CN101632377B - 电热灭虫片 - Google Patents
电热灭虫片 Download PDFInfo
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- CN101632377B CN101632377B CN 200910142185 CN200910142185A CN101632377B CN 101632377 B CN101632377 B CN 101632377B CN 200910142185 CN200910142185 CN 200910142185 CN 200910142185 A CN200910142185 A CN 200910142185A CN 101632377 B CN101632377 B CN 101632377B
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- acid
- electrothermal
- tablet
- ester
- pyrethroid
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Abstract
本发明提供一种含有式(1)表示的拟除虫菊酯(式中R为氢原子,甲基或甲氧基甲基)、PBO以及酯化合物的电热灭虫片。可以在较长时间内有效的防除蚊蝇等飞翔性卫生害虫。
Description
技术领域
本发明涉及一种电热灭虫片
背景技术
电热灭虫片是把有效杀虫成分保持在纤维质或多孔质载体中的制品,通常用于在约140-200℃下加热来防除蚊蝇等卫生害虫的。
人们一直希望能够找到一种能在10-12小时左右的较长时间内一直可以有效防除害虫,特别是蚊蝇等飞翔性卫生害虫的电热灭虫片。
经过本发明人的研究,发现了含式(1)所示的拟除虫菊酯(pyrethroid)化合物以及酯化合物的电热灭虫片显示出对害虫,特别是蚊蝇等飞翔性卫生害虫具有长时间的效力,并且进一步发现如果在其中添加α-[2-(2-丁氧基乙氧基)乙氧基]-4,5-亚甲基二氧-2-丙基甲苯(以下称为PBO)可以在不影响对害虫的防治效果的前提下减少拟除虫菊酯化合物(1)的用量。
发明内容
本发明的目的是提供一种电热灭虫片。
本发明中,拟除虫菊酯化合物(1)包含式(1)所示结构的各化合物以及它们所有的因环丙烷平面不对称及烯烃双键不对称所引起的立体异构体或它们的混合物,具体实例包括2,3,5,6-四氟-4-甲氧甲基苄基-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯;2,3,5,6-四氟-4-甲氧甲基苄基-1R-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯;2,3,5,6-四氟-4-甲氧甲基苄基-1R,反式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯;2,3,5,6-四氟-4-甲氧甲基苄基-1R,顺式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯。这些化合物是已知的,或者可以通过已知方法制备。
本发明电热灭虫片的酯化合物,用的是常温下为液体的不含卤原子的酯化合物,如:己二酸、癸二酸、壬二酸与碳原子数2至10的醇的二酯;苹果酸或乙酰基柠檬酸与碳原子数3至10的醇的酯;月桂酸、棕榈酸与碳原子数3至10的醇的酯;邻苯二甲酸与碳原子数2至10的醇的二酯。
作为这样的酯化合物的具体例子有己二酸二正丁酯、己二酸二异癸酯、己二酸二异丙酯、癸二酸二辛酯、癸二酸二丁酯等饱和二元脂肪酸酯,苹果酸二-2-乙基己酯等羟基脂肪酸酯、乙酰基柠檬酸三丁酯等乙酰氧基脂肪酸酯,月桂酸二-2-乙基己酯、棕榈酸异丙酯等饱和一元脂肪酸酯,邻苯二甲酸二甲酯、邻苯二甲酸二异癸酯等邻苯二甲酸酯。
添加了PBO后可起到增效的作用,在不影响对害虫的防治效果的前提下可减少拟除虫菊酯化合物(1)的用量。
本发明药片中,除了本化合物以及酯化合物之外,也可以适当含有溶剂、色素、抗氧剂、稳定剂等。
作为本发明药片中使用的溶剂可列举的有,十一碳烷(沸点195.9℃),十二碳烷(沸点216℃),十三碳烷(沸点235.4℃),十四碳烷(沸点253.7℃),D60(埃克森美孚石油化工公司,沸点186℃~201℃),D80(埃克森美孚石油化工公司,沸点206℃~243℃),D100(埃克森美孚石油化工公司,沸点223℃~254℃)、D110(埃克森美孚石油化工公司,沸点249℃~267℃)、D130(埃克森美孚石油化工公司,沸点279℃~313℃)、,Isopar-H(埃克森美孚石油化工公司,沸点179℃~188℃),Isopar-L(埃克森美孚石油化工公司,沸点186℃~201℃),Isopar-M(埃克森美孚石油化工公司,沸点223℃~253℃)。
作为本发明药片中使用的色素可列举的有,例如,1,4-二丁氨基蒽醌、1,4-二异丙氨基蒽醌、1,4-二(2,6-二乙基-4-甲基苯氨基)蒽醌、1-甲氨基-4-邻甲苯氨基蒽醌等蒽醌系蓝色色素。这些色素既可以单独使用,也可以2种以上混合使用,或与颜色不同的其他色素混合使用。
作为本发明药片中使用的抗氧剂可列举的有,例如,二丁基羟基甲苯、丁基羟基苯甲醚、2,2-亚甲基二(4-甲基-6-叔丁基苯酚)、2,6-二叔丁基-4-甲基苯酚等酚类抗氧剂等。
作为本发明药片中使用的稳定剂可列举的有,例如,苯并三唑类紫外吸收剂、二苯甲酮类紫外吸收剂等紫外吸收剂。
本发明药片可以进一步适当地含有其他的杀虫活性成分、忌避活性成分等,由此可以期待进一步提高其效力。
作为其他的杀虫活性成分,可以列举的有,例如,丙烯菊酯(Allethrin)、苯醚菊酯(Phenothrin)、苄呋菊酯(Resmethrin)、氯氰菊酯(Cypermethrin)、溴氰菊酯(Deltamethrin)、氟氯氰菊酯(Cyfluthrin)、炔咪菊酯(Imiprothrin)、醚菊酯(Etof enprox)、杀灭菊酯(Fenvalerate)、甲氰菊酯(Fenpropathrin)、四氟苯菊酯、环戊烯丙菊酯(Terallethrin)、氟氯菊酯(Bifenthrin)、炔丙菊酯等拟除虫菊酯化合物、毒死蜱(Chloropyrifos)等有机磷化合物、残杀威(Propoxur)、甲萘威(Carbaryl)、恶虫酮(Metoxadiazone)、丁苯威(Fenobucarb)等氨基甲酸酯化合物、氟丙氧脲(Lufenuron)、定虫隆(Chlorfluazuron)、氟铃脲(Hexaflumuron)、氟脲杀(Diflubenzuron)、灭蝇胺(Cyromazine)等阻止甲壳质形成的物质、新烟碱(neonicotinoido)类化合物、N-苯基吡唑类化合物等。
作为忌避活性成分,可以列举的有,里哪醇、香茅醛、薄荷醇、薄荷酮、4-异丙基环庚二烯酚酮、香叶醇、桉叶油素(eucalyptol)、嗯二唑酮(Indoxacarb)、蒈烷-3,4-二醇、吡啶-2,5-二甲酸二丙酯、2-(辛基硫)乙醇等。
本发明杀虫片可由纤维质载体或多孔质载体浸渍在由本拟除虫菊酯化合物(1)、酯化合物及可以添加的PBO和溶剂、色素、抗氧剂、稳定剂、香料等混合得到的溶液中而制备。
作为纤维质载体可以列举的有,例如,纸浆、纤维素、棉花等天然纤维、聚酯、丙烯酸类等合成纤维、玻璃纤维、石棉等无机纤维等;作为多孔质载体可以列举的有,例如,硅藻土等多孔质无机物质、素瓷等多孔质磁性物质、聚氨酯泡沫、聚丙烯泡沫等多孔质树脂等。
通常使用的电子捕灭蚊虫用药片的大小约2.2cm*3.5cm*0.28cm,不过并不特别限制于这种形状,随药片的形状的变化可以使用适当调整配合组合物的比例。在本发明中,每1片2.2cm*3.5cm*0.28cm药片通常含有5-200mg左右的酯化合物、约1-20mg的本拟除虫菊酯化合物(1)、还可含有拟除虫菊酯化合物(1)质量0.5-10倍的PBO,需要时可以含合计量为约0.1-4mg的色素、约2-100mg的稳定剂、约2-20mg的香料。
本发明电热灭虫片可以由带加热器的普通电子灭蚊虫器加热到140-200℃来防除害虫。
可以防除的害虫可以是各种有害昆虫、壁虱类等节足动物,特别是飞翔性害虫,例如淡色库蚊、三带喙库蚊等库蚊属、埃及伊蚊、白纹伊蚊等伊蚊属、中华按蚊等按蚊属、家蝇等蝇科、虻科、蚋科、等双翅目害虫。
具体实施方式
下面用实施例的形式详细解释本发明的技术方案和效果,但本发明并不限于以下实施例。
实施例1
把100mg由2%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、0.5%的1,4-二丁氨基蒽醌、40%己二酸二异丙酯以及57.5%的溶剂D60构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片1。
实施例2
把100mg由3%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、0.5%的1,4-二丁氨基蒽醌、40%己二酸二正丁酯以及56.5%的溶剂D80构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片2。
实施例3
把100mg由3%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-1R,反式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、3%的PBO、0.5%的1,4-二异丙氨基蒽醌、35%癸二酸二丁酯以及58.5%的溶剂D80构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片3。
实施例4
把100mg由4%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-1R,反式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、0.5%的1,4-二异丙氨基蒽醌、35%癸二酸二丁酯以及60.5%的溶剂十四碳烷构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片4。
实施例5
把100mg由2%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-1R,顺式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、4%的PBO、0.5%的1,4-二异丙氨基蒽醌、45%苹果酸二-2-乙基己酯以及48.5%的溶剂D80构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片5。
实施例6
把100mg由6%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-1R,反式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、1%的炔丙菊酯、0.5%的1,4-二异丙氨基蒽醌、92.5%己二酸二异丁酯构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片6。
实施例7
把100mg由6%重量(以下无特殊说明均为重量百分数)的2,3,5,6-四氟-4-甲氧甲基苄基-1R,反式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、1%的炔丙菊酯、3%的PBO、0.5%的1,4-二异丙氨基蒽醌、90.5%己二酸二异丁酯构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片7。
实施例8
把100mg由15%重量(以下无特殊说明均为重量百分数)的顺:反比为1∶9的2,3,5,6-四氟-4-甲氧甲基苄基-1R-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、0.5%的1,4-二异丙氨基蒽醌、35%癸二酸二丁酯以及49.5%的溶剂D80构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片8。
实施例9
把100mg由19%重量(以下无特殊说明均为重量百分数)的顺:反比为2∶8的2,3,5,6-四氟-4-甲氧甲基苄基-1R-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯、0.5%的1,4-二异丙氨基蒽醌、35%癸二酸二丁酯以及45.5%的溶剂D80构成的溶液浸渍到由2.2cm*3.5cm*0.28cm的纸浆料和棉绒构成的纤维质载体中,得到本发明的电热灭虫片9。
测试例1
将本发明的的电热灭虫片1-7与目前市售最常用的10mg/片的炔丙菊酯电热蚊香片按照GB13917.5-92进行对蚊虫的药效测定对比,采用密闭圆桶装置。具体过程如下。将电热蚊香片样品通电预热1h,2h,4h,8h,10h,用吸蚊管吸取20头雌性淡色库蚊,放入密闭圆桶测试装置,准确熏杀1min,同时记时,熏后切断电源,并移去电热蚊香片装置,随时计数击倒蚊子的数量,根据结果统计击倒50%试虫(KT50)所需时间,结果示于表1:
表1.
结果显示:本发明的电热灭虫片可以在较长时间内以很好的效果防除飞翔性卫生害虫,其中拟除虫菊酯化合物(1)的环丙烷1位为R构型的异构体药效要明显优于消旋体。添加PBO可以起到一定的增效作用。
Claims (3)
1.一种电热灭虫片,其特征在于该药片含有(1)式所示的拟除虫菊酯,以及酯化合物和纤维质载体或多孔质载体;所述的式(1)的拟除虫菊酯化合物中,R为甲氧甲基、菊酸部分的双键部分为Z构型、且菊酸部分的三元环的立体结构为1R,反式或1R,顺式;即所述的式(1)的拟除虫菊酯化合物是2,3,5,6-四氟-4-甲氧甲基苄基-1R,反式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯,或2,3,5,6-四氟-4-甲氧甲基苄基-1R,顺式-(Z)-3-(3,3,3-三氟-1-丙烯基)-2,2-二甲基环丙烷羧酸酯;所述的酯化合物是己二酸、癸二酸或壬二酸与碳原子数2至10的醇的二酯、苹果酸或乙酰基柠檬酸与碳原子数3至10的醇的酯、月桂酸或棕榈酸与碳原子数3至10的醇的酯、或邻苯二甲酸与碳原子数2至10的醇的二酯
2.根据权利要求1所述的电热灭虫片,其特征在于每1片2.2cm*3.5cm*0.28cm的灭虫药片分别含有1-20mg的式(1)表示的拟除虫菊酯和5-200mg的酯化合物。
3.根据权利要求1所述的电热灭虫片,特征在于还可含有重量为式(1)表示的拟除虫菊酯0.5-10倍的α-[2-(2-丁氧基乙氧基)乙氧基]-4,5-亚甲基二氧-2-丙基甲苯。
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