrosive oil, this slushing oil all has good rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Claims (3)
- One kind without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: 80～90% No. 15 machinery oil, 2～10% zinc naphthenate, 1～6% KORANTIN SH stearylamine, 2～10% dodecenylsuccinic acid, 1～5% 2,6 ditertiary butyl p cresol.
- According to claim 1 without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: 85～81% No. 15 machinery oil, 3～6% zinc naphthenate, 2～5% KORANTIN SH stearylamine, 4～7% dodecenylsuccinic acid, 2～3% 2,6 ditertiary butyl p cresol.
- According to claim 1 without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: 85% No. 15 machinery oil, 6% zinc naphthenate, 2% KORANTIN SH stearylamine, 4% dodecenylsuccinic acid, 3% 2,6 ditertiary butyl p cresol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410168119.XA CN103911206B (en) | 2014-04-24 | 2014-04-24 | Without barium without sulfonate electrostatic painting anticorrosive oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410168119.XA CN103911206B (en) | 2014-04-24 | 2014-04-24 | Without barium without sulfonate electrostatic painting anticorrosive oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103911206A true CN103911206A (en) | 2014-07-09 |
| CN103911206B CN103911206B (en) | 2015-12-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410168119.XA Expired - Fee Related CN103911206B (en) | 2014-04-24 | 2014-04-24 | Without barium without sulfonate electrostatic painting anticorrosive oil |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841432A (en) * | 2018-05-28 | 2018-11-20 | 湖北三环化学新材料股份有限公司 | A kind of degradable punching oil of food-grade and preparation method thereof |
| CN111117739A (en) * | 2019-12-12 | 2020-05-08 | 沈阳防锈包装材料有限责任公司 | Gas-phase anti-rust oil and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643683A (en) * | 2008-08-08 | 2010-02-10 | 沈阳防锈包装材料有限责任公司 | Environmentally-friendly barium-free thixotropic antirust oil |
-
2014
- 2014-04-24 CN CN201410168119.XA patent/CN103911206B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643683A (en) * | 2008-08-08 | 2010-02-10 | 沈阳防锈包装材料有限责任公司 | Environmentally-friendly barium-free thixotropic antirust oil |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841432A (en) * | 2018-05-28 | 2018-11-20 | 湖北三环化学新材料股份有限公司 | A kind of degradable punching oil of food-grade and preparation method thereof |
| CN111117739A (en) * | 2019-12-12 | 2020-05-08 | 沈阳防锈包装材料有限责任公司 | Gas-phase anti-rust oil and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103911206B (en) | 2015-12-09 |
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Effective date of registration: 20170725 Address after: 430083, Hubei Wuhan Qingshan District Factory No. 2 Gate joint stock company organs Patentee after: Wuhan iron and Steel Company Limited Address before: 430080 Wuchang, Hubei Friendship Road, No. A, block, floor 999, 15 Patentee before: Wuhan Iron & Steel (Group) Corp. |
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Granted publication date: 20151209 Termination date: 20190424 |
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