CN114395437A - Illumination-resistant anti-rust oil composition - Google Patents
Illumination-resistant anti-rust oil composition Download PDFInfo
- Publication number
- CN114395437A CN114395437A CN202210013047.6A CN202210013047A CN114395437A CN 114395437 A CN114395437 A CN 114395437A CN 202210013047 A CN202210013047 A CN 202210013047A CN 114395437 A CN114395437 A CN 114395437A
- Authority
- CN
- China
- Prior art keywords
- component
- calcium
- mass content
- light
- oil composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/285—Esters of aromatic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention provides an illumination-resistant anti-rust oil composition which comprises the following components in percentage by mass: 0.3-2.0% of a second component, 0.5-2.0% of a third component, 0.3-10.0% of a fourth component, 0.1-1.0% of a fifth component, 0.1-2.0% of a sixth component, 0.1-0.8% of a seventh component, 0.1-0.3% of an eighth component, and the balance of the first component; the first component is base oil, the second component is a film forming agent, the third component is a film forming aid, the fourth component is a main corrosion inhibitor, the fifth component is an auxiliary corrosion inhibitor, the sixth component is a solubilizing reinforcing agent, the seventh component is a light stabilizing main agent, and the eighth component is a light stabilizing aid. According to the light-resistant anti-rust oil composition provided by the invention, through the synergistic cooperation effect of the components, the anti-rust oil can provide excellent light stability while meeting good anti-rust performance, and the problem that the anti-rust oil generates colored deposited glue stains on the surface of an oiled workpiece is solved.
Description
Technical Field
The invention relates to the technical field of antirust materials, in particular to an illumination-resistant antirust oil composition.
Background
Metal parts mainly composed of iron are often manufactured by machining such as cutting and pressing. In addition, rust preventive oil is applied in order to prevent rusting or discoloration during the manufacturing process or when shipped as a product. The main purpose of using rust preventive oil is to form a coating on the surface of a metal and to block oxygen to prevent oxidation of the metal (i.e., rust).
In order to improve the rust-proof performance of oil products, various rust-proof additives are available on the market. Petroleum sulfonates (neutral calcium petroleum sulfonate, basic calcium petroleum sulfonate, barium petroleum sulfonate, sodium petroleum sulfonate), naphthalene sulfonates (neutral calcium dinonylnaphthalene sulfonate, neutral barium dinonylnaphthalene sulfonate, basic barium dinonylnaphthalene sulfonate), organic acid salts (oxidized barium paraffin soap, oxidized calcium paraffin soap, zinc naphthenate, magnesium lanolin soap, calcium lanolin soap, alkylphosphite salts, oleoyl sarcosinate salts, oleoyl imidazoline oleoyl sarcosinate salts, carboxylic acid alkylamine salts, oleoyl imidazoline dodecenyl succinate salts), organic esters (dodecenyl succinic acid half-ester, dilauryl phosphite, pentaerythritol carboxylic acid full ester, trimethylolpropane carboxylic acid full ester, sorbitan carboxylic acid full ester, pentaerythritol carboxylic acid partial ester, trimethylolpropane carboxylic acid partial ester, sorbitol carboxylic acid partial ester), organic acids (dodecenyl succinic acid, oleoyl sarcosinate), Amide (polybutylene succinimide), paraffin, vaseline, resin, etc. Depending on the desired properties, there may be synergy between the various additives, or there may be effects that counteract or even worsen the properties. To obtain a composition that meets the application requirements ideally, performance optimization tests are required.
The anti-rust oil not only needs to have good anti-rust performance, but also needs to have low-temperature stability to provide low-temperature fluidity in relation to a spray oiling process; good degreasing performance is also required in relation to subsequent processes of workpieces; in order to reduce the oil consumption of the workpiece and provide a thinner oil film thickness, it is necessary to have an anti-adhesion property. CN113490769A provides an antirust oil composition containing metal sulfonate, alkaline earth metal sulfonate, oxidized wax, polyol full ester and polyol partial ester, which realizes the functions of preventing additive from separating out and precipitating at the low temperature of-10 ℃ and degreasing a steel sheet coated with oil for 24 hours in alkaline cleaning solution with PH 12-13. JPA JP 2002-363592 discloses an antirust oil composition containing alkali metal sulfonate, alkaline earth metal sulfonate, dodecyl amine alkylsulfonate, carboxylic soap of oxidized paraffin, carboxylic ester of oxidized paraffin, salt of linseed oil fatty acid, ester of linseed oil fatty acid, and polyol partial ester, which has storage stability of 50% and 95% humidity for 10 days or more under sunlight irradiation environment, and degreasing performance of 90% by alkali cleaning agent containing sodium phosphate and sodium silicate after being oiled for 24 hours. JPA laid-open No. 2013-199670 provides an antirust oil composition containing fatty acid amine salt, pentaerythrite linolenate, sorbitan stearate, sorbitan oleate, trimethylolpropane oleate, sarcosine compounds and sulfonate, which has the stability of keeping for 10 days in a constant temperature bath at 45 ℃ without precipitation. JPA kokai 2012-62488 provides an antirust oil composition for processing, which comprises trimethylolpropane ester, high-alkaline calcium sulfonate, neutral calcium sulfonate, acidification preventing agent, benzotriazole, thiadiazole and alkenyl succinate, and has the degreasing performance that workpieces can be degreased by 2% alkaline degreasing liquid after being oiled for 7 days. In the practical application process of the anti-rust oil, the oiling process is not operated in a dark place, the anti-rust oil is supplemented for use, and an oiled workpiece is not packaged and stored in time even if the oiled workpiece is in a light environment for a long time. Therefore, new requirements are provided for the light stability of the anti-rust oil.
After the workpiece is processed and oiled for rust prevention, the rust prevention oil decays under the influence of illumination because of insufficient illumination stability, and colored deposited glue spots are formed on the surface of the workpiece. At present, in the existing anti-rust oil technology, no report is provided on which anti-rust oil functional additive or additive combination is easy to generate light discoloration, light precipitation or light precipitation. The antirust performance of the antirust oil depends on the selection of the components and the proportion of the components. The decrease or loss of the rust-proof performance and the illumination stability of the rust-proof oil can be caused by the selection and the change of any one component and the change of the mixture ratio among the components.
Disclosure of Invention
In view of the above situation, the present invention provides an illumination-resistant rust preventive oil composition, which has good illumination stability while ensuring rust preventive performance of the rust preventive oil.
An illumination-resistant anti-rust oil composition comprises the following components in percentage by mass:
0.3-2.0% of a second component, 0.5-2.0% of a third component, 0.3-10.0% of a fourth component, 0.1-1.0% of a fifth component, 0.1-2.0% of a sixth component, 0.1-0.8% of a seventh component, 0.1-0.3% of an eighth component, and the balance of the first component;
the first component is base oil, in particular hydrorefined or clay refined mineral oil;
the second component is a film forming agent, and specifically is at least one of lanolin magnesium soap and oxidized paraffin calcium soap;
the third component is a film-forming additive, specifically trimellitic acid triester;
the fourth component is a main corrosion inhibitor, and specifically is at least one of calcium petroleum sulfonate and calcium dinonylnaphthalene sulfonate;
the fifth component is an auxiliary corrosion inhibitor, and specifically is at least one of isoprene glycol didodecyl succinate, dilauryl phosphite and dodecenyl succinic acid;
the sixth component is a solubilizing reinforcing agent, and specifically is at least one of oleoyl sarcosine octadecylamine salt and polyisobutylene succinimide;
the seventh component is a light stabilizing main agent, and specifically is at least one of phosphite ester and shielding phenol;
the eighth component is a light stabilizing additive, and specifically is alkylated diphenylamine or alkylated phenylnaphthylamine.
The light-resistant anti-rust oil composition comprises the following components in parts by weight:
when the second component is lanolin magnesium soap, the base number of the lanolin magnesium soap is below 10mgKOH/g, and the mass content of the lanolin magnesium soap is 0.3-1.0%;
when the second component is the oxidized calcium paraffin soap, the base number of the oxidized calcium paraffin soap is less than 10mgKOH/g, and the mass content of the oxidized calcium paraffin soap is 0.5-1.0%.
The light-resistant anti-rust oil composition comprises the following components in parts by weight: in the third component, the trimellitic triester is any one of triisononyl trimellitate, tri-2-hexyldecyl trimellitate, tri-tridecyl trimellitate and tri-2-octyl-dodecyl trimellitate.
In the light-resistant anti-rust oil composition, in the fourth component, calcium petroleum sulfonate or calcium dinonylnaphthalene sulfonate is neutral, low in base number and high in base number;
when the fourth component is neutral calcium petroleum sulfonate or calcium dinonylnaphthalene sulfonate, the base number is lower than 10mgKOH/g, and the mass content of the fourth component is 2.0-8.0%;
when the fourth component is low-base-number calcium petroleum sulfonate or calcium dinonylnaphthalenesulfonate, the base number is 10-30mgKOH/g, and the mass content of the fourth component is 0.3-1.0%;
when the fourth component is high-base-number calcium petroleum sulfonate or calcium dinonylnaphthalenesulfonate, the base number is 250-350mgKOH/g, and the mass content of the fourth component is 0.3-0.5%.
The light-resistant anti-rust oil composition comprises the following components in parts by weight:
when the fifth component is the isoprene glycol didodecyl succinate, the mass content of the isoprene glycol didodecyl succinate is 0.1-1.0%;
when the fifth component is dilauryl alcohol phosphite, the mass content of the dilauryl alcohol phosphite is 0.1-0.3%;
when the fifth component is dodecenylsuccinic acid, the mass content of dodecenylsuccinic acid is preferably 0.2-0.5%.
The light-resistant anti-rust oil composition comprises the following components in parts by weight:
when the sixth component is oleoyl sarcosine octadecylamine salt, the mass content of oleoyl sarcosine octadecylamine salt is 0.1-2.0%;
when the sixth component is polyisobutylene succinimide, the mass content of the polyisobutylene succinimide is 0.1-0.3%, and the polyisobutylene succinimide is specifically bis-polyisobutylene succinimide, wherein the molecular weight of the polyisobutylene is 1300-2400-.
The light-resistant anti-rust oil composition comprises the following components in parts by weight:
when the seventh component is phosphite ester, the mass content of the phosphite ester is 0.1-0.3%, and the phosphite ester is one of tris (2, 4-di-tert-butylphenol) phosphite ester and tris (nonylphenol) phosphite ester;
when the seventh component is shielding phenol, the mass content of the shielding phenol is 0.1-0.5%, and the shielding phenol is one of octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, tridecyl 4-hydroxy-3, 5-di-tert-butyl-phenylpropionate and isooctyl 3, 5-di-tert-butyl-4-hydroxy phenylpropionate.
In the above light-resistant rust preventive oil composition, when the eighth component is alkylated diphenylamine, the alkylated diphenylamine is one of bis [4- (1,1,3, 3-tetramethylbutylbenzene) ] amine and N-butylphenyl-octylaniline.
The light-resistant anti-rust oil composition comprises a first component and a second component, wherein in the first component, the base oil is synthetic hydrocarbon base oil or mineral base oil, and is refined by a hydrogenation process or a clay process, so that the kinematic viscosity is 2.0-100mm2The flash point is 60-240 ℃.
According to the illumination-resistant anti-rust oil composition provided by the invention, through the synergistic cooperation effect of the components, the anti-rust oil can provide excellent illumination stability while meeting good anti-rust performance, and through an anti-rust performance test, an oil illumination discoloration test, an oil illumination precipitation test and an oil-coated steel sheet glue spot deposition test, the anti-rust performance and the illumination stability of the illumination-resistant anti-rust oil composition are superior to those of the prior art, and the problem that the anti-rust oil generates colored deposition glue spots on the surface of an oil-coated workpiece is solved.
Detailed Description
The present invention will now be described more fully hereinafter with reference to various embodiments for the purpose of facilitating an understanding of the invention, but the invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The embodiment of the invention provides an illumination-resistant anti-rust oil composition which comprises the following components in percentage by mass:
0.3-2.0% of a second component, 0.5-2.0% of a third component, 0.3-10.0% of a fourth component, 0.1-1.0% of a fifth component, 0.1-2.0% of a sixth component, 0.1-0.8% of a seventh component, 0.1-0.3% of an eighth component, and the balance of the first component;
the first component is base oil, in particular hydrorefined or clay refined mineral oil;
the second component is a film forming agent, and specifically is at least one of lanolin magnesium soap and oxidized paraffin calcium soap;
the third component is a film-forming additive, specifically trimellitic acid triester;
the fourth component is a main corrosion inhibitor, and specifically is at least one of calcium petroleum sulfonate and calcium dinonylnaphthalene sulfonate;
the fifth component is an auxiliary corrosion inhibitor, and specifically is at least one of isoprene glycol didodecyl succinate, dilauryl phosphite and dodecenyl succinic acid;
the sixth component is a solubilizing reinforcing agent, and specifically is at least one of oleoyl sarcosine octadecylamine salt and polyisobutylene succinimide;
the seventh component is a light stabilizing main agent, and specifically is at least one of phosphite ester and shielding phenol;
the eighth component is a light stabilizing additive, and specifically is alkylated diphenylamine or alkylated phenylnaphthylamine.
Wherein, when the second component is lanolin magnesium soap, the base number of the lanolin magnesium soap is below 10mgKOH/g, and the mass content of the lanolin magnesium soap is 0.3-1.0%;
when the second component is the oxidized calcium paraffin soap, the base number of the oxidized calcium paraffin soap is less than 10mgKOH/g, and the mass content of the oxidized calcium paraffin soap is 0.5-1.0%.
In the third component, the trimellitic triester is any one of triisononyl trimellitate, tri-2-hexyldecyl trimellitate, tridecyl trimellitate and tri-2-octyl-dodecyl trimellitate.
Wherein, in the fourth component, the calcium petroleum sulfonate or calcium dinonylnaphthalene sulfonate is neutral, low in base number and high in base number;
when the fourth component is neutral calcium petroleum sulfonate or calcium dinonylnaphthalene sulfonate, the base number is lower than 10mgKOH/g, and the mass content of the fourth component is 2.0-8.0%;
when the fourth component is low-base-number calcium petroleum sulfonate or calcium dinonylnaphthalenesulfonate, the base number is 10-30mgKOH/g, and the mass content of the fourth component is 0.3-1.0%;
when the fourth component is high-base-number calcium petroleum sulfonate or calcium dinonylnaphthalenesulfonate, the base number is 250-350mgKOH/g, and the mass content of the fourth component is 0.3-0.5%.
Wherein when the fifth component is isoprene glycol didodecyl succinate, the mass content of the isoprene glycol didodecyl succinate is 0.1-1.0%;
when the fifth component is dilauryl alcohol phosphite, the mass content of the dilauryl alcohol phosphite is 0.1-0.3%;
when the fifth component is dodecenylsuccinic acid, the mass content of dodecenylsuccinic acid is preferably 0.2-0.5%.
Wherein when the sixth component is oleoyl sarcosine octadecylamine salt, the mass content of the oleoyl sarcosine octadecylamine salt is 0.1-2.0%;
when the sixth component is polyisobutylene succinimide, the mass content of the polyisobutylene succinimide is 0.1-0.3%, and the polyisobutylene succinimide is specifically bis-polyisobutylene succinimide, wherein the molecular weight of the polyisobutylene is 1300-2400-.
Wherein, when the seventh component is phosphite ester, the mass content of the phosphite ester is 0.1-0.3%, and the phosphite ester is one of tris (2, 4-di-tert-butylphenol) phosphite ester and tris (nonylphenol) phosphite ester;
when the seventh component is shielding phenol, the mass content of the shielding phenol is 0.1-0.5%, and the shielding phenol is one of octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, tridecyl 4-hydroxy-3, 5-di-tert-butyl-phenylpropionate and isooctyl 3, 5-di-tert-butyl-4-hydroxy phenylpropionate.
Wherein, when the eighth component is alkylated diphenylamine, the alkylated diphenylamine is one of bis [4- (1,1,3, 3-tetramethylbutylbenzene) ] amine and N-butylphenyl-octylaniline.
Wherein in the first component, the base oil is synthetic hydrocarbon base oil or mineral base oil, and is refined by hydrogenation process or clay process to obtain a product with kinematic viscosity of 2.0-100mm2The flash point is 60-240 ℃.
The following examples are intended to illustrate the invention in more detail. The embodiments of the present invention are not limited to the following specific examples. The present invention can be modified and implemented as appropriate within the scope of the main claim.
Tables 1 to 3 show the ingredient ratios of each of 22 examples and 11 comparative examples, and the results of the relevant tests.
TABLE 1
TABLE 2
TABLE 3
Description in tables 1 to 3:
a0 represents a trimellitic triester (wherein a represents triisononyl trimellitate, b represents tri-2-hexyldecyl trimellitate, c represents tridecyl trimellitate, and d represents tri-2-octyl-dodecyl trimellitate), and for example, in Table 1, 1.0a represents triisononyl trimellitate having a mass percentage of 1.0% in example 1, 1.5a represents triisononyl trimellitate having a mass percentage of 1.5% in example 4, 1.0b below No. 10 represents tri-2-hexyldecyl trimellitate having a mass percentage of 1.0% in example 10, 1.0b below No. 11 represents tri-2-hexyldecyl trimellitate having a mass percentage of 1.0% in example 11, and so forth in the other tables).
A1 represents low-base number calcium petroleum sulfonate
A2 represents neutral calcium petroleum sulfonate
A3 represents overbased calcium dinonylnaphthalenesulfonate
A4 represents neutral calcium dinonylnaphthalenesulfonate
A5 represents zinc naphthenate
A6 represents lanolin magnesium soap
A7 represents oxidized paraffin calcium soap
A8 represents sorbitol monooleate
A9 denotes isoprene glycol didodecyl succinate
A10 represents dilauryl alcohol phosphite
A11 denotes dodecenylsuccinic acid
A12 represents oleoyl sarcosine octadecylamine
A13 represents polyisobutylene succinimide
B1 represents tris (2, 4-di-tert-butylphenyl) phosphite
B2 represents tris (nonylphenol) phosphite
B3 represents dioctadecyl pentaerythritol diphosphite
B4 represents bis (2, 4-di-tert-butylphenyl) pentaerythritol diphosphite
B5 represents bis (2, 6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite
C1 represents 4, 4' -methylenebis (2, 6-di-tert-butylphenol)
C2 represents tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propanoic acid ] pentaerythritol ester
C3 represents 1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene
C4 represents octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate
C5 represents 4-hydroxy-3, 5-di-tert-butyl-benzenepropanoic acid tridecyl ester
C6 represents isooctyl 3, 5-di-tert-butyl-4-hydroxyphenylpropionate
C7 represents 2, 2' -methylenebis (4-methyl-6-tert-butylphenol)
C8 represents 2, 6-di-tert-butyl-4-methylphenol
D1 represents bis [4- (1,1,3, 3-tetramethylbutylbenzene) ] amine
D2 represents N-butylphenyl-octylaniline
D3 represents N- (dodecylphenyl) -a-naphthylamine
E1 represents 2-hydroxy-4-n-octyloxybenzophenone
E2 represents 2-hydroxy-4-methoxybenzophenone
E3 represents 2- (2 '-hydroxy-3' -5-di-tert-butylphenyl) -benzotriazole
E4 represents 2- (2 '-hydroxy-3' -5-di-tert-butylphenyl) -5-chlorobenzotriazole
E5 represents 2- (2 ' -hydroxy-3 ' -tert-butyl-5 ' -methylphenyl) -5-chlorobenzotriazole
E6 represents poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino ] ] -1,3, 5-triazine-2, 4- [ (2,2,6,6, -tetramethyl-piperidyl) imino ] -1, 6-hexamethylene [ (2,2,6, 6-tetramethyl-4-piperidyl) imido
E7 represents bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate
E8 represents polysuccinic acid 4-hydroxy-2, 2,6, 6-tetramethyl-1-piperidinol.
And (3) testing the rust resistance: for the rust preventive oil compositions of the respective examples and comparative examples, the rust preventive oil composition was prepared in accordance with JIS K2246: 2017, by the neutral salt water spray test method (45# steel sheet, 48 hours and 60 hours), evaluation was made based on the following evaluation criteria. The evaluation II or more was judged to be acceptable.
I: the 48 hour rust rating was grade a and the 60 hour rust rating was grade B.
II: the 48 hour rust rating was grade a and the 60 hour rust rating was grade C.
III: the 48 hour rust rating was grade B.
IV: the 24 hour rust rating was grade B.
And (3) testing the illumination discoloration of the oil product: a colorimetric tube with a plunger and the diameter of 20mm and the height of 120mm is adopted, a sample to be detected is placed in the colorimetric tube, and the plunger is covered. Exposing in sunlight. The evaluation II or more was judged to be acceptable.
I: the time for changing the oil into brown and red is more than 30 hours.
II: the time for changing the oil into brown and red is more than 20 hours and less than or equal to 30 hours.
III: the time for changing the oil into brown and red is more than 10 hours and less than or equal to 20 hours.
IV: the time for changing the oil into brown and red is less than or equal to 10 hours.
And (3) oil product illumination precipitation test: a colorimetric tube with a plunger and the diameter of 20mm and the height of 120mm is adopted, a sample to be detected is placed in the colorimetric tube, and the plunger is covered. Exposing in sunlight. The evaluation II or more was judged to be acceptable.
I: the oil product has insoluble suspension and precipitation time longer than 12 days.
II: the oil product has insoluble suspension and precipitation time longer than 8 days and less than or equal to 12 days.
III: the oil product has insoluble suspension and precipitation time longer than 2 days and less than or equal to 8 days.
IV: the oil product has insoluble suspension and precipitation time less than or equal to 2 days.
And (3) testing the spot deposition of the oiled steel sheet: a No. 10 steel sheet is adopted, oil is applied to the steel sheet, oil is drained for 24 hours, and then the steel sheet is placed in a sealed plastic bag. Exposing in sunlight. The evaluation II or more was judged to be acceptable.
I: the time for the dark spots on the surface of the steel sheet is more than 20 days.
II: the time for the dark spots on the surface of the steel sheet is more than 10 days and less than or equal to 20 days.
III: the time for the dark spots on the surface of the steel sheet is more than 5 days and less than or equal to 10 days.
IV: the time for the steel sheet surface to generate dark glue spots is less than or equal to 5 days.
The comparative test results show that the antirust performance and the illumination stability of the antirust oil composition of each embodiment of the invention are superior to each proportion.
In conclusion, the anti-rust oil composition provided by the invention has excellent illumination stability while meeting good anti-rust performance through the synergistic cooperation effect of the components, and the anti-rust oil composition is proved to have better anti-rust performance and illumination stability than the prior art through an anti-rust performance test, an oil illumination discoloration test, an oil illumination precipitation test and an oil coated steel sheet adhesive spot deposition test, thereby solving the problem that the anti-rust oil generates colored deposited adhesive spots on the surface of an oil coated workpiece.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (9)
1. The light-resistant anti-rust oil composition is characterized by comprising the following components in percentage by mass:
0.3-2.0% of a second component, 0.5-2.0% of a third component, 0.3-10.0% of a fourth component, 0.1-1.0% of a fifth component, 0.1-2.0% of a sixth component, 0.1-0.8% of a seventh component, 0.1-0.3% of an eighth component, and the balance of the first component;
the first component is base oil, in particular hydrorefined or clay refined mineral oil;
the second component is a film forming agent, and specifically is at least one of lanolin magnesium soap and oxidized paraffin calcium soap;
the third component is a film-forming additive, specifically trimellitic acid triester;
the fourth component is a main corrosion inhibitor, and specifically is at least one of calcium petroleum sulfonate and calcium dinonylnaphthalene sulfonate;
the fifth component is an auxiliary corrosion inhibitor, and specifically is at least one of isoprene glycol didodecyl succinate, dilauryl phosphite and dodecenyl succinic acid;
the sixth component is a solubilizing reinforcing agent, and specifically is at least one of oleoyl sarcosine octadecylamine salt and polyisobutylene succinimide;
the seventh component is a light stabilizing main agent, and specifically is at least one of phosphite ester and shielding phenol;
the eighth component is a light stabilizing additive, and specifically is alkylated diphenylamine or alkylated phenylnaphthylamine.
2. The light-resistant rust preventive oil composition according to claim 1, characterized in that:
when the second component is lanolin magnesium soap, the base number of the lanolin magnesium soap is below 10mgKOH/g, and the mass content of the lanolin magnesium soap is 0.3-1.0%;
when the second component is the oxidized calcium paraffin soap, the base number of the oxidized calcium paraffin soap is less than 10mgKOH/g, and the mass content of the oxidized calcium paraffin soap is 0.5-1.0%.
3. The light-resistant rust preventive oil composition as claimed in claim 1, wherein in said third component, the trimellitic acid triester is any one of triisononyl trimellitate, tri-2-hexyldecyl trimellitate, tridecyl trimellitate, tri-2-octyl-dodecyl trimellitate.
4. The light-resistant rust preventive oil composition as claimed in claim 1, wherein in said fourth component, calcium petroleum sulfonate or calcium dinonylnaphthalene sulfonate is classified into neutral, low base number, high base number;
when the fourth component is neutral calcium petroleum sulfonate or calcium dinonylnaphthalene sulfonate, the base number is lower than 10mgKOH/g, and the mass content of the fourth component is 2.0-8.0%;
when the fourth component is low-base-number calcium petroleum sulfonate or calcium dinonylnaphthalenesulfonate, the base number is 10-30mgKOH/g, and the mass content of the fourth component is 0.3-1.0%;
when the fourth component is high-base-number calcium petroleum sulfonate or calcium dinonylnaphthalenesulfonate, the base number is 250-350mgKOH/g, and the mass content of the fourth component is 0.3-0.5%.
5. The light-resistant rust preventive oil composition according to claim 1, characterized in that:
when the fifth component is the isoprene glycol didodecyl succinate, the mass content of the isoprene glycol didodecyl succinate is 0.1-1.0%;
when the fifth component is dilauryl alcohol phosphite, the mass content of the dilauryl alcohol phosphite is 0.1-0.3%;
when the fifth component is dodecenylsuccinic acid, the mass content of dodecenylsuccinic acid is preferably 0.2-0.5%.
6. The light-resistant rust preventive oil composition according to claim 1, characterized in that:
when the sixth component is oleoyl sarcosine octadecylamine salt, the mass content of oleoyl sarcosine octadecylamine salt is 0.1-2.0%;
when the sixth component is polyisobutylene succinimide, the mass content of the polyisobutylene succinimide is 0.1-0.3%, and the polyisobutylene succinimide is specifically bis-polyisobutylene succinimide, wherein the molecular weight of the polyisobutylene is 1300-2400-.
7. The light-resistant rust preventive oil composition according to claim 1, characterized in that:
when the seventh component is phosphite ester, the mass content of the phosphite ester is 0.1-0.3%, and the phosphite ester is one of tris (2, 4-di-tert-butylphenol) phosphite ester and tris (nonylphenol) phosphite ester;
when the seventh component is shielding phenol, the mass content of the shielding phenol is 0.1-0.5%, and the shielding phenol is one of octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, tridecyl 4-hydroxy-3, 5-di-tert-butyl-phenylpropionate and isooctyl 3, 5-di-tert-butyl-4-hydroxy phenylpropionate.
8. The light-fast rust preventive oil composition according to claim 1, wherein when the eighth component is an alkylated diphenylamine, the alkylated diphenylamine is one of bis [4- (1,1,3, 3-tetramethylbutylbenzene) ] amine and N-butylphenyl-octylaniline.
9. The light-resistant anti-rust oil composition as claimed in claim 1, wherein in the first component, the base oil is a synthetic hydrocarbon base oil or a mineral base oil, which is refined by a hydrogenation process or a clay process and has a kinematic viscosity of 2.0-100mm2The flash point is 60-240 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210013047.6A CN114395437B (en) | 2022-01-06 | 2022-01-06 | Illumination-resistant anti-rust oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210013047.6A CN114395437B (en) | 2022-01-06 | 2022-01-06 | Illumination-resistant anti-rust oil composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114395437A true CN114395437A (en) | 2022-04-26 |
| CN114395437B CN114395437B (en) | 2022-08-30 |
Family
ID=81229496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210013047.6A Active CN114395437B (en) | 2022-01-06 | 2022-01-06 | Illumination-resistant anti-rust oil composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114395437B (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050215442A1 (en) * | 2004-03-23 | 2005-09-29 | The Lubrizol Corporation, A Corporation Of The State Of Ohio | Functionalized polymer composition for grease |
| CN101643683A (en) * | 2008-08-08 | 2010-02-10 | 沈阳防锈包装材料有限责任公司 | Environmentally-friendly barium-free thixotropic antirust oil |
| CN104342253A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Oxidation-resistant knitting machine oil composition and application thereof |
| CN104450023A (en) * | 2014-10-29 | 2015-03-25 | 合肥市华阳工程机械有限公司 | Rust-proof oil for metal processing molding |
| CN108517246A (en) * | 2018-05-17 | 2018-09-11 | 北美防锈技术（上海）有限公司 | A kind of environment protection antirust oil with synergy |
| CN108728224A (en) * | 2018-07-01 | 2018-11-02 | 芜湖市欧贝润滑剂有限责任公司 | A kind of synthesis ultrahigh-temperature chain oils |
| CN109897718A (en) * | 2017-12-11 | 2019-06-18 | 中国石油天然气股份有限公司 | Barium-free soft film anti-rust oil |
| CN110591796A (en) * | 2019-08-21 | 2019-12-20 | 北美防锈技术（上海）有限公司 | Environment-friendly emulsified antirust oil |
| CN111073737A (en) * | 2019-12-01 | 2020-04-28 | 苏州福瑞斯德新材料科技有限公司 | Anti-rust oil without containing heavy metal |
| CN112011391A (en) * | 2020-07-23 | 2020-12-01 | 希玛石油制品（镇江）有限公司 | Environment-friendly ductile iron rust preventive oil |
-
2022
- 2022-01-06 CN CN202210013047.6A patent/CN114395437B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050215442A1 (en) * | 2004-03-23 | 2005-09-29 | The Lubrizol Corporation, A Corporation Of The State Of Ohio | Functionalized polymer composition for grease |
| CN101643683A (en) * | 2008-08-08 | 2010-02-10 | 沈阳防锈包装材料有限责任公司 | Environmentally-friendly barium-free thixotropic antirust oil |
| CN104342253A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Oxidation-resistant knitting machine oil composition and application thereof |
| CN104450023A (en) * | 2014-10-29 | 2015-03-25 | 合肥市华阳工程机械有限公司 | Rust-proof oil for metal processing molding |
| CN109897718A (en) * | 2017-12-11 | 2019-06-18 | 中国石油天然气股份有限公司 | Barium-free soft film anti-rust oil |
| CN108517246A (en) * | 2018-05-17 | 2018-09-11 | 北美防锈技术（上海）有限公司 | A kind of environment protection antirust oil with synergy |
| CN108728224A (en) * | 2018-07-01 | 2018-11-02 | 芜湖市欧贝润滑剂有限责任公司 | A kind of synthesis ultrahigh-temperature chain oils |
| CN110591796A (en) * | 2019-08-21 | 2019-12-20 | 北美防锈技术（上海）有限公司 | Environment-friendly emulsified antirust oil |
| CN111073737A (en) * | 2019-12-01 | 2020-04-28 | 苏州福瑞斯德新材料科技有限公司 | Anti-rust oil without containing heavy metal |
| CN112011391A (en) * | 2020-07-23 | 2020-12-01 | 希玛石油制品（镇江）有限公司 | Environment-friendly ductile iron rust preventive oil |
Non-Patent Citations (3)
| Title |
|---|
| 姜建卫等: "溶剂稀释型软膜防锈油的研制", 《润滑油》 * |
| 王文忠: "金属防锈剂", 《电镀与环保》 * |
| 黄文轩: "防锈剂的作用机理、主要品种及应用", 《石油商技》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114395437B (en) | 2022-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4698614B2 (en) | Lubricant composition comprising an antioxidant blend | |
| EP0434464B1 (en) | Transition-metal free Lubricant | |
| EP2177595B1 (en) | Lubricating composition with good oxidative stability and reduced deposit formation | |
| CN110283641B (en) | Electrostatic spraying anti-rust oil for cold-rolled steel sheets and preparation and performance test methods thereof | |
| US5104558A (en) | Rust-proofing oil composition | |
| JP4494726B2 (en) | Anti-rust and press working oil composition | |
| CN114395437B (en) | Illumination-resistant anti-rust oil composition | |
| JP2728708B2 (en) | Corrosion inhibiting composition | |
| JP3406339B2 (en) | Lubricating oil composition | |
| CN113490769A (en) | Rust preventive oil composition and method for producing same | |
| JPH05339589A (en) | Rustproofing press oil | |
| US20040192563A1 (en) | Lubricant containing a synergistic combination of rust inhibitors, antiwear agents, and a phenothiazine antioxidant | |
| JP5502848B2 (en) | Anti-rust oil composition for processing | |
| US20100294166A1 (en) | Oleaginous Corrosion-Resistant Coatings | |
| JP3639876B2 (en) | Rust preventive lubricant composition for plastic working | |
| US3857789A (en) | Slushing oil or rust inhibiting compositions | |
| JPH10279977A (en) | Highly lubricant rust preventing oil composition | |
| JP5148224B2 (en) | Lubricating oil for press working and press working method of metal material using the same | |
| JPH02252799A (en) | Rust-preventive oil for steel sheet combinedly used in press working | |
| JPH10245577A (en) | Plastic working/rust-preventive oil composition | |
| US4938883A (en) | Overbased alkaline earth alkenyl succinates as a silver-mild source of alkalinity for heavy duty diesel engines | |
| JP2988887B2 (en) | Forming and rust-preventive oil composition for surface-treated steel sheets | |
| JP3103859B2 (en) | Anti-rust oil composition for bearings | |
| JPH07258677A (en) | Turbine oil composition | |
| CA1093545A (en) | Metalworking corrosion inhibitor/drawing lubricant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |