CN101602896A - Brown disperse dye composition - Google Patents
Brown disperse dye composition Download PDFInfo
- Publication number
- CN101602896A CN101602896A CNA2009101007280A CN200910100728A CN101602896A CN 101602896 A CN101602896 A CN 101602896A CN A2009101007280 A CNA2009101007280 A CN A2009101007280A CN 200910100728 A CN200910100728 A CN 200910100728A CN 101602896 A CN101602896 A CN 101602896A
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- CN
- China
- Prior art keywords
- dye
- formula
- dye monomer
- monomer
- fastness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000000986 disperse dye Substances 0.000 title claims abstract description 19
- 239000000975 dye Substances 0.000 claims abstract description 60
- 239000000178 monomer Substances 0.000 claims abstract description 39
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 238000000859 sublimation Methods 0.000 abstract description 6
- 230000008022 sublimation Effects 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000013508 migration Methods 0.000 abstract description 4
- 230000005012 migration Effects 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000002131 composite material Substances 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 9
- ROPYWXVRNREIQD-UHFFFAOYSA-N 2-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]ethyl acetate Chemical compound C1=CC(N(CCC#N)CCOC(=O)C)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl ROPYWXVRNREIQD-UHFFFAOYSA-N 0.000 description 7
- 238000004043 dyeing Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000001049 brown dye Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- SQECYPINZNWUTE-UHFFFAOYSA-N 1,2,3,5,6,7,8,8a-octahydroindolizine-1,2-diol Chemical compound C1CCCC2C(O)C(O)CN21 SQECYPINZNWUTE-UHFFFAOYSA-N 0.000 description 1
- MUERWWKQVXXPML-UHFFFAOYSA-N 3-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound ClC1=CC([N+](=O)[O-])=CC(Cl)=C1N=NC1=CC=C(N(CCC#N)CCC#N)C=C1 MUERWWKQVXXPML-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention discloses a brown disperse dye composition which comprises the following components in percentage by weight: 15-43% of at least one dye monomer A shown as a formula ; 5-14.3% of at least one dye compound B shown as a formula (2); 3.6-10.5% of a dye monomer C shown in a formula (3); the balance of auxiliary agent. The disperse dye composition has excellent compatibility, high lifting force and good migration property; the dye has good sublimation fastness, washing fastness and rubbing fastness, particularly excellent light fastness and wide pH value range.
Description
Technical field
The present invention relates to a kind of brown disperse dye composition, be applicable to the dyeing and the stamp of terylene and BLENDED FABRIC thereof, also be applicable to simultaneously to wash/dyeing of cotton co-bathing dyeing and ultra-fine fibre.
Background technology
In early days, brown dye generally is made up of Red 167 #, Disperse Blue-56 # and DISPERSE ORANGE 30 200 30#, though said composition pH scope is wider, but because Disperse Blue-56 # is the low temperature modification dyestuff, Red 167 #, DISPERSE ORANGE 30 200 30# are the high temperature modification dyestuff, dye the curve difference on them, compatibleness is undesirable, so this dye composite is replaced by new dye composite gradually.
Brown dye in the market generally is made up of Red 167 #, Disperse Blue-79 # and DISPERSE ORANGE 30 200 30#.In secular use, this dye composite also exposes some weakness.Its reason is that Disperse Blue-79 # is to alkali, comparatively responsive to temperature.Its composition repeatability is relatively poor, and the migration phenomenon is obvious, brings inconvenience when printing and dyeing in enormous quantities.
Summary of the invention
The invention provides all good brown disperse dye composition of a kind of compatibleness, equalization, sublimation fastness, light fastness, particularly, this dye composite dye bath pH value scope is wide, and the migration phenomenon is not obvious during dyeing.
A kind of brown disperse dye composition, by weight percentage, composed of the following components:
15～43% at least a dye monomer A as the formula (1)
X
1, X
2Be independently nitro, cyano group or halogen separately;
R
1Be CH
2CH
2CN or CH
2CH
3Or CH
2CH
2OCOCH
3
5～14.3% at least a dye monomer B as the formula (2)
X
3Be H or NHCOCH
2CH
3Or NHCOCH
3
R
2Be CH
2CH
2OCOCH
3Or CH
2CH
2CN;
3.6～10.5% as the formula (3) dye monomer C
Surplus is an auxiliary agent.
Described dye monomer A is one or more the mixture of formula (1-1), (1-2), (1-3), (1-4):
Described dye monomer B is one or more the mixture of formula (2-1), (2-2):
A kind of preferred brown disperse dye composition, by weight percentage, composed of the following components: at least a dye monomer as the formula (1) of 20-35% A; At least a dye monomer B as the formula (2) of 6-9%; 4-7% dye monomer C as the formula (3); Surplus is an auxiliary agent.The dye composite pH scope of this prescription is wider, and light fastness is better.
A kind of preferred brown disperse dye composition, by weight percentage, composed of the following components: at least a dye monomer as the formula (1) of 15-25% A; At least a dye monomer B as the formula (2) of 8-13%; 7-10% dye monomer C as the formula (3); Surplus is an auxiliary agent.The dye composite lifting force of this prescription is better.
A kind of preferred brown disperse dye composition, by weight percentage, composed of the following components: at least a dye monomer as the formula (1) of 30%-43% A; At least a dye monomer B as the formula (2) of 6-8%; 4-6% dye monomer C as the formula (3); Surplus is an auxiliary agent.The dye composite sublimation fastness of this prescription is better.
Described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents etc. commonly used when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.
Disperse dye composition of the present invention can be with the preparation of following method: after the former dyestuff of dye monomer is mixed in proportion, carry out corpusculed with pulverizers such as sand mill or shredders in the presence of auxiliary agent, water and other tensio-active agent, then spraying drying.Above-mentioned dye monomer all can adopt the commercially available prod.
Disperse dye composition of the present invention can be aqueously behind the corpusculed, can be powdery, particulate state after the spraying drying.The compatibleness of this dye composite is fabulous, the lifting force height, and migration property is good; Sublimation fastness, washing fastness, crock fastness are all good, and particularly light fastness is splendid, pH value scope is wide.
Embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
Embodiment 1～24
According in the table 1 shown in the data, will be suc as formula the former dyestuff of the dispersed dye shown in (1), (2), (3) with after condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A), other tensio-active agent and water mix, grind dispersion with sand mill, carry out spraying drying then.
The DISPERSE YELLOW 163# that dye monomer shown in its Chinese style (1-1) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 30# that dye monomer shown in the formula (1-2) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 61# that the DISPERSE ORANGE 30 200 44# that dye monomer shown in the formula (1-3) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the dye monomer shown in the formula (1-4) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce.
The Red 167 # that the Disperse Red 54# that dye monomer shown in the formula (2-1) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the dye monomer shown in the formula (2-2) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce.
The EX-SF DISPERSE BLUE EX-SF 300 367# that dye monomer C shown in the formula (3) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce.
Table 1:
| 18 | (1-3) | 23 | (2-2) | 6.1 | (3) | 6.9 | 85A | 64 |
| 19 | (1-1) | 26 | (2-1) | 13.1 | (3) | 5.3 | 83A | 55.6 |
| 20 | (1-1) (1-2) (1-3) (1-4) | 12 3 3 3 | (2-1) | 6.5 | (3) | 7.9 | Dispersing agent CNF | 64.6 |
| 21 | (1-2) | 24 | (2-1) (2-2) | 6 1.8 | (3) | 8.1 | Dispersant MF | 60.1 |
| 22 | (1-3) | 32 | (2-2) | 10.3 | (3) | 9.5 | Dispersing agent NNO | 48.2 |
| 23 | (1-1) (1-4) | 20 16 | (2-1) | 6.8 | (3) | 10.1 | 85A | 47.1 |
| 24 | (1-1) (1-2) (1-3) (1-4) | 12 12 12 3 | (2-2) | 7.0 | (3) | 8.1 | 83A | 45.9 |
Make the brown dye formed by Red 167 #, Disperse Blue-79 # and DISPERSE ORANGE 30 200 30# on dye composite and the existing market after the dispersed dye of the foregoing description, auxiliary agent, water mixed as a comparison case, carry out performance test, comparison.Testing method is well following:
Respectively get the disperse dye composition that 15 gram embodiment 1-24 make, it is 1g/500ml dispersion suspension liquid that water is mixed with concentration respectively.The water of drawing 10ml, 60ml suspension and 90ml, 40ml respectively mixes; Regulate dye bath pH value to 5 with acetic acid, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.Adopt GB GB/T3921-1997, GB/T3920-1997, GB/T5718-1997, GB/T8427-1998, GB/T2397-2003 to measure, its washing fastness, crock fastness, sublimation fastness, light fastness, lifting force test result are shown in Table 2.
Table 2
| The embodiment title | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) | Light fastness (20h) | Lifting force | The PH scope |
| 1 | 5 | 4-5 | 4-5 | 6-7 | A - | 3-9 |
| 2 | 5 | 4-5 | 4-5 | 6-7 | A - | 3-7 |
| 3 | 5 | 4-5 | 4-5 | 6-7 | A - | 3-7 |
| 4 | 5 | 4-5 | 4 | 7 | A | 3-9 |
| 5 | 4-5 | 4-5 | 4 | 6-7 | A | 3-9 |
| 6 | 4-5 | 4-5 | 4 | 7 | A | 3-7 |
| 7 | 5 | 4 | 4 | 6-7 | A | 3-7 |
| 8 | 5 | 4-5 | 4 + | 6-7 | A - | 3-8 |
| 9 | 4-5 | 4-5 | 4 | 7 - | A | 3-9 |
| 10 | 4-5 | 4-5 | 4 | 7 | A | 3-7 |
| 11 | 5 | 4-5 | 4 | 6-7 | A | 3-8 |
| 12 | 5 | 4-5 | 4 | 7 | A - | 3-9 |
| 13 | 4-5 | 4-5 | 4 | 7 - | A | 3-7 |
| 14 | 4-5 | 4-5 | 4 | 7 - | A | 3-7 |
| 15 | 5 | 4 | 4 | 7 | A | 3-7 |
| 16 | 4-5 | 4-5 | 4 | 7 | A | 3-9 |
| 17 | 5 | 4-5 | 4 + | 7 | A - | 3-9 |
| 18 | 4-5 | 4-5 | 4 | 7 - | A | 3-7 |
| 19 | 5 | 4 | 4 | 7 | A | 3-9 |
| 20 | 4-5 | 4-5 | 4 | 6-7 | A | 3-9 |
| 21 | 4-5 | 4-5 | 4 | 7 - | A | 3-9 |
| 22 | 5 | 4-5 | 4 | 7 - | A | 3-7 |
| 23 | 5 | 4-5 | 4 | 6-7 | A | 3-9 |
| 24 | 5 | 4-5 | 4 | 7 - | A - | 3-7 |
| Comparative Examples | 4 | 4 | 3-4 | 6-7 | A-B | 3-5 |
Claims (6)
1, a kind of brown disperse dye composition, by weight percentage, composed of the following components:
15～43% at least a dye monomer A as the formula (1)
X
1, X
2Be independently nitro, cyano group or halogen separately;
R
1Be CH
2CH
2CN or CH
2CH
3Or CH
2CH
2OCOCH
3
5～14.3% at least a dye monomer B as the formula (2)
X
3Be H or NHCOCH
2CH
3Or NHCOCH
3
R
2Be CH
2CH
2OCOCH
3Or CH
2CH
2CN;
3.6～10.5% as the formula (3) dye monomer C
Surplus is an auxiliary agent.
2, brown disperse dye composition as claimed in claim 1 is characterized in that: described dye monomer A is one or more the mixture among formula (1-1), (1-2), (1-3), (1-4):
3, brown disperse dye composition as claimed in claim 1 is characterized in that: described dye monomer B is one or more the mixture among formula (2-1), (2-2):
4, brown disperse dye composition as claimed in claim 1 is characterized in that: by weight percentage, composed of the following components: at least a dye monomer as the formula (1) of 20-35% A; At least a dye monomer B as the formula (2) of 6-9%; 4-7% dye monomer C as the formula (3); Surplus is an auxiliary agent.
5, brown disperse dye composition as claimed in claim 1 is characterized in that: by weight percentage, composed of the following components: at least a dye monomer as the formula (1) of 15-25% A; At least a dye monomer B as the formula (2) of 8-13%; 7-10% dye monomer C as the formula (3); Surplus is an auxiliary agent.
6, brown disperse dye composition as claimed in claim 1 is characterized in that: by weight percentage, composed of the following components: at least a dye monomer as the formula (1) of 30%-43% A; At least a dye monomer B as the formula (2) of 6-8%; 4-6% dye monomer C as the formula (3); Surplus is an auxiliary agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101007280A CN101602896B (en) | 2009-07-20 | 2009-07-20 | Brown disperse dye composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101007280A CN101602896B (en) | 2009-07-20 | 2009-07-20 | Brown disperse dye composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101602896A true CN101602896A (en) | 2009-12-16 |
| CN101602896B CN101602896B (en) | 2012-07-25 |
Family
ID=41468798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101007280A Active CN101602896B (en) | 2009-07-20 | 2009-07-20 | Brown disperse dye composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101602896B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660144A (en) * | 2012-04-18 | 2012-09-12 | 浙江闰土股份有限公司 | Composite disperse dye composition |
| CN102924970A (en) * | 2012-11-07 | 2013-02-13 | 上海贝通色彩科技有限公司 | Alkali-resistant disperse dye composition and preparation method and application thereof |
| CN104629492A (en) * | 2015-02-04 | 2015-05-20 | 郑华娟 | Disperse violet complex dye composition |
| CN106752081A (en) * | 2016-12-30 | 2017-05-31 | 浙江闰土研究院有限公司 | A kind of disperse dye composition and its production and use |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100354377C (en) * | 2005-06-07 | 2007-12-12 | 浙江闰土股份有限公司 | Composite environment-friendly disperse grey dye |
| CN100543087C (en) * | 2007-02-14 | 2009-09-23 | 浙江龙盛染料化工有限公司 | Azo disperse dye composition |
-
2009
- 2009-07-20 CN CN2009101007280A patent/CN101602896B/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660144A (en) * | 2012-04-18 | 2012-09-12 | 浙江闰土股份有限公司 | Composite disperse dye composition |
| CN102660144B (en) * | 2012-04-18 | 2014-04-16 | 浙江闰土股份有限公司 | Composite disperse dye composition |
| CN102924970A (en) * | 2012-11-07 | 2013-02-13 | 上海贝通色彩科技有限公司 | Alkali-resistant disperse dye composition and preparation method and application thereof |
| CN104629492A (en) * | 2015-02-04 | 2015-05-20 | 郑华娟 | Disperse violet complex dye composition |
| CN106752081A (en) * | 2016-12-30 | 2017-05-31 | 浙江闰土研究院有限公司 | A kind of disperse dye composition and its production and use |
| CN106752081B (en) * | 2016-12-30 | 2020-05-01 | 浙江闰土研究院有限公司 | Disperse dye composition and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101602896B (en) | 2012-07-25 |
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