CN101591162B - Novel environment-friendly composite material and application thereof - Google Patents
Novel environment-friendly composite material and application thereof Download PDFInfo
- Publication number
- CN101591162B CN101591162B CN2009103039178A CN200910303917A CN101591162B CN 101591162 B CN101591162 B CN 101591162B CN 2009103039178 A CN2009103039178 A CN 2009103039178A CN 200910303917 A CN200910303917 A CN 200910303917A CN 101591162 B CN101591162 B CN 101591162B
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- CN
- China
- Prior art keywords
- composite material
- mould
- friendly composite
- environment
- magnesium chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0004—Compounds chosen for the nature of their cations
- C04B2103/0013—Iron group metal compounds
- C04B2103/0014—Fe
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0004—Compounds chosen for the nature of their cations
- C04B2103/0017—Refractory metal compounds
- C04B2103/0019—Ti
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00965—Uses not provided for elsewhere in C04B2111/00 for household applications, e.g. use of materials as cooking ware
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a novel environment-friendly composite material and application thereof, and belongs to the technical field of material preparation. The composite material comprises raw materials of magnesium oxide and magnesium chloride taken as substrates, sawdust powder or sand or bamboo flour taken as a filler, and silicon dioxide and titanium dioxide added as active agents. The method for preparing the composite material comprises the following steps: dissolving the magnesium chloride into water 12 hours earlier in a ratio of 1:1-2; then, mixing the solution with other raw materials evenly; pouring the mixture into a mould for natural solidification or heating solidification; and obtaining the formed composite material after mould stripping. The novel environment-friendly composite material can be used for preparing tea trays, tea sets, rilievo and various decorating boards with carving effect. The novel environment-friendly composite material overcomes the defects of the prior single material and composite material, has the advantages of scientific and reasonable raw material matching, broad and rich raw material sources, environmental protection and energy conservation, low price, simple manufacture process, and excellent performance of prepared products, and has strong use and decoration effects and strong market competitive force.
Description
Technical field
The invention belongs to technical field of material, more specifically relate to a kind of novel environment-friendly composite material and application thereof.
Background technology
Tea tray on the market, tea set, embossment or the various single wood materials of the many employings of materials such as dalle with engraving effect are made, and wood material costs an arm and a leg, and too much felling timber also can bring harm to environment.Also have the stone of employing matter, beautiful material to make, cost of material is expensive, processing is inconvenient but all exist, and manufacture craft takes time and effort, shortcomings such as cost height.Various ornamental matrix material is also arranged now on the market, but because raw material and making different, have that performance is bad, cost is high more, make the shortcoming of inconvenience or the like.
Summary of the invention
The purpose of this invention is to provide a kind of novel environment-friendly composite material and application thereof, in order to solve the defective of above-mentioned existing single-material or matrix material, its proportioning raw materials is scientific and reasonable; Wide material sources are abundant; Environment protecting and power-saving, cheap, manufacture craft is simple; The excellent product performance of preparation possesses very strong use and decorative effect and the market competitiveness.
Novel environment-friendly composite material of the present invention is characterized in that: the raw material of said matrix material comprises: making base-material with Natural manganese dioxide and magnesium chloride, is filler with sawdust powder or sand or bamboo powder, adds with silicon-dioxide and titanium oxide as promoting agent; The preparation method is: is 1 with magnesium chloride and water according to mass ratio: the ratio of 1-2 was melted in water in 12 hours in advance, stirred with other raw materials mix again, poured in the mould, and after natural coagulation or heat was solidified, depanning was prepared into the matrix material of moulding.
Novel environment-friendly composite material of the present invention can be used to prepare tea tray, tea set, embossment, various dalle with engraving effect.
Remarkable advantage of the present invention is:
Raw material of the present invention forms through the scientific formula easy making; Its starting material wide material sources are abundant, environment protecting and power-saving, and cheap, manufacture craft is simple.Can produce the dalle of tea tray tea set and embossment or various engraving effects.The imitative wood of quality, stone are the ideal substitutes of tea set such as wooden, Shi Zhi or dalle product, possess very strong use and decorative effect and the market competitiveness.
The product that the present invention produces has resistance to acids and bases, resistivity against fire, heat insulating ability, moisture absorption, and specific functions such as ageing-resistant, corrosion-resistant, self-cleaning, Ginkgo Biloba Leaf Extract, and wear resistance and hardness have oxidation susceptibility simultaneously, have the antibiotic and sterilizing performance.
Product appearance of the present invention is attractive in appearance changeable, clean mark, good quality, moulding arbitrarily, a great variety of models.Surface treatment is simple, but water mill, waxing, paint, glazing etc. possess the toughness of woodwork, or the quality of stoneware are hard, and intensity is high, anti-folding, shock resistance.Fire-proof and damp-proof, oil resistant is water-fast, and is corrosion-resistant, and heat-insulating sound-insulating fire prevention is aging not indeformable, does not turn black, and mouse bite preventing is damaged by worms, and is durable in use, and the raw materials for production like one type of urea-formaldehyde resin etc. are never used in environmental protection, do not produce formaldehyde, benzene, ammonia and radiocontamination.
Embodiment
Each component of the raw material of matrix material comprises: according to mass fraction:
Natural manganese dioxide 8-10 part
Magnesium chloride 8-10 part
Silicon-dioxide and titanium oxide (according to any mass ratio) 1-3 part
Sand or sawdust powder or bamboo powder 3-10 part.
The preparation method is: is 1 with magnesium chloride and water according to mass ratio: the ratio of 1-2 was melted in water in 12 hours in advance, stirred with other raw materials mix again, poured in the mould, and after natural coagulation or heat was solidified, depanning was prepared into the matrix material of moulding.
When mixing, can also add versicolor pigment, this pigment is used pigment for finishing material commonly used, and as preferably adding versicolor iron oxide pigment, the color of adding and consumption can be according to the color needs adjustment of product.
Also comprise glass fiber in the raw material in the said matrix material, when mixing, add that the addition of said glass fiber is 0-4 part according to mass fraction, add glass fiber and increase toughness of products.
This novel environment-friendly composite material is used to prepare tea tray, tea set, embossment, various dalle with engraving effect; The preparation process is: at first according to the production mould of making, before the preparation with the mould waxing or go up releasing agent so that product is detached mould; Is 1 with magnesium chloride and water according to mass ratio: the ratio of 1-2 was melted in water in advance in 12 hours; Again with other raw material mixing and stirring proportionally; Pour in the mould; The natural room temperature held solidified in 3-10 hour or heat solidified in held 3-10 hour to 25 ℃-50 ℃ after, depanning is the moulding product, the moulding product surface is through polishing, waxing, paint, cement paint or use low temperature glaze to do to prepare finished product after handle on the surface.
Said mould is planted with woodcarving, stone carving or mud carver and is carved the product of making or directly buying various material outward appearances, or produces mould with silica gel, gypsum or glass reinforced plastic, plastics, leather, iron or steel.
Matrix material of the present invention is nontoxic, tasteless, is particularly suitable for being used as tea tray, tea set.
Magnesium chloride, Natural manganese dioxide and sand or sawdust powder or bamboo powder interact in the composite material by adopting raw material of the present invention; Can play the bonding effect of nature; Need not add any organic adhesive again; Make this matrix material nonpoisonous and tasteless, do not contain any objectionable impurities, possess the toughness of woodwork and the hard quality of stoneware.
The process test determination: matrix material water logging 48h of the present invention is indeformable, at plum rain season, and no buckling deformation; Has good humidity resistance, bending strength: 28-38MPa, bending resistance bullet mould: 3.0-4.5GPa; Tensile strength: 30-38MPa; Wear resistance: 0.01-0.03g/100r, erosion resistance (rate of weight loss): 0.4-0.6, water-intake rate (48 hours rates of body weight gain): 0.5%.
Below be several embodiments of the present invention, further specify the present invention, but the present invention is not limited only to this.
Embodiment 1
The tea tray tea set
Each component of the raw material of matrix material comprises: according to mass fraction:
8 parts in Natural manganese dioxide
8 parts in magnesium chloride
1 part of silicon-dioxide and titanium oxide (according to any mass ratio)
3 parts in sand or sawdust powder or bamboo powder.
Color needs according to product when mixing add pigment, add yellow, brown and green iron oxide pigment, add consumption color adjustment as required, like the color of furnishing log.
The preparation process is:
At first according to the production tea tray tea set mould of making, mould is planted with woodcarving, stone carving or mud carver and is carved the product of making or directly buying various material outward appearances, or produces mould with silica gel, gypsum or glass reinforced plastic, plastics, leather, iron or steel;
Before the preparation with mould waxing or go up releasing agent so that product is detached mould; Is that 1: 1 ratio was melted in water in advance in 12 hours with magnesium chloride and water according to mass ratio; Again with other raw material mixing and stirring proportionally; Pour in the mould; Natural coagulation 5-8 hour or heat solidified in held 3-4 hour to 40 ℃-50 ℃ after, depanning is the moulding product, the moulding product surface prepares finished product through polishing, waxing, paint after handling.
Embodiment 2
Dalle
Each component of the raw material of matrix material comprises: according to mass fraction:
10 parts in Natural manganese dioxide
10 parts of magnesium chloride solutions
3 parts of silicon-dioxide and titanium oxide (according to any mass ratio)
10 parts in sand or sawdust powder or bamboo powder.
When mixing, add versicolor pigment, this pigment is used pigment for finishing material commonly used, and the color of adding and consumption can be according to the color needs adjustment of product.
When mixing, add glass fiber, the addition of said glass fiber is: 4 parts; Add glass fiber and increase toughness of products.
The preparation process is:
At first, state the product that mould is planted and carved making or directly buy various material outward appearances with woodcarving, stone carving or mud carver, or produce mould with silica gel, gypsum or glass reinforced plastic, plastics, leather, iron or steel according to the production dalle mould of making.
Before the preparation with mould waxing or go up releasing agent so that product is detached mould; Is 1 with magnesium chloride and water according to mass ratio: the ratio of 1-2 was melted in water in advance in 12 hours; Again with other raw material mixing and stirring proportionally; Pour in the mould; After natural coagulation 10 hours or heat was solidified to 25 ℃-30 ℃ in held 4-6 hour, depanning was the moulding product, the moulding product surface through polishing, waxing, use low temperature glaze to do to prepare finished product after handle on the surface.
Embodiment 3
Embossment
Each component of the raw material of matrix material comprises: according to mass fraction:
9 parts in Natural manganese dioxide
9 parts of magnesium chloride solutions
2 parts of silicon-dioxide and titanium oxide (according to any mass ratio)
5 parts in sand or sawdust powder or bamboo powder.
When mixing, can also add versicolor pigment, this pigment is used pigment for finishing material commonly used, and the color of adding and consumption can be according to the color needs adjustment of product.
Also comprise glass fiber in the raw material in the said matrix material, when mixing, add that the addition of said glass fiber is: 2-3 part; Add glass fiber and increase toughness of products.
The preparation process is:
At first make relief die according to the embossment of making; The product of various material outward appearances is made or directly bought to said mould with woodcarving, stone carving or the mud carver engraving of planting, or produce relief die with silica gel, gypsum or glass reinforced plastic, plastics, leather, iron or steel can.
Before the preparation with mould waxing or go up releasing agent so that product is detached mould; Is that 1: 1.5 ratio was melted in water in advance in 12 hours with magnesium chloride and water according to mass ratio; Again with other raw material mixing and stirring proportionally; Pour in the mould; Natural coagulation 8-9 hour or heat solidified in 3 hours to 50 ℃ of held after, depanning is the moulding product, the moulding product surface is through polishing, waxing, paint, cement paint or use low temperature glaze to do to prepare finished product after handle on the surface.
Claims (7)
1. environment-friendly composite material, it is characterized in that: the raw material of said matrix material comprises: making base-material with Natural manganese dioxide and magnesium chloride, is filler with sawdust powder or sand or bamboo powder, adds with silicon-dioxide and titanium oxide as promoting agent; The preparation method is: is that the ratio of 1:1-2 was melted in water in advance in 12 hours with magnesium chloride and water according to mass ratio, stirs with other raw materials mix again, pours in the mould, and after natural coagulation or heat was solidified, depanning was prepared into the matrix material of moulding;
Each component of the raw material of said matrix material comprises: according to mass fraction:
Natural manganese dioxide 8-10 part
Magnesium chloride 8-10 part
Silicon-dioxide and titanium oxide 1-3 part
Sand or sawdust powder or bamboo powder 3-10 part.
2. environment-friendly composite material according to claim 1 is characterized in that: also add versicolor pigment in the said matrix material.
3. environment-friendly composite material according to claim 2 is characterized in that: described pigment is iron oxide pigment.
4. environment-friendly composite material according to claim 1 is characterized in that: also comprise glass fiber in the raw material in the said matrix material, the addition of said glass fiber according to mass fraction is: 0-4 part.
5. application like claim 1,2,3 or 4 described environment-friendly composite materials is characterized in that: described environment-friendly composite material is used to prepare tea tray, tea set, embossment, various dalle with engraving effect.
6. the application of environment-friendly composite material according to claim 5; It is characterized in that: described environment-friendly composite material is used to prepare tea tray, tea set, embossment, various preparation process with dalle of engraving effect and is: at first according to the production mould of making, before the preparation with the mould waxing or go up releasing agent so that product is detached mould; Is that the ratio of 1:1-2 was melted in water in advance in 12 hours with magnesium chloride and water according to mass ratio; Again with other raw material mixing and stirring proportionally; Pour in the mould; The natural room temperature held solidified in 3-10 hour or heat solidified in held 3-10 hour to 25 ℃-50 ℃ after, depanning is the moulding product, the moulding product surface is through polishing, waxing, paint, cement paint or use low temperature glaze to do to prepare finished product after handle on the surface.
7. the application of environment-friendly composite material according to claim 6; It is characterized in that: said mould is planted with woodcarving, stone carving or mud carver and is carved the product of making or directly buying various material outward appearances, or produces mould with silica gel, gypsum or glass reinforced plastic, plastics, leather, iron or steel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009103039178A CN101591162B (en) | 2009-07-01 | 2009-07-01 | Novel environment-friendly composite material and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009103039178A CN101591162B (en) | 2009-07-01 | 2009-07-01 | Novel environment-friendly composite material and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101591162A CN101591162A (en) | 2009-12-02 |
| CN101591162B true CN101591162B (en) | 2012-01-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009103039178A Expired - Fee Related CN101591162B (en) | 2009-07-01 | 2009-07-01 | Novel environment-friendly composite material and application thereof |
Country Status (1)
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| CN (1) | CN101591162B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102152701B (en) * | 2010-12-31 | 2013-06-26 | 卢云山 | Durable sand sculpture process |
| CN102777762A (en) * | 2012-07-24 | 2012-11-14 | 梁绍勇 | Ecological composite plate |
| CN104692713A (en) * | 2015-02-05 | 2015-06-10 | 安徽忠盛新型装饰材料有限公司 | Waste porcelain powder composite environment-friendly decorative plate and preparation method thereof |
| CN105645910A (en) * | 2015-12-31 | 2016-06-08 | 文登蓝岛建筑工程有限公司 | Sheet material with radiation protection function and preparation method thereof |
| CN107796556A (en) * | 2017-09-23 | 2018-03-13 | 南京律智诚专利技术开发有限公司 | A kind of production method of acidproof pressure transmitter |
| CN107775789B (en) * | 2017-11-03 | 2020-06-09 | 钦州学院 | Manufacturing process of high-strength nixing pottery gypsum mold |
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| US7052542B2 (en) * | 2002-04-12 | 2006-05-30 | American As Recycle Technique Co., Ltd. | Composition for construction material and its method of making and using the same |
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2009
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7052542B2 (en) * | 2002-04-12 | 2006-05-30 | American As Recycle Technique Co., Ltd. | Composition for construction material and its method of making and using the same |
| CN101007725A (en) * | 2007-01-29 | 2007-08-01 | 王惠陵 | Water-resistant chlorine oxygen magnesium silicon series composite material and its preparing process |
Non-Patent Citations (2)
| Title |
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| CN101591162A (en) | 2009-12-02 |
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