CN101606779B - The trailing of transparent or semitransparent bottle - Google Patents

The trailing of transparent or semitransparent bottle Download PDF

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Publication number
CN101606779B
CN101606779B CN200910148363.9A CN200910148363A CN101606779B CN 101606779 B CN101606779 B CN 101606779B CN 200910148363 A CN200910148363 A CN 200910148363A CN 101606779 B CN101606779 B CN 101606779B
Authority
CN
China
Prior art keywords
bottle
layer
trailing
pigment
cosmetics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200910148363.9A
Other languages
Chinese (zh)
Other versions
CN101606779A (en
Inventor
阿尔梅·古赫德
乔那桑·克拉克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
COURVAL VERRERIES
Original Assignee
COURVAL VERRERIES
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0807039A external-priority patent/FR2939615B1/en
Application filed by COURVAL VERRERIES filed Critical COURVAL VERRERIES
Publication of CN101606779A publication Critical patent/CN101606779A/en
Application granted granted Critical
Publication of CN101606779B publication Critical patent/CN101606779B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/02Scent flasks, e.g. with evaporator
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/003General methods for coating; Devices therefor for hollow ware, e.g. containers
    • C03C17/004Coating the inside
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D2034/007Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes with special decorative arrangements or form
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/05Details of containers
    • A45D2200/053Transparent containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/22Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes
    • B05D7/227Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes of containers, cans or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/48Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
    • C03C2217/485Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/72Decorative coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/113Deposition methods from solutions or suspensions by sol-gel processes

Abstract

The trailing of the transparent or semitransparent bottle of glass or plastic material; it is used for cosmetic field; in order to accommodate such as perfume or similar cosmetics; this trailing is implemented on inside bottle; on the inner surface of bottle, at least one cover layer is formed by carrying out liquid spray in bottle; it is characterized in that; described solution has the chemical inertness close with glass attribute; described inner covering layer thus constitutes a protective layer; formed and stop to avoid in any migration the quality to cosmetics to cause possible infringement, such as fragrance and/or color and its storage.

Description

The trailing of transparent or semitransparent bottle
Technical field
The present invention relates to the trailing of a kind of transparent or semitransparent bottle for cosmetic field, it passes through One inner covering layer is set inside the bottle of glass or plastic material and reaches to decorate the purpose of bottle.Cover in described Cap rock can be avoided causing the quality of its content, such as perfume, paste etc. when needs migration bottle Infringement, such as affects the fragrance of content and/or color and its storage.
Background technology
Nowadays, aesthetic need to become buyer and select a key factor of this series products.And, no matter Which kind of field this series products is used for, and manufacturers all make every effort to make its product the most attractive in appearance, arouse with this and disappear The desire to buy of the person of expense.
Certainly, fashion, jewelry, cosmetics and perfume area focus on product particularly its packaging very much Situation is the most attractive in appearance, especially perfume manufacturer, tries hard to the bottle by showing one's talent in competition especially Attract client, promote the perfume products of oneself with more attractive in appearance and novel bottle moulding and decoration.
The trailing of known transparent or semitransparent bottle is to spray one layer of colored paint in the inside of bottle.The method Disclose in No. 2851940 French Patent (FRP).Such as one can be realized by the method and have single be Upholstery to multiple decorative layers.What described method used paints the epoxy-based lacquers for liquid or polyurethane paint, or Person is by the epoxy powder of no-solvent type, polyurethane powder, polyester powder or even polyethylene and derivative Thing powder is prepared from.But this kind of decoration with excellent effect but has a problem that, because can fill Most of perfume in the bottle of so decoration may be with this single decorative layer or described multiple decorative layers Attribute is not compatible, and perfume can be polluted by this decorative layer, destroys its quality.One solution is Arrange a natural bed in last step to permeate to perfume with the harmful components stopping enamelled coating.
It is known that a kind of method proposed in No. 2889485 french patent application, according to the method decoration One or more internal decking sheet are glaze layer.But the method defect requires heat to such as when being roasting The high temperature of 800 DEG C, its manufacturing cost height can not be used for the bottle of plastic material.
Summary of the invention
Bottle alleged by the present invention, it is thus understood that for such as perfume, cologne, the cosmetics such as paste All types of packaging bottles.
The present invention provides a kind of new method decorating bottle inside, can be obtained very by the method Exquisite decorative effect, and the obstruction layer with buffer action can protect cosmetics not to be destroyed, and Described bottle can be glass or plastic material.
The method according to the invention, this ornamentation is implemented on inside bottle, by complete on the inner surface of bottle All standing one decoration, this decoration is made up of an inner covering layer contacted with cosmetics.According to the present invention's Trailing, bottle at least has a decorative layer, i.e. furtherly, and described decoration can be covered by multiple Cap rock is constituted, and can be wherein inertia nexine with the layer of perfume contact.Described inertia nexine has and connects with glass Near characteristic.
Therefore, the glass proposed according to the present invention or plastic material, the trailing of transparent or semitransparent bottle, Described bottle is used for cosmetic field, in order to accommodate liquid of such as perfume or the like, the spy of described method Levying and be, this decorative method realizes by forming at least one internal decking sheet in bottle interior spray.Institute State layer be one for isolating perfume, have and the chemically inert layer of glass similar properties.
According to the present invention, that arrange from inside and perfume contact inertia nexine be one with silicon dioxide and Pigment is the inorganic product layer of main component, and with preferably one by sol-gel process (SOLGEL) The inorganic polymer layers prepared.The layer being arranged such is inert polymerization nitride layer, and it has the spy close with glass Property.
Constitute inner covering layer decorative layer, be by one there is elongated portion, one end has nozzle, permissible Stretch into the low-pressure pneumatic atomizing lance within bottle, from bottle internal directly on glass (or plastics, In the case of bottle is plastic material) it is atomized what a kind of coloured or colourless liquid realized.In spray process, Nozzle and bottle relative motion are to obtain uniform enamelled coating.Therefore nozzle is configured to can be vertically around certainly Body rotates.Equally being vertically arranged by nozzle, the vertical axis making bottle be formed around nozzle rotates.Also may be used So that bottle is disposed vertically, it is allowed to relative to nozzle rotation.
Owing to interior spray is formed in the bottle of heat, therefore a step before spraying is to add bottle Heat, such as, use hot-air or allow bottle pass through heated oven, make bottle reach about 40 DEG C to 50 DEG C it Between temperature.
Spraying is to realize inside bottle by the outlet of nozzle being stretched into, and nozzle is arranged on injection spray pipe One end, and be preferably made up of center tube, this nozzle has one group of scattering hole, described scattering hole and receiving The container of liquid to be sprayed is connected.Certainly, atomizer can have other various structures.
Atomization is that liquid is formed in the ambient temperature of hot bottle.It is dry that the next one after spraying supplements step Dry then cool down.
It is understood that bottle should carry out front heating of spraying, in order to decorative layer is preferably attached to bottle Inner surface on.
Detailed description of the invention
Method according to the invention it is possible in advance before arranging layer described previously, implement such as one or many The individual decorative layer pre-set, the one or more layer defines the decorative layer being positioned at last layer and bottle Interlayer between wall.
As such, it is possible to such as by the first color (C1) liquid or powder coatings for having the first color (C1) The first decorative layer.So later intermediate steps for example is by laser machining and is specifying this layer of area damages. By destroying the operation of described layer, colourless mark zone can be set, then, spray the second color in the vial The liquid of color (C2) or powder, to implement second decorative layer with the second color (C2).Externally, Only visible the second described decorative layer from the region that the first decorative layer of described first color is destroyed.Logical Cross the method, it is possible to achieve the decoration of different color, it is also possible to such as Laser Processing destroy one or Multiple internal decking sheet, reserve arming lace, in order to can see that the horizontal level of bottle content capacity.With Rear spraying inertia last layer, to guarantee between chemicals or stain and the bottle content contained in decorative layer not There is any infiltration.
You need to add is that, this method can realize a kind of interior trim, such as, have three different color layers, And can only destroy ground floor and manifest the second layer in destroyed region as required, and in other region, When said two layer is all destroyed, then can manifest third layer, Laser Processing only destroys the paint of pigment Layer.
According to another embodiment of the invention, it is possible to achieve a kind of by the layer structure of two or more different color The interior trim become, only laser damage ground floor can make the second layer manifest in destroyed region, and works as said two Layer all when other region is by laser damage, then can manifest third layer in this region.
Present invention is equally related to the method according to the invention and decorate the bottle obtained, it is characterised in that be described little Bottle has upholstery, and it is preferably glass material, it is also possible to for plastic material, such as thermoplastic polyester Plastics (PET, PET-A, PET-G ...), poly methyl methacrylate plastic (PMMA), polyolefin plastics is such as Polyethylene (PE or PE-HD high density polyethylene (HDPE)) or polypropylene (PP), polystyrene (PS), or propylene tree Fat, or even mix material, such as Surlyn Brand or Abcite Commercially available material.
The inner covering layer of bottle is formed and stops to avoid damaging bottle content, and this layer is inorganic material, and As previously described, it prepares preferably through sol-gel process (SOLGEL), and this product contains two Silicon oxide substrate (between 50% to 95%, preferably 90%) and mineral, such as zircon, titanium, or The mixture of both persons.Adding the pigment in silica matrix to is such as the colour painted to internal layer Pigment.Described pigment has such as metal-oxide, such as bismuth oxide, zinc oxide, stannum oxide, copper oxide, oxygen Change chromium, sodium oxide and aluminium oxide.For the pigment painted to described layer for such as cobalt aluminate, white carbon black even Graphite.Described pigment or be inorganic pigment, or be limited in the silica matrix of described layer organic Pigment, described pigment is thus without penetrating in bottle content.
Being a kind of inorganic polymer for forming the atomized liquid of the internal layer contacted with bottle content, this is inorganic Polymer passes through simple chemical reaction, passes through sol-gel when close to ambient temperature (20 DEG C-150 DEG C) Method (SOLGEL) prepares.It is synthesized by spirit (solution obtained by distilled spirit aromatic radical), Silicon and alkyl organo-functional group (Hydrocarbon (alkane) derived molecules only includes single covalent bond).Due to When close to ambient temperature, main component reacts, as long as not thermally decomposed, and organic moiety and ore deposit Thing part just can combine.Organic moiety is dissolved in synthetic, and so, desired molecule all has Just mineral coagulant is defined time standby.The organic moiety ratio being limited in that embedding mineral portion of this method Less.The feasible method of the second is the precursor using and having hydrolysis properties and organic functions simultaneously, its hydrolysis Characteristic produces silicate system, and organic functions is transplanted and is maintained in mineral tissue.Organic segment is through carbon silicon bonds (Si-C) being connected with silicon, hydrolysis is less likely to occur described carbon silicon bonds.The characteristic of organic moiety makes it permissible As constituting body or variety body, because it is similar with the composition body of the glass of high temperature process and variety body.
Certainly, the invention is not limited in several embodiments as described above, but include other equally The technology of all equivalences and the combination of these technology.

Claims (27)

1. the trailing of the transparent or semitransparent bottle of glass or plastic material, described bottle is used for cosmetics Field, in order to accommodate cosmetics, this trailing is implemented on inside bottle, by carrying out liquid in bottle It is sprayed on the inner surface of bottle and forms at least one decorative layer, it is characterised in that in contacting with cosmetics Decorative layer is inorganic polymer layers, and this inorganic polymer layers contains silica matrix and is limited in titanium dioxide Pigment in silicon matrix, has the chemical inertness close with glass attribute, in order to by liquid spray at bottle Interior formation internal decking sheet, and be consequently formed protective layer can to avoid in any migration, cosmetics quality being caused The infringement of energy.
The trailing of bottle the most according to claim 1, it is characterised in that described cosmetics are fragrant Water.
The trailing of bottle the most according to claim 1, it is characterised in that add silicon dioxide to Pigment in substrate is dyeing pigment.
The trailing of bottle the most according to claim 3, it is characterised in that described dyeing pigment is Inorganic pigment.
The trailing of bottle the most according to claim 3, it is characterised in that described dyeing pigment is Organic pigment.
6. according to the trailing of the bottle according to any one of Claims 1 to 5, it is characterised in that with change It is containing silica matrix and mineral zircon, titanium that cosmetic contacts and formed the inertia internal decking sheet of protective layer Inorganic polymer layers.
7. according to the trailing of the bottle according to any one of Claims 1 to 5, it is characterised in that described Liquid spray is to spray in ambient temperature in hot bottle, heats bottle before spraying.
The trailing of bottle the most according to claim 7, it is characterised in that be dried after spraying Then cool down.
9. according to the trailing of the bottle according to any one of Claims 1 to 5, it is characterised in that with change Cosmetic contacts and is formed the inertia internal decking sheet of protective layer and is formed directly on glass or plastics.
10. according to the trailing of the bottle according to any one of Claims 1 to 5, it is characterised in that in spray Before painting contacts with cosmetics and forms the inertia internal decking sheet of protective layer, pre-set one or more decoration Layer, those decorative layers are sandwiched between decorative layer and the vial inside-wall of last layer.
The trailing of 11. bottles according to claim 10, it is characterised in that one of them decoration Layer is paint.
The trailing of 12. bottles according to claim 11, it is characterised in that one of them decoration Layer is the paint with pigment.
The trailing of 13. bottles according to claim 10, it is characterised in that one of them decoration Layer is formed by spraying liquid or powder.
The trailing of 14. bottles according to claim 10, it is characterised in that form a decoration Layer, is then destroyed the appointment region of this decorative layer, is then carried out last inert layer by the method for laser.
The trailing of 15. bottles according to claim 10, it is characterised in that upholstery is passed through The layer of two or more different color is formed, or before other area damages two-layer and manifest third layer.
16. according to the trailing of the bottle according to any one of Claims 1 to 5, it is characterised in that institute State internal decking sheet to be prepared by sol-gel process.
17. 1 kinds of bottles, for cosmetic field, in order to accommodate cosmetics, it uses claim 1~16 According to any one of trailing carry out upholstery, it is characterised in that bottle is transparent or semitransparent, For glass or plastic material, the inner surface of this bottle forms at least one decorative layer, contact with cosmetics Decorative layer is the inorganic polymer containing silica matrix with the pigment being limited in silica matrix, Having the chemical inertness close with glass attribute, it is right to avoid in any migration that this decorative layer constitutes protective layer Cosmetics quality causes possible infringement.
18. bottles according to claim 17, it is characterised in that described cosmetics are perfume.
19. bottles according to claim 17, it is characterised in that described pigment is dyeing pigment.
20. bottles according to claim 19, it is characterised in that described dyeing pigment is inorganic pigment.
21. bottles according to claim 19, it is characterised in that described dyeing pigment is organic pigment.
22. bottles according to claim 17, it is characterised in that described pigment be metal-oxide, Cobalt aluminate, white carbon black, graphite.
23. according to the bottle according to any one of claim 17~22, it is characterised in that contact with cosmetics And the internal decking sheet forming protective layer is containing silica matrix and mineral zircon, the inorganic polymer layers of titanium.
24. according to the bottle according to any one of claim 17~22, it is characterised in that contact with cosmetics And the internal decking sheet forming protective layer directly forms internal layer on glass or plastic jar.
25. according to the bottle according to any one of claim 17~22, it is characterised in that include one or many Individual decorative layer, those decorative layers are sandwiched between decorative layer and the vial inside-wall of last layer.
26. bottles according to claim 25, it is characterised in that described one or more decorative layers For paint.
27. according to the bottle according to any one of claim 17~22, it is characterised in that described internal decking sheet Prepared by sol-gel process.
CN200910148363.9A 2008-06-16 2009-06-16 The trailing of transparent or semitransparent bottle Expired - Fee Related CN101606779B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0803351A FR2939614A1 (en) 2008-06-16 2008-06-16 PROCESS FOR DECORATING A TRANSPARENT OR TRANSLUCENT BOTTLE
FR0803351 2008-06-16
FR0807039A FR2939615B1 (en) 2008-06-16 2008-12-15 PROCESS FOR DECORATING A TRANSPARENT OR TRANSLUCENT BOTTLE
FR0807039 2008-12-15

Publications (2)

Publication Number Publication Date
CN101606779A CN101606779A (en) 2009-12-23
CN101606779B true CN101606779B (en) 2016-09-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN200910148363.9A Expired - Fee Related CN101606779B (en) 2008-06-16 2009-06-16 The trailing of transparent or semitransparent bottle

Country Status (2)

Country Link
CN (1) CN101606779B (en)
FR (1) FR2939614A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109123961B (en) * 2018-09-21 2023-12-08 象牙塔(上海)国际贸易有限公司 Portable protective housing of perfume bottle
CN112890779A (en) * 2021-01-28 2021-06-04 贵州省农作物品种资源研究所 Preparation of whitening and whitening effect evaluation method of whitening and whitening gelatin dry powder
CN113308101B (en) * 2021-07-14 2023-01-10 威骏(上海)环保包装有限公司 Extinction degradable daily chemical bottle and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648009A (en) * 2004-01-09 2005-08-03 肖特股份公司 Container with internal decoration part

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648009A (en) * 2004-01-09 2005-08-03 肖特股份公司 Container with internal decoration part

Also Published As

Publication number Publication date
CN101606779A (en) 2009-12-23
FR2939614A1 (en) 2010-06-18

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